WO2010082772A3 - 고순도 부탄올 제조 공정 - Google Patents

고순도 부탄올 제조 공정 Download PDF

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Publication number
WO2010082772A3
WO2010082772A3 PCT/KR2010/000237 KR2010000237W WO2010082772A3 WO 2010082772 A3 WO2010082772 A3 WO 2010082772A3 KR 2010000237 W KR2010000237 W KR 2010000237W WO 2010082772 A3 WO2010082772 A3 WO 2010082772A3
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WO
WIPO (PCT)
Prior art keywords
butanol
high purity
preparing high
butanoic acid
separated
Prior art date
Application number
PCT/KR2010/000237
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English (en)
French (fr)
Other versions
WO2010082772A2 (ko
Inventor
장종산
이정호
황영규
하종욱
이승환
김형록
황동원
Original Assignee
한국화학연구원
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 한국화학연구원 filed Critical 한국화학연구원
Publication of WO2010082772A2 publication Critical patent/WO2010082772A2/ko
Publication of WO2010082772A3 publication Critical patent/WO2010082772A3/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/16—Butanols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

본 발명은, (1) 미생물을 이용하여 바이오매스를 발효하는 단계, (2) (1)에서 수득된 발효액으로부터 n-부탄산을 분리하는 단계, (3) (2)에서 분리한 n-부탄산을 루테늄계 수소화 촉매 또는 구리계 나노복합체 촉매 상에서 수소에 의하여 직접 기상 환원시키는 단계, 및 (4) 수소화에 의해 얻어진 부탄올의 증류에 의한 부탄올 정제를 포함하는, 고선택성 및 고생산성을 나타내는 고순도 부탄올의 제조 방법 및 이를 구현하기 위한 수소화 촉매를 제공하는 것이다.
PCT/KR2010/000237 2009-01-15 2010-01-15 고순도 부탄올 제조 공정 WO2010082772A2 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2009-0003481 2009-01-15
KR20090003481 2009-01-15

Publications (2)

Publication Number Publication Date
WO2010082772A2 WO2010082772A2 (ko) 2010-07-22
WO2010082772A3 true WO2010082772A3 (ko) 2010-11-04

Family

ID=42340210

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/000237 WO2010082772A2 (ko) 2009-01-15 2010-01-15 고순도 부탄올 제조 공정

Country Status (2)

Country Link
KR (1) KR101177565B1 (ko)
WO (1) WO2010082772A2 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11201504817RA (en) * 2012-12-21 2015-07-30 Ee Terrabon Biofuels Llc System and process for obtaining products from biomass
CN107076714B (zh) * 2014-10-22 2019-12-10 朗泽科技新西兰有限公司 气体测试单元和方法
KR20220110945A (ko) * 2021-02-01 2022-08-09 한화솔루션 주식회사 이종금속 수소화 촉매의 제조 방법
KR102384964B1 (ko) 2021-10-29 2022-04-08 부경대학교 산학협력단 1-헵탄올 추출에 의한 분리 효율이 높은 부탄올 분리장치 및 이 장치를 이용한 부탄올의 분리방법
KR20240105321A (ko) * 2022-12-28 2024-07-05 한화솔루션 주식회사 수소화 반응용 촉매

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5426246A (en) * 1993-07-27 1995-06-20 Arakawa Chemical Industries, Ltd. Catalyst for direct reduction of carboxylic acid, process for preparation thereof and process for preparation of alcohol compound using the catalyst
US5658843A (en) * 1994-01-20 1997-08-19 Kao Corporation Method for preparing copper-containing hydrogenation reaction catalyst and method for producing alcohol
US6495730B1 (en) * 1999-09-21 2002-12-17 Asahi Kasei Kabushiki Kaisha Catalysts for hydrogenation of carboxylic acid
US20080248540A1 (en) * 2007-04-03 2008-10-09 The Ohio State University Methods of producing butanol

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4380654B2 (ja) 2005-04-22 2009-12-09 三菱化学株式会社 ポリエステル及びその製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5426246A (en) * 1993-07-27 1995-06-20 Arakawa Chemical Industries, Ltd. Catalyst for direct reduction of carboxylic acid, process for preparation thereof and process for preparation of alcohol compound using the catalyst
US5658843A (en) * 1994-01-20 1997-08-19 Kao Corporation Method for preparing copper-containing hydrogenation reaction catalyst and method for producing alcohol
US6495730B1 (en) * 1999-09-21 2002-12-17 Asahi Kasei Kabushiki Kaisha Catalysts for hydrogenation of carboxylic acid
US20080248540A1 (en) * 2007-04-03 2008-10-09 The Ohio State University Methods of producing butanol

Also Published As

Publication number Publication date
KR101177565B1 (ko) 2012-08-28
WO2010082772A2 (ko) 2010-07-22
KR20100084131A (ko) 2010-07-23

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