WO2011000267A1 - Method for manufacturing cylindrical battery capable of improving battery capacity - Google Patents

Method for manufacturing cylindrical battery capable of improving battery capacity Download PDF

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Publication number
WO2011000267A1
WO2011000267A1 PCT/CN2010/074081 CN2010074081W WO2011000267A1 WO 2011000267 A1 WO2011000267 A1 WO 2011000267A1 CN 2010074081 W CN2010074081 W CN 2010074081W WO 2011000267 A1 WO2011000267 A1 WO 2011000267A1
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WIPO (PCT)
Prior art keywords
battery
height
annular groove
manufacturing
cylindrical
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PCT/CN2010/074081
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French (fr)
Chinese (zh)
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任灿
王春光
陈保同
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深圳市比克电池有限公司
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Publication of WO2011000267A1 publication Critical patent/WO2011000267A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/049Processes for forming or storing electrodes in the battery container
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/572Means for preventing undesired use or discharge
    • H01M50/584Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
    • H01M50/59Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries characterised by the protection means
    • H01M50/593Spacers; Insulating plates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/147Lids or covers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/147Lids or covers
    • H01M50/148Lids or covers characterised by their shape
    • H01M50/152Lids or covers characterised by their shape for cells having curved cross-section, e.g. round or elliptic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

A method for manufacturing cylindrical battery capable of improving the battery capacity, includes following steps: increasing the height h1 of an electrode group (13) by △h and packing the electrode group (13) into a battery can (11); forming an annular groove (112) with height h2 at the open end of the battery can (11); connecting a combination cap (12) with height h3 with the electrode group (13) and placing the combination cap (12) above the annular groove (112) with height h2, then sealing the battery can (11); exerting force F2 to compress the annular groove (112) and combination cap (12) with total height h2+h3 by △h, so as to improve the battery capacity by increasing height of the electrode group (13) △h without changing battery standard height. The method of the invention reduces the height of the annular groove (112) by compression process, therefore increases the space holding the electrode group (13) within the battery.

Description

一种可提高电池容量的圆柱形电池制造方法 Cylindrical battery manufacturing method capable of improving battery capacity 技术领域Technical field
本发明涉及电池制造领域,具体涉及一种圆柱形电池的制造方法。 The present invention relates to the field of battery manufacturing, and in particular to a method of manufacturing a cylindrical battery.
背景技术Background technique
请参考图1至图7,圆柱形电池一般包括电池筒体1、设置在电池筒体1内卷绕形成的高度为h1的电池极组3、安装在电池筒体1顶端的组合盖帽2以及设置在电池极组3中间的圆柱状支撑架4等部件。电池筒体1底部通常还设置用于将正/负极引出端52和电池极组隔开的底部绝缘圈7,电池筒体的顶部设置有用于将电池极组3和组合盖帽2绝缘隔开的顶部绝缘圈6。该顶部绝缘圈6压在电池极组3的上方并卡在电池筒体1上成型的高度为h2的环形槽12下。该顶部绝缘圈6的中心设有一个可使向上延伸的负/正极引出端51穿过的极耳孔,其直径略大于支撑架4的直径并可容纳该负/正极引出端51,该极耳孔还用于从电池筒体1的敞开端放入支撑架4。现有的圆柱形电池制造工艺中,一般通过辊槽工艺加工成型环形槽12,在成型环形槽12的同时,电池筒体1的环形槽12上方则形成用于卡装高度为h3的组合盖帽2的环形壁11。封装电池时,将组合盖帽放置在顶部绝缘圈6的上方,同时将向上延伸的负/正极引出端51焊接在组合盖帽2上,之后,用外力F1将环形壁11弯折压合在组合盖帽2的最外部的绝缘密封件22上。Referring to FIG. 1 to FIG. 7 , the cylindrical battery generally includes a battery cylinder 1 , a battery pole group 3 having a height h1 formed by winding in the battery cylinder 1 , a combined cap 2 mounted on the top end of the battery cylinder 1 , and A cylindrical support frame 4 and the like are disposed in the middle of the battery pole group 3. The bottom of the battery cylinder 1 is usually further provided with a bottom insulating ring 7 for separating the positive/negative electrode terminal 52 from the battery electrode group, and the top of the battery cylinder is provided with insulation for insulating the battery electrode group 3 and the combination cap 2 Top insulation ring 6. The top insulating ring 6 is pressed above the battery pole group 3 and is caught under the annular groove 12 of the height h2 formed on the battery cylinder 1. The center of the top insulating ring 6 is provided with a tab hole through which the upwardly extending negative/positive terminal 51 can pass, the diameter of which is slightly larger than the diameter of the support frame 4 and can accommodate the negative/positive terminal 51. It is also used to put the support frame 4 from the open end of the battery can 1. In the existing cylindrical battery manufacturing process, the annular groove 12 is generally formed by a roll groove process. At the same time as the annular groove 12 is formed, a combination cap for the hook height h3 is formed above the annular groove 12 of the battery cylinder 1. 2 annular wall 11. When the battery is packaged, the combined cap is placed above the top insulating ring 6, while the upwardly extending negative/positive terminal 51 is welded to the combined cap 2, after which the annular wall 11 is bent and pressed against the combined cap by an external force F1. 2 of the outermost insulating seal 22.
请参考图7,现有的组合盖帽2的具体结构包括引出电极的顶板21、用来在过热情况下切断电流的热敏电阻23、防爆的压力保护装置24以及与压力保护装置24焊接在一起的导电板25。所述顶板21、热敏电阻23、压力保护装置24和导电板25通过绝缘密封件22紧扣在一起。Referring to FIG. 7, the specific structure of the prior art combined cap 2 includes a top plate 21 for extracting an electrode, a thermistor 23 for cutting off current in case of overheating, an explosion-proof pressure protection device 24, and welding with the pressure protection device 24. Conductive plate 25. The top plate 21, the thermistor 23, the pressure protection device 24, and the conductive plate 25 are fastened together by an insulating seal 22.
如图1至图6所示,现有技术中制造圆柱形电池的具体步骤一般包括:As shown in FIG. 1 to FIG. 6, the specific steps of manufacturing a cylindrical battery in the prior art generally include:
首先制作电池筒体1,电池筒体1的底部放置将正/负极引出端52和电池极组3隔开的底部绝缘圈7;然后向电池筒体1内放入高度为h1的电池极组3,并将向下的正/负极引出端52绕过底部绝缘圈7与底部电极连接。First, the battery cylinder 1 is fabricated. The bottom of the battery cylinder 1 is placed with a bottom insulating ring 7 separating the positive/negative electrode terminal 52 and the battery electrode group 3; and then a battery group of height h1 is placed into the battery cylinder 1. 3. Connect the downward positive/negative lead terminal 52 around the bottom insulating ring 7 to the bottom electrode.
接着如图1所示,将顶部绝缘圈6放置在电池极组3的上端面上,并使竖直向上延伸的负/正极引出端51穿过顶部绝缘圈6的极耳孔。Next, as shown in FIG. 1, the top insulating ring 6 is placed on the upper end surface of the battery pole group 3, and the negative/positive terminal end 51 extending vertically upward passes through the tab hole of the top insulating ring 6.
之后,如图2所示,在电池筒体1上利用辊压工艺形成高度为h2的环形槽1,该环形槽12在电池筒体1内部形成一压紧在顶部绝缘圈6上的凸缘(未标示),该电池筒体1内部的凸缘1使顶部绝缘圈6紧压在电池极组3上,同时在电池筒体1的顶部形成环形壁11。Thereafter, as shown in FIG. 2, an annular groove 1 having a height h2 is formed on the battery cylinder 1 by a rolling process, and the annular groove 12 forms a flange which is pressed against the top insulating ring 6 inside the battery cylinder 1. (not shown), the flange 1 inside the battery cylinder 1 presses the top insulating ring 6 against the battery pole group 3 while forming the annular wall 11 at the top of the battery cylinder 1.
接着,如图3所示使支撑架4穿过顶部绝缘圈6上的极耳孔伸入电池极组3的内部中心,并与电池极组3形成紧密配合。Next, as shown in FIG. 3, the support frame 4 is inserted through the tab holes on the top insulating ring 6 into the inner center of the battery pole group 3, and forms a close fit with the battery pole group 3.
最后,将向上延伸的负/正极引出端51的自由端焊接在组合盖帽2的导电板25底部,向电池筒体1内部注入电解液后,并将组合盖帽2放置在电池筒体1的敞开端(以上步骤的顺序视具体工艺而定),并使得电池筒体1顶部的环形壁11围绕该组合盖帽,并贴紧组合盖帽外围的绝缘密封件22。利用外力F1将该环形壁压合贴紧在绝缘密封件22上,得到图6所示的圆柱形电池。Finally, the free end of the upwardly extending negative/positive terminal 51 is welded to the bottom of the conductive plate 25 of the combined cap 2, after the electrolyte is injected into the interior of the battery can 1, and the combined cap 2 is placed in the open of the battery can 1. The end (the order of the above steps depends on the specific process), and the annular wall 11 at the top of the battery cylinder 1 surrounds the combined cap and abuts against the insulating seal 22 at the periphery of the combined cap. The annular wall is press-fitted against the insulating sealing member 22 by an external force F1 to obtain a cylindrical battery as shown in FIG.
然而,电池容量与内部卷绕的电池极组3的体积直接相关。电池极组3的体积与电池极组3高度h1和展开宽度成正比。现有圆柱形电池的制造方法中,在电池筒体1有限的内部空间中,体积较大的包括电池极组3以及组合盖帽2,电池极组3的高度为h1,组合盖帽2的高度为h3。组合盖帽2承担了过热保护、压力保护、密封以及绝缘等多种功能,组合中功能部件很多。同时用来分离电池极组3和组合盖帽2的高度为h2的环形槽12结构也占用了较大的电池筒体1内部空间。现有各种型号电池整体高度H都是恒定不变的标准值,大致上电池整体高度H等于电池极组3的高度h1与环形槽的高度h2以及组合盖帽2的高度h3之和,H=h1+h2+h3。因此,现有的圆柱形电池制造方法中,电池筒体1的内部空间利用率较低,为了满足电子产品对大容量的电池的需求,电池容量还有待提升。However, the battery capacity is directly related to the volume of the internally wound battery pole group 3. The volume of the battery pole group 3 is proportional to the height h1 of the battery pole group 3 and the spread width. In the manufacturing method of the existing cylindrical battery, in the limited internal space of the battery cylinder 1, the larger volume includes the battery pole group 3 and the combined cap 2, the height of the battery pole group 3 is h1, and the height of the combined cap 2 is H3. The combined cap 2 takes on many functions such as overheat protection, pressure protection, sealing and insulation, and there are many functional components in the combination. At the same time, the structure of the annular groove 12 having the height h2 for separating the battery pole group 3 and the combined cap 2 also occupies a large internal space of the battery cylinder 1. The current overall height H of various types of batteries is a constant standard value. Generally, the overall height H of the battery is equal to the sum of the height h1 of the battery pole group 3 and the height h2 of the annular groove and the height h3 of the combined cap 2, H= H1+h2+h3. Therefore, in the existing cylindrical battery manufacturing method, the internal space utilization rate of the battery can 1 is low, and the battery capacity needs to be improved in order to meet the demand for large-capacity batteries of electronic products.
技术问题technical problem
本发明要解决的技术问题是弥补上述现有技术的不足,提供一种可充分利用电池内部空间,提高电池容量的圆柱形电池制造方法。 The technical problem to be solved by the present invention is to make up for the deficiencies of the above prior art, and to provide a cylindrical battery manufacturing method which can fully utilize the internal space of the battery and increase the battery capacity.
技术解决方案Technical solution
本发明的技术问题是通过以下技术方案予以解决的:一种可提高电池容量的圆柱形电池制造方法,包括以下步骤:将高度为h1+Δh的电池极组装入圆柱形电池的电池筒体内;在所述电池筒体的敞开端成型高度为h2的环形槽;将高度为h3的组合盖帽放置在电池筒体内的环形槽上方,所述组合盖帽连接电池极组,并将所述组合盖帽固定密封在电池筒体上,此时,电池总高度为H+Δh=(h1+Δh)+h2+h3,其中,H为圆柱形电池的标准高度;从电池的封口端施加压力(F2),所述压力(F2)将高度为(h2+h3)的环形槽和组合盖帽缩短Δh,环形槽和组合盖帽的高度降为(h2+h3)’,亦即(h2+h3)’=(h2+h3)-Δh,压缩环形槽以后,圆柱形电池恢复标准高度H =(h1+Δh)+(h2+h3)’=(h1+Δh)+(h2+h3)-Δh。The technical problem of the present invention is solved by the following technical solution: a cylindrical battery manufacturing method capable of improving battery capacity, comprising the steps of: loading a battery pole group having a height h1+Δh into a battery cylinder of a cylindrical battery; Forming an annular groove of height h2 at the open end of the battery barrel; placing a combined cap of height h3 above the annular groove in the battery barrel, the combined cap connecting the battery pole set, and fixing the combined cap Sealed on the battery barrel, at this time, the total height of the battery is H + Δh = (h1 + Δh) + h2 + h3, where H is the standard height of the cylindrical battery; pressure (F2) is applied from the sealing end of the battery, The pressure (F2) shortens the (h2+h3) annular groove and the combined cap by Δh, and the height of the annular groove and the combined cap decreases to (h2+h3)', that is, (h2+h3)'=(h2 +h3)-Δh, after compressing the annular groove, the cylindrical battery recovers to the standard height H = (h1 + Δh) + (h2+h3)' = (h1 + Δh) + (h2+h3) - Δh.
其中,所述电池筒体在环形槽上方的敞开端形成环形壁,组合盖帽放置在电池筒体的环形槽上方以后,利用外力将环形壁向内折弯,所述折弯的环形壁将所述组合盖帽固定密封在电池筒体内。Wherein, the battery cylinder forms an annular wall at an open end above the annular groove, and after the combined cap is placed over the annular groove of the battery cylinder, the annular wall is bent inward by an external force, and the bent annular wall will be The combined cap is fixedly sealed in the battery barrel.
具体来说,在将电池极组装入电池筒体之前,在所述电池筒体底部装设绝缘圈,从电池极组向下引出正/负极引出端,所述正/负极引出端绕过绝缘圈并与电池筒体的底部接触。Specifically, before the battery pole assembly is assembled into the battery cylinder, an insulating ring is disposed at the bottom of the battery cylinder, and a positive/negative electrode terminal is drawn downward from the battery pole group, and the positive/negative electrode terminal bypasses the insulation. The ring is in contact with the bottom of the battery barrel.
在所述电池极组的上部装设绝缘圈,从电池极组向上引出负/正极引出端,所述负/正极引出端穿过电池极组上方的绝缘圈并焊接在所述组合盖帽的底部。An insulating ring is disposed on an upper portion of the battery pole group, and a negative/positive terminal is drawn upward from the battery pole group, and the negative/positive terminal leads through the insulating ring above the battery pole group and welded to the bottom of the combined cap .
接着,将支撑架装入所述电池极组中间。Next, the support frame is loaded into the middle of the battery pole group.
本例中,在负/正极引出端与组合盖帽焊接之前或者之后,都可以向电池筒体内的电池极组注入电解液。In this example, the electrolyte may be injected into the battery pack of the battery cartridge before or after the negative/positive terminal is welded to the combined cap.
优选的,所述组合盖帽包括连接电池极组的导电板、导电的压力保护装置、热敏电阻以及导电的顶板,所述组合盖帽依次叠加的导电板、压力保护装置、热敏电阻以及顶板通过绝缘密封件从周围扣紧组合在一起。Preferably, the combined cap comprises a conductive plate connecting the battery pole set, a conductive pressure protection device, a thermistor and a conductive top plate, wherein the combined cap sequentially stacks the conductive plate, the pressure protection device, the thermistor and the top plate through The insulating seals are fastened together from the periphery.
具体的,所述压力保护装置包括焊接导电板的弹性部以及从弹性部延伸的连接部,所述弹性部和连接部交接处开设有保护缺口。Specifically, the pressure protection device includes an elastic portion that welds the conductive plate and a connecting portion that extends from the elastic portion, and a protective gap is formed at the intersection of the elastic portion and the connecting portion.
所述压力F2作用于折弯后的环形壁上。The pressure F2 acts on the bent annular wall.
有益效果Beneficial effect
本发明与现有技术相比的有益效果是:1)本发明的可提高电池容量的圆柱形电池制造方法,使用通过压缩工艺,从而将电池筒体上环形槽和组合盖帽的高度(h2+h3)减小为(h2+h3)’,从而使得电池极组的高度h1增大Δh,直接增大了电池极组13的展开面积,从而提升电池容量,充分利用电池内部空间;2)本发明的可提高电池容量的圆柱形电池制造方法,能够显著提升电池容量,比如型号为18650的辊槽封口锂离子电池,该型号圆柱形电池标准高度H 为65毫米,传统工艺中电池极组的高度为58毫米,本发明中电池极组的高度为59.5=58+1.5毫米;其环形槽的高度h2传统为1.7毫米,采用本发明的工艺后环形槽的高度h2’减小为0.1~0.2毫米。采用本发明的工艺,电池筒体选材可采用比原来高1.5毫米多的电池筒体,该高出的1.5毫米多电池筒体部分为电池极组提供了增加高度的机会,从而增大电池极组的实际使用空间,通过增加将电池极组的高度来达到提升电池容量的目的。 The beneficial effects of the present invention compared with the prior art are: 1) a cylindrical battery manufacturing method of the present invention capable of improving battery capacity, using a compression process to thereby height the annular groove and the combined cap on the battery cylinder (h2+ H3) is reduced to (h2+h3)', so that the height h1 of the battery pole group is increased by Δh, which directly increases the expansion area of the battery pole group 13, thereby increasing the battery capacity and making full use of the internal space of the battery; 2) The invention discloses a cylindrical battery manufacturing method capable of improving battery capacity, which can significantly increase battery capacity, such as a 18650-type roll-sealed lithium ion battery, and a cylindrical battery standard height H 65 mm, the height of the battery pole set in the conventional process is 58 mm, the height of the battery pole set in the present invention is 59.5=58+1.5 mm; the height h2 of the annular groove is conventionally 1.7 mm, and the ring shape is adopted by the process of the present invention. The height h2' of the groove is reduced to 0.1 to 0.2 mm. By adopting the process of the invention, the battery cylinder can be selected from a battery cylinder which is more than 1.5 mm higher than the original, and the upper 1.5 mm multi-cell cylinder portion provides an opportunity for the battery pole group to increase the height, thereby increasing the battery pole. The actual use space of the group is achieved by increasing the height of the battery pole group to increase the battery capacity.
附图说明DRAWINGS
下面通过实施例并结合附图,对本发明作进一步的详细说明:The present invention will be further described in detail below by way of embodiments with reference to the accompanying drawings:
图1为现有的圆柱形电池制造方法中将顶部绝缘圈放入电池筒体的剖视图;1 is a cross-sectional view showing a method of manufacturing a cylindrical battery in which a top insulating ring is placed in a battery can;
图2为现有的圆柱形电池制造方法中辊槽工艺后的圆柱形电池剖视图;2 is a cross-sectional view of a cylindrical battery after a roll groove process in a conventional cylindrical battery manufacturing method;
图3为现有的圆柱形电池制造方法中将支撑架放入极组中间的圆柱形电池剖视图;3 is a cross-sectional view of a cylindrical battery in which a support frame is placed in the middle of a pole group in a conventional method of manufacturing a cylindrical battery;
图4为现有的圆柱形电池制造方法中将组合盖帽放置在电池筒体顶部的剖视图;4 is a cross-sectional view showing a conventional cap battery manufacturing method in which a cap is placed on top of a battery can;
图5为现有的圆柱形电池制造方法中整合组合盖帽的剖视图;Figure 5 is a cross-sectional view showing an integrated composite cap in a conventional cylindrical battery manufacturing method;
图6为现有的圆柱形电池制造方法中电池组件的高度分布示意图;6 is a schematic view showing a height distribution of a battery assembly in a conventional method for manufacturing a cylindrical battery;
图7为现有的圆柱形电池制造方法中的组合盖帽的剖视图;Figure 7 is a cross-sectional view of a combined cap in a conventional method of manufacturing a cylindrical battery;
图8为本发明的圆柱形电池制造方法中组合盖帽的剖视图; Figure 8 is a cross-sectional view showing a combined cap in the method of manufacturing a cylindrical battery of the present invention;
图9为本发明的圆柱形电池制造方法中将底部和顶部绝缘圈放入电池筒体的剖视图;Figure 9 is a cross-sectional view showing the bottom and top insulating rings placed in the battery can in the method of manufacturing a cylindrical battery of the present invention;
图10为本发明的圆柱形电池制造方法中辊槽工艺后的圆柱形电池剖视图;Figure 10 is a cross-sectional view showing a cylindrical battery after the roll groove process in the method for manufacturing a cylindrical battery of the present invention;
图11为本发明的圆柱形电池制造方法中将支撑架放入极组中间的圆柱形电池剖视图;Figure 11 is a cross-sectional view showing a cylindrical battery in which a support frame is placed in the middle of a pole group in a method of manufacturing a cylindrical battery of the present invention;
图12为本发明的圆柱形电池制造方法中置入组合盖帽的剖视图;Figure 12 is a cross-sectional view showing the assembled cap in the method of manufacturing a cylindrical battery of the present invention;
图13为本发明的圆柱形电池制造方法中施加外力F1组装组合盖帽的电池剖视图。Figure 13 is a cross-sectional view showing a battery in which a combined cap is applied by applying an external force F1 in the method of manufacturing a cylindrical battery of the present invention.
图14为本发明的圆柱形电池制造方法中电池组件的高度分布示意图。Figure 14 is a schematic view showing the height distribution of the battery assembly in the method of manufacturing a cylindrical battery of the present invention.
图15为本发明的圆柱形电池制造方法中施加压力F2压缩环形槽的电池剖视图。Figure 15 is a cross-sectional view of a battery in which a pressure F2 compression annular groove is applied in a method of manufacturing a cylindrical battery of the present invention.
图16为本发明的圆柱形电池制造方法中环形槽被压缩后,电池组件的高度分布示意图。 Figure 16 is a schematic view showing the height distribution of the battery assembly after the annular groove is compressed in the method for manufacturing a cylindrical battery of the present invention.
本发明的实施方式Embodiments of the invention
下面通过具体的实施方式并结合附图对本发明做进一步详细说明。The invention will be further described in detail below with reference to specific embodiments and drawings.
本发明涉及一种可提高电池容量的圆柱形电池制造方法,该圆形电池制造方法采用将高度为h1+Δh的电池极组13装入圆柱形电池的电池筒体11内;在所述电池筒体11的敞开端成型高度为h2的环形槽112;将高度为h3的组合盖帽12放置在电池筒体11内的环形槽112上方,所述组合盖帽12连接电池极组13,并将所述组合盖帽12固定密封在电池筒体11上。本例中,该电池筒体11高度为H+Δh=(h1+Δh)+h2+h3,其中,H为圆柱形电池的标准高度。The present invention relates to a method of manufacturing a cylindrical battery capable of increasing battery capacity by using a battery electrode group 13 having a height h1 + Δh in a battery can 11 of a cylindrical battery; The open end of the barrel 11 is formed with an annular groove 112 having a height h2; a combined cap 12 having a height h3 is placed over the annular groove 112 in the battery cylinder 11, and the combined cap 12 is connected to the battery electrode group 13, and The combination cap 12 is fixedly sealed to the battery can 11 . In this example, the height of the battery barrel 11 is H + Δh = (h1 + Δh) + h2 + h3, where H is the standard height of the cylindrical battery.
本例中的电池筒体11底部封闭,顶部具有用来装入电池组件的开口,在电池极组13和组合盖帽12等组件组装完毕之后,在电池顶部形成封口端。对封口端施加压力(F2),从电池的封口端施加压力(F2),所述压力(F2)将高度为h2+h3的环形槽和组合盖帽缩短Δh,环形槽和组合盖帽的高度降为(h2+h3)’,亦即(h2+h3)’=(h2+h3)-Δh,压缩环形槽以后,圆柱形电池恢复标准高度H =(h1+Δh)+ (h2+h3)’=(h1+Δh)+(h2+h3)-Δh。从而使得电池极组13的高度h1增大Δh,直接增大了电池极组13的展开面积,提高了电池容量。The battery cylinder 11 in this example is closed at the bottom, and the top has an opening for loading the battery assembly. After the components such as the battery electrode group 13 and the combination cap 12 are assembled, a sealing end is formed on the top of the battery. Applying pressure (F2) to the sealing end, applying pressure (F2) from the sealing end of the battery, the pressure (F2) shortening the annular groove and the combined cap of height h2+h3 by Δh, and the height of the annular groove and the combined cap is reduced to (h2+h3)', that is, (h2+h3)'=(h2+h3)-Δh, after compressing the annular groove, the cylindrical battery recovers to the standard height H =(h1+Δh)+ (h2+h3)'=(h1+Δh)+(h2+h3)-Δh. Thereby, the height h1 of the battery pole group 13 is increased by Δh, which directly increases the expanded area of the battery pole group 13, and increases the battery capacity.
以下具体介绍本发明的技术方案。The technical solution of the present invention will be specifically described below.
请参考图1至图16,本实施方式中的圆柱形电池主要包括电池筒体11、设置在电池筒体11内卷绕形成的高度为h1+Δh的电池极组13、安装在电池筒体11顶端的高度为h3的组合盖帽12以及设置在电池极组13中间的圆柱状支撑架14等部件。本例中,该电池筒体11高度为H+Δh=(h1+Δh)+h2+h3,其中,H为圆柱形电池的标准高度。Referring to FIG. 1 to FIG. 16 , the cylindrical battery in the present embodiment mainly includes a battery cylinder 11 , a battery pole set 13 formed by winding in the battery cylinder 11 and having a height h1+Δh, and being mounted on the battery cylinder. 11 is a combination of a cap 12 having a height h3 at the top end and a cylindrical support frame 14 disposed in the middle of the battery pole group 13. In this example, the height of the battery barrel 11 is H + Δh = (h1 + Δh) + h2 + h3, where H is the standard height of the cylindrical battery.
电池筒体11底部设置用于将正/负极引出端152和电池极组13隔开的底部绝缘圈17,所述正/负极引出端152绕过底部绝缘圈17并与电池筒体11的底部接触。电池筒体11的顶部设置有用于将电池极组13和组合盖帽12绝缘隔开的顶部绝缘圈16。该顶部绝缘圈16压在电池极组13的上方并卡在电池筒体11上成型的环形槽112下。该顶部绝缘圈16的中心设有一个可使向上延伸的负/正极引出端151穿过的极耳孔(图未示),其直径略大于支撑架14的直径并可容纳该负/正极引出端151,通过该极耳孔,可从电池筒体11的敞开端将支撑架14放入电池极组13的中心。A bottom insulating ring 17 for separating the positive/negative electrode terminal 152 and the battery electrode group 13 is disposed at the bottom of the battery can 11 , and the positive/negative electrode terminal 152 bypasses the bottom insulating ring 17 and the bottom of the battery can 11 contact. The top of the battery barrel 11 is provided with a top insulating ring 16 for insulating the battery electrode group 13 and the combined cap 12 from each other. The top insulating ring 16 is pressed over the battery pole group 13 and is caught under the annular groove 112 formed on the battery cylinder 11. The center of the top insulating ring 16 is provided with a tab hole (not shown) through which the upwardly extending negative/positive terminal 151 can pass, the diameter of which is slightly larger than the diameter of the support frame 14 and can accommodate the negative/positive terminal. 151. The support frame 14 can be placed in the center of the battery pole group 13 from the open end of the battery can 11 through the tab hole.
所述电池筒体11通过辊槽工艺在电池筒体11外部成型高度为h2的环形槽112。本实施方式中,该辊槽工艺是三个位置呈正三角安排的旋转的辊槽盘片,加工的电池筒体本身也旋转,通过盘片和电池筒体的相对运动,在电池筒体的外部辊出均匀的环槽。该环形槽112在电池筒体11内部形成压紧顶部绝缘圈16的凸缘,并且所述电池筒体11在环形槽112上方的敞开端形成环形壁111。The battery cylinder 11 forms an annular groove 112 having a height h2 outside the battery cylinder 11 by a roll groove process. In the embodiment, the roller groove process is a rotating roller groove disk arranged in a positive triangle at three positions, and the processed battery cylinder itself also rotates, and the relative movement of the disk and the battery cylinder is outside the battery cylinder. Roll out a uniform ring groove. The annular groove 112 forms a flange for pressing the top insulating ring 16 inside the battery cylinder 11, and the battery cylinder 11 forms an annular wall 111 at the open end above the annular groove 112.
本实施方式中,所述组合盖帽12包括连接电池极组13的导电板128、导电的压力保护装置124、热敏电阻123以及导电的顶板121。所述组合盖帽12依次叠加的导电板128、压力保护装置124、热敏电阻123以及顶板121通过绝缘密封件122从周围扣紧组合在一起。导电板128底部设置若干焊接点,该焊接点与电池极组13向上延伸的负/正极引出端151焊接。导电板128与压力保护装置124焊接在一起。In the present embodiment, the combined cap 12 includes a conductive plate 128 connecting the battery pole group 13, a conductive pressure protection device 124, a thermistor 123, and a conductive top plate 121. The conductive plates 128, the pressure protection device 124, the thermistor 123, and the top plate 121, which are sequentially stacked by the combination cap 12, are fastened together by the insulating seal 122 from the periphery. A plurality of solder joints are disposed at the bottom of the conductive plate 128, and the solder joints are soldered to the negative/positive terminal terminals 151 extending upward from the battery pole group 13. The conductive plate 128 is welded to the pressure protection device 124.
所述绝缘密封件122的下方设置有用来围栏导电板128的收容环。A receiving ring for the fence conductive plate 128 is disposed below the insulating sealing member 122.
本例中采用了热敏电阻123连接压力保护装置124和顶板121。锂离子圆柱形电池由于轻重量和高能量密度,具有优于其它类型可充电电池,比如镍镉电池和镍金属氢化物电池。锂离子电池对过充电极其敏感,安全性一直是电池制造众关注的问题。例如,电池单元变为过充电,金属锂可能镀到电池单元的电极上去,由于金属锂具有易燃特性而引发火灾,当电池温度变得过高时,排除有毒气体。所以需要热敏电阻123作为安全保护装置,在电池温度升高过热时,实践中温度在80至90摄氏度之间时,该热敏电阻123的阻值升高切断电流,防止发生灾害。In this example, a thermistor 123 is used to connect the pressure protection device 124 and the top plate 121. Lithium-ion cylindrical batteries are superior to other types of rechargeable batteries, such as nickel-cadmium batteries and nickel metal hydride batteries, due to their light weight and high energy density. Lithium-ion batteries are extremely sensitive to overcharging, and safety has always been a concern of battery manufacturers. For example, the battery unit becomes overcharged, and metallic lithium may be plated on the electrode of the battery unit, which causes a fire due to the flammable characteristics of the metallic lithium, and removes the toxic gas when the battery temperature becomes too high. Therefore, the thermistor 123 is required as a safety protection device. When the temperature of the battery rises and overheats, when the temperature is between 80 and 90 degrees Celsius in practice, the resistance of the thermistor 123 rises to cut off the current and prevent a disaster.
本例中从安全性考量,进一步采用了压力保护装置124,该压力保护装置124是破坏性保护装置。一般来说,电池的压力保护装置需要耐受一定压力,当电池内压超过压力保护装置的耐压极限,压力保护装置被内部破坏,使电池泄压,防止电池爆炸。所述压力保护装置124包括焊接导电板128的弹性部242以及从弹性部242向四周延伸的连接部246,所述弹性部242和连接部246交接处开设有保护缺口244。该保护缺口244在电池内压超过压力保护装置的耐压极限时,压力保护装置从弹性部242和连接部246交接处的保护缺口244被撑破,使得电池泄压,防止爆炸,但是电池从此被损坏,不能再使用。In this example, from the perspective of safety, a pressure protection device 124 is further employed, which is a destructive protection device. Generally speaking, the pressure protection device of the battery needs to withstand a certain pressure. When the internal pressure of the battery exceeds the withstand voltage limit of the pressure protection device, the pressure protection device is internally damaged, and the battery is released from pressure to prevent the battery from exploding. The pressure protection device 124 includes an elastic portion 242 that welds the conductive plate 128 and a connecting portion 246 that extends from the elastic portion 242 to the periphery. The protective portion 244 is formed at the intersection of the elastic portion 242 and the connecting portion 246. When the internal pressure of the battery exceeds the withstand voltage limit of the pressure protection device, the protection gap 244 of the pressure protection device from the intersection of the elastic portion 242 and the connecting portion 246 is broken, so that the battery is released from pressure and prevents explosion, but the battery is It is damaged and can no longer be used.
请参考图9至图16,以下具体介绍本例中的可提高电池容量的圆柱形电池制造方法,具体包括以下步骤:Referring to FIG. 9 to FIG. 16 , a method for manufacturing a cylindrical battery capable of improving battery capacity in the present embodiment is specifically described below, and specifically includes the following steps:
如图9所示,在所述电池筒体11底部装设底部绝缘圈17,将高度为h1+Δh的电池极组13装入圆柱形电池的电池筒体11内;从电池极组13向下引出正/负极引出端152,所述正/负极引出端152绕过绝缘圈17并与电池筒体11的底部接触。所述电池极组13上部装设顶部绝缘圈16。进一步的,从电池极组13向上引出负/正极引出端151。所述负/正极引出端151穿过电池极组13上方的顶部绝缘圈16并焊接在所述组合盖帽12的底部,本例中,该负/正极引出端151穿过顶部绝缘圈16焊接在所述组合盖帽12的导电板128底部。As shown in FIG. 9, a bottom insulating ring 17 is disposed at the bottom of the battery cylinder 11, and a battery pole group 13 having a height h1+Δh is loaded into the battery cylinder 11 of the cylindrical battery; The positive/negative electrode terminal 152 is taken down, and the positive/negative electrode terminal 152 bypasses the insulating ring 17 and comes into contact with the bottom of the battery can 11 . A top insulating ring 16 is mounted on the upper portion of the battery pole group 13. Further, the negative/positive terminal 151 is drawn upward from the battery pole group 13. The negative/positive terminal 151 passes through the top insulating ring 16 above the battery pole set 13 and is welded to the bottom of the combined cap 12, in this example, the negative/positive terminal 151 is soldered through the top insulating ring 16 The bottom of the conductive plate 128 of the combined cap 12.
如图10所示,在所述电池筒体11外通过辊槽工艺成型高度为h2的环形槽112。该环形槽112在电池筒体11内部形成压紧顶部绝缘圈16的凸缘。所述电池筒体11在环形槽112上方的敞开端形成环形壁111。As shown in FIG. 10, an annular groove 112 having a height h2 is formed by a roll groove process outside the battery cylinder 11. The annular groove 112 forms a flange that presses the top insulating ring 16 inside the battery barrel 11. The battery cylinder 11 forms an annular wall 111 at the open end above the annular groove 112.
如图11所示,将支撑架14装入所述电池极组13中间。As shown in Fig. 11, the support frame 14 is placed in the middle of the battery pole group 13.
本例中,在负/正极引出端151与组合盖帽12的导电板128焊接之前或者之后,都可以向电池筒体11内的电池极组13注入电解液。In this example, the electrolyte may be injected into the battery electrode group 13 in the battery can 11 before or after the negative/positive terminal 151 is welded to the conductive plate 128 of the combination cap 12.
如图12所示,将高度为h3的组合盖帽12放置在电池筒体11内的凸缘上方。所述组合盖帽12底端的导电板128通过负/正极引出端151连接电池极组13。As shown in FIG. 12, the combined cap 12 of height h3 is placed over the flange in the battery barrel 11. The conductive plates 128 at the bottom end of the combined cap 12 are connected to the battery electrode group 13 through the negative/positive terminal terminals 151.
如图13与图14所示,利用外力F1将环形壁111向电池筒体11内折弯,所述环形壁111贴紧在组合盖帽12的顶板121,从而将组合盖帽12固定安装在电池筒体11上。此时,电池总高度为H+Δh=(h1+Δh)+h2+h3,其中,H为圆柱形电池的标准高度。As shown in FIG. 13 and FIG. 14, the annular wall 111 is bent into the battery cylinder 11 by an external force F1, and the annular wall 111 is in close contact with the top plate 121 of the combined cap 12, thereby fixing the combined cap 12 to the battery can. On body 11. At this time, the total height of the battery is H + Δh = (h1 + Δh) + h2 + h3, where H is the standard height of the cylindrical battery.
如图15与图16所示,从电池的封口端施加压力(F2),所述压力(F2)将高度为(h2+h3)的环形槽和组合盖帽缩短Δh,环形槽和组合盖帽的高度降为(h2+h3)’,亦即(h2+h3)’=(h2+h3)-Δh,压缩环形槽以后,圆柱形电池恢复标准高度H =(h1+Δh)+ (h2+h3)’=(h1+Δh)+(h2+h3)-Δh。其中,所述压力F2作用于折弯后的环形壁上。As shown in Figures 15 and 16, a pressure (F2) is applied from the sealing end of the battery, the pressure (F2) shortening the annular groove and the combined cap of height (h2+h3) by Δh, the height of the annular groove and the combined cap Drop to (h2+h3)', ie (h2+h3)'=(h2+h3)-Δh, after compressing the annular groove, the cylindrical battery recovers to the standard height H = (h1 + Δh) + (h2+h3)' = (h1 + Δh) + (h2+h3) - Δh. Wherein, the pressure F2 acts on the bent annular wall.
具体以型号为18650的辊槽封口锂离子电池为例。该型号圆柱形电池标准高度H 为65毫米,传统工艺中电池极组的高度为58毫米,本发明中电池极组的高度为59.5=58+1.5毫米;其环形槽的高度h2传统为1.7毫米,采用本发明的工艺后环形槽的高度h2’减小为0.1~0.2毫米。采用本发明的工艺,电池筒体选材可采用比原来高1.5毫米多的电池筒体,该高出的1.5毫米多电池筒体部分为电池极组提供了增加高度的机会,从而增大电池极组的实际使用空间,通过增加将电池极组的高度来达到提升电池容量的目的。Take the example of a 18650-roller-sealed lithium-ion battery as an example. This model cylindrical battery standard height H 65 mm, the height of the battery pole set in the conventional process is 58 mm, the height of the battery pole set in the present invention is 59.5=58+1.5 mm; the height h2 of the annular groove is conventionally 1.7 mm, and the ring shape is adopted by the process of the present invention. The height h2' of the groove is reduced to 0.1 to 0.2 mm. By adopting the process of the invention, the battery cylinder can be selected from a battery cylinder which is more than 1.5 mm higher than the original, and the upper 1.5 mm multi-cell cylinder portion provides an opportunity for the battery pole group to increase the height, thereby increasing the battery pole. The actual use space of the group is achieved by increasing the height of the battery pole group to increase the battery capacity.
以上内容是结合具体的优选实施方式对本发明所作的进一步详细说明,不能认定本发明的具体实施只局限于这些说明。对于本发明所属技术领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干简单推演或替换,都应当视为属于本发明的保护范围。 The above is a further detailed description of the present invention in connection with the specific preferred embodiments, and the specific embodiments of the present invention are not limited to the description. It will be apparent to those skilled in the art that the present invention may be made without departing from the spirit and scope of the invention.

Claims (10)

  1. 一种可提高电池容量的圆柱形电池制造方法,包括以下步骤: A method of manufacturing a cylindrical battery capable of increasing battery capacity, comprising the steps of:
    将高度h1的电池极组增加高度Δh并装入电池筒体内;Adding a height Δh of the battery pole group of height h1 into the battery barrel;
    在所述电池筒体的敞开端成型h2高度的环形槽;Forming an annular groove of height h2 at an open end of the battery barrel;
    将高度为h3的组合盖帽连接电池极组并放置在h2高度的环形槽上方后与电池筒体密封;Connecting the combined cap of height h3 to the battery pole set and placing it above the annular groove of height h2, and sealing with the battery cylinder;
    施加压力(F2)将总共高度为h2+h3的环形槽和组合盖帽压缩Δh,使得在不改变电池标准高度的情况下将电池极组的高度增大Δh以提高电池容量。Applying pressure (F2) compresses the annular groove and the combined cap of a total height of h2+h3 by Δh, so that the height of the battery pole group is increased by Δh without changing the standard height of the battery to increase the battery capacity.
  2. 根据权利要求1所述的可提高电池容量的圆柱形电池制造方法,其特征在于:A method of manufacturing a cylindrical battery capable of improving battery capacity according to claim 1, wherein:
    所述组合盖帽固定密封在电池筒体上后,电池总高度高于标准高度,为H+Δh=(h1+Δh)+h2+h3,其中,H为圆柱形电池的标准高度;After the combined cap is fixedly sealed on the battery cylinder, the total height of the battery is higher than the standard height, and is H + Δh = (h1 + Δh) + h2 + h3, wherein H is the standard height of the cylindrical battery;
    所述压力(F2)在压缩环形槽和组合盖帽之后,环形槽和组合盖帽的高度降为(h2+h3)’ =(h2+h3)-Δh,压缩环形槽以后,圆柱形电池恢复标准高度H =(h1+Δh)+(h2+h3)’=(h1+Δh)+(h2+h3)-Δh。The pressure (F2) after the compression of the annular groove and the combined cap, the height of the annular groove and the combined cap is reduced to (h2+h3)' =(h2+h3)-Δh, after compressing the annular groove, the cylindrical battery recovers to the standard height H = (h1 + Δh) + (h2+h3)' = (h1 + Δh) + (h2+h3) - Δh.
  3. 根据权利要求2所述的可提高电池容量的圆柱形电池制造方法,其特征在于:所述电池筒体在环形槽上方的敞开端形成环形壁,组合盖帽放置在电池筒体的环形槽上方以后,利用外力(F1)将环形壁向内折弯,所述折弯的环形壁将所述组合盖帽固定密封在电池筒体内。The method of manufacturing a cylindrical battery according to claim 2, wherein the battery cylinder forms an annular wall at an open end above the annular groove, and the combined cap is placed over the annular groove of the battery cylinder. The annular wall is bent inward by an external force (F1) that securely seals the combined cap in the battery barrel.
  4. 根据权利要求3所述的可提高电池容量的圆柱形电池制造方法,其特征在于:在将电池极组装入电池筒体之前,在所述电池筒体底部装设绝缘圈,从电池极组向下引出正/负极引出端,所述正/负极引出端绕过绝缘圈并与电池筒体的底部接触。The method of manufacturing a cylindrical battery according to claim 3, wherein before the battery pole assembly is assembled into the battery cylinder, an insulating ring is disposed at the bottom of the battery cylinder, from the battery pole group The positive/negative lead terminals are taken out, and the positive/negative lead terminals bypass the insulating ring and are in contact with the bottom of the battery can.
  5. 根据权利要求4所述的可提高电池容量的圆柱形电池制造方法,其特征在于:在所述电池极组的上部装设绝缘圈,从电池极组向上引出负/正极引出端,所述负/正极引出端穿过电池极组上方的绝缘圈并焊接在所述组合盖帽的底部。The method of manufacturing a cylindrical battery according to claim 4, wherein an insulating ring is disposed on an upper portion of the battery pole group, and a negative/positive terminal is drawn upward from the battery pole group, the negative / The positive terminal leads through the insulating ring above the battery pole set and is welded to the bottom of the combined cap.
  6. 根据权利要求5所述的可提高电池容量的圆柱形电池制造方法,其特征在于:将支撑架装入所述电池极组中间。The method of manufacturing a cylindrical battery according to claim 5, wherein the support frame is placed in the middle of the battery pole group.
  7. 根据权利要求4或5所述的可提高电池容量的圆柱形电池制造方法,其特征在于:向电池筒体内的电池极组注入电解液。A method of manufacturing a cylindrical battery capable of improving battery capacity according to claim 4 or 5, wherein the electrolyte is injected into the battery electrode group in the battery can.
  8. 根据权利要求1所述的可提高电池容量的圆柱形电池制造方法,其特征在于:所述组合盖帽包括连接电池极组的导电板、导电的压力保护装置、热敏电阻以及导电的顶板,所述组合盖帽依次叠加的导电板、压力保护装置、热敏电阻以及顶板通过绝缘密封件从周围扣紧组合在一起。 The method of manufacturing a cylindrical battery according to claim 1, wherein the combined cap comprises a conductive plate connecting the battery pole group, a conductive pressure protection device, a thermistor, and a conductive top plate. The conductive plates, the pressure protection device, the thermistor, and the top plate in which the combined caps are sequentially stacked are fastened together by an insulating seal.
  9. 根据权利要求8所述的可提高电池容量的圆柱形电池制造方法,其特征在于:所述压力保护装置包括焊接导电板的弹性部以及从弹性部延伸的连接部,所述弹性部和连接部交接处开设有保护缺口。A method of manufacturing a cylindrical battery capable of improving battery capacity according to claim 8, wherein said pressure protecting means comprises an elastic portion for welding a conductive plate and a connecting portion extending from the elastic portion, said elastic portion and said connecting portion A protection gap is provided at the junction.
  10. 根据权利要求8所述的可提高电池容量的圆柱形电池制造方法,其特征在于:压力F2作用于折弯后的环形壁上。 A method of manufacturing a cylindrical battery capable of improving battery capacity according to claim 8, wherein a pressure F2 acts on the bent annular wall.
PCT/CN2010/074081 2009-06-29 2010-06-18 Method for manufacturing cylindrical battery capable of improving battery capacity WO2011000267A1 (en)

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