WO2010132332A1 - Phosphorus-containing flame retardants - Google Patents
Phosphorus-containing flame retardants Download PDFInfo
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- WO2010132332A1 WO2010132332A1 PCT/US2010/034187 US2010034187W WO2010132332A1 WO 2010132332 A1 WO2010132332 A1 WO 2010132332A1 US 2010034187 W US2010034187 W US 2010034187W WO 2010132332 A1 WO2010132332 A1 WO 2010132332A1
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- resin composition
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- melamine
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5397—Phosphine oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Definitions
- This invention relates to phosphorus-containing flame retardants particularly, but not exclusively for glass-filled polyamide resins.
- Polyamides are, in general, characterized as being relatively thermally stable upon long exposure to processing temperatures and shear. Upon exposure to flame, however, they burn quite readily, with the flammability being characterized by a dripping behavior of the burning resin. There is therefore a substantial and increasing demand for flame retardant polyamides and especially flame retardant glass-filled polyamides. Likewise, there is also demand for their polyester resin cousins, typically glass reinforced, with the choice of resin being dependent on several factors such as a balance between cost and mechanical property performance.
- organic phosphorus compounds typically phosphates and phosphonates. These may be non-halogenated or may include phosphorus-halogen compounds and blends of phosphorous compounds with halogenated flame retardants, typically brominated flame retardants.
- organic phosphorus compounds provide fire retardant activity through a combination of condensed phase reactions, polymer carbonization promotion, and char formation. These processes obviously depend on the polymer in which such additive(s) reside. Therefore, specific phosphorus containing structures need to be designed for various polymers types [0006] For example, U.S. Patent No.
- 3,681,281 discloses a shaped structure comprising a polyester, at least 1 percent by weight of the polyester of a tertiary phosphine oxide, and from about 10 to about 50 percent by weight of the tertiary phosphine oxide of a synergist selected from the group consisting of triphenylmelamine, benzil and dibenzyl.
- a synergist selected from the group consisting of triphenylmelamine, benzil and dibenzyl.
- tertiary phosphine oxides exemplified is xylylene bis-diphenylphosphine oxide.
- U.S. Patent No. 4,341,696 discloses a glass filled thermoplastic polyamide polymer rendered flame retardant by having combined therewith an effective amount of a tris-(3-hydroxyalkyl) phosphine oxide having the formula:
- R 1 and R 3 are any radical selected from the group consisting of hydrogen, phenyl and alkyl radicals of 1 to 4 carbon atoms and R 2 is any radical selected from the group consisting of hydrogen, phenyl and alkyl radicals of 2 to 4 carbon atoms, provided that when R 1 and R 3 are hydrogen radicals, R 2 is either an alkyl radical of 2 to 4 carbon atoms or a phenyl radical.
- U.S. Patent No. 7,332,534 discloses a flame retardant formulation for thermoplastic and thermoset polymers, including polyesters and polyamides, containing, as flame retardant component A, from 90 to 99.9% by weight of phosphinate salt of the formula:
- R 1 , R 2 are the same or different and are each C 1 - C ⁇ -alkyl, linear or branched, and/or aryl;
- R 3 is CrCio-alkylene, linear or branched, C ⁇ -Cio-arylene, -alkylarylene or -arylalkylene;
- M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K;
- m is from 1 to 4;
- n is from 1 to 4;
- x is from 1 to 4 and, as component B, from 0 to 50% by weight of a nitrogen- containing synergist or of a phosphorus/nitrogen flame retardant and, as component C, from 0.1 to 10% by weight of a liquid component.
- U.S. Patent No. 7,411,013 discloses a flame-retardant resin composition
- a base resin (A) such as a polyester, polyamide or styrenic resin
- an organic phosphorus compound (B) and a flame-retardant auxiliary (C)
- the organic phosphorus compound (B) has a unit represented by the following formula:
- Ar represents an aromatic hydrocarbon ring or a nitrogen-containing aromatic heterocycle
- X 1 represents an oxygen atom or a sulfur atom
- Y 1 and Y 2 are the same or different and each represents a hydrocarbon group, an alkoxy group, an aryloxy group, or an aralkyloxy group
- Z 1 represents an alkylene group, or a nitrogen-containing bivalent group corresponding to an alkylamine
- Y 1 and Y 2 may bind to each other, and Y 1 and Y 2 together with the adjacent phosphorus atom may form a ring
- "a" denotes 0 or 1
- "b” denotes an integer of 1 to 6.
- thermoplastic resins including polyamides, especially glass filled polyamides.
- a flame-retardant resin composition comprising a base resin (A), an organophosphorus compound (B) comprising a unit represented by at least one of the following formulas (I), (II) and (III): where A is selected from O, S, SO 2 , a single bond, alkyl, and -CH 2 -P 1 ; P 1 is a phosphorus -containing group of the formula:
- R 1 and R 2 are the same or different and each is selected from H, O-alkyl, O-aryl, alkyl, aryl, and OM;
- R 3 is H or alkyl
- M Na, K, Zn, Al, Ca; a is an integer from 0 to 4, provided that a is at least 1 unit for each polymer chain; n is an integer from 1 to 100,000 and m is an integer from 0 to 100,000, and optionally at least one flame retardant adjuvant material (C).
- the organophosphorus compound (B) is present in an amount of about 10% to about 30 % by weight of the flame-retardant resin composition.
- At least one flame retardant adjuvant material (C) is present and is selected from a melamine salt, an inorganic metal compound, a clay material, a layered double hydroxide material, and a polyphenylene ether resin.
- the at least one flame retardant adjuvant material (C) comprises a melamine salt and an inorganic metal compound in a weight ratio of between about 10:1 and about 1:1.
- the inorganic metal compound comprises a metal salt such as a borate, particularly zinc borate.
- the melamine salt comprises a melamine phosphate, particularly melamine polyphosphate or melamine pyrophosphate.
- the at least one flame retardant adjuvant material (C) is present in an amount of about 1 to about 20 wt% of the flame-retardant resin composition.
- the base resin (A) comprises at least one of a thermoplastic or thermoset resin.
- a typical thermoset resin is an epoxy resin and a typical thermoplastic resin is polyester, a polyamide, a polycarbonate or a styrenic resin.
- the base resin (A) comprises a polyamide and particularly a glass-filled polyamide, typically containing about 15 and about 40
- a flame-retardant resin composition comprising a base resin (A), a benzylic-substituted organophosphorus compound (B) and optionally at least one flame retardant adjuvant material (C).
- the base resin can be any organic macromolecular material, such as a polyester-series resin, a styrenic resin, a polyamide- series resin, a polycarbonate- series resin, a polyphenylene oxide-series resin, a vinyl-series resin, an olefinic resin, an acrylic resin, or an epoxy resin.
- the base resin can be a thermoplastic or a thermoset resin.
- Particularly preferred are engineering resins, such as polyester- series resins, poly amide- series resins and polycarbonates, especially glass-filled polyesters and polyamides.
- Polyester-series resins include homopolyesters and copolyesters obtained by, for example, polycondensation of a dicarboxylic acid component and a diol component, and polycondensation of a hydroxycarboxylic acid or a lactone component.
- Preferred polyester-series resins usually include a saturated polyester- series resin, in particular an aromatic saturated polyester-series resin, such as polybutylene terephthalate.
- Poly amide- series resins include polyamides derived from a diamine and a dicarboxylic acid; polyamides obtained from an aminocarboxylic acid, if necessary in combination with a diamine and/or a dicarboxylic acid; and polyamides derived from a lactam, if necessary in combination with a diamine and/or a dicarboxylic acid.
- the polyamide also includes a copolyamide derived from at least two different kinds of polyamide constituent components.
- Suitable polyamide- series resins include aliphatic polyamides (such as nylon 46, nylon 6, nylon 66, nylon 610, nylon 612, nylon 11 and nylon 12), polyamides obtained from an aromatic dicarboxylic acid (e.g., terephthalic acid and/or isophthalic acid) and an aliphatic diamine (e.g., hexamethylenediamine, nonamethylenediamine), and polyamides obtained from both aromatic and aliphatic dicarboxylic acids (e.g., both terephthalic acid and adipic acid) and an aliphatic diamine (e.g., hexamethylenediamine), and others. These polyamides may be used singly or in combination.
- aromatic dicarboxylic acid e.g., terephthalic acid and/or isophthalic acid
- an aliphatic diamine e.g., hexamethylenediamine, nonamethylenediamine
- the base resin may be composited with a filler to modify its properties, such as mechanical strength, rigidity, thermal stability and electrical conductivity.
- the filler may be fibrous or non-fibrous. Suitable fibrous fillers include glass fibers, asbestos fibers, carbon fibers, silica fibers, fibrous wollastonite, silica-alumina fibers, zirconia fibers, potassium titanate fibers, metal fibers, and organic fibers having high melting point (e.g., an aliphatic or aromatic polyamide, an aromatic polyester, a fluorine-containing resin, an acrylic resin such as a poly aery lonitrile).
- Suitable non-fibrous fillers include plate-like (or layered) fillers, such as kaolin, talc, glass flakes, mica, graphite, metal foil, and layered phosphates (e.g., zirconium phosphate, and titanium phosphate).
- plate-like (or layered) fillers such as kaolin, talc, glass flakes, mica, graphite, metal foil, and layered phosphates (e.g., zirconium phosphate, and titanium phosphate).
- particulate or amorphous fillers can be used including carbon black, white carbon, silicon carbide, silica, powdered quartz, glass beads, glass powder, milled fibers (such as milled glass fiber), silicates (e.g., calcium silicate, aluminum silicate, clays, diatomites), metal oxides (e.g., iron oxide, titanium oxide, zinc oxide, and alumina), metal carbonates (e.g., calcium carbonate and magnesium carbonate), metal sulfates (e.g., calcium sulfate and barium sulfate), and metal powders.
- silicates e.g., calcium silicate, aluminum silicate, clays, diatomites
- metal oxides e.g., iron oxide, titanium oxide, zinc oxide, and alumina
- metal carbonates e.g., calcium carbonate and magnesium carbonate
- metal sulfates e.g., calcium sulfate and barium sulfate
- metal powders e.g.
- Preferred fillers include glass fiber and carbon fiber.
- the base resin comprises a glass-filled polyamide containing about 15 and about 40 % glass fiber by weight of the total weight of the polyamide and glass.
- the organophosphorus compound employed in the present flame- retardant resin composition can be represented by at least one of the following formulas (I), (II) and (III):
- R 1 and R 2 are the same or different and each is selected from H, O-alkyl, O-aryl, alkyl, aryl, and OM;
- R 3 is H or alkyl
- M Na, K, Zn, Al, Ca; a is an integer from 0 to 4, provided that a is at least 1 unit for each polymer chain; n is an integer from 1 to 100,000 and m is an integer from 0 to 100,000.
- Representative benzylic-substituted organophosphorus compounds within the above formulas include diphenylphosphine oxide derivatives of diphenyl ether (Compound V below), diphenylphosphine oxide derivatives of diphenoxybenzenes (Compound VI below), diphenylphosphine oxide derivatives of oligomeric aryl ethers (Compound VII below), diphenylphosphine oxide derivative of polyphenylene ethers (Compound VIII below), diphenylphosphine oxide derivatives of polystyrene (Compound IX below), and p- xylylenebis(diphenylphosphine oxide) (Compound X below):
- the organophosphorus compound (B) is present in an amount of about 10% to about 30 % by weight of the flame-retardant resin composition.
- the present resin composition can include at least one flame retardant adjuvant material in addition to the organophosphorus compound described above.
- Suitable flame retardant adjuvant materials comprise melamine salts, inorganic metal compounds, clay compounds, layered double hydroxide materials, polyphenylene ether resins and mixtures thereof.
- Suitable melamine salts include salts of melamine itself as well as salts of melamine derivatives, such as substituted melamines (e.g., an alkylmelamine such as 2-methylmelamine, guanylmelamine), condensation products of melamine (e.g., melam, melem, melon), and copolycondensed resins of melamine (e.g., melamine-formaldehyde resins, phenol-melamine resins, benzoguanamine-melamine resins and aromatic polyamine-melamine resins).
- substituted melamines e.g., an alkylmelamine such as 2-methylmelamine, guanylmelamine
- condensation products of melamine e.g., melam, melem, melon
- copolycondensed resins of melamine e.g., melamine-formaldehyde resins, phenol-melamine resins, benzoguanamine-melamine resins and aromatic
- the salts are produced by reaction of the melamine with an oxygen- containing acid, such as nitric acid, a chloric acid (such as perchloric acid, chloric acid, chlorous acid, hypochlorous acid), a phosphorous acid, a sulfuric acid, a sulfonic acid, a boric acid, a chromic acid, an antimonic acid, a molybdic acid, a tungstic acid, stannic acid, or silicic acid.
- an oxygen- containing acid such as nitric acid, a chloric acid (such as perchloric acid, chloric acid, chlorous acid, hypochlorous acid), a phosphorous acid, a sulfuric acid, a sulfonic acid, a boric acid, a chromic acid, an antimonic acid, a molybdic acid, a tungstic acid, stannic acid, or silicic acid.
- an oxygen- containing acid such as nitric acid, a chloric
- Suitable melamine salts include melamine orthophosphate, melamine phosphate, melamine pyrophosphates (including melamine pyrophosphate and dimelamine pyrophosphate), melamine polyphosphates (including melamine triphosphate and melamine tetraphosphate), melamine sulfates (including melamine sulfate, dimelamine sulfate and guanylmelamine sulfate), melamine pyrosulfates (e.g., melamine pyrosulfate and dimelamine pyrosulfate), melamine sulfonates (e.g., melamine methanesulfonate, melam methanesulfonate, and melem methanesulfonate) and melamine orthoborates (e.g., mono- to trimelamine orthoborates).
- the preferred melamine salts are melamine pyrophosphates
- Suitable inorganic metal compounds for use in the present synergist combination include metal salts of inorganic acids, metal oxides and hydroxides, and metal sulfides.
- suitable inorganic acids include phosphorous acids (such as orthophosphoric acid, metaphosphoric acid, phosphorous acid, hypophosphorous acid, hypophosphoric, pyrophosphoric acid, polyphosphoric acids, anhydrous phosphoric acid and poly metaphosphoric acid), boric acids (such as orthoboric acid, metaboric acid; pyroboric acid, tetraboric acid, pentaboric acid and octaboric acid), a stannic acid (such as stannic acid, metastannic acid, orthostannic acid and hexahydroxostannic acid), a molybdic acid, and a tungstic acid.
- phosphorous acids such as orthophosphoric acid, metaphosphoric acid, phosphorous acid, hypophosphorous acid, hypophosphoric, pyrophosphoric acid, polyphosphoric acids, anhydrous phosphoric acid and poly metaphosphoric acid
- boric acids such as orthoboric acid, metaboric acid; pyroboric acid, tetraboric acid, pentaboric acid
- suitable metal salts include calcium pyrophosphate, calcium polymetaphosphate, alkaline earth metal hydrogenphosphates (such as magnesium hydrogen orthophosphate and calcium hydrogen orthophosphate); transition metal hydrogenphosphate (such as manganese hydrogenphosphate, iron hydrogenphosphate, zinc hydrogenphosphate and cadmium hydrogenphosphate); a hydrogenphosphate of a metal of Group 13 of the Periodic Table of Elements (such as aluminum hydrogenphosphate); a hydrogenphosphate of a metal of Group 14 of the Periodic Table of Elements (such as tin hydrogenphosphate), an alkaline earth metal borate (such as calcium orthoborate, calcium metaborate, calcium pyroborate and trimagnesium tetraborate); a transition metal borate (such as manganese orthoborate, manganese tetraborate, nickel diborate, copper metaborate, zinc metaborate, zinc tetraborate, cadmium metaborate and cadmium tetraborate), an alkali metal stann
- suitable metal oxides and hydroxides include molybdenum oxide, tungstic oxide, titanium oxide, zirconium oxide, tin oxide, copper oxide, zinc oxide, aluminum oxide, nickel oxide, iron oxide, manganese oxide, antimony trioxide, antimony tetraoxide, antimony pentoxide, aluminum hydroxide, magnesium hydroxide, tin hydroxide, and zirconium hydroxide. Mixed oxides such as aluminosilicates, including clays, can also be used.
- suitable metal sulfides include molybdenum sulfide, tungstic sulfide and zinc sulfide.
- the preferred inorganic metal compounds are borates and particularly zinc borates.
- the flame retardant adjuvant is a combination of a melamine salt and an inorganic metal compound in a weight ratio of between about 10: 1 and about 1:1.
- the flame retardant adjuvant material is a char-forming organic compound such as a polyphenylene ether (PPE) type resin.
- PPE polyphenylene ether
- a specific PPE resin example would be PPO 803 from Sabic Innovative Plastics.
- the PPE resin can be used typically at a load level between about 1% and about 25%, more typically between about 5% and about 15%.
- the white powder obtained was slurried in hexanes at room temperature and gave 162 g of material after drying.
- the white powder product (135 g) was washed with acetone and gave, after filtration and drying, 95.0 g of Compound VI as a solid.
- a polyphenylene ether resin (PPO 803 resin from GE Plastics) (45 g), 22.5 g of paraformaldehyde, 367.4 g of 33% HBr in AcOH, and 150 g of methylene bromide were stirred and heated at 60 0 C overnight. After workup the organics were precipitated into acetone. Upon drying, 78.9 g of a white powder was obtained. Analysis: 1 H NMR (CDCl 3 ): ⁇ 6.07 (m), 4.75 (m), 4.2-1.90 (m).
- the various flame retardant compounds described in Examples 1 to 6 were formulated with PA66 resin by mixing the materials either with a twin screw extruder using a PA66 glass concentrate to produce a target 30% glass fiber reinforcement or in a vented Brabender Preparation Center.
- the samples were compounded for four minutes at 265 0 C.
- glass fiber was added over a period of about 15 seconds to produce a target 30% glass fiber reinforcement.
- the compounded materials were ground on a Thomas Wiley mill and then molded by using a small injection molding machine at 265 0 C to form 1/16" thick UL- 94 test bars.
- test bars were subjected to the UL- 94 vertical burn test protocol in which a bar is subjected to two 10 second flame applications.
- the time for the bar to extinguish after each application is noted and reported as Time 1 (Tl) and Time 2 (T2) for the bar.
- the average burn times for 5 test bars were noted for both flame applications (Tl, T2).
- the total burn times were also summed for each of the two flame applications across all five test bars along with the observations of any dripping behavior. The results are shown in Table 1.
- Example 8 Use of Flame Retardant in Glass-Reinforced PA66 with Melamine or PPE Based Adjuvants.
- Formulations were made as described in Example 7 and the molded bars were tested for flammability as shown in Table 2.
- Various melamine based materials were also added to the formulations as FR adjuvant compounds to determine the effect on flammability properties.
- a PPE resin was also tested as an FR adjuvant material in this system.
- the test bars were subjected to the UL-94 vertical burn test protocol and the average burn times for 5 test bars were noted for both flame applications (Tl, T2). The total burn times were also summed for each of the two flame applications across all five test bars along with the observations of any dripping behavior.
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012510893A JP5639156B2 (en) | 2009-05-13 | 2010-05-10 | Phosphorus-containing flame retardant |
CN201080013048.6A CN102369237B (en) | 2009-05-13 | 2010-05-10 | Phosphorus-containing flame retardants |
RU2011150488/05A RU2535687C2 (en) | 2009-05-13 | 2010-05-10 | Phosphorus-containing fire retardants |
EP10719192A EP2430090B1 (en) | 2009-05-13 | 2010-05-10 | Phosphorus-containing flame retardants for glass-filled polyamide resins |
IL216316A IL216316A0 (en) | 2009-05-13 | 2011-11-10 | Phosphorus-containing flame retardants |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US17775009P | 2009-05-13 | 2009-05-13 | |
US61/177,750 | 2009-05-13 |
Publications (1)
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WO2010132332A1 true WO2010132332A1 (en) | 2010-11-18 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/US2010/034187 WO2010132332A1 (en) | 2009-05-13 | 2010-05-10 | Phosphorus-containing flame retardants |
Country Status (8)
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US (2) | US8895648B2 (en) |
EP (1) | EP2430090B1 (en) |
JP (1) | JP5639156B2 (en) |
KR (1) | KR101647532B1 (en) |
CN (1) | CN102369237B (en) |
IL (1) | IL216316A0 (en) |
RU (1) | RU2535687C2 (en) |
WO (1) | WO2010132332A1 (en) |
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WO2013085620A1 (en) | 2011-12-08 | 2013-06-13 | E. I. Du Pont De Nemours And Company | Preparation of (phosphonyl) aromatic diesters and acids |
US8722846B2 (en) | 2011-12-08 | 2014-05-13 | E I Du Pont De Nemours And Company | Preparation of homopolymer and copolymers of (phosphonyl)aromatic diesters and acids |
US9221948B2 (en) | 2009-05-13 | 2015-12-29 | Chemtura Corporation | Phosphorus-containing flame retardants |
KR20170055488A (en) * | 2014-09-15 | 2017-05-19 | 켐트라 코포레이션 | Phosphorus-containing flame retardants |
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US9221948B2 (en) | 2009-05-13 | 2015-12-29 | Chemtura Corporation | Phosphorus-containing flame retardants |
WO2013085620A1 (en) | 2011-12-08 | 2013-06-13 | E. I. Du Pont De Nemours And Company | Preparation of (phosphonyl) aromatic diesters and acids |
US8513454B2 (en) | 2011-12-08 | 2013-08-20 | E I Du Pont De Nemours And Company | Preparation of (phosphonyl) aromatic diesters and acids |
US8722846B2 (en) | 2011-12-08 | 2014-05-13 | E I Du Pont De Nemours And Company | Preparation of homopolymer and copolymers of (phosphonyl)aromatic diesters and acids |
KR20170055488A (en) * | 2014-09-15 | 2017-05-19 | 켐트라 코포레이션 | Phosphorus-containing flame retardants |
KR102578770B1 (en) | 2014-09-15 | 2023-09-15 | 란세스 솔루션즈 유에스 인코퍼레이티드 | Phosphorus-containing flame retardants |
Also Published As
Publication number | Publication date |
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US8420719B2 (en) | 2013-04-16 |
US8895648B2 (en) | 2014-11-25 |
EP2430090B1 (en) | 2013-01-09 |
RU2011150488A (en) | 2013-06-20 |
EP2430090A1 (en) | 2012-03-21 |
KR20120030331A (en) | 2012-03-28 |
US20100292376A1 (en) | 2010-11-18 |
CN102369237B (en) | 2014-04-02 |
CN102369237A (en) | 2012-03-07 |
KR101647532B1 (en) | 2016-08-10 |
JP5639156B2 (en) | 2014-12-10 |
US20120172501A1 (en) | 2012-07-05 |
RU2535687C2 (en) | 2014-12-20 |
IL216316A0 (en) | 2012-01-31 |
JP2012526900A (en) | 2012-11-01 |
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