WO2011036002A1 - Compositions de polymères du propylène - Google Patents

Compositions de polymères du propylène Download PDF

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Publication number
WO2011036002A1
WO2011036002A1 PCT/EP2010/062225 EP2010062225W WO2011036002A1 WO 2011036002 A1 WO2011036002 A1 WO 2011036002A1 EP 2010062225 W EP2010062225 W EP 2010062225W WO 2011036002 A1 WO2011036002 A1 WO 2011036002A1
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WO
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Prior art keywords
propylene
polymerization
xylene
composition
iso
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PCT/EP2010/062225
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English (en)
Inventor
Marco Ciarafoni
Paola Massari
Gisella Biondini
Tiziana Caputo
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Basell Poliolefine Italia S.R.L.
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Publication of WO2011036002A1 publication Critical patent/WO2011036002A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/02—Heterophasic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst

Definitions

  • the present invention relates to a propylene polymer composition having an optimum balance of properties in particular improved impact strength at room temperature.
  • the isotactic polypropylene is endowed with an exceptional combination of excellent properties which render it suitable for a very great number of uses.
  • one or more copolymerization steps or one or more monomer have been introduced in the homopolymer matrix.
  • WO 05/014713 relates to a heterophasic polyolefin composition comprising (percent by weight):
  • a crystalline propylene polymer selected from propylene homopolymer and random polymer of propylene with 0.1-10% of an a-olefin selected from ethylene, a C4-C 10 alpha-olefin and a mixture thereof, the said polymer being insoluble in xylene at ambient temperature in an amount over 85% and having a polydispersity index ranging from 4 to 13, preferably 4.5 to 12, more preferably 5 to 9, and an intrinsic viscosity value over 2.2 dl/g, preferably 2.2 to 4.5 dl/g; and
  • WO 2006/037705 relates to an olefin polymer composition comprising (by weight, unless otherwise specified):
  • the olefin polymer composition according to the present invention exhibits a value of elongation at break ranging from 150 to 600%, preferably 200-500%, according to ISO method 527.
  • the object of the present invention is a propylene composition comprising (percent by weight):
  • P.I. Polydispersity Index
  • composition having an intrinsic viscosity of the fraction soluble in xylene at 25 °C comprised between 3.0 and 5.0 dl/g; preferably between 3.5 and 5.0 dl/g more preferably between 3.8 and 4.5 dl/g.
  • copolymer includes polymers containing only two kinds of comonomers.
  • compositions of the present invention are:
  • MFR L Melt Flow Rate according to ISO 1 133, condition L, i.e. 230°C and 2.16 kg load
  • 5 to 60 g/10 min in particular from 10 to 50 g/10 min.; more preferably from 15 to 40 g/10 min even more preferably from 20 to 30 g/10 min .
  • compositions of the present invention preferably are endowed with some or all these properties:
  • a Flexural Modulus is comprised between 1000 MPa and 2000 MPa; preferably from 1510 MPa to 1900 MPa; even more preferably from 1540 MPa to 1850 MPa;
  • the propylene polymer compositions of the present invention can be prepared by sequential polymerization in at least two stages, with each subsequent polymerization stage being conducted in the presence of the polymeric material formed in the immediately preceding polymerization reaction, wherein the copolymer (A) is normally prepared in at least one first polymerization stage and the copolymer (B) is normally prepared in at least one second polymerization stage.
  • each polymerization stage is carried out in presence of a highly stereospecific heterogeneous Ziegler-Natta catalyst.
  • the Ziegler-Natta catalysts suitable for producing the propylene polymer compositions of the invention comprise a solid catalyst component comprising at least one titanium compound having at least one titanium-halogen bond and at least an electron-donor compound (internal donor), both supported on magnesium chloride.
  • the Ziegler-Natta catalysts systems further comprise an organo-aluminum compound as essential co- catalyst and optionally an external electron-donor compound.
  • Suitable catalysts systems are described in the European patents EP45977, EP361494, EP728769, EP 1272533 and in the international patent application W000163261.
  • the solid catalyst component comprises Mg, Ti, halogen and an electron donor selected from succinates of formula (I):
  • radicals R 1 and R 2 are a Q-C20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms belonging to groups 15-17 of the periodic table;
  • the radicals R 3 to R 6 equal to or different from each other, are hydrogen or a C1-C2 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms, and the radicals R 3 to R 6 which are joined to the same carbon atom can be linked together to form a cycle.
  • R and R are preferably Ci-Cs alkyl, cycloalkyl, aryl, arylalkyl and alkylaryl groups. Particularly preferred are the compounds in which R 1 and R 2 are selected from primary alkyls and
  • R and R groups are methyl, ethyl, n-propyl, n-butyl, isobutyl, neopentyl, 2-ethylhexyl. Particularly preferred are ethyl, isobutyl, and neopentyl.
  • R to R are hydrogen and R 6 is a branched alkyl, cycloalkyl, aryl, arylalkyl and alkylaryl radical having from 3 to 10 carbon atoms.
  • R 6 is a branched alkyl, cycloalkyl, aryl, arylalkyl and alkylaryl radical having from 3 to 10 carbon atoms.
  • Another preferred group of compounds within those of formula (I) is that in which at least two radicals from R 3 to R 6 are different from hydrogen and are selected from Q-C 20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms belonging to groups.
  • the solid catalyst component can be prepared by reacting a titanium compound of formula Ti(OR) n _ y X y where n is the valence of titanium and y is a number between 1 and n, preferably TiC4, with a magnesium chloride deriving from an adduct of formula MgCi 2 -pROH, where p is a number between 0.1 and 6, preferably from 2 to 3.5, and R is a hydrocarbon radical having 1-18 carbon atoms.
  • the adduct can be suitably prepared in spherical form by mixing alcohol and magnesium chloride in the presence of an inert hydrocarbon immiscible with the adduct, operating under stirring conditions at the melting temperature of the adduct (100-130 "C). Then, the emulsion is quickly quenched, thereby causing the solidification of the adduct in form of spherical particles. Examples of spherical adducts prepared according to this procedure are described in US 4,399,054 and US 4,469,648.
  • the so obtained adduct can be directly reacted with the Ti compound or it can be previously subjected to thermal controlled dealcoholation (80-130 °C) so as to obtain an adduct in which the number of moles of alcohol is generally lower than 3, preferably between 0.1 and 2.5.
  • the reaction with the Ti compound can be carried out by suspending the adduct (dealcoholated or as such) in cold T1CI 4 (generally 0 °C); the mixture is heated up to 80-130 °C and kept at this temperature for 0.5-2 hours.
  • the treatment with Tic4 can be carried out one or more times.
  • the internal donor can be added during the treatment with T1CI 4 and the treatment with the electron donor compound can be repeated one or more times.
  • the succinate of formula (I) is used in molar ratio with respect to the MgC12 of from 0.01 to 1 preferably from 0.05 to 0.5.
  • the preparation of catalyst components in spherical form is described for example in European patent application EP-A-395083 and in the International patent application W098144001.
  • the solid catalyst components obtained according to the above method show a surface area (by B.E.T. method) generally between 20 and 500 m21g and preferably between 50 and 400 m21g, and a total porosity (by B.E.T. method) higher than 0.2 cm31 g preferably between 0.2 and 0.6 cm31g.
  • the porosity (Hg method) due to pores with radius up to 10.000A generally ranges from 0.3 to 1.5 cm31g, preferably from 0.45 to 1 cm31g.
  • the organo-aluminum compound is preferably an alkyl-Al selected from the trialkyl aluminum compounds such as for example triethylaluminum, triisobutylaluminum, tri-n-butylaluminum, tri- n-hexylaluminum, tri-n-octylaluminum. It is also possible to use mixtures of trialkylaluminum's with alkylaluminum halides, alkylaluminum hydrides or alkylaluminum sesquichlorides such as
  • Preferred external electron-donor compounds include silicon compounds, ethers, esters such as ethyl 4-ethoxybenzoate, amines, heterocyclic compounds and particularly 2,2,6,6-tetramethyl piperidine, ketones and the 1 ,3-diethers.
  • Another class of preferred external donor compounds is that of silicon compounds of formula R a 5 Rb 6 Si(OR 7 ) c where a and b are integer from 0 to 2, c is an integer from 1 to 3 and the sum (a+b+c) is 4; R 5 , R 6 , and R 7 , are alkyl, cycloalkyl or aryl radicals with 1-18 carbon atoms optionally containing heteroatoms.
  • methylcyclohexyldimethoxysilane diphenyldimethoxysilane, methyl-t-butyldimethoxysilane, dicyclopentyldimethoxysilane, 2-ethylpiperidinyl-2-t-butyldimethoxysilane and 1,1 ,1 ,trifluoropropyl-2-ethylpiperidinyl-dimethoxysilane and 1,1 ,1 ,trifiuoropropyl- metildimethoxysilane.
  • the external electron donor compound is used in such an amount to give a molar ratio between the organo-aluminum compound and said electron donor compound of from 0.1 to 500.
  • the polymerization process can be carried out in gas phase andlor in liquid phase, in continuous or batch reactors, such as fiuidized bed or slurry reactors.
  • continuous or batch reactors such as fiuidized bed or slurry reactors.
  • all the sequential polymerization stages can be carried out in gas phase.
  • the reaction time, temperature and pressure of the polymerization steps are not critical, however the temperature for the preparation of fraction (A) and (B), that can be the same or different, is usually from 50°C to 120°C.
  • the polymerization pressure preferably ranges from 0.5 to 12 MPa if the polymerization is carried out in gas-phase.
  • the catalytic system can be pre-contacted (pre- polymerized) with small amounts of olefins.
  • the molecular weight of the propylene polymer composition is regulated by using known regulators, such as hydrogen.
  • the propylene polymer (A) is produced by a gas-phase polymerization process carried out in at least two interconnected polymerization zones. Said polymerization process is described in the European patent EP 782587.
  • the process is carried out in a first and in a second interconnected polymerization zone to which propylene and ethylene or propylene and alpha-olefins are fed in the presence of a catalyst system and from which the polymer produced is discharged.
  • the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said first polymerization zone and enter the second of said polymerization zones (downcomer) through which they flow in a densified form under the action of gravity, leave said second polymerization zone and are reintroduced into said first polymerization zone, thus establishing a circulation of polymer between the two polymerization zones.
  • the conditions of fast fluidization in the first polymerization zone is established by feeding the monomers gas mixture below the point of reintroduction of the growing polymer into said first polymerization zone.
  • the velocity of the transport gas into the first polymerization zone is higher than the transport velocity under the operating conditions and is normally between 2 and 15 m/s
  • the second polymerization zone where the polymer flows in densified form under the action of gravity, high values of density of the solid are reached which approach the bulk density of the polymer; a positive gain in pressure can thus be obtained along the direction of flow, so that it becomes possible to reintroduce the polymer into the first reaction zone without the help of mechanical means.
  • a "loop" circulation is set up, which is defined by the balance of pressures between the two polymerization zones and by the head loss introduced into the system.
  • one or more inert gases such as nitrogen or an aliphatic hydrocarbon, are maintained in the polymerization zones, in such quantities that the sum of the partial pressures of the inert gases is preferably between 5 and 80% of the total pressure of the gases.
  • the operating parameters such as, for example, the temperature are those that are usual in gas-phase olefin polymerization processes, for example between 50°C and 120°C.
  • the process can be carried out under operating pressure of between 0,5 and 10 MPa, preferably between 1.5 and 6 MPa.
  • the various catalyst components are fed to the first polymerization zone, at any point of said first polymerization zone. However, they can also be fed at any point of the second polymerization zone.
  • Molecular weight regulators known in the art, particularly hydrogen, can be used to regulate the molecular weight of the growing polymer.
  • the propylene/ethylene copolymer (B) is produced in a conventional fluidized-bed gas-phase reactor in the presence of the polymeric material and the catalyst system coming from the preceding polymerization step.
  • the polymerization mixture is discharged from the downcomer to a gas-solid separator, and subsequently fed to the fluidized-bed gas-phase reactor operating under conventional conditions of temperature and pressure.
  • the propylene polymer compositions of the present invention can also be obtained by separately preparing the said copolymers (A) and (B), operating with the same catalysts and substantially under the same polymerization conditions as previously illustrated and subsequently mechanically blending said copolymers in the molten state using conventional mixing apparatuses, like twin-screw extruders.
  • the propylene polymer compositions of the present invention may further comprise additives commonly employed in the polyolefin field, such as antioxidants, light stabilizers, nucleating agents, antiacids, colorants and fillers.
  • additives commonly employed in the polyolefin field such as antioxidants, light stabilizers, nucleating agents, antiacids, colorants and fillers.
  • the main application of the propylene polymer compositions of the invention is the production of molded articles, particularly injection-molded items.
  • the injection-molded articles comprising the propylene polymer compositions of the invention have good flexibility and good impact properties and are also endowed with good transparency.
  • the comonomer content of the Component B is determined on the precipitated "amorphous" fraction of the polymer.
  • the precipitated "amorphous" fraction is obtained as follows: to one 100 ml aliquot of the filtered liquid obtained as described above (procedure for the Xylene-soluble faction) 200 ml of acetone are added under vigorous stirring. Precipitation must be complete as evidenced by a clear solid-solution separation. The solid thus obtained is filtered on a tared metallic screen and dried in a vacuum oven at 70°C until a constant weight is reached.
  • the melting and crystallization temperatures were measured by Differential Scanning Calorimetry (DSC) on a Perkin Elmer DSC-1 calorimeter equipped with the Pyris 1 software performing scans in a flowing N 2 atmosphere.
  • the DSC apparatus was previously calibrated at indium and zinc melting points with particular attention in determining the baseline with required accuracy.
  • the preparation of the samples, for calorimetric investigations, was performed by cutting them into small pieces by using a cutter. The weight of the samples in every DSC crucible was kept at 6.0 ⁇ 0.5 mg.
  • the weighted sample was sealed into aluminium pans and heated to 180°C at 20°C/minute.
  • the sample was kept at 180°C for 5 minutes to allow a complete melting of all the crystallites, and then cooled down to - 20°C at 20°C/minute. After standing 2 minutes at -20°C, the sample was heated for the second time to 180°C at 20°C/min.
  • PI Polydispersity Index
  • modulus separation is defined as:
  • G' is the storage modulus and G" is the loss modulus.
  • the Ziegler-Natta catalyst was prepared according to the Example 5, lines 48-55 of the European Patent EP728769. Triethylalurninium (TEAL) was used as co-catalyst and
  • the propylene polymer compositions of the examples were prepared in a two-step polymerization process, wherein the copolymer (A) was prepared in the first polymerization step by feeding the monomers and the catalyst system to a gas-phase polymerization reactor comprising two interconnected polymerization zones, a riser and a downcomer, as described in the European Patent EP782587.
  • the polymerization mixture was discharged from said reactor, conveyed to a gas-solid separator and the polymerized material was sent into a conventional gas- phase fiuidized-bed reactor where the propylenelethylene copolymer (B) was produced.
  • the operative conditions are indicated in Table 1.
  • the polymer particles exiting from the second polymerization step were subjected to a steam treatment to remove the unreacted monomers and dried.
  • Component B gas phase reactor

Abstract

L'invention porte sur une composition à base de propylène comprenant (en pourcentage en poids) : A) 70 % à 95 % d'un homopolymère du propylène ayant une valeur d'indice de polydispersité (P. I.) de 4,6 à 10, une fraction insoluble dans le xylène à 25°C supérieure à 90 % et un MFR L (Indice de fluage selon la norme ISO 1133, dans les conditions L, c'est-à-dire à 230°C et sous une charge de 21,16 kg) de 47 à 90 g/10 min ; B) 5 % à 30 % d'un copolymère du propylène contenant de 40 % à 34,5 %, les valeurs extrêmes étant incluses, de motifs issus de l'éthylène ; la composition ayant une viscosité intrinsèque de la fraction soluble dans le xylène à 25°C comprise entre 3 et 5 dl/g.
PCT/EP2010/062225 2009-09-22 2010-08-23 Compositions de polymères du propylène WO2011036002A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP09170966 2009-09-22
EP09170966.7 2009-09-22
US27775509P 2009-09-29 2009-09-29
US61/277,755 2009-09-29

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3094681B1 (fr) 2014-01-15 2021-01-20 ExxonMobil Chemical Patents Inc. Copolymères choc à base de propylène

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0045977A2 (fr) 1980-08-13 1982-02-17 Montedison S.p.A. Composants et catalyseurs pour la polymérisation d'oléfines
US4399054A (en) 1978-08-22 1983-08-16 Montedison S.P.A. Catalyst components and catalysts for the polymerization of alpha-olefins
US4469648A (en) 1978-06-13 1984-09-04 Montedison S.P.A. Process for preparing spheroidally shaped products, solid at room temperature
EP0361494A2 (fr) 1988-09-30 1990-04-04 Montell North America Inc. Composants et catalyseurs pour la polymérisation d'oléfines
EP0395083A2 (fr) 1989-04-28 1990-10-31 Montell North America Inc. Composant et catalyseur pour polymérisation d'oléfines
EP0728769A1 (fr) 1995-02-21 1996-08-28 Montell North America Inc. Composants et catalyseurs pour la polymérisation d'oléfines
EP0782587A1 (fr) 1995-07-20 1997-07-09 Montell Technology Company bv Procede et appareil de polymerisation en phase gazeuse d'alpha-olefines
WO1998044001A1 (fr) 1997-03-27 1998-10-08 Commonwealth Scientific And Industrial Research Organisation Reactifs polyvalents presentant une avidite elevee et une specificite multiple
WO2000063261A1 (fr) 1999-04-15 2000-10-26 Basell Technology Company B.V. Constituants et catalyseurs de polymerisation d'olefines
EP1272533A1 (fr) 2000-10-13 2003-01-08 Basell Poliolefine Italia S.p.A. Constituants de catalyseur pour la polymerisation d'olefines
WO2005014713A1 (fr) 2003-08-05 2005-02-17 Basell Poliolefine Italia S.R.L. Articles a base de polyolefines
WO2005113672A1 (fr) * 2004-05-21 2005-12-01 Basell Poliolefine Italia S.R.L. Compositions polyoléfines résistantes aux chocs
WO2006037705A1 (fr) 2004-10-04 2006-04-13 Basell Poliolefine Italia S.R.L. Compositions polyolefiniques elastomeres
WO2006067023A1 (fr) * 2004-12-23 2006-06-29 Basell Poliolefine Italia S.R.L. Composition polyolefiniques ayant une bonne resistance au blanchiment

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4469648A (en) 1978-06-13 1984-09-04 Montedison S.P.A. Process for preparing spheroidally shaped products, solid at room temperature
US4399054A (en) 1978-08-22 1983-08-16 Montedison S.P.A. Catalyst components and catalysts for the polymerization of alpha-olefins
EP0045977A2 (fr) 1980-08-13 1982-02-17 Montedison S.p.A. Composants et catalyseurs pour la polymérisation d'oléfines
EP0361494A2 (fr) 1988-09-30 1990-04-04 Montell North America Inc. Composants et catalyseurs pour la polymérisation d'oléfines
EP0395083A2 (fr) 1989-04-28 1990-10-31 Montell North America Inc. Composant et catalyseur pour polymérisation d'oléfines
EP0728769A1 (fr) 1995-02-21 1996-08-28 Montell North America Inc. Composants et catalyseurs pour la polymérisation d'oléfines
EP0782587A1 (fr) 1995-07-20 1997-07-09 Montell Technology Company bv Procede et appareil de polymerisation en phase gazeuse d'alpha-olefines
WO1998044001A1 (fr) 1997-03-27 1998-10-08 Commonwealth Scientific And Industrial Research Organisation Reactifs polyvalents presentant une avidite elevee et une specificite multiple
WO2000063261A1 (fr) 1999-04-15 2000-10-26 Basell Technology Company B.V. Constituants et catalyseurs de polymerisation d'olefines
EP1272533A1 (fr) 2000-10-13 2003-01-08 Basell Poliolefine Italia S.p.A. Constituants de catalyseur pour la polymerisation d'olefines
WO2005014713A1 (fr) 2003-08-05 2005-02-17 Basell Poliolefine Italia S.R.L. Articles a base de polyolefines
WO2005113672A1 (fr) * 2004-05-21 2005-12-01 Basell Poliolefine Italia S.R.L. Compositions polyoléfines résistantes aux chocs
WO2006037705A1 (fr) 2004-10-04 2006-04-13 Basell Poliolefine Italia S.R.L. Compositions polyolefiniques elastomeres
WO2006067023A1 (fr) * 2004-12-23 2006-06-29 Basell Poliolefine Italia S.R.L. Composition polyolefiniques ayant une bonne resistance au blanchiment

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3094681B1 (fr) 2014-01-15 2021-01-20 ExxonMobil Chemical Patents Inc. Copolymères choc à base de propylène

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