WO2010095279A1

WO2010095279A1 - Cosmetic which includes alkali reducing mineral ion water, and process for producing the same

Info

Publication number: WO2010095279A1
Application number: PCT/JP2009/056799
Authority: WO
Inventors: 胤昭及川
Original assignee: 株式会社創造的生物工学研究所
Priority date: 2009-02-17
Filing date: 2009-04-01
Publication date: 2010-08-26
Also published as: JPWO2010095279A1; JP2015143235A

Abstract

Disclosed is an eau de toilette including alkali reducing ion water which can release negative hydrogen ions, and a process for producing the same. The process for producing eau de toilette of the present invention includes a step wherein a substance which includes at least one alkali metal, alkaline earth metal, group 13 or group 14 metal is processed from a normal-temperature oxygen-free reduced state, via a high-temperature oxygen-free reduced state, to a normal-temperature oxygen-free reduced state, this treated substance is immersed in water, and the aforementioned water is mixed with eau de toilette. Preferably the process for producing eau de toilette further includes a step wherein a pH regulator is added in order to regulate the pH of the aforementioned treated water. The aforementioned treated substance is alkali reducing ion water which includes negative hydrogen ions.

Description

Cosmetics containing alkali-reduced mineral ion water and method for producing the same

The present invention relates to a cosmetic containing alkali-reducing mineral ion water and a method for producing the same.

In general, the energy necessary for life on earth to sustain life is captured through the respiratory chain. The respiratory chain exists in an embedded state in the inner membrane of an intracellular organ called a mitochondria within the cell. In the respiratory chain, most of the energy generated by the reaction of H ₂ + 1 / 2O ₂ → H ₂ O is stored as a chemical bond energy called a high energy phosphate bond shown by the reaction of ADP + Pi → ATP. Negative hydrogen ions (H ⁻ ) are present in the mitochondrial inner respiratory chain in a form bound to NAF ⁺ of an intermediate electron carrier called NADH. The NADH molecule bonded to the intermediate electron carrier (NAD ⁺ ) is not a hydrogen atom but a hydride ion, that is, a negative hydrogen ion (H ⁻ ).

When active oxygen is generated in the human body, it is pointed out that active oxygen damages cells or oxidizes lipids in the body more than necessary, thereby inhibiting health and promoting aging. Yes. Negative hydrogen ions are very active, and if they can be taken into the body from the outside, the active oxygen generated in the body can be effectively extinguished, thereby maintaining the health of the human body and preventing aging. It becomes possible.

As shown in Patent Document 1, the present inventor has disclosed a method of manufacturing a magnetic ceramic ball having strong reduction characteristics. In this production method, water is added to a material containing 48% zeolite, 33% ceramic clay, 3% coral calcium, and 16% Fe ₂ O ₃ to form clay balls, which are then air-dried for 2 to 3 days. 950 ° C. in a first step, followed by a second step of firing in the atmosphere for 8 hours under the condition of 950 ° C., and in a gas obtained by mixing this oxidized and fired ceramic ball in a ratio of 90:10 nitrogen gas and hydrogen gas. A third step of reducing and firing for 12 hours and a fourth step of irradiating the obtained ceramic ball with a 2T Gaussian magnet five times with a gap of 5 seconds to energize the magnetic force. When a ceramic ball manufactured by this method is put into water, electrolysis occurs in or near the ceramic ball, hydrogen atoms become monomolecular (protiumation), and hydrogen bubbles are generated from the N pole of the ceramic ball. Arise.

If water containing negative hydrogen ions or food that generates negative hydrogen ions can be taken into the body, the active oxygen can be converted into oxygen or good oxygen that is friendly to the human body by electrons generated by the dissociation of the negative hydrogen ions. . Therefore, Patent Document 2 discloses a method for producing eating negative hydrogen ions. According to this, a mixture of coral calcium and wheat flour is formed, oxidized and reduced, and calcium hydride capable of inducing unimolecularization of hydrogen atoms (protiumation) is produced. Tablets or capsules are used to convert water in the cells of the body into negative hydrogen ions (H ⁻ ).

Japanese Patent No. 4218939 JP-A-2005-245265

Although the above Patent Document 2 makes it possible to release negative hydrogen ions into the human body by a substance mainly composed of coral calcium, this production method is limited to coral calcium. Accordingly, if negative hydrogen ions can be generated in still other substances, the use of the negative hydrogen ions can be broadened.

The present invention has been made to solve such problems, and an object thereof is to provide a lotion or soft drink containing alkali-reducing ionic water capable of releasing negative hydrogen ions and a method for producing the same.

As a result of intensive studies, the present inventor has found that negative hydrogen ions can be similarly generated in hydrogen storage metals. For example, in the production of ceramic balls and coral calcium, hydrogen gas H ₂ contained in the furnace atmosphere during the process of returning from the room temperature oxygen-free reduced state to the room temperature oxygen-free reduced state through the high-temperature oxygen-free reduced state is H ₂ ₂ ⇔H ⁺ + H ^- into plasma as, ceramming silicon melt contained in the clay in the material. It is considered that CaCO ₃ contained in the coral calcium powder changes from CaCO ₃ → CaO → CaH ₂ to form calcium hydride (hydrogen storage calcium = a kind of metal hydride). Therefore, other metals contained in coral calcium powder, for example, alkali metals, alkaline earth metals, Group 13 and Group 14 metals shown on the Periodic Table of Elements are also considered to be changed to metal hydrides. . When the metal hydride is immersed in water, it is thought that protiumation occurs on the surface of the metal hydride. FIG. 1 is a schematic view of protiumation of hydrogen, and it is considered that charge conversion occurs in hydrogen atoms such as H ₂ ⇔2H ⁰ , H ⁺ ⇔H ⁰ , H ₂ ⇔2H ⁻ , and H ⁺ ⇔H ⁻ .

In the field of hydrogen engineering, the physicochemical reaction of H ⁻ ⇔H ⁺ ⇔2e ⁻ has been experimentally confirmed. When the ceramic ball disclosed in Patent Document 1 is immersed in water, it can be formed in the ceramic ball. It is certain that hydrogen is protiumized on the surface of the metal hydride. Therefore, on the structure surface of the metal hydride present in the ceramic ball, hydrogenation of protium occurs, H ⁺ ⇔H ⁰ ⇔H ⁻ occurs, and the ceramic ball has polarity, so that hydrogen gas is generated on the polar surface. The generated water that has passed through the ceramic ball contains negative hydrogen ions (H ⁻ ).

However, H ^- is, in the presence of oxygen at room temperature, long-time, whether can exist stably is another problem. FIG. 2 shows changes over time in pH and ORP (oxygen reduction potential) of raw water (Sendai City tap water), and FIG. 3 shows changes in pH and ORP over time when 5 g of ceramic balls are immersed in 200 ml of raw water. It shows a change. 2 and 3, the vertical axis represents pH and ORP (mV), and the horizontal axis represents time (h). As shown in FIG. 2, the pH of the raw water continues to be somewhat higher than 7, and the ORP is almost constant as well. On the other hand, in FIG. 3, when the ceramic ball is immersed in water, the ceramic ball controls the pH of the surrounding water to be slightly less than pH 11, and controls the ORP to −260 mV, thereby maintaining a constant value for a long time. it is obvious. Therefore, at least when the ceramic ball is immersed in water, the surrounding water (conditioning water) changes to a completely different water quality from the raw water (tap water). This shows that there can exist a system in which negative hydrogen ions (H ⁻ ) can exist stably as ordinary ions in alkaline reduced mineral ion water.

FIG. 3A shows changes over time in pH and ORP when hydrogen gas was blown into 200 ml of raw water for 5 minutes, and FIG. 3B shows when hydrogen gas was blown into conditioned water for 5 minutes. When hydrogen gas is blown twice for 5 minutes, FIG. 3D shows changes over time in pH and ORP when hydrogen gas is blown three times for 5 minutes in the conditioned water. As apparent from FIG. 3A, when hydrogen gas is blown into the raw water, the ORP is temporarily lowered in synchronism with it, and then returns to the original ORP. That is, it is understood that the reducing power is not maintained for a long time even when hydrogen gas is blown into the raw water. On the other hand, from FIG. 3B to FIG. 3D, if hydrogen gas is blown into the conditioned water, the ORP decreases in synchronization with it, but the ORP maintains a negative potential thereafter, that is, negative hydrogen ions (H ⁻ ) are ionized. It can be confirmed that it exists stably.

In the alkali-reduced mineral ion water conditioned as described above, protiumated hydrogen is considered to be in a state such as H ⁰ ₂ ⇔H ⁺ + H ⁻ . The H ⁺ and H ⁻ therein can freely become hydrogen molecules H ⁰ ₂ at any time. When air or oxygen gas is blown into such water, a reaction of H ⁰ ₂ ⇔H ⁺ + H ⁻ can be caused, and H ⁰ ₂ , that is, hydrogen gas can be released from a state in which dissolved oxygen is zero. it can. Of course, this time, ORP, it is clear that increases in proportion to the amount of released H ⁰ _2.

FIG. 4A shows changes over time in pH and ORP when oxygen gas (O ₂ ) was blown into conditioned water for 5 minutes, and FIG. 5A shows the amount of dissolved hydrogen when oxygen gas was blown into conditioned water for 5 minutes. FIG. 4B shows changes over time in pH and ORP when oxygen gas (O ₂ ) was blown into raw water (tap water) for 5 minutes, and FIG. 5B shows raw water (tap water). It is a graph which shows the time-dependent change of the amount of dissolved hydrogen when OR gas is blown in for 5 minutes.

As shown in FIG. 4A, when oxygen gas is blown in, the ORP increases somewhat in synchronization with this. Further, as shown in FIG. 5A, the dissolved hydrogen amount is H ⁰ ₂ from scratch can be ascertained experimentally to be released. When oxygen gas is blown into the raw water, as shown in FIG. 4B, the ORP is lowered, the pH is increased somewhat, and hydrogen gas is released as shown in FIG. 5B. These facts indicate that hydrogen gas can be dissolved and stored in the form of ions in conditioned water that can be derived from ceramic balls containing metal hydride.

Figure 6 shows the change over time in the pH and ORP when blown into 60 minutes oxygen gas (O ₂₎ in conditioned water, 7, when blown oxygen gas (O ₂₎ for 60 minutes to condition water It is a graph which shows a time-dependent change of the amount of dissolved hydrogen. As is apparent from FIG. 6, when oxygen gas is blown in, the ORP rises in synchronism with it, but there is no rapid change in pH. On the other hand, FIG. 7 shows that the amount of dissolved hydrogen gradually increases due to the blowing of oxygen gas. These facts indicate that there exists a system in which negative hydrogen ions (H ⁻ ) can be maintained in a stable state for a long time at room temperature and near neutral pH in the presence of oxygen.

FIG. 8 is a graph showing changes in the pH and ORP of conditioned water over time when a pH-adjusted product prepared from milk is added. The result of FIG. 8 shows that the conditioned water can easily adjust the desired pH condition without changing the ORP by dissolving an appropriate amount of the pH adjuster.

The lotion according to the present invention contains alkali-reduced mineral ion water treated with a substance containing a metal hydride. Preferably, the metal hydride is at least one of an alkali metal, an alkaline earth metal, a Group 13 and a Group 14 metal. The alkali-reduced mineral ion water contains negative hydrogen ions. Furthermore, the skin lotion may contain a pH adjuster.

The soft drink according to the present invention contains alkali-reduced mineral ion water treated with a substance containing a metal hydride. The metal hydride is at least one of alkali metal, alkaline earth metal, Group 13 and Group 14, and the alkali-reduced mineral ion water contains negative hydrogen ions.

The method for producing a skin lotion according to the present invention includes a substance containing at least one metal selected from an alkali metal, an alkaline earth metal, a group 13 metal and a group 14 metal from a room temperature oxygen-free reduced state to a high-temperature oxygen-free reduced state. It includes a step of treating in a room temperature oxygen-free reduction state, immersing the treated substance in water, and mixing the water with lotion. The method for producing the skin lotion may further include a step of adding a pH adjuster to adjust the pH of the treated water. Further, the treated substance is alkali reducing ion water containing negative hydrogen ions.

According to the present invention, aging and oxidation of skin cells can be prevented by using a lotion of alkali-reduced mineral ion water for human skin. Furthermore, by taking such a soft drink into the body, it is possible to effectively reduce the active oxygen in the body, prevent the oxidation of lipids in the body, prevent aging, and maintain health.

It is a schematic diagram of the hydrogenation of protium. It is a graph which shows temporal change of pH of raw water (tap water) and oxygen reduction potential (ORP). It is a graph which shows the time-dependent change of pH and redox potential (ORP) of water conditioned with ceramic balls. It is a graph which shows a time-dependent change of pH and ORP when hydrogen gas is blown into 200 ml raw water for 5 minutes. It is a graph which shows a time-dependent change of pH and ORP when hydrogen gas is blown into conditioned water for 5 minutes. It is a graph which shows a time-dependent change of pH and ORP when hydrogen gas 5 minutes is blown twice into conditioned water. It is a graph which shows a time-dependent change of pH and ORP when hydrogen gas is blown 5 times into conditioned water three times. It is a graph which shows a time-dependent change of pH and ORP when oxygen gas is blown into conditioned water for 5 minutes. It is a graph which shows change with time of pH and ORP when oxygen gas is blown into raw water for 5 minutes. It is a graph which shows the time-dependent change of the amount of dissolved hydrogen and ORP when oxygen gas is blown into conditioned water for 5 minutes. It is a graph which shows the time-dependent change of the amount of dissolved hydrogen and ORP when oxygen gas is blown into raw water for 5 minutes. It is a graph which shows a time-dependent change of pH and ORP when oxygen gas is blown into conditioned water for 60 minutes. It is a graph which shows the time-dependent change of the amount of dissolved hydrogen and ORP when oxygen gas is blown into conditioned water for 60 minutes. It is a graph which shows the time-dependent change of pH and ORP of conditioned water when a pH adjuster adjusted from milk is added. It is a figure which shows the manufacturing process of alkali reducible mineral ion water.

Hereinafter, embodiments for carrying out the present invention will be described in detail with reference to the drawings.

The cosmetic product according to the first embodiment of the present invention contains alkali reducing ionic water conditioned by a metal hydride. FIG. 9 is a diagram showing a process for producing alkali-reduced mineral ionic water in the present example. First, a material containing at least one of alkali metals, alkaline earth metals, group 13 and group 14 metals shown on the periodic table of elements is prepared (step S101). ). Next, the substance is placed in a room temperature oxygen-free reduction state (step S102). For example, the substance is placed in a furnace containing hydrogen gas or a mixed gas of hydrogen gas and nitrogen gas. Next, the substance is placed in a high temperature oxygen-free reduction state (step S103). For example, the temperature in the furnace is maintained at 950 ° C. or higher and reduction firing is performed for a certain time. Next, the substance is placed in the room temperature oxygen-free reduction state again (step S104). For example, the temperature in the furnace is set to 25 ° C., and the substance is held at room temperature for a certain time.

By performing the treatment from the room temperature oxygen-free reduction state to the room temperature oxygen-free reduction state, the hydrogen gas H ₂ in the furnace is turned into plasma as H ₂ ⇔H ⁺ + H ⁻ , and the metal hydride That is, a hydrogenated storage metal is produced. When this metal hydride is immersed in water, protiumation occurs on the surface of the metal hydride, and alkali-reducible ionic water containing negative hydrogen ions (H ⁻ ) can be obtained.

The alkali-reducing ionic water thus obtained has a system in which negative hydrogen ions (H ⁻ ) can be maintained in a stable state for a long time at room temperature in the presence of oxygen, as described above. By applying this alkali-reducing ionic water to liquid lotion, it is possible to expect the effect of suppressing oxidation of skin cells and preventing aging. Lotions generally have the effect of moisturizing, conditioning and smoothing the skin and contain various ingredients for that purpose. The skin lotion is configured to contain substances such as water, ethanol, hyaluronic acid, brown algae extract, and citric acid. The alkali-reduced mineral ion water produced | generated by the present Example can be added to a lotion, or the whole lotion water can be substituted with the alkali-reduced mineral ion water of a present Example. However, the configuration of the above-mentioned lotion is an example and may have other configurations.

Furthermore, the lotion according to the present embodiment can contain a pH adjuster. Alkali-reducing ionic water can obtain a desired pH by adding a pH adjusting agent as described above, while maintaining the reducing power of ORP. For example, by adding a pH adjuster, it is possible to obtain a skin lotion that is almost neutral but has reducing power.

Next, a second embodiment of the present invention will be described. In the second embodiment, alkali-reducible mineral ion water is generated using ceramic balls and used for skin lotion. Ceramink balls, for example, are formed by adding water to a material containing silicon, ceramic clay, calcium, and iron oxide as a basic blend, and are fired in the atmosphere at about 950 degrees. The fired ceramic ball is subjected to a treatment in a room temperature oxygen free state through a room temperature oxygen free reduced state through a high temperature oxygen free reduced state. This treatment is performed, for example, by baking at a temperature of about 950 ° C. for a certain time in a hydrogen gas atmosphere and returning to normal temperature.

The ceramic ball thus obtained contains a metal hydride of calcium, and when the ceramic ball is immersed in water, protiumation occurs on the surface of the calcium, and an alkali-reducing ionic water containing negative hydrogen ions (H ⁻ ). Can be obtained. The ceramic balls may include other alkali metals other than calcium, alkaline earth metals, Group 13 and Group 14 metals in various combinations.

Next, a third embodiment of the present invention will be described. In the third example, coral calcium or calcium carbonate, silica, and wheat flour are added to water, kneaded and dried, and the dried molded body is oxidized and fired, and then changed from room temperature oxygen free state to high temperature oxygen free state. Then, room temperature oxygen-free reduction is performed. In this treatment, for example, reduction firing is performed at a temperature of about 650 ° C. for a predetermined time in a nitrogen gas and hydrogen gas reduction furnace, and the temperature is returned to room temperature.

By soaking the coral calcium thus obtained in water, alkali-reduced mineral ion water can be obtained, and by adding or substituting it into the lotion, a skin-friendly lotion can be obtained.

In the above embodiment, the example in which the alkali-reducing mineral ion water is applied to the skin lotion has been shown, but such ion water can also be applied to soft drinks. Since negative hydrogen ions contained in alkali-reduced mineral ion water can maintain a stable state for a long time, when taken into the body as a soft drink, the active oxygen in the body is effectively removed. It can be expected to reduce and prevent cell damage and aging. Furthermore, water soaked with metal hydride has a function as a hydrogen storage body as described above, and has a function of reddening hydrogen gas by blowing oxygen gas or the like, and is used for hydrogen batteries and other applications. You can expect the potential to.

Although the preferred embodiments of the present invention have been described in detail, the present invention is not limited to the specific embodiments, and various modifications and changes can be made within the scope of the gist of the present invention described in the claims. It can be changed.

Claims

A lotion containing alkali-reduced mineral ion water treated with a substance containing a metal hydride.
The lotion according to claim 1, wherein the metal hydride is at least one of an alkali metal, an alkaline earth metal, a Group 13 metal, and a Group 14 metal.
The lotion according to claim 1, wherein the alkali-reduced mineral ion water contains negative hydrogen ions.
The lotion according to any one of claims 1 to 3, wherein the lotion contains a pH adjuster.
A soft drink containing alkali-reduced mineral ion water treated with a substance containing a metal hydride.
The hydride metal is at least one of an alkali metal, an alkaline earth metal, a Group 13 and a Group 14 metal, and the alkali-reduced mineral ion water includes negative hydrogen ions. Drinking water.
A substance containing at least one of an alkali metal, an alkaline earth metal, a group 13 metal and a group 14 metal is treated from a room temperature oxygen free state to a room temperature oxygen free reduced state through a high temperature oxygen free reduced state;
Soaking the treated material in water,
Mixing the water with lotion,
Method for producing lotion.
The method for producing a lotion according to claim 7, further comprising a step of adding a pH adjuster to adjust the pH of the treated water.
The manufacturing method according to claim 7, wherein the treated substance is alkali reducing ion water containing negative hydrogen ions.