WO2010034109A1

WO2010034109A1 - Flame retardant coating

Info

Publication number: WO2010034109A1
Application number: PCT/CA2009/001327
Authority: WO
Inventors: Tony Lagrange; Shawn Chizen
Original assignee: Quantum Technical Services Ltd.
Priority date: 2008-09-26
Filing date: 2009-09-25
Publication date: 2010-04-01

Abstract

A flame retardant coating is disclosed. The flame retardant coating comprises polyurea elastomer, spray processable graphite, a graphite stabilizer agent, and a flame retardant. A method of manufacturing a flame retardant polyurea elastomer coating is also disclosed. A two part polymerizable system is provided comprising a first part containing isocyanates, and a second part containing polyamines. At least one of the first part and the second part contains a flame retardant, and both of spray processable graphite and a graphite stabilizer agent.The first part and the second part are then mixed to form the flame retardant polyurea elastomer coating.

Description

FLAME RETARDANT COATING

TECHNICAL FIELD

[0001] This document relates to flame retardant coatings, and flame retardant polyurea elastomer coatings

BACKGROUND

[0002] An intumescent is a substance which swells as a result of heat exposure, thus increasing in volume, and decreasing in density Intumescents are typically used in passive fire protection and, in America, require listing and approval use and compliance in their installed configurations in order to comply with the law

SUMMARY

[0003] A flame retardant coating is disclosed The flame retardant coating comprises polyurea elastomer, spray processable graphite, a graphite stabilizer agent, and a flame retardant

[0004] A method of manufacturing a flame retardant polyurea elastomer coating is also disclosed A two part polymerizable system is provided comprising a first part containing isocyanates, and a second part containing poly amines At least one of the first part and the second part contains a flame retardant, and both of spray processable graphite and a graphite stabilizer agent The first part and the second part are then mixed to form the flame retardant polyurea elastomer coating

[0005] A method of adhering a flame retardant polyurea elastomer coating to a smooth surface is also disclosed A first part and a second part are provided, the first part containing isocyanates, and the second part containing polyamines At least one of the first part and the second part contains a flame retardant, a mineral matrix agent, and both of spray processable expandable graphite and a graphite stabilizer agent The first part and the second part are mixed to form the flame retardant polyurea elastomer coating on the smooth surface [0006] A method of manufacturing a flame retardant polyurea elastomer coating is also disclosed A two part polymerizable system is disclosed comprising a first part containing isocyanates, and a second part containing poly amines At least one of the first part and the second part contains both of spray processable graphite and a graphite suspending agent The first part and the second part are mixed to form the flame retardant polyurea elastomer coating

[0007] Disclosed are polyurea elastomers with built-in intumescence In some embodiments, the polyurea elastomer have no polyurethane present

[0008] A flame retardant composition is also disclosed comprising polymer matrix comprising at least one of polyurethane and polyurea, spray processable graphite, a graphite stabilizer agent, and a flame retardant In some embodiments, the polymer matrix further comprises polyurethane

[0009] These and other aspects of the device and method are set out in the claims, which are incorporated here by reference

BRIEF DESCRIPTION OF THE FIGURES

[0010] Embodiments will now be described with reference to the figures, in which like reference characters denote like elements, by way of example, and in which

[0011 ] Fig l is a perspective view of a flame retardant polyurea elastomer coating

[0012] Fig 2 is a side elevation view of a transport vehicle, with a partial cut-away illustrating the interior of the vehicle

[0013] Fig 3 is a flow schematic of a method of manufacturing a flame retardant polyurea elastomer coating

[0014] Fig 4 is a flow schematic of a method of adhering a flame retardant polyurea elastomer coating to a smooth surface [0015] Fig 5 is a further method of manufacturing a flame retardant polyurea elastomer coating comprising a graphite suspending agent

[0016] Fig 6 is a side elevation view, in section, of a flame retardant polyurea elastomer coating on structural steel

[0017] Fig 7 is a side elevation view, in section, of a flame retardant polyurea elastomer coating over rocks

DETAILED DESCRIPTION

[0018] Immaterial modifications may be made to the embodiments described here without departing from what is covered by the claims

[0019] Polyureas are commonly used as, for example, secondary containment liners because of their seamless application and rapid cure The flammability of existing polyurea secondary containment linings may actually contribute to the intensity of a fire, and thus intumescents may be added to improve flame resistance

[0020] In some embodiments, a coating is provided that has the surface hardness, flexibility, and chemical resistance of a sprayed polyurea Tear strength may be slightly lower than regular polyureas The coating may have the longevity of a polyurea as well as low flammability Unlike many existing secondary containment liners, the intumescent polyurea do not require covering with sand for fire protection This feature minimizes disposal issues due to contaminated sand from spills

[0021] In some embodiments, a coating is provided that is a fire resistant, zero VOC, high performance polyurea elastomer This coating may be designed to provide a flame resistant, durable, chemical resistant lining for secondary containment applications and as a surface coating for metal, concrete or wood for example In some embodiments, the coating is a fast set system which allows a fast return to service It may be intended for use with plural component spray equipment with a mix ratio of 1 to 1, for example [0022] Referring to Fig 1, a flame retardant coating 10, for example a flame retardant polyurea elastomer coating is illustrated Coating 10 comprises polyurea elastomer, spray processable graphite, a graphite stabilizer agent, and a flame retardant As illustrated coating 10 is flame retardant, and intumesces under flame heat, for example forming an expanded portion 12

[0023] Spraying coating 10 may require on-site machine processing Spray processable graphite refers to the fact that the graphite is suitable to be processed in the type of machinery used to apply polymer formulations, for example a high pressure proportioner or a reaction injection molding machine In order to achieve suitable intumescent expansion of the sprayed expandable graphite, a large enough particle size is required, but if the particle size is too large then it will not be spray processable in a machine On the other hand, if too small of a size is used, the graphite won't expand enough or provide enough fire protection Because larger graphite particle sizes give better fire retardant performance, previous systems employed the use of larger graphite particles However, systems with larger graphite particles can't process through RIM or HP proportioners, and had to be mixed by hand or in a static mixer, which have reduced productivity relative to a spray device Thus, a sprayable system that provides good fire retardant properties was needed

[0024] In some embodiments, a blend of graphite small enough to machine process, but also large enough to give a more stable char is used The combination of two or more types of graphite may improve the performance In some embodiments, the spray processable graphite is 50-110 mesh, with at least 50% of the spray processable graphite being between 50 and 70 mesh In other embodiments, the spray processable graphite is 100% 60 mesh For reference, 50 mesh corresponds to a size of about 300 microns, while 100 mesh corresponds to a particle size of about 150 microns Graphite is not typically used in elastomers because it causes problems and doesn't process well In some embodiments, this document teaches a modified form of graphite that will avoid these problems In general, the use of suitable densities of machine spray processable graphite produces a coating 10 that passes at least the flame spread test [0025] The graphite stabilizer agent is employed to form a polymer char that locks the graphite together under flame heat The presence of the graphite stabilizer agent insulates the graphite as it expands, gluing the graphite together and forming a skin that limits the amount of oxygen that can access the graphite Graphite, on its own, may form a porous material that falls off under turbulent flame conditions The graphite stabilizer agent may comprise for example at least one of ammonium polyphosphate, zinc polyborate, melamine polyphosphate, melamine pyrophosphate, triethyl phosphate, and zinc phosphate

[0026] The coating 10 is designed to pass Federal US regulations for the ASTM E

1354 Test Method for Heat and Visible Smoke Release Rate, the ASTM E162 Test Method for Surface Flammability, and the ASTM E662 Test Method for Specific Optical Density of Smoke Generated by Solid Materials An example of a suitable flame retardant is TCPP In some embodiments the flame retardant comprises no brominated compounds, as these are known carcinogens In some embodiments, coating 10 may be provided with or without halogenated flame retardants, depending on the application In general, halogenated flame retardants may be used where high performance is required, although good performance may still be obtained using a halogen-free composition

[0027] In some embodiments, coating 10 may further comprise a graphite suspending agent Because the graphite comprises particulates, the graphite may settle out of the liquid formulation used to create coating 10 The suspending agent suspends the graphite, allowing the coating 10 formed by spraying and reacting the formulation to have graphite suitably uniformly dispersed throughout the coating 10 This gives the coating 10 better flame retardant characteristics This may also be important during processing of the formulation used to create coating 10, since any settled graphite may clog the spray machinery The graphite suspending agent is to be contrasted with standard thickeners, or viscosity modifiers, in that it physically suspends the graphite beyond merely reducing the rate of drop out Some thickeners, such as hydroxyethyl cellulose, have been found to be not effective at suspending the graphite In some embodiments, the graphite suspending agent comprises thixatrol

[0028] In some embodiments, the polymeric composition further comprises a mineral matrix agent The mineral matrix agent greatly aids the performance of coating 10 when affixed to smooth surfaces, for example steel or metal Under the intense heat of a flame, the mineral matrix agent leaves a mineral matrix that prolongs the life of the char that is formed The mineral matrix formed prevents the pyrolysis of the carbon char, the pyrolysis of which may otherwise result in the char being blown off of the surface it is affixed to, leaving bare surface to be incinerated This is important in steel applications, as the longer the char is maintained, the longer it takes for the surface of the material coating 10 is affixed to reach its critical temperature In some embodiments, the mineral matrix agent comprises at least one of glass and perlite The glass may be provided as small spheres, or as processed shards for example Referring to Fig 6, in some embodiments, coating 10 may be used as fire protection for staictural steel 30

[0029] Referring to Fig 7, in some embodiments, coating 10 may be used as a rock reinforcing coating in, for example, an underground mine In the example shown, coating 10 is covering a pile of rocks 32 In other of these embodiments, coating 10 may be sprayed on the walls, roof, or floor of the interior of a mine, in order to reinforce it Coating 10 forms a gas impermeable stop that prevents hazardous gases from leaching from the formation and into the mine shaft

[0030] In some embodimens, coating 10 is formed by a two-part polymerizable system In the case of polyurea elastomers, one component typically contains isocyantes, while the other component contains polyamines The mixing of these two components causes the reaction that forms the coating 10

[0031] Referring to Fig 3, a method of manufacturing a flame retardant polyurea elastomer coating is illustrated In a step 14, a two part polymerizable system comprising a first part containing isocyanates, and a second part containing polyamines, is provided At least one of the first part and the second part contains a flame retardant, and both of spray processable graphite and a graphite stabilizer agent In a second step 16, the first part and the second part are mixed to form the flame retardant polyurea elastomer coating 10

[0032] Referring to Fig 4, a method of preparing a flame retardant polyurea elastomer coating on a smooth surface is illustrated In a step 18, a first part containing isocyanates, and a second part containing polyamines, is provided At least one of the first part and the second part contains a flame retardant, a mineral matrix agent, and both of spray processable graphite and a graphite stabilizer agent In a step 20, the first part and the second part are mixed to form the flame retardant polyurea elastomer coating 10 on the smooth surface The smooth surface may comprise, for example, metal The smooth surface may comprise, for example, phenolic composite panels (not shown)

[0033] Referring to Fig 5, a method of manufacturing a flame retardant polyurea elastomer coating is illustrated In step 22, a two part polymerizable system comprising a first part containing isocyanates, and a second part containing polyamines, is provided At least one of the first part and the second part contains both of spray processable graphite and a graphite suspending agent In step 24, the first part and the second part are mixed to form the flame retardant polyurea elastomer coating 10

[0034] Referring to Fig 2, the coating 10 may be used as flooring 26 in a transport vehicle 28 The coating 10 may be a spray applied polymer that cures rapidly to form a seamless, durable floor finish This spray may be available in a range of solid colors or with optional accent colors for a designer finish As a spray-in-place floor system it offers the design flexibility of color variations Options include guided walkways to ensure optimum traffic flow, borders or outlines, safety markings and custom logos permanently imbedded in the floor Flooring 26 is the only spray-in-place floor system that exceeds all federal fire safety standards for use in mass transit applications Flooring 26 may be used in passenger railcar, bus and other transit vehicles, for example, as well as station and other floor areas One advantage with using the disclosed flooring 26 is an improvement in productivity brought about by the ability to spray apply the system Previous flooring systems in railcars and buses required that a aibber surface had to be glued down using contact cement This type of procedure, including drying and installation time, could take at least 8 days to complete This can be contrasted with the installation of flooring 26, which may be achieved in a single day, allowing the vehicle to be back online in at most two days In some embodiments, flooring 26 may be any type of flooring Flooring 26 is highly abrasion resistant, long lasting and has superior impact resistance Because it is an elastomer, flooring 26 has no cracking or chipping Flooring 26 remains flexible at low temperatures and gives excellent traction in cold weather Flooring 26 is also stain resistant, which reduces cleaning time In order to avoid graphite streaking, the two-component system may be adjusted to change the speed with which it is cured, allowing the graphite to settle below the surface of coating 10 before curing

[0035] Table 1 below illustrates an exemplary two part polymerizable system As is evident, there are numerous optional components that may be present, such as moisture scavengers, defoamers, thixotropic agents, solvents, coupling agents, and a variety of other species that may improve or tailor the resulting coating 10 In addition, various coloring agents may be used, such as for example Black Paste, Red Oxide, and Yellow Oxide In the exemplary system, two different types of polymeric isocyanates are used, in order to carefully control the hardness of the resulting coating

[0036] Table 1 exemplary two part polymerizable system

% by Range ingredients lbs Kg L Function Weight (%)

COMPONENTA

Polypropylene diamine 53.21 24.14 24.21 Reactive amine 36.5 25-50 moisture scavenger 3.1

Zeolite Paste 4.55 2.06 1.79 - optional 0-5

Thixatrol ST 0.13 0.06 0.06 suspending agent 0.09 0-0.2

Airex 900 0.09 0.04 0.04 defoamer 0.06 <1

0.08 0.05-

Fumed Silica 0.10 0.05 0.02 thixotropic agent 0.10

Ammonium 20.8

Polyphosphate 30.40 13.79 7.26 Forms polymer char 0-30 Airex 900 0.03 0.01 0.01 Defoamer 0.02 <1

Diethyltoluene diamine 24.50 11.11 10.87 Reactive amine 16.8 0-25 coupling agent to 0.3

Silquest A-187 0.48 0.22 0.20 adhere to surface 0-1 graphite 3626 23.65 10.73 5.364 expander 16.2 0-30 graphite 3538 8.69 3.94 1.970 expander 6 0-30 sub total 145.82 66.14 51.80 100

COMPONENT B

TCPP 32.92 14.93 11 .58 flame retardant 24.8 0-40 polymeric 37.6

HXI 1624 50.00 22.68 19.89 isocyanate 0-100 combo harder or 37.6

HXI 1644 50.00 22.68 19.89 softer 0-100 sub total 132.92 60.29 51.36 100

TOTAL 278.74 126.44 103.16

[0037] Table 2 Further exemplary two part polymerizable system ingredients lbs Kg L

COMPONENT A

D-2000 1359.17 616.51 618.37

Zeolite Paste 116.22 52.72 45.63

Thixatrol ST 3.19 1.45 1.42

Airex 900 2.30 1.04 1.10

R-972 2.55 1.16 0.53

APP 776.55 352.24 185.39

Tio2 0.00 0.00 0.00

Raven 410

Red Oxide

Yellow Oxide

Airex 900 0.64 0.29 0.30

Ethacure 100 625.78 283.85 277.74

Silquest A-187 12.26 5.56 5.20 graphite 3626 604.07 274.00 130.478 graphite 3538 221.86 100.63 47.921 sub total 3724.59 1689.46 1314.08

COMPONENT B

TCPP 840.84 381.40 295.66

HXI 1624 1277.10 579.29 522.35

HXI 1644 1277.10 579.29 514.01 sub total 3395.04 1539.98 1332.02 I TOTAL 7119.63 3229.44 2646.10 |

[0038] In Table 2, a further exemplary system is illustrated This table is not necessarily indicative of every species present in each component Further, the amounts of pigment have not been indicated, as these will vary depending on the desired color This system has been used to create the flooring in the trains of the BART transport system in San Francisco In order to create component A (also known as the resin), a clean resin blend tank is placed on a platform scale, and D-2000 (polyamine) and the Zeolite paste are added Next, The tank is placed under a mixer and blended at high speed While mixing, the thixatrol, Airex 900, R-972 (fumed silica), APP (Ammonium polyphosphate), TiO2, Raven 410 (black paste), Red Oxide, and Yellow Oxide are added The mixture is then blended for 60 minutes, and the temperature is raised to 31 degrees Celsius The blender is then slowed to medium speed, and Airex 900), Silquest A-187 and graphite are added At first only the 3538 Graphite is added slowly and ground over 10 minutes Then, the 3626 Graphite is added slowly and ground over another 5 minutes The entire mixture is then blended at medium speed for 15 minutes A sample is then collected and submitted for quality control, and upon approval, the mixture is filled into storage drums

[0039] In order to create component B (also called the Iso), a clean ISO blend tank is placed on a scale DOP, if present, is removed from the tank, and HXI 1644, HXI 1624, and TCPP are added The tank is then placed under a mixer and blended for 45 minutes A sample is then collected and submitted for quality control, and upon approval, the mixture is filled into storage dαims DOP (dioctyl phthalate) is put into the tank before storage A single batch size used to create a coating 10 with these components may comprise 1323 liters of component A, and 1332 liters of component B Table 3 illustrates some E162 test results with exemplary coatings

[0040] For application, a regulated high-pressure proportioner (1 1) and spray gun system capable of producing 2000 - 2500 psi may be used Component A may be thoroughly mixed for 45 to 60 minutes prior to use Component A may also be preheated to achieve a uniform mix It should be checked that no residue is left on the bottom of drum after mixing Recommended Heat Settings include Line/Pre-Heaters 150 - 160 F, Hose Heat 150 - 160 F The components are then applied to a properly prepared substrate A first coat is applied at less than 10 mm and allowed to become tack free before continuing Following coats are then applied at 20 mm per coat, allowing the surface to become tack free before the application of subsequent coats The coating is sprayed with a uniform motion, allowing 50 to 75% overlap

(Is) = 27.03

[0042] Table 4 illustrates some physical properties of an exemplary coating used as flooring material in the BART system The exemplary finished spray flooring coating material with a thickness of 60 to 125 mil (1500 to 3000 micron) meets the requirements listed in Table 4

[0043] Table 4 Physical properties of exemplary coating used as flooring material

[0044] The exemplary flooring has been manufactured to meet the following test requirements for fire, smoke, toxicity, and friction In the Standard Test Method for Critical Radiant Flux of Floor Covering Systems Using a Radiant Heat Energy Source (Method ASTM E-648), the requirement was that the flooring have a Critical Radial Flux of more than or equal to 0 50 watts/sq cm In the Standard Method for Specific Optical Density of Smoke Generated by Solid Materials (Method ASTM E-662), the requirements in the flaming and non-flaming modes were Ds @ 1 5 minutes - maximum 100, DS @ 4 0 minutes - maximum 200, Dm @ 15 0 minutes - maximum 300, and Dm @ 20 0 minutes - maximum 300 In the Cone Calorimeter tests, three tests were required at each of the following 25, 50, and 75 kW/sq meter using horizontal sample position (Method ASTM E- 1354) The requirements were a maximum heat release rate of less than 150 kW/sq meter, an average heat release rate at 3 minutes of less than 100kW/sq meter, and an average heat release ignition to flameout of less than 50 kW/sq meter In the toxicity tests, (Bombardier test method SMP800 or Boeing test method BSS-7238 "Test Method for Smoke Generation by Materials in Combustion"), the requirements were that the generation of toxic gases identified below do not exceed the indicated concentration in either the flaming or non- flaming modes Carbon Monoxide (CO) 3500 ppm, Nitrogen Oxides (NO2) 100 ppm, Sulphur Dioxide (SO2) 100 ppm, Hydrogen Chloride (HCL) 500 ppm, Hydrogen Fluoride (HF) 200 ppm, and Hydrogen Cyanide (HCN) 150 ppm In the slip Resistance tests (Method ASTM C- 1028), the requirements were that the Coefficient of friction for both wet and dry conditions is 0 6 or greater In the Adhesion, Bonding tests, which illustrate the bonding strength of the spray coating to the fiberglass and steel substrate of the floor Method ASTM D-4541), the requirement was that the Pull-off strength, using a 20mm (0 79 inches) diameter plug, must be 500 psi or greater

[0045] Disclosed is a novel fire resistant polymer coating 10 This can be spray and injection moulded or spray applied to a wide range of substrates The rapid cure rate of this coating allows a fast return to service in retrofit applications and rapid deployment in OEM applications This coating may be used where all the benefits of durability and performance are needed, and where life safety is paramount, such as marine applications, passenger rail and mass transit Some physical properties may include a Flame Spread Classification (ASTM E84) of 20, a Smoke Developed Classification (ASTM E84) of 115, a Service Temperature of -50 to 200 C, a Shore Hardness of 50D approximately, an Elongation of 100%, and a Tensile Strength of 1000 psi

[0046] In some embodiments, the polyurea elastomer may have no polyurethane present This may be accomplished, for example, by providing component A with no polyols In some embodiments, in order to achieve the desired targets for flammability and smoke densities, polyurethane must be avoided Polyurethane is thermoplastic, and thus it may soften too much and fall away under the intense heat of flame, failing fire tests [0047] In some embodiments, a coating is provided that is a fire resistant, polyaspartic polyurea coating This coating may be designed to provide a flame resistant, UV resistant finish coat for application to metal, concrete or wood for example Table 5 illustrates an exemplary preparation for a coating 10 of this nature

[0048] Table 5 Exemplary polyaspartic coating

% by Range

Ingredients lbs Kg L weight (%)

COMPONENT A

Desmophen 1420 985.13 446.85 421.56 41.7 0-50

Desmophen XP 7076 146.93 66.65 76.61 6.2 10-Feb

Acematt TSIOO 0 0 0 0-5

Byk 333 4.31 1.95 1.88 0.2 <1

Additive OF 26.72 12.12 13.46 1.1 0.5-2

Propylene Carbonate 0 0 0 0-20

TCPP 0 0 0 0-25

Borchi GoI 0011 30.39 13.78 16.03 1.3 2-Jan

Eversorb 74 41.74 18.93 16.18 1.8 0-5

Tio2 46.72 21.19 5.3 2 Varies

Raven 410 1.44 0.65 0.36 0.1 Varies

Red Oxide 2.61 1.18 0.26 0.1 Varies

Yellow Oxide 7.31 3.32 0.72 0.3 Varies

APP 396.73 179.96 94.71 16.8 0-30 graphite 3626 316.6 143.61 71.805 13.4 0-25 graphite 3538 105.58 47.89 23.945 4.5 0-25

Eversorb 93 0 0 0

Desmophen 1520 250.46 113.61 107.18 10.6 0-50 sub total 2362.67 1071.7 850 100

COMPONENT B

TEP 523.62 237.51 221.97 32.2 0-50

MEK 0 0 0 0 0-10

Desmodur N-3600 1102.01 499.87 430.92 67.8 50-80

Xylene 0 0 0 0 0-10 sub total 1625.63 737.38 652.9 100

[0049] The polyaspartic polyurea uses an aliphatic isocyanate rather than for example an aromatic isocyanate, in order to impart different characteristics to the resulting coating, such as UV resistance Uv resistance makes the coating 10 more resistant to degradation by the sun The desmodur N-3600 is an HDI, which may be contrasted with the MDIs used in other coating 10 embodiments In some embodiments, a combination of MDI and HDI may be used

[0050] There are numerous examples of applications for the coatings 10 disclosed herein Examples include, but are not limited to, roofing, siding, insulation, wall covering, structural element coating, exterior covering for buildings or vehicles, floorways, walkways, and reinforcing covering

[0051] A flame retardant polymer composition is also disclosed comprising polymer matrix, spray processable graphite, a graphite stabilizer agent, and a flame retardant The polymer matrix may comprise at least one of polyurethane and polyurea In some embodiments, the polymer matrix comprises polyurethane It should be understood that the polymer composition may have all of the same characteristics, and be made in similar ways as, any of the coating 10 embodiments disclosed herein A skilled worker would understand that all of the methods disclosed herein may be adapted to create these polymer compositions, by substituting at least one of the polyamines and isocyanates in the preparations For example, a two part polymerizable system may be produced that will yield a polyurethane coating if polyols are used in component A Similar to coating 10, the flame retardant polymer composition may further comprise thixatrol as a graphite suspending agent In some embodiments, the flame retardant polymer composition is a coating In some embodiments, the polymer composition is a combination of polyurea and polyurethane

[0052] The system disclosed herein may be applied in the field using existing high output spray equipment The system meets fire properties that haven't been met in any system known to the inventors

[0053] In the claims, the word "comprising" is used in its inclusive sense and does not exclude other elements being present The indefinite article "a" before a claim feature does not exclude more than one of the feature being present Each one of the individual features described here may be used in one or more embodiments and is not, by virtue only of being described here, to be constaied as essential to all embodiments as defined by the claims

Claims

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS

1 A flame retardant coating comprising polyurea elastomer, spray processable graphite, a graphite stabilizer agent, and a flame retardant

2 The flame retardant coating of claim 1 further comprising thixatrol as a graphite suspending agent

3 The flame retardant coating of any one of claim 1 - claim 2 in which the graphite stabilizer agent comprises at least one of ammonium polyphosphate, zinc polyborate, melamine polyphosphate, melamine pyrophosphate, triethyl phosphate, and zinc phosphate

4 The flame retardant coating of any one of claim 1 - claim 3 further comprising a mineral matrix agent

5 The flame retardant coating of claim 4 in which the mineral matrix agent comprises at least one of glass and perlite

6 The flame retardant coating of any one of claim 1 - claim 5 formed by a two-part polymerizable system

7 The flame retardant coating of any one of claim 1 - claim 6 in which the spray processable graphite is 50-110 mesh, with at least 50% of the spray processable graphite being between 50 and 70 mesh 8 The flame retardant coating of any one of claim 1 - claim 7 used as flooring in a transport vehicle

9 The flame retardant coating of any one of claim 1 - claim 8 used as fire protection for staictural steel

10 The flame retardant coating of any one of claim 1 - claim 9 used as a rock reinforcing coating in an underground mine

11 A method of manufacturing a flame retardant polyurea elastomer coating, the method comprising providing a two part polymerizable system comprising a first part containing isocyanates, and a second part containing polyamines, in which at least one of the first part and the second part contains a flame retardant, and both of spray processable graphite and a graphite stabilizer agent, mixing the first part and the second part to form the flame retardant polyurea elastomer coating

12 A method of adhering a flame retardant polyurea elastomer coating to a smooth surface, the method comprising providing a first part containing isocyanates, and a second part containing polyamines, in which at least one of the first part and the second part contains a flame retardant, a mineral matrix agent, and both of spray processable graphite and a graphite stabilizer agent, mixing the first part and the second part to form the flame retardant polyurea elastomer coating on the smooth surface

13 The method of claim 12 in which the smooth surface comprises metal 14 The method of any one of claim 12 - claim 13 in which the smooth surface comprises phenolic composite panels

15 A method of manufacturing a flame retardant polyurea elastomer coating, the method comprising providing a two part polymerizable system comprising a first part containing isocyanates, and a second part containing polyamines, in which at least one of the first part and the second part contains both of spray processable graphite and thixatrol as a graphite suspending agent, mixing the first part and the second part to form the flame retardant polyurea elastomer coating

16 A flame retardant composition comprisin ⁱgg polymer matrix comprising at least one of polyurethane and polyurea, spray processable graphite, a graphite stabilizer agent, and a flame retardant

17 The flame retardant composition of claim 16 further comprising thixatrol as a graphite suspending agent

18 The flame retardant composition of any one of claim 16 - claim 17 in which the polymer matrix comprises polyurethane