WO2010035233A2 - Method of combusting sulfur-containing fuel - Google Patents
Method of combusting sulfur-containing fuel Download PDFInfo
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- WO2010035233A2 WO2010035233A2 PCT/IB2009/054184 IB2009054184W WO2010035233A2 WO 2010035233 A2 WO2010035233 A2 WO 2010035233A2 IB 2009054184 W IB2009054184 W IB 2009054184W WO 2010035233 A2 WO2010035233 A2 WO 2010035233A2
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- furnace
- sulfur
- exhaust gas
- temperature
- fluidized bed
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C10/00—Fluidised bed combustion apparatus
- F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
- F23C10/04—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/003—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for pulverulent fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J7/00—Arrangement of devices for supplying chemicals to fire
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
- F23L7/007—Supplying oxygen or oxygen-enriched air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2215/00—Preventing emissions
- F23J2215/20—Sulfur; Compounds thereof
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07001—Injecting synthetic air, i.e. a combustion supporting mixture made of pure oxygen and an inert gas, e.g. nitrogen or recycled fumes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/32—Direct CO2 mitigation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
Definitions
- the present invention relates to a method of efficiently combusting sulfur-containing fuel in a circulating fluidized bed boiler by using oxyfuel combustion, i.e., the fuel is combusted by using pure oxygen or a mixture of substantially pure oxidant and circulated fluidizing gas as the oxidant gas.
- the invention relates especially to oxyfuel combustion, where the fuel is combusted with an oxidant gas having oxygen content of about the same or higher than that of air.
- the formed calcium sulfate can then be removed from the furnace together with the ashes.
- a combustion process using a circulating fluidized bed boiler does not need additional sulfur capturing equipment in the exhaust gas channel, or the efficiency of such equipment can be relatively low.
- the process of combusting sulfur-containing fuel, especially bituminous coal, in a fluidized bed boiler has in practice a desired operating temperature, typically near to about 850 0 C.
- the combustion temperature affects to the highest obtainable steam temperature and, thereby, the thermal efficiency of the boiler.
- An object of the present invention is to provide a method of efficiently combusting sulfur-containing fuel in a circulating fluidized bed boiler.
- a method of combusting sulfur-containing fuel in a circulating fluidized bed boiler comprising the steps of: feeding sulfur-containing fuel into a furnace of the circulating fluidized bed boiler, combusting the fuel with oxidant gas consisting essentially of pure oxygen and circulated exhaust gas, so as to form exhaust gas having carbon dioxide and water as its main components, and feeding calcium carbonate containing material into the furnace so as to capture sulfur dioxide into calcium sulfate in the furnace, wherein the temperature in the furnace is maintained above 870 0 C.
- the temperature in the furnace is preferably maintained above 900 0 C, even more preferably above 930 0 C.
- the temperature in the furnace can be maintained at a desired level by controlling the fuel feeding rate or the cooling rate of the furnace.
- the heat absorption rate can advantageously be controlled by using a controllable heat exchange chamber arranged in the hot loop of the circulating fluidized bed boiler.
- the oxygen feeding rate is usually controlled so that substantially complete combustion of the fuel is obtained and a desired excess oxygen level, typically about 3 %, remains in the exhaust gas.
- the present invention is based on a series of surprising results obtained by the inventors when adding calcium carbonate to a fluidized bed combustion reactor maintained at different temperatures when combusting bituminous coal by using a mixture of oxygen and recirculated exhaust gas as the oxidant gas. The results will be discussed more in details below, in the section DETAILED DESCRIPTION OF THE INVENTION.
- the use of combustion temperatures higher than those used in conventional air-firing fluidized bed combustion allows a circulating fluidized bed boiler to generate steam at higher temperatures, while still achieving a high level of in-furnace sulfur dioxide capture.
- the boiler is then preferably used to generate steam at a temperature of at least about 650 0 C, even more preferably at least about 700 0 C.
- the oxygen content of the oxidant gas used in the process is about the same or somewhat above that of air, i.e. about or above 21 %.
- the oxygen content of the oxidant gas is about 28 %, typically from about 26 % to about 30 %.
- the oxygen content of the oxidant gas may be above about 28 %, for example from about 28 % to about 40 %.
- the oxygen content of the oxidant gas may be from about 21 % to about 28 %, for example about 24 %.
- the main components of the exhaust gas are carbon dioxide, water and, for example, about 3 % of excess oxygen.
- the oxygen content of the oxidant gas is thus determined by the recycling rate of the exhaust gas.
- an oxygen content of 28 % is obtained by recycling approximately 70 % of the exhaust gas.
- the average carbon dioxide content in the combustion reactor may alternatively be considered as the key parameter for advantageous oxyfuel combustion of sulfur-containing fuels in fluidized bed boilers.
- the carbon dioxide content in the furnace depends on the exhaust gas circulation rate and water content of the circulated exhaust gas.
- the average carbon dioxide content in the combustion reactor is advantageously about 70 %, typically from about 68 % to about 72 %.
- the average carbon dioxide content in the furnace may be even higher, for example from about 70 % to about 80 %, especially when recycling dry and relatively cold exhaust gas.
- the average carbon dioxide content in the combustion reactor is lower than 70 %, for example, from about 50 % to about 70 %.
- FIG. 1 is a schematic diagram of a typical circulating fluidized bed combustion reactor used for oxyfuel combustion.
- FIG. 2 is a schematic diagram of experimentally observed calcium utilization in oxygen and air combustion of bituminous coal as a function of average temperature in the combustion reactor.
- FIG. 1 shows a schematic diagram of a typical power plant 10 used for oxyfuel combustion of sulfur-containing fuel, such as bituminous coal.
- the power plant 10 comprises a circulating fluidized bed (CFB) boiler 12 with a furnace 14 comprising conventional means for feeding fuel 16 and calcium carbonate, CaCO 3 , containing sorbent 18 for capturing sulfur dioxide, SO2, generated when combusting the fuel with an oxidant gas, to calcium sulfate, CaSO 4 .
- the oxidant gas is fed to the furnace as primary oxidant gas 20, fed through a grid at the bottom of the furnace, and secondary oxidant gas 22, fed to the furnace at a higher level. Oxidant gas may in some cases be fed to the furnace at even more locations and levels.
- Exhaust gas produced by combusting the fuel with the oxidant gas in a fluidized bed formed in the furnace 14 is lead from the furnace through a particle separator 24 to an exhaust gas channel 26.
- the temperature in the furnace may be controlled to a desired value, to be discussed later, by controlling the fuel feed rate and by a heat exchanger 28 advantageously connected to a return leg arranged for leading separated particles from the particle separator 24 to the lower portion of the furnace 14.
- the temperature and, advantageously, temperature distribution in the furnace can be monitored by temperature measuring means 30, such as thermocouples, arranged at one or more suitable locations in the furnace.
- An exhaust gas recycling channel 32 is branched off from the exhaust gas channel 26, so as to recycle a portion of the exhaust gas back to the furnace 14.
- the exhaust gas recycling channel 32 advantageously comprises means, such as a fan 34 and a damper 36, for controlling the exhaust gas recycling rate.
- the rest of the exhaust gas is conveyed through an end portion 38 of the exhaust gas channel for final processing.
- the furnace 14 usually comprises evaporation surfaces, not shown in FIG. 1
- the exhaust gas channel 26 further comprises heat exchanger surfaces 40, for example, superheaters, reheaters and economizers, for generating steam by the boiler 12.
- FIG. 1 only shows one such heat exchanger surface 40, but, in practice, the exhaust gas channel system usually comprises multiple superheating, reheating and economizer surfaces for recovering heat from the exhaust gas.
- a gas-gas heat exchanger 42 for example, a regenerative heat exchanger, is advantageously also arranged in the exhaust gas channel 26, downstream of the steam generating heat exchange surfaces 40, for transferring heat from the exhaust gas to the recycling portion of the exhaust gas.
- the exhaust gas channel 26 also usually comprises conventional units for cleaning particles and gaseous pollutants from the exhaust gas, which units are schematically represented in FIG. 1 only by a dust separator 44. Between the gas-gas heat exchanger 42 and the dust separator 44, there is shown a further heat exchanger 40', a low-pressure economizer, which may alternatively be arranged downstream of the dust separator or in the exhaust gas recycling channel 32.
- the end portion 38 of the exhaust gas channel is equipped with exhaust gas processing means, schematically represented by a carbon dioxide processing unit 46, for cooling, cleaning and compressing carbon dioxide.
- the carbon dioxide processing unit 46 usually comprises a dryer for completely drying all water from the exhaust gas, and a separator for separating a stream of non-condensable gas 48, such as oxygen, and other possible impurities, from the carbon dioxide.
- a stream of carbon dioxide 50 is typically captured in a liquid or supercritical state, at a pressure of, for example, about one hundred ten bars, so that it can be transported to further use or to be stored in a suitable place.
- FIG. 1 separately shows a condensing gas cooler 52, located upstream of the carbon dioxide processing unit 46, for initially removing water from the exhaust gas.
- the condensing gas cooler may be arranged either in the end portion 38 of the exhaust gas channel, as in FIG. 1 , or upstream of the branch point of the recycling exhaust gas channel 32. In the latter case, the water content in the recycling exhaust gas and in the furnace 14 is minimized.
- the oxidant gas is preferably produced by mixing a stream of substantially pure oxygen 54, produced from an air stream 56 in an air separation unit (ASU) 58, and at least a portion of the recycling portion of the exhaust gas in a mixing unit 60.
- the air separation unit produces a gas stream consisting essentially of pure oxygen, containing typically at least about 95 % oxygen.
- the recycling rate of the exhaust gas is advantageously adjusted such that the resulting gas flow rate in the furnace 14 obtains a desired value, whereby the average O2 content of the oxidant gas is, typically, close to that of air, preferably, from about 21 % to about 28%.
- the oxygen content of the oxidant gas may be higher, for example, from about 28 % to about 40 %. It is also possible to introduce the streams of recycled exhaust gas and substantially pure oxygen separately, or multiple streams with different O2 contents, produced in separate mixing units, at, for example, different heights into the furnace 14.
- FIG. 2 shows a diagram of experimentally observed calcium utilization, in percents, in otherwise similar oxyfuel combustion and air combustion processes of bituminous coal as a function of average temperature in the combustion reactor.
- the calcium utilization is defined as
- Calcium utilization RET / (Ca/S), where RET is sulfur retention [%], and Ca/S is calcium to fuel sulfur feed ratio [mol/mol].
- Experimental points of oxyfuel combustion are shown as black squares, whereas points measured in air combustion are shown as hatched triangles.
- the calcium utilization decreases with temperature in air combustion, from about 50 % at 800 0 C to about 30 % at 900 0 C.
- the calcium utilization does not show any clear decrease in the temperature range extending up to 930 0 C.
- the calcium utilization seems to increase, from slightly above 50 % to near to 60 %, when increasing the temperature from 800 0 C to 900 0 C.
Abstract
A method of combusting sulfur-containing fuel in a circulating fluidized bed boiler (12) includes the steps of (a) feeding sulfur-containing fuel into a furnace (14) of the circulating fluidized bed boiler, (b) combusting the fuel (16) with oxidant gas (20, 22) consisting essentially of pure oxygen and circulated exhaust gas, so as to form exhaust gas having carbon dioxide and water as its main components, and (c) feeding calcium carbonate (18) containing material into the furnace so as to capture sulfur dioxide into calcium sulfate in the furnace. The temperature in the furnace is maintained above 870 °C.
Description
METHOD OF COMBUSTING SULFUR-CONTAINING FUEL
BACKGROUND OF THE INVENTION
[0001] Field of the Invention
[0002] The present invention relates to a method of efficiently combusting sulfur-containing fuel in a circulating fluidized bed boiler by using oxyfuel combustion, i.e., the fuel is combusted by using pure oxygen or a mixture of substantially pure oxidant and circulated fluidizing gas as the oxidant gas. The invention relates especially to oxyfuel combustion, where the fuel is combusted with an oxidant gas having oxygen content of about the same or higher than that of air.
[0003] Description of the Related Art
[0004] Combustion of sulfur-containing fuels, such as coal, generates sulfur dioxide, SO2, which is an acid rain creating pollutant if released to the atmosphere. In order to minimize pollution of the environment, today's combustion systems often comprise special equipment, such as an exhaust gas scrubber, arranged in the exhaust gas channel to remove sulfur dioxide from the exhaust gas. Such special equipment is usually expensive to build and operate.
[0005] When combusting fuel in a circulating fluidized bed boiler, most of released sulfur dioxide is usually captured already in the furnace by feeding calcium carbonate containing material, typically limestone, into the furnace. The calcium carbonate, CaCO3, is calcined in the furnace to calcium oxide, CaO, which captures sulfur dioxide into calcium sulfate, according to the reactions:
(i) CaCO3 -> CaO + CO2
(ii) CaO + SO2 + V≥- O2 -> CaSO4.
The formed calcium sulfate can then be removed from the furnace together with the ashes. Thus, a combustion process using a circulating fluidized bed boiler does not need additional sulfur capturing equipment in the exhaust gas channel, or the efficiency of such equipment can be relatively low.
[0006] The reactivity of calcium carbonate to capture sulfur dioxide in a conventional circulating fluidized bed boiler increases with temperature, reaching an optimum value typically around 850 0C. The optimum temperature may vary depending on the type of the fuel and the sorbent and other parameters of the process. The efficiency of the capturing of sulfur dioxide drops quite rapidly at temperatures above the optimum. Many explanations are proposed for the reduced capturing at higher temperatures, including sintering of pores of the CaO particles, decomposition of CaSO4 with CO, instability of the intermediate product CaSO3 and the depletion of oxide in the region of the capturing process. Thus, the process of combusting sulfur-containing fuel, especially bituminous coal, in a fluidized bed boiler has in practice a desired operating temperature, typically near to about 850 0C. The
combustion temperature affects to the highest obtainable steam temperature and, thereby, the thermal efficiency of the boiler.
[0007] H. Liu et al. have suggested in an article published in Fuel (2000) 945 -
953 that when using oxyfuel combustion in a fluidized bed, the calcium carbonate based sulfur capture is replaced at temperatures below 850 0C by direct sulfation from CaCO3 to CaSO4. This reaction enables higher sulfation degree of the calcium due to the porosity of the CaCO3 particles generated therein by the counter-diffusion of the CO2.
[0008] At low partial pressures of carbon dioxide, CO2, prevailing in combustion processes using air as the oxidant gas, the equilibrium of the reaction (i) is, in the typical temperatures of fluidized bed combustion, always on the right hand side, i.e., CaCO3 calcines to CaO. On the other hand, at typical partial pressures of CO2 prevailing in a circulating fluidized bed boiler when using oxyfuel combustion, for example at about 0,7 atm, the CaCO3 does not calcine to CaO below a calcination temperature of about 870 0C, and SO2 is captured by direct sulfation. However, above the calcination temperature CaCO3 calcines to CaO, and direct sulfation should not be important.
[0009] Due to the above mentioned reasons, there is a need for an improved combustion method of a circulating fluidized bed boiler, in order to improve the thermal efficiency of the boiler while still effectively capturing sulfur dioxide in the furnace.
SUMMARY OF THE INVENTION
[0010] An object of the present invention is to provide a method of efficiently combusting sulfur-containing fuel in a circulating fluidized bed boiler. [0011] According to an aspect of the present invention, a method of combusting sulfur-containing fuel in a circulating fluidized bed boiler is provided, the method comprising the steps of: feeding sulfur-containing fuel into a furnace of the circulating fluidized bed boiler, combusting the fuel with oxidant gas consisting essentially of pure oxygen and circulated exhaust gas, so as to form exhaust gas having carbon dioxide and water as its main components, and feeding calcium carbonate containing material into the furnace so as to capture sulfur dioxide into calcium sulfate in the furnace, wherein the temperature in the furnace is maintained above 870 0C.
[0012] According to other embodiments of the present invention, the temperature in the furnace is preferably maintained above 900 0C, even more preferably above 930 0C.
[0013] As is well known to a person skilled in the art of fluidized bed combustion, the temperature in the furnace can be maintained at a desired level by controlling the fuel feeding rate or the cooling rate of the furnace. The heat absorption rate can advantageously be controlled by using a controllable heat exchange chamber arranged in the hot loop of the circulating fluidized bed boiler. The oxygen feeding rate is usually controlled so that substantially complete combustion of the fuel
is obtained and a desired excess oxygen level, typically about 3 %, remains in the exhaust gas.
[0014] The present invention is based on a series of surprising results obtained by the inventors when adding calcium carbonate to a fluidized bed combustion reactor maintained at different temperatures when combusting bituminous coal by using a mixture of oxygen and recirculated exhaust gas as the oxidant gas. The results will be discussed more in details below, in the section DETAILED DESCRIPTION OF THE INVENTION.
[0015] It appears that the conditions giving rise to a decreasing sulfur capture at high temperatures in air-firing fluidized bed boilers are changed in oxyfuel combustion. As a result of the change, the temperature range of decreasing efficiency appears to be removed or at least shifted to a higher temperature. An improved sulfur capture in the furnace in oxyfuel combustion can be expected, in any temperature, on the basis of the extended time of SO2 presence of in the furnace due to the recirculation of the exhaust gas. In addition to that, the contents of the gas in the furnace are in oxyfuel combustion clearly different than in air combustion. Thus, the enhanced sulfur capture at high temperatures may be related to the higher content of CO2 or O2 in the furnace.
[0016] Similar enhanced sulfur capture at high temperatures has been observed earlier in air-firing fluidized bed boilers when used at elevated pressures of 10 to 20 atm. In that case the improved sulfur capture at high temperatures is probably related to changing of the sulfur dioxide capturing process to direct sulfation of CaCO3 as described above. In the present case, where enhanced sulfur capture
was observed at ambient pressure and at temperatures above 870 0C, the sulfur capturing process remains to be via the route including calcination of CaCO3 to CaO, and direct sulfation is not important.
[0017] The efficiency of calcium carbonate based sulfur capture in a circulating fluidized bed boiler at even higher temperatures, say above 1000 0C, is not yet known. Anyhow, the present observations encourage to test sulfur capture up to 1000 0C and above, in order to find the full usable operation range for oxyfuel combustion of sulfur-containing fuels in circulating fluidized bed boilers in order to obtain high steam temperatures. However, it is clear that a fluidized bed boiler cannot be operated above the softening temperature of the bed, which depends on the fuel, being, for example, about 1100 0C.
[0018] The use of combustion temperatures higher than those used in conventional air-firing fluidized bed combustion allows a circulating fluidized bed boiler to generate steam at higher temperatures, while still achieving a high level of in-furnace sulfur dioxide capture. Thus, the present invention helps to facilitate improved steam cycle efficiency in supercritical and ultra-supercritical circulating fluidized bed boiler applications. The boiler is then preferably used to generate steam at a temperature of at least about 650 0C, even more preferably at least about 700 0C. [0019] Preferably, the oxygen content of the oxidant gas used in the process is about the same or somewhat above that of air, i.e. about or above 21 %. According to a preferred embodiment of the present invention, the oxygen content of the oxidant gas is about 28 %, typically from about 26 % to about 30 %.. In some cases, the
oxygen content of the oxidant gas may be above about 28 %, for example from about 28 % to about 40 %. In some other cases, the oxygen content of the oxidant gas may be from about 21 % to about 28 %, for example about 24 %. [0020] In oxyfuel combustion, where the oxidant gas is a mixture of substantially pure oxygen and recycled exhaust gas, the main components of the exhaust gas are carbon dioxide, water and, for example, about 3 % of excess oxygen. The oxygen content of the oxidant gas is thus determined by the recycling rate of the exhaust gas. Thus, for example, an oxygen content of 28 % is obtained by recycling approximately 70 % of the exhaust gas.
[0021] The average carbon dioxide content in the combustion reactor may alternatively be considered as the key parameter for advantageous oxyfuel combustion of sulfur-containing fuels in fluidized bed boilers. The carbon dioxide content in the furnace depends on the exhaust gas circulation rate and water content of the circulated exhaust gas. According to the present experiments, the average carbon dioxide content in the combustion reactor is advantageously about 70 %, typically from about 68 % to about 72 %. In other advantageous cases, the average carbon dioxide content in the furnace may be even higher, for example from about 70 % to about 80 %, especially when recycling dry and relatively cold exhaust gas. In still other advantageous cases, the average carbon dioxide content in the combustion reactor is lower than 70 %, for example, from about 50 % to about 70 %. [0022] The above brief description, as well as further objects, features, and advantages of the present invention will be more fully appreciated by reference to the following detailed description of the currently preferred, but nonetheless illustrative,
embodiments of the present invention, taken in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
[0023] FIG. 1 is a schematic diagram of a typical circulating fluidized bed combustion reactor used for oxyfuel combustion.
[0024] FIG. 2 is a schematic diagram of experimentally observed calcium utilization in oxygen and air combustion of bituminous coal as a function of average temperature in the combustion reactor.
DETAILED DESCRIPTION OF THE INVENTION
[0025] FIG. 1 shows a schematic diagram of a typical power plant 10 used for oxyfuel combustion of sulfur-containing fuel, such as bituminous coal. The power plant 10 comprises a circulating fluidized bed (CFB) boiler 12 with a furnace 14 comprising conventional means for feeding fuel 16 and calcium carbonate, CaCO3, containing sorbent 18 for capturing sulfur dioxide, SO2, generated when combusting the fuel with an oxidant gas, to calcium sulfate, CaSO4. The oxidant gas is fed to the furnace as primary oxidant gas 20, fed through a grid at the bottom of the furnace, and secondary oxidant gas 22, fed to the furnace at a higher level. Oxidant gas may in some cases be fed to the furnace at even more locations and levels.
[0026] Exhaust gas produced by combusting the fuel with the oxidant gas in a fluidized bed formed in the furnace 14 is lead from the furnace through a particle separator 24 to an exhaust gas channel 26. The temperature in the furnace may be controlled to a desired value, to be discussed later, by controlling the fuel feed rate and by a heat exchanger 28 advantageously connected to a return leg arranged for leading separated particles from the particle separator 24 to the lower portion of the furnace 14. The temperature and, advantageously, temperature distribution in the furnace can be monitored by temperature measuring means 30, such as thermocouples, arranged at one or more suitable locations in the furnace. [0027] An exhaust gas recycling channel 32 is branched off from the exhaust gas channel 26, so as to recycle a portion of the exhaust gas back to the furnace 14. The exhaust gas recycling channel 32 advantageously comprises means, such as a fan 34 and a damper 36, for controlling the exhaust gas recycling rate. The rest of the exhaust gas is conveyed through an end portion 38 of the exhaust gas channel for final processing.
[0028] As is conventional, the furnace 14 usually comprises evaporation surfaces, not shown in FIG. 1 , and the exhaust gas channel 26 further comprises heat exchanger surfaces 40, for example, superheaters, reheaters and economizers, for generating steam by the boiler 12. For the sake of simplicity, FIG. 1 only shows one such heat exchanger surface 40, but, in practice, the exhaust gas channel system usually comprises multiple superheating, reheating and economizer surfaces for recovering heat from the exhaust gas.
[0029] A gas-gas heat exchanger 42, for example, a regenerative heat exchanger, is advantageously also arranged in the exhaust gas channel 26, downstream of the steam generating heat exchange surfaces 40, for transferring heat from the exhaust gas to the recycling portion of the exhaust gas. The exhaust gas channel 26 also usually comprises conventional units for cleaning particles and gaseous pollutants from the exhaust gas, which units are schematically represented in FIG. 1 only by a dust separator 44. Between the gas-gas heat exchanger 42 and the dust separator 44, there is shown a further heat exchanger 40', a low-pressure economizer, which may alternatively be arranged downstream of the dust separator or in the exhaust gas recycling channel 32.
[0030] In accordance with the main object of oxyfuel combustion, i.e., to recover carbon dioxide from the exhaust gas, having carbon dioxide as its largest component, the end portion 38 of the exhaust gas channel is equipped with exhaust gas processing means, schematically represented by a carbon dioxide processing unit 46, for cooling, cleaning and compressing carbon dioxide. The carbon dioxide processing unit 46 usually comprises a dryer for completely drying all water from the exhaust gas, and a separator for separating a stream of non-condensable gas 48, such as oxygen, and other possible impurities, from the carbon dioxide. A stream of carbon dioxide 50 is typically captured in a liquid or supercritical state, at a pressure of, for example, about one hundred ten bars, so that it can be transported to further use or to be stored in a suitable place.
[0031] FIG. 1 separately shows a condensing gas cooler 52, located upstream of the carbon dioxide processing unit 46, for initially removing water from the exhaust
gas. The condensing gas cooler may be arranged either in the end portion 38 of the exhaust gas channel, as in FIG. 1 , or upstream of the branch point of the recycling exhaust gas channel 32. In the latter case, the water content in the recycling exhaust gas and in the furnace 14 is minimized.
[0032] The oxidant gas is preferably produced by mixing a stream of substantially pure oxygen 54, produced from an air stream 56 in an air separation unit (ASU) 58, and at least a portion of the recycling portion of the exhaust gas in a mixing unit 60. The air separation unit produces a gas stream consisting essentially of pure oxygen, containing typically at least about 95 % oxygen. The recycling rate of the exhaust gas is advantageously adjusted such that the resulting gas flow rate in the furnace 14 obtains a desired value, whereby the average O2 content of the oxidant gas is, typically, close to that of air, preferably, from about 21 % to about 28%. In some other cases, the oxygen content of the oxidant gas may be higher, for example, from about 28 % to about 40 %. It is also possible to introduce the streams of recycled exhaust gas and substantially pure oxygen separately, or multiple streams with different O2 contents, produced in separate mixing units, at, for example, different heights into the furnace 14.
[0033] FIG. 2 shows a diagram of experimentally observed calcium utilization, in percents, in otherwise similar oxyfuel combustion and air combustion processes of bituminous coal as a function of average temperature in the combustion reactor. The calcium utilization is defined as
Calcium utilization = RET / (Ca/S),
where RET is sulfur retention [%], and Ca/S is calcium to fuel sulfur feed ratio [mol/mol]. Experimental points of oxyfuel combustion are shown as black squares, whereas points measured in air combustion are shown as hatched triangles. [0034] As can be seen in FIG. 2, the calcium utilization decreases with temperature in air combustion, from about 50 % at 800 0C to about 30 % at 9000C. In oxyfuel combustion, the calcium utilization does not show any clear decrease in the temperature range extending up to 930 0C. To the contrary, the calcium utilization seems to increase, from slightly above 50 % to near to 60 %, when increasing the temperature from 800 0C to 9000C.
[0035] The measurements suggest, surprisingly, that, when using oxyfuel combustion, sulfur-containing fuels, especially bituminous coals, can be advantageously combusted in a circulating fluidized bed boiler at a temperature which is preferably higher than 870 0C, more preferably higher than 900 0C and even more preferably higher than 930 0C, while still obtaining efficient sulfur capture in the furnace. Such a combustion process renders possible to generate steam at a higher temperature than conventionally, preferably at a temperature of at least 650 0C, even more preferably at least about 700 0C, and to thereby obtain an improved thermal efficiency of the boiler.
[0036] While the invention has been described herein by way of examples in connection with what are, at present, considered to be the most preferred embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but is intended to cover various combinations or modifications of its
features and several other applications included within the scope of the invention as defined in the appended claims.
Claims
1. A method of combusting sulfur-containing fuel in a circulating fluidized bed boiler comprising the steps of:
(a) feeding sulfur-containing fuel into a furnace of the circulating fluidized bed boiler,
(b) combusting the fuel with oxidant gas consisting essentially of pure oxygen and circulated exhaust gas, so as to form exhaust gas having carbon dioxide and water as its main components,
(c) feeding calcium carbonate containing material into the furnace so as to capture sulfur dioxide into calcium sulfate in the furnace, wherein the temperature in the furnace is maintained above 870 0C.
2. A method according to claim 1 , wherein the temperature in the furnace is maintained above 900 0C.
3. A method according to claim 1 , wherein the temperature in the furnace is maintained above 930 0C.
4. A method according to claim 3, wherein the circulating fluidize bed boiler generates steam at a temperature of at least about 650 0C.
5. A method according to claim 4, wherein the circulating fluidize bed boiler generates steam at a temperature of at least about 700 0C.
6. A method according to any of the claims 1 - 3, where the sulfur- containing fuel is bituminous coal.
7. A method according to claim 1 , wherein the oxygen content of the oxidant gas is about or more than about 21 %.
8. A method according to claim 5, wherein the oxygen content of the oxidant gas is from about 21 % to about 28 %.
9. A method according to claim 5, wherein the oxygen content of the oxidant gas is about or more than about 28 %.
10. A method according to claim 7, wherein the oxygen content of the oxidant gas is from about 28 % to about 40 %.
11. A method according to claim 1 , wherein the average carbon dioxide content in the furnace is about 70 %.
12. A method according to claim 1 , wherein the average carbon dioxide content in the furnace is from about 50 % to about 70 %.
13. A method according to claim 1 , wherein the average carbon dioxide content in the furnace is from about 70 % to about 80 %.
Applications Claiming Priority (2)
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US12/238,768 US20100077947A1 (en) | 2008-09-26 | 2008-09-26 | Method of combusting sulfur-containing fuel |
US12/238,768 | 2008-09-26 |
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WO2010035233A2 true WO2010035233A2 (en) | 2010-04-01 |
WO2010035233A3 WO2010035233A3 (en) | 2011-05-12 |
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PCT/IB2009/054184 WO2010035233A2 (en) | 2008-09-26 | 2009-09-24 | Method of combusting sulfur-containing fuel |
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WO (1) | WO2010035233A2 (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7874140B2 (en) * | 2007-06-08 | 2011-01-25 | Foster Wheeler North America Corp. | Method of and power plant for generating power by oxyfuel combustion |
JP5174618B2 (en) * | 2008-10-31 | 2013-04-03 | 株式会社日立製作所 | Oxyfuel combustion boiler system and control method for oxygen combustion boiler system |
US20110139046A1 (en) * | 2009-12-16 | 2011-06-16 | Foster Wheeler Energy Corporation | Emissionless Oxyfuel Combustion Process and a Combustion System Using Such a Process |
JP5510174B2 (en) * | 2010-08-12 | 2014-06-04 | 株式会社Ihi | Oxygen fluid combustion system in circulating fluidized bed system. |
WO2012068293A2 (en) * | 2010-11-16 | 2012-05-24 | Alstom Technology Ltd | Apparatus and method of controlling the thermal performance of an oxygen-fired boiler |
CN103717289A (en) | 2011-04-11 | 2014-04-09 | Ada-Es股份有限公司 | Fluidized bed method and system for gas component capture |
CN102363095B (en) * | 2011-09-16 | 2014-07-16 | 莫沙纱 | Dry flue gas desulfurization process method and dry flue gas desulfurization system thereof |
JP5929253B2 (en) * | 2012-02-01 | 2016-06-01 | 株式会社Ihi | Oxy-combustion circulating fluidized bed boiler and its temperature control device |
JP5872337B2 (en) * | 2012-03-14 | 2016-03-01 | 東京瓦斯株式会社 | Chemical loop combustion apparatus and method of operating the same |
US20140065559A1 (en) * | 2012-09-06 | 2014-03-06 | Alstom Technology Ltd. | Pressurized oxy-combustion power boiler and power plant and method of operating the same |
AU2013317997B2 (en) | 2012-09-20 | 2016-04-07 | ADA-ES, Inc. | Method and system to reclaim functional sites on a sorbent contaminated by heat stable salts |
US9939153B2 (en) | 2013-06-03 | 2018-04-10 | Washington University | Method and apparatus for capturing carbon dioxide during combustion of carbon containing fuel |
KR101428452B1 (en) | 2014-04-18 | 2014-08-08 | 한솔이엠이(주) | Method for combusting waste resources using fluidized bed combustor |
CN103953922B (en) * | 2014-05-15 | 2016-01-13 | 浙江菲尼克斯环境技术有限公司 | Low-carbon (LC) Inner eycle oxygen enrichment combustion technology device and combustion method again |
US10113740B2 (en) | 2016-08-12 | 2018-10-30 | Gas Technology Institute | Fluidized bed combustion of carbonaceous fuels |
CN108361731B (en) * | 2018-01-03 | 2019-08-06 | 大唐东北电力试验研究所有限公司 | Hot-water boiler air and flue system automation control method |
BE1028191B9 (en) * | 2020-04-07 | 2021-11-30 | Lhoist Rech Et Developpement Sa | Lime or dolomite calcination process and annular upright furnace implemented |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3546465A1 (en) * | 1985-11-02 | 1987-05-14 | Helmut Kohler | Process and arrangement for operating a fuel-burning power station |
US4854249A (en) * | 1987-08-03 | 1989-08-08 | Institute Of Gas Technology | Two stage combustion |
US4867756A (en) * | 1986-05-20 | 1989-09-19 | Institute Of Gas Technology | Removal of sulfur compounds in fluidized bed carbonaceous solids gasification |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5335609A (en) * | 1993-04-29 | 1994-08-09 | University Of Chicago | Thermal and chemical remediation of mixed waste |
US20080178845A1 (en) * | 2007-01-31 | 2008-07-31 | Denso Corporation | Fuel injection pump |
-
2008
- 2008-09-26 US US12/238,768 patent/US20100077947A1/en not_active Abandoned
-
2009
- 2009-09-24 WO PCT/IB2009/054184 patent/WO2010035233A2/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3546465A1 (en) * | 1985-11-02 | 1987-05-14 | Helmut Kohler | Process and arrangement for operating a fuel-burning power station |
US4867756A (en) * | 1986-05-20 | 1989-09-19 | Institute Of Gas Technology | Removal of sulfur compounds in fluidized bed carbonaceous solids gasification |
US4854249A (en) * | 1987-08-03 | 1989-08-08 | Institute Of Gas Technology | Two stage combustion |
Non-Patent Citations (2)
Title |
---|
Chen C., Zhao C.,: "Mechanism of Highly Efficient In-Furnace Desulfurization by Limestone under O2/CO2 Coal Combustion Atmosphere" Ind. Eng. Chem. Res., vol. 45, 6 October 2006 (2006-10-06), pages 5078-5085, XP002623906 * |
Jia L., Tan Y., Wang C., Anthony E. J.: "Experimental Study of Oxy-Fuel Combustion and Sulfur Capture in a Mini-CFBC" Energy & Fuels, [Online] vol. 21, no. 6, 18 September 2007 (2007-09-18), pages 3160-3164, XP002623907 Energy & Fuels Retrieved from the Internet: URL:http://pubs.acs.org/doi/pdf/10.1021/ef7002359> [retrieved on 2011-02-22] * |
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US20100077947A1 (en) | 2010-04-01 |
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