WO2010070286A1

WO2010070286A1 - Fibre reinforced theromplastic composite tubes

Info

Publication number: WO2010070286A1
Application number: PCT/GB2009/002900
Authority: WO
Inventors: Michael James Dewhirst
Original assignee: Crompton Technology Group Ltd.
Priority date: 2008-12-18
Filing date: 2009-12-17
Publication date: 2010-06-24
Also published as: GB0822996D0; US20110281052A1; EP2376272B1; EP2376272A1

Abstract

A method of forming a fibre reinforced thermoplastic composite tube (P) in which reinforcing fibres (10 ) and thermoplastic resin matrix material (12) are placed around a mandrel (M) to provide a composite tubular pre-form (20) on the mandrel (M) which is then passed through a heated die (30) to compact and reduce the diameter of the pre-form (20) and change the state of matrix, the mandrel (M) with the formed tube (P) thereon exiting the die and the now formed tube (P) is removed from the mandrel, the composite tubular pre-form (20) being produced by winding reinforcment fiber (10) and thermoplastic fiber (11) onto the mandrel, the thermoplastic matrix being caused to flow and then solidify on cooling.

Description

Fibre Reinforced Theromplastic Composite Tubes

Field

This invention relates to a method of forming fibre reinforced thermoplastic composite tubes by placement of fibres and resin matrix onto a mandrel and further processing the composite materials insitu .

Background of the Invention

It is well known to manufacture reinforced composite shafts or tubes by winding resin fibres impregnated with a thermosetting resin such as an epoxy resin, sometimes in the form of a tape, around a mandrel and then curing the fibre/resin composite on the mandrel. It is also known from WO-A-9218559 to impregnate glass fibres with a thermoplastic material and then wind the impregnated glass fibres around a mandrel and heat the windings to fuse the thermoplastic polymer resin.

Elongated fibre and thermosetting resin composites are also formed by a pultrusion process as is illustrated in US-A-4943338, and US 4673,541 in which impregnated fibres are drawn through an elongated die and the resin is substantially set within y the die. A similar process is described in GB-A-1275379- which describes reinforcing a thermoplastic pipe by applying a layer of fibrous material to the cold pipe and then pulling the pipe through a tapered sleeve cold forming the pipe and layer to a smaller diameter. The pipe is then heated to soften the thermoplastic material so that the softened plastic is forced between the fibres as the pipe is pulled through a heated former.

The present invention provides a method of forming a fibre reinforced resin composite which is particularly useful for forming tubular thermoplastic composite components.

Statements of Invention

A first aspect of the present invention is provided by a method of forming a fibre reinforced composite tube or pipe in which reinforcing fibres and resin matrix material are formed around a mandrel to provide a composite tubular pre-form on the mandrel, the mandrel with the perform thereon is then passed through a heated die to compact and reduce the diameter of the pre-form and change the state of matrix, the mandrel with the formed tube thereon exiting the die and the now formed tube is removed from the mandrel, the reinforcing fibres being helically wound around the mandrel characterised in that the reinforced thermoplastic composite tube is formed by winding a tubular pre-form of reinforcement fibre and thermoplastic fibre onto the mandrel , the thermoplastic fibre being caused to flow and solidify on cooling to form the matrix.

The mandrel may be pushed or pulled through the die as is desired. Fibre reinforced thermoplastic tube may be formed by mixing the reinforcment fibres with thermoplastic fibres and then winding the mixed fibrous material onto the mandrel using a conventional filament winding machine but with no wet-out system, the thermoplastic fibres being softened in the heated die and caused to flow and form the resin matrix during compaction.

The ratio of reinforcment fibre and thermoplastic filaments co-wound is approximately 40%-60% (by volume). The pre-form is compacted in the die such that the finished composite tube preferably has a Fibre Volume Fraction of 60- 70%, and preferably about between 55%-65%.

The mandrel may be passed through a heated die having a plurality of heat zones of increasing temperature including a zone having temperature higher than the melting point of the thermoplastic fibres. The formed tube then exits the die via a cooling zone.

The reinforcement fibre may be supplied as a rovtog orr a spool with either no ^izing or a thermoplastic specific sizing. The thermoplastic fibres matrix may be supplied in a multifilament form δn a spool.

According to a second aspect of the present invention, there is provided a fibre reinforced thermoplastic resin composite tube or pipe, which is formed by a method in accordance with the first aspect of the Invention. Typical reinforcement fibres comprise at least one of E-glass, S-glass, Aramid, Quartz, Ceramic, polymer fibre, a liquid crystal polymer fibre , any one of a range of carbon fibres, or a mixture thereof.

The matrix could be any thermoplastic, preferably one of PEI (polyetherimide), PPS ( Polyphenylenesulpone), PAI (Polyamide-imide), PES (polyethersulphone) and more preferably PEEK (Polyetheretherketone). Other additives may be supplied separately or as part of the reinforcing fibre and/or matrix ravings. These additives may be used to impart specific mechanical or physical properties to the composite, for example increased resistance to impact or electrical conductivity.

Description of the Drawings

The Invention will be described by way of Example and with reference to the accompanying drawings in which:

Fig.1 is a schematic view of the forming of the wound composite pre-form onto the mandrel, in accordance with the invention, Fig. 2 shows a fisrt stage in heating and compaction of the pre-form on the mandrel and Fig.3 shows a second stage in the heating and compaction process, and

Fig 4 shows a section of a composite tube formed in accordance with the present invention. Detailed Description of the Invention

With reference to Fig. 1 of the drawings, there is illustrated a winding process for manufacturing a composite tube or pipe P having a thermoplastic matrix (Fig.4). Continuous reinforcing fibres 10 in this example S glass or Carbon fibre and continuous length thermoplastic fibres or filaments 11 , in this example PEEK , which form the resin matrix 12 of the pipe body, are provided on spools S1 and S2 respectively which are typically housed in a creel. During the winding process the reinforcement fibre 10 and the matrix filaments 11 will be mounted on tensioners T1 and T2 respectively at the rear of a winding machine W. The two fibrous materials 10 & 11 will pass over a series of pins and rollers, schematically shown as rollers R1 and R2 to allow the tows or bundles of fibres 10 and filaments 11 to be spread. The reinforcement fibres 10 and matrix filaments 11 will be kept separate over their own sets of rollers and pins R during the spreading process.

The PEEK filaments are typically < 0.7μ in diameter and the reinforcement carbon fibres may be 5-7 μ in diameter and the Glass fibre about 12 μ in diameter.

The spread fibres 10 and filaments 11 will be laid on joint pulleys and pins, shown schematically as rollers 15 , with the reinforcement fibre 10 spread on top of the spread matrix filaments 11 . This is to promote substantially total co-mingling of the fibres and filaments to ensure that the matrix filaments are evenly distributed amongst the reinforcement fibres so during the next stage of the process the matrix resin has a minimal distance to flow so as to promote maximum "wet-out" of the reinforcement fibres, as the materials are consolidated and heated to form a composite tube P. The ratio of reinforcment fibre 10 and thermoplastic filaments 11 co-wound will be approximately 50% each (by volume) and preferably 40% - 60% respectively. The mingled fibres and filaments are then passed through a placement head H for placement onto a rotatable mandrel M in order to helically wind the fibres and filaments onto the mandrel and form a perform 20 comprising oppositely biased layers 16 & 17.

Upon completion of the winding process represented in Figure 1, the co-wound semi-finished fibre/thermoplastic pre-form 20 in situ on the madrel M and has a predetermined external diameter of D1. The pre-form and mandrel are presented to a heated die 30 as shown in Fig. 2 and then pushed through the die 30 as shown in Figs. 3. The die 30 has plurality of temperature zones 31,32,33. The perform 20 is processed through these increasing temperature stages. The first zone 31 has a larger diameter cylindrical portion 36 and is a pre-heat zone (typically at approximately 250⁰C) t. The second zone 32 is a process heat zone 32 which is at a temperature above the melting point of the thermoplastic, ( for PEEK the hearing zone 32 is typically at approximately 390⁰C). At the process heat zone 32, the internal bore 34 of the die 30 gradually tapers from the first cylindrical portion 36 to a second cylindrical portion 35 having a minimum diameter D₂ . As the pre-form 20 is pushed through this lower diameter portion, the now molten thermoplastic fibre is squeezed within the pre-form as it is pushed through the die and caused to flow and consolidate and form the matrix, removing any air pockets that may have formed during the co-winding process and producing a substantially non-porous composite material.. The value of D₂ is such that the finished part has a Fibre Volume Fraction of between approximately 55% and approximately 65%.

As the now formed tube P gradually exits the process heat zone 32 (where the thermoplastic is above its melting point), it enters a cool down zone 33 where the thermoplastic matrix is brought below its melting point and solidifies. The composite tube P is then removed from the mandrel. The speed with which the mandrel passes through the cooling zone and the cooling zone temperature may be utilized to control the cool down of the thermoplastic matrix in order to obtain optimized properties such as cross-linking and crystallinity, of the composite material Typically the speed of the mandrel through the die will be about 1 metre/minute.

The continuous pipe P as shown in Fig.4 may for example comprise a fuel carrying pipe for an aircraft and may typically have a length between 1.0-3.0 metres and a diameter of between 8-13 mm. The pipe should have a low porosity and good chemical resistance, and a controlled electrical resistivity. The helically wound fibre reinforcement 10 is held in a matrix 12 of PEEK with a fibre content of about 55% -70% by volume .

Claims

1. A method of forming a fibre reinforced composite tube or pipe in which reinforcing fibres and polymeric resin matrix material are formed around a mandrel to provide a composite tubular pre-form on the mandrel, the mandrel with the perform thereon is then passed through a heated die to compact and reduce the diameter of the pre-form and change the state of matrix, the mandrel with the formed tube thereon exiting the die and the now formed tube is removed from the mandrel, the reinforcing fibres being helically wound around the mandrel , characterised in that a thermoplastic composite tube is formed from a composite tubular pre-form produced by winding reinforcment fibre and thermoplastic fibre onto the mandrel , the thermoplastic fibres being caused to flow and then solidify on cooling to form the matrix.

2. A method as claimed in Claim 1 , wherein the reinforcing fibres are mixed with thermoplastic fibres and the mixed fibres are then wound onto the mandrel of a filament winding machine.

3. A method as claimed in Claim 2, wherein the reinforcing fibres and the thermoplastic fibres are spread and the reinforcing fibres are laid over the thermoplastic fibres.

4. A method as claimed in any one of Claims 1 to 3, wherein the ratio of the co- wound reinforcement fibre and thermoplastic filaments will be approximately 40% to 60% respectively (by volume).

5. A method as claimed in any one of Claims 1 to 4, wherein the pre-form is compacted in the die such that the finished part has a Fibre Volume Fraction of between 55%-65%.

6. A method as claimed in any one of Claims 1 to 5, wherein the mandrel is

I passed through a heated die having a plurality of heat zones of increasing temperature including a zone having temperature higher than the melting point of the thermoplastic fibres and the formed tube then exits the die via a cooling zone.

7. A method as claimed in Claim 6 the composite tube is subject to a controlled cool down in order to optimize the properties of the material.

8. A method as claimed in any one of Claims 1 to 7; wherein additives are supplied separately or as part of the reinforcement fibre and or matrix fibre mix.

9. A fibre reinforced thermoplastic resin composite tube or pipe and which is formed by a method as claimed in any one of Claims 1 to 8.

10. A tube as claimed in Claim 9. wherein the reinforcement fibres comprise at least one of E-glass, S-glass, Aramid, Quartz, Ceramic, polymer fibre, a liquid crystal polymer fibre , any one of a range of carbon fibres, or a mixture thereof.

11. A tube as claimed in claim 10, wherein the matrix comprises one of PEI (polyetherimide), PPS ( Polyphenylenesulpone), PAI (Polyamide-imide), PES (polyethersulphone) and more preferably PEEK (Polyetheretherketone).