WO2010058975A3 - Carbon nanotube-poly(x-4-styrenesulphonate) composite, and a carbon nanotube-electrically conductive polymer composite produced using the same - Google Patents

Carbon nanotube-poly(x-4-styrenesulphonate) composite, and a carbon nanotube-electrically conductive polymer composite produced using the same Download PDF

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Publication number
WO2010058975A3
WO2010058975A3 PCT/KR2009/006823 KR2009006823W WO2010058975A3 WO 2010058975 A3 WO2010058975 A3 WO 2010058975A3 KR 2009006823 W KR2009006823 W KR 2009006823W WO 2010058975 A3 WO2010058975 A3 WO 2010058975A3
Authority
WO
WIPO (PCT)
Prior art keywords
carbon nanotube
electrically conductive
conductive polymer
composite
styrenesulphonate
Prior art date
Application number
PCT/KR2009/006823
Other languages
French (fr)
Korean (ko)
Other versions
WO2010058975A2 (en
Inventor
서광석
김종은
김태영
김원중
이태희
Original Assignee
Suh Kwang Suck
Kim Jong Eun
Kim Tae Young
Kim Won Jung
Lee Tae Hee
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suh Kwang Suck, Kim Jong Eun, Kim Tae Young, Kim Won Jung, Lee Tae Hee filed Critical Suh Kwang Suck
Publication of WO2010058975A2 publication Critical patent/WO2010058975A2/en
Publication of WO2010058975A3 publication Critical patent/WO2010058975A3/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82BNANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/168After-treatment
    • C01B32/174Derivatisation; Solubilisation; Dispersion in solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/80Constructional details
    • H10K30/81Electrodes
    • H10K30/82Transparent electrodes, e.g. indium tin oxide [ITO] electrodes
    • H10K30/821Transparent electrodes, e.g. indium tin oxide [ITO] electrodes comprising carbon nanotubes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10Organic polymers or oligomers
    • H10K85/111Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • H10K85/1135Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/20Carbon compounds, e.g. carbon nanotubes or fullerenes
    • H10K85/221Carbon nanotubes
    • H10K85/225Carbon nanotubes comprising substituents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/10Particle morphology extending in one dimension, e.g. needle-like
    • C01P2004/13Nanotubes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/22Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

Abstract

The present invention relates to a technique for making carbon nanotube-poly(X-4-styrenesulphonate) by using ionic bonding to introduce poly(X-4-styrenesulphonate) onto the surfaces of carbon nanotubes, and it relates to a method in which the carbon nanotube-poly(X-4-styrenesulphonate) is used as a dopant in the synthesis of an electrically conductive polymer in such a way as to finally produce a carbon nanotube-electrically conductive polymer composite which has outstanding dispersion properties. When producing a mixture of an electrically conductive polymer and carbon nanotubes, the technique of the present invention can be used in order to overcome the problem of phase separation between the electrically conductive polymer and the carbon nanotube components which is the greatest disadvantage exhibited by simple mixtures of the two components. Thus the present invention makes it possible to produce a composite in which an electrically conductive polymer has been synthesised on the surfaces of carbon nanotubes. Further, an advantageous effect can be obtained in that the composite has improved dispersion properties in solvents such as water.
PCT/KR2009/006823 2008-11-20 2009-11-19 Carbon nanotube-poly(x-4-styrenesulphonate) composite, and a carbon nanotube-electrically conductive polymer composite produced using the same WO2010058975A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2008-0115615 2008-11-20
KR1020080115615A KR101089300B1 (en) 2008-11-20 2008-11-20 CNT -polyX-4 Styrenesulfonate composites and CNT - Conductive polymer composites produced with the same

Publications (2)

Publication Number Publication Date
WO2010058975A2 WO2010058975A2 (en) 2010-05-27
WO2010058975A3 true WO2010058975A3 (en) 2010-09-10

Family

ID=42198669

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2009/006823 WO2010058975A2 (en) 2008-11-20 2009-11-19 Carbon nanotube-poly(x-4-styrenesulphonate) composite, and a carbon nanotube-electrically conductive polymer composite produced using the same

Country Status (3)

Country Link
KR (1) KR101089300B1 (en)
TW (1) TW201033244A (en)
WO (1) WO2010058975A2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102102243B (en) * 2010-12-13 2012-07-25 中国航空工业集团公司北京航空材料研究院 Method for preparing polythiophene derivative-carbon nano tube nano composite fibers at low temperature
CN102660801B (en) * 2012-02-24 2013-12-25 长春理工大学 Method for preparing erbium and ytterbium double-doped yttrium lithium tetrafluoride up-conversion luminescent nanobelt
CN102660802B (en) * 2012-02-24 2014-01-15 长春理工大学 Preparation method for erbium and ytterbium double-doped up-conversion luminescence nano-fiber
CN102660800B (en) * 2012-02-24 2014-02-12 长春理工大学 Method for preparing erbium and ytterbium co-doped sodium yttrium tetrafluoride upconversion luminescent nanofibers
GB2515004B (en) * 2013-05-16 2020-08-26 Technical Fibre Products Ltd Carbon nanotube derivatives
CN105778571B (en) * 2014-12-24 2018-05-04 中国科学院宁波材料技术与工程研究所 A kind of graphene composite mortar and preparation method thereof
CN105778572B (en) * 2014-12-24 2018-05-01 中国科学院宁波材料技术与工程研究所 A kind of graphene composite powder and preparation method thereof
KR101690543B1 (en) * 2015-07-29 2016-12-28 창원대학교 산학협력단 Method for Preparing Polymer Coated Fludized Bed Carbon Electrode, and Fludized Bed Carbon Electrode By The Same
TWI632169B (en) * 2016-12-09 2018-08-11 鈺邦科技股份有限公司 Polymer composite material, method for manufacturing the polymer composite material, capacitor package structure using the polymer composite material and method for manufacturing the capacitor package structure
CN111100255B (en) * 2018-10-25 2022-11-01 中国石油化工股份有限公司 Carbon nano tube-styrene derivative compound, preparation method and application
CN109449296A (en) * 2018-10-31 2019-03-08 浙江海洋大学 A kind of flexible solar battery material and preparation method based on carbon nanotube
CN115044949B (en) * 2022-06-09 2023-10-20 合肥工业大学 Preparation device and method of modified organic anti-corrosion coating

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006137846A2 (en) * 2004-09-17 2006-12-28 Eastman Kodak Company Coatable conductive polyethylenedioxythiophene with carbon nanotubes

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006137846A2 (en) * 2004-09-17 2006-12-28 Eastman Kodak Company Coatable conductive polyethylenedioxythiophene with carbon nanotubes

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
KHABASHESKU, V.N. ET AL.: "Sidewall Carboxylic Acid Functionalization of Single- Walled Carbon Nanotubes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 125, 15 November 2003 (2003-11-15), pages 15174 - 15182 *
LIU, P.: "Modifications of carbon nanotubes with polymers", EUROPEAN POLYMER JOURNAL, vol. 41, 11 July 2005 (2005-07-11), pages 2693 - 2703 *
ZHITOMIRSKY, I. ET AL.: "Electrodeposition of composite materials containing functionalized carbon nanotubes", MATERIALS CHEMISTRY AND PHYSICS, vol. 111, 15 September 2008 (2008-09-15), pages 42 - 49 *

Also Published As

Publication number Publication date
KR101089300B1 (en) 2011-12-02
KR20100056689A (en) 2010-05-28
WO2010058975A2 (en) 2010-05-27
TW201033244A (en) 2010-09-16

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