WO2011009972A1 - Composition de formation de mousse pour la génération de signalisations à durée temporelle limitée - Google Patents

Composition de formation de mousse pour la génération de signalisations à durée temporelle limitée Download PDF

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Publication number
WO2011009972A1
WO2011009972A1 PCT/ES2010/000286 ES2010000286W WO2011009972A1 WO 2011009972 A1 WO2011009972 A1 WO 2011009972A1 ES 2010000286 W ES2010000286 W ES 2010000286W WO 2011009972 A1 WO2011009972 A1 WO 2011009972A1
Authority
WO
WIPO (PCT)
Prior art keywords
foam
sorbitan
composition according
forming composition
sodium
Prior art date
Application number
PCT/ES2010/000286
Other languages
English (en)
Spanish (es)
Inventor
Pablo César SILVA
Original Assignee
Zuazo Gauger, S.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zuazo Gauger, S.L. filed Critical Zuazo Gauger, S.L.
Priority to MX2012000968A priority Critical patent/MX2012000968A/es
Priority to EP10801977A priority patent/EP2457622A1/fr
Priority to BR112012001486A priority patent/BR112012001486A2/pt
Priority to CN2010800329019A priority patent/CN102481480A/zh
Priority to US13/386,070 priority patent/US20120148741A1/en
Publication of WO2011009972A1 publication Critical patent/WO2011009972A1/fr
Priority to US14/514,076 priority patent/US20150037495A1/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63C—SKATES; SKIS; ROLLER SKATES; DESIGN OR LAYOUT OF COURTS, RINKS OR THE LIKE
    • A63C19/00—Design or layout of playing courts, rinks, bowling greens or areas for water-skiing; Covers therefor
    • A63C19/06—Apparatus for setting-out or dividing courts
    • A63C19/065—Line markings, e.g. tapes; Methods therefor
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B71/00—Games or sports accessories not covered in groups A63B1/00 - A63B69/00
    • A63B71/02—Games or sports accessories not covered in groups A63B1/00 - A63B69/00 for large-room or outdoor sporting games
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/008—Temporary coatings
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63C—SKATES; SKIS; ROLLER SKATES; DESIGN OR LAYOUT OF COURTS, RINKS OR THE LIKE
    • A63C19/00—Design or layout of playing courts, rinks, bowling greens or areas for water-skiing; Covers therefor
    • A63C19/06—Apparatus for setting-out or dividing courts
    • A63C19/065—Line markings, e.g. tapes; Methods therefor
    • A63C2019/067—Machines for marking

Definitions

  • the present invention relates to the field of devices and products used for the generation of brands, signals, writings, coatings, and the like, of the type that remain stable for a predetermined time that is limited to a desired period to comply with its signaling function and then disappear and, more particularly, the invention relates to a foam that can be easily applied by means of an atomizing device or of the aerosol type, and which has a texture and volume that makes it visible from a great distance and that lasts in that state for a very short period of time, enough to be applied in an event such as a sports show.
  • the referees of the game rarely get the players that form the barrier to respect the regulatory distance and it becomes difficult to check if the players remain aligned behind the distance indicated by the referee at the time of penalty. While the executor is accommodated to kick it is very common for the players of the barrier to advance antiregulatoryly without the referee noticing because the referee does not have any point or reference line to determine if the players have advanced with respect to the virtual line that The referee has indicated.
  • At least one propellant At least one propellant
  • At least one foam forming emulsifier at least one foam forming emulsifier
  • composition of the invention comprises:
  • At least one propellant at least one propellant, - at least one emulsifier for foaming; at least one cation hijacker;
  • this composition is capable of generating, when applied with an aerosol container of the type used for the application of foams, a foam that remains stable for a minimum time and up to a maximum time, preferably at least 1 minute and up to three minutes maximum, after which it disappears without leaving marks or residues that could damage the surface where it was applied or the game that takes place on it. In these conditions, it must remain under any inclement weather, that is, it must remain stable with rain, cold, heat, sunlight, etc.
  • the foam of the invention finds a special use in the demarcation of lines, points or areas on the grass in a soccer field, however the foam has proven to be efficient on any other surface, such as clay, if necessary, for tennis, cement, wood, etc. for board games, granite tiles, ceramics, and any other surfaces.
  • emulsifier foaming agent
  • foaming agent which met the objectives of the invention had to be chosen.
  • foam-forming emulsifiers were tested, including the following: sorbitan oleate (Span 20), sorbitan trioleate, sorbitan palmitate, sorbitan stearate, sorbitan triestearate, sorbitan isoestearate, sorbitan distearate, sorbitan dioleate , sorbitan diisoestearate, sorbitan triisoestearate, sorbitan cocoate, sorbitan caprylate, sorbitan sesquiisoestearate, sorbitan sesquioleate, sorbitan sesquiestearate, series 21-40-60-61-65-80-81-85 lauryl sulfate, ammonium lauryl sulfate, sodium lauryl sulfate, TEA lauryl sulfate,
  • sorbitan oleate (Span 20), sorbitan palmitate, sorbitan stearate, sorbitan isoestearate, sorbitan distearate, sorbitan dioleate were used, and the results obtained were of low stability, using concentrations between 0.50 % and 1.00%, and too stable between 1.00% and 5.00%, which was not as satisfactory according to the objectives of the invention.
  • Another foam was formed with the emulsifiers PEG-5 cocamide, hydrogenated PEG-40 castor oil, cetrimonium chloride, pEG-5 stearyl ammonium lactate, cetyl palmitate, PPG-2 isodeceth-7-carboxylate cetyl, DEA cocamide but in some tests, perforations of the container were generated and in others the decomposition of the product, for which reason they were not included among the preferred ones of the invention.
  • polyoxyethylene sorbitan monolaurate (polysorbate 20) had provided the best characteristics and expected results in a content of between 0.50% and 5.00%, obtaining an excellent characteristic in a concentration of around 0.94%.
  • the propellant was also tested and dimethyl ether, difluoroethane, tetrafluoroethane, butane, isobutane and propane were used.
  • Dimethyl ether was used because it was soluble in water. which gave a completely homogeneous aerosol, forming with the aqueous solution, a single phase.
  • propellant percentages of between 5% and 30%.
  • the aerosol gave a very good performance but when the compatibility was performed, some attack and perforation of the container was found, for which different types of antioxidants were tested to prevent corrosion, so it was preferred not to adopt this propellant among the preferred ones. It was also tested with ethane difluor that is not soluble in water and tests from 5% to 30% were performed.
  • the composition of the invention also includes a cation sequestrant that is selected from the group comprising diethylene triamine pentaacetic acid (DTPA), pentasodium DTPA, 1.3 DTPA, 1.3 Ammonium Ferric DTPA, ethylenediaminetetraacetic acid (EDTA), disodium EDTA, Disodium calcium EDTA, ammonic ferric EDTA, tetrasodium EDTA.
  • diethylene triamine pentaacetic acid (DTPA), pentasodium DTPA, 1.3 DTPA, 1.3 Ammonium Ferric DTPA have not given the best results expected by the invention.
  • tetrasodium EDTA acid present between 0.20% and 3.00%, has been the one that has produced the best results.
  • composition of the invention also employs a preservative selected from the group comprising 2-bromo-2- nitro-1,3-propanediol; 1,3-dimethylol-5,5-dimethylhydantoin; Chloroxylenol; Methylparaben; Propylparaben; Tertiary Butyl Hydroquinone; diazonidinyl urea, and a composition of diazolidinyl urea, propylene glycol and butylcarbamate.
  • a preservative selected from the group comprising 2-bromo-2- nitro-1,3-propanediol; 1,3-dimethylol-5,5-dimethylhydantoin; Chloroxylenol; Methylparaben; Propylparaben; Tertiary Butyl Hydroquinone; diazonidinyl urea, and a composition of diazolidinyl urea, propylene glycol and
  • the preferred preservative comprises a composition of diazolidinyl urea, propylene glycol and butylcarbamate, present between 0.10% and 2.00%. The conservative prevents the growth of Gram positive and Gram negative bacteria, molds and yeasts as well as a large number of common microorganisms.
  • preservative does not require additional preservatives, being effective at low levels of use, since only 0.1% to 0.5% is required. It can be used in both rinsable products and those that remain on the skin. It is compatible with virtually all raw materials that are used in the formulation of personal care products including proteins, vitamins, botanical extracts, surfactants and other complex ingredients. This preservative is applied in water-in-oil and oil-in-water emulsions, sunscreen products, moisturizers and lotions, makeups and other highly pigmented products.
  • a composition has been obtained for the generation of foam that has been applied successfully on different surfaces and in particular on grass, where the foam has remained stable, even in conditions of heavy rains, for a period measured between 1 and 3 minutes, being the composition comprised of: at least one propellant, present between 3.00% and 15.00% by weight based on the total weight of the composition;
  • At least one foam-forming emulsifier present between 0.20% and 6.00% by weight based on the total weight of the composition
  • At least one cation sequestrant present between 0.20% and 3.00% by weight based on the total weight of the composition
  • At least one non-toxic preservative present between 0.10% and 2.00% by weight based on the total weight of the composition
  • said foam-forming emulsifier comprises polyoxyethylene sorbitan monolaurate (polysorbate 20), present between 0.50% and 5.00%, at a concentration of 0.94%
  • said propellant comprises butane-isobutane-propane
  • said cation sequestrant comprises tetrasodium EDTA which is present between 0.20% and 3.00%
  • said preservative comprises said a composition of diazolidinyl urea, propylene glycol and butylcarbamate and is present between 0.10% and 2.00%
  • the water is distilled water present between 80.00% and 95.00%

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Medicinal Preparation (AREA)
  • Paints Or Removers (AREA)
  • Detergent Compositions (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

L'invention concerne une composition de formation de mousse pour la génération de marquages à durée temporelle limitée, de préférence pour marquer les lignes de mur et les points d'exécution des tirs de réparation dans le jeu du football. Ladite mousse reste stable pendant une très courte période de temps suffisante pour exécuter le tir, et la composition contient un agent propulseur, un agent émulsifiant de formation de mousse, un agent séquestrant des cations, un conservateur et de l'eau.
PCT/ES2010/000286 2009-07-21 2010-07-01 Composition de formation de mousse pour la génération de signalisations à durée temporelle limitée WO2011009972A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
MX2012000968A MX2012000968A (es) 2009-07-21 2010-07-01 Composicion formadora de espuma para la generacion de señalizaciones de duracion temporal acotada.
EP10801977A EP2457622A1 (fr) 2009-07-21 2010-07-01 Composition de formation de mousse pour la génération de signalisations à durée temporelle limitée
BR112012001486A BR112012001486A2 (pt) 2009-07-21 2010-07-01 composição espumante para gerar indicações temporárias
CN2010800329019A CN102481480A (zh) 2009-07-21 2010-07-01 用于产生临时标示的起泡组合物
US13/386,070 US20120148741A1 (en) 2009-07-21 2010-07-01 Foaming composition for creating indications for a limited duration of time
US14/514,076 US20150037495A1 (en) 2009-07-21 2014-10-14 Foaming composition for generating temporary indications

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ARP090102774A AR073346A1 (es) 2009-07-21 2009-07-21 Composicion formadora de espuma para la generacion de senalizaciones de duracion temporal acotada
ARP090102774 2009-07-21

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US13/386,070 A-371-Of-International US20120148741A1 (en) 2009-07-21 2010-07-01 Foaming composition for creating indications for a limited duration of time
US14/514,076 Division US20150037495A1 (en) 2009-07-21 2014-10-14 Foaming composition for generating temporary indications

Publications (1)

Publication Number Publication Date
WO2011009972A1 true WO2011009972A1 (fr) 2011-01-27

Family

ID=43498797

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/ES2010/000286 WO2011009972A1 (fr) 2009-07-21 2010-07-01 Composition de formation de mousse pour la génération de signalisations à durée temporelle limitée

Country Status (9)

Country Link
US (2) US20120148741A1 (fr)
EP (1) EP2457622A1 (fr)
CN (1) CN102481480A (fr)
AR (1) AR073346A1 (fr)
BR (1) BR112012001486A2 (fr)
CL (1) CL2012000173A1 (fr)
CO (1) CO6491056A2 (fr)
MX (1) MX2012000968A (fr)
WO (1) WO2011009972A1 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013448B (zh) * 2012-12-27 2014-06-25 山东美多包装股份有限公司 一种水基气雾剂及其制备方法
BE1022092B1 (nl) * 2014-08-14 2016-02-15 R.L.B.-SYSTEMEN, besloten vennootschap met beperkte aansprakelijkheid Samenstelling voor het vormen van een tijdelijk schuim, spuitbus voorzien van een dergelijke samenstelling, en werkwijze om een tijdelijke aanduiding op een sportveld aan te brengen
MX354930B (es) * 2014-10-23 2018-03-20 Consorcio Comex S A De C V Composicion para aerosol usada para marcar o delimitar en cualquier tipo de superficie con una duracion temporal.
CN106280930A (zh) * 2015-06-11 2017-01-04 上海福岛化工科技发展有限公司 水性醇酸气雾面漆及其制备方法
JP5963986B1 (ja) * 2015-10-08 2016-08-03 株式会社クイックレスポンス 泡でラインを引く芝のフィールド用マーキング剤および泡でラインを引く芝のフィールド用マーキングエアゾール剤
EP3402610B1 (fr) * 2016-01-13 2023-06-14 Record, Jason Procédé de distribution de mousse par contact prolongé et par pulvérisation et dispositif associé
CN105625029B (zh) * 2016-01-25 2018-09-14 谢丽萍 一种用于纺织泡沫上浆的起泡剂及其制备方法
US10011725B2 (en) 2016-06-16 2018-07-03 International Business Machines Corporation Paint compositions with color change characteristics
CN109862944A (zh) * 2016-10-21 2019-06-07 宝洁公司 用于以最佳制剂空间递送消费者所需的剂型体积和表面活性剂量的泡沫剂型
RU2732490C2 (ru) * 2016-11-29 2020-09-17 Акционерное общество "Международный инновационный нанотехнологический центр" Композиция для футбольной исчезающей пены
US10646772B1 (en) 2019-05-15 2020-05-12 Taylor Christopher Lowe Water balloon with eradicable colorant
US20210403678A1 (en) * 2020-06-24 2021-12-30 Evonik Operations Gmbh Use of long-chain phosphoric acid esters in aqueous polyurethane dispersions

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US20070134174A1 (en) * 2005-11-03 2007-06-14 Christopher Irwin Personal care composition
WO2008023295A2 (fr) * 2006-08-24 2008-02-28 Kimberly-Clark Worldwide, Inc. Formule nettoyante liquide aux propriétés de suspension et de formation de mousse
US20080206161A1 (en) * 2002-10-25 2008-08-28 Dov Tamarkin Quiescent foamable compositions, steroids, kits and uses thereof
US20080253973A1 (en) * 2002-10-25 2008-10-16 Foamix Ltd. Sensation modifying topical composition foam

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US20080206161A1 (en) * 2002-10-25 2008-08-28 Dov Tamarkin Quiescent foamable compositions, steroids, kits and uses thereof
US20080253973A1 (en) * 2002-10-25 2008-10-16 Foamix Ltd. Sensation modifying topical composition foam
US20050025736A1 (en) * 2003-07-30 2005-02-03 Janusz Jachowicz Hair and skin altering and protecting compositions
US20070134174A1 (en) * 2005-11-03 2007-06-14 Christopher Irwin Personal care composition
WO2008023295A2 (fr) * 2006-08-24 2008-02-28 Kimberly-Clark Worldwide, Inc. Formule nettoyante liquide aux propriétés de suspension et de formation de mousse

Also Published As

Publication number Publication date
AR073346A1 (es) 2010-11-03
EP2457622A1 (fr) 2012-05-30
CN102481480A (zh) 2012-05-30
US20150037495A1 (en) 2015-02-05
MX2012000968A (es) 2012-04-19
CO6491056A2 (es) 2012-07-31
BR112012001486A2 (pt) 2016-03-15
CL2012000173A1 (es) 2012-08-03
US20120148741A1 (en) 2012-06-14

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