WO2010124172A3 - A metal air battery system - Google Patents

A metal air battery system Download PDF

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Publication number
WO2010124172A3
WO2010124172A3 PCT/US2010/032182 US2010032182W WO2010124172A3 WO 2010124172 A3 WO2010124172 A3 WO 2010124172A3 US 2010032182 W US2010032182 W US 2010032182W WO 2010124172 A3 WO2010124172 A3 WO 2010124172A3
Authority
WO
WIPO (PCT)
Prior art keywords
solvent
oxygen
dissolution
metal oxide
electrodes
Prior art date
Application number
PCT/US2010/032182
Other languages
French (fr)
Other versions
WO2010124172A2 (en
Inventor
Rachid Yazami
Original Assignee
California Institute Of Technology
Centre National De La Recherche Scientifique (C.N.R.S.)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/612,409 external-priority patent/US20100141211A1/en
Application filed by California Institute Of Technology, Centre National De La Recherche Scientifique (C.N.R.S.) filed Critical California Institute Of Technology
Publication of WO2010124172A2 publication Critical patent/WO2010124172A2/en
Publication of WO2010124172A3 publication Critical patent/WO2010124172A3/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • H01M4/608—Polymers containing aromatic main chain polymers containing heterocyclic rings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/72—Grids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/80—Porous plates, e.g. sintered carriers
    • H01M4/808—Foamed, spongy materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

Described herein are electrodes comprising a fluorinated or metalloprotein oxygen dissolution enhancer provided in a solvent for enhancing dissolution of oxygen in the solvent. In related embodiments, a metal oxide dissolution enhancer is provided in the solvent for enhancing dissolution of metal oxide formed via reaction of oxygen with metal ions in the solvent. The oxygen and metal oxide dissolution enhancers of electrodes and electrochemical generators described herein enable an increased oxidation and/or reduction rate and enhance the stability and efficiency of the electrochemical generators described herein. Positive electrodes described herein, for example, are highly versatile and compatible with a wide range of solid state and liquid anode and electrolyte systems, including anodes comprising readily available and inexpensive materials such as solvated electron solutions as well as a range of solid state anodes.
PCT/US2010/032182 2009-04-23 2010-04-23 A metal air battery system WO2010124172A2 (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US17211409P 2009-04-23 2009-04-23
US61/172,114 2009-04-23
US24788209P 2009-10-01 2009-10-01
US61/247,882 2009-10-01
US12/612,409 2009-11-04
US12/612,409 US20100141211A1 (en) 2008-11-04 2009-11-04 Hybrid electrochemical generator with a soluble anode
USPCT/US2009/063235 2009-11-04
PCT/US2009/063235 WO2010053962A1 (en) 2008-11-04 2009-11-04 Hybrid electrochemical generator with a soluble anode

Publications (2)

Publication Number Publication Date
WO2010124172A2 WO2010124172A2 (en) 2010-10-28
WO2010124172A3 true WO2010124172A3 (en) 2011-01-20

Family

ID=43011761

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/032182 WO2010124172A2 (en) 2009-04-23 2010-04-23 A metal air battery system

Country Status (1)

Country Link
WO (1) WO2010124172A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9431660B2 (en) 2010-09-23 2016-08-30 Robert Bosch Gmbh Lithium battery with charging redox couple
WO2013077863A1 (en) * 2011-11-22 2013-05-30 Robert Bosch Gmbh Lithium battery with charging redox couple
CN102794200B (en) * 2012-08-31 2014-11-05 华南师范大学 Preparation method of anode catalyst used for microbial fuel cells and application thereof
WO2014133466A1 (en) * 2013-02-28 2014-09-04 Nanyang Technological University Ionic liquid electrolyte and fluorinated carbon electrode
EP3648726A4 (en) 2017-08-29 2021-07-21 Roam Robotics Inc. Semi-supervised intent recognition system and method
CN111755670B (en) * 2019-03-28 2021-11-30 中国科学院物理研究所 Negative electrode material of lithium battery, preparation method and application
IL293829A (en) 2019-12-13 2022-08-01 Roam Robotics Inc Powered device to benefit a wearer during skiing
US11652252B2 (en) 2020-05-06 2023-05-16 Revolution Power Inc. Zinc-air battery systems and methods
CN112382769B (en) * 2020-11-04 2021-10-15 江苏科技大学 High-performance metal-air battery anode catalyst and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6376123B1 (en) * 1994-11-23 2002-04-23 Polyplus Battery Company Rechargeable positive electrodes
US20020155330A1 (en) * 2001-02-20 2002-10-24 Hideaki Tanaka Fuel cell system and hydrogen-generating system therefor
US20070269688A1 (en) * 2004-05-19 2007-11-22 Sri International Liquid anode electrochemical cell
US20080280191A1 (en) * 2007-05-09 2008-11-13 Rachid Yazami Lithium fluoropolymer and fluoro-organic batteries

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6376123B1 (en) * 1994-11-23 2002-04-23 Polyplus Battery Company Rechargeable positive electrodes
US20020155330A1 (en) * 2001-02-20 2002-10-24 Hideaki Tanaka Fuel cell system and hydrogen-generating system therefor
US20070269688A1 (en) * 2004-05-19 2007-11-22 Sri International Liquid anode electrochemical cell
US20080280191A1 (en) * 2007-05-09 2008-11-13 Rachid Yazami Lithium fluoropolymer and fluoro-organic batteries

Also Published As

Publication number Publication date
WO2010124172A2 (en) 2010-10-28

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