WO2011017183A3 - Uzm-29 family of crystalline zeolitic compositions and a method of preparing the compositions - Google Patents

Uzm-29 family of crystalline zeolitic compositions and a method of preparing the compositions Download PDF

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Publication number
WO2011017183A3
WO2011017183A3 PCT/US2010/043630 US2010043630W WO2011017183A3 WO 2011017183 A3 WO2011017183 A3 WO 2011017183A3 US 2010043630 W US2010043630 W US 2010043630W WO 2011017183 A3 WO2011017183 A3 WO 2011017183A3
Authority
WO
WIPO (PCT)
Prior art keywords
compositions
uzm
family
preparing
crystalline zeolitic
Prior art date
Application number
PCT/US2010/043630
Other languages
French (fr)
Other versions
WO2011017183A2 (en
Inventor
Susan C. Koster
Jaime G. Moscoso
Original Assignee
Uop Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/535,248 external-priority patent/US8017824B2/en
Priority claimed from US12/535,254 external-priority patent/US8268290B2/en
Application filed by Uop Llc filed Critical Uop Llc
Priority to EP10806940A priority Critical patent/EP2462060A2/en
Publication of WO2011017183A2 publication Critical patent/WO2011017183A2/en
Publication of WO2011017183A3 publication Critical patent/WO2011017183A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins

Abstract

This invention relates to a new family of crystalline microporous zeolite designated the UZM-29 family. These zeolites are represented by the empirical formula: Mm n+R+rAll-x ExSiyOz UZM-29 has the PHI structure type topology but is thermally stable up to a temperature of at least 350°C. The UZM-29 family of zeolite can be used in various hydrocarbon conversion processes such as, isomerization of butane.
PCT/US2010/043630 2009-08-04 2010-07-29 Uzm-29 family of crystalline zeolitic compositions and a method of preparing the compositions WO2011017183A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP10806940A EP2462060A2 (en) 2009-08-04 2010-07-29 Uzm-29 family of crystalline zeolitic compositions and a method of preparing the compositions

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US12/535,248 2009-08-04
US12/535,248 US8017824B2 (en) 2009-08-04 2009-08-04 Hydrocarbon conversion processes using UZM-29 and UZM-29HS crystalline zeolitic compositions
US12/535,254 2009-08-04
US12/535,254 US8268290B2 (en) 2009-08-04 2009-08-04 UZM-29 family of crystalline zeolitic compositions and a method of preparing the compositions

Publications (2)

Publication Number Publication Date
WO2011017183A2 WO2011017183A2 (en) 2011-02-10
WO2011017183A3 true WO2011017183A3 (en) 2011-06-30

Family

ID=43544882

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/043630 WO2011017183A2 (en) 2009-08-04 2010-07-29 Uzm-29 family of crystalline zeolitic compositions and a method of preparing the compositions

Country Status (2)

Country Link
EP (1) EP2462060A2 (en)
WO (1) WO2011017183A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8623321B1 (en) * 2012-12-12 2014-01-07 Uop Llc UZM-44 aluminosilicate zeolite

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6049018A (en) * 1999-01-21 2000-04-11 Mobil Corporation Synthetic porous crystalline MCM-68, its synthesis and use
US20050065016A1 (en) * 2003-09-23 2005-03-24 Lewis Gregory J. Crystalline aluminosilicates:UZM-13, UZM-17, UZM-19 and UZM-25
US6890511B2 (en) * 2003-03-21 2005-05-10 Uop Llc Crystalline aluminosilicate zeolitic composition: UZM-15
US20070209968A1 (en) * 2003-12-23 2007-09-13 Patrick Euzen Zeolitic catalyst, substrate based on a silica-alumina matrix and zeolite, and hydrocracking process for hydrocarbon feedstocks
US20080031810A1 (en) * 2006-08-03 2008-02-07 Miller Mark A Uzm-22 aluminosilicate zeolite, method of preparation and processes using uzm-22

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6049018A (en) * 1999-01-21 2000-04-11 Mobil Corporation Synthetic porous crystalline MCM-68, its synthesis and use
US6890511B2 (en) * 2003-03-21 2005-05-10 Uop Llc Crystalline aluminosilicate zeolitic composition: UZM-15
US20050065016A1 (en) * 2003-09-23 2005-03-24 Lewis Gregory J. Crystalline aluminosilicates:UZM-13, UZM-17, UZM-19 and UZM-25
US20070209968A1 (en) * 2003-12-23 2007-09-13 Patrick Euzen Zeolitic catalyst, substrate based on a silica-alumina matrix and zeolite, and hydrocracking process for hydrocarbon feedstocks
US20080031810A1 (en) * 2006-08-03 2008-02-07 Miller Mark A Uzm-22 aluminosilicate zeolite, method of preparation and processes using uzm-22

Also Published As

Publication number Publication date
EP2462060A2 (en) 2012-06-13
WO2011017183A2 (en) 2011-02-10

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