WO2011011217A1 - Impact locating day and night marker for a projectile - Google Patents
Impact locating day and night marker for a projectile Download PDFInfo
- Publication number
- WO2011011217A1 WO2011011217A1 PCT/US2010/041671 US2010041671W WO2011011217A1 WO 2011011217 A1 WO2011011217 A1 WO 2011011217A1 US 2010041671 W US2010041671 W US 2010041671W WO 2011011217 A1 WO2011011217 A1 WO 2011011217A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- projectile
- compartments
- target
- components
- training
- Prior art date
Links
- 239000003550 marker Substances 0.000 title claims description 12
- 239000000126 substance Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 12
- 239000008188 pellet Substances 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 4
- 239000002184 metal Substances 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 12
- 239000011888 foil Substances 0.000 claims description 9
- 230000001133 acceleration Effects 0.000 claims description 7
- 239000003380 propellant Substances 0.000 claims description 2
- 238000010586 diagram Methods 0.000 description 7
- 238000010304 firing Methods 0.000 description 4
- 239000011800 void material Substances 0.000 description 3
- 238000005192 partition Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000001044 red dye Substances 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/02—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
- F42B12/36—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
- F42B12/40—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information of target-marking, i.e. impact-indicating type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/02—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
- F42B12/36—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
- F42B12/38—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information of tracer type
- F42B12/382—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information of tracer type emitting an electromagnetic radiation, e.g. laser beam or infrared emission
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/02—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
- F42B12/36—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
- F42B12/46—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information for dispensing gases, vapours, powders or chemically-reactive substances
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B8/00—Practice or training ammunition
- F42B8/12—Projectiles or missiles
- F42B8/14—Projectiles or missiles disintegrating in flight or upon impact
Definitions
- the present invention relates to the field of practice ammunition and, specifically, to an ammunition projectile that can mark its point of impact both by day and by night.
- the invention concerns a device
- projectile incorporated into a projectile, that provides for marking the point of impact of the projectile when the projectile strikes a target.
- projectile is intended to include both mortar ammunition and artillery ammunition.
- Marking projectiles which use a dry powder, such as a red powder dye, for marking the impact by day are known, for example, from the U.S. Patent Publication No. 2006/0032393 to Haeselich. Marking projectiles which use chemi- luminescent materials for marking their impact by night are also known. Reference is made, for example, to the U.S. Patent No. 6,619,211 and the aforementioned Patent
- the components which are liquid, are
- the liquid components react and produce a luminescent glow.
- the mixed chemi-luminescent material is released and dispersed to mark the point of impact.
- the projectile has a translucent ogive so that it can also emit light during flight.
- the Haeselich reissue patent referred to above, discloses two compartments, arranged either side by side or one above the other in the projectile, with a frangible partition between them. While this arrangement is satisfactory under most conditions, it is not fully reliable in that the frangible partition can sometimes withstand the
- a principal object of the present invention is to provide a marking device for a projectile which reliably marks the point of impact with a target.
- a further object of the present invention is to provide a day and night marking device for a projectile which
- the frangible compartments in such a way that, instead of (or in addition to) utilizing the forces at acceleration setback to mix the liquid chemical components , they utilize centrifugal forces to initiate mixing.
- the projectile rotation that is induced by lands and grooves in the barrel of the weapon imparts a centrifugal force on one or more masses that are suspended in the chemical components disposed within their respective compartments.
- the resulting outward motion of the masses causes them to penetrate the foil packaging material of the compartments , releasing the liquid into a surrounding medium, which may, for example, be a dry powder. This medium provides for even distribution of the reacting liquid while the projectile is in flight.
- the present invention relates to a training projectile having (1) a cartridge shell with a propulsion chamber containing a propellant charge, and (2) a hollow projectile body inserted in the cartridge shell.
- the projectile body includes the following four elements : (a) A projectile head designed to withstand the forces applied when the projectile is fired from a weapon and having a frangible ogive designed to burst when the
- At least one marking agent disposed in the projectile head for marking the position of the projectile upon striking a target when the ogive has burst.
- This marking agent has two liquid components , each disposed in a
- Each mass is denser than the liquid component in its respective compartment and serves to break the compartment due to the centrifugal forces that act on the projectile when the projectile is fired from a weapon.
- the masses disposed in each of the compartments are metal pellets and a carrier surrounds the compartments to receive the mixed chemical components when the compartments are broken .
- the carrier preferably comprises a dry, fine powder of low density which may also serve as a second marking agent.
- This powder material, or other dry powder material is disposed in a separate compartment in the projectile head and is designed to create a plume for daytime marking of a target when the projectile strikes the target and the ogive bursts.
- the liquid chemical components of the marking agent are preferably either chemi-luminescent or exothermic, or both.
- liquid chemical components which, when mixed, create heat (called exothermic reactions) include (1) hydration of anhydrous salts , for example water and
- anhydrous calcium chloride or copper sulfate anhydrous calcium chloride or copper sulfate, and (2) liquid components that create polymerization reactions , such as the catalyzed polymerization of mono-methacrylate.
- the training projectile may additionally also comprise a third marking agent that includes a plurality of second chemical components , each received in a separate
- the third chemical components are preferably exothermic and create heat for thermally marking a target when the projectile strikes the target.
- the marking device of the present invention is thus incorporated into a projectile and includes:
- a projectile ogive or hood constructed of
- a frangible ogive which includes a void.
- a frangible foil container having multiple
- the compartments are filled with reactive chemicals to create chemical luminance, or create heat (NIR radiation) , when mixed, and
- the compartments each contain one or more dense penetrating masses, which are
- Fig. 1 is a representational diagram showing a hollow projectile disposed in the chamber of a weapon prior to firing.
- Fig. 2 is a representational diagram showing a projectile in the chamber of a weapon, which projectile incorporates a marking device according to the preferred embodiment of the invention .
- Fig. 3 is a representational diagram of the projectile of Fig. 2 during setback and immediately after firing in a weapon .
- Fig. 4 is a representational diagram of the projectile of Fig. 2 as it begins to emerge from the barrel of the weapon .
- Fig. 5 is a representational diagram of the projectile of Fig. 2 as it has almost entirely emerged from the barrel of the weapon.
- Fig. 6 is a representational diagram of the projectile of Fig. 2 just after it exits from the barrel of the weapon.
- Fig. 7 is a representational diagram of the projectile of Fig. 2 as it strikes a target and bursts open, marking the target after impact.
- Fig. 1 shows a projectile 10 disposed in the chamber of a weapon with a barrel 12, prior to firing and setback.
- the projectile 10 comprises a hollow projectile body 14 having a void 16 at the projectile head.
- FIG. 2 shows a projectile 20 having a marking device 22 in accordance with the preferred embodiment of the present invention, disposed in the projectile head.
- This marking device comprises four elements :
- These components are preferably either chemi-luminescent or exothermic, or both.
- the two compartments 24 and 26 are disposed substantially symmetrically about the center of rotation 32 of the projectile. 2.
- a red dye powder 30 disposed in the ogive of the projectile which, when released, forms a plume and serves as a day marker of the point of impact of the projectile.
- compartment 24, 26 which is suspended in the liquid component within each compartment.
- the pellets 34 and 36 are preferably made of a relatively dense metal, such as lead.
- the pellets 34 and 36 have punctured the foil 24 and 26, respectively, encasing the two compartments, allowing the chemical components within the compartments to disperse into the surrounding dry powder medium 28 and mix together so that they chemically react.
- Fig. 5 The liquid compartment continues to flow out through the openings in the foil as the projectile exits the barrel and continues to spin.
- the momentary deceleration due to air resistance on the projectile, causes a measured migration of escaped liquid toward the projectile ogive, as shown in Fig. 6.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Electromagnetism (AREA)
- Optics & Photonics (AREA)
- Toxicology (AREA)
- Toys (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK10802663.4T DK2457057T3 (en) | 2009-07-21 | 2010-07-12 | Day and night impact location marker for a projectile |
CA2768569A CA2768569C (en) | 2009-07-21 | 2010-07-12 | Impact locating day and night marker for a projectile |
AU2010274184A AU2010274184B2 (en) | 2009-07-21 | 2010-07-12 | Impact locating day and night marker for a projectile |
SG2012002309A SG177631A1 (en) | 2009-07-21 | 2010-07-12 | Impact locating day and night marker for a projectile |
EP10802663.4A EP2457057B1 (en) | 2009-07-21 | 2010-07-12 | Impact locating day and night marker for a projectile |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US27145209P | 2009-07-21 | 2009-07-21 | |
US61/271,452 | 2009-07-21 | ||
US12/834,223 US8297187B2 (en) | 2009-07-21 | 2010-07-12 | Impact locating day and night marker for a projectile |
US12/834,223 | 2010-07-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2011011217A1 true WO2011011217A1 (en) | 2011-01-27 |
WO2011011217A8 WO2011011217A8 (en) | 2012-04-19 |
Family
ID=43499353
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2010/041671 WO2011011217A1 (en) | 2009-07-21 | 2010-07-12 | Impact locating day and night marker for a projectile |
Country Status (7)
Country | Link |
---|---|
US (1) | US8297187B2 (en) |
EP (1) | EP2457057B1 (en) |
AU (1) | AU2010274184B2 (en) |
CA (1) | CA2768569C (en) |
DK (1) | DK2457057T3 (en) |
SG (1) | SG177631A1 (en) |
WO (1) | WO2011011217A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011107960B3 (en) * | 2011-07-20 | 2012-03-22 | Rheinmetall Waffe Munition Gmbh | Ammunition, particularly blank ammunition, has projectile body which comprises projectile casing, where charge is held to be exploded in air |
EP2862881A1 (en) | 2013-10-16 | 2015-04-22 | Solvay Acetow GmbH | Acylation process |
EP2862880A1 (en) | 2013-10-16 | 2015-04-22 | Solvay Acetow GmbH | Acylation process |
US10239959B2 (en) | 2013-10-16 | 2019-03-26 | Solvay Acetow Gmbh | Acylation process |
CN111253197A (en) * | 2020-03-10 | 2020-06-09 | 陈巧云 | Color-changing firework dyeing block of image-text firework dot matrix emitter and preparation method thereof |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL2464944T3 (en) * | 2009-08-11 | 2018-05-30 | Rheinmetall Waffe Munition Gmbh | Projectile with a multi-spectral marking plume |
US9068807B1 (en) * | 2009-10-29 | 2015-06-30 | Lockheed Martin Corporation | Rocket-propelled grenade |
US8485102B2 (en) * | 2010-04-14 | 2013-07-16 | Alliant Techsystems, Inc. | Marking ammunition |
US9074857B2 (en) * | 2010-10-24 | 2015-07-07 | Cyalume Technologies, Inc. | Multi-marker marking system |
US9140528B1 (en) | 2010-11-16 | 2015-09-22 | Lockheed Martin Corporation | Covert taggant dispersing grenade |
WO2013109634A1 (en) | 2012-01-16 | 2013-07-25 | Alliant Techsystems Inc. | Spin stabilized non-lethal projectile with a shear-thinning fluid |
EP2850381A1 (en) * | 2012-05-15 | 2015-03-25 | Selectamark Security Systems PLC | Tagging system |
US9423222B1 (en) | 2013-03-14 | 2016-08-23 | Lockheed Martin Corporation | Less-than-lethal cartridge |
US9217627B2 (en) * | 2013-03-21 | 2015-12-22 | Kms Consulting, Llc | Training ammunition cartridge with reactive liquid materials for marking a point of impact |
US9200876B1 (en) | 2014-03-06 | 2015-12-01 | Lockheed Martin Corporation | Multiple-charge cartridge |
US11226183B1 (en) * | 2015-04-21 | 2022-01-18 | Mezzimatic LLC | Throwable paint balls, kit, and method of manufacture |
US11639845B2 (en) * | 2017-08-24 | 2023-05-02 | Nostromo, Llc | Mid-body marking projectile |
CN110398185B (en) * | 2019-07-10 | 2023-07-04 | 中国科学院上海技术物理研究所 | Aviation training bullet with infrared target |
US11015906B2 (en) * | 2019-10-17 | 2021-05-25 | Sharon Lulay | Aerial reconnaissance marking projectile |
WO2022154851A2 (en) * | 2020-11-04 | 2022-07-21 | Nostromo, Llc | Mid body marking projectile |
US11287236B1 (en) * | 2020-11-04 | 2022-03-29 | Frank Dindl | Training cartridge with day/night/thermal visible signature |
IL309205A (en) * | 2021-06-09 | 2024-02-01 | Cyalume Tech Inc | Projectile payload for training ammunition with multi-spectral output |
US11892276B2 (en) * | 2021-12-08 | 2024-02-06 | Savit Corporation | Rear illumination projectile |
Citations (4)
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US4505200A (en) * | 1983-02-02 | 1985-03-19 | The United States Of America As Represented By The Secretary Of The Army | Dynamic seal |
US6619211B1 (en) * | 1999-06-02 | 2003-09-16 | Nico-Pyrotechnik Hanns-Juergen Diederichs Gmbh & Co. Kg | Practice ammunition |
US6931993B1 (en) | 2003-12-10 | 2005-08-23 | The United States Of America As Represented By The Secretary Of The Army | System and method for a flameless tracer / marker for ammunition housing multiple projectiles utilizing chemlucent chemicals |
US20060032393A1 (en) * | 2004-04-08 | 2006-02-16 | Nico-Pyrotechnik Hanns-Juergen Diederichs Gmbh & Co. Kg | 40 mm low cost cartridge |
Family Cites Families (11)
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GB2284252B (en) | 1993-11-25 | 1997-11-12 | Constantia Int Ltd | Marking bullet |
FR2718229B1 (en) | 1994-03-31 | 1996-06-21 | Ruggieri | Projectile, especially a non-lethal bullet. |
US5590886A (en) * | 1995-08-01 | 1997-01-07 | Lush; Craig L. | Reusable paint ball grenade, reloadable with standard .68 caliber paint balls |
FR2765869B1 (en) * | 1997-07-09 | 1999-08-13 | Giat Ind Sa | MARKING COMPOSITION AND EXERCISE AMMUNITION IMPLEMENTING SUCH COMPOSITION |
US6065404A (en) * | 1998-02-04 | 2000-05-23 | Cubic Defense Systems, Inc. | Training grenade for multiple integrated laser engagement system |
US6497181B1 (en) | 2001-12-04 | 2002-12-24 | The Government Of The United States Of America As Represented By The Secretary Of The Army | Flameless tracer ammunition |
US6990905B1 (en) * | 2003-06-30 | 2006-01-31 | The United States Of America As Represented By The Secretary Of The Army | Marker projectile |
US7055438B1 (en) * | 2003-10-21 | 2006-06-06 | The United States Of America As Represented By The Secretary Of The Army | System and method for a flameless tracer/marker utilizing heat marking chemicals |
DE102004017466A1 (en) | 2004-04-08 | 2005-11-03 | Nico-Pyrotechnik Hanns-Jürgen Diederichs GmbH & Co. KG | Projectile with marking of the impact point |
US7380503B2 (en) * | 2004-12-20 | 2008-06-03 | Newtec Services Group | Method and apparatus for self-destruct frangible projectiles |
US7784455B1 (en) * | 2007-09-18 | 2010-08-31 | Chong Carlton Le Loong | Reusable pellet shooting grenade |
-
2010
- 2010-07-12 AU AU2010274184A patent/AU2010274184B2/en active Active
- 2010-07-12 SG SG2012002309A patent/SG177631A1/en unknown
- 2010-07-12 US US12/834,223 patent/US8297187B2/en active Active
- 2010-07-12 CA CA2768569A patent/CA2768569C/en active Active
- 2010-07-12 WO PCT/US2010/041671 patent/WO2011011217A1/en active Application Filing
- 2010-07-12 EP EP10802663.4A patent/EP2457057B1/en active Active
- 2010-07-12 DK DK10802663.4T patent/DK2457057T3/en active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4505200A (en) * | 1983-02-02 | 1985-03-19 | The United States Of America As Represented By The Secretary Of The Army | Dynamic seal |
US6619211B1 (en) * | 1999-06-02 | 2003-09-16 | Nico-Pyrotechnik Hanns-Juergen Diederichs Gmbh & Co. Kg | Practice ammunition |
US6931993B1 (en) | 2003-12-10 | 2005-08-23 | The United States Of America As Represented By The Secretary Of The Army | System and method for a flameless tracer / marker for ammunition housing multiple projectiles utilizing chemlucent chemicals |
US20060032393A1 (en) * | 2004-04-08 | 2006-02-16 | Nico-Pyrotechnik Hanns-Juergen Diederichs Gmbh & Co. Kg | 40 mm low cost cartridge |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011107960B3 (en) * | 2011-07-20 | 2012-03-22 | Rheinmetall Waffe Munition Gmbh | Ammunition, particularly blank ammunition, has projectile body which comprises projectile casing, where charge is held to be exploded in air |
EP2549221A2 (en) | 2011-07-20 | 2013-01-23 | Rheinmetall Waffe Munition GmbH | Ammunition |
EP2862881A1 (en) | 2013-10-16 | 2015-04-22 | Solvay Acetow GmbH | Acylation process |
EP2862880A1 (en) | 2013-10-16 | 2015-04-22 | Solvay Acetow GmbH | Acylation process |
US10239959B2 (en) | 2013-10-16 | 2019-03-26 | Solvay Acetow Gmbh | Acylation process |
US10538597B2 (en) | 2013-10-16 | 2020-01-21 | Rhodia Acetow Gmbh | Acylation process |
US10626193B2 (en) | 2013-10-16 | 2020-04-21 | Rhodia Acetow Gmbh | Acylation process |
US11041024B2 (en) | 2013-10-16 | 2021-06-22 | Solvay Acetow Gmbh | Acylation process |
CN111253197A (en) * | 2020-03-10 | 2020-06-09 | 陈巧云 | Color-changing firework dyeing block of image-text firework dot matrix emitter and preparation method thereof |
CN111253197B (en) * | 2020-03-10 | 2021-09-21 | 陈巧云 | Color-changing firework dyeing block of image-text firework dot matrix emitter and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
DK2457057T3 (en) | 2017-12-04 |
US8297187B2 (en) | 2012-10-30 |
CA2768569A1 (en) | 2011-01-27 |
EP2457057A4 (en) | 2014-12-10 |
CA2768569C (en) | 2016-10-11 |
EP2457057B1 (en) | 2017-08-30 |
EP2457057A1 (en) | 2012-05-30 |
SG177631A1 (en) | 2012-02-28 |
AU2010274184A1 (en) | 2012-01-19 |
AU2010274184B2 (en) | 2014-06-12 |
US20120227614A1 (en) | 2012-09-13 |
WO2011011217A8 (en) | 2012-04-19 |
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