WO2010089852A1 - Case for sealed battery, sealed battery and method of manufacturing the sealed battery, vehicle having the battery, and battery-mounted device - Google Patents

Case for sealed battery, sealed battery and method of manufacturing the sealed battery, vehicle having the battery, and battery-mounted device Download PDF

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Publication number
WO2010089852A1
WO2010089852A1 PCT/JP2009/051832 JP2009051832W WO2010089852A1 WO 2010089852 A1 WO2010089852 A1 WO 2010089852A1 JP 2009051832 W JP2009051832 W JP 2009051832W WO 2010089852 A1 WO2010089852 A1 WO 2010089852A1
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WO
WIPO (PCT)
Prior art keywords
case
battery
sealed battery
opening
sealing member
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Application number
PCT/JP2009/051832
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French (fr)
Japanese (ja)
Inventor
鈴木 哲
勝巳 伊藤
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トヨタ自動車株式会社
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Priority to PCT/JP2009/051832 priority Critical patent/WO2010089852A1/en
Publication of WO2010089852A1 publication Critical patent/WO2010089852A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/218Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by the material
    • H01M50/22Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by the material of the casings or racks
    • H01M50/222Inorganic material
    • H01M50/224Metals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/271Lids or covers for the racks or secondary casings
    • H01M50/273Lids or covers for the racks or secondary casings characterised by the material
    • H01M50/276Inorganic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/204Racks, modules or packs for multiple batteries or multiple cells
    • H01M50/207Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
    • H01M50/213Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for cells having curved cross-section, e.g. round or elliptic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present invention relates to a sealed battery case having a case for housing a power generation element and a sealing plate for sealing the power generation element, a sealed battery manufactured using the case, and a method for manufacturing the sealed battery. More specifically, the present invention relates to a sealed battery case, a sealed battery, and a manufacturing method thereof, in which both the case and the sealing plate are made of metal and the inside is sealed by welding them. Furthermore, it extends to vehicles equipped with the battery and battery-equipped devices.
  • a battery in which a power generation element is housed in a metal case.
  • a metal sealing plate is welded to the opening of the case body, which has an opening on one side.
  • the inside is sealed.
  • batteries are used, for example, in vehicles and electrical equipment.
  • a lithium ion secondary battery there is a lithium ion secondary battery in which a sealing plate is put on an opening of a flat rectangular case having an opening on one side. Some of them are manufactured by laser welding around the entire periphery of the sealing plate. In such a case, high welding reliability such as sufficient welding strength and sufficient hermeticity is required for the welded portion.
  • Patent Document 1 discloses a secondary battery in which a satin-like unevenness is formed in advance on a surface portion irradiated with a laser beam. According to the technique of this document, reflection of a laser beam is supposed to be suppressed. Furthermore, it is said that the surface area of the irradiated part is increased. For these reasons, it is said that the efficiency and reliability of welding are improved.
  • Japanese Patent Laid-Open No. 2005-116208 Japanese Patent Laid-Open No. 2005-116208
  • the present invention has been made in order to solve the problems of the conventional techniques described above.
  • the problem is to provide a sealed battery case, sealed battery and manufacturing method thereof, a vehicle equipped with the battery, and a battery-equipped device that suppresses blowholes caused by fume and has high welding reliability. There is to do.
  • the sealed battery case according to the first aspect of the present invention which has been made for the purpose of solving this problem, has a case body having an opening on one side, and a sealing member that closes the opening of the case body.
  • a first facing surface to be welded facing is formed, a second facing surface to be welded facing the first facing surface is formed on the sealing member, and the first facing surface and the second facing surface are formed.
  • a recess that forms a gap communicating with the internal space of the case body between the opposing surfaces when the first opposing surface and the second opposing surface are opposed to each other. At least inside the case body in the thickness direction of the case body From a position corresponding to, those which are formed toward the outside of the case body.
  • the first opposing surface of the case body and the second opposing surface of the sealing member are opposed to each other and welded.
  • a recess is formed between the opposing surfaces. Through this recess, the metal portion melted during welding is communicated with the inside of the case body. Therefore, even if fumes are generated in the molten metal, the fumes can escape into the case body. Thereby, the blowhole resulting from a fume can be suppressed. And the sealing part with high welding reliability is obtained.
  • the outer end of the recess is located within a range that melts during welding. Such a thing can surely escape the fume.
  • the recess is a groove formed discretely with respect to the circumferential direction of the opening of the case body. If it is such, the channel
  • the groove is formed over the entire thickness of the case body. If it is such, the location which melts at the time of welding and the inside of a case main body can be connected reliably.
  • the pitch of the groove portion with respect to the circumferential direction of the opening of the case body is equal to or less than the pitch of the welded portion during welding. If it is such, even when pulsed laser welding is used, the welding location by each pulse can be made to correspond to a groove part, respectively.
  • the depth of the groove is not more than 0.3 times the thickness of the case body. With this size, it is possible to ensure both the welding strength and the communication path.
  • the second aspect of the present invention includes a power generation element, a case main body having an opening on one side, and a sealing member that closes the opening of the case main body.
  • a sealed battery in which the opening of the case body is sealed with a sealing member by welding, and a first facing surface facing the sealing member is formed on the edge of the opening of the case body, A recess that is formed with a second facing surface that faces the first facing surface, and that forms a gap between at least one of the first facing surface and the second facing surface that communicates with the internal space of the case body between the facing surfaces.
  • the contact points of both opposing surfaces are welded from the outside over the entire circumference, and the recess melted during welding from at least the position corresponding to the inner surface of the case body in the thickness direction of the case body. Formed to a position A sealed battery are.
  • a power generation element a case main body having an opening on one surface, and a sealing member that closes the opening of the case main body, the power generation element is accommodated in the case main body, and welding is performed.
  • a method for manufacturing a sealed battery by sealing an opening of a case body with a sealing member, wherein a first opposing surface that is welded facing the sealing member is formed on the edge of the opening as the case body
  • the two facing surfaces are brought into contact with each other by closing with a sealing member, and the contact portion of both facing surfaces is welded from the outside over the entire circumference.
  • the process to prepare may be that the member is manufactured in-house, or may be obtained by subcontracting, or purchased if the corresponding shape exists in the market. You may do it.
  • the present invention extends to vehicles and battery-equipped devices equipped with a sealed battery according to the second aspect of the present invention.
  • the sealed battery case the sealed battery and its manufacturing method, the vehicle equipped with the battery, and the battery-equipped device of the present invention, blowholes due to fume are suppressed and welding reliability is high. ing.
  • the present embodiment is an example in which the present invention is applied to a flat and square lithium ion secondary battery and its battery case.
  • the secondary battery 10 of this embodiment has a battery case 11 and a sealing plate 12 that seals one surface thereof, as shown in FIG.
  • the boundary between the battery case 11 and the sealing plate 12 (shown by a thick black line in the figure) is the welded portion 13.
  • the welded portion 13 is formed over the entire circumference of the sealing plate 12.
  • a positive electrode terminal 14 and a negative electrode terminal 15 which are external electrode terminals are respectively attached to the upper portion of the sealing plate 12 in the figure so as to protrude.
  • the positive terminal 14 and the negative terminal 15 are connected to the respective electrodes of the power generation element 16 housed in the battery case 11.
  • the battery case 11 has a bottomed and flat box shape as shown in FIG.
  • the upper part in the figure is the opening 21. That is, the battery case 11 has a bottom surface 22 and four side surfaces 23. A portion surrounded by the upper end surface 24 of the side surface 23 is the opening 21. A number of grooves 25 in the thickness direction of the side surface 23 are formed on the upper end surface 24 over the entire circumference of the opening 21. The groove 25 extends over the entire thickness of the side surface 23.
  • the battery case 11 and the sealing plate 12 are made of the same metal material.
  • aluminum and iron are suitable.
  • a battery case having a thickness t of about 1 mm is used at least in the vicinity of the upper end surface 24 of the side surface 23.
  • the battery case 11 corresponds to a case body
  • the sealing plate 12 corresponds to a sealing member.
  • the upper end surface 24 of the battery case 11 is the first opposing surface
  • the surface (the lower surface in FIG. 3) on the side facing the upper end surface 24 of the peripheral portion 31 (see FIG. 3 described later) of the sealing plate 12 is the second. Corresponds to the facing surface.
  • the sealing plate 12 is a plate-like member that is placed on the upper end surface 24 of the battery case 11. That is, the peripheral portion of the sealing plate 12 is placed on the upper end surface 24.
  • the opening 21 is covered with the sealing plate 12.
  • a part of the cross section of the sealing plate 12 is shown in FIG. This figure shows the state of the cross section at the location of the groove 25 in the upper end surface 24. At a place other than the groove 25, the upper end surface 24 contacts the sealing plate 12.
  • the sealing plate 12 has a peripheral portion 31 formed with a width s along the outer periphery, and a central portion 32 surrounded by the peripheral portion 31.
  • the peripheral portion 31 is a portion placed on the upper end surface 24 of the battery case 11 as shown in FIG. Further, the central portion 32 has a shape that is slightly lowered to the inside of the battery case 11 than the peripheral portion 31. Therefore, a step is formed between the central portion 32 and the peripheral portion 31. This figure shows a state in which the sealing plate 12 is merely placed on the battery case 11 and is not yet welded.
  • the sealing plate 12 When the sealing plate 12 is placed on the battery case 11, as shown in FIG. 3, the upper end surface 24 of the battery case 11 is entirely covered by the peripheral portion 31 of the sealing plate 12. Further, as shown in this figure, the width s of the peripheral portion 31 is larger than the plate thickness t of the battery case 11. Therefore, in this state, the upper part of the groove 25 is covered. Both end portions of the groove 25 are opened to the outside and inside of the battery case 11, respectively.
  • the depth H of the groove 25 is within a range satisfying the following expression 1 with respect to the plate thickness t. 0.03 ⁇ t ⁇ H ⁇ 0.3 ⁇ t (Formula 1)
  • the secondary battery 10 of the present embodiment is obtained by placing a sealing plate 12 on a battery case 11 and performing laser welding on the joint. As a result, as shown in FIG. 4, a welded portion 13 is formed.
  • the laser beam is irradiated from the left lateral direction in the drawing parallel to the overlapping surface of the battery case 11 and the sealing plate 12. Thereby, the vicinity of the upper end surface 24 of the battery case 11 and the peripheral portion 31 of the sealing plate 12 are partially melted together.
  • a pulse laser such as a YAG laser is used for laser welding. Welding is performed over the entire circumference along the upper end surface 24 of the battery case 11 while slightly shifting so that the irradiation positions of the respective pulses partially overlap each other.
  • the weld 13 formed for each pulse has a substantially hemispherical shape. Therefore, the cross-sectional shape is approximately semicircular as shown in FIG. In this figure, the deepest part of the welded part 13 by each pulse is shown. As shown in this figure, the depth d of the welded portion 13 is smaller than the plate thickness t of the battery case 11 even at the deepest portion. Further, the inner surface of the welded portion 13 faces the groove 25.
  • FIG. 5 shows the AA cross section of FIG.
  • the left end in the figure is the outer surface of the side surface 23 of the battery case 11 and is covered by the welded portion 13 without a gap.
  • the depth of the side surface 23 that is covered by the welded portion 13 without a gap is referred to as a welding depth D.
  • This welding depth D cannot be adjusted strictly. That is, even if laser irradiation conditions such as irradiation intensity are set, the welding depth D is affected to some extent by the state of the joint. In this embodiment, the welding depth D is set so as to be about half of the plate thickness t.
  • the pitch p of the groove 25 is equal to or less than the pitch r of the laser pulse. Therefore, the melted part by each pulse always faces one or more grooves 25.
  • p r. That is, the welded portions 13 by each one-time pulse irradiation are communicated with the inside of the battery case 11 through the corresponding grooves 25.
  • the pitch r of the laser pulses is preferably in the range of (0.2R ⁇ r ⁇ 0.5R) with respect to the bead width R of the laser.
  • the battery case 11 is formed with a plurality of grooves 25.
  • a bottomed box-shaped member may be formed by deep drawing aluminum material, and then a groove 25 may be formed on the upper end surface 24 of each side surface 23 by cutting or the like.
  • external electrode terminals (positive terminal 14 and negative terminal 15) are attached to the sealing plate 12. Then, the positive and negative electrodes of the electrode winding body serving as the power generation element 16 and the external electrode terminal of the sealing plate 12 are connected. Then, the electrode winding body is accommodated in the battery case 11. Then, the sealing plate 12 is placed on the battery case 11 and the joint is laser welded. A pulse laser is irradiated at equal intervals of pitch r, and makes a round around the sealing plate 12. At this time, since the groove 25 is formed in the battery case 11 as described above, the metal portion melted by the laser irradiation is communicated with at least one of the grooves 25.
  • the fumes generated in the molten metal during welding can escape to the inside of the battery case 11 through the groove 25. Accordingly, no gas remains in the welded portion 13 after welding, so there is no blow hole. It should be noted that the entry of fume into the battery has no problem in terms of battery performance. Then, after the welding of the entire circumference is completed, the electrolytic solution is then injected into the battery case 11 using a liquid injection port or the like formed in the sealing plate 12. This completes the secondary battery 10.
  • channel 25 may be sufficient.
  • the rectangular groove 41 having a square cross-sectional shape may be used.
  • a round groove 42 having a semicircular cross section may be used.
  • a triangular groove 43 having a triangular cross section may be used.
  • a trapezoidal groove 44 having a trapezoidal cross section may be used.
  • a plurality of hook-like protrusions 45 formed on the upper end surface 24 can be used. In the case of the hook-shaped protrusion 45, the height corresponding to the groove depth H is the height of the hook-shaped protrusion 45.
  • the groove depth H is set to 0.03, 0.05, 0.10, 0.20, and 0.30 (mm). These satisfy the range of Equation 1 above.
  • the groove depth H is 0.40 and 0.50 (mm). Since this is a battery case with a plate thickness of 1 mm, these comparative examples are out of the range of Equation 1 above.
  • the comparative example 3 uses the conventional battery case which does not provide the groove
  • Each measurement method is as follows.
  • the average number of blowholes was measured by taking a section of the welded portion 13 and counting it visually. That is, the vicinity of the welded portion 13 was hardened with resin, and the sealing plate 12 was polished in a direction to reduce its thickness.
  • the number of blowholes was counted by cutting the welded portion 13 so that the cross section of the welded portion 13 was visible.
  • the welding depth D was also measured.
  • the average pressure strength was measured by making a through hole at a location other than the welded portion 13 in the welded battery case and injecting a liquid into the battery case from the through hole. And the pressure of the liquid when the welding part 13 was destroyed was measured.
  • FIG. 12 shows a BB cross section of FIG. This figure shows a cross-sectional view near the upper end surface 24 of the side surface 23 in a state where it has not been welded yet.
  • the groove 52 opens to the inner surface of the battery case 51 in the side surface 23. There is no opening to the outer surface.
  • the length L from the inner surface of the groove 52 is preferably within the range of the following formula 2 from the plate thickness t of the battery case 11 and the welding depth D.
  • L ⁇ t ⁇ D (Formula 2)
  • this welding depth D is a set value.
  • the set value of the welding depth D is half of the plate thickness t.
  • any shape of the groove may be used.
  • the depth of the groove may be larger than the range of Equation 1.
  • the inventors performed the following experiment 2. That is, the performance of an example of a groove that does not penetrate in the thickness direction as shown in FIG.
  • a groove that does not penetrate in the thickness direction was formed in the upper end surface of the test aluminum battery case.
  • Several types of battery cases with different groove lengths were manufactured, and the sealing plate was welded by laser welding from the outside. The state of the welded part was observed.
  • the groove depth H was 0.05 mm in all cases.
  • the groove length L is 0.70 and 0.50 mm. These satisfy the range of Equation 2 above.
  • the groove lengths L are 0.30, 0.20, and 0.10 (mm), respectively. Since the battery case t has a thickness of 1 mm, these comparative examples are out of the range of Equation 2 above.
  • the comparative example 4 uses the conventional battery case which does not provide the groove
  • Example 2 The result of Experiment 2 is as shown in Table 2.
  • Example 1 welds in good condition were obtained for all the samples.
  • Example 2 although most of the samples were good, there was an example in which blowholes were slightly generated. Therefore, the evaluation was rated as “good”.
  • Comparative Examples 1 to 4 the generation of blow holes could not be suppressed. This is probably because the groove length was too small and the welding depth did not reach the groove. Therefore, it was confirmed that the preferable range of the groove length L is a range satisfying the above-described Expression 2.
  • the groove 25 having a size in a range satisfying the formula 1 or the formula 2 may be formed. If the groove penetrates in the plate thickness direction, the above equation 1 is satisfied, and if the groove does not penetrate, the equation 2 is satisfied. If it is such, it will become possible to communicate with the inside of the battery case 11 for each melting range by each laser pulse during welding.
  • a groove may be formed so as to enable such communication.
  • FIGS. In the example of FIG. 13, vertical grooves 61 in the direction along the side surface of the battery case 11 (up and down direction in the figure) are formed at positions slightly outside the welding depth D. At the same time, one or more lateral grooves 62 that communicate the longitudinal grooves 61 and the inside of the battery case 11 are formed. Further, in the example of FIG. 14, a step is formed slightly outside the welding depth D, and the inner surface side is a recess 63.
  • the groove depth is not necessarily constant. You may make it become deep gradually from the external side of a battery case toward an internal side.
  • a groove having a shape of a part of a cone or a pyramid may be used.
  • the same effect can be obtained by forming a groove on the back surface of the sealing plate instead of forming the groove on the battery case.
  • the groove 64 extends to a position further inside than the thickness t of the side surface 23. Or you may form in the position which does not mutually interfere in both a case and a sealing board.
  • the concave portion may be formed by appropriately roughening the surface instead of the groove at the position where the groove is formed in the above examples. This is also included in the method of forming the recess.
  • the groove 25 is formed in the upper end surface 24 of the battery case 11 before welding. Therefore, when the sealing plate 12 is placed on the upper end surface 24 and laser welding is performed, the molten metal communicates with the inside of the battery case 11 through the groove 25. Therefore, the occurrence of blow holes in the welded portion 13 is prevented. As a result, the generation of blowholes due to fume is suppressed, and a secondary battery with high welding reliability can be obtained.
  • a battery pack 100 using a plurality of secondary batteries 10 is manufactured and used.
  • a plurality of secondary batteries 10 are arranged such that the side surfaces (large area surfaces) of adjacent secondary batteries 10 are in contact with each other so that the external electrode terminals are arranged on the same side.
  • the restraint plates 110 are brought into contact with both sides thereof, and the restraint plates 110 are fastened with the restraint screws 111 and the nuts 112.
  • each secondary battery 10 can be restrained and used at a restraining pressure suitable for use.
  • the positive electrode terminal 14 and the negative electrode terminal 15 of each secondary battery 10 are connected in series in order to form a battery pack 100 that is mounted on various devices.
  • the battery pack 100 can be used by being mounted on a vehicle 200 as shown in FIG. 17, for example.
  • the vehicle 200 is a hybrid vehicle that is driven by using an engine 240, a front motor 220, and a rear motor 230 in combination.
  • This vehicle 200 includes a vehicle body 290, an engine 240, a front motor 220, a rear motor 230 attached thereto, a cable 250, an inverter 260, and a battery pack 100 having a plurality of secondary batteries 10 therein.
  • the vehicle may be a vehicle that uses battery-generated electric energy for all or a part of its power source.
  • an electric vehicle, a hybrid vehicle, a plug-in hybrid vehicle, a hybrid railway vehicle, a forklift, an electric vehicle Wheelchairs, electric assist bicycles, electric scooters, etc. are listed.
  • the battery pack 100 can be used for a battery-equipped device as shown in FIG. Shown in this figure is a hammer drill 300 on which a battery pack 100 including the secondary battery 10 of this embodiment is mounted.
  • the hammer drill 300 is a battery-equipped device having a battery pack 100 and a main body 320.
  • the battery pack 100 is detachably accommodated in the bottom 321 of the main body 320 of the hammer drill 300.
  • the battery-equipped device may be any device equipped with a battery and using it as at least one energy source.
  • a personal computer a mobile phone, a battery-powered electric tool, an uninterruptible power supply, etc.
  • Various types of home appliances, office equipment, and industrial equipment driven by In addition to the battery pack 100, devices that can be used with a single battery that is not in an assembled battery state are also included.
  • this form is only a mere illustration and does not limit this invention at all. Therefore, the present invention can naturally be improved and modified in various ways without departing from the gist thereof.
  • lithium ion secondary batteries but also sealed batteries can be widely applied.
  • the outer shape of the battery is not limited to a flat box shape, and can be applied to a cylindrical battery.

Abstract

A case for a sealed battery comprises a battery case (11) having an opening part (21) on one side and a sealing plate (12) for closing the opening part (21) of the battery case (11). A power generating element (16) is contained in the battery case (11), and the battery case (11) is welded to the sealing plate (12) to seal the opening part (21) for forming a battery. An upper end surface (24) so welded to the sealing plate (12) as to be opposed to the sealing plate is formed at the edge side of the opening part (21) of the battery case (11). A peripheral part (31) so welded to the battery case as to be opposed to the upper end surface (24) is formed on the sealing plate (12). A groove (25) which forms the gap communicating with the inner space of the battery case (11) between the opposed surfaces of the upper end surface (24) and the peripheral part (31) when the upper end surface and the peripheral part are opposed to each other is formed in at least one of the upper end surface (24) and the peripheral part (31). The groove (25) is formed in the battery case (11) starting at the position of the inner surface of the battery case (11) to the position thereof fused during the welding in the plate thickness direction of the battery case (11).

Description

密閉型電池用ケース,密閉型電池とその製造方法,及びその電池を搭載した車両,電池搭載機器Sealed battery case, sealed battery and method for manufacturing the same, vehicle equipped with the battery, battery-equipped device
 本発明は,発電要素を収容するケースとそれを封口する封口板とを有する密閉型電池用ケースおよびそのケースを用いて製造された密閉型電池とその製造方法に関する。さらに詳細には,ケースと封口板とがともに金属製であり,それらが溶接されることによって内部が封止される密閉型電池用ケース,密閉型電池とその製造方法に関するものである。さらには,その電池を搭載した車両や電池搭載機器にも及ぶ。 The present invention relates to a sealed battery case having a case for housing a power generation element and a sealing plate for sealing the power generation element, a sealed battery manufactured using the case, and a method for manufacturing the sealed battery. More specifically, the present invention relates to a sealed battery case, a sealed battery, and a manufacturing method thereof, in which both the case and the sealing plate are made of metal and the inside is sealed by welding them. Furthermore, it extends to vehicles equipped with the battery and battery-equipped devices.
 従来より,発電要素が金属製のケース内に収容されている電池がある。通常,一面が開口部となっているケース本体の開口部に,金属製の封口板が溶接されている。これにより,その内部を密閉しているのである。このような電池は,例えば,車両や電気機器等に使用されている。例えば,リチウムイオン二次電池として,一面が開口した扁平な角形のケースの開口部に封口板を被せたものがある。そして,その封口板の周囲に全周にわたってレーザ溶接を行うことによって製造されるものがある。このようなものでは,十分な溶接強度や十分な密閉性等,その溶接箇所についての高い溶接信頼性が求められる。 Conventionally, there is a battery in which a power generation element is housed in a metal case. Usually, a metal sealing plate is welded to the opening of the case body, which has an opening on one side. As a result, the inside is sealed. Such batteries are used, for example, in vehicles and electrical equipment. For example, as a lithium ion secondary battery, there is a lithium ion secondary battery in which a sealing plate is put on an opening of a flat rectangular case having an opening on one side. Some of them are manufactured by laser welding around the entire periphery of the sealing plate. In such a case, high welding reliability such as sufficient welding strength and sufficient hermeticity is required for the welded portion.
 そのために,例えば特許文献1には,レーザビームを照射する表面部分に予め梨地状の凹凸を形成した二次電池が開示されている。本文献の技術によれば,レーザビームの反射が抑制されるとされている。さらには,照射箇所の表面積が増加されるとされている。これらのことから,溶接の効率や信頼性が向上するとされている。
特開2005-116208号公報
For this purpose, for example, Patent Document 1 discloses a secondary battery in which a satin-like unevenness is formed in advance on a surface portion irradiated with a laser beam. According to the technique of this document, reflection of a laser beam is supposed to be suppressed. Furthermore, it is said that the surface area of the irradiated part is increased. For these reasons, it is said that the efficiency and reliability of welding are improved.
Japanese Patent Laid-Open No. 2005-116208
 しかしながら,前記した従来の技術には,以下の問題点があった。溶接時には,溶接箇所から高温のガス(ヒューム)が発生することがある。さらに,発生したヒュームが溶接部の内部に滞留する場合がある。そうすると,気泡状のブローホールとなって残るおそれがある。ブローホールが多く発生すると,溶接部の強度の低下や内部で発生するガスの漏れ等の発生の原因となるおそれがある。このような箇所がある電池は,車両や電気機器等への搭載には適さない。上記の技術によっても,これらの課題は依然として残されたままである。 However, the conventional techniques described above have the following problems. During welding, high-temperature gas (fumes) may be generated from the weld location. In addition, the generated fumes may stay inside the weld. If it does so, it may remain as a bubble-like blowhole. If many blow holes are generated, there is a risk that the strength of the welded portion will be reduced and the gas leaks generated inside. Batteries with such locations are not suitable for mounting on vehicles or electrical equipment. Even with the above technology, these challenges still remain.
 本発明は,前記した従来の技術が有する問題点を解決するためになされたものである。すなわちその課題とするところは,ヒュームに起因するブローホールを抑制し,溶接信頼性の高い密閉型電池用ケース,密閉型電池とその製造方法,及びその電池を搭載した車両,電池搭載機器を提供することにある。 The present invention has been made in order to solve the problems of the conventional techniques described above. In other words, the problem is to provide a sealed battery case, sealed battery and manufacturing method thereof, a vehicle equipped with the battery, and a battery-equipped device that suppresses blowholes caused by fume and has high welding reliability. There is to do.
 この課題の解決を目的としてなされた本発明の第1の態様における密閉型電池用ケースは,一面が開口部となっているケース本体と,ケース本体の開口部を塞ぐ封口部材とを有し,ケース本体に発電要素を収納して,溶接により封口部材でケース本体の開口部が封口されることで電池となる密閉型電池用ケースであって,ケース本体の開口部の縁辺に,封口部材と対面して溶接される第1対向面が形成されており,封口部材に,第1対向面と対面して溶接される第2対向面が形成されており,第1対向面と第2対向面との少なくとも一方に,第1対向面と第2対向面とを対面させたときに,ケース本体の内部空間に連通する隙間を両対向面間に形成する凹部が形成されており,凹部は,ケース本体の板厚方向に少なくとも,ケース本体の内面に相当する位置から,ケース本体の外側に向かって形成されているものである。 The sealed battery case according to the first aspect of the present invention, which has been made for the purpose of solving this problem, has a case body having an opening on one side, and a sealing member that closes the opening of the case body. A case for a sealed battery in which a power generation element is housed in a case body and the opening of the case body is sealed with a sealing member by welding to form a battery, and a sealing member and an edge of the opening of the case body A first facing surface to be welded facing is formed, a second facing surface to be welded facing the first facing surface is formed on the sealing member, and the first facing surface and the second facing surface are formed. And a recess that forms a gap communicating with the internal space of the case body between the opposing surfaces when the first opposing surface and the second opposing surface are opposed to each other. At least inside the case body in the thickness direction of the case body From a position corresponding to, those which are formed toward the outside of the case body.
 上記構成の密閉型電池用ケースによれば,ケース本体の第1対向面と封口部材の第2対向面とが対向されて,溶接される。この両対向面間に凹部が形成されている。この凹部を介して,溶接時に溶融した金属部分はケース本体の内部に連通される。従って,溶融金属中にヒュームが発生しても,ヒュームはケース本体の内部に逃げることができる。これにより,ヒュームに起因するブローホールを抑制できる。そして,溶接信頼性の高い封口部分が得られる。 According to the sealed battery case having the above configuration, the first opposing surface of the case body and the second opposing surface of the sealing member are opposed to each other and welded. A recess is formed between the opposing surfaces. Through this recess, the metal portion melted during welding is communicated with the inside of the case body. Therefore, even if fumes are generated in the molten metal, the fumes can escape into the case body. Thereby, the blowhole resulting from a fume can be suppressed. And the sealing part with high welding reliability is obtained.
 さらに上記構成では,凹部の外側端部が,溶接時に溶融する範囲内に位置することが望ましい。このようなものであれば,確実にヒュームを逃がすことができる。 Furthermore, in the above configuration, it is desirable that the outer end of the recess is located within a range that melts during welding. Such a thing can surely escape the fume.
 さらに上記構成では,凹部が,ケース本体の開口部の周方向に対して離散的に形成された溝部であることが望ましい。このようなものであれば,接合強度を確保しつつ,ヒュームを逃がす通路を形成することができる。 Furthermore, in the above configuration, it is desirable that the recess is a groove formed discretely with respect to the circumferential direction of the opening of the case body. If it is such, the channel | path which escapes a fume can be formed, ensuring joining strength.
 さらに上記構成では,溝部が,ケース本体の板厚全体にわたって形成されていることが望ましい。このようなものであれば,溶接時に溶融する箇所とケース本体の内部とを,確実に連通させることができる。 Furthermore, in the above configuration, it is desirable that the groove is formed over the entire thickness of the case body. If it is such, the location which melts at the time of welding and the inside of a case main body can be connected reliably.
 さらに上記構成では,ケース本体の開口部の周方向に対する溝部の配置のピッチが,溶接時の溶接箇所のピッチ以下であることが望ましい。このようなものであれば,パルス状のレーザ溶接を用いた場合でも,各パルスによる溶接箇所をそれぞれ溝部に対応させることができる。 Furthermore, in the above configuration, it is desirable that the pitch of the groove portion with respect to the circumferential direction of the opening of the case body is equal to or less than the pitch of the welded portion during welding. If it is such, even when pulsed laser welding is used, the welding location by each pulse can be made to correspond to a groove part, respectively.
 さらに上記構成では,溝部の深さは,ケース本体の板厚の0.3倍以下であることが望ましい。この程度の大きさであれば,溶接強度の確保と連通路の確保とをともに確実なものとすることができる。 Furthermore, in the above configuration, it is desirable that the depth of the groove is not more than 0.3 times the thickness of the case body. With this size, it is possible to ensure both the welding strength and the communication path.
 また本発明における第2の態様は,発電要素と,一面が開口部となっているケース本体と,ケース本体の開口部を塞ぐ封口部材とを有し,ケース本体に発電要素を収納して,溶接により封口部材でケース本体の開口部が封口されている密閉型電池であって,ケース本体の開口部の縁辺に,封口部材と対面する第1対向面が形成されており,封口部材に,第1対向面と対面する第2対向面が形成されており,第1対向面と第2対向面との少なくとも一方に,ケース本体の内部空間に連通する隙間を両対向面間に形成する凹部が形成されており,両対向面の接触箇所が,全周にわたり外側から溶接されており,凹部は,ケース本体の板厚方向に少なくとも,ケース本体の内面に相当する位置から,溶接時に溶融した位置までにわたって形成されている密閉型電池である。 The second aspect of the present invention includes a power generation element, a case main body having an opening on one side, and a sealing member that closes the opening of the case main body. A sealed battery in which the opening of the case body is sealed with a sealing member by welding, and a first facing surface facing the sealing member is formed on the edge of the opening of the case body, A recess that is formed with a second facing surface that faces the first facing surface, and that forms a gap between at least one of the first facing surface and the second facing surface that communicates with the internal space of the case body between the facing surfaces. The contact points of both opposing surfaces are welded from the outside over the entire circumference, and the recess melted during welding from at least the position corresponding to the inner surface of the case body in the thickness direction of the case body. Formed to a position A sealed battery are.
 また本発明における第3の態様は,発電要素と,一面が開口部となっているケース本体と,ケース本体の開口部を塞ぐ封口部材とを用い,ケース本体に発電要素を収納して,溶接により封口部材でケース本体の開口部を封口することによる密閉型電池の製造方法であって,ケース本体として,その開口部の縁辺に,封口部材と対面して溶接される第1対向面が形成されているものを準備し,封口部材として,第1対向面と対面して溶接される第2対向面が形成されているものを準備する工程と,発電要素を収納したケース本体の開口部を封口部材で塞ぐことにより両対向面が接触する状態とし,両対向面の接触箇所を,全周にわたり外側から溶接する工程とを有し,準備する工程では,ケース本体および封口部材の組合せとして,第1対向面と第2対向面との少なくとも一方に,第1対向面と第2対向面とを対面させたときに,ケース本体の内部空間に連通する隙間を両対向面間に形成する凹部を,ケース本体の板厚方向に少なくとも,ケース本体の内面に相当する位置から,ケース本体の外側に向かって形成したものを準備する密閉型電池の製造方法である。 According to a third aspect of the present invention, a power generation element, a case main body having an opening on one surface, and a sealing member that closes the opening of the case main body, the power generation element is accommodated in the case main body, and welding is performed. A method for manufacturing a sealed battery by sealing an opening of a case body with a sealing member, wherein a first opposing surface that is welded facing the sealing member is formed on the edge of the opening as the case body A step of preparing a second facing surface to be welded facing the first facing surface as a sealing member, and an opening of the case body housing the power generation element The two facing surfaces are brought into contact with each other by closing with a sealing member, and the contact portion of both facing surfaces is welded from the outside over the entire circumference. In the preparation step, as a combination of the case body and the sealing member, 1st facing A recess that forms a gap communicating with the internal space of the case body between the opposing surfaces when the first opposing surface and the second opposing surface face each other at least one of the second opposing surface and the second opposing surface. This is a method for manufacturing a sealed battery in which a battery formed in the thickness direction of the battery from at least a position corresponding to the inner surface of the case body toward the outside of the case body is prepared.
 なお,準備する工程とは,その部材を社内で製造することによってもよいし,外注により製造させて入手してもよいし,該当する形状のものが仮に市場に存在した場合にはそれを購入することによってもよい。 In addition, the process to prepare may be that the member is manufactured in-house, or may be obtained by subcontracting, or purchased if the corresponding shape exists in the market. You may do it.
 さらに上記構成では,準備する工程では,ケース本体および封口部材の組合せとして,凹部の外側端部を,溶接時に溶融する範囲内に位置するように形成したものを準備することが望ましい。 Further, in the above-described configuration, it is desirable to prepare a combination of the case main body and the sealing member in which the outer end portion of the recess is formed so as to be located within a range that melts during welding.
 さらに本発明の第2の態様における密閉型電池を搭載する車両,電池搭載機器にも及ぶ。 Further, the present invention extends to vehicles and battery-equipped devices equipped with a sealed battery according to the second aspect of the present invention.
 本発明の密閉型電池用ケース,密閉型電池とその製造方法,及びその電池を搭載した車両,電池搭載機器によれば,ヒュームに起因するブローホールを抑制し,溶接信頼性の高いものとなっている。 According to the sealed battery case, the sealed battery and its manufacturing method, the vehicle equipped with the battery, and the battery-equipped device of the present invention, blowholes due to fume are suppressed and welding reliability is high. ing.
本形態の二次電池を示す斜視図である。It is a perspective view which shows the secondary battery of this form. 本形態の電池ケースを示す上面図である。It is a top view which shows the battery case of this form. 溶接前の電池ケースと封口板との合わせ目を示す断面図である。It is sectional drawing which shows the seam of the battery case and sealing plate before welding. 溶接後の電池ケースと封口板との合わせ目を示す断面図である。It is sectional drawing which shows the joint line of the battery case and sealing plate after welding. 溶接後の電池ケースと封口板との合わせ目を示す断面図である。It is sectional drawing which shows the joint line of the battery case and sealing plate after welding. 角溝の形状の例を示す説明図である。It is explanatory drawing which shows the example of the shape of a square groove. 丸溝の形状の例を示す説明図である。It is explanatory drawing which shows the example of the shape of a round groove. 三角溝の形状の例を示す説明図である。It is explanatory drawing which shows the example of the shape of a triangular groove. 台形溝の形状の例を示す説明図である。It is explanatory drawing which shows the example of the shape of a trapezoid groove. シボの形状の例を示す説明図である。It is explanatory drawing which shows the example of the shape of a wrinkle. 溶接前の電池ケースと封口板との合わせ目の別の例を示す断面図である。It is sectional drawing which shows another example of the joint of the battery case before welding, and a sealing board. 溶接前の電池ケースと封口板との合わせ目の別の例を示す断面図である。It is sectional drawing which shows another example of the joint of the battery case before welding, and a sealing board. 溶接前の電池ケースと封口板との合わせ目の別の例を示す断面図である。It is sectional drawing which shows another example of the joint of the battery case before welding, and a sealing board. 溶接前の電池ケースと封口板との合わせ目の別の例を示す断面図である。It is sectional drawing which shows another example of the joint of the battery case before welding, and a sealing board. 溶接前の電池ケースと封口板との合わせ目の別の例を示す断面図である。It is sectional drawing which shows another example of the joint of the battery case before welding, and a sealing board. 本形態の2次電池を使用した電池パックを示す側面図である。It is a side view which shows the battery pack which uses the secondary battery of this form. 本形態の2次電池を使用した車両を示す説明図である。It is explanatory drawing which shows the vehicle using the secondary battery of this form. 本形態の2次電池を使用したハンマードリルを示す説明図である。It is explanatory drawing which shows the hammer drill using the secondary battery of this form.
符号の説明Explanation of symbols
 10 二次電池
 11 電池ケース
 12 封口板
 21 開口部
 24 上端面
 25 溝
 100 電池パック
 200 車両
 300 ハンマードリル
DESCRIPTION OF SYMBOLS 10 Secondary battery 11 Battery case 12 Sealing plate 21 Opening part 24 Upper end surface 25 Groove 100 Battery pack 200 Vehicle 300 Hammer drill
 以下,本発明を具体化した最良の形態について,添付図面を参照しつつ詳細に説明する。本形態は,扁平で角形のリチウムイオン二次電池およびその電池ケースに本発明を適用した例である。 Hereinafter, the best mode for embodying the present invention will be described in detail with reference to the accompanying drawings. The present embodiment is an example in which the present invention is applied to a flat and square lithium ion secondary battery and its battery case.
 本形態の二次電池10は,図1に示すように,電池ケース11とその一面を封口する封口板12とを有している。そして,電池ケース11と封口板12との境界(図中に黒い太線で示している)が,溶接部13である。溶接部13は,封口板12の全周にわたって形成されている。これにより電池ケース11と封口板12とが接合されている。また,封口板12の図中上部には,それぞれ外部電極端子である正極端子14と負極端子15とが突出して取り付けられている。これらの正極端子14と負極端子15とは,電池ケース11の内部に収納されている発電要素16の各電極に,それぞれ接続されている。 The secondary battery 10 of this embodiment has a battery case 11 and a sealing plate 12 that seals one surface thereof, as shown in FIG. The boundary between the battery case 11 and the sealing plate 12 (shown by a thick black line in the figure) is the welded portion 13. The welded portion 13 is formed over the entire circumference of the sealing plate 12. Thereby, the battery case 11 and the sealing plate 12 are joined. Further, a positive electrode terminal 14 and a negative electrode terminal 15 which are external electrode terminals are respectively attached to the upper portion of the sealing plate 12 in the figure so as to protrude. The positive terminal 14 and the negative terminal 15 are connected to the respective electrodes of the power generation element 16 housed in the battery case 11.
 電池ケース11は,単体での状態を図2に示すように,有底で扁平な箱形のものである。その図中上方が開口部21となっている。すなわち,電池ケース11は,底面22と4つの側面23を有しているものである。そして,側面23の上端面24で囲まれた箇所が,開口部21である。この上端面24には,側面23の板厚方向の溝25が,開口部21の全周にわたって多数個形成されている。この溝25は,側面23の板厚全体にわたっている。 The battery case 11 has a bottomed and flat box shape as shown in FIG. The upper part in the figure is the opening 21. That is, the battery case 11 has a bottom surface 22 and four side surfaces 23. A portion surrounded by the upper end surface 24 of the side surface 23 is the opening 21. A number of grooves 25 in the thickness direction of the side surface 23 are formed on the upper end surface 24 over the entire circumference of the opening 21. The groove 25 extends over the entire thickness of the side surface 23.
 なお,本形態では,この電池ケース11及び封口板12は,同一の金属材料で形成されている。例えば,アルミ,鉄等が適している。本形態の電池ケース11としては,側面23のうち少なくとも上端面24の近傍においては,その板厚tが1mm程度のものを使用している。この電池ケース11がケース本体に,封口板12が封口部材にそれぞれ相当している。そして,電池ケース11の上端面24が第1対向面に,封口板12の周辺部31(後述,図3参照)のうち上端面24に対面する側の面(図3中下面)が第2対向面に相当する。 In this embodiment, the battery case 11 and the sealing plate 12 are made of the same metal material. For example, aluminum and iron are suitable. As the battery case 11 of this embodiment, a battery case having a thickness t of about 1 mm is used at least in the vicinity of the upper end surface 24 of the side surface 23. The battery case 11 corresponds to a case body, and the sealing plate 12 corresponds to a sealing member. The upper end surface 24 of the battery case 11 is the first opposing surface, and the surface (the lower surface in FIG. 3) on the side facing the upper end surface 24 of the peripheral portion 31 (see FIG. 3 described later) of the sealing plate 12 is the second. Corresponds to the facing surface.
 また,封口板12は,電池ケース11の上端面24の上に載る板状の部材である。すなわち,上端面24に,封口板12の周辺部分が載せられる。そして,この封口板12により,開口部21が覆われる。封口板12の断面の一部を図3に示す。この図は,上端面24のうち,溝25の箇所での断面の状態を示している。溝25以外の箇所では,上端面24が封口板12に接触する。図示のように,封口板12は,外周に沿って幅sに形成された周辺部31と,周辺部31に囲まれた中央部32とを有している。 The sealing plate 12 is a plate-like member that is placed on the upper end surface 24 of the battery case 11. That is, the peripheral portion of the sealing plate 12 is placed on the upper end surface 24. The opening 21 is covered with the sealing plate 12. A part of the cross section of the sealing plate 12 is shown in FIG. This figure shows the state of the cross section at the location of the groove 25 in the upper end surface 24. At a place other than the groove 25, the upper end surface 24 contacts the sealing plate 12. As shown in the figure, the sealing plate 12 has a peripheral portion 31 formed with a width s along the outer periphery, and a central portion 32 surrounded by the peripheral portion 31.
 周辺部31は,図3に示すように,電池ケース11の上端面24に載る部分である。また,中央部32は,周辺部31よりも電池ケース11の内部側にやや下がった形状となっている。そのために,中央部32と周辺部31との間に段差が形成されている。なお,この図は,電池ケース11上に封口板12を載せただけで,まだ溶接していない状態を示している。 The peripheral portion 31 is a portion placed on the upper end surface 24 of the battery case 11 as shown in FIG. Further, the central portion 32 has a shape that is slightly lowered to the inside of the battery case 11 than the peripheral portion 31. Therefore, a step is formed between the central portion 32 and the peripheral portion 31. This figure shows a state in which the sealing plate 12 is merely placed on the battery case 11 and is not yet welded.
 電池ケース11に封口板12を載せると,図3に示すように,封口板12の周辺部31によって電池ケース11の上端面24はすべて覆われる。さらにこの図に示すように,周辺部31の幅sは,電池ケース11の板厚tより大きい。そのためこの状態では,溝25の上方は覆われている。溝25の両端部は,電池ケース11の外部側および内部側にそれぞれ開口している。また,本形態では,溝25の深さHは,板厚tに対して,次の式1を満たす範囲内とする。
 0.03×t ≦ H ≦ 0.3×t     … (式1)
When the sealing plate 12 is placed on the battery case 11, as shown in FIG. 3, the upper end surface 24 of the battery case 11 is entirely covered by the peripheral portion 31 of the sealing plate 12. Further, as shown in this figure, the width s of the peripheral portion 31 is larger than the plate thickness t of the battery case 11. Therefore, in this state, the upper part of the groove 25 is covered. Both end portions of the groove 25 are opened to the outside and inside of the battery case 11, respectively. In the present embodiment, the depth H of the groove 25 is within a range satisfying the following expression 1 with respect to the plate thickness t.
0.03 × t ≦ H ≦ 0.3 × t (Formula 1)
 本形態の二次電池10は,図3に示すように電池ケース11に封口板12を載せ,そしてその合わせ目にレーザ溶接を行ったものである。その結果,図4に示すように,溶接部13が形成されている。本形態では,図中に白抜きの矢印Lで示すように,電池ケース11と封口板12との重ね面に平行に,図中左横方向からレーザ光を照射する。これにより,電池ケース11の上端面24の近傍と封口板12の周辺部31とが部分的に溶かし合わされている。 As shown in FIG. 3, the secondary battery 10 of the present embodiment is obtained by placing a sealing plate 12 on a battery case 11 and performing laser welding on the joint. As a result, as shown in FIG. 4, a welded portion 13 is formed. In this embodiment, as indicated by a white arrow L in the drawing, the laser beam is irradiated from the left lateral direction in the drawing parallel to the overlapping surface of the battery case 11 and the sealing plate 12. Thereby, the vicinity of the upper end surface 24 of the battery case 11 and the peripheral portion 31 of the sealing plate 12 are partially melted together.
 本形態では,レーザ溶接としては,YAGレーザ等のパルスレーザを使用する。各パルスの照射位置が互いに部分的に重なるようにすこしずつずらしながら,電池ケース11の上端面24に沿って,全周にわたって溶接する。その場合,各パルスごとに形成される溶接部13は,それぞれ略半球形状である。従って,その断面形状は,図4に示すように,およそ半円形となる。この図では,各パルスによる溶接部13の最も深い箇所を示している。この図に示すように,最も深い箇所でも溶接部13の深さdは,電池ケース11の板厚tより小さい。また,溶接部13の内面は,溝25に面している。 In this embodiment, a pulse laser such as a YAG laser is used for laser welding. Welding is performed over the entire circumference along the upper end surface 24 of the battery case 11 while slightly shifting so that the irradiation positions of the respective pulses partially overlap each other. In that case, the weld 13 formed for each pulse has a substantially hemispherical shape. Therefore, the cross-sectional shape is approximately semicircular as shown in FIG. In this figure, the deepest part of the welded part 13 by each pulse is shown. As shown in this figure, the depth d of the welded portion 13 is smaller than the plate thickness t of the battery case 11 even at the deepest portion. Further, the inner surface of the welded portion 13 faces the groove 25.
 次に,図4のA-A断面を図5に示す。図中左端が,電池ケース11の側面23の外面であり,溶接部13によって隙間なく覆われている。また,側面23のうち,溶接部13によって隙間なく覆われている範囲の深さを,溶接深さDという。この溶接深さDは,厳密に調整できるものではない。すなわち,照射強度等のレーザの照射条件を設定しても,接合部の状態等によって溶接深さDはある程度影響される。本形態では,この溶接深さDが,板厚tの半分程度となるようにねらって設定している。 Next, FIG. 5 shows the AA cross section of FIG. The left end in the figure is the outer surface of the side surface 23 of the battery case 11 and is covered by the welded portion 13 without a gap. Further, the depth of the side surface 23 that is covered by the welded portion 13 without a gap is referred to as a welding depth D. This welding depth D cannot be adjusted strictly. That is, even if laser irradiation conditions such as irradiation intensity are set, the welding depth D is affected to some extent by the state of the joint. In this embodiment, the welding depth D is set so as to be about half of the plate thickness t.
 また,溝25のピッチpは,レーザパルスのピッチr以下である。従って,各パルスによる溶解部分は,必ず1つ以上の溝25に対向する。図5では,p=rとしている。すなわち,各1回のパルスの照射による溶接部13は,それぞれ対応する溝25を介して,電池ケース11の内部に連通されている。なお,レーザパルスのピッチrは,レーザのビード幅Rに対して,(0.2R<r<0.5R)の範囲内とすることが好ましい。 Further, the pitch p of the groove 25 is equal to or less than the pitch r of the laser pulse. Therefore, the melted part by each pulse always faces one or more grooves 25. In FIG. 5, p = r. That is, the welded portions 13 by each one-time pulse irradiation are communicated with the inside of the battery case 11 through the corresponding grooves 25. The pitch r of the laser pulses is preferably in the range of (0.2R <r <0.5R) with respect to the bead width R of the laser.
 次に,本形態の二次電池10の製造方法について説明する。まず,電池ケース11,封口板12,発電要素16となる電極捲回体等をそれぞれ製造する。この電池ケース11は,複数の溝25が形成されたものである。例えば,アルミ材を深絞りすることによって有底の箱状の部材を形成し,その後,切削等によって,各側面23の上端面24に溝25を形成したものとすればよい。 Next, a method for manufacturing the secondary battery 10 of this embodiment will be described. First, the battery case 11, the sealing plate 12, the electrode winding body that becomes the power generation element 16, and the like are manufactured. The battery case 11 is formed with a plurality of grooves 25. For example, a bottomed box-shaped member may be formed by deep drawing aluminum material, and then a groove 25 may be formed on the upper end surface 24 of each side surface 23 by cutting or the like.
 一方,封口板12には,外部電極端子(正極端子14と負極端子15)を取り付ける。そして,発電要素16となる電極捲回体の正負の電極と,封口板12の外部電極端子とを接続する。そして,電池ケース11の内部に電極捲回体を収容する。そして,封口板12を電池ケース11に被せ,その合わせ目をレーザ溶接する。パルスレーザをピッチrの等間隔で照射し,封口板12の周囲を一周する。このとき,上記のように電池ケース11に溝25が形成されているので,レーザの照射によって溶融した金属部分は,溝25の少なくとも1つと連通される。 On the other hand, external electrode terminals (positive terminal 14 and negative terminal 15) are attached to the sealing plate 12. Then, the positive and negative electrodes of the electrode winding body serving as the power generation element 16 and the external electrode terminal of the sealing plate 12 are connected. Then, the electrode winding body is accommodated in the battery case 11. Then, the sealing plate 12 is placed on the battery case 11 and the joint is laser welded. A pulse laser is irradiated at equal intervals of pitch r, and makes a round around the sealing plate 12. At this time, since the groove 25 is formed in the battery case 11 as described above, the metal portion melted by the laser irradiation is communicated with at least one of the grooves 25.
 従って,溶接時に溶融金属内に発生したヒュームは,その溝25を介して電池ケース11の内部へと逃げることができる。従って,溶接後の溶接部13内に気体が残ることはないので,ブローホールとなることはない。なお,電池内部へのヒュームの進入は,電池性能上全く問題ない。そして,全周の溶接が終了したら,その後,封口板12に形成されている注液口等を利用して,電池ケース11の内部に電解液を注入する。これで,二次電池10の完成である。 Therefore, the fumes generated in the molten metal during welding can escape to the inside of the battery case 11 through the groove 25. Accordingly, no gas remains in the welded portion 13 after welding, so there is no blow hole. It should be noted that the entry of fume into the battery has no problem in terms of battery performance. Then, after the welding of the entire circumference is completed, the electrolytic solution is then injected into the battery case 11 using a liquid injection port or the like formed in the sealing plate 12. This completes the secondary battery 10.
 なお,各溝25の断面形状はどのようなものでもよい。例えば,図6に示すように断面形状が四角形の角溝41のものでもよい。あるいは,図7に示すように断面形状が半円の丸溝42でもよい。あるいは,図8に示すように断面形状が三角形の三角溝43でもよい。あるいは,図9に示すように断面形状が台形の台形溝44でもよい。また,溝25とする代わりに,図10に示すように,上端面24上に形成した複数の畝状突起45を用いることもできる。畝状突起45の場合には,溝の深さHに相当するものは,畝状突起45の高さである。 In addition, what kind of cross-sectional shape of each groove | channel 25 may be sufficient. For example, as shown in FIG. 6, the rectangular groove 41 having a square cross-sectional shape may be used. Alternatively, as shown in FIG. 7, a round groove 42 having a semicircular cross section may be used. Alternatively, as shown in FIG. 8, a triangular groove 43 having a triangular cross section may be used. Alternatively, as shown in FIG. 9, a trapezoidal groove 44 having a trapezoidal cross section may be used. Further, instead of the groove 25, as shown in FIG. 10, a plurality of hook-like protrusions 45 formed on the upper end surface 24 can be used. In the case of the hook-shaped protrusion 45, the height corresponding to the groove depth H is the height of the hook-shaped protrusion 45.
 次に,発明者らは,以下の実験1を行った。実験1では,テスト用のアルミ製電池ケースの上端面に,溝を形成したものを製造した。さらに,封口板12を通常のレーザ溶接によって溶接して,その溶接箇所の状態を観察した。ここでは,電池ケースとして板厚1mm(t=1)のものを使用した。また,溝の深さHの異なる複数種のものを製造した。溶接後,溶接部に発生した平均ブローホール数と,溶接部の平均耐圧強度とを測定し,評価した。なお,この実験では,溝の幅と溝の深さHとがほぼ同等で,断面形状が略正方形の角溝41を使用した。 Next, the inventors performed the following experiment 1. In Experiment 1, an aluminum battery case for testing was manufactured with a groove formed on the upper end surface. Further, the sealing plate 12 was welded by ordinary laser welding, and the state of the welded portion was observed. Here, a battery case having a thickness of 1 mm (t = 1) was used. A plurality of types having different groove depths H were manufactured. After welding, the average number of blow holes generated in the weld and the average pressure strength of the weld were measured and evaluated. In this experiment, a square groove 41 having a groove width and a groove depth H substantially equal to each other and having a substantially square cross section was used.
 実施例1~5は,溝深さHを0.03,0.05,0.10,0.20,0.30(mm)としたものである。これらは,上記の式1の範囲を満たしている。比較例1と2は,溝深さHを0.40,0.50(mm)としたものである。板厚1mmの電池ケースであるので,これらの比較例は,上記の式1の範囲を外れている。また,比較例3は,溝を設けていない従来の電池ケースを使用したものである。 In Examples 1 to 5, the groove depth H is set to 0.03, 0.05, 0.10, 0.20, and 0.30 (mm). These satisfy the range of Equation 1 above. In Comparative Examples 1 and 2, the groove depth H is 0.40 and 0.50 (mm). Since this is a battery case with a plate thickness of 1 mm, these comparative examples are out of the range of Equation 1 above. Moreover, the comparative example 3 uses the conventional battery case which does not provide the groove | channel.
 それぞれの測定方法は以下の通りである。平均ブローホール数の測定は,溶接部13の断面を出し,目視で数えて行った。すなわち,溶接部13の近傍を樹脂で固め,封口板12をその厚さを薄くする方向に研磨した。溶接部13の断面が目視できる程度まで削って,ブローホール数を数えた。このとき,溶接深さDも測定した。また,平均耐圧強度の測定は,溶接済みの電池ケースのうち溶接部13以外の箇所に貫通穴を開け,その貫通穴から電池ケースの内部に液体を注入して行った。そして,溶接部13が破壊されたときの液体の圧力を測定した。 Each measurement method is as follows. The average number of blowholes was measured by taking a section of the welded portion 13 and counting it visually. That is, the vicinity of the welded portion 13 was hardened with resin, and the sealing plate 12 was polished in a direction to reduce its thickness. The number of blowholes was counted by cutting the welded portion 13 so that the cross section of the welded portion 13 was visible. At this time, the welding depth D was also measured. The average pressure strength was measured by making a through hole at a location other than the welded portion 13 in the welded battery case and injecting a liquid into the battery case from the through hole. And the pressure of the liquid when the welding part 13 was destroyed was measured.
 各例ごとに10個のサンプルを作成して,溶接深さ,ブローホール数,耐圧強度をそれぞれ測定し,それぞれの測定結果の平均を算出して評価した。また,評価の基準は,以下の通りとした。
 平均ブローホール数が0個で,かつ,平均耐圧強度が4.0MPa以上の場合に◎
 いずれか一方でも満たしていない場合に×
Ten samples were prepared for each example, and the welding depth, the number of blow holes, and the pressure strength were measured, and the average of each measurement result was calculated and evaluated. The evaluation criteria were as follows.
When the average number of blow holes is 0 and the average pressure resistance is 4.0 MPa or more.
If either of them is not met ×
Figure JPOXMLDOC01-appb-T000001
 
Figure JPOXMLDOC01-appb-T000001
 
 実験1の結果は,表1に示す通りとなった。実施例1~5のものはいずれも良好な状態の溶接部が得られた。比較例1,2は,溶接深さが小さく,平均耐圧強度が基準に達しなかった。これは,溝の深さが大きすぎるためと考えられる。また,比較例3は,多数のブローホールが観察された。従って,溝深さHの好ましい範囲は,上記の式1を満たす範囲であることが確認できた。 The result of Experiment 1 is as shown in Table 1. In all of Examples 1 to 5, welds in good condition were obtained. In Comparative Examples 1 and 2, the welding depth was small, and the average pressure strength did not reach the standard. This is probably because the depth of the groove is too large. In Comparative Example 3, many blow holes were observed. Therefore, it was confirmed that the preferable range of the groove depth H is a range satisfying the above-described expression 1.
 次に,上記の実施の形態の別の例を,図11に示す。この電池ケース51には,溝25に代えて,板厚全体にわたっていない溝52が形成されている。また,図11のB-B断面を図12に示す。この図は,まだ溶接していない状態における,側面23の上端面24近くの断面図を示している。図示のように,溝52は,側面23のうち,電池ケース51の内面へ開口している。外面へは開口していない。 Next, another example of the above embodiment is shown in FIG. In the battery case 51, a groove 52 that does not cover the entire plate thickness is formed instead of the groove 25. FIG. 12 shows a BB cross section of FIG. This figure shows a cross-sectional view near the upper end surface 24 of the side surface 23 in a state where it has not been welded yet. As illustrated, the groove 52 opens to the inner surface of the battery case 51 in the side surface 23. There is no opening to the outer surface.
 この場合では,溝52の内面からの長さLは,電池ケース11の板厚tと溶接深さDとから,以下の式2の範囲内とすることが好ましい。
 L ≧ t-D       … (式2)
ただし,この溶接深さDは,設定値である。例えば本形態では,溶接深さDの設定値を板厚tの半分としている。この例でも,溝の形状はどのようなものでもよい。この例では溝の深さは,式1の範囲より大きくてもよい。
In this case, the length L from the inner surface of the groove 52 is preferably within the range of the following formula 2 from the plate thickness t of the battery case 11 and the welding depth D.
L ≧ t−D (Formula 2)
However, this welding depth D is a set value. For example, in this embodiment, the set value of the welding depth D is half of the plate thickness t. In this example, any shape of the groove may be used. In this example, the depth of the groove may be larger than the range of Equation 1.
 次に,発明者らは以下の実験2を行った。すなわち,図11に示したような,板厚方向に貫通していない溝の例について,実験1と同様にその性能を確認した。そのために,テスト用のアルミ製電池ケースの上端面に,板厚方向に貫通しない溝を形成した。溝の長さの異なる複数種の電池ケースを製造して,封口板を外側からのレーザ溶接によって溶接した。その溶接箇所の状態を観察した。 Next, the inventors performed the following experiment 2. That is, the performance of an example of a groove that does not penetrate in the thickness direction as shown in FIG. For this purpose, a groove that does not penetrate in the thickness direction was formed in the upper end surface of the test aluminum battery case. Several types of battery cases with different groove lengths were manufactured, and the sealing plate was welded by laser welding from the outside. The state of the welded part was observed.
 ここでは,電池ケースとして板厚1mm(t=1)のものを使用し,溝の長さLの異なる複数種のものを製造した。溝深さHは,いずれも0.05mmとした。溶接後,溶接部に発生した平均ブローホール数と,溶接部の平均耐圧強度とを測定し,評価した。なお,この実験でも,溝の形状として角溝を使用した。 Here, a battery case having a thickness of 1 mm (t = 1) was used, and a plurality of types having different groove lengths L were manufactured. The groove depth H was 0.05 mm in all cases. After welding, the average number of blow holes generated in the weld and the average pressure strength of the weld were measured and evaluated. In this experiment, a square groove was used as the groove shape.
 実施例1,2は,溝長さLを0.70,0.50mmとしたものである。これらは,上記の式2の範囲を満たしている。比較例1~3は,溝長さLをそれぞれ,0.30,0.20,0.10(mm)としたものである。板厚tが1mmの電池ケースであるので,これらの比較例は,上記の式2の範囲を外れている。また,比較例4は,溝を設けていない従来の電池ケースを使用したものである。また,測定方法と評価基準は,実験1と同様である。 In Examples 1 and 2, the groove length L is 0.70 and 0.50 mm. These satisfy the range of Equation 2 above. In Comparative Examples 1 to 3, the groove lengths L are 0.30, 0.20, and 0.10 (mm), respectively. Since the battery case t has a thickness of 1 mm, these comparative examples are out of the range of Equation 2 above. Moreover, the comparative example 4 uses the conventional battery case which does not provide the groove | channel. The measurement method and evaluation criteria are the same as in Experiment 1.
Figure JPOXMLDOC01-appb-T000002
 
Figure JPOXMLDOC01-appb-T000002
 
 実験2の結果は,表2に示す通りとなった。実施例1のものはすべてのサンプルについて良好な状態の溶接部が得られた。実施例2では,ほとんどのサンプルで良好であったが,僅かにブローホールの発生した例が見られた。そのため,評価を○とした。また,比較例1~4は,ブローホールの発生を抑止することができなかった。溝の長さが小さすぎて,溶接深さが溝まで届かなかったためであると考えられる。従って,溝長さLの好ましい範囲は,上記の式2を満たす範囲であることが確認できた。 The result of Experiment 2 is as shown in Table 2. In the case of Example 1, welds in good condition were obtained for all the samples. In Example 2, although most of the samples were good, there was an example in which blowholes were slightly generated. Therefore, the evaluation was rated as “good”. In Comparative Examples 1 to 4, the generation of blow holes could not be suppressed. This is probably because the groove length was too small and the welding depth did not reach the groove. Therefore, it was confirmed that the preferable range of the groove length L is a range satisfying the above-described Expression 2.
 すなわち,本形態の電池ケース11としては,式1または式2を満たす範囲の大きさの溝25を形成したものとすればよい。板厚方向に貫通する溝であれば上記の式1を,貫通しない溝であれば式2をそれぞれ満たすようにする。このようなものであれば,溶接時の各レーザパルスによる溶解範囲ごとに,それぞれ電池ケース11の内部への連通が可能となる。 That is, as the battery case 11 of the present embodiment, the groove 25 having a size in a range satisfying the formula 1 or the formula 2 may be formed. If the groove penetrates in the plate thickness direction, the above equation 1 is satisfied, and if the groove does not penetrate, the equation 2 is satisfied. If it is such, it will become possible to communicate with the inside of the battery case 11 for each melting range by each laser pulse during welding.
 逆に言えば,このような連通を可能とするように,溝を形成すればよい。その他の例を,図13と図14に示す。図13の例では,溶接深さDよりやや外側よりの箇所に,電池ケース11の側面に沿った方向(図中上下方向)の縦溝61が形成されている。それとともに,その縦溝61と電池ケース11の内部とを連通する横溝62が1本以上形成されているものである。また,図14の例は,溶接深さDよりやや外側に段差が形成され,その内面側がすべて凹部63となっているものである。 In other words, a groove may be formed so as to enable such communication. Other examples are shown in FIGS. In the example of FIG. 13, vertical grooves 61 in the direction along the side surface of the battery case 11 (up and down direction in the figure) are formed at positions slightly outside the welding depth D. At the same time, one or more lateral grooves 62 that communicate the longitudinal grooves 61 and the inside of the battery case 11 are formed. Further, in the example of FIG. 14, a step is formed slightly outside the welding depth D, and the inner surface side is a recess 63.
 また,溝深さは必ずしも一定でなくともよい。電池ケースの外部側から内部側へ向かって,次第に深くなるようにしてもよい。例えば,円錐や角錐の一部分の形状の溝としてもよい。あるいは,電池ケースに溝を形成する代わりに,封口板の裏面に溝を形成しても同様の効果が得られる。この場合には,図15に示すように,側面23の板厚tよりもさらに内部へ入った位置までの溝64とすることが望ましい。またはケースと封口板の両方に,互いに干渉しない位置に形成してもよい。また例えば,これまでの例で溝を形成した位置に,溝の代わりに表面を適度に荒らすことにより凹部を形成してもよい。このようにすることも凹部を形成する方法に含まれる。 Also, the groove depth is not necessarily constant. You may make it become deep gradually from the external side of a battery case toward an internal side. For example, a groove having a shape of a part of a cone or a pyramid may be used. Alternatively, the same effect can be obtained by forming a groove on the back surface of the sealing plate instead of forming the groove on the battery case. In this case, as shown in FIG. 15, it is desirable that the groove 64 extends to a position further inside than the thickness t of the side surface 23. Or you may form in the position which does not mutually interfere in both a case and a sealing board. Further, for example, the concave portion may be formed by appropriately roughening the surface instead of the groove at the position where the groove is formed in the above examples. This is also included in the method of forming the recess.
 以上詳細に説明したように本形態の二次電池10によれば,溶接前の電池ケース11の上端面24に溝25が形成されている。従って,上端面24に封口板12を載せてレーザ溶接すると,溝25を介して溶融金属は電池ケース11の内部と連通する。従って,溶接部13にブローホールが発生することが防止されている。これにより,ヒュームに起因するブローホールの発生を抑制し,溶接信頼性の高い二次電池が得られる。 As described in detail above, according to the secondary battery 10 of this embodiment, the groove 25 is formed in the upper end surface 24 of the battery case 11 before welding. Therefore, when the sealing plate 12 is placed on the upper end surface 24 and laser welding is performed, the molten metal communicates with the inside of the battery case 11 through the groove 25. Therefore, the occurrence of blow holes in the welded portion 13 is prevented. As a result, the generation of blowholes due to fume is suppressed, and a secondary battery with high welding reliability can be obtained.
 次に,本形態の二次電池10を各種の機器に搭載して使用する場合の使用例について説明する。例えば,図16に示すように,複数個の二次電池10を用いた電池パック100を製造して使用する。複数個の二次電池10を,その外部電極端子が同じ側に配置されるように,隣接する二次電池10の側面(大面積の面)同士を接触させて並べる。さらに,その両側にそれぞれ拘束板110を当接させて,拘束板110同士を拘束ネジ111とナット112とで締め付ける。これにより,各二次電池10を使用に適した拘束圧で拘束して使用することができる。さらに,各二次電池10の正極端子14と負極端子15とを順に直列に接続して,電池パック100とし,各種の機器に搭載する。 Next, a usage example when the secondary battery 10 of the present embodiment is used in various devices will be described. For example, as shown in FIG. 16, a battery pack 100 using a plurality of secondary batteries 10 is manufactured and used. A plurality of secondary batteries 10 are arranged such that the side surfaces (large area surfaces) of adjacent secondary batteries 10 are in contact with each other so that the external electrode terminals are arranged on the same side. Further, the restraint plates 110 are brought into contact with both sides thereof, and the restraint plates 110 are fastened with the restraint screws 111 and the nuts 112. Thereby, each secondary battery 10 can be restrained and used at a restraining pressure suitable for use. Furthermore, the positive electrode terminal 14 and the negative electrode terminal 15 of each secondary battery 10 are connected in series in order to form a battery pack 100 that is mounted on various devices.
 この電池パック100は,例えば,図17に示すように,車両200に搭載して使用することができる。この車両200は,エンジン240,フロントモータ220及びリアモータ230を併用して駆動するハイブリッド自動車である。この車両200は,車体290,エンジン240,これに取り付けられたフロントモータ220,リアモータ230,ケーブル250,インバータ260及び複数の2次電池10を自身の内部に有する電池パック100を有している。 The battery pack 100 can be used by being mounted on a vehicle 200 as shown in FIG. 17, for example. The vehicle 200 is a hybrid vehicle that is driven by using an engine 240, a front motor 220, and a rear motor 230 in combination. This vehicle 200 includes a vehicle body 290, an engine 240, a front motor 220, a rear motor 230 attached thereto, a cable 250, an inverter 260, and a battery pack 100 having a plurality of secondary batteries 10 therein.
 なお,車両としては,その動力源の全部あるいは一部に電池による電気エネルギを使用している車両であれば良く,例えば,電気自動車,ハイブリッド自動車,プラグインハイブリッド自動車,ハイブリッド鉄道車両,フォークリフト,電気車椅子,電動アシスト自転車,電動スクータ等が挙げられる。 The vehicle may be a vehicle that uses battery-generated electric energy for all or a part of its power source. For example, an electric vehicle, a hybrid vehicle, a plug-in hybrid vehicle, a hybrid railway vehicle, a forklift, an electric vehicle Wheelchairs, electric assist bicycles, electric scooters, etc. are listed.
 電池パック100は,あるいは,図18に示すように,電池搭載機器に使用することもできる。この図に示すのは,本形態の2次電池10を含む電池パック100を搭載したハンマードリル300である。このハンマードリル300は,電池パック100,本体320を有する電池搭載機器である。なお,電池パック100は,ハンマードリル300の本体320のうち底部321に着脱可能に収容されている。 Alternatively, the battery pack 100 can be used for a battery-equipped device as shown in FIG. Shown in this figure is a hammer drill 300 on which a battery pack 100 including the secondary battery 10 of this embodiment is mounted. The hammer drill 300 is a battery-equipped device having a battery pack 100 and a main body 320. The battery pack 100 is detachably accommodated in the bottom 321 of the main body 320 of the hammer drill 300.
 なお,電池搭載機器としては,電池を搭載しこれをエネルギー源の少なくとも1つとして利用する機器であれば良く,例えば,パーソナルコンピュータ,携帯電話,電池駆動の電動工具,無停電電源装置など,電池で駆動される各種の家電製品,オフィス機器,産業機器が挙げられる。また,電池パック100以外にも,組電池状態としていない単電池で使用できる機器をも含む。 The battery-equipped device may be any device equipped with a battery and using it as at least one energy source. For example, a personal computer, a mobile phone, a battery-powered electric tool, an uninterruptible power supply, etc. Various types of home appliances, office equipment, and industrial equipment driven by In addition to the battery pack 100, devices that can be used with a single battery that is not in an assembled battery state are also included.
 なお,本形態は単なる例示にすぎず,本発明を何ら限定するものではない。したがって本発明は当然に,その要旨を逸脱しない範囲内で種々の改良,変形が可能である。
 例えば,リチウムイオン二次電池にかぎらず,密封型の電池であれば広く適用することができる。また,電池の外形も,扁平な箱形状のものに限らず,筒型の電池にも適用可能である。
In addition, this form is only a mere illustration and does not limit this invention at all. Therefore, the present invention can naturally be improved and modified in various ways without departing from the gist thereof.
For example, not only lithium ion secondary batteries but also sealed batteries can be widely applied. Further, the outer shape of the battery is not limited to a flat box shape, and can be applied to a cylindrical battery.

Claims (11)

  1. 一面が開口部となっているケース本体と,前記ケース本体の開口部を塞ぐ封口部材とを有し,前記ケース本体に発電要素を収納して,溶接により前記封口部材で前記ケース本体の開口部が封口されることで電池となる密閉型電池用ケースにおいて,
     前記ケース本体の開口部の縁辺に,前記封口部材と対面して溶接される第1対向面が形成されており,
     前記封口部材に,前記第1対向面と対面して溶接される第2対向面が形成されており,
     前記第1対向面と前記第2対向面との少なくとも一方に,前記第1対向面と前記第2対向面とを対面させたときに,前記ケース本体の内部空間に連通する隙間を両対向面間に形成する凹部が形成されており,
     前記凹部は,前記ケース本体の板厚方向に少なくとも,前記ケース本体の内面に相当する位置から,前記ケース本体の外側に向かって形成されていることを特徴とする密閉型電池用ケース。
    A case main body having an opening on one side; and a sealing member that closes the opening of the case main body. The power generation element is accommodated in the case main body, and the opening of the case main body is sealed by the sealing member by welding. In a sealed battery case that becomes a battery by sealing
    A first opposing surface welded to face the sealing member is formed on the edge of the opening of the case body,
    The sealing member is formed with a second opposing surface that is welded facing the first opposing surface,
    When at least one of the first opposing surface and the second opposing surface faces the first opposing surface and the second opposing surface, a gap communicating with the internal space of the case body is defined as both opposing surfaces. A recess formed between them,
    The sealed battery case is characterized in that the recess is formed in the thickness direction of the case body from at least a position corresponding to the inner surface of the case body toward the outside of the case body.
  2. 請求項1に記載する密閉型電池用ケースにおいて,前記凹部の外側端部は,
     溶接時に溶融する範囲内に位置することを特徴とする密閉型電池用ケース。
    The sealed battery case according to claim 1, wherein the outer end of the recess is
    A sealed battery case characterized by being located within a range that melts during welding.
  3. 請求項1または請求項2に記載する密閉型電池用ケースにおいて,前記凹部は,
     前記ケース本体の開口部の周方向に対して離散的に形成された溝部であることを特徴とする密閉型電池用ケース。
    The sealed battery case according to claim 1 or 2, wherein the recess is
    A sealed battery case, wherein the case is a groove formed discretely with respect to the circumferential direction of the opening of the case body.
  4. 請求項3に記載する密閉型電池用ケースにおいて,前記溝部は,
     前記ケース本体の板厚全体にわたって形成されていることを特徴とする密閉型電池用ケース。
    The sealed battery case according to claim 3, wherein the groove is
    A sealed battery case characterized by being formed over the entire thickness of the case body.
  5. 請求項3または請求項4に記載する密閉型電池用ケースにおいて,
     前記ケース本体の開口部の周方向に対する前記溝部の配置のピッチが,
     溶接時の溶接箇所のピッチ以下であることを特徴とする密閉型電池用ケース。
    In the sealed battery case according to claim 3 or claim 4,
    The pitch of the arrangement of the grooves with respect to the circumferential direction of the opening of the case body is
    A sealed battery case characterized by having a pitch equal to or less than a pitch of welding points during welding.
  6. 請求項4に記載する密閉型電池用ケースにおいて,
     前記溝部の深さは,前記ケース本体の板厚の0.3倍以下であることを特徴とする密閉型電池用ケース。
    In the sealed battery case according to claim 4,
    The sealed battery case, wherein the depth of the groove is 0.3 times or less the plate thickness of the case body.
  7. 発電要素と,一面が開口部となっているケース本体と,前記ケース本体の開口部を塞ぐ封口部材とを有し,前記ケース本体に発電要素を収納して,溶接により前記封口部材で前記ケース本体の開口部が封口されている密閉型電池において,
     前記ケース本体の開口部の縁辺に,前記封口部材と対面する第1対向面が形成されており,
     前記封口部材に,前記第1対向面と対面する第2対向面が形成されており,
     前記第1対向面と前記第2対向面との少なくとも一方に,前記ケース本体の内部空間に連通する隙間を両対向面間に形成する凹部が形成されており,
     両対向面の接触箇所が,全周にわたり外側から溶接されており,
     前記凹部は,前記ケース本体の板厚方向に少なくとも,前記ケース本体の内面に相当する位置から,溶接時に溶融した位置までにわたって形成されていることを特徴とする密閉型電池。
    A power generation element; a case main body having an opening on one side; and a sealing member that closes the opening of the case main body. The power generation element is housed in the case main body and welded to the case by the sealing member. In a sealed battery in which the opening of the main body is sealed,
    A first opposing surface facing the sealing member is formed on an edge of the opening of the case body;
    A second facing surface facing the first facing surface is formed on the sealing member;
    At least one of the first facing surface and the second facing surface is formed with a recess that forms a gap communicating with the internal space of the case body between the facing surfaces.
    The contact points on both opposing surfaces are welded from the outside over the entire circumference,
    The sealed battery is characterized in that the recess is formed in a thickness direction of the case body from at least a position corresponding to the inner surface of the case body to a position melted during welding.
  8. 発電要素と,一面が開口部となっているケース本体と,前記ケース本体の開口部を塞ぐ封口部材とを用い,前記ケース本体に発電要素を収納して,溶接により前記封口部材で前記ケース本体の開口部を封口することによる密閉型電池の製造方法において,
     前記ケース本体として,その開口部の縁辺に,前記封口部材と対面して溶接される第1対向面が形成されているものを準備し,前記封口部材として,前記第1対向面と対面して溶接される第2対向面が形成されているものを準備する工程と,
     発電要素を収納した前記ケース本体の開口部を前記封口部材で塞ぐことにより両対向面が接触する状態とし,両対向面の接触箇所を,全周にわたり外側から溶接する工程とを有し,
     前記準備する工程では,前記ケース本体および前記封口部材の組合せとして,前記第1対向面と前記第2対向面との少なくとも一方に,前記第1対向面と前記第2対向面とを対面させたときに,前記ケース本体の内部空間に連通する隙間を両対向面間に形成する凹部を,前記ケース本体の板厚方向に少なくとも,前記ケース本体の内面に相当する位置から,前記ケース本体の外側に向かって形成したものを準備することを特徴とする密閉型電池の製造方法。
    A power generation element, a case main body having an opening on one side, and a sealing member that closes the opening of the case main body, the power generation element is accommodated in the case main body, and the case main body by the sealing member by welding In the manufacturing method of a sealed battery by sealing the opening of
    The case body is prepared with a first opposing surface formed on the edge of the opening facing the sealing member and facing the sealing member, and as the sealing member facing the first opposing surface. Preparing a second opposing surface to be welded;
    A step of closing the opening of the case body containing the power generation element with the sealing member so that the opposing surfaces come into contact with each other, and welding the contact points of the opposing surfaces from the outside over the entire circumference,
    In the step of preparing, as the combination of the case body and the sealing member, the first facing surface and the second facing surface are made to face at least one of the first facing surface and the second facing surface. Sometimes, a recess that forms a gap communicating with the internal space of the case body between the opposing surfaces is formed at least from the position corresponding to the inner surface of the case body in the thickness direction of the case body. A method for producing a sealed battery, characterized in that a battery formed toward the surface is prepared.
  9. 請求項8に記載する密閉型電池の製造方法において,
     前記準備する工程では,前記ケース本体および前記封口部材の組合せとして,前記凹部の外側端部を,溶接時に溶融する範囲内に位置するように形成したものを準備することを特徴とする密閉型電池の製造方法。
    In the manufacturing method of the sealed battery according to claim 8,
    In the preparing step, as a combination of the case main body and the sealing member, a sealed battery is prepared in which the outer end portion of the recess is formed so as to be located within a range that melts during welding. Manufacturing method.
  10. 請求項7に記載の密閉型電池を搭載することを特徴とする車両。 A vehicle comprising the sealed battery according to claim 7.
  11. 請求項7に記載の密閉型電池を搭載することを特徴とする電池搭載機器。 A battery-mounted device comprising the sealed battery according to claim 7.
PCT/JP2009/051832 2009-02-04 2009-02-04 Case for sealed battery, sealed battery and method of manufacturing the sealed battery, vehicle having the battery, and battery-mounted device WO2010089852A1 (en)

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