WO2010130299A3 - Method for producing oxide-based metal-organic framework materials by means of inverse methods - Google Patents

Method for producing oxide-based metal-organic framework materials by means of inverse methods Download PDF

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Publication number
WO2010130299A3
WO2010130299A3 PCT/EP2009/066729 EP2009066729W WO2010130299A3 WO 2010130299 A3 WO2010130299 A3 WO 2010130299A3 EP 2009066729 W EP2009066729 W EP 2009066729W WO 2010130299 A3 WO2010130299 A3 WO 2010130299A3
Authority
WO
WIPO (PCT)
Prior art keywords
compounds
organic framework
based metal
producing oxide
omof
Prior art date
Application number
PCT/EP2009/066729
Other languages
German (de)
French (fr)
Other versions
WO2010130299A2 (en
Inventor
Steffen Hausdorf
Florian Mertens
Felix Baitalow
Jürgen Seidel
Roland Fischer
Original Assignee
Technische Universität Bergakademie Freiberg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Technische Universität Bergakademie Freiberg filed Critical Technische Universität Bergakademie Freiberg
Priority to EP09807537A priority Critical patent/EP2429981A2/en
Publication of WO2010130299A2 publication Critical patent/WO2010130299A2/en
Publication of WO2010130299A3 publication Critical patent/WO2010130299A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00—Compounds of zinc
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
    • C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic System without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area

Abstract

The invention relates to a method for producing oxide-based metal-organic framework compounds, known as OMOF's, of general formula M4OBx (M = bivalent metal, x ≤ 3). OMOF-compounds are built in a uniform grid which has a defined porous size distribution. The high specific pore volume and the thus associated large equivalent surface make said compounds excellent quality materials for, amongst other things, gas accumulators, chemical-technical catalysis or as separation material e.g. in gas or liquid chromatography. The claimed compounds are produced in such a manner that M4OA6 type compounds, wherein M represents a bivalent metal cation and A represents any remaining anion, are reacted, in the presence of a solvent, with exchange compounds from which an anion B having at least 2 functional groups and at least 4 donor atoms, is produced in order to form M4OB x type compounds wherein x ≤ 3.
PCT/EP2009/066729 2009-05-15 2009-12-09 Method for producing oxide-based metal-organic framework materials by means of inverse methods WO2010130299A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP09807537A EP2429981A2 (en) 2009-05-15 2009-12-09 Method for producing oxide-based metal-organic framework materials by means of inverse methods

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009021479A DE102009021479A1 (en) 2008-06-04 2009-05-15 Process for the preparation of oxide-based metal-organic frameworks by inverse synthesis
DE102009021479.8 2009-05-15

Publications (2)

Publication Number Publication Date
WO2010130299A2 WO2010130299A2 (en) 2010-11-18
WO2010130299A3 true WO2010130299A3 (en) 2011-03-31

Family

ID=42735600

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/066729 WO2010130299A2 (en) 2009-05-15 2009-12-09 Method for producing oxide-based metal-organic framework materials by means of inverse methods

Country Status (3)

Country Link
EP (1) EP2429981A2 (en)
DE (1) DE102009021479A1 (en)
WO (1) WO2010130299A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114632496B (en) * 2020-12-15 2023-02-28 中国科学院大连化学物理研究所 Reversible lattice transformation method of zeolite imidazolate framework material
CN115819792B (en) * 2022-12-16 2023-08-18 陕西煤业化工技术研究院有限责任公司 Mixed metal-based tricarboxylic acid coordination polymer, preparation method and adsorption method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004101575A2 (en) * 2003-05-09 2004-11-25 The Regents Of The University Of Michigan Implementation of a strategy for achieving extraordinary levels of surface and porosity in crystals
WO2007090864A1 (en) * 2006-02-10 2007-08-16 Basf Se Process for preparing porous organic framework materials
DE102006048043A1 (en) * 2006-10-11 2008-04-17 Bayer Materialscience Ag Process for the preparation of organometallic framework compounds

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004101575A2 (en) * 2003-05-09 2004-11-25 The Regents Of The University Of Michigan Implementation of a strategy for achieving extraordinary levels of surface and porosity in crystals
WO2007090864A1 (en) * 2006-02-10 2007-08-16 Basf Se Process for preparing porous organic framework materials
DE102006048043A1 (en) * 2006-10-11 2008-04-17 Bayer Materialscience Ag Process for the preparation of organometallic framework compounds

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHRISTIAN SERRE, FRANCK MILLANGE, SUZY SURBLÉ, GÉRARD FÉREY: "A Route to the Synthesis of Trivalent Transition-Metal Porous Carboxylates with Trimeric Secondary Building Units", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 43, no. 46, 7 September 2004 (2004-09-07), pages 6285 - 6289, XP002604647 *
ROWSELL J L C ET AL: "Metal-organic frameworks: a new class of porous materials", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER SCIENCE PUBLISHING, NEW YORK, US LNKD- DOI:10.1016/J.MICROMESO.2004.03.034, vol. 73, no. 1-2, 6 August 2004 (2004-08-06), pages 3 - 14, XP004522126, ISSN: 1387-1811 *
TRANCHEMONTAGNE D J ET AL: "Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0", TETRAHEDRON, ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, NL LNKD- DOI:10.1016/J.TET.2008.06.036, vol. 64, no. 36, 1 September 2008 (2008-09-01), pages 8553 - 8557, XP023315820, ISSN: 0040-4020, [retrieved on 20080614] *

Also Published As

Publication number Publication date
DE102009021479A1 (en) 2010-09-16
WO2010130299A2 (en) 2010-11-18
EP2429981A2 (en) 2012-03-21

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