WO2010088121A2 - Oxygen production method and apparatus - Google Patents
Oxygen production method and apparatus Download PDFInfo
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- WO2010088121A2 WO2010088121A2 PCT/US2010/021551 US2010021551W WO2010088121A2 WO 2010088121 A2 WO2010088121 A2 WO 2010088121A2 US 2010021551 W US2010021551 W US 2010021551W WO 2010088121 A2 WO2010088121 A2 WO 2010088121A2
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- air
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- oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F3/00—Plate-like or laminated elements; Assemblies of plate-like or laminated elements
- F28F3/02—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
- F28F3/025—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being corrugated, plate-like elements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/0409—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04187—Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
- F25J3/04218—Parallel arrangement of the main heat exchange line in cores having different functions, e.g. in low pressure and high pressure cores
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04296—Claude expansion, i.e. expanded into the main or high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04303—Lachmann expansion, i.e. expanded into oxygen producing or low pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/04309—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/04309—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
- F25J3/04315—Lowest pressure or impure nitrogen, so-called waste nitrogen expansion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J5/00—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
- F25J5/002—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D9/00—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D9/0062—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by spaced plates with inserted elements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
- F25J2290/10—Mathematical formulae, modeling, plot or curves; Design methods
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
- F25J2290/12—Particular process parameters like pressure, temperature, ratios
Definitions
- the present invention relates to a method and apparatus, including an air separation plant and a heat exchanger, for producing an oxygen product as a supercritical fluid by heating a pumped liquid oxygen stream within a heat exchanger through indirect heat exchange with compressed air. More particularly, the present invention relates to such a method and apparatus in which the air pressure utilized in a heat exchanger to heat the pumped liquid oxygen stream is selected on the basis of a function of the oxygen pressure that results in a minimum or very close to minimum expenditure of compression energy. Even more particularly, the present invention relates to such a method and apparatus and air separation plant in which the heat exchanger is a plate-fin heat exchanger.
- Gasification is an environmentally friendly technology which can utilize coal or other relatively low value feedstocks and convert them into high-value products, or alternatively produce a clean source of electrical power by gasifying the feedstock within gasifiers into hydrogen and carbon monoxide containing streams.
- These gasifiers typically require oxygen at high pressures in which the oxygen is supplied as a supercritical fluid.
- a low-grade carbon containing material in the presence of oxygen is converted to a hydrogen and carbon monoxide containing stream that can be further processed to be used as a fuel in the generation of electricity and/or as a source of hydrogen, or further processed to manufacture valuable products such as chemicals, fertilizers or liquid fuels.
- steam is generated in such processing that can be further used to drive generators .
- the liquid oxygen can be pumped to a high pressure and then heated to a critical temperature at which the resulting oxygen product will exist as a supercritical fluid.
- the pumping operation is incorporated into a cryogenic air separation plant, although, it is possible that the pumping operation could be conducted independently of such a plant.
- air is compressed, purified and then cooled to a temperature suitable for its rectification in a distillation column system.
- the liquid oxygen that is drawn from residual oxygen-rich liquid in the low pressure column is pumped to pressure and then heated in a multi-stream main heat exchanger that is used in cooling the air against one or more product streams, or in a separate heat exchanger dedicated to the heating of the oxygen. In either case, part of the air to be rectified is further compressed in a booster compressor and then used to heat the oxygen and then produce the high pressure oxygen product that can be used in a gasifier or other process requiring high pressure oxygen.
- the raw material used in producing the oxygen is the electrical power drawn, or steam consumed or fuel burned to produce the energy for compressing the air in the first instance and further compressing the air to vaporize the pumped oxygen.
- cryogenic rectification is conducted at cryogenic temperatures and there exists thermal loss due to heat leakage, liquid products that are removed from the plant for storage, backup or merchant liquid sale and warm end losses, refrigeration must be imparted. This is commonly accomplished by further compressing part of the air to be separated and then expanding the air in a turboexpander with removal of the work of expansion. The resulting exhaust is then introduced into the distillation column system.
- turboexpander with removal of the work of expansion.
- the resulting exhaust is then introduced into the distillation column system.
- U.S. Patent No. 6,430,962-B2 also considers the production of oxygen as a supercritical fluid.
- the oxygen produced in a low pressure column of an air separation plant is pumped to a supercritical pressure and then vaporized in a brazed aluminum plate-fin heat exchanger. It is mentioned that the more narrow the temperature difference between the oxygen and the air at the warm end of the heat exchanger, the lower the thermal stress within the heat exchanger. Two cases were compared, one at 0.61 Mpa less than the critical pressure of oxygen, 5.043 MPa and another far above the critical pressure, a pressure of 8.14 MPa.
- U.S. Patent No. 7,219,719 B2 a brazed aluminum plate-fin heat exchanger design is disclosed that is designed to be used at oxygen pressures above 100 bar.
- straight extruded fins are used in the high pressure channels, having a sufficient thickness to withstand such high pressures. It is mentioned that the ratio of the mean fin thickness to the geometric pitch, or spacing between adjacent fins is preferably greater than 0.2 and less than 0.8.
- U.S. Patent No. 6,951,245 discloses another brazed aluminum plate-fin heat exchanger that employs straight fins.
- the present invention provides a method of producing an oxygen product as a supercritical fluid that involves heating a pumped liquid oxygen stream with the use of supercritical pressure air in which a relationship has been determined that will allow the power consumed by the air compressor to be minimized and that can be used in connection with a heat exchanger design that will incorporate a more efficient fin design than disclosed in the prior art.
- the present invention provides a method of producing an oxygen product in which a liquid oxygen stream having a purity of no less than about 90 percent by volume is pumped to produce a pumped liquid oxygen stream.
- the pumped liquid oxygen stream is heated within a heat exchanger through indirect heat exchange with at least a compressed air stream to produce the oxygen product.
- the term "at least" as used herein and in the claims in this context is meant to cover a banked heat exchange process in which the only heating stream is the air stream or alternatively a heat exchanger in which there might be other streams that would serve a heating function, albeit at a much lesser extent, such the main air stream and boosted streams to be passed into a turboexpander to generate refrigeration in an air separation plant.
- the pumped liquid oxygen stream is pressurized to an oxygen pressure in a range above about 55 bar (a) and no greater than about 150 bar (a) upon entering the heat exchanger and is heated within the heat exchanger to a temperature at which the oxygen product will be a supercritical fluid.
- the "temperature” is any temperature at or above the supercritical temperature of oxygen which will be at and above 154.78 K.
- the energy of compression will always be at or very close to a minimum at a given heat exchanger duty.
- the heat exchanger could be free-standing to deliver oxygen at pressure from a liquid source, the heat exchanger could be incorporated within an air separation plant.
- the air pressure for reasons that will also be discussed, although not necessarily at the minimum could be equal to a value within a range of no less than about 10 percent below and about 20 percent above the quantity determined from the equation set forth above.
- the oxygen pressure can be maintained at the oxygen pressure during turn-down operation conditions of the air separation plant.
- the pumped liquid oxygen stream and the compressed air stream can be passed countercurrently through passages within a plate-fin heat exchanger comprising parting sheets separated by and connected to corrugated fins to at least form air passages for the air and oxygen passages for the pumped liquid oxygen stream.
- air and oxygen passages are "at least" formed in that, as indicated above, the present invention is equally applicable to a heat exchanger dedicated to the vaporization of oxygen, a so called “banked" design that will be discussed hereinafter, as well as a unit having passages for multiple streams, such as air and nitrogen.
- the fins in at least the air passages can be provided with a wavy or undulating configuration such that the flow path of the compressed air through the fins is increased over a straight through plain fin arrangement with the same fin thickness and pitch, and the compressed air stream is passed through the air passages containing the undulating fin at a velocity sufficient to induce flow separations due to the undulating configuration of the fins.
- a velocity could be in a transition regime between laminar and turbulent flow or fully turbulent flow.
- the flow separations will periodically break the thermal boundary layer due to the periodic changes in flow direction resulting in an enhancement in the heat transfer rate from the fluid to the surface of the undulating fins which are in turn thermally connected to the other layers in the heat exchanger.
- the present invention provides an apparatus for producing an oxygen product from a liquid oxygen stream having a purity of no less than about 90 percent by volume.
- a pump is provided to pump the liquid oxygen stream, thereby to produce a pumped liquid oxygen stream.
- a compressor is provided to compress air and thereby to produce a compressed air stream and a heat exchanger is connected to the pump and the compressor such that the pumped liquid oxygen stream is heated within a heat exchanger through indirect heat exchange with at least the compressed air stream to produce the oxygen product.
- the term "at least" as used herein and in the claims in this context, is meant to cover a banked heat exchange process in which the only heating stream is the air stream or alternatively a heat exchanger in which there might be other streams that would serve a heating function, albeit at a much lesser extent, such the main air stream and boosted streams to be passed into a turboexpander to generate refrigeration in an air separation plant.
- the pump is configured to pump the liquid oxygen stream so that the pumped liquid oxygen stream is pressurized to an oxygen pressure in a range above about 55 bar (a) and no greater than about 150 bar (a) upon entering the heat exchanger.
- the heat exchanger is configured such that the pumped liquid oxygen stream is heated within the heat exchanger to a temperature at which the oxygen product will be a supercritical fluid.
- the "temperature” is any temperature at or above the supercritical temperature of oxygen which will be at and above 154.78 K.
- the present invention provides an air separation plant for producing an oxygen product.
- a compressor is provided to compress the air and a pre-purification is connected to the compressor to purify the air and thereby to produce a compressed and purified air stream.
- a booster compressor is connected to the pre-purification unit.
- At least one heat exchanger is connected to the pre- purification unit and the booster compressor and is configured such that part of the compressed and purified air stream is cooled within the at least one heat exchanger and a further part of the compressed and purified air stream is compressed in the booster compressor to form a compressed air stream that is cooled within the at least one heat exchanger.
- An air separation unit is connected to the at least one heat exchanger so as to receive the part of the compressed and purified air stream and the compressed air stream after having been cooled and is configured to rectify the air and thereby produce a liquid oxygen stream having an oxygen purity of no less than about 90 percent by volume.
- a pump connected to the air separation unit to pump the liquid oxygen stream, thereby to produce a pumped liquid oxygen stream.
- the at least one heat exchanger is positioned between the pump and the booster compressor and is also configured such that the pumped liquid oxygen stream is heated within the at least one heat exchanger through indirect heat exchange with at least the compressed air stream to produce the oxygen product at a supercritical temperature, at which the oxygen product will be a supercritical fluid and the compressed air stream will be a liquid.
- the pump is configured to pump the liquid oxygen stream so that the pumped liquid oxygen stream is pressurized to an oxygen pressure in a range above about 55 bar (a) and no greater than about 150 bar (a) upon entering the heat exchanger.
- the booster compressor is configured to compress the compressed air stream so that the compressed air stream has an air pressure upon entering the at least one heat exchanger equal to a value within a range of no less than ten percent below and no greater than 20 percent above a quantity equal to 0.0003 x (oxygen pressure) 3 - (0.01141 x (oxygen pressure) 2 ) + (2.263 x (oxygen pressure) 2 + 2.5175.
- the at least one heat exchanger can be a first heat exchanger and a second heat exchanger. The first heat exchanger is positioned between the pre- purification unit and the air separation unit and is configured to cool the part of the compressed and purified air stream.
- the second heat exchanger is positioned between the booster compressor and the pump and is configured to cool the compressed air stream and to warm the pumped liquid oxygen stream.
- the indirect heat exchange between the pumped liquid oxygen stream and the air can be conducted in a plate-fin heat exchanger.
- a plate-fin heat exchanger is provided that comprises parting sheets separated by and connected to fins to form at least air passages for a compressed air stream and oxygen passages for a pumped liquid oxygen stream.
- air and oxygen passages are "at least" formed in that, as indicated above, the present invention is equally applicable to a heat exchanger dedicated to the heating of the pumped liquid oxygen.
- a second heat exchanger in the air separation plant discussed above where a second heat exchanger is employed in the so called "banked" design, it can be dedicated to the heating the pumped liquid oxygen stream.
- the fins in at least the air passages have an undulating configuration.
- such a heat exchanger is configured to withstand an oxygen pressure of the pumped liquid oxygen stream in a range above about 55 bar (a) and no greater than about 150 bar (a) upon entering the heat exchanger and an air pressure of the compressed air stream, upon entering the heat exchanger, equal to a value within a range of no less than ten percent below and no greater than 20 percent above a quantity equal to 0.0003 x (oxygen pressure) 3 - (0.01141 x (oxygen pressure) 2 ) + (2.263 x (oxygen pressure) 2 + 2.5175.
- the fins in at least the air passages can be provided with a wavy or undulating configuration such that the flow path of the compressed air through the fins is increased over a straight through plain fin arrangement with the same fin thickness and pitch.
- the undulating configuration can have regular spaced points of maximum amplitude along a length dimension of each of the fins forming peaks and troughs of arcuate configuration.
- the peaks and the troughs are connected by straight segments of each of the fins.
- the wavelengths of the fins are preferably equal to about in a wavelength range no less than about 0.125 inches and no greater than about 1.5 inches.
- the oxygen pressure is at least about 80 bar (a)
- the air passages and the oxygen passages can have an identical configuration.
- the fins have a maximum amplitude greater than a pitch dimension as measured between adjacent fins.
- the fins can have a ratio of transverse thickness to the pitch dimension which is greater than about .4 multiplied by a factor that is equal to the air pressure divided by an allowable tensile stress equal to about the yield stress for a material forming the heat exchanger multiplied by a safety factor of not greater than about 0.5 and no less than about 0.15.
- the heat exchanger in any aspect of the present invention can be of brazed aluminum construction.
- Fig. 1 is a graph of oxygen pressure versus air pressure in accordance with a preferred embodiment of the present invention that also compares such relationship with that shown in the prior art
- Fig. 2 is a schematic diagram of an air separation plant in which an oxygen product is pumped and vaporized;
- FIG. 3 is a heat exchanger in accordance with the present invention
- Fig. 4 is a schematic, sectional view of the heat exchanger shown in Fig. 3 taken along line 3-3 of Fig. 3;
- Fig. 5 is a fragmentary, plan view of an arrangement of fins in the heat exchanger shown in Fig. 3 with portions of such heat exchanger broken away; and [0030] Fig. 6 is a fragmentary, elevational transverse view of Fig. 5.
- the illustrated curve shown in a solid line represents the air pressure required to heat pumped liquid oxygen in accordance with the present invention at a particular oxygen pressure to produce an oxygen product as a result of the pumping and the heating as a supercritical fluid.
- the minimum compression power will be obtained for a particular oxygen pressure .
- the power expended in compressing the air has two components, namely, the pressure to which the air is to be compressed and the flow rate of the air.
- the air pressure and flow rate in turn must be sufficient to heat the oxygen at a specified flow rate and pressure from a pressurized liquid to a supercritical fluid after having passed through a heat exchanger.
- the lower the flow rate of the air the higher the required pressure and vice-versa that is required for a particular flow and pressure of the oxygen.
- the required flow rate of the air will depend upon the flow rate of the oxygen and the design of the particular heat exchanger used. Put another way, the flow rate of the air is dependent on a product of the overall heat transfer coefficient and the heat transfer area ("UA") and the log mean temperature difference. In any heat exchanger, the variation is dependent upon a minimum approach of the heating and cooling curves, known as the "pinch", which optimally should be no less than 1.0 K. When the pinch gets too tight, it becomes difficult to achieve the particular heat exchange desired in that small flow variations will have a large effect on the process.
- air separation plant 1 is an air expanded double column plant that is used to make oxygen and nitrogen products
- the present invention would have application to any air separation plant in which a liquid oxygen product were produced and then pumped to a supercritical pressure.
- oxygen can be produced by air separation plants at a purity ranging from very low purity, about 90 percent by volume to a high purity, above 99 percent by volume oxygen
- the results presented in Figure 1 would not be affected by a measurable amount with respect to oxygen purities of about 90 percent and above.
- the present invention is equally applicable to any compression of air in heating pumped liquid oxygen.
- a stream of liquid oxygen might be obtained from a tank containing the liquid oxygen, such stream would then be pumped and then heated in a heat exchanger in which the compressed air were the heat transfer medium.
- an air stream 10 is compressed by a compressor 12 to produce a compressed air stream 14.
- Compressed air stream 14 is then passed through an after-cooler 16 to remove the heat of compression and is introduced into a prepurification unit 18.
- Prepurification unit 18 removes higher boiling contaminants in the air such as carbon dioxide, water vapor and potentially flammable hydrocarbons.
- the resulting compressed and purified air stream 20 is then divided into first, second and third subsidiary streams 22, 24 and 26.
- First subsidiary stream 22 is fully cooled in a heat exchanger 28 to a temperature suitable for its rectification and then passed into an air separation unit 30 that can consist of a high pressure distillation column thermally linked to a low pressure distillation column to separate the air into an oxygen- rich liquid stream 32 withdrawn from the base of the low pressure column and a nitrogen-rich vapor stream 34 withdrawn from the top of the high pressure column.
- Nitrogen-rich vapor stream 34 can be fully warmed to ambient temperature within heat exchanger 28 and then compressed in a product compressor 36 to produce a nitrogen product stream 38.
- An impure nitrogen stream 40 can be withdrawn from the low pressure column, below the nitrogen-rich vapor stream, and then divided into first and second portions 42 and 44.
- First portion 42 is fully warmed within heat exchanger 28 and a part 44 thereof is used in regenerating adsorbent beds within the prepurification unit 18 and part 46 is discharged as a waste stream.
- the second portion 24 of compressed air stream 20 is compressed in a booster compressor 48 and, after removal of the heat of compression in an after- cooler 50, is partially cooled to a temperature between the warm and cold ends of heat exchanger 28 and is introduced into a turboexpander 52 to produce an exhaust stream 54.
- Exhaust stream 54 could be introduced into the low pressure column to impart refrigeration into the air separation plant 1.
- turboexpander 52 is coupled to compressor 48 to drive the same with the work of expansion. It is also possible that the exhaust stream 54 be introduced into the high pressure column to impart the refrigeration. Nitrogen or waste expansion is also possible .
- Third portion 26 of the compressed air stream 20 is introduced into a booster compressor 56 and, after removal of the heat of compression in an after- cooler 58, forms a compressed air stream 59 that is fully cooled within a heat exchanger 60 into a liquid stream 62.
- the compressed air stream 59 is the compressed stream that is used in heating a pumped liquid oxygen stream 64 that is formed by pumping oxygen-rich liquid stream 32 in a pump 66 and thereby producing an oxygen product stream 68.
- Pumped liquid oxygen stream 64 has a pressure that is above about 55 bar (a) which is above the critical pressure. As such, upon fully warming the pumped liquid oxygen stream 64, the resulting oxygen product stream at ambient temperatures is a supercritical fluid.
- a common heat exchanger could be used. Such a heat exchanger would have no effect on the optimum air pressure calculated on the basis of the data presented in Figure 1.
- the liquid stream 64 is expanded, either in a liquid expander to generate additional refrigeration or in an expansion valve so that the liquid can be introduced into the columns.
- the resulting liquid after expansion could be divided into two portions for introduction into intermediate locations of the high and low pressure columns.
- Second part 44 of the waste stream 40 is fully warmed within heat exchanger 60 and discharged as another waste stream 70.
- second part 44 of waste steam 40 is used to thermally balance the heat exchangers 28 and 60 so that the difference between warm end temperatures of the streams exiting the lower pressure heat exchanger 28 and the higher pressure heat exchanger 68 to inhibit warm end losses of refrigeration by such heat exchangers and also to decrease the temperature difference of the liquid stream 62 and the first portion 22 of the compressed and purified air stream 20 at the cold end of the high pressure heat exchanger 60 and the low pressure heat exchanger 28.
- the temperature difference between the liquid stream 60 and the pumped liquid oxygen stream 64 at the cold end of the higher pressure heat exchanger 60 can be optimized.
- compressed air stream 59 upon entering heat exchanger 60 has a pressure determined in a manner indicated in Figure 1 for a particular pressure of pumped liquid oxygen stream 64. However, in certain circumstances it might be necessary to compress second portion 26 of compressed and purified air stream 20 either above or below the pressure determined in Figure 1.
- the dashed line located above the solid line represents the pressure that is about 20 percent above and the dashed line located below the solid line represents the pressure that is about 10 percent below the air pressure derived from the solid line.
- the efficiency is that of booster compressor 56 and not necessarily that of the entire air separation plant. As mentioned above, roughly 30 percent of the incoming air is sent to compressor 56.
- the exact amount can be balanced with the amount of air sent to booster compressor 48 for purposes of generating refrigeration. For example, if heat exchanger 60 incorporates a more compact design, the warm end temperature difference will be greater requiring an additional amount of refrigeration to be generated. At the same time, however, the more compact heat exchanger would be less expensive to build than a larger heat exchanger. Thus, the pressure selected for booster compressor 56 might under those circumstances be higher than that predicted by the curve shown in Figure 1 given the low flow to booster compressor 56. [0044] An air separation plant having the features of the air separation plant illustrated in Figure 2 was simulated with the use of the UNISIM DESIGN computer program and at a series of oxygen pressures, an air pressure was found for each oxygen pressure that produced a minimum unit power.
- Table 1 shows such calculation for a pumped liquid oxygen stream 64 pumped to 100 bar (a) and a flow rate of 5326 kcfh. As illustrated, the minimum unit power for booster compressor 56 occurs at 138 bar (a) (2000 psia) .
- Table 2 illustrates the effect on the pressure when the UA is varied by about 20 percent from the base case shown in Table 1. Again the minimum unit power for booster compressor 56 is found to be 138 bar (a) (2000 psia) . Table 2
- the oxygen pressure sets the air pressure in accordance with Figure 1.
- a heat exchanger is designed that will accomplish an efficient warm end temperature difference to lower overall power requirements for compressing the air, while balancing the capital cost of the heat exchanger.
- a plate-fin heat exchanger is preferred, other designs could be used such as prior art spiral heat exchangers in connection with Figure 1.
- a brazed aluminum plate-fin heat exchanger is used that unlike prior art high pressure designs that incorporate a straight fin structure, an undulating fin structure is provided for increasing the flow path length generating turbulence and mixing in the flow and thereby to effectuate an efficient heat exchanger design.
- Heat transfer is enhanced with the use of such fins by extension of the flow path length (more heat transfer surface) , breaking of the boundary layer as a result of periodic changes of the flow direction and impingement of the flow on to the neighboring fin surface.
- the intensity of such effects depends on the fin pitch "P", wave length "L”, amplitude "A” and fin thickness "T”.
- the amplitude "A” is less than the fin pitch "P"
- the channel flow path length is not increased, merely roughened. While this will enhance heat transfer somewhat, there will not be the enhancement that exists when amplitude "A” is greater than the pitch "P".
- Heat exchanger 60 is in the form of a brazed aluminum fin heat exchanger.
- Such a heat exchanger has at least a series of oxygen passages 72 for the oxygen to be warmed in the formation of the oxygen product stream 68, air passages 74 for the compressed air stream to be fully cooled into the two-phase stream 62 and nitrogen balance passages 76 for passage of the part 44 of the nitrogen waste stream 40 for thermal balancing purposes.
- Each of the passages is formed between parting sheets 78 and sealed at opposite sides by blocks 80 and 82 at the ends by end blocks that are not illustrated.
- the fins 100 have an undulating configuration in order to impart flow separations to the flow through the passages and therefore a greater heat transfer coefficient.
- the velocity of the flow passing through the undulating fins 100 is selected to produce such flow separations that can either be within a transition between laminar and turbulent flow or at turbulent flow.
- the velocity is selected to produce a Reynolds number of greater than about 400 as defined at a temperature midway between the warm and cold end temperatures of the heat exchanger.
- the fins 100 have a maximum amplitude "A" greater than a pitch dimension "P" as measured between adjacent fins 100.
- the fins having a transverse thickness equal to the pitch dimension "P" which is greater than about .4 multiplied by a factor that is equal to the air pressure of compressed air stream 59 divided by an allowable tensile stress equal to about the yield stress for a material forming the heat exchanger multiplied by a safety factor of not greater than about 0.5 and preferably not less than .15.
- a safety factor of 0.25 is typically used.
- Practical wavelengths "L" of each of the fins 100 is in a wavelength range no less than about 0.125 inches and no greater than about 1.5 inches.
- the fins 100 within the oxygen passages 72 could be made thinner in that such fins would not be subjected to the same degree of stress induced by the compressed air stream 59 in the air passages 74.
- a perforated material to form the fins 100. The perforations provide added turbulence but at the expense of some loss of structural strength.
- fin design to be used in heat exchanger 60 when used in a service discussed with respect to Figure 1 that is a heat exchanger capable of heating oxygen pumped to a pressure of about 100 bar
- such heat exchanger could incorporate fins having a pitch "P" of about 0.038" and a thickness "T" of 0.016".
- the fin height "H” will be in a range of between about 0.1" to about 0.4".
- the maximum allowable tensile stress would be 24 x 10 Pa, which represents the ultimate tensile stress (UTS) multiplied by a safety factor of 0.25.
- the thickness to pitch ratio of the fin would be equal to 0.42. If a fin thickness of 0.020 were used, the corresponding pitch would need to be 0.05" (20 fins per inch) .
- the preferred mode is to use a smaller pitch and corresponding thickness to maintain the ratio thickness to pitch of greater than about .42. This is because the surface area will be higher for higher pitch.
- the same fin design could be used for both the air and the oxygen passages 74 and 72 respectively in case of heat exchanger 60.
- the heat exchanger, for example, heat exchanger 60 would then be designed with respect to the number of layers, the arrangement of layers and the flow area within each of the layers in a manner well known to anyone skilled in the art .
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201080015765.2A CN102439385A (en) | 2009-01-30 | 2010-01-21 | Oxygen production method and apparatus |
EP10701767A EP2404129A2 (en) | 2009-01-30 | 2010-01-21 | Oxygen production method and apparatus |
JP2011548080A JP2012517576A (en) | 2009-01-30 | 2010-01-21 | Oxygen generation method and apparatus |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/363,279 US20100192629A1 (en) | 2009-01-30 | 2009-01-30 | Oxygen product production method |
US12/363,279 | 2009-01-30 | ||
US12/648,775 | 2009-12-29 | ||
US12/648,775 US20100192628A1 (en) | 2009-01-30 | 2009-12-29 | Apparatus and air separation plant |
Publications (2)
Publication Number | Publication Date |
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WO2010088121A2 true WO2010088121A2 (en) | 2010-08-05 |
WO2010088121A3 WO2010088121A3 (en) | 2013-06-13 |
Family
ID=42396291
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2010/021551 WO2010088121A2 (en) | 2009-01-30 | 2010-01-21 | Oxygen production method and apparatus |
Country Status (5)
Country | Link |
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US (1) | US20100192628A1 (en) |
EP (1) | EP2404129A2 (en) |
JP (1) | JP2012517576A (en) |
CN (1) | CN102439385A (en) |
WO (1) | WO2010088121A2 (en) |
Families Citing this family (3)
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US8418472B2 (en) * | 2009-05-22 | 2013-04-16 | General Electric Company | Method and system for use with an integrated gasification combined cycle plant |
US10018412B2 (en) * | 2015-11-09 | 2018-07-10 | Praxair Technology, Inc. | Method and system for providing supplemental refrigeration to an air separation plant |
JP7460973B2 (en) * | 2020-03-05 | 2024-04-03 | 日本エア・リキード合同会社 | air separation equipment |
Citations (3)
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US6430962B2 (en) | 2000-02-23 | 2002-08-13 | Kabushiki Kaisha Kobe Seiko Sho. | Production method for oxygen |
US6951245B1 (en) | 2002-10-01 | 2005-10-04 | L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude | Plate-type heat exchanger comprising a thick fin, and use of such a heat exchanger |
US7219719B2 (en) | 2002-10-01 | 2007-05-22 | Nordon Cryogenie Snc | Fin for a plate heat exchanger, methods for the manufacture of such a fin, and a heat exchanger comprising such a fin |
Family Cites Families (18)
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US4555256A (en) * | 1982-05-03 | 1985-11-26 | Linde Aktiengesellschaft | Process and device for the production of gaseous oxygen at elevated pressure |
US4984686A (en) * | 1989-01-17 | 1991-01-15 | Med-Safe Systems, Inc. | Sharps container closure and needle extractor assembly |
FR2652887B1 (en) * | 1989-10-09 | 1993-12-24 | Air Liquide | PROCESS AND PLANT FOR THE PRODUCTION OF VARIABLE FLOW GAS OXYGEN BY AIR DISTILLATION. |
JP2909678B2 (en) * | 1991-03-11 | 1999-06-23 | レール・リキード・ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード | Method and apparatus for producing gaseous oxygen under pressure |
ATA166091A (en) * | 1991-08-23 | 1996-02-15 | Faigle Heinz Kg | FILLING BODY |
FR2721383B1 (en) * | 1994-06-20 | 1996-07-19 | Maurice Grenier | Process and installation for producing gaseous oxygen under pressure. |
DE19529681C2 (en) * | 1995-08-11 | 1997-05-28 | Linde Ag | Method and device for air separation by low-temperature rectification |
FR2744795B1 (en) * | 1996-02-12 | 1998-06-05 | Grenier Maurice | PROCESS AND PLANT FOR THE PRODUCTION OF HIGH-PRESSURE GASEOUS OXYGEN |
GB2348481A (en) * | 1999-03-27 | 2000-10-04 | Chart Marston Limited | Heat exchanger and/or fluid mixing means with perforated plates |
GB0005374D0 (en) * | 2000-03-06 | 2000-04-26 | Air Prod & Chem | Apparatus and method of heating pumped liquid oxygen |
FR2819048B1 (en) * | 2000-12-28 | 2005-08-19 | Air Liquide | WINDED FIN IN HEAT EXCHANGER WITH FLAT PLATES AND CORRESPONDING HEAT EXCHANGER |
CA2391077A1 (en) * | 2001-06-28 | 2002-12-28 | York International Corporation | High-v plate fin for a heat exchanger and a method of manufacturing |
CA2372399C (en) * | 2002-02-19 | 2010-10-26 | Long Manufacturing Ltd. | Low profile finned heat exchanger |
US6834515B2 (en) * | 2002-09-13 | 2004-12-28 | Air Products And Chemicals, Inc. | Plate-fin exchangers with textured surfaces |
FR2865027B1 (en) * | 2004-01-12 | 2006-05-05 | Air Liquide | FIN FOR HEAT EXCHANGER AND HEAT EXCHANGER PROVIDED WITH SUCH FINS |
JP2006125767A (en) * | 2004-10-29 | 2006-05-18 | Tokyo Institute Of Technology | Heat exchanger |
US20070095100A1 (en) * | 2005-11-03 | 2007-05-03 | Rankin Peter J | Cryogenic air separation process with excess turbine refrigeration |
US9222725B2 (en) * | 2007-06-15 | 2015-12-29 | Praxair Technology, Inc. | Air separation method and apparatus |
-
2009
- 2009-12-29 US US12/648,775 patent/US20100192628A1/en not_active Abandoned
-
2010
- 2010-01-21 JP JP2011548080A patent/JP2012517576A/en active Pending
- 2010-01-21 EP EP10701767A patent/EP2404129A2/en not_active Withdrawn
- 2010-01-21 WO PCT/US2010/021551 patent/WO2010088121A2/en active Application Filing
- 2010-01-21 CN CN201080015765.2A patent/CN102439385A/en active Pending
Patent Citations (3)
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US6430962B2 (en) | 2000-02-23 | 2002-08-13 | Kabushiki Kaisha Kobe Seiko Sho. | Production method for oxygen |
US6951245B1 (en) | 2002-10-01 | 2005-10-04 | L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude | Plate-type heat exchanger comprising a thick fin, and use of such a heat exchanger |
US7219719B2 (en) | 2002-10-01 | 2007-05-22 | Nordon Cryogenie Snc | Fin for a plate heat exchanger, methods for the manufacture of such a fin, and a heat exchanger comprising such a fin |
Non-Patent Citations (1)
Title |
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W.F. CASTLE: "89 AIChE Symposium Series", vol. 294, BOC PROCESS PLANTS, article "Modern Liquid Pump Oxygen Plants: Equipment and Performance", pages: 14 |
Also Published As
Publication number | Publication date |
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US20100192628A1 (en) | 2010-08-05 |
CN102439385A (en) | 2012-05-02 |
WO2010088121A3 (en) | 2013-06-13 |
EP2404129A2 (en) | 2012-01-11 |
JP2012517576A (en) | 2012-08-02 |
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