WO2010098649A1 - Una composición de repelente botánico a base de allium sativum y ácidos húmicos para combatir insectos plaga y procedimiento de obtención y usos - Google Patents
Una composición de repelente botánico a base de allium sativum y ácidos húmicos para combatir insectos plaga y procedimiento de obtención y usos Download PDFInfo
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- WO2010098649A1 WO2010098649A1 PCT/MX2009/000103 MX2009000103W WO2010098649A1 WO 2010098649 A1 WO2010098649 A1 WO 2010098649A1 MX 2009000103 W MX2009000103 W MX 2009000103W WO 2010098649 A1 WO2010098649 A1 WO 2010098649A1
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- Prior art keywords
- garlic
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- humic acids
- garlic extract
- botanical
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- 150000002989 phenols Chemical class 0.000 description 1
- RGCLLPNLLBQHPF-HJWRWDBZSA-N phosphamidon Chemical compound CCN(CC)C(=O)C(\Cl)=C(/C)OP(=O)(OC)OC RGCLLPNLLBQHPF-HJWRWDBZSA-N 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
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- 244000062645 predators Species 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 150000003180 prostaglandins Chemical class 0.000 description 1
- 108060006633 protein kinase Proteins 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
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- 150000003505 terpenes Chemical class 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Definitions
- the present invention relates to a botanical repellent composition based on allium sativum and humic acids to combat pest insects, in which aqueous garlic extract is used as active ingredient, humic acids and water as diluents, obtaining a greater repellent effect.
- plants produce more than 100,000 low molecular weight substances also known as secondary metabolites. These are normally not essential for the basic metabolic process of the plant. Among them are terpenes, lignans, alkaloids, sugars, steroids, fatty acids, etc. Such chemical diversity is a consequence of the evolutionary process that has led to the selection of species with better defenses against microbial attack, or the predation of insects and animals (Dixon, 2001).
- these secondary metabolites play an important role in the defensive mechanism of plants (Jacobson, 1989). Therefore, in recent years, the use of plants as a safer source of pesticides for the environment and human health is being returned (Ottaway, 2001; Mansaray, 2000).
- Pesticides can be classified according to the type of organism against which they are effective: fungicides, herbicides, insecticides, molluscicides, nematicides, rodenticides (Evans, 1991). Undoubtedly natural insecticides from plant extracts they constitute a very interesting alternative of control of insects besides that only very few plants have been evaluated in relation to the natural source that the planet offers, reason why the future perspectives as far as investigation, are even greater.
- Garlic for example, has been used as an insect and animal repellent, and that its antimicrobial properties have been studied extensively, its commercial success, as an agrochemical pesticide, has been very limited due to its relatively low efficacy.
- the U.S. document 6,231,865 describes a synergistic mixture of garlic oil or extract and cotton and cinnamon oil as a natural insecticide for the inhibition of insect growth.
- the garlic extract used is obtained by combining and mixing garlic cloves with water, oil or organic solvents.
- US 6,511,674 describes that one of the reasons why garlic is ineffective is that it has a low amount of garlic in the extracts, it also describes the use of a garlic extract solution, which has a quantifiable concentration greater than 10% by weight of a garlic extract and a second component selected from an agricultural treatment agent for a pesticide, miticide, fungicide, antibiotic, herbicide, defoliant, nutrient, adjuvant and water.
- composition of the present invention only has a concentration greater than 10%, unlike the composition of the present invention has a garlic extract concentration of 87% that makes it highly effective, 13% humic acids plus water, to be introduced into the vascular system of the plant and enhance its 4 mechanisms of action for the fight of plague insects. In addition to not presenting any component of agricultural pesticide treatment agents.
- WO 2007/046680 (MX / a / 2007/015628) describes an insecticidal organic mixture for the control of Aedes aegypti (dengue fly) and other plague insects, the insecticide comprises a extract of kep saporia, whose function is to destroy the Chitin of insects, an extract of crysanthemum cinerariaefolium (pyrethrins), whose function is to penetrate the insect by paralyzing your nervous system, an extract of azadirachtin whose function is their stage changes will interfere, inhibit feeding and repellency, liquid vegetable soap based on quillaja saporia whose function is to destroy the chitin of insects, adhesion and dispersant of the other components and an aqueous extract of garlic (allium spp) whose function is only repellency.
- WO 2007/041886 (MX / a / 2008/004311) describes a fungicidal preparation for the control of pests and fungi in seeds and plants, which is formed from i) a fungicidal composition of a) an allyl sulfide provided (oil of garlic) and b) an alkyl or alkenyl benzene substituted in a ratio 1:19 (eugenol and thymol) and optionally ii) one or more additional constituents, the oils are selected from garlic, clove and thymus oil, in which a) is provided with garlic oil and b) is provided with clove and thymus oil.
- WO 2007/041885 (MX / a / 2008/004312) describes a pesticidal soil preparation especially for nematodes, formed by a mixture of garlic oil and allyl asothiocyanates (AITC) of mustard oil in a 90:10 ratio in a solid form to facilitate its application to the ground.
- AITC allyl asothiocyanates
- WO 2007/144694 (MX / a / 2008/004819) describes a natural pesticide formed from an ingredient active based on a combination of garlic (powder) and mustard oil in an 85:15 ratio to inhibit the growth of bacteria, fungi and eradicate insect pests, a carrier that includes a portion of barcia and a cob ring.
- compositions mentioned in the previous documents are different from the composition of botanical repellent based on Allium sativum and humic acids to combat insect pests, in which aqueous garlic extract is used as an active ingredient as a repellent, humic acids as an agent adjuvant bioprotector for the penetration of garlic extract into the vascular system of the plant, because there is no mention of a composition in which humic acids are used to surprisingly increase the repellent affect in the indicated proportions, so it is considered that they do not affect the novelty, nor the inventive activity of the present invention, because surprisingly a repellent effect is achieved due to its high concentration of garlic extract, which is not achieved with the repellents currently known that use garlic as an active ingredient for this finish.
- the present invention relates to a botanical repellent composition based on allium sativum and humic acids to combat pest insects, in which aqueous garlic extract is used as active ingredient, humic acids and water as diluents that surprisingly have an improved repellent effect. unlike those currently known.
- the garlic extract in the composition makes it highly effective as an insect repellent and humic acids plus water are introduced into the vascular system of the plant and enhance its 4 mechanisms of action for the control of insect pests.
- humic acids function as auxiliary bioprotective agents for the penetration of garlic extract into the vascular system of the plant, which surprisingly enhances its repellent effect.
- composition proposes to provide a botanical insect repellent based on aqueous garlic extract.
- REPELLENT EFFECT by systemic action, garlic extract is absorbed by the plant through the vascular system; thus altering the enzyme system causing changes in perspiration and in the change of intracellular juices such as sap.
- MASK EFFECT By pheromones produced by insects decreasing the mating between them, which means the interruption in the vine cycle and biology.
- ANTIALIMENTARY EFFECT The ingestion or contact with garlic modifies the eating habits of insects, making the crop less palatable and therefore difficult to ingest.
- the present invention relates to a composition of botanical repellent based on garlic extract (allium sativum), humic acids and diluents to combat insect pests, in which humic acids surprisingly improve the repellent effect.
- the botanical insect repellent composition to combat pest insects comprises garlic extract (Allium sativum) from 75% up to 92%, humic acids and diluents from 25% up to 8%.
- the diluent can be selected from water among others.
- the botanical repellent composition to combat pest insects comprises:
- these preferred percentages in the composition are those that guarantee a control of more than 70% for adults, above 60% on nymphs and greater than 60
- % on whitefly eggs (Bemicia tabaci) in pumpkin (Cuc ⁇ rbita pepo).
- the percentages by weight are based on the total weight of the botanical repellent; in which the organic matter is obtained from the extract of Garlic (Allium sativum), in which it is obtained by a method of maceration or precolation with an alcoholic solvent, without damaging its active ingredients.
- Humic acids provide a bioprotective effect that surprisingly contributes to the repellent effect in this composition, increase the permeability of the membranes making the systemic action of garlic extract easier, stimulate biochemical processes in plants, contributing to the rapid change of juices intracellular that subsequently give the effect of repellency when transpired by the plant, increase the absorption of nutrients and stimulate the growth of plants providing greater resistance to plants, in addition to providing the characteristic color of the product and keep it for longer.
- Garlic is an excellent insect and animal repellent, as such its extract is used to block pests of beetles and homoptera.
- the repellent effect is associated with the systemic action of garlic extract, which is incorporated into the vascular system of the cultivated plant by modifying its aroma and, consequently, modifying its natural attack behavior of its specific pests.
- the garlic plant Garlic is a bulb from central and southern Asia from where it spread to the Mediterranean area and from there to the rest of the world. It has small, whitish, six-piece flowers, arranged in umbels.
- the fruit is a capsule that contains black cornered seeds.
- Common garlic is grown from the bulb; of intense and characteristic smell and taste; It is covered by a papery sheath and consists of several separate pieces easy ⁇ calls teeth; It contains a substance called ali ⁇ a, which by action of a ferment contained in them is transformed into allyl disulfide, which has the characteristic smell of garlic; Its reproduction is asexual and sexual.
- Root numerous, simple, fine and tuft-shaped, which reach shallow depth in the ground.
- Bulbs gathered at its base by means of a thin film, forming what is known as the “garlic head.” Each bulb is surrounded by a white robe, sometimes somewhat reddish, membranous, transparent and very thin, similar to They cover the whole bulb.
- Leaf radical, long, alternate, compressed and without apparent nerves.
- Stem peeks through the center of the leaves. It is hollow, very plump and hairless and grows from 40 cm to more than 55, ending with flowers.
- Umbrellas are grouped.
- the biochemical composition of garlic is represented by condensed carbohydrates of the fructose type and glutamyl dipeptides with sulfur radicals. Among the latter, the one formed by glutamic acid and alicysteine sulfoxide is called aluna.
- This compound provides the raw garlic flavor and its antibiotic properties.
- the tooth tissues break down, it is biochemically transformed, by means of the enzyme alliinase, in the process it is broken down into two molecules of pyruvic acid and one of allicin and two of ammonia.
- the resulting products maintain an interesting vermifuge and insecticide action although it loses its antibiotic properties to a large extent.
- Whole bulbs contain large amounts of alpha-glutamyl cysteines.
- garlic also contains: glycosides, lectins, prostaglandins, fructuano, pectin, adenosine, thiamine, riboflavin, pyridoxine, vitamin C, vitamin E, biotin, nicotinic acid, fatty acids, glycolipids, phospholipids, anthocyanins, flavonoids, essential phenols and amino acids.
- glycosides, lectins, prostaglandins, fructuano, pectin, adenosine, thiamine, riboflavin, pyridoxine, vitamin C, vitamin E, biotin, nicotinic acid, fatty acids, glycolipids, phospholipids, anthocyanins, flavonoids, essential phenols and amino acids Several of these substances act synergistically to increase the intrinsic properties of garlic (Amagase, 2001)
- Garlic and its extracts are considered GRAS (Generally Recongnized as Safe), by the Environmental Protection Agency of E. U. A (EPA, 1992).
- GRAS Generally Recongnized as Safe
- the two garlic compounds can be grouped into 2 large groups:
- 2.-Hydrophilic They are found in the aqueous garlic extract, initially they are a mixture of seasoning and allicin, which degrades over time in S-allyl-L-cysteine (SAC), S-allyl-L-mercaptocysteine (SAMC ), saponins and small amounts of lipophilic compounds. It is not cytotoxic, it is repellent to a wide variety of insects and has some cholesterol lowering properties.
- the process of obtaining a fluid garlic extract is carried out by the method of maceration or precolation, which consists in subjecting the garlic bulbs to a cleaning, grinding, mixing and understanding process with a single alcoholic solvent, without damaging the active principles, is performed as follows:
- Garlic extract is added to the repellent by diluting this mixture with water.
- Garlic depends on its maturity (Lancaster, et al., 1984) production and cultivation practices (Mazza, 1998), location in the plant (Freeman, 1975) and processing conditions (Malkeja, 1990).
- Obtaining garlic essences and extracts, dehydration, canning and freezing lead to the formation of products with different physicochemical characteristics and biological properties (eg allicin has a half-life that can range from hours to days depending on the extraction solvent used or of the pH of the medium since at all acidic pH alliinase, enzyme responsible for the formation of allicin is inactivated Storage also seems to influence the increase of sulfur compounds, probably by the gradual formation of S-alk (en) il-L -cysteine sulfoxides from precursors with g-glutamic acid (Freeman, 1976)
- the sulfur compounds of garlic trigger a varied and unique set of chemical reactions, which are what generate many of its metabolic effects.
- thiosulphinates are transformed into other sulfur compounds such as thiosulphinates, cepenes, mono, di, tri and tetrasulfides, thiols, thiophenes and sulfur dioxide.
- natural products from a wide variety of plants act by inhibiting, repelling, deterring or eliminating insects pests of different types (crawlers, flyers, suckers, defollers, etc.) as well as stimulating vital processes of crops to strengthen them and thus protect against attacks from different pests.
- insects pests of different types crawlers, flyers, suckers, defollers, etc.
- a botanical insect repellent composition to combat pest insects comprising garlic extract (Allium sativum) from 75% up to 92%, humic acids and diluents from 25% up to 8% is applied by spraying.
- composition of botanical repellent garlic attacks aphids, whitefly, soldier worm, grasshoppers, weevil, blind hen, cabbage worm, bean beetle, fake apple moth, Potato catarina, red spider and nematodes.
- Water volumes for application area are 25-30 liters and 100 to 200 liters per hectare in the case of land applications.
- the botanical repellent composition can be applied in several ways, it is recommended to start the application of this product at an early hour of the day or in the afternoon during the sunset, since it is not recommended to apply it in times of intense heat and solar radiation, at the time of mixing, it is suggested to use plastic or other non-ionizing containers and that the pH of the water is previously adjusted to 6.0, this product favors the ecological balance of the microenvironment that surrounds the crop and reduces or eliminates physiological stress by phytotoxicity
- the doses should be applied in the volume of water necessary to achieve good coverage, depending on whether it is in-band spray depending on whether it is in-band spray or total spray.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pest Control & Pesticides (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES201090057A ES2360447B1 (es) | 2009-02-24 | 2009-10-05 | Una composición de repelente botánico a base de allium sativum y ácidos húmicos para combatir insectos plaga y procedimiento de obtención y usos. |
US13/055,513 US8883229B2 (en) | 2009-02-24 | 2009-10-05 | Pesticidal compositions and related methods |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2009002081A MX2009002081A (es) | 2009-02-24 | 2009-02-24 | Una composicion de repelente botanico a base de allium sativum y acidos humicos para combatir insectos plaga y procedimiento de obtencion y usos. |
MXMX/A/2009/002081 | 2009-02-24 |
Publications (1)
Publication Number | Publication Date |
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WO2010098649A1 true WO2010098649A1 (es) | 2010-09-02 |
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PCT/MX2009/000103 WO2010098649A1 (es) | 2009-02-24 | 2009-10-05 | Una composición de repelente botánico a base de allium sativum y ácidos húmicos para combatir insectos plaga y procedimiento de obtención y usos |
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US (1) | US8883229B2 (es) |
CO (1) | CO6410260A2 (es) |
EC (1) | ECSP11011179A (es) |
ES (1) | ES2360447B1 (es) |
MX (1) | MX2009002081A (es) |
WO (1) | WO2010098649A1 (es) |
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EP3763200A1 (en) | 2012-01-12 | 2021-01-13 | FBSciences Holdings, Inc. | Modulation of plant biology |
US20210400989A1 (en) * | 2018-09-25 | 2021-12-30 | Beatriz Flores Samaniego | Agricultural pesticide containing allium sativum and heliopsis longipes extracts |
GB2599620B (en) * | 2020-08-04 | 2023-11-22 | Hayne Lane Ltd | Ectoparasiticide veterinary composition |
CN115777730A (zh) * | 2022-12-07 | 2023-03-14 | 御兴堂(北京)生物科技有限责任公司 | 一种防治病虫害的环保型制剂及应用 |
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US6511674B1 (en) * | 1998-06-17 | 2003-01-28 | Anthony Arand | Garlic composition for foliar applications |
US20040063582A1 (en) * | 2002-09-17 | 2004-04-01 | Johnson William S. | Seed treatment and method of treating seed |
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2009
- 2009-02-24 MX MX2009002081A patent/MX2009002081A/es active IP Right Grant
- 2009-10-05 US US13/055,513 patent/US8883229B2/en active Active
- 2009-10-05 WO PCT/MX2009/000103 patent/WO2010098649A1/es active Application Filing
- 2009-10-05 ES ES201090057A patent/ES2360447B1/es active Active
-
2011
- 2011-07-05 EC EC2011011179A patent/ECSP11011179A/es unknown
- 2011-07-08 CO CO11085058A patent/CO6410260A2/es active IP Right Grant
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US20040063582A1 (en) * | 2002-09-17 | 2004-04-01 | Johnson William S. | Seed treatment and method of treating seed |
WO2007144694A2 (en) * | 2005-10-14 | 2007-12-21 | Genaro Casas Jassan | Natural pesticide |
KR100869349B1 (ko) * | 2007-07-10 | 2008-11-19 | 조성동 | 친환경 토양활성제와 그 제조방법 |
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CO6410260A2 (es) | 2012-03-30 |
MX2009002081A (es) | 2009-10-14 |
US8883229B2 (en) | 2014-11-11 |
US20120040032A1 (en) | 2012-02-16 |
ECSP11011179A (es) | 2011-08-31 |
ES2360447A1 (es) | 2011-06-06 |
ES2360447B1 (es) | 2012-02-22 |
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