WO2010106370A1 - Coated substrate - Google Patents
Coated substrate Download PDFInfo
- Publication number
- WO2010106370A1 WO2010106370A1 PCT/GB2010/050467 GB2010050467W WO2010106370A1 WO 2010106370 A1 WO2010106370 A1 WO 2010106370A1 GB 2010050467 W GB2010050467 W GB 2010050467W WO 2010106370 A1 WO2010106370 A1 WO 2010106370A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- metal oxide
- coating
- nanoparticles
- substrate
- metal
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/006—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels to produce glass through wet route
- C03C1/008—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels to produce glass through wet route for the production of films or coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
- C23C18/1208—Oxides, e.g. ceramics
- C23C18/1216—Metal oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1229—Composition of the substrate
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1258—Spray pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1262—Process of deposition of the inorganic material involving particles, e.g. carbon nanotubes [CNT], flakes
- C23C18/127—Preformed particles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
Definitions
- the present invention relates to methods for coating substrates, and to coated substrates in particular coated transparent substrates such as glass.
- Coloured glass is generally prepared by adding tinting agents, usually metal oxides, to molten glass in closely controlled amounts. Metallic colouring agents have also been used.
- the Roman soda-lime-silica glass Lytheticus Cup is a famous example believed to have been manufactured in the 4 th century AD; analysis has revealed that the cup contains a colloidal alloy of gold and silver (Au-Ag, 40 ppm and 300 ppm respectively). The cup is ruby red in transmitted light and green in reflected light - these colours arise from the small amounts of embedded Au/Ag alloyed nanoparticles.
- the Romans formed these highly coloured objects by adding coins into the glass melt. The coins dissolved in the high temperature of the glass forming process and adventitiously formed alloyed nanoparticles embedded within the bulk glass matrix.
- the brilliant colours of metal nanoparticles are due to the surface plasmon resonance (SPR) absorption governed by the metal nanoparticles' morphology, size, shape and the dielectric constant of the surrounding medium (G Walters and I. P. Parkin J. Mater. Chem. 2009, 19 pp 574-590).
- SPR surface plasmon resonance
- G Walters and I. P. Parkin Appl. Surf. Sci (2009) (doi:10.1016/j:apsusc. 2009.02.039) discuss methods of depositing coatings of nanoparticles in metal oxides using solution precursors of the nanoparticles and oxides.
- the present invention accordingly provides, in a first aspect, a method for coating a substrate, the method comprising, a) providing a substrate b) providing pre-formed nanoparticles of an inorganic material, c) providing at least one precursor of a first metal oxide, and d) depositing a coating on at least one surface of the substrate, by contacting the surface with the precursor of the metal oxide and pre-formed nanoparticles.
- the result is deposition of a coating comprising the metal oxide and the pre-formed nanoparticles.
- the substrate is a transparent or a translucent substrate, most preferably glass or plastics.
- the inorganic material will normally comprise a metal, usually a d-block metal and most preferably either a platinum group metal or a coinage metal.
- Platinum group metals include metals of Group 9 (cobalt, rhodium and iridium) and Group 10 (nickel, palladium and platinum) of the periodic table.
- Coinage metals are those metals of Group 1 1 of the periodic table (copper, silver and gold).
- the metal is selected from gold, silver, copper, nickel, palladium, platinum or an alloy thereof. Suitable alloys include alloys containing gold and silver, gold and copper, silver and copper or gold, silver and/or copper with other alloying metals, preferably d-block metals.
- the nanoparticles are usually contained within an inorganic matrix.
- the inorganic matrix preferably comprises a matrix metal oxide.
- the inorganic matrix containing the nanoparticles may be a separate layer to the first metal oxide layer of the coating; the coating would, therefore, have at least two layers.
- the matrix metal oxide is the first metal oxide. This is advantageous because it provides colour in a single layer of the coating.
- the coating method comprises depositing the coating as pre-formed nanoparticles in a matrix of the first metal oxide.
- the nature of the first metal oxide can significantly modify the colour properties of the nanoparticles by shifting the plasmon resonance of the nanoparticles towards the red end of the visual spectrum as the matrix refractive index is increased.
- modifying the amount and/or nature of the metal oxide (and/or any dopants if present) in the first metal oxide can significantly affect the colour of the coating provided by the nanoparticles.
- the first metal oxide comprises an oxide of cerium, tin, aluminium, titanium, zirconium, zinc, hafnium or silicon.
- the preferred oxide for the first metal oxide is tin oxide.
- Zinc oxide is also advantageous. If zinc oxide is the first metal oxide it is preferred if the precursor is not Zn(acac) 2 .
- the first metal oxide may be doped.
- Preferred dopants include one or more of aluminium, gallium, fluorine, nitrogen, niobium or antimony to form a doped metal oxide. It is preferred if, when the doped metal oxide comprises tin oxide, it is doped with fluorine (providing a fluorine doped tin oxide) antimony and/or niobium. When the doped metal oxide is zinc oxide, it is preferred if the oxide is doped with aluminium or gallium.
- An advantage of this feature is that because the coating comprises both doped metal oxides and nanoparticles of an inorganic material, the interaction of the components is able to beneficially modify both the thermal (e.g. reflectance) properties and colour of the substrate. This is particularly advantageous because tinted glass often has problems when used for thermal control (i.e. to reduce transmission of heat energy either for solar control, for insulation, or both), because the tinted glass absorbs thermal energy, rather than reflecting the energy as in heat reflecting coatings.
- the doped metal oxide is usually an electrically conductive doped metal oxide and is preferably substantially transparent (i.e. allowing light to pass without significant distortion).
- Such doped metal oxides are advantageous because they provide thermal control and, in particular, provide good infra-red reflectivity in the range of approximately 0.8 microns - 3 microns. This, therefore, provides both solar control (by reflecting the heat component of the sun's energy) and also some insulation properties.
- the metal oxide of the inorganic matrix (e.g. if it is not first metal oxide) will usually comprise an oxide of zinc, tin, titanium, silicon, zirconium, hafnium, cerium, indium or aluminium.
- One other possibility for the metal oxide is a solid solution of indium oxide and tin oxide (indium tin oxide e.g. 90% In 2 O 3 , 10% SnO2).
- the nature of the metal oxide depends upon the desired properties provided by the nanoparticles. As discussed above, it is possible to tune the colour provided by the nanoparticles by selecting the dielectric constant, including refractive index, of the inorganic matrix. Selection of the appropriate refractive index (and thickness) of metal oxide can therefore be of significant advantage.
- the size of the nanoparticles also affects the colour and other properties of the nanoparticle component of the coating.
- the nanoparticles will have a particle size of 1 nm to 300 nm, 1 nm - 150 nm, preferably 5 - 100 nm, or more preferably 10 - 80 nm, especially 10 - 60 nm and most preferably 20 - 50 nm.
- the coating will usually have a thickness of 10 - 400 nm, preferably 20 - 300 nm.
- Each layer, in a multi-layer coating will usually have a thickness of between 10 and 150 nm, depending both upon whether the particular layer contains doped metal oxides and/or nanoparticles and also depending upon the refractive index of each of the layers of the coating and their interaction in modifying the transmission and reflection properties of the transparent substrate.
- Suitable techniques for coating include chemical vapour deposition, spray pyrolysis, aerosol spray pyrolysis, and/or flame spraying.
- the method is to be applied to glass on-line (i.e. during the production process for rolled or float glass), it is preferred if the method is on-line spray deposition or chemical vapour deposition, especially atmospheric pressure chemical vapour deposition (APCVD).
- On-line coating may take place in the float bath, lehr or lehr gap depending upon the optimum temperature and atmosphere for coating.
- the temperature of deposition may be chosen from a wide range depending on precursor and coating method.
- the surface of the substrate will be at a temperature in the range 80°C to 750°C, preferably 100°C to 650°C, more preferably 100°C to 600°C, most preferably 100°C to 550°C.
- the coating method comprises depositing the coating as nanoparticles in a matrix of the first metal oxide. This may be achieved by co- depositing the doped metal oxide and nanoparticles at substantially the same time.
- the nanoparticles (in an inorganic matrix, e.g. of a metal oxide) and the doped metal oxide may be deposited sequentially (in any order) in substantially separate layers.
- the present invention provides a substrate having a coating, the coating comprising a first metal oxide and pre-formed nanoparticles of an inorganic material.
- the method and substrate of the two aspects of the invention are advantageous because they allow for substrates having colour in either transmission or reflection or both without the disadvantages of tinting the substrate itself.
- Figure 1 illustrates the variation of plasmon resonance and red shift with increasing matrix refractive index.
- FIG. 2 illustrates configurations, according to the invention, of glass coatings for colouration and thermal control.
- Layer 1 a single nanoparticle in a doped metal oxide matrix
- 2 glass substrate
- 3 nanoparticles in a metal oxide layer with no doping to obtain colouration only
- 4 transparent conducting oxide with no nanoparticle aggregate to obtain thermal control only.
- Figure 3 illustrates measured transmission spectrum of a fluorine doped tin oxide film with embedded gold nanoparticles deposited using the spray coating process according to the invention.
- the colouration is derived from the plasmon absorption in the visible part of the spectrum.
- Figure 4 illustrates spectral normal reflectance R and transmittance T computed from quantitative data of the optical properties of the corresponding film of 2% aluminium doped zinc oxide embedded with 0.5% gold nanoparticles according to the invention.
- Figure 5 illustrates spectral normal reflectance R and transmittance T computed from quantitative data of the optical properties of the corresponding film of fluorine doped tin oxide embedded with 0.5% gold nanoparticles according to the invention.
- Figure 6 illustrates the measured optical properties (transmission, coated and glass side reflection and absorption) of Example 3.
- Figure 7 illustrates the measured optical properties of Example 4.
- Figure 8 illustrates the measured optical properties of Comparative Example 1.
- Figure 9 illustrates the measured optical properties of Example 5.
- Figure 10 illustrates the measured optical properties of Example 6.
- Figure 1 1 illustrates the measured optical properties of Example 7.
- FIG. 12 illustrates the Energy Dispersive Spectrum (EDS) of Example 8.
- FIG. 13 illustrates the EDS of Example 9.
- a precursor solution is spray deposited onto a heated glass substrate to obtain a single layer of tin oxide embedded with gold nanoparticles to achieve a robust and durable film suitable for large area window glass.
- the substrate temperature was held at 330 - 370 degree C.
- the precursor includes aminobenzoate stabilized gold nanoparticles and monobutyltin trichloride in ethanol.
- Figure 3 shows the corresponding transmission spectrum with the plasmon absorption arising from the nanoparticles clearly visible as a dip in the transmission in the visible part of the spectrum, leading to a purple-blue coloured film. Similar results have been demonstrated, for example, with gold/titania composite films producing a controllable and aesthetically pleasing blue tint.
- Example 2 Dual function films for both colour and infra red control using different matrix materials
- Figure 4 shows reflection and transmission for a single spray deposited layer of aluminium doped zinc oxide embedded with gold nanoparticles.
- Figure 5 shows an equivalent layer with gold nanoparticles in a fluorine doped tin oxide layer.
- the solar control performance relates to the extent and position of the plasma edge reflection (i.e. rapid decrease in transmission, increase in reflection). The closer the edge is to the red end of the visible spectrum the better. This is controlled by the impurity doping of the matrix film.
- Example 3 Coatings from Au nanoparticles with Al-liqand (Au-AI2O3)
- Solution 0.1 %w/v Au nanoparticles, stabilised with Al containing aminobenzoate ligand, in ethanol. The solution was sonicated for 1 hour prior to use and the pH adjusted to 1 -2 with HNO 3 .
- Optical analysis indicates the presence of a Surface Plasmon Resonance band at 557nm and this is reflected in the transmitted colour coordinates (see Table 2 and Figure 7). XRD analysis has also confirmed the presence of large amounts of Gold.
- Coatings were deposited from a solution containing monobutyl tin trichloride and trifluoroacetic acid in ethanol (Surchem E1 ). When sprayed this solution gives a fluorine-doped tin oxide coating that is electrically conducting. Preformed gold nanoparticles were added to the solution to give a blue colouration (see Table 3 and Figure 9). An SPR band was observed at 597nm that is consistent with nanoparticle inclusion in the host metal oxide coating.
- Coatings were deposited from a solution containing a mixture of titanium tetra ethoxide and titanium tetra isopropoxide (Surchem SG1 ). When sprayed this gives a titanium dioxide coating. Preformed silver nanoparticles were added to the solution to give a blue colouration (see Table 4).
- Example 7 Coatings using Surchem SG1 (TiO2) solution + Au
- Coatings were deposited from a solution containing a mixture of titanium tetra ethoxide and titanium tetra isopropoxide (Surchem SG1 ). When sprayed this gives a titanium dioxide coating. Preformed gold nanoparticles were added to the solution to give a blue colouration (see Table 5 and Figure
- the deposited coating was approximately 168 nm thick and contained gold (see Figure 12).
- the precursor solution (solution 4) was prepared as 100 cm 3 of solution 2 with 900 cm 3 of 0.4 wt% Au preformed nanoparticle solution.
- Solution 2 was 44.5L of solution 1 and 750 cm 3 0.4 wt% Au solution.
- Solution 1 was 50 kg Surchem E1 solution and 2L 0.4 wt% Au solution.
- Solution 4 was delivered at a flow rate of 0.1 L/Min.
- the coating contains gold as shown in Figure 13.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Metallurgy (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Nanotechnology (AREA)
- Ceramic Engineering (AREA)
- Composite Materials (AREA)
- Surface Treatment Of Glass (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2010224634A AU2010224634A1 (en) | 2009-03-20 | 2010-03-19 | Coated substrate |
CN201080016789XA CN102395536A (en) | 2009-03-20 | 2010-03-19 | Coated substrate |
EP10710417A EP2408722A1 (en) | 2009-03-20 | 2010-03-19 | Coated substrate |
US13/138,690 US20120040175A1 (en) | 2009-03-20 | 2010-03-19 | Coated substrate |
JP2012500320A JP2012520758A (en) | 2009-03-20 | 2010-03-19 | Coated substrate |
BRPI1013163A BRPI1013163A2 (en) | 2009-03-20 | 2010-03-19 | method for coating a substrate, and substrate having a coating |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0904803.4 | 2009-03-20 | ||
GBGB0904803.4A GB0904803D0 (en) | 2009-03-20 | 2009-03-20 | Coated substrate |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010106370A1 true WO2010106370A1 (en) | 2010-09-23 |
Family
ID=40639867
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2010/050467 WO2010106370A1 (en) | 2009-03-20 | 2010-03-19 | Coated substrate |
Country Status (8)
Country | Link |
---|---|
US (1) | US20120040175A1 (en) |
EP (1) | EP2408722A1 (en) |
JP (1) | JP2012520758A (en) |
CN (1) | CN102395536A (en) |
AU (1) | AU2010224634A1 (en) |
BR (1) | BRPI1013163A2 (en) |
GB (1) | GB0904803D0 (en) |
WO (1) | WO2010106370A1 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2438443A1 (en) * | 2012-07-11 | 2014-01-16 | Asociación De Investigación De Las Industrias Cerámicas A.I.C.E. | Procedure for decorating a vitreous surface of a substrate through thermal decomposition of an aerosol (Machine-translation by Google Translate, not legally binding) |
WO2015036426A1 (en) | 2013-09-10 | 2015-03-19 | Saint-Gobain Glass France | Laser process for the implementation of metallic nanoparticles into the surface of large size glass substrates |
WO2015036427A1 (en) | 2013-09-10 | 2015-03-19 | Saint-Gobain Glass France | Laser process for the modification of metallic nanoparticles on large size glass substrates |
DE102017100759A1 (en) | 2017-01-16 | 2018-07-19 | Logis AG | Floor, wall and ceiling paneling |
WO2018197823A1 (en) | 2017-04-28 | 2018-11-01 | Saint-Gobain Coating Solutions | Target for obtaining coloured glazing |
WO2018197821A1 (en) | 2017-04-28 | 2018-11-01 | Saint-Gobain Glass France | Coloured glazing and method for obtaining same |
RU2720846C2 (en) * | 2015-12-09 | 2020-05-13 | Сэн-Гобэн Гласс Франс | Method and apparatus for producing colored glazing |
EP3768280A2 (en) * | 2018-05-08 | 2021-01-27 | Rise Nano Optics Ltd. | Products using gold and silver nanoparticles and ions to absorb visible and uv light |
US11994755B2 (en) | 2021-10-28 | 2024-05-28 | Rise Nano Optics Ltd. | Diffusion of nanoparticles into transparent plastic |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8974896B2 (en) * | 2013-03-08 | 2015-03-10 | Vapor Technologies, Inc. | Coated article with dark color |
US10112209B2 (en) * | 2015-12-11 | 2018-10-30 | VITRO S.A.B. de C.V. | Glass drawdown coating system |
EP3704194A1 (en) | 2017-11-02 | 2020-09-09 | Universiteit Antwerpen | Self-cleaning coating |
CN111139421B (en) * | 2020-01-13 | 2021-10-01 | 中航装甲科技有限公司 | Preparation method of composite coating for light composite armor ceramic |
CN113805254B (en) * | 2021-09-30 | 2022-10-21 | 台州星星光电科技有限公司 | Display screen of electronic product and quantum hidden cover plate for display screen |
CN117987814B (en) * | 2024-04-03 | 2024-06-04 | 陕西神木能源神北航天矿用装备有限公司 | High-strength wear-resistant steel plate for mining new energy automobile and preparation method thereof |
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US5731091A (en) * | 1993-11-10 | 1998-03-24 | Institut Fuer Neue Materialien Gemeinnuetzige Gmbh | Process for producing functional vitreous layers |
US20060091810A1 (en) * | 2002-10-11 | 2006-05-04 | Abraham Balkenende | Light-transmitting substrate provided with a light-absorbing coating |
WO2008060699A2 (en) * | 2006-05-25 | 2008-05-22 | High Performance Coatings Inc | High temperature ceramic coatings incorporating nanoparticles |
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FR2704545B1 (en) * | 1993-04-29 | 1995-06-09 | Saint Gobain Vitrage Int | Glazing provided with a functional conductive and / or low-emissive layer. |
FI121669B (en) * | 2006-04-19 | 2011-02-28 | Beneq Oy | Method and apparatus for coating glass |
-
2009
- 2009-03-20 GB GBGB0904803.4A patent/GB0904803D0/en not_active Ceased
-
2010
- 2010-03-19 EP EP10710417A patent/EP2408722A1/en not_active Withdrawn
- 2010-03-19 BR BRPI1013163A patent/BRPI1013163A2/en not_active Application Discontinuation
- 2010-03-19 CN CN201080016789XA patent/CN102395536A/en active Pending
- 2010-03-19 JP JP2012500320A patent/JP2012520758A/en active Pending
- 2010-03-19 WO PCT/GB2010/050467 patent/WO2010106370A1/en active Application Filing
- 2010-03-19 AU AU2010224634A patent/AU2010224634A1/en not_active Abandoned
- 2010-03-19 US US13/138,690 patent/US20120040175A1/en not_active Abandoned
Patent Citations (3)
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US5731091A (en) * | 1993-11-10 | 1998-03-24 | Institut Fuer Neue Materialien Gemeinnuetzige Gmbh | Process for producing functional vitreous layers |
US20060091810A1 (en) * | 2002-10-11 | 2006-05-04 | Abraham Balkenende | Light-transmitting substrate provided with a light-absorbing coating |
WO2008060699A2 (en) * | 2006-05-25 | 2008-05-22 | High Performance Coatings Inc | High temperature ceramic coatings incorporating nanoparticles |
Non-Patent Citations (5)
Title |
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Also Published As
Publication number | Publication date |
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CN102395536A (en) | 2012-03-28 |
BRPI1013163A2 (en) | 2016-04-05 |
US20120040175A1 (en) | 2012-02-16 |
GB0904803D0 (en) | 2009-05-06 |
JP2012520758A (en) | 2012-09-10 |
EP2408722A1 (en) | 2012-01-25 |
AU2010224634A1 (en) | 2011-10-13 |
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