WO2010128208A3 - Method and apparatus for preparing fuel components from tall oil - Google Patents

Method and apparatus for preparing fuel components from tall oil Download PDF

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Publication number
WO2010128208A3
WO2010128208A3 PCT/FI2010/050362 FI2010050362W WO2010128208A3 WO 2010128208 A3 WO2010128208 A3 WO 2010128208A3 FI 2010050362 W FI2010050362 W FI 2010050362W WO 2010128208 A3 WO2010128208 A3 WO 2010128208A3
Authority
WO
WIPO (PCT)
Prior art keywords
fuel
tall oil
hydrodeoxygenation step
fuel components
fraction
Prior art date
Application number
PCT/FI2010/050362
Other languages
French (fr)
Other versions
WO2010128208A2 (en
Inventor
Pekka Knuuttila
Ulf Hotanen
Original Assignee
Upm-Kymmene Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Upm-Kymmene Corporation filed Critical Upm-Kymmene Corporation
Publication of WO2010128208A2 publication Critical patent/WO2010128208A2/en
Publication of WO2010128208A3 publication Critical patent/WO2010128208A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/22Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • C10G3/44Catalytic treatment characterised by the catalyst used
    • C10G3/45Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1011Biomass
    • C10G2300/1014Biomass of vegetal origin
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04Diesel oil
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Abstract The invention relates to a method for separating components from fuel raw material, where tall oil feedstock is introduced to a continuous process comprising a catalytic hydrodeoxygenation step to convert unsaturated fatty acids to fuel components. A light fraction comprising the unsaturated fatty acids is separated from a heavier fraction of the feedstock, and the light fraction is introduced separately to the hydrodeoxygenation step and taken out as fuel component product stream, and the heavier fraction comprising sterols is left untreated in the hydrodeoxygenation step and is taken out as residual stream. The separation step and the hydrodeoxygenation step take place in the same reactor. The invention also relates to an apparatus for separating components from fuel raw material.
PCT/FI2010/050362 2009-05-04 2010-05-04 Method and apparatus for separating components from fuel raw material WO2010128208A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20095506A FI124194B (en) 2009-05-04 2009-05-04 Method and apparatus for separating components from fuel feedstock
FI20095506 2009-05-04

Publications (2)

Publication Number Publication Date
WO2010128208A2 WO2010128208A2 (en) 2010-11-11
WO2010128208A3 true WO2010128208A3 (en) 2010-12-29

Family

ID=40680691

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI2010/050362 WO2010128208A2 (en) 2009-05-04 2010-05-04 Method and apparatus for separating components from fuel raw material

Country Status (2)

Country Link
FI (1) FI124194B (en)
WO (1) WO2010128208A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI20106252A0 (en) 2010-11-26 2010-11-26 Upm Kymmene Corp Method and system for making fuel components
EP2699652B9 (en) 2011-04-18 2023-10-25 UPM-Kymmene Corporation Catalytic process for producing hydrocarbons from biooils
FI127206B2 (en) 2012-04-18 2021-08-31 Upm Kymmene Corp Process for producing biofuel and biofuel components
SE544325C2 (en) * 2020-07-15 2022-04-05 Sunpine Ab Tall diesel composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996018704A1 (en) * 1994-12-13 1996-06-20 Chemical Research & Licensing Company Process for the removal of mercaptans and hydrogen sulfide from hydrocarbon streams
US5705722A (en) * 1994-06-30 1998-01-06 Natural Resources Canada Conversion of biomass feedstock to diesel fuel additive
WO2009011639A2 (en) * 2007-07-19 2009-01-22 Sunpine Ab Diesel range fuels from carboxylic acids with plant origin
WO2009131510A1 (en) * 2008-04-21 2009-10-29 Sunpine Ab Conversion of crude tall oil to renewable feedstock for diesel range fuel compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5705722A (en) * 1994-06-30 1998-01-06 Natural Resources Canada Conversion of biomass feedstock to diesel fuel additive
WO1996018704A1 (en) * 1994-12-13 1996-06-20 Chemical Research & Licensing Company Process for the removal of mercaptans and hydrogen sulfide from hydrocarbon streams
WO2009011639A2 (en) * 2007-07-19 2009-01-22 Sunpine Ab Diesel range fuels from carboxylic acids with plant origin
WO2009131510A1 (en) * 2008-04-21 2009-10-29 Sunpine Ab Conversion of crude tall oil to renewable feedstock for diesel range fuel compositions

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
LIU, MONNIER,TOURIGNY,KRIZ,HOGAN,WONG: "Production of high quality cetane enhancer from depitched tall oil", PETROLEUM SCIENCE AND TECHNOLOGY, vol. 15, 1998, pages 597 - 609, XP008128406 *

Also Published As

Publication number Publication date
FI20095506A (en) 2010-11-05
FI20095506A0 (en) 2009-05-04
WO2010128208A2 (en) 2010-11-11
FI124194B (en) 2014-04-30

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