WO2011033563A1 - Method of manufacturing hollow continuous body - Google Patents

Method of manufacturing hollow continuous body Download PDF

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Publication number
WO2011033563A1
WO2011033563A1 PCT/JP2009/004659 JP2009004659W WO2011033563A1 WO 2011033563 A1 WO2011033563 A1 WO 2011033563A1 JP 2009004659 W JP2009004659 W JP 2009004659W WO 2011033563 A1 WO2011033563 A1 WO 2011033563A1
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WO
WIPO (PCT)
Prior art keywords
hollow
continuous body
joining
objects
fusion
Prior art date
Application number
PCT/JP2009/004659
Other languages
French (fr)
Japanese (ja)
Inventor
藤木浩之
隅敏則
広本泰夫
倉科正樹
Original Assignee
三菱レイヨン株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 三菱レイヨン株式会社 filed Critical 三菱レイヨン株式会社
Priority to PCT/JP2009/004659 priority Critical patent/WO2011033563A1/en
Priority to CN200980161462.9A priority patent/CN102596540B/en
Priority to KR1020127008809A priority patent/KR101382944B1/en
Priority to JP2009543686A priority patent/JP5430405B2/en
Publication of WO2011033563A1 publication Critical patent/WO2011033563A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08Hollow fibre membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08Hollow fibre membranes
    • B01D69/082Hollow fibre membranes characterised by the cross-sectional shape of the fibre
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10Supported membranes; Membrane supports
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/08Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using ultrasonic vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/78Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus
    • B29C65/7841Holding or clamping means for handling purposes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • B29C66/1122Single lap to lap joints, i.e. overlap joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/52Joining tubular articles, bars or profiled elements
    • B29C66/522Joining tubular articles
    • B29C66/5227Joining tubular articles for forming multi-tubular articles by longitudinally joining elementary tubular articles wall-to-wall (e.g. joining the wall of a first tubular article to the wall of a second tubular article) or for forming multilayer tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/81General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps
    • B29C66/814General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps
    • B29C66/8141General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined
    • B29C66/81411General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined characterised by its cross-section, e.g. transversal or longitudinal, being non-flat
    • B29C66/81421General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined characterised by its cross-section, e.g. transversal or longitudinal, being non-flat being convex or concave
    • B29C66/81423General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined characterised by its cross-section, e.g. transversal or longitudinal, being non-flat being convex or concave being concave
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/83General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/832Reciprocating joining or pressing tools
    • B29C66/8322Joining or pressing tools reciprocating along one axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/42Details of membrane preparation apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding

Definitions

  • the present invention relates to a method for producing a hollow continuous body used as a support for producing a hollow fiber membrane or a hollow fiber membrane.
  • a hollow fiber membrane production support is sent out from the center hole of the annular nozzle, and the membrane is spun from the outer circumference of the annular nozzle to the outer circumference of the hollow fiber membrane production support.
  • the stock solution is applied and solidified to obtain a hollow fiber membrane.
  • the support for producing a hollow fiber membrane also needs to be long.
  • the length of the support for producing the hollow fiber membrane is a hollow fiber. Because it is shorter than the desired length of the membrane, multiple supports must be joined.
  • Patent Document 4 discloses that a plastic round string is overlapped or twisted in parallel, and partially heat-pressed at regular intervals to alternately form heat-bonded portions and non-heat-bonded portions. There has been proposed a method of joining the two.
  • the joining method described in Patent Document 4 is applied to a hollow object such as a support for manufacturing a hollow fiber membrane, the heat-sealed portion is slightly smaller than the combined size of the two hollow objects.
  • the non-heat-sealed portion has a size obtained by combining two hollow objects.
  • a step is formed on the side surface after joining, and when the obtained continuous body is passed through a portion where the outer diameter is regulated, such as the center hole of the annular nozzle, Clogging and catching occur, and the production stability of the hollow fiber membrane is reduced.
  • Patent Document 5 a method has been proposed in which after knitting an elastic cord body, the stitches are folded and overlapped, and fused by ultrasonic vibration or heating (see Patent Document 5).
  • the fusion in Patent Document 5 does not join two string bodies to obtain one continuous body.
  • the object to be fused is a solid string, a step is formed on any part of the side surface after joining.
  • the object of the present invention is to prevent hollow fiber membrane production methods such as lack of bonding strength and increase in the diameter of the joining portion of hollow materials represented by a support, and to produce hollow fiber membranes without greatly impairing flexibility.
  • Another object of the present invention is to provide a method for producing a hollow continuum in which deterioration in process stability during processing is prevented.
  • the gist of the present invention is that a pair of hollow objects are arranged so that their end portions are in contact with each other, or each end portion is in contact with one connecting member on its outer peripheral surface, and then the ends thereof are arranged.
  • the whole part is compressed and deformed and then joined.
  • a hollow continuous body of the present invention it is possible to prevent problems such as insufficient joining strength and an increase in diameter of the joined portion of the hollow article, and at the time of hollow fiber membrane production and processing without greatly impairing flexibility.
  • a hollow continuous body in which a decrease in process stability is prevented can be produced.
  • connection apparatus used by one Embodiment of the manufacturing method of the hollow continuous body of this invention. It is a figure which shows the state which inserted the hollow thing adjacent to the connection jig. It is sectional drawing which shows the aspect which inserted the edge part of a pair of hollow thing into the groove
  • the hollow material referred to in the present invention is a material having a continuous space along the longitudinal direction, so that the inside of the fiber, the solid monofilament or the multifilament becomes hollow.
  • the shape of the hollow portion is not particularly limited, but a substantially circular shape is preferable.
  • the outer diameter of the hollow material is not particularly limited, but is preferably 0.5 to 5 mm.
  • the inner diameter is preferably 0.2 to 4 mm.
  • the inner diameter is determined so that the volume of the hollow portion of the hollow article is 10 to 90%, preferably 20 to 80% of the volume of the hollow article obtained from the outer diameter of the hollow article. Is preferred.
  • the material of the hollow material is not particularly limited, but a material that can be fused is preferable. Specific examples include polyethylene terephthalate, nylon, polyethylene, polypropylene, polyvinyl chloride, polysulfone, polyacrylonitrile, cellulose acetate, and polyvinylidene fluoride. These may be used alone or in combination.
  • the pair of hollow objects may be made of the same material, may be different, or may be a combination of these.
  • the pair of hollow objects are arranged such that the end portions thereof are in contact with each other, or each end portion is in contact with one connecting member on the outer peripheral surface thereof.
  • the length of the contact portion in the yarn length direction of the contact portion is appropriately determined according to the desired bonding strength and flexibility after bonding.
  • the ratio of the larger outer diameter (mm) is preferably 1 or more.
  • the length A of the contact portion which will later correspond to the length of the joined portion, is preferably in the range of 5 mm to 1550 mm, more preferably 5 mm to 100 mm, and most preferably 10 mm to 40 mm.
  • the connecting member is a member for joining hollow objects, and can be easily joined to the hollow object, and is necessary for stably passing through the hollow fiber membrane manufacturing process and processing process. Those capable of maintaining strength and flexibility are preferred. Specifically, fiber bundles, hollow or solid braids, hollow or solid braids, strips of fiber knitted fabric, porous rods, porous strips, etc. Is mentioned. Further, when compressing and deforming the joint portion to join, a hollow continuous body having no step on the side surface is obtained, and as the connecting member, a material having a large volume reduction rate at the time of compressive deformation is preferable.
  • the connecting member it is preferable to use a member made of the same material as the hollow material to be joined in terms of thermal characteristics and chemical resistance.
  • the connecting member is disposed so as to be in contact with each end portion of the pair of hollow objects and the outer peripheral surface thereof. In this case, since the contact portion becomes the connection portion, in order to make an effective connection, it is preferable that the contact surface is made large and is closely attached so that a gap is not generated as much as possible.
  • a method of compressing and deforming is not particularly limited, and examples thereof include a method of applying a constant load with a weight, an air cylinder, or the like.
  • the load to be applied can be changed by increasing or decreasing the supply air pressure, and the load supply and removal can be easily performed by reversing the cylinder supply direction of the supply air with a valve or the like.
  • the bonding method include a bonding method using an adhesive and a bonding method using fusion.
  • the method is not particularly limited. For example, after applying an appropriate amount of adhesive to the connection surfaces of the hollow objects or between the hollow object and the joining member, it is inserted into the connection jig and compressed and deformed. Examples include a method of curing the adhesive while it is left and joining it into a desired shape. Examples of the adhesive used include a solvent evaporation type, a hot melt type, and a reaction curing type.
  • connection time a softness
  • flexibility a softness
  • connection strength a softness
  • connection strength a softness
  • connection strength a connection strength
  • the amount of adhesive used for bonding is such that when the bonded portion is compressed and deformed, the adhesive sufficiently permeates between the hollow objects or the bonding surfaces of the hollow object and the bonding member, and a large amount from the bonding surface to the outside. It is preferable to select an amount that does not flow out to the connection jig and adhere to the connection jig according to the porosity of the hollow object or the joining member.
  • connection jig when the adhesive adheres and hardens on the inner surface of the connection jig, it is preferable to perform a releasable surface treatment such as a fluorine resin coating so that the bonded portion and the connection jig can be easily separated.
  • the method is not particularly limited.
  • a method of compressing and deforming with a connecting jig and then bringing it into contact with a heated connecting jig for fusing and joining there may be mentioned a method of compressing and deforming with a connecting jig and then bringing it into contact with a heated connecting jig for fusing and joining.
  • the heating temperature at that time is preferably about 250 ° C. to 280 ° C., which is a temperature near the melting point.
  • fusion refers to a state in which a part or all of a portion where the ends of a pair of hollow objects are overlapped is melted.
  • a peelable surface treatment is performed so that the bonded portion and the connecting jig can be easily separated in preparation for the case where the hollow objects melted at the time of fusion or the bonding member adhere and cool and solidify.
  • the fusing temperature is high, it is preferable to perform a heat-resistant peelable surface treatment.
  • connection jig When joining by fusion, it is necessary to cool the connection jig once because the shape of the fusion product is not fixed if the connection jig heated in the fused state is released, but fusion is performed by ultrasonic fusion. Since ultrasonic horns, connection jigs and the like are not heated and can be processed for a short time, it is most preferable to perform fusion using ultrasonic waves. In the case of ultrasonic fusion, since the temperature of the connecting jig does not rise, the peelable surface treatment of the inner surface of the connecting jig can use a normal fluorine resin coating.
  • an ultrasonic horn 1 as shown in FIG. 1 and FIG.
  • a connection device comprising a connection jig 2 is used.
  • the lower surface 1a is a surface in contact with the hollow objects 3a and 3b, and ultrasonic waves are transmitted from the lower surface to the hollow objects 3a and 3b.
  • the connection jig 2 of the present manufacturing example is a rectangular plate, and a groove 2a is linearly formed from one side of the plate to a side opposite to the side.
  • the depth of the groove 2a is a pair of hollow plates.
  • the articles 3a and 3b can be stacked and stored.
  • the end portions 3c and 3d of the hollow objects are respectively inserted into the grooves 2a of the connecting jig 2, as shown in FIG.
  • the end of the ultrasonic horn 1 is inserted into the groove 2a and the end portions 3c, 3d are pressed against the bottom of the groove 2a, and the hollow objects 3a, 3b adjacent so that the end portions 3c, 3d overlap each other.
  • the end portions 3c and 3d are compressed and deformed.
  • ultrasonic waves are transmitted from the ultrasonic horn 1 to the end portions 3c and 3d of the adjacent hollow objects 3a and 3b to be fused.
  • the ultrasonic horn 1 When the hollow objects 3a and 3b are fused together using the ultrasonic horn 1, local heat generation occurs due to friction at the contact portions of the hollow objects 3a and 3b, and the bonded parts are thermally deformed and fused. Or the oxide layer on the surface disappears and the interface is activated to form intermolecular bonds. Therefore, even in a wet state where water or other liquid exists between the fibers of the hollow materials 3a and 3b or in the porous portion, the liquid melts. Evaporation and movement from the adhesion interface enable fusion.
  • the shape (hereinafter referred to as a cross-sectional shape) is preferably substantially the same as the cross-sectional shape of one hollow object before being compressed and deformed, that is, approximately circular.
  • a cross-sectional shape is preferably substantially the same as the cross-sectional shape of one hollow object before being compressed and deformed, that is, approximately circular.
  • a method using an ultrasonic horn 1 in which a groove recessed in an arc shape is formed on the lower surface 1 a and a connection jig 2 in which a U-shaped groove 2 a is formed can be employed.
  • the ultrasonic horn 1 is inserted into the groove 2a of the connecting jig 2, a hollow portion having a substantially circular cross section is formed.
  • the connection jig 2 and the ultrasonic horn 1 are used, a minute gap is generated between them, and a burr-like thing may be formed after ultrasonic fusion. A burr-like thing may be generated.
  • the end portions 3c and 3d of the adjacent hollow objects 3a and 3b can be fused at a time.
  • a desired bonding strength can be obtained more easily.
  • the thrust (surface pressure) and the ultrasonic oscillation time applied to compress and deform the hollow object when compressing and deforming the ends of the hollow object are the types of the ultrasonic horn, What is necessary is just to select suitably according to the kind of hollow thing, desired joining strength, and a softness
  • the maximum output and the oscillation frequency in the ultrasonic welder for performing ultrasonic fusion are not particularly limited as long as fusion is possible, but the maximum output is 30 to 2500 W, and the oscillation frequency is 60 kHz to 15. What is necessary is just to select suitably the commercially available welder used as the range of about 15 kHz according to joining conditions.
  • any method may be used for the thrust (surface pressure) applied to compress and deform the hollow object as long as a desired thrust can be applied.
  • a weight, a spring, a method using human power, a method using air pressure, hydraulic pressure, and the like can be given.
  • the power source is air
  • a commercially available compressor or the like can be used to adjust to a desired pressure using a regulator and can be easily supplied.
  • the air cylinder can be used suitably because it can easily change the thrust by changing the supply pressure and can cope with various conditions.
  • the thrust can be obtained by the product of the cross-sectional area obtained from the air cylinder diameter and the air cylinder supply pressure.
  • the end portions of a pair of adjacent hollow objects are not partial, but the entire end portion is compressed and deformed so that the end portions overlap each other. It is possible to prevent problems such as insufficient bonding strength and an increase in diameter of the bonded portion of the shaped article, and to prevent a step from occurring on the side surface of the resulting hollow continuous body. This is because the space portion of the hollow object is compressed by the ultrasonic fusion treatment and deformed so as to decrease or disappear. Therefore, the obtained hollow continuous body is in a straight line, and is less likely to be clogged or caught when passing through a portion whose outer diameter is regulated.
  • the flexibility is not greatly impaired, the travel of the hollow object is stable, and a decrease in process stability during the production and processing of the hollow fiber membrane is prevented.
  • the manufacturing method of the hollow continuous body of the said manufacture example since joining time can be shortened and heating of an ultrasonic horn, a connection jig, etc. is unnecessary, the fusion
  • ultrasonic fusion is performed, bonding can be performed under the same conditions regardless of whether the hollow material is in a dry or wet state. Therefore, a hollow continuous body can be produced efficiently.
  • the hollow continuous body obtained by the above production method can be suitably used as a support for use in producing a hollow fiber membrane.
  • a specific method for producing a hollow fiber membrane using a hollow continuous body as a support a hollow continuous body is fed out from the center hole of the annular nozzle, and the annular nozzle is disposed on the outer periphery of the hollow continuous body.
  • a membrane-forming stock solution spun from the outer periphery is applied and solidified to form a continuous hollow fiber membrane and then cut.
  • the cross-sectional shape of the portion where the ends of the pair of hollow objects overlap each other is made into a substantially circular shape.
  • a substantially circular shape For example, an ellipse, a triangle, a quadrangle, etc. may be used.
  • the ends of a pair of adjacent hollow objects may be divided into a plurality of parts and finally fused together.
  • the fusion part may thermally shrink while the non-fusion part expands, which may impair the running stability of the resulting hollow continuous body.
  • the subsequent fusion treatment acts on the end portion subjected to the fusion treatment first and overmelts, the desired bonding strength may not be obtained. For these reasons, it is preferable to fuse the entire ends of a pair of adjacent hollow objects at one time as in the above embodiment.
  • connection jig 2 and an ultrasonic welder including the ultrasonic horn 1 as shown in FIGS. 1 and 2 were used.
  • Connection jig A U-shaped groove 2a having a depth C of 6.1 mm formed linearly was used.
  • the ultrasonic horn 1 has a tip width E of 2.2 mm and a length D of 40 mm, and a groove recessed in an arc along the length direction is formed on the lower surface 1a as a pressing surface, and moves vertically in the vertical direction. We used what to do. Moreover, the ultrasonic horn 1 was installed so that the tip could enter the groove 2 a of the connection jig 2.
  • a low speed air cylinder was used as the power for the vertical movement of the ultrasonic horn 1. This air cylinder is supplied with air whose pressure is adjusted by a pressure reducing valve and whose exhaust speed is adjusted by a speed controller for low speed.
  • a stopper was provided so that the tip of the ultrasonic horn 1 stopped immediately before the bottom surface of the groove 2 a of the connection jig 2 to prevent contact between the tip of the ultrasonic horn 1 and the bottom surface of the groove 2 a of the connection jig 2.
  • Examples 1 to 18 The hollow body (A) 3a and the hollow body (B) 3b having the combinations shown in Tables 1 to 3 were joined to obtain a continuous body of hollow bodies. Specifically, the end 3c of the hollow object (A) 3a is inserted into the groove 2a of the connection jig 2, and then the end 3d of the hollow object (B) 3b is connected in parallel as shown in Tables 1 to 3. Inserted in parallel with length A. Next, the ultrasonic horn 1 is lowered by supplying air to the air cylinder under the conditions shown in Tables 1 to 3, and thrust (surface pressure) is applied to the hollow object (A) 3a and the hollow object (B) 3b. It was.
  • Example 18 a syringe needle capable of supplying water is inserted into the hollow part from the end of each of the same hollow objects (A) and (B) as in Example 16, and water is put into the hollow part with a pressurized pressure of 200 KPa. Was supplied until water came out from the outer surface of the end of the hollow object to make the hollow object wet.
  • the joint strength of the joint part of the obtained hollow continuous body was measured as follows using a digital force gauge (ZP-500N) manufactured by Imada Corporation. First, a ring that can be hooked at both ends of the hollow continuous body was made, one ring was hung on a fixed hook, and the other ring was hung on a hook of a digital force gauge. Next, the digital force gauge was moved so that the pulling direction of the digital force gauge was substantially vertical or horizontal, and the digital force gauge was turned on with no tensile tension applied to the hollow continuous body, and the display value was reset to zero. And it pulled manually and the breaking load was measured using the peak hold function. The breaking load was measured twice, and the average value was obtained. The measurement results are shown in Tables 1 to 3.
  • the breaking load at the joint portion of the obtained hollow continuous body was sufficiently high.
  • the cross-sectional shape of the joined portion was substantially the same as the cross-sectional shape of the hollow object before compression deformation. Therefore, when the hollow continuum obtained in Examples 1 to 11 was passed through the center hole of the annular nozzle, it passed smoothly without being caught at the joint. Further, when the hollow continuum obtained in Examples 12 to 18 was passed through the hollow fiber membrane production process, it passed smoothly without being caught at the joint portion as in Examples 1 to 11. Therefore, a decrease in process stability in the production of hollow fiber membranes was prevented. Further, by comparing Example 16 and Example 18, it was found that sufficient bonding strength was exhibited regardless of whether the hollow object to be bonded was dry or wet.
  • the manufacturing method of the present invention prevents problems such as insufficient bonding strength and increased diameter of the bonded portion of the hollow material, and prevents deterioration in process stability during hollow fiber membrane manufacturing and processing without greatly impairing flexibility. It is useful for producing a hollow continuous body.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

A method of manufacturing a hollow continuous body, wherein a pair of hollow objects are arranged such that each of the pair of hollow objects is in contact with each other at one end thereof or such that the outer peripheral surface of the end of each of the pair of hollow objects is in contact with a single connecting member, and then the entire ends are joined together after being compressed and deformed.

Description

中空状連続体の製造方法Method for producing hollow continuum
  本発明は、中空糸膜製造用の支持体または中空糸膜等として使用される中空状連続体の製造方法に関する。 The present invention relates to a method for producing a hollow continuous body used as a support for producing a hollow fiber membrane or a hollow fiber membrane.
 近年、環境汚染に対する関心が高まり、環境に関する各種規制法が強化されており、様々な分野でその対策が進められている。例えば、水処理の分野においては、汚染物質を高度に分離するために、小型の濾過膜を用いた処理が検討されている。
 ところで、濾過膜を水処理に使用する場合には、高い機械的物性(例えば、耐圧性、引張強度等)が求められる。機械的強度に優れた多孔質の濾過膜を製造する方法としては、中空状の丸打ちの組紐を中空糸膜支持体として用いた中空糸膜の製造方法が提案されている(特許文献1,2,3参照)。この製造方法では、具体的には、環状ノズルの中心孔から中空糸膜製造用支持体を送出させ、その中空糸膜製造用支持体の外周に、環状ノズルの外周から紡出させた製膜原液を塗布し、凝固させて、中空糸膜を得る。
 上記製造方法において、長尺の中空糸膜を得るためには、中空糸膜製造用支持体も長尺である必要があるが、通常、前記中空糸膜製造用支持体の長さは中空糸膜の所望の長さより短いため、複数の支持体を接合しなければならない。
中空糸膜の製造工程においては、通過工程中に中空糸膜の外径に近く、パイプのように閉じた形状の通過部がある。このため、中空糸膜製造用支持体同士を結ぶなどして作られた連続体を使用すると、接合部の外径が他の部分より大きくなるため、中空糸膜を連続走行させながら工程を通過させることが困難となる。  
In recent years, interest in environmental pollution has increased, and various environmental laws have been strengthened, and countermeasures are being promoted in various fields. For example, in the field of water treatment, treatment using a small filtration membrane is being studied in order to highly separate contaminants.
By the way, when using a filtration membrane for water treatment, high mechanical properties (for example, pressure resistance, tensile strength, etc.) are required. As a method for producing a porous filtration membrane having excellent mechanical strength, a method for producing a hollow fiber membrane using a hollow round braid as a hollow fiber membrane support has been proposed ( Patent Document 1, 2 and 3). Specifically, in this production method, a hollow fiber membrane production support is sent out from the center hole of the annular nozzle, and the membrane is spun from the outer circumference of the annular nozzle to the outer circumference of the hollow fiber membrane production support. The stock solution is applied and solidified to obtain a hollow fiber membrane.
In the above production method, in order to obtain a long hollow fiber membrane, the support for producing a hollow fiber membrane also needs to be long. Usually, the length of the support for producing the hollow fiber membrane is a hollow fiber. Because it is shorter than the desired length of the membrane, multiple supports must be joined.
In the manufacturing process of the hollow fiber membrane, there is a passing portion close to the outer diameter of the hollow fiber membrane and closed like a pipe during the passing step. For this reason, if a continuous body made by linking the supports for manufacturing hollow fiber membranes is used, the outer diameter of the joint becomes larger than other parts, so the process passes through the process while continuously running the hollow fiber membrane. It becomes difficult to make it.
 中空糸膜製造用支持体同士を接合する方法としては、例えば、公知のスプライサを用いる方法が知られている。しかし、スプライサを用いた接合方法では、熟練した技術を要するため、中空糸膜製造用支持体同士を適切に接合することが困難であり、これらが適切に接合されなかった場合には、接合強度不足や接合部の大径化などの不具合が生じる。その結果、中空糸膜製造用支持体の接合部分が環状ノズルの中心孔に詰まったり、引っ掛かり、製造工程の安定性を低下させることになる。 As a method for joining hollow fiber membrane production supports, for example, a method using a known splicer is known. However, in the joining method using a splicer, it is difficult to properly join the supports for manufacturing the hollow fiber membranes because skilled techniques are required, and if these are not properly joined, the joining strength Problems such as shortage and enlargement of the joint diameter occur. As a result, the joining portion of the support for manufacturing the hollow fiber membrane is clogged or caught in the center hole of the annular nozzle, and the stability of the manufacturing process is lowered.
 ところで、中実の紐体の接合方法については、これまでに様々な方法が提案されている。例えば、特許文献4には、プラスチック製丸紐を平行に重ね合わすか撚り合わせ、一定間隔で部分的に加熱加圧することによって、熱融着部と非熱融着部を交互に形成して紐体を接合する方法が提案されている。
 しかしながら、特許文献4に記載の接合方法を、中空糸膜製造用支持体のような中空状物に適用した場合、熱融着部は2本の中空状物を合わせた大きさよりもわずかに小さくなる程度である上に、非熱融着部は2本の中空状物を合わせた大きさとなる。したがって、特許文献4に記載の接合方法では、接合後の側面に段差が形成され、得られた連続体を、環状ノズルの中心孔等、外径が規制された部分に通した際には、詰まりや、引っ掛かかりが発生し、中空糸膜の製造安定性が低下する。
By the way, various methods have been proposed so far for the solid string member joining method. For example, Patent Document 4 discloses that a plastic round string is overlapped or twisted in parallel, and partially heat-pressed at regular intervals to alternately form heat-bonded portions and non-heat-bonded portions. There has been proposed a method of joining the two.
However, when the joining method described in Patent Document 4 is applied to a hollow object such as a support for manufacturing a hollow fiber membrane, the heat-sealed portion is slightly smaller than the combined size of the two hollow objects. In addition, the non-heat-sealed portion has a size obtained by combining two hollow objects. Therefore, in the joining method described in Patent Document 4, a step is formed on the side surface after joining, and when the obtained continuous body is passed through a portion where the outer diameter is regulated, such as the center hole of the annular nozzle, Clogging and catching occur, and the production stability of the hollow fiber membrane is reduced.
 また、伸縮紐体を絡めて編んだ後、編目を折り返して重ね合わせ、超音波振動あるいは加熱により融着する方法が提案されている(特許文献5参照)。しかしながら、特許文献5における融着は、2本の紐体を接合して1本の連続体を得るものではない。また、融着の対象物は中実の紐体であるから、接合後の側面のいずれかの部分に段差が形成される。 In addition, a method has been proposed in which after knitting an elastic cord body, the stitches are folded and overlapped, and fused by ultrasonic vibration or heating (see Patent Document 5). However, the fusion in Patent Document 5 does not join two string bodies to obtain one continuous body. Further, since the object to be fused is a solid string, a step is formed on any part of the side surface after joining.
 一方、中空状物の中空部に芯材を挿入し、芯材と中空状物を超音波融着させる方法が提案されている(特許文献6参照)。しかしながら特許文献6における接合方法においては、所望の接合強度を得るために端部の各々を接合する必要があることから、接合部が長くなる。これに加えて芯材を中空部に挿入することから、接合部における中空状物の柔軟性が低下する。こうした接合部の柔軟性低下は、中空状物を連続して走行させる際、走行方向の変更等に使用される、回転ガイドや固定ガイド走行時に、ガイドへの追従性が低下し、中空状物の安定走行に支障をきたすことになる。特に接合長が長くなるほど、その影響が大きいことが懸念される。また、芯材が別に必要となり、コスト及び操作性の面での負荷が増加することも考えられる。 On the other hand, a method has been proposed in which a core material is inserted into a hollow part of a hollow material, and the core material and the hollow material are ultrasonically fused (see Patent Document 6). However, in the joining method in Patent Document 6, it is necessary to join the end portions in order to obtain a desired joining strength, so that the joining portion becomes long. In addition, since the core material is inserted into the hollow portion, the flexibility of the hollow material at the joint portion is reduced. Such a decrease in the flexibility of the joint is caused by a decrease in the followability to the guide when the rotating guide or the fixed guide travels, which is used for changing the traveling direction when continuously traveling the hollow object. Will interfere with the stable running of the car. In particular, there is a concern that the longer the bonding length, the greater the effect. In addition, a core material is required separately, and the load in terms of cost and operability may be increased.
特開昭52-81076号公報Japanese Patent Laid-Open No. 52-81076 特開平5-7746号公報JP-A-5-7746 国際公開第04/43579号パンフレットWO04 / 43579 pamphlet 特開昭50-4358号公報JP 50-4358 A 特許第2962243号公報Japanese Patent No. 2962243 特開2008-105014号公報JP 2008-105014 A
 本発明の目的は、中空糸膜製造法支持体に代表される中空状物の接合部分の接合強度不足及び大径化などの不具合を防止でき、柔軟性を大きく損ねることなく、中空糸膜製造や加工時における工程安定性の低下が防止された、中空状連続体の製造方法を提供することである。 The object of the present invention is to prevent hollow fiber membrane production methods such as lack of bonding strength and increase in the diameter of the joining portion of hollow materials represented by a support, and to produce hollow fiber membranes without greatly impairing flexibility. Another object of the present invention is to provide a method for producing a hollow continuum in which deterioration in process stability during processing is prevented.
 本発明の要旨は、一対の中空状物を、その端部同士が互いに接触するように、もしくはそれぞれの端部が1つの接続用部材にその外周面で接触するように配置した後、その端部全体を圧縮変形させた後接合する中空状連続体の製造方法にある。 The gist of the present invention is that a pair of hollow objects are arranged so that their end portions are in contact with each other, or each end portion is in contact with one connecting member on its outer peripheral surface, and then the ends thereof are arranged. In the method of manufacturing a hollow continuous body, the whole part is compressed and deformed and then joined.
 本発明の中空状連続体の製造方法によれば、中空状物の接合部分の接合強度不足及び大径化などの不具合を防止でき、柔軟性を大きく損ねることなく中空糸膜製造や加工時における工程安定性の低下が防止された中空状連続体を製造できる。 According to the method for producing a hollow continuous body of the present invention, it is possible to prevent problems such as insufficient joining strength and an increase in diameter of the joined portion of the hollow article, and at the time of hollow fiber membrane production and processing without greatly impairing flexibility. A hollow continuous body in which a decrease in process stability is prevented can be produced.
本発明の中空状連続体の製造方法の一実施形態例で使用する接続装置を示す斜視図である。It is a perspective view which shows the connection apparatus used by one Embodiment of the manufacturing method of the hollow continuous body of this invention. 接続ジグに中空状物を隣接させて挿入した状態を示す図である。It is a figure which shows the state which inserted the hollow thing adjacent to the connection jig. 一対の中空状物の端部を接続ジグの溝に挿入した態様を示す断面図である。It is sectional drawing which shows the aspect which inserted the edge part of a pair of hollow thing into the groove | channel of the connection jig. 溝に挿入した一対の中空状物の端部を超音波ホーンで圧縮変形させた態様を示す断面図である。It is sectional drawing which shows the aspect which compression-deformed the edge part of a pair of hollow thing inserted in the groove | channel with the ultrasonic horn.
 本願発明でいう中空状物とは、長手方向に沿って連続した空間部を有する物であり、内部が中空状となった繊維や、中実のモノフィラメントまたはマルチフィラメントを内部が中空状となるよう織り、または編んだもの、スポンジのような連続あるいは不連続な空隙部を有する多孔質体などがあり、更に具体的には、中空繊維、中空組紐、中空編紐、中空糸膜等が挙げられる。
 中空部の形状は特に限定されないが、略円形状のものが好ましい。中空状物の外径は特に限定されないが、0.5~5mmが好ましい。また、その内径は、0.2~4mmが好ましい。なお、前記内径は、中空状物の中空部の体積が、中空状物の外径から求めた中空状物の体積の容10~90%、好ましくは20~80%となるように決められることが好ましい。
The hollow material referred to in the present invention is a material having a continuous space along the longitudinal direction, so that the inside of the fiber, the solid monofilament or the multifilament becomes hollow. There are woven or knitted fabrics, porous bodies having continuous or discontinuous voids such as sponge, and more specifically, hollow fibers, hollow braids, hollow knitted cords, hollow fiber membranes, etc. .
The shape of the hollow portion is not particularly limited, but a substantially circular shape is preferable. The outer diameter of the hollow material is not particularly limited, but is preferably 0.5 to 5 mm. The inner diameter is preferably 0.2 to 4 mm. The inner diameter is determined so that the volume of the hollow portion of the hollow article is 10 to 90%, preferably 20 to 80% of the volume of the hollow article obtained from the outer diameter of the hollow article. Is preferred.
 中空状物の材質は、特に限定されないが、融着が可能であるものが好ましい。具体的には、ポリエチレンテレフタレート、ナイロン、ポリエチレン、ポリプロピレン、ポリ塩化ビニル、ポリスルホン、ポリアクリロニトリル、セルロースアセテート、ポリフッ化ビニリデン等が挙げられる。これらは単独で用いてもよいし、複数を組み合わせてもよい。
 一対の中空状物は同一の素材からなっていてもよいし、異なっていてもよく、またこれら複数の組み合わせでも良い。
The material of the hollow material is not particularly limited, but a material that can be fused is preferable. Specific examples include polyethylene terephthalate, nylon, polyethylene, polypropylene, polyvinyl chloride, polysulfone, polyacrylonitrile, cellulose acetate, and polyvinylidene fluoride. These may be used alone or in combination.
The pair of hollow objects may be made of the same material, may be different, or may be a combination of these.
 本発明においては、一対の中空状物を、その端部同士が互いに接触するように、もしくはそれぞれの端部が1つの接続用部材にその外周面で接触するように配置する。
 一対の中空状物を、その端部同士が互いに接触するように配置する場合、接触部分の糸長方向における接触部分の長さは、所望の接合強度や接合後の柔軟性に応じて適宜決められるが、得られた中空状連続体を繰返し使用した際の安定性等を考慮すると、(糸長方向における接触部分の長さA(mm))/(一対の中空状物のそれぞれの外径のうち、いずれか大きい方の外径(mm))の比が1以上であることが好ましい。この比が30を超えると、接合の際に中空状物を変形させる際に要する力が大きくなり、接合のための装置が大型化する傾向にある。
更に、中空状物が接合された部分は、他の部分に比べ剛直化し易く、中空状連続体をガイドなどに沿わせて走行させた場合、接合部がガイド表面から浮き上がり、中空状物がガイドから外れてしまう恐れがある。
従って、後に接合部分の長さに該当することになる接触部分の長さAは、5mm~150mm、更に好ましくは5mm~100mm、もっとも好ましくは10mm~40mmの範囲が好ましい。接触部分の長さを前述した範囲とし、この部分を接合することで、高い接合強度が得られ、柔軟性にもすぐれた中空状連続体を得ることができる。
 さらに、中空状物同士を接触させるに際しては、側面に段差のない中空状連続体を容易に製造できることから、各中空状物の端部の軸心が、鉛直方向に沿った同一直線上となるように接触させることが好ましい。
In the present invention, the pair of hollow objects are arranged such that the end portions thereof are in contact with each other, or each end portion is in contact with one connecting member on the outer peripheral surface thereof.
When arranging a pair of hollow objects so that the ends thereof are in contact with each other, the length of the contact portion in the yarn length direction of the contact portion is appropriately determined according to the desired bonding strength and flexibility after bonding. However, in consideration of the stability when the obtained hollow continuous body is repeatedly used, (the length A (mm) of the contact portion in the yarn length direction) / (the respective outer diameters of the pair of hollow materials Of these, the ratio of the larger outer diameter (mm) is preferably 1 or more. When this ratio exceeds 30, the force required for deforming the hollow object during joining increases, and the joining apparatus tends to increase in size.
Furthermore, the part where the hollow object is joined is more rigid than the other part, and when the hollow continuous body is run along the guide or the like, the joint part is lifted from the guide surface, and the hollow object is guided. There is a risk of losing.
Accordingly, the length A of the contact portion, which will later correspond to the length of the joined portion, is preferably in the range of 5 mm to 1550 mm, more preferably 5 mm to 100 mm, and most preferably 10 mm to 40 mm. By making the length of the contact part in the above-described range and joining this part, a hollow continuous body having high joint strength and excellent flexibility can be obtained.
Furthermore, when the hollow objects are brought into contact with each other, a hollow continuous body having no step on the side surface can be easily manufactured, so that the axial centers of the ends of the hollow objects are on the same straight line along the vertical direction. It is preferable to make contact.
 以下、一対の中空状物を、それぞれの端部が1つの接続用部材にその外周面で接触するように配置する場合について説明する。
 接続用部材としては、中空状物同士を接合するための部材であり、中空状物と容易に接合することができ、中空糸膜製造工程や加工工程を安定して通過させるのに必要な接合強度、柔軟性を維持できるものが好ましく、具体的には、繊維束、中空又は中実の組紐、中空又は中実の組紐、繊維編織物の帯状物、多孔質棒状物、多孔質帯状物などが挙げられる。また接合部を圧縮変形させ接合する際、側面に段差のない中空状連続体を得る上で、接続用部材として圧縮変形時の体積減少率が大きい物が好ましく、そのような接続用部材としては、中空繊維束、中空組紐、中空編紐、中空糸膜、中空状多孔質物、中空状ネット、チューブ等が挙げられる。
接続用部材としては、熱的特性、対薬品性などの面から、接合する中空状物と同一の素材、からなるものを使用することが好ましい。
 接続用部材は、一対の中空状物のそれぞれの端部とその外周面で接触するように配置される。
 この場合、接触部が接続部となることから、効果的に接続するためには、接触面を大きく取り、隙間が極力生じないよう密着させるのが好ましい。
Hereinafter, a case where a pair of hollow objects are arranged so that each end portion contacts one connection member on the outer peripheral surface thereof will be described.
The connecting member is a member for joining hollow objects, and can be easily joined to the hollow object, and is necessary for stably passing through the hollow fiber membrane manufacturing process and processing process. Those capable of maintaining strength and flexibility are preferred. Specifically, fiber bundles, hollow or solid braids, hollow or solid braids, strips of fiber knitted fabric, porous rods, porous strips, etc. Is mentioned. Further, when compressing and deforming the joint portion to join, a hollow continuous body having no step on the side surface is obtained, and as the connecting member, a material having a large volume reduction rate at the time of compressive deformation is preferable. , Hollow fiber bundles, hollow braids, hollow braids, hollow fiber membranes, hollow porous materials, hollow nets, tubes and the like.
As the connecting member, it is preferable to use a member made of the same material as the hollow material to be joined in terms of thermal characteristics and chemical resistance.
The connecting member is disposed so as to be in contact with each end portion of the pair of hollow objects and the outer peripheral surface thereof.
In this case, since the contact portion becomes the connection portion, in order to make an effective connection, it is preferable that the contact surface is made large and is closely attached so that a gap is not generated as much as possible.
 本発明においては、一対の中空状物を、その端部同士が互いに接触するように、もしくはそれぞれの端部が1つの接続用部材にその外周面で接触するように配置した後、その端部を圧縮変形させる。
 圧縮変形させる方法としては、特に限定されないが、例えば、重り、エアーシリンダ等により一定荷重を付与する方法をあげることができる。特にエアーシリンダーを用いた場合、供給エアー圧の増減により付与する荷重を変更でき、さらに供給エアーのシリンダー供給方向をバルブなどで反転させ荷重付与、除去を簡便に行うことができる。
In the present invention, after arranging a pair of hollow objects so that the end portions thereof are in contact with each other or each end portion is in contact with one connecting member on the outer peripheral surface thereof, the end portions thereof Is compressed and deformed.
A method of compressing and deforming is not particularly limited, and examples thereof include a method of applying a constant load with a weight, an air cylinder, or the like. In particular, when an air cylinder is used, the load to be applied can be changed by increasing or decreasing the supply air pressure, and the load supply and removal can be easily performed by reversing the cylinder supply direction of the supply air with a valve or the like.
 本発明においては、中空状物の端部を圧縮変形させた後、中空状物同士若しくは中空状物と接合用部材の接合を行う。
 接合を行う方法としては、接着剤により接合する方法、融着により接合する方法が挙げられる。
 接着剤により接合を行う場合、その方法は特に限定されないが、例えば、中空状物同士若しくは中空状物と接合用部材の接続面に、適量の接着剤を塗布した後接続ジグに挿入、圧縮変形させたまま接着剤を硬化させ、所望の形状に接合する方法等が挙げられる。使用する接着剤としては、溶媒蒸発型、ホットメルト型、反応硬化型等が挙げられる。また、接続時間、柔軟性、接続強度等、所望の条件に応じ接着剤を適宜選定すればよい。また、接合に使用する接着剤量としては、接合部を圧縮変形させた際、中空状物同士若しくは中空状物と接合用部材の接合面に接着剤が十分浸透し、接合面から外部に多量に流出し、接続ジグに付着しない程度の量を、中空状物若しくは接合用部材の空隙率に応じて選択することが好ましい。また、接続ジグ内面には接着剤が付着硬化した場合、接着部と接続ジグが容易に分離できるように剥離性表面処理、例えばフッ素系樹脂コーティングを行っておくと良い。
 融着により接合を行う場合、その方法は特に限定されないが、例えば、加熱した接続ジグを直接中空状物と接触させながら圧縮変形させて所望の形状に融着し接合する方法や、あらかじめ非加熱の接続ジグによって圧縮変形させた後、加熱した接続ジグに接触させて融着し接合する方法等が挙げられる。その際の加熱温度は、例えばポリエチレンテレフタレートを融着させる場合、融点近傍の温度である250℃から280℃程度が好ましい。また、本発明でいう融着とは、一対の中空状物の端部同士を重ね合わせた部分の一部又は全部が溶融した状態をいう。また、接続ジグ内面には、融着時に溶融した中空状物同士若しくは接合用部材が付着し冷却固化した場合に備えて、接着部と接続ジグが容易に分離できるように剥離性表面処理を、融着温度が高い場合には耐熱剥離性表面処理を施しておくことが好ましい。
 融着により接合を行う場合、融着状態で加熱した接続ジグ等を離すと融着物の形状が固定されないため、一旦接続ジグを冷却する必要があるが、超音波による融着では融着を行う超音波ホーンや接続ジグ等が非加熱であり、且つ短時間処理が可能であることから、超音波による融着を行うことが最も好ましい。また超音波融着の場合は接続ジグの温度が上がらないため、接続ジグ内面の剥離性表面処理は通常のフッ素系樹脂コーティングを用いることができる。
In the present invention, after compressing and deforming the ends of the hollow objects, the hollow objects or the hollow object and the joining member are joined.
Examples of the bonding method include a bonding method using an adhesive and a bonding method using fusion.
When joining with an adhesive, the method is not particularly limited. For example, after applying an appropriate amount of adhesive to the connection surfaces of the hollow objects or between the hollow object and the joining member, it is inserted into the connection jig and compressed and deformed. Examples include a method of curing the adhesive while it is left and joining it into a desired shape. Examples of the adhesive used include a solvent evaporation type, a hot melt type, and a reaction curing type. Moreover, what is necessary is just to select an adhesive agent suitably according to desired conditions, such as connection time, a softness | flexibility, and connection strength. In addition, the amount of adhesive used for bonding is such that when the bonded portion is compressed and deformed, the adhesive sufficiently permeates between the hollow objects or the bonding surfaces of the hollow object and the bonding member, and a large amount from the bonding surface to the outside. It is preferable to select an amount that does not flow out to the connection jig and adhere to the connection jig according to the porosity of the hollow object or the joining member. Further, when the adhesive adheres and hardens on the inner surface of the connection jig, it is preferable to perform a releasable surface treatment such as a fluorine resin coating so that the bonded portion and the connection jig can be easily separated.
When joining by fusion, the method is not particularly limited. For example, a method in which a heated connection jig is compressed and deformed while being directly in contact with a hollow object, and is fused and joined to a desired shape, or is not heated in advance. For example, there may be mentioned a method of compressing and deforming with a connecting jig and then bringing it into contact with a heated connecting jig for fusing and joining. For example, when fusing polyethylene terephthalate, the heating temperature at that time is preferably about 250 ° C. to 280 ° C., which is a temperature near the melting point. In addition, the term “fusion” as used in the present invention refers to a state in which a part or all of a portion where the ends of a pair of hollow objects are overlapped is melted. In addition, on the inner surface of the connecting jig, a peelable surface treatment is performed so that the bonded portion and the connecting jig can be easily separated in preparation for the case where the hollow objects melted at the time of fusion or the bonding member adhere and cool and solidify. When the fusing temperature is high, it is preferable to perform a heat-resistant peelable surface treatment.
When joining by fusion, it is necessary to cool the connection jig once because the shape of the fusion product is not fixed if the connection jig heated in the fused state is released, but fusion is performed by ultrasonic fusion. Since ultrasonic horns, connection jigs and the like are not heated and can be processed for a short time, it is most preferable to perform fusion using ultrasonic waves. In the case of ultrasonic fusion, since the temperature of the connecting jig does not rise, the peelable surface treatment of the inner surface of the connecting jig can use a normal fluorine resin coating.
 以下、超音波融着を行う場合の製造例について具体的に説明する。
 本製造例においては、隣接した一対の中空状物の端部の全体を、前記端部同士が互いに重なり合うように圧縮変形させるために、図1および図2に示すような、超音波ホーン1と接続ジグ2とを備えた接続装置を用いる。
 本製造例の超音波ホーン1は、下面1aが中空状物3a及び3bに接触する面になっており、下面から中空状物3a,3bに超音波を伝達させるものである。
 本製造例の接続ジグ2は、矩形状のプレートであって、プレートの一辺からその辺に対向する辺に向かって直線的に溝2aが形成され、その溝2aの深さが、一対の中空状物3a,3bを重ねて収納可能になっているものである。
 上記の超音波ホーン1と接続ジグ2を用いた融着では、図3に示すように、接続ジグ2の溝2aに中空状物の端部3c,3dを各々挿入し、次いで、図4に示すように、溝2aに超音波ホーン1の先端を挿入して端部3c,3dを溝2aの底部に押圧して、端部3c,3d同士が重なり合うように隣接した中空状物3a,3bの端部3c,3dを圧縮変形させる。そして、その圧縮変形状態を維持したまま、超音波ホーン1から隣接した中空状物3a,3bの端部3c,3dに超音波を伝達させて融着する。
 上記超音波ホーン1を用いて中空状物3a,3b同士を融着する場合には、中空状物3a,3bの接触部に摩擦による局所発熱が生じて被接合部分が熱変形、融着したり、表面の酸化被膜が消失して界面が活性化し分子間結合するため、中空状物3a,3bの繊維間や多孔質部等に水等の液体が存在するウェットな状態でも、液体は融着界面から蒸発や移動し、融着が可能となる。
Hereinafter, a production example in the case of performing ultrasonic fusion will be specifically described.
In this production example, in order to compress and deform the entire ends of a pair of adjacent hollow objects so that the ends overlap each other, an ultrasonic horn 1 as shown in FIG. 1 and FIG. A connection device comprising a connection jig 2 is used.
In the ultrasonic horn 1 of this production example, the lower surface 1a is a surface in contact with the hollow objects 3a and 3b, and ultrasonic waves are transmitted from the lower surface to the hollow objects 3a and 3b.
The connection jig 2 of the present manufacturing example is a rectangular plate, and a groove 2a is linearly formed from one side of the plate to a side opposite to the side. The depth of the groove 2a is a pair of hollow plates. The articles 3a and 3b can be stacked and stored.
In the fusion using the ultrasonic horn 1 and the connecting jig 2, the end portions 3c and 3d of the hollow objects are respectively inserted into the grooves 2a of the connecting jig 2, as shown in FIG. As shown, the end of the ultrasonic horn 1 is inserted into the groove 2a and the end portions 3c, 3d are pressed against the bottom of the groove 2a, and the hollow objects 3a, 3b adjacent so that the end portions 3c, 3d overlap each other. The end portions 3c and 3d are compressed and deformed. Then, while maintaining the compression deformation state, ultrasonic waves are transmitted from the ultrasonic horn 1 to the end portions 3c and 3d of the adjacent hollow objects 3a and 3b to be fused.
When the hollow objects 3a and 3b are fused together using the ultrasonic horn 1, local heat generation occurs due to friction at the contact portions of the hollow objects 3a and 3b, and the bonded parts are thermally deformed and fused. Or the oxide layer on the surface disappears and the interface is activated to form intermolecular bonds. Therefore, even in a wet state where water or other liquid exists between the fibers of the hollow materials 3a and 3b or in the porous portion, the liquid melts. Evaporation and movement from the adhesion interface enable fusion.
 この圧縮変形では、得られる中空状連続体の工程安定性がより高くなることから、圧縮変形後の、一対の中空状物の端部同士が重なり合った部分の、長さ方向に対する垂直な断面の形状(以下、断面形状という。)を、圧縮変形させる前の一方の中空状物の断面形状と略同一、すなわち略円形状にすることが好ましい。
 圧縮変形後の、一対の中空状物の端部同士が重なり合った部分の断面形状を、圧縮変形させる前の一方の中空状物の断面形状と略同一にするためには、例えば、図1に示すように、超音波ホーン1として下面1aに円弧状に凹んだ溝が形成されたものを用い、接続ジグ2としてU字状の溝2aが形成されたものを用いる方法を採用できる。上記接続ジグ2の溝2aに超音波ホーン1を挿入した際には、断面形状が略円形の空洞部を形成するようになる。
 上記接続ジグ2および超音波ホーン1を用いた場合には、それらの間に微小な隙間が生じ、超音波融着後にバリ状のものが生じることがあるが、工程通過性が損なわなければ、バリ状のものが発生しても構わない。
In this compressive deformation, the process stability of the resulting hollow continuous body becomes higher, and therefore, the cross section perpendicular to the length direction of the portion where the ends of the pair of hollow objects overlap each other after the compressive deformation is obtained. The shape (hereinafter referred to as a cross-sectional shape) is preferably substantially the same as the cross-sectional shape of one hollow object before being compressed and deformed, that is, approximately circular.
In order to make the cross-sectional shape of the portion where the ends of the pair of hollow objects overlap after compression deformation substantially the same as the cross-sectional shape of one hollow object before compression deformation, for example, in FIG. As shown, a method using an ultrasonic horn 1 in which a groove recessed in an arc shape is formed on the lower surface 1 a and a connection jig 2 in which a U-shaped groove 2 a is formed can be employed. When the ultrasonic horn 1 is inserted into the groove 2a of the connecting jig 2, a hollow portion having a substantially circular cross section is formed.
When the connection jig 2 and the ultrasonic horn 1 are used, a minute gap is generated between them, and a burr-like thing may be formed after ultrasonic fusion. A burr-like thing may be generated.
 上記超音波ホーン1と接続ジグ2を用いると、隣接した中空状物3a,3bの端部3c,3dを一度に融着することができる。隣接した中空状物3a,3bの端部3c,3dを一度に融着することにより、所望の接合強度をより容易に得ることができる。 When the ultrasonic horn 1 and the connection jig 2 are used, the end portions 3c and 3d of the adjacent hollow objects 3a and 3b can be fused at a time. By bonding the end portions 3c and 3d of the adjacent hollow objects 3a and 3b at a time, a desired bonding strength can be obtained more easily.
 中空状物の端部同士を圧縮変形させながら超音波融着処理する際の、中空状物を圧縮変形させるために付与する推力(面圧)および超音波発振時間は、超音波ホーンの種類、中空状物の種類、所望の接合強度および柔軟性に応じて適宜選択すればよい。
また超音波融着を行うための超音波ウェルダーにおける最大出力、発振周波数は、融着が可能であれば特に限定されることは無いが、最大出力は30Wから2500W、発振周波数は60kHzから15.15kHz程度の範囲となる市販のウェルダーを接合条件に応じ、適宜選定すればよい。
中空状物を圧縮変形させるために付与する推力(面圧)は、所望の推力が付与可能であればどのような方法を用いても良い。例えば、重りやバネ、人力による方法や空圧、油圧を用いる方法等が挙げられる。中でも、空圧を利用したエアーシリンダは、動力源が空気であり、市販のコンプレッサー等を用い、レギュレータを用いて所望の圧力に調整し、容易に供給可能である。エアーシリンダは、供給圧力を変えることにより、推力を容易に変更でき、種々の条件に対応可能であり、好適に使用される。この場合の推力は、エアーシリンダ径より求める断面積とエアーシリンダ供給圧力の積で、推力を求めることができる。
 例えば、最大出力300W、発振周波数28.5kHzの超音波ウェルダーと直径32mmのエアーシリンダを使用し、外径2.5mm、内径1.2mm程度の中空状組紐(ポリエチレンテレフタレート,830dtex-96fil×16打)同士を2.5~30mm程度並列させて接合する場合には、発振時間を0.4~2秒程度、推力を50~400N程度(エアーシリンダ供給圧力は0.06MPa~0.51MPa程度)、とすることが好ましい。
The thrust (surface pressure) and the ultrasonic oscillation time applied to compress and deform the hollow object when compressing and deforming the ends of the hollow object are the types of the ultrasonic horn, What is necessary is just to select suitably according to the kind of hollow thing, desired joining strength, and a softness | flexibility.
Further, the maximum output and the oscillation frequency in the ultrasonic welder for performing ultrasonic fusion are not particularly limited as long as fusion is possible, but the maximum output is 30 to 2500 W, and the oscillation frequency is 60 kHz to 15. What is necessary is just to select suitably the commercially available welder used as the range of about 15 kHz according to joining conditions.
Any method may be used for the thrust (surface pressure) applied to compress and deform the hollow object as long as a desired thrust can be applied. For example, a weight, a spring, a method using human power, a method using air pressure, hydraulic pressure, and the like can be given. Among them, in an air cylinder using air pressure, the power source is air, and a commercially available compressor or the like can be used to adjust to a desired pressure using a regulator and can be easily supplied. The air cylinder can be used suitably because it can easily change the thrust by changing the supply pressure and can cope with various conditions. In this case, the thrust can be obtained by the product of the cross-sectional area obtained from the air cylinder diameter and the air cylinder supply pressure.
For example, using an ultrasonic welder with a maximum output of 300 W and an oscillation frequency of 28.5 kHz and an air cylinder with a diameter of 32 mm, a hollow braid (polyethylene terephthalate, 830 dtex-96 fil × 16 shots) with an outer diameter of 2.5 mm and an inner diameter of 1.2 mm ) When joining 2.5 to 30 mm in parallel, oscillation time is about 0.4 to 2 seconds, thrust is about 50 to 400 N (air cylinder supply pressure is about 0.06 MPa to 0.51 MPa) It is preferable that
 上記のように、本製造例の製造方法では、隣接した一対の中空状物の端部を部分的でなく全体を、前記端部同士が互いに重なり合うように圧縮変形させて融着するため、中空状物の接合部分の接合強度不足及び大径化などの不具合を防止でき、得られる中空状連続体の側面に段差が生じることを防止できる。これは、超音波融着処理により中空状物の空間部が圧縮され、減少あるいは消失するよう変形するためである。
 したがって、得られる中空状連続体は一直線状になり、外径が規制された部分を通した際に詰まったり、引っ掛かったりしにくい。また、柔軟性を大きく損ねないことから、中空状物の走行が安定しており、中空糸膜製造や加工時における工程安定性の低下が防止されている。
 また、上記製造例の中空状連続体の製造方法によれば、接合時間を短くできる上に、超音波ホーンや接続ジグ等の加熱が不要なため、これらに対する融着が防止されている。また、超音波融着するから、中空状物がドライ、ウェットの状態のいずれであっても同様の条件で接合できる。そのため、中空状連続体を効率的に製造できる。
As described above, in the manufacturing method of the present manufacturing example, the end portions of a pair of adjacent hollow objects are not partial, but the entire end portion is compressed and deformed so that the end portions overlap each other. It is possible to prevent problems such as insufficient bonding strength and an increase in diameter of the bonded portion of the shaped article, and to prevent a step from occurring on the side surface of the resulting hollow continuous body. This is because the space portion of the hollow object is compressed by the ultrasonic fusion treatment and deformed so as to decrease or disappear.
Therefore, the obtained hollow continuous body is in a straight line, and is less likely to be clogged or caught when passing through a portion whose outer diameter is regulated. In addition, since the flexibility is not greatly impaired, the travel of the hollow object is stable, and a decrease in process stability during the production and processing of the hollow fiber membrane is prevented.
Moreover, according to the manufacturing method of the hollow continuous body of the said manufacture example, since joining time can be shortened and heating of an ultrasonic horn, a connection jig, etc. is unnecessary, the fusion | melting with respect to these is prevented. In addition, since ultrasonic fusion is performed, bonding can be performed under the same conditions regardless of whether the hollow material is in a dry or wet state. Therefore, a hollow continuous body can be produced efficiently.
 上記の製造方法により得た中空状連続体は、中空糸膜を製造する際に使用する支持体として好適に使用できる。
 支持体として中空状連続体を使用して中空糸膜を製造する具体的な方法としては、環状ノズルの中心孔から中空状連続体を送出させ、その中空状連続体の外周に、環状ノズルの外周から紡出させた製膜原液を塗布し、凝固させて、中空糸膜の連続体を形成し、これを切断する方法が挙げられる。
The hollow continuous body obtained by the above production method can be suitably used as a support for use in producing a hollow fiber membrane.
As a specific method for producing a hollow fiber membrane using a hollow continuous body as a support, a hollow continuous body is fed out from the center hole of the annular nozzle, and the annular nozzle is disposed on the outer periphery of the hollow continuous body. There is a method in which a membrane-forming stock solution spun from the outer periphery is applied and solidified to form a continuous hollow fiber membrane and then cut.
 また、圧縮変形後の、一対の中空状物の一端部同士が重なり合った部分の断面形状を略円形状にしたが、外径が規制された部分の通過性が損なわなければ、どのような形状(例えば、楕円形、三角形、四角形等)であってもよい。 In addition, after compression deformation, the cross-sectional shape of the portion where the ends of the pair of hollow objects overlap each other is made into a substantially circular shape. (For example, an ellipse, a triangle, a quadrangle, etc.) may be used.
 さらに、本発明では、隣接した一対の中空状物の端部を複数に分けて融着し、最終的に全体を融着させてもよい。しかし、その場合には、融着部が熱収縮する一方で非融着部が膨張して、得られる中空状連続体の走行安定性を損ねることがある。また、先に融着処理した端部に後の融着処理が作用し、過溶融になるため、所望の接合強度が得られないことがある。これらのことから、上記実施形態例のように、隣接した一対の中空状物の端部の全体を一度に融着することが好ましい。 Further, in the present invention, the ends of a pair of adjacent hollow objects may be divided into a plurality of parts and finally fused together. However, in that case, the fusion part may thermally shrink while the non-fusion part expands, which may impair the running stability of the resulting hollow continuous body. Further, since the subsequent fusion treatment acts on the end portion subjected to the fusion treatment first and overmelts, the desired bonding strength may not be obtained. For these reasons, it is preferable to fuse the entire ends of a pair of adjacent hollow objects at one time as in the above embodiment.
 以下、実施例に基づいて本発明を更に詳しく説明する。
 なお、中空状物の接合では、図1および図2に示すような、接続ジグ2と、超音波ホーン1を備える超音波ウェルダーとを用いた。
[接続ジグ]
 U字状に凹んだ深さCが6.1mmの溝2aが直線的に形成されたものを用いた。
[超音波ウェルダー]
 精電舎電子工業株式会社製、SONOPET 302S-G-M(最大出力300W、発振周波数28.5kHz)を使用した。
 超音波ホーン1としては、先端幅Eが2.2mm、長さDが40mmで、押圧面である下面1aに長さ方向に沿って円弧状に凹んだ溝が形成され、鉛直方向に上下動するものを用いた。また、超音波ホーン1は、その先端が接続ジグ2の溝2aに進入可能なように設置した。
 超音波ホーン1の上下動の動力には、低速度用エアシリンダを使用した。このエアシリンダには、減圧弁で圧力調整し、低速度用スピードコントローラで排気速度を調整した空気が供給されている。
 超音波ホーン1の先端が接続ジグ2の溝2aの底面の直前で停止するようにストッパーを設けて、超音波ホーン1の先端と接続ジグ2の溝2aの底面との接触を防止した。
Hereinafter, the present invention will be described in more detail based on examples.
In joining the hollow objects, a connection jig 2 and an ultrasonic welder including the ultrasonic horn 1 as shown in FIGS. 1 and 2 were used.
[Connection jig]
A U-shaped groove 2a having a depth C of 6.1 mm formed linearly was used.
[Ultrasonic welder]
SONOPET 302S-GM (maximum output 300 W, oscillation frequency 28.5 kHz) manufactured by Seidensha Electronics Co., Ltd. was used.
The ultrasonic horn 1 has a tip width E of 2.2 mm and a length D of 40 mm, and a groove recessed in an arc along the length direction is formed on the lower surface 1a as a pressing surface, and moves vertically in the vertical direction. We used what to do. Moreover, the ultrasonic horn 1 was installed so that the tip could enter the groove 2 a of the connection jig 2.
A low speed air cylinder was used as the power for the vertical movement of the ultrasonic horn 1. This air cylinder is supplied with air whose pressure is adjusted by a pressure reducing valve and whose exhaust speed is adjusted by a speed controller for low speed.
A stopper was provided so that the tip of the ultrasonic horn 1 stopped immediately before the bottom surface of the groove 2 a of the connection jig 2 to prevent contact between the tip of the ultrasonic horn 1 and the bottom surface of the groove 2 a of the connection jig 2.
(実施例1~18)
 表1~3に示す組み合わせの中空状物(A)3aと中空状物(B)3bとを接合して中空状物の連続体を得た。
 具体的には、接続ジグ2の溝2a内に中空状物(A)3aの端部3cを挿入し、次いで、中空状物(B)3bの端部3dを、表1~3に示す並列長さAで並列するよう挿入した。次いで、表1~3に示す条件で、エアシリンダに空気を供給して超音波ホーン1を下降させ、中空状物(A)3aおよび中空状物(B)3bに推力(面圧)を掛けた。
 そして、隣接した中空状物(A)3aおよび中空状物(B)3bの端部3c,3dの全体を、端部3c,3d同士が互いに重なり合うように圧縮変形させ(図4参照)、その状態で超音波を発振させた。これにより、中空状物(A)3aと中空状物(B)3bとを超音波融着させて接合して、中空状連続体を得た。実施例18では、実施例16と同じ中空状物(A)、(B)それぞれの端部より、水の供給可能なシリンジの針を中空部に差し込み、200KPaの加圧圧力で中空部に水を供給し、中空状物端部の外表面から水が出るまで供給して中空状物をウェット状態とした。
(Examples 1 to 18)
The hollow body (A) 3a and the hollow body (B) 3b having the combinations shown in Tables 1 to 3 were joined to obtain a continuous body of hollow bodies.
Specifically, the end 3c of the hollow object (A) 3a is inserted into the groove 2a of the connection jig 2, and then the end 3d of the hollow object (B) 3b is connected in parallel as shown in Tables 1 to 3. Inserted in parallel with length A. Next, the ultrasonic horn 1 is lowered by supplying air to the air cylinder under the conditions shown in Tables 1 to 3, and thrust (surface pressure) is applied to the hollow object (A) 3a and the hollow object (B) 3b. It was.
Then, the end portions 3c and 3d of the adjacent hollow object (A) 3a and hollow object (B) 3b are compressed and deformed so that the end portions 3c and 3d overlap each other (see FIG. 4), Ultrasonic waves were oscillated in the state. As a result, the hollow article (A) 3a and the hollow article (B) 3b were joined by ultrasonic fusion to obtain a hollow continuous body. In Example 18, a syringe needle capable of supplying water is inserted into the hollow part from the end of each of the same hollow objects (A) and (B) as in Example 16, and water is put into the hollow part with a pressurized pressure of 200 KPa. Was supplied until water came out from the outer surface of the end of the hollow object to make the hollow object wet.
 得られた中空状連続体の接合部分の接合強度を、株式会社イマダ製デジタルフォースゲージ(ZP-500N)を用いて以下のように測定した。
 まず、中空状連続体の両端にフックを掛けることが可能な輪を作り、一方の輪を、固定したフックに掛け、他方の輪をデジタルフォースゲージのフックに掛けた。次いで、デジタルフォースゲージの引張り移動方向が概ね鉛直方向か水平方向となるようにし、中空状連続体に引張り張力がかからない状態でデジタルフォースゲージの電源を投入し、表示値のゼロリセットを行った。そして、手動で引張り、ピークホールド機能を利用して破断荷重を測定した。破断荷重の測定は2回行い、その平均値を求めた。測定結果を表1~3に示す。
The joint strength of the joint part of the obtained hollow continuous body was measured as follows using a digital force gauge (ZP-500N) manufactured by Imada Corporation.
First, a ring that can be hooked at both ends of the hollow continuous body was made, one ring was hung on a fixed hook, and the other ring was hung on a hook of a digital force gauge. Next, the digital force gauge was moved so that the pulling direction of the digital force gauge was substantially vertical or horizontal, and the digital force gauge was turned on with no tensile tension applied to the hollow continuous body, and the display value was reset to zero. And it pulled manually and the breaking load was measured using the peak hold function. The breaking load was measured twice, and the average value was obtained. The measurement results are shown in Tables 1 to 3.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 実施例1~18のいずれにおいても、得られた中空状連続体の接合部分の破断荷重はいずれも充分に高かった。また、接合部分の断面形状は圧縮変形前の中空状物の断面形状とほぼ同様であった。そのため、実施例1~11で得られた中空状連続体を、環状ノズルの中心孔に通したところ、接合部分にて引っ掛かることがなく、円滑に通過した。また、実施例12~18で得られた中空状連続体を中空糸膜製造工程に通したところ、実施例1~11と同様、接合部分にて引っ掛かることがなく、円滑に通過した。したがって、中空糸膜製造における工程安定性の低下が防止されていた。
 また、実施例16と実施例18とを比較することにより、接合させる中空状物がドライ、ウェットのいずれであっても、充分な接合強度が発現することが判明した。
In any of Examples 1 to 18, the breaking load at the joint portion of the obtained hollow continuous body was sufficiently high. Moreover, the cross-sectional shape of the joined portion was substantially the same as the cross-sectional shape of the hollow object before compression deformation. Therefore, when the hollow continuum obtained in Examples 1 to 11 was passed through the center hole of the annular nozzle, it passed smoothly without being caught at the joint. Further, when the hollow continuum obtained in Examples 12 to 18 was passed through the hollow fiber membrane production process, it passed smoothly without being caught at the joint portion as in Examples 1 to 11. Therefore, a decrease in process stability in the production of hollow fiber membranes was prevented.
Further, by comparing Example 16 and Example 18, it was found that sufficient bonding strength was exhibited regardless of whether the hollow object to be bonded was dry or wet.
 本発明の製造方法は、中空状物の接合部分の接合強度不足及び大径化などの不具合が防止され、柔軟性を大きく損ねることなく中空糸膜製造や加工時における工程安定性の低下が防止された、中空状連続体の製造に有用である。 The manufacturing method of the present invention prevents problems such as insufficient bonding strength and increased diameter of the bonded portion of the hollow material, and prevents deterioration in process stability during hollow fiber membrane manufacturing and processing without greatly impairing flexibility. It is useful for producing a hollow continuous body.
1 超音波ホーン
1a 下面
2 接続ジグ
2a 溝
3a,3b 中空状物
3c,3d 端部
A 並列長さ
B 溝の幅
C 溝の深さ
D 超音波ホーン長
E 超音波ホーン幅
d1 中空状物外径
d2 中空状物内径
DESCRIPTION OF SYMBOLS 1 Ultrasonic horn 1a Bottom surface 2 Connection jig 2a Groove 3a, 3b Hollow object 3c, 3d End A Parallel length B Groove width C Groove depth D Ultrasonic horn length E Ultrasonic horn width d1 Outside hollow object Diameter d2 Hollow internal diameter

Claims (7)

  1.  一対の中空状物を、その端部同士が互いに接触するように、もしくはそれぞれの端部が1つの接続用部材にその外周面で接触するように配置した後、その端部全体を圧縮変形させた後接合する中空状連続体の製造方法。 After arranging a pair of hollow objects so that the end portions are in contact with each other or each end portion is in contact with one connecting member on the outer peripheral surface, the entire end portions are compressed and deformed. A method for producing a hollow continuous body to be joined after welding.
  2. 端部を融着により接合する請求項1記載の中空状連続体の製造方法。 The manufacturing method of the hollow continuous body of Claim 1 which joins an edge part by melt | fusion.
  3. 端部を超音波融着により接合する請求項2記載の中空状連続体の製造方法。 The manufacturing method of the hollow continuous body of Claim 2 which joins an edge part by ultrasonic fusion.
  4. 接合した部分の糸長方向における長さが150mm以下である請求項1記載の中空状連続体の製造方法。 The method for producing a hollow continuous body according to claim 1, wherein the length of the joined portions in the yarn length direction is 150 mm or less.
  5.  中空状物が組紐、編紐、中空糸膜から選ればれる何れか1種以上である請求項1記載の中空状連続体の製造方法。 The method for producing a hollow continuous body according to claim 1, wherein the hollow material is at least one selected from braided cords, braided cords, and hollow fiber membranes.
  6. 接続用部材が中空状である請求項1記載の中空状連続体の製造方法。 The method for producing a hollow continuous body according to claim 1, wherein the connecting member is hollow.
  7. 接続用部材が中空状物と同じ素材からなる請求項6記載の中空状連続体の製造方法。 The method for producing a hollow continuous body according to claim 6, wherein the connecting member is made of the same material as that of the hollow body.
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