WO2010082062A2 - Acoustic markers - Google Patents
Acoustic markers Download PDFInfo
- Publication number
- WO2010082062A2 WO2010082062A2 PCT/GB2010/050058 GB2010050058W WO2010082062A2 WO 2010082062 A2 WO2010082062 A2 WO 2010082062A2 GB 2010050058 W GB2010050058 W GB 2010050058W WO 2010082062 A2 WO2010082062 A2 WO 2010082062A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acoustic
- shell
- reflector
- core
- reflected
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G10—MUSICAL INSTRUMENTS; ACOUSTICS
- G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
- G10K11/00—Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/18—Methods or devices for transmitting, conducting or directing sound
- G10K11/20—Reflecting arrangements
- G10K11/205—Reflecting arrangements for underwater use
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01S—RADIO DIRECTION-FINDING; RADIO NAVIGATION; DETERMINING DISTANCE OR VELOCITY BY USE OF RADIO WAVES; LOCATING OR PRESENCE-DETECTING BY USE OF THE REFLECTION OR RERADIATION OF RADIO WAVES; ANALOGOUS ARRANGEMENTS USING OTHER WAVES
- G01S1/00—Beacons or beacon systems transmitting signals having a characteristic or characteristics capable of being detected by non-directional receivers and defining directions, positions, or position lines fixed relatively to the beacon transmitters; Receivers co-operating therewith
- G01S1/72—Beacons or beacon systems transmitting signals having a characteristic or characteristics capable of being detected by non-directional receivers and defining directions, positions, or position lines fixed relatively to the beacon transmitters; Receivers co-operating therewith using ultrasonic, sonic or infrasonic waves
- G01S1/76—Systems for determining direction or position line
- G01S1/82—Rotating or oscillating beam beacons defining directions in the plane of rotation or oscillation
Definitions
- WO2006/075167 and WO2009/122184 (both the Secretary of State for Defense and both incorporated herein by reference) describe, inter-alia, acoustic reflectors which can be used in a variety of ways to mark underwater structures, objects or geological features.
- GB Patent Applications 0913203.6, 0913388.5 and 0917714.8 (all Subsea Asset Location Technologies Limited and incorporated herein by reference) describe and claim further acoustic reflectors.
- These applications describe an acoustic reflector comprising a shell surrounding a core, said shell being capable of transmitting acoustic waves incident on the surface of the shell into the core to be focused and reflected from an area of the shell located opposite to the area of incidence so as to provide a reflected acoustic signal output from the reflector, having a core in which the shell is dimensioned relative to the core such that a portion of the acoustic waves incident on the shell wall are coupled into the shell and guided therein around the circumference of the shell and then re-radiated to combine constructively with the said reflected acoustic signal output so as to provide an enhanced reflected acoustic signal output in which the ratio of the speed of the wave transmission in the core to the speed of the wave transmission in the shell is in the range of about 3:1 and
- reflectors are normally omni-directional, and can provide little information about the specific reflector concerned, its environment or the relative position of the source of acoustic waves with respect to the reflector.
- an acoustic reflector comprises a shell around a core, portions at least of said shell being capable of transmitting acoustic waves incident on the shell into the core to be focused and reflected from an area of the shell located opposite to the area of incidence of the acoustic waves so as to provide a reflected acoustic signal output from the reflector, and in which incident acoustic radiation will be differentially reflected depending on the portion of the reflector on which the incident acoustic radiation impinges.
- the acoustic reflector is in the form of an object of rotation about a central axis, so that it can be mounted and turned, or allowed to turn to provide a pulsed reflection at one or more different frequencies which are characteristic of the reflector or its environment.
- Suitable reflector shapes include spheres, right cylinders, right cones, or ovoids.
- the acoustic reflector has a core material having a compressional wave speed of from 840 to 1500 ms 1 and a shell dimensioned relative to the core such that a portion of the acoustic waves incident on portions of the shell are coupled into the shell and guided therein around the circumference of the shell and then re-radiated to combine constructively with the said reflected acoustic signal output to provide an enhanced reflected acoustic signal output.
- the shell is dimensioned relative to the core such that a portion of the acoustic waves incident on at least one portion of the shell are coupled into the shell wall and guided therein around the circumference of the shell and then re-radiated to combine constructively with the said reflected acoustic signal output to provide an enhanced reflected acoustic signal output.
- an acoustic reflector comprises a shell surrounding a core, said shell being capable of transmitting acoustic waves incident on the surface of the shell into the core to be focused and reflected from an area of the shell located opposite to the area of incidence so as to provide a reflected acoustic signal output from the reflector, having a core in which the shell is dimensioned relative to the core such that a portion of the acoustic waves incident on the shell wall are coupled into the shell and guided therein around the circumference of the shell and then re-radiated to combine constructively with the said reflected acoustic signal output so as to provide an enhanced reflected acoustic signal output in which the ratio of the speed of the wave transmission in the core to the speed of the wave transmission in the shell is in the range of about 3:1 and 3.2: 1, inclusive, or a harmonic thereof.
- the core of the acoustic reflector may be formed of one or more concentric layers of a solid material.
- the core has parallel layers of materials having different compressional wave speeds.
- part of the surface of the shell is covered by an acoustic absorbing material that will absorb incident acoustic at frequencies at which the reflector would otherwise be reflective.
- the acoustic reflector is a right cylinder
- the acoustic absorbing material is can be arranged in parallel strips on the surface of the cylinder parallel to the central axis of the cylinder. Rotation to the cylinder will proved a reflected acoustic wave characteristic of the width and separation of the strips and the speed of rotation.
- the acoustic reflector is a sphere in which the acoustic absorbing material is arranged in segment s on its surface.
- the core can be formed from one or more elastomer material, by having different elastomer materials in different layers of a core, the physical behaviour of the core in different areas will differ for different acoustic frequencies.
- parts of the core can respond to an transport an acoustic wave at one frequency that will combine constructively with a portion of the same wave that has been transmitted around the shell, but other parts will transport the wave in a way that will recombine destructively at the same frequency with the portion that has been transmitted around the shell wall, and thus little or not reflection is obtained.
- the reflected signal, and the frequency at which a reflected signal is obtained can provide information about the spatial relationship between the source of the signal and the reflector.
- Suitable materials for the core can include silicone rubbers such as an RTV12 or
- the shell is may be formed from a rigid material. Steel is possible as is glass reinforced plasties (GRP) or glass filled polyamide or glass filled nylon.
- GRP glass reinforced plasties
- the core material may be metal with a metallic shell provided that the ratio of the speed of the wave transmission in the core to the speed of the wave transmission in the shell is in the range of about 3:1 and 3.2:1, inclusive, or a harmonic thereof.
- an acoustic reflector is shaped in such a way that incoming acoustic waves impinging on parts of the surface will be scattered and not reflected.
- a right cone an example of such a shape, acoustic waves directed at the point will be scattered, simply acoustic waves directed at the base will be scattered, the same will occur on the inclined sides of the cone nearest the point and base, however incoming acoustic waves impinging on the middle portion of the inclined sides will be reflected.
- An ovoid shape will work in a similar way.
- Devices of this invention can be used as markers to indicate specific directions to approach underwater objects, to help in final navigation towards an object or to provide directional information.
- an underwater valve may be marked with a reflector of this invention.
- the pipeline to which the valve is connected may be marked more generally with omni-directional reflectors to indicate to a submersible its position.
- the directional reflector attached to the valve can be used by the submersible to indicate the correct direction from which to approach the valve safely.
- Another application of the devices of this invention would be to provide an underwater "lighthouse”. If a reflector capable of reflecting acoustic signals in one or more specific directions is rotatably mounted and powered or fitted with a fin to cause it to rotate in a marine current, it will reflect a pulsing signal when interrogated acoustically. The rate of rotation or the position of the absorbent materials will give the reflected acoustic signals a particular pulsed characteristic by which the reflector concerned can be identified. As in a "lighthouse” the characteristic can be used to give location information.
- Another application of this invention would be to mark the sites of underwater channels or passages between fixed objects, say, wrecks or underwater cliff.
- the characteristics of the reflectors on one side of the channel can be different from those on the other side to act in a similar way as red and green lights on buoys marking sea channels,
- Figure 1 illustrates the principles of an acoustic reflector of a kind used in the present invention
- Figure 2 is a schematic representation of a cross section through a development of an acoustic reflector of a kind used in this invention showing some acoustic paths through the reflector core;
- Figure 3 is a graph of target strength against frequency for two different reflectors of the kind shown in figure 2 showing the effect of different thicknesses of shell wall on the frequency response;
- Figure 4 shows a spherical reflector according to the invention with a reflection exclusion zone
- Figures 5 and 6 show similar spherical reflectors mounted to rotate and to provide pulses of reflected acoustic signals when interrogated by a narrow beam acoustic source;
- Figure 7 shows another spherical reflector according to the invention.
- Figure 8 shows a cylindrical reflector according to the invention.
- Figure 9 shows a further cylindrical reflector according to the invention designed to reflect acoustic signals at different frequencies according to the part of the surface on which the acoustic signal impinges.
- an acoustic reflector 10 comprises a spherical shell 12.
- the shell 12 surrounds a core 16.
- the shell 12 is formed from a rigid material such as a glass reinforced plastics (GRP) material or steel.
- the core 16 is formed from a solid material such as an elastomer.
- the frequency, or range of frequencies, at which the acoustic reflector is applicable is dependent on predetermined combinations of materials, used to form the shell and core, and the relative dimensions thereof.
- the materials which form the shell 12 and the core 16 and the relative dimensions of the shell and core are predetermined such that the transit time of the shell wave 26 is the same as the transit time of the internal geometrically focused returning wave (i.e. the reflected acoustic signal output 22). Therefore, the contributions of the shell wave, which is re-radiated into the fluid, and the reflected acoustic signal output are in phase with each other and therefore combine constructively at a frequency of interest to provide an enhanced reflected acoustic signal output (i.e. high target strength).
- the circumference of the shell is the path length and therefore must be dimensioned in accordance with the respective transmission speed properties of the shell and the core, such that resonant standing waves are formed in the shell which are in phase with the reflected acoustic signal output to combine constructively therewith.
- the core is formed from a single solid material having a wave speed between 840 ms 1 and 1300 ms 1 .
- the core may comprise two or more layers of different materials where, for a particular selected frequency of the acoustic waves, these would provide either more effective focussing of the incoming waves and/or lower attenuation within the material so as to result, overall, in a stronger output signal.
- the complexity and costs of manufacture in the case of a layered core would be expected to be greater.
- the core is formed of two or more layers of different materials, either or both of the materials may have a wave speed of up to 1500ms 1 .
- the core material must be such that it exhibits a wave speed in the required range without suffering from a high absorption of acoustic energy.
- the core may be formed from an elastomer material such as, for example, a silicone, particularly RTV12 or RTV655 silicone rubbers from Bayer or Alsil 14401 peroxide-cured silicone rubbers.
- the shell may be formed of a rigid material, such as, for example, a glass reinforced plastics (GRP) material, particularly a glass filled nylon such as 50% glass filled Nylon 66, "Zytel” ® - 33% glass reinforced nylon, or 40% glass filled semi-aromatic polyamide, or steel and may be dimensioned such that its thickness is approximately one-tenth of the radius of the core.
- GRP glass reinforced plastics
- an acoustic reflector 10 comprises a spherical shell 12.
- the shell 12 surrounds a core 16.
- the shell 12 is formed from a rigid material such as a glass reinforced plastics (GRP) material or steel.
- the core 16 is formed from a solid material such as an elastomer.
- Acoustic waves 18, transmitted from an acoustic source are incident as shown on the shell 12.
- the properties of the shell are selected in the manner previously described such that it exhibits two regions disposed around lines of latitude of the shell which act as transmission "windows", i.e. such that the incident acoustic waves are in these regions efficiently transmitted through the shell 12 and into the core 16. Consequently the incident acoustic waves then follow two paths (19, 19') as they travel through the core 16 and are refracted and thereby focused onto an area 20 of the opposing side of the shell from the side on which the acoustic waves 18 are incident. The waves are then reflected back, along the same respective paths and combine together to provide an enhanced reflected acoustic signal output 22 of the reflector.
- a portion of the incident waves 18 is coupled into the shell 12 and generates elastic waves 26 which are guided within the shell 12 around the circumference of the shell 12.
- the materials which form the shell 12 and the core 16 and the relative dimensions of the shell and core are predetermined such that the transit time of the shell wave 26 is the same as the transit time of the internal geometrically focused returning waves (19, 19')
- the elastic wave travelling through the shell wall and the reflected acoustic signal output are in phase with each other and therefore combine constructively at a frequency of interest to provide a further enhanced reflected acoustic signal output 22 (i.e. a strong target response).
- Figure 3 shows the spectral response for two different reflectors having the same core and shell properties as for the reflector of Figure 2 and an external radius of 210mm but where the ratio of internal to external radii have different values (0.942 (heavy line) and 0.838 (light line) respectively, corresponding to shell thicknesses of 12mm and 34mm).
- reflectors having different shell thickness results in reflectors have quite markedly different spectral responses. Further variation may be obtained by changing the material properties of the inner core and/or the outer shell of the reflector.
- an acoustic reflector 10 of the find shown in figure 2 comprises the sphere having a shell 12 and core 16 made of elastomer materials as described in figure 2. Portions 25 of the outside of the shell skin are coated with an acoustic absorbing material 28.
- the material can be any one of a number of acoustic absorbing materials ranging from polystyrene foam, syntactic foam and rubber to more sophisticated materials such as used to coat submarines.
- slots or windows 29 are defined in the shell through which incoming acoustic signals 18 will be transmitted to the core 16 and around the shell itself as described with reference to figures 1 and 2. Between the windows 29 the acoustic absorbing material 28, making the portions 25 essentially deaf to incoming acoustic signals, and no reflection of signals directed at the portions 25 will occur.
- the device of figure 4 has the acoustic reflecting materials arranged as regular segments 28 on the surface of the reflector and is rotated using a motor 30 connected to its central axis 32.
- the segments 28 are about the central axis 32.
- the size of the slots or windows 29 and the speed of rotation of the reflector 10 and the repeat frequency of the sonar characterise the nature of the emitted acoustic wave 22 (in the same way as flashing lights on lighthouses).
- the rate of rotation and the repeat frequency of the sonar are synchronised, nothing will be reflected.
- the rate of flashing can be used to identify the particular reflector concerned.
- Figure 6 shows a similar arrangement that figure of figure 5, but in this instance the reflector is rotatably mounted on a pivot 36.
- a fin 34 mounted on the central axis, but opposite the pivot 36 is acted on by underwater currents 38 to turn the reflector.
- This device can be used for direction finding, but variations in current speed may make accurate identification of the reflector concerned less reliable. Instead such a device could be used to provide information about current speeds, particularly when these are critical to underwater activities or safety.
- FIG 7 a similar output to the device of figure 4 obtained by constructing the reflector 10 with a shell 12 constructed of varying thicknesses.
- the shell 12 has areas of three different thicknesses 34, 36 and 38, these areas being disposed around the inside of the shell in opposing pairs (74 and 74', 76 and 76', and 78 and 78').
- the area 74 may form a deaf portion to certain frequencies whereas for other frequencies it will be a window, and similarly of the other areas. It can be seen therefore that is possible to construct a reflector where different portions of the shell present reflections at frequencies.
- the reflected acoustic will be characteristic of the area of the shell that the acoustic wave impinged.
- the presence of a response or not will be indicative of the relative position and orientation of the reflector to the source of the acoustic signal.
- the angle to which it is necessary to steer the beam to get a response will provide considerable relative position information.
- the acoustic reflector 10 comprises a right cylinder 80.
- the cylinder is mounted on its central axis 32 to motor 30.
- the cylinder itself comprises a cylindrical shell 12 and core 16.
- the outer surface of the shell 12 has a series of parallel longitudinal strips of acoustic absorbing material 28 thereon each strip also parallel to the central axis. This material would be of the same kind that might be used in the example of figure 4. Between the strips of acoustic absorbing material 28, slots or windows 29 occur in the shell 12 through which incident acoustic waves may be reflected.
- an acoustic reflector 10 comprises a right cylinder 80 with a shell 12.
- the core 16 comprises layers 92, 94, and 96 of elastomer material.
- the elastomer material in the layers is of different densities.
- the layer 94 extends across the axis of the cylinder will transmit certain acoustic frequencies but not others. It will be seen that an incoming acoustic wave impinging on areas the shell 12 adjoining the layer 94, if at the frequencies to which layer 94 responds will be reflected by the cylinder as previously described. However, acoustic wave at other frequencies will not be reflected.
- acoustic waves impinging on the areas of the shell outside layers 92 and 96 may be reflected or not depending on the response of these layers to the frequency concerned and on whether the acoustic wave can cross the middle band 94.
- Such reflectors again can provide guidance information, by arranging for relatively weak reflections from the areas of the shell outside layers 92 and 96, but a very strong reflection from the areas of the shell around the layer 94. This can be useful particularly for under-water navigation and direction finding, giving an indication of whether the acoustic source is in a desired alignment or not with the reflector. If three different kind of reflection came depending on the area of the shell interrogated, in effect an acoustic system akin to optical landing lights can be obtained.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Multimedia (AREA)
- General Physics & Mathematics (AREA)
- Remote Sensing (AREA)
- Radar, Positioning & Navigation (AREA)
- Computer Networks & Wireless Communication (AREA)
- Transducers For Ultrasonic Waves (AREA)
- Measurement Of Velocity Or Position Using Acoustic Or Ultrasonic Waves (AREA)
- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
- Obtaining Desirable Characteristics In Audible-Bandwidth Transducers (AREA)
- Building Environments (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2748884A CA2748884A1 (en) | 2009-01-16 | 2010-01-15 | Acoustic markers |
JP2011545801A JP2012515364A (en) | 2009-01-16 | 2010-01-15 | Acoustic marker |
SG2011051141A SG172994A1 (en) | 2009-01-16 | 2010-01-15 | Acoustic markers |
GB1110673.9A GB2477711B (en) | 2009-01-16 | 2010-01-15 | Acoustic Markers |
CN2010800044762A CN102282607B (en) | 2009-01-16 | 2010-01-15 | Acoustic markers |
EP10702161A EP2387784A2 (en) | 2009-01-16 | 2010-01-15 | Acoustic markers |
AU2010205518A AU2010205518A1 (en) | 2009-01-16 | 2010-01-15 | Acoustic markers |
RU2011133882/28A RU2011133882A (en) | 2009-01-16 | 2010-01-15 | ACOUSTIC MARKERS |
BRPI1007503A BRPI1007503A2 (en) | 2009-01-16 | 2010-01-15 | acoustic reflector. |
US13/067,996 US8547780B2 (en) | 2009-01-16 | 2011-07-14 | Acoustic markers |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0900668.5 | 2009-01-16 | ||
GB0900668A GB0900668D0 (en) | 2009-01-16 | 2009-01-16 | Acoustic markers |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2010/051161 Continuation-In-Part WO2011012877A2 (en) | 2009-01-16 | 2010-07-16 | Acoustic reflectors |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/067,996 Continuation-In-Part US8547780B2 (en) | 2009-01-16 | 2011-07-14 | Acoustic markers |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010082062A2 true WO2010082062A2 (en) | 2010-07-22 |
WO2010082062A3 WO2010082062A3 (en) | 2011-03-24 |
Family
ID=40433382
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2010/050058 WO2010082062A2 (en) | 2009-01-16 | 2010-01-15 | Acoustic markers |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2387784A2 (en) |
JP (1) | JP2012515364A (en) |
CN (1) | CN102282607B (en) |
AU (1) | AU2010205518A1 (en) |
BR (1) | BRPI1007503A2 (en) |
CA (1) | CA2748884A1 (en) |
GB (2) | GB0900668D0 (en) |
RU (1) | RU2011133882A (en) |
SG (1) | SG172994A1 (en) |
WO (1) | WO2010082062A2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2460154B1 (en) * | 2009-07-29 | 2015-09-09 | Subsea Asset Location Technologies Limited | Acoustic reflectors |
CN109599089A (en) * | 2018-11-21 | 2019-04-09 | 中国人民解放军海军工程大学 | A kind of underwater sound corner reflector with foam layer |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006075167A1 (en) | 2005-01-14 | 2006-07-20 | The Secretary Of State For Defence | An acoustic reflector |
WO2009122184A2 (en) | 2008-04-02 | 2009-10-08 | The Secretary Of State For Defence | Tunable acoustic reflector |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3599747A (en) * | 1968-12-16 | 1971-08-17 | Palle G Hansen | Spherical reflector |
DE2855207C2 (en) * | 1978-12-21 | 1980-04-10 | Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt | Sonar reflector |
US5822272A (en) * | 1997-08-13 | 1998-10-13 | The United States Of America As Represented By The Secretary Of The Navy | Concentric fluid acoustic transponder |
GB2437016B (en) * | 2005-01-14 | 2008-05-28 | Secr Defence | An acoustic reflector |
WO2007093002A1 (en) * | 2006-02-16 | 2007-08-23 | Ecobuoy Pty Ltd | Sonar accessory & method |
-
2009
- 2009-01-16 GB GB0900668A patent/GB0900668D0/en not_active Ceased
-
2010
- 2010-01-15 AU AU2010205518A patent/AU2010205518A1/en not_active Abandoned
- 2010-01-15 SG SG2011051141A patent/SG172994A1/en unknown
- 2010-01-15 EP EP10702161A patent/EP2387784A2/en not_active Withdrawn
- 2010-01-15 CA CA2748884A patent/CA2748884A1/en not_active Abandoned
- 2010-01-15 WO PCT/GB2010/050058 patent/WO2010082062A2/en active Application Filing
- 2010-01-15 BR BRPI1007503A patent/BRPI1007503A2/en not_active Application Discontinuation
- 2010-01-15 GB GB1110673.9A patent/GB2477711B/en not_active Expired - Fee Related
- 2010-01-15 JP JP2011545801A patent/JP2012515364A/en active Pending
- 2010-01-15 CN CN2010800044762A patent/CN102282607B/en not_active Expired - Fee Related
- 2010-01-15 RU RU2011133882/28A patent/RU2011133882A/en not_active Application Discontinuation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006075167A1 (en) | 2005-01-14 | 2006-07-20 | The Secretary Of State For Defence | An acoustic reflector |
WO2009122184A2 (en) | 2008-04-02 | 2009-10-08 | The Secretary Of State For Defence | Tunable acoustic reflector |
Also Published As
Publication number | Publication date |
---|---|
BRPI1007503A2 (en) | 2016-02-16 |
GB2477711A (en) | 2011-08-10 |
EP2387784A2 (en) | 2011-11-23 |
CN102282607B (en) | 2012-11-21 |
GB0900668D0 (en) | 2009-02-25 |
GB2477711B (en) | 2012-12-12 |
GB201110673D0 (en) | 2011-08-10 |
AU2010205518A1 (en) | 2011-07-21 |
WO2010082062A3 (en) | 2011-03-24 |
CA2748884A1 (en) | 2010-07-22 |
CN102282607A (en) | 2011-12-14 |
RU2011133882A (en) | 2013-02-27 |
SG172994A1 (en) | 2011-08-29 |
JP2012515364A (en) | 2012-07-05 |
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