WO2009154281A1 - Printed material and method for producing printed material - Google Patents
Printed material and method for producing printed material Download PDFInfo
- Publication number
- WO2009154281A1 WO2009154281A1 PCT/JP2009/061243 JP2009061243W WO2009154281A1 WO 2009154281 A1 WO2009154281 A1 WO 2009154281A1 JP 2009061243 W JP2009061243 W JP 2009061243W WO 2009154281 A1 WO2009154281 A1 WO 2009154281A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- resin
- printed matter
- transparent layer
- styrene
- printed
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims description 40
- 239000011347 resin Substances 0.000 claims abstract description 93
- 229920005989 resin Polymers 0.000 claims abstract description 93
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000839 emulsion Substances 0.000 claims abstract description 19
- 239000011342 resin composition Substances 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 150000007514 bases Chemical class 0.000 claims abstract description 13
- -1 amine compound Chemical class 0.000 claims abstract description 12
- 150000002334 glycols Chemical class 0.000 claims abstract description 12
- 235000011187 glycerol Nutrition 0.000 claims abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 15
- 239000000758 substrate Substances 0.000 claims description 13
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 12
- 239000004606 Fillers/Extenders Substances 0.000 claims description 11
- 239000006096 absorbing agent Substances 0.000 claims description 10
- 239000000049 pigment Substances 0.000 claims description 10
- 229920005792 styrene-acrylic resin Polymers 0.000 claims description 10
- 239000004925 Acrylic resin Substances 0.000 claims description 9
- 229920000178 Acrylic resin Polymers 0.000 claims description 9
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 9
- 238000013461 design Methods 0.000 description 76
- 230000001629 suppression Effects 0.000 description 51
- 239000000976 ink Substances 0.000 description 48
- 239000011111 cardboard Substances 0.000 description 30
- 230000000694 effects Effects 0.000 description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 239000000975 dye Substances 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002689 maleic acids Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- FBOUIAKEJMZPQG-AWNIVKPZSA-N (1E)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1Cl FBOUIAKEJMZPQG-AWNIVKPZSA-N 0.000 description 1
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 1
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 150000001656 butanoic acid esters Chemical class 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- LKKPNUDVOYAOBB-UHFFFAOYSA-N naphthalocyanine Chemical compound N1C(N=C2C3=CC4=CC=CC=C4C=C3C(N=C3C4=CC5=CC=CC=C5C=C4C(=N4)N3)=N2)=C(C=C2C(C=CC=C2)=C2)C2=C1N=C1C2=CC3=CC=CC=C3C=C2C4=N1 LKKPNUDVOYAOBB-UHFFFAOYSA-N 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/382—Special inks absorbing or reflecting infrared light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/387—Special inks absorbing or reflecting ultraviolet light
Definitions
- the present invention relates to a printed material and a printed material manufacturing method.
- the technology described above has been used to suppress imitation of printed materials of important documents such as securities and various certificates.
- the design of the cardboard case it is desired to adopt a printing technique that can suppress imitation of the product.
- the number of colors is 2 to 3 and printing of fine characters such as micro characters due to the printing specifications of printing on a non-smooth substrate such as corrugated cardboard.
- the printing method with low reproducibility that cannot be used is used, and the above-described technique cannot be used to suppress imitation of the design of the cardboard case.
- the present invention has been made in view of the above-described problems, and an object thereof is to provide a printed matter and a printed matter manufacturing method capable of suppressing imitation.
- the printed matter according to the first aspect of the present invention which has been made to solve the above-described problems, has a base material and a transparent layer that contains at least a resin emulsion and a resin composition and is disposed on the surface of the base material.
- the resin composition is a resin selected from the group consisting of water, glycerin, glycol, and glycol derivatives in the presence of at least one of an organic amine compound and an inorganic basic compound. It is dissolved in the above solvent.
- the resin in the resin composition may be the same resin as that contained in the resin emulsion, or may be a different resin.
- the transparent layer formed on the substrate surface reads the design (shape along the substrate surface, hereinafter also referred to as imitation suppression design) using a device such as a copying machine or a scanner. I can't. Therefore, imitation of the imitation suppression design can be suppressed by forming the imitation suppression design on the printed material in advance with a transparent layer. Thereby, it is possible to suppress the production of the printed material on which the imitation suppression design is formed using a copying machine or the like.
- the coating to the transparent layer surface by colored ink can be favorably performed by including a resin composition.
- the effect of suppressing imitation can be obtained simply by forming a transparent layer, there is no need for a high-quality printing device for printing micro characters or latent image patterns. Can be manufactured at a low cost.
- the transparent layer is irradiated with light and visually observed from an oblique direction with an angle with the normal to the substrate surface.
- the said base material is what can coat the surface by colored ink, for example, corrugated cardboard is mentioned.
- the said transparent layer should just be transparent to such an extent that the base-material surface can be visually recognized in the state formed in the base-material surface.
- the organic amine compound include monoethanolamine and triethanolamine.
- the inorganic basic compound include sodium hydroxide, potassium hydroxide, ammonium hydroxide and the like.
- the printed matter of the second aspect of the present invention is the printed matter of the first aspect, wherein the resin emulsion is a rosin-modified maleic resin, acrylic resin, styrene-acrylic resin, styrene-maleic resin, styrene-acrylic resin. It contains at least one resin selected from the group consisting of maleic acid-based resins and one or more solvents selected from the group consisting of water, glycerin, glycol and glycol derivatives.
- the printed matter of the third aspect of the present invention is the printed matter of the first aspect or the second aspect, wherein the resin in the resin composition is a rosin-modified maleic resin, an acrylic resin, a styrene-acrylic resin, a styrene-maleic acid type.
- the resin is one or more resins selected from the group consisting of styrene-acrylic-maleic acid resins.
- the printed matter according to the fourth aspect of the present invention is the printed matter according to any one of the first to third aspects, wherein the transparent layer contains an extender pigment.
- the drying property of the transparent layer is improved, so that the time required for drying can be reduced immediately after the transparent layer is formed.
- printing with colored inks other than the transparent layer can be easily executed in one step.
- the coating on the surface of the transparent layer with colored ink can be performed more satisfactorily.
- a colored layer of colored ink may be formed on the substrate surface.
- a colored layer design hereinafter also referred to as a normal design.
- the printed matter has the following fifth and sixth aspects.
- the printed matter according to the fifth aspect of the present invention is the printed matter according to any one of the first to fourth aspects, wherein a colored layer is formed on at least a part of the surface of the substrate and / or the surface of the transparent layer. It is characterized by that.
- the transparent layer can be hidden by the normal design with the colored layer and the shape of the imitation suppression design can be obscured. Can be suppressed.
- the printed matter of the sixth aspect of the present invention is characterized in that, in the printed matter of the fifth aspect, the colored layer is formed so as to cover the entire surface of the transparent layer. If it is a printed matter comprised in this way, since the transparent layer of the base-material surface can be hidden with a colored layer, discovery of a imitation suppression design can be made still more difficult.
- the printed matter according to the seventh aspect of the present invention is the printed matter according to any one of the first to sixth aspects, wherein the transparent layer contains an ultraviolet absorber. If it is a printed matter comprised in this way, since an ultraviolet absorber will light-emit and bulge out by irradiating an ultraviolet-ray, presence of a transparent layer can be confirmed easily.
- the printed matter according to an eighth aspect of the present invention is the printed matter according to any one of the first to seventh aspects, wherein the transparent layer contains an infrared absorber.
- the transparent layer contains an infrared absorber.
- the printed matter manufacturing method of the ninth aspect of the present invention comprises a transparent layer forming step of forming a transparent layer by applying a transparent layer forming material containing a resin emulsion and a resin composition to the surface of the substrate,
- the resin is used as a solvent comprising at least one selected from the group consisting of water, glycerin, glycol, and glycol derivatives in the presence of at least one of an organic amine compound and an inorganic basic compound. It has been dissolved.
- the resin in the resin composition may be the same resin as that contained in the resin emulsion, or may be a different resin.
- the printed matter which produces the effect similar to the printed matter of the 1st aspect of this invention can be manufactured.
- various commonly used methods such as printing can be applied.
- the method for producing a printed matter according to a tenth aspect of the present invention is the method for producing a printed matter according to the ninth aspect of the present invention, wherein the resin emulsion is a rosin-modified maleic acid resin, an acrylic resin, a styrene-acrylic resin, or a styrene-maleic acid system.
- Resin one or more resins selected from the group consisting of styrene-acrylic-maleic acid resins, and one or more solvents selected from the group consisting of water, glycerin, glycol, glycol derivatives It is a thing to do.
- the printed matter manufacturing method of the eleventh aspect of the present invention is the printed matter manufacturing method of the ninth or tenth aspect of the present invention, wherein the resin in the resin composition is a rosin-modified maleic resin, acrylic resin, styrene-acrylic resin. It is one or more resins selected from the group consisting of a resin, a styrene-maleic acid resin, and a styrene-acrylic-maleic acid resin.
- the printed matter manufacturing method of the twelfth aspect of the present invention is the printed matter manufacturing method of any one of the ninth to eleventh aspects of the present invention, wherein the transparent layer forming material contains an extender pigment.
- a printed matter manufacturing method is the printed matter manufacturing method according to any one of the ninth to twelfth aspects of the present invention, wherein the printed matter manufacturing method is provided on at least a part of the surface of the substrate surface and / or the transparent layer surface.
- a colored layer forming step of forming a colored layer is provided.
- the printed matter manufacturing method of the fourteenth aspect of the present invention is characterized in that, in the printed matter manufacturing method of the thirteenth aspect of the present invention, the colored layer is formed so as to cover the entire surface of the transparent layer.
- the printed matter manufacturing method of the fifteenth aspect of the present invention is characterized in that in the printed matter manufacturing method of any of the ninth to fourteenth aspects of the present invention, the transparent layer forming material contains an ultraviolet absorber.
- the method for producing a printed matter according to a sixteenth aspect of the present invention is the method for producing a printed matter according to any one of the ninth to fifteenth aspects of the present invention, wherein the transparent layer forming material contains an infrared absorber.
- the printed matter manufacturing method of the seventeenth aspect of the present invention is the printed matter manufacturing method of any one of the ninth to sixteenth aspects of the present invention, wherein the transparent layer forming step is performed by flexographic printing.
- Such a printed matter manufacturing method can produce a printed matter at low cost by flexographic printing.
- the transparent ink of this example comprises 10% by weight of a solvent, 40% by weight of an extender pigment, 40% by weight of a water-soluble resin (resin composition in the present invention), and 10% by weight of a resin emulsion. Details of each material will be described below.
- Solvent water, extender pigment: calcium carbonate, water-soluble resin: 25% by weight of rosin-modified maleic resin, 65% by weight of water (solvent), and 10% of triethylamine as a basic compound for dissolving the resin in water
- a transparent ink was produced by stirring and mixing the above materials.
- (2) Printing method A B flute sheet consisting of a K liner and a core was used as the corrugated base paper. For printing, a flexo folder gluer usually used in corrugated cardboard printing was used, and three colors of transparent ink and colored ink (1) were prepared. As the colored ink, DF04 red and DF26 sumi were used.
- the printing conditions are shown in Table 1 below.
- the printing environment was the same as the normal cardboard printing environment.
- imitation suppression design 2 was printed on cardboard 1 using transparent ink.
- the transparent ink was printed and then dried to form a transparent film (transparent layer in the present invention) composed of a rosin-modified maleic resin copolymer.
- Fig. 1 shows an example of an imitation suppression design 2 printed using transparent ink.
- This imitation suppression design 2 was created using JURA's GS art screen.
- This software is a software that can arrange an arbitrary character or symbol at random and create a pattern with the aggregate, and can create a pattern that is more difficult to imitate.
- FIG. 3 shows a schematic diagram of a corrugated board cross section after the normal design 3 is printed.
- the normal design 3 (colored ink) includes an area printed on the imitation suppression design 2 (transparent ink) and an area printed directly on the cardboard 1.
- the normal design 3 printed using this colored ink corresponds to the colored layer in the present invention.
- the imitation suppression design 2 and the normal design 3 were printed by passing the flexo folder gluer once.
- the imitation suppression design 2 printed in this way is almost invisible when the cardboard 1 is viewed from the front, but the shape can be confirmed when the cardboard is tilted obliquely and irradiated with light.
- the normal design 3 had no difference at a glance between the area printed on the imitation suppression design 2 and the area printed directly on the cardboard 1, and could be printed well in any area.
- (3) Test for confirming the effect The imitation suppression design of the cardboard printed by the above printing method was tried to imitate by the following method.
- FIG. 4 shows an image obtained by scanning the imitation suppression design printed with the transparent ink.
- FIG. 5 shows an image of the imitation suppression design of this test printed with colored ink.
- the imitation suppression design printed with clear ink could not be scanned at all. This is considered to be because reading is impossible unless the image can be recognized from the vertical direction because the scanner is a machine that reads data reflected by applying light to the medium from the vertical direction.
- the imitation suppression design was printed on the cardboard with transparent ink, and the normal design was printed with colored ink on the cardboard, which was then scanned with the scanner.
- the scanned image is shown in FIG. 6A. In FIG. 6A, the imitation suppression design is not shown on the cardboard, and it can be seen that scanning could not be performed.
- FIG. 6B a part of the characters “NOCOPY” by the imitation suppression design not seen in FIG. 6A is copied, and it can be seen that scanning was possible (the effect of imitation suppression was small).
- 7A and 7B show images taken of imitation suppression designs printed on different cardboards.
- photographed the imitation suppression design printed with colored ink for reference to FIG. 7C is shown.
- the configuration using water as the solvent constituting the transparent ink, the water-soluble resin, and the resin emulsion is exemplified, but a configuration using other solvents may be used.
- water, glycerin, glycol, glycol derivatives and the like can be selectively used alone or in combination depending on the printing environment.
- Diol compounds such as ethylene glycol, propylene glycol, butylene glycol and diethylene glycol can be used as the glycol component, and derivatives thereof include alkyl ether compounds such as methyl, ethyl, propyl, butyl, hexyl and octyl of the glycol, acetic acid.
- Ester compounds such as esters and butyric acid esters, and ester ether compounds can be used.
- the solvent constituting the transparent ink, the water-soluble resin, and the resin emulsion is 0 to 100% by weight of water, 0 to 80% by weight of glycerin, one or more solvents selected from the group consisting of glycol and glycol derivatives.
- the content ratio is preferably 50% by weight.
- the configuration using calcium carbonate as the extender is exemplified, but the white one usually used for flexographic relief printing ink can be used as it is.
- the white one usually used for flexographic relief printing ink can be used as it is.
- calcium carbonate kaolin, clay, barium sulfate, aluminum hydroxide, talc, titanium oxide, or the like may be used.
- the structure which uses only 1 type may be sufficient as an extender, and the structure which uses a some mixture may be sufficient as it.
- the configuration using the rosin-modified maleic acid resin as the resin constituting the water-soluble resin and the resin emulsion is exemplified, but the rosin-modified maleic resin, acrylic resin, styrene-acrylic resin, styrene- A resin selected from the group consisting of a maleic resin and a styrene-acrylic-maleic resin can be used.
- the water-soluble resin and the resin constituting the resin emulsion may be the same resin or different resins.
- the structure which uses a triethylamine as a basic compound which comprises water-soluble resin was illustrated, other organic amine compounds (monoethanolamine, a triethanolamine, etc.) may be sufficient, and an inorganic basic compound (water Sodium oxide, potassium hydroxide, ammonium hydroxide, etc.).
- an organic amine compound is used as the basic compound, an alkylammonium salt is produced as in the above examples.
- an inorganic basic compound is used, a saponified resin is produced. Regardless of which is produced, the transparent layer can be formed together with the copolymer of the resin contained in the resin emulsion in the same manner as in the above embodiment, and the colored ink can be printed favorably on the surface of the transparent layer.
- the mixing ratio of the resin, water, and basic compound in the water-soluble resin is preferably in the range of 15 to 25% by weight of the resin, 60 to 84% by weight of water, and 1 to 15% by weight of the basic compound. .
- the mixing ratio of the resin and water in the resin emulsion is preferably in the range of 40 to 50% by weight of resin and 50 to 60% by weight of water.
- the content ratio of each component in the transparent ink ranges from 0 to 30% by weight of the solvent, 0 to 50% by weight of the extender pigment, 20 to 50% by weight of the water-soluble resin, and 5 to 20% by weight of the resin emulsion. Is good.
- the extender pigment does not necessarily need to be contained, but by including the extender, the drying property of the transparent ink can be improved.
- the transparent ink may contain one or both of an ultraviolet absorber and an infrared absorber.
- an ultraviolet absorber When an ultraviolet absorber is contained, the ultraviolet absorber emits light and emerges when irradiated with ultraviolet rays, so that the presence of the transparent layer can be easily confirmed.
- an infrared absorber When an infrared absorber is contained, the infrared absorber absorbs infrared rays when irradiated with infrared rays. Therefore, the presence of the transparent layer can be easily confirmed by using an infrared absorption measuring device.
- ultraviolet absorbers such as a benzophenone type, a benzotriazole type, an acrylate type, a salicylate type, can be used, for example.
- infrared absorbers such as cyanine dyes, phthalocyanine dyes, naphthoquinone dyes, anthraquinone dyes, diol dyes, and triphenylmethane dyes can be used. Specific examples include metal naphthalocyanine pigments.
- the structure which prints a transparent ink and a colored ink by the process of a flexo folder gluer once was illustrated, you may print separately.
- the configuration in which the normal design is printed so as to partially overlap the imitation suppression design is illustrated, but the normal design may be printed so as to cover the entire imitation suppression design, and the imitation suppression may be suppressed.
- the normal design may be printed so as not to overlap the design.
- the structure which prints only an imitation suppression design on a cardboard may be sufficient.
- the normal design is printed so as to cover the entire imitation suppression design, the imitation suppression design on the surface of the corrugated cardboard can be hidden by the normal design, so that the detection of the imitation suppression design can be made more difficult.
Abstract
Disclosed is a printed material comprising a base and a transparent layer arranged on the surface of the base and containing at least a resin emulsion and a resin composition. The resin composition is obtained by dissolving a resin into a solvent, which is composed of one or more members selected from the group consisting of water, glycerin, glycols and glycol derivatives, in the presence of at least one of an organic amine compound and an inorganic basic compound.
Description
本発明は、印刷物および印刷物製造方法に関する。
The present invention relates to a printed material and a printed material manufacturing method.
近年、複写機や印刷装置の性能の向上、またパソコンやスキャナなどデジタル処理機の技術向上に伴うＤＴＰ技術の発展に伴い、印刷物の模倣・複製が簡易かつ精密に行えるようになってきている。そこで、従来、印刷物の複製を抑制するために、マイクロ文字を印刷する技術（特許文献１参照）、潜像模様および凹凸構造を形成する技術（特許文献２参照）、多色刷りなどの技術を利用している。
In recent years, with the development of DTP technology accompanying improvements in the performance of copiers and printing devices, and improvements in digital processing machines such as personal computers and scanners, it has become possible to imitate and duplicate printed materials easily and precisely. Therefore, conventionally, in order to suppress duplication of printed matter, a technique for printing micro characters (see Patent Document 1), a technique for forming a latent image pattern and a concavo-convex structure (see Patent Document 2), and a technique for multicolor printing are used. is doing.
上述した技術は有価証券や各種証明書などの重要書類の印刷物における模倣抑制に用いられていた。
一方、段ボールケースのデザインについても、商品の模倣を抑制できる印刷技術を採ることが望まれる。しかしながら、通常の作業工程で段ボールケースを印刷する場合には、段ボール板紙という平滑性のない基材に印刷するという印刷スペックの関係上、色数は２～３色でマイクロ文字など細かい文字の印刷ができない再現性の低い印刷方法が用いられており、段ボールケースのデザインの模倣を抑制するために上述した技術を用いることはできなかった。 The technology described above has been used to suppress imitation of printed materials of important documents such as securities and various certificates.
On the other hand, regarding the design of the cardboard case, it is desired to adopt a printing technique that can suppress imitation of the product. However, when printing corrugated cardboard cases in the normal work process, the number of colors is 2 to 3 and printing of fine characters such as micro characters due to the printing specifications of printing on a non-smooth substrate such as corrugated cardboard. The printing method with low reproducibility that cannot be used is used, and the above-described technique cannot be used to suppress imitation of the design of the cardboard case.
一方、段ボールケースのデザインについても、商品の模倣を抑制できる印刷技術を採ることが望まれる。しかしながら、通常の作業工程で段ボールケースを印刷する場合には、段ボール板紙という平滑性のない基材に印刷するという印刷スペックの関係上、色数は２～３色でマイクロ文字など細かい文字の印刷ができない再現性の低い印刷方法が用いられており、段ボールケースのデザインの模倣を抑制するために上述した技術を用いることはできなかった。 The technology described above has been used to suppress imitation of printed materials of important documents such as securities and various certificates.
On the other hand, regarding the design of the cardboard case, it is desired to adopt a printing technique that can suppress imitation of the product. However, when printing corrugated cardboard cases in the normal work process, the number of colors is 2 to 3 and printing of fine characters such as micro characters due to the printing specifications of printing on a non-smooth substrate such as corrugated cardboard. The printing method with low reproducibility that cannot be used is used, and the above-described technique cannot be used to suppress imitation of the design of the cardboard case.
本発明は、上述した問題に鑑みてなされたものであり、模倣を抑制できる印刷物および印刷物製造方法を提供することを目的とする。
The present invention has been made in view of the above-described problems, and an object thereof is to provide a printed matter and a printed matter manufacturing method capable of suppressing imitation.
上述した問題を解決するためになされた本発明の第１局面の印刷物は、基材と、少なくとも樹脂エマルジョンおよび樹脂組成物を含有し、前記基材表面に配置される透明層と、を有するものであって、前記樹脂組成物は、樹脂を、有機アミン化合物および無機塩基性化合物のうち少なくともいずれか一方の存在下にて、水，グリセリン，グリコール，グリコール誘導体からなる群から選択される１種以上からなる溶媒に溶解させたものである。なお、樹脂組成物における樹脂は、樹脂エマルジョンに含有される樹脂と同じ樹脂であってもよいし、異なる樹脂であってもよい。
The printed matter according to the first aspect of the present invention, which has been made to solve the above-described problems, has a base material and a transparent layer that contains at least a resin emulsion and a resin composition and is disposed on the surface of the base material. The resin composition is a resin selected from the group consisting of water, glycerin, glycol, and glycol derivatives in the presence of at least one of an organic amine compound and an inorganic basic compound. It is dissolved in the above solvent. The resin in the resin composition may be the same resin as that contained in the resin emulsion, or may be a different resin.
このように構成された印刷物において、基材表面に形成された透明層は、そのデザイン（基板表面に沿った形状、以下模倣抑制デザインともいう）を複写機やスキャナなどの装置を用いて読み取ることができない。したがって、印刷物に予め透明層で模倣抑制デザインを形成しておくことで、模倣抑制デザインの模倣を抑制できる。それにより、当該模倣抑制デザインが形成された印刷物の偽物を、複写機等を用いて製造されることを抑制できる。
In the printed matter configured in this way, the transparent layer formed on the substrate surface reads the design (shape along the substrate surface, hereinafter also referred to as imitation suppression design) using a device such as a copying machine or a scanner. I can't. Therefore, imitation of the imitation suppression design can be suppressed by forming the imitation suppression design on the printed material in advance with a transparent layer. Thereby, it is possible to suppress the production of the printed material on which the imitation suppression design is formed using a copying machine or the like.
また、樹脂組成物が含まれることにより、有色インキによる透明層表面への塗装を良好に行うことができる。
また、透明層を形成するだけで模倣を抑制する効果を得ることができるので、マイクロ文字や潜像模様などを印刷するための高品質な印刷装置が必要ないため、通常の印刷工程と同程度のコストで製造することができる。 Moreover, the coating to the transparent layer surface by colored ink can be favorably performed by including a resin composition.
In addition, since the effect of suppressing imitation can be obtained simply by forming a transparent layer, there is no need for a high-quality printing device for printing micro characters or latent image patterns. Can be manufactured at a low cost.
また、透明層を形成するだけで模倣を抑制する効果を得ることができるので、マイクロ文字や潜像模様などを印刷するための高品質な印刷装置が必要ないため、通常の印刷工程と同程度のコストで製造することができる。 Moreover, the coating to the transparent layer surface by colored ink can be favorably performed by including a resin composition.
In addition, since the effect of suppressing imitation can be obtained simply by forming a transparent layer, there is no need for a high-quality printing device for printing micro characters or latent image patterns. Can be manufactured at a low cost.
模倣抑制デザインの確認方法としては、例えば、透明層に光を当てて、基材表面の垂線と角度をつけた斜め方向から目視することが挙げられる。
なお、上記基材とは、有色インキによる表面の塗装が可能なものであり、例えば段ボールが挙げられる。 As a confirmation method of the imitation suppression design, for example, the transparent layer is irradiated with light and visually observed from an oblique direction with an angle with the normal to the substrate surface.
In addition, the said base material is what can coat the surface by colored ink, for example, corrugated cardboard is mentioned.
なお、上記基材とは、有色インキによる表面の塗装が可能なものであり、例えば段ボールが挙げられる。 As a confirmation method of the imitation suppression design, for example, the transparent layer is irradiated with light and visually observed from an oblique direction with an angle with the normal to the substrate surface.
In addition, the said base material is what can coat the surface by colored ink, for example, corrugated cardboard is mentioned.
また、上記透明層は、基材表面に形成された状態で実質的に基材表面が視認できる程度に透明であればよい。
また、有機アミン化合物としては、例えば、モノエタノールアミン，トリエタノールアミン等が挙げられる。また、無機塩基性化合物としては、水酸化ナトリウム、水酸化カリウム、水酸化アンモニウム等が挙げられる。 Moreover, the said transparent layer should just be transparent to such an extent that the base-material surface can be visually recognized in the state formed in the base-material surface.
Examples of the organic amine compound include monoethanolamine and triethanolamine. Examples of the inorganic basic compound include sodium hydroxide, potassium hydroxide, ammonium hydroxide and the like.
また、有機アミン化合物としては、例えば、モノエタノールアミン，トリエタノールアミン等が挙げられる。また、無機塩基性化合物としては、水酸化ナトリウム、水酸化カリウム、水酸化アンモニウム等が挙げられる。 Moreover, the said transparent layer should just be transparent to such an extent that the base-material surface can be visually recognized in the state formed in the base-material surface.
Examples of the organic amine compound include monoethanolamine and triethanolamine. Examples of the inorganic basic compound include sodium hydroxide, potassium hydroxide, ammonium hydroxide and the like.
本発明の第２局面の印刷物は、第１局面の印刷物において、前記樹脂エマルジョンが、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群のから選択される１種以上の樹脂と、水，グリセリン，グリコール，グリコール誘導体からなる群から選択される１種以上からなる溶媒と、を含有するものであることを特徴とする。
The printed matter of the second aspect of the present invention is the printed matter of the first aspect, wherein the resin emulsion is a rosin-modified maleic resin, acrylic resin, styrene-acrylic resin, styrene-maleic resin, styrene-acrylic resin. It contains at least one resin selected from the group consisting of maleic acid-based resins and one or more solvents selected from the group consisting of water, glycerin, glycol and glycol derivatives. Features.
このように構成された印刷物であれば、模倣抑制デザインの模倣抑制を良好に実現することができる。
本発明の第３局面の印刷物は、第１局面または第２局面の印刷物において、前記樹脂組成物における樹脂が、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群から選択される１種以上の樹脂であることを特徴とする。 If it is a printed matter comprised in this way, imitation suppression of an imitation suppression design can be implement | achieved favorably.
The printed matter of the third aspect of the present invention is the printed matter of the first aspect or the second aspect, wherein the resin in the resin composition is a rosin-modified maleic resin, an acrylic resin, a styrene-acrylic resin, a styrene-maleic acid type. The resin is one or more resins selected from the group consisting of styrene-acrylic-maleic acid resins.
本発明の第３局面の印刷物は、第１局面または第２局面の印刷物において、前記樹脂組成物における樹脂が、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群から選択される１種以上の樹脂であることを特徴とする。 If it is a printed matter comprised in this way, imitation suppression of an imitation suppression design can be implement | achieved favorably.
The printed matter of the third aspect of the present invention is the printed matter of the first aspect or the second aspect, wherein the resin in the resin composition is a rosin-modified maleic resin, an acrylic resin, a styrene-acrylic resin, a styrene-maleic acid type. The resin is one or more resins selected from the group consisting of styrene-acrylic-maleic acid resins.
このように構成された印刷物であれば、透明層表面において良好に有色インキを塗布することができる。
本発明の第４局面の印刷物は、第１局面～第３局面のいずれかの印刷物において、前記透明層が体質顔料を含有することを特徴とする。 If it is a printed matter comprised in this way, colored ink can be favorably apply | coated on the transparent layer surface.
The printed matter according to the fourth aspect of the present invention is the printed matter according to any one of the first to third aspects, wherein the transparent layer contains an extender pigment.
本発明の第４局面の印刷物は、第１局面～第３局面のいずれかの印刷物において、前記透明層が体質顔料を含有することを特徴とする。 If it is a printed matter comprised in this way, colored ink can be favorably apply | coated on the transparent layer surface.
The printed matter according to the fourth aspect of the present invention is the printed matter according to any one of the first to third aspects, wherein the transparent layer contains an extender pigment.
このように構成された印刷物であれば、透明層の乾燥性が向上するため、透明層を形成した直後に乾燥のために必要な時間が低減できる。それにより、例えば透明層以外の有色インキ等による印刷を一の工程で容易に実行できるようになる。また、有色インキによる透明層表面への塗装がさらに良好に行うことができるようになる。
If the printed matter has such a configuration, the drying property of the transparent layer is improved, so that the time required for drying can be reduced immediately after the transparent layer is formed. Thereby, for example, printing with colored inks other than the transparent layer can be easily executed in one step. In addition, the coating on the surface of the transparent layer with colored ink can be performed more satisfactorily.
ところで、基材表面に有色インキによる有色層が形成される場合がある。例えば段ボールの場合、表面に内容物や製造者を表示する印刷が行われる。模倣抑制デザインは、そのような有色層によるデザイン（以下、通常デザインともいう）に組み合わせて使用することができる。具体的には、次の第５局面、第６局面の印刷物の構成とすることが考えられる。
By the way, a colored layer of colored ink may be formed on the substrate surface. For example, in the case of cardboard, printing is performed to display the contents and manufacturer on the surface. The counterfeit suppression design can be used in combination with such a colored layer design (hereinafter also referred to as a normal design). Specifically, it is conceivable that the printed matter has the following fifth and sixth aspects.
本発明の第５局面の印刷物は、第１局面～第４局面のいずれかの印刷物において、前記基材表面および／または前記透明層表面における少なくとも一部の領域上に有色層が形成されてなることを特徴とする。
The printed matter according to the fifth aspect of the present invention is the printed matter according to any one of the first to fourth aspects, wherein a colored layer is formed on at least a part of the surface of the substrate and / or the surface of the transparent layer. It is characterized by that.
このように構成された印刷物であれば、有色層による通常デザインにより透明層を隠すことや模倣抑制デザインの形状を不明瞭にすることができるため、模倣抑制デザインの他者からの発見や模倣を抑制することができる。
If the printed matter is configured in this way, the transparent layer can be hidden by the normal design with the colored layer and the shape of the imitation suppression design can be obscured. Can be suppressed.
また、本発明の第６局面の印刷物は、第５局面の印刷物において、前記有色層が、前記透明層表面を全て覆うように形成されることを特徴とする。
このように構成された印刷物であれば、基材表面の透明層を有色層によって隠すことができるため、模倣抑制デザインの発見をさらに困難にすることができる。 The printed matter of the sixth aspect of the present invention is characterized in that, in the printed matter of the fifth aspect, the colored layer is formed so as to cover the entire surface of the transparent layer.
If it is a printed matter comprised in this way, since the transparent layer of the base-material surface can be hidden with a colored layer, discovery of a imitation suppression design can be made still more difficult.
このように構成された印刷物であれば、基材表面の透明層を有色層によって隠すことができるため、模倣抑制デザインの発見をさらに困難にすることができる。 The printed matter of the sixth aspect of the present invention is characterized in that, in the printed matter of the fifth aspect, the colored layer is formed so as to cover the entire surface of the transparent layer.
If it is a printed matter comprised in this way, since the transparent layer of the base-material surface can be hidden with a colored layer, discovery of a imitation suppression design can be made still more difficult.
本発明の第７局面の印刷物は、第１局面～第６局面のいずれかの印刷物において、前記透明層が紫外線吸収剤を含有することを特徴とする。
このように構成された印刷物であれば、紫外線を照射することにより紫外線吸収剤が発光して浮き出すため、容易に透明層の存在を確認することができる。 The printed matter according to the seventh aspect of the present invention is the printed matter according to any one of the first to sixth aspects, wherein the transparent layer contains an ultraviolet absorber.
If it is a printed matter comprised in this way, since an ultraviolet absorber will light-emit and bulge out by irradiating an ultraviolet-ray, presence of a transparent layer can be confirmed easily.
このように構成された印刷物であれば、紫外線を照射することにより紫外線吸収剤が発光して浮き出すため、容易に透明層の存在を確認することができる。 The printed matter according to the seventh aspect of the present invention is the printed matter according to any one of the first to sixth aspects, wherein the transparent layer contains an ultraviolet absorber.
If it is a printed matter comprised in this way, since an ultraviolet absorber will light-emit and bulge out by irradiating an ultraviolet-ray, presence of a transparent layer can be confirmed easily.
本発明の第８局面の印刷物は、第１局面～第７局面のいずれかの印刷物において、前記透明層が赤外線吸収剤を含有することを特徴とする。
このように構成された印刷物であれば、赤外線を照射すると赤外線吸収剤が赤外線を吸収するため、赤外線吸収測定装置を用いることにより容易に透明層の存在を確認することができる。 The printed matter according to an eighth aspect of the present invention is the printed matter according to any one of the first to seventh aspects, wherein the transparent layer contains an infrared absorber.
In the case of a printed matter configured as described above, when an infrared ray is irradiated, the infrared absorbent absorbs the infrared ray. Therefore, the presence of the transparent layer can be easily confirmed by using an infrared absorption measuring device.
このように構成された印刷物であれば、赤外線を照射すると赤外線吸収剤が赤外線を吸収するため、赤外線吸収測定装置を用いることにより容易に透明層の存在を確認することができる。 The printed matter according to an eighth aspect of the present invention is the printed matter according to any one of the first to seventh aspects, wherein the transparent layer contains an infrared absorber.
In the case of a printed matter configured as described above, when an infrared ray is irradiated, the infrared absorbent absorbs the infrared ray. Therefore, the presence of the transparent layer can be easily confirmed by using an infrared absorption measuring device.
本発明の第９局面の印刷物製造方法は、基材表面に、樹脂エマルジョンおよび樹脂組成物を含有する透明層形成材料を塗布することで透明層を形成する透明層形成工程を備えており、前記樹脂組成物は、樹脂を、有機アミン化合物および無機塩基性化合物のうち少なくともいずれか一方の存在下にて、水，グリセリン，グリコール，グリコール誘導体からなる群から選択される１種以上からなる溶媒に溶解させたものである。なお、樹脂組成物における樹脂は、樹脂エマルジョンに含有される樹脂と同じ樹脂であってもよいし、異なる樹脂であってもよい。
The printed matter manufacturing method of the ninth aspect of the present invention comprises a transparent layer forming step of forming a transparent layer by applying a transparent layer forming material containing a resin emulsion and a resin composition to the surface of the substrate, In the resin composition, the resin is used as a solvent comprising at least one selected from the group consisting of water, glycerin, glycol, and glycol derivatives in the presence of at least one of an organic amine compound and an inorganic basic compound. It has been dissolved. The resin in the resin composition may be the same resin as that contained in the resin emulsion, or may be a different resin.
このような印刷物製造方法であれば、本発明の第１局面の印刷物と同様の効果を奏する印刷物を製造することができる。
なお、上述した塗布の具体的な態様としては、印刷などの一般的に用いられる様々な方法を適用することができる。 If it is such a printed matter manufacturing method, the printed matter which produces the effect similar to the printed matter of the 1st aspect of this invention can be manufactured.
In addition, as a specific aspect of the application described above, various commonly used methods such as printing can be applied.
なお、上述した塗布の具体的な態様としては、印刷などの一般的に用いられる様々な方法を適用することができる。 If it is such a printed matter manufacturing method, the printed matter which produces the effect similar to the printed matter of the 1st aspect of this invention can be manufactured.
In addition, as a specific aspect of the application described above, various commonly used methods such as printing can be applied.
本発明の第１０局面の印刷物製造方法は、本発明の第９局面の印刷物製造方法において、前記樹脂エマルジョンが、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群から選択される１種以上の樹脂と、水，グリセリン，グリコール，グリコール誘導体からなる群から選択される１種以上からなる溶媒と、を含有するものであることを特徴とする。
The method for producing a printed matter according to a tenth aspect of the present invention is the method for producing a printed matter according to the ninth aspect of the present invention, wherein the resin emulsion is a rosin-modified maleic acid resin, an acrylic resin, a styrene-acrylic resin, or a styrene-maleic acid system. Resin, one or more resins selected from the group consisting of styrene-acrylic-maleic acid resins, and one or more solvents selected from the group consisting of water, glycerin, glycol, glycol derivatives It is a thing to do.
このような印刷物製造方法であれば、本発明の第２局面の印刷物と同様の効果を奏する印刷物を製造することができる。
本発明の第１１局面の印刷物製造方法は、本発明の第９局面または第１０局面の印刷物製造方法において、前記樹脂組成物における樹脂が、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群から選択される１種以上の樹脂であることを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which has an effect similar to the printed matter of the 2nd aspect of this invention can be manufactured.
The printed matter manufacturing method of the eleventh aspect of the present invention is the printed matter manufacturing method of the ninth or tenth aspect of the present invention, wherein the resin in the resin composition is a rosin-modified maleic resin, acrylic resin, styrene-acrylic resin. It is one or more resins selected from the group consisting of a resin, a styrene-maleic acid resin, and a styrene-acrylic-maleic acid resin.
本発明の第１１局面の印刷物製造方法は、本発明の第９局面または第１０局面の印刷物製造方法において、前記樹脂組成物における樹脂が、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群から選択される１種以上の樹脂であることを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which has an effect similar to the printed matter of the 2nd aspect of this invention can be manufactured.
The printed matter manufacturing method of the eleventh aspect of the present invention is the printed matter manufacturing method of the ninth or tenth aspect of the present invention, wherein the resin in the resin composition is a rosin-modified maleic resin, acrylic resin, styrene-acrylic resin. It is one or more resins selected from the group consisting of a resin, a styrene-maleic acid resin, and a styrene-acrylic-maleic acid resin.
このような印刷物製造方法であれば、本発明の第３局面の印刷物と同様の効果を奏する印刷物を製造することができる。
本発明の第１２局面の印刷物製造方法は、本発明の第９局面～第１１局面のいずれかの印刷物製造方法において、前記透明層形成材料が、体質顔料を含有することを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which produces the effect similar to the printed matter of the 3rd aspect of this invention can be manufactured.
The printed matter manufacturing method of the twelfth aspect of the present invention is the printed matter manufacturing method of any one of the ninth to eleventh aspects of the present invention, wherein the transparent layer forming material contains an extender pigment.
本発明の第１２局面の印刷物製造方法は、本発明の第９局面～第１１局面のいずれかの印刷物製造方法において、前記透明層形成材料が、体質顔料を含有することを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which produces the effect similar to the printed matter of the 3rd aspect of this invention can be manufactured.
The printed matter manufacturing method of the twelfth aspect of the present invention is the printed matter manufacturing method of any one of the ninth to eleventh aspects of the present invention, wherein the transparent layer forming material contains an extender pigment.
このような印刷物製造方法であれば、本発明の第４局面の印刷物と同様の効果を奏する印刷物を製造することができる。
本発明の第１３局面の印刷物製造方法は、本発明の第９局面～第１２局面のいずれかの印刷物製造方法において、前記基材表面および／または前記透明層表面における少なくとも一部の領域上に有色層を形成する有色層形成工程を備えることを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which has an effect similar to the printed matter of the 4th aspect of this invention can be manufactured.
A printed matter manufacturing method according to a thirteenth aspect of the present invention is the printed matter manufacturing method according to any one of the ninth to twelfth aspects of the present invention, wherein the printed matter manufacturing method is provided on at least a part of the surface of the substrate surface and / or the transparent layer surface. A colored layer forming step of forming a colored layer is provided.
本発明の第１３局面の印刷物製造方法は、本発明の第９局面～第１２局面のいずれかの印刷物製造方法において、前記基材表面および／または前記透明層表面における少なくとも一部の領域上に有色層を形成する有色層形成工程を備えることを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which has an effect similar to the printed matter of the 4th aspect of this invention can be manufactured.
A printed matter manufacturing method according to a thirteenth aspect of the present invention is the printed matter manufacturing method according to any one of the ninth to twelfth aspects of the present invention, wherein the printed matter manufacturing method is provided on at least a part of the surface of the substrate surface and / or the transparent layer surface. A colored layer forming step of forming a colored layer is provided.
このような印刷物製造方法であれば、本発明の第５局面の印刷物と同様の効果を奏する印刷物を製造することができる。
本発明の第１４局面の印刷物製造方法は、本発明の第１３局面の印刷物製造方法において、前記有色層が前記透明層表面を全て覆うように形成されることを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which produces the effect similar to the printed matter of the 5th aspect of this invention can be manufactured.
The printed matter manufacturing method of the fourteenth aspect of the present invention is characterized in that, in the printed matter manufacturing method of the thirteenth aspect of the present invention, the colored layer is formed so as to cover the entire surface of the transparent layer.
本発明の第１４局面の印刷物製造方法は、本発明の第１３局面の印刷物製造方法において、前記有色層が前記透明層表面を全て覆うように形成されることを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which produces the effect similar to the printed matter of the 5th aspect of this invention can be manufactured.
The printed matter manufacturing method of the fourteenth aspect of the present invention is characterized in that, in the printed matter manufacturing method of the thirteenth aspect of the present invention, the colored layer is formed so as to cover the entire surface of the transparent layer.
このような印刷物製造方法であれば、本発明の第６局面の印刷物と同様の効果を奏する印刷物を製造することができる。
本発明の第１５局面の印刷物製造方法は、本発明の第９局面～第１４局面のいずれかの印刷物製造方法において、前記透明層形成材料が紫外線吸収剤を含有することを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which has an effect similar to the printed matter of the 6th aspect of this invention can be manufactured.
The printed matter manufacturing method of the fifteenth aspect of the present invention is characterized in that in the printed matter manufacturing method of any of the ninth to fourteenth aspects of the present invention, the transparent layer forming material contains an ultraviolet absorber.
本発明の第１５局面の印刷物製造方法は、本発明の第９局面～第１４局面のいずれかの印刷物製造方法において、前記透明層形成材料が紫外線吸収剤を含有することを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which has an effect similar to the printed matter of the 6th aspect of this invention can be manufactured.
The printed matter manufacturing method of the fifteenth aspect of the present invention is characterized in that in the printed matter manufacturing method of any of the ninth to fourteenth aspects of the present invention, the transparent layer forming material contains an ultraviolet absorber.
このような印刷物製造方法であれば、本発明の第７局面の印刷物と同様の効果を奏する印刷物を製造することができる。
本発明の第１６局面の印刷物製造方法は、本発明の第９局面～第１５局面のいずれかの印刷物製造方法において、前記透明層形成材料が赤外線吸収剤を含有することを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which produces the effect similar to the printed matter of the 7th aspect of this invention can be manufactured.
The method for producing a printed matter according to a sixteenth aspect of the present invention is the method for producing a printed matter according to any one of the ninth to fifteenth aspects of the present invention, wherein the transparent layer forming material contains an infrared absorber.
本発明の第１６局面の印刷物製造方法は、本発明の第９局面～第１５局面のいずれかの印刷物製造方法において、前記透明層形成材料が赤外線吸収剤を含有することを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which produces the effect similar to the printed matter of the 7th aspect of this invention can be manufactured.
The method for producing a printed matter according to a sixteenth aspect of the present invention is the method for producing a printed matter according to any one of the ninth to fifteenth aspects of the present invention, wherein the transparent layer forming material contains an infrared absorber.
このような印刷物製造方法であれば、本発明の第８局面の印刷物と同様の効果を奏する印刷物を製造することができる。
本発明の第１７局面の印刷物製造方法は、本発明の第９局面～第１６局面のいずれかの印刷物製造方法において、前記透明層形成工程がフレキソ印刷により実行されることを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which has an effect similar to the printed matter of the 8th aspect of this invention can be manufactured.
The printed matter manufacturing method of the seventeenth aspect of the present invention is the printed matter manufacturing method of any one of the ninth to sixteenth aspects of the present invention, wherein the transparent layer forming step is performed by flexographic printing.
本発明の第１７局面の印刷物製造方法は、本発明の第９局面～第１６局面のいずれかの印刷物製造方法において、前記透明層形成工程がフレキソ印刷により実行されることを特徴とする。 If it is such a printed matter manufacturing method, the printed matter which has an effect similar to the printed matter of the 8th aspect of this invention can be manufactured.
The printed matter manufacturing method of the seventeenth aspect of the present invention is the printed matter manufacturing method of any one of the ninth to sixteenth aspects of the present invention, wherein the transparent layer forming step is performed by flexographic printing.
このような印刷物製造方法であれば、フレキソ印刷により低コストで印刷物を製造することができる。
Such a printed matter manufacturing method can produce a printed matter at low cost by flexographic printing.
１…段ボール、２…模倣抑制デザイン（透明インキによる透明層）、３…通常デザイン（有色インキによる有色層）
1 ... Corrugated cardboard, 2 ... Imitation suppression design (transparent layer with transparent ink), 3 ... Normal design (colored layer with colored ink)
1 ... Corrugated cardboard, 2 ... Imitation suppression design (transparent layer with transparent ink), 3 ... Normal design (colored layer with colored ink)
以下に本発明の実施形態を図面と共に説明する。
［実施例］
本実施例では、以下に説明する透明インキ（本発明における透明層形成材料）を用いて、段ボールに模倣抑制デザインを印刷した印刷物を製造した。
（１）透明インキの構成
本実施例の透明インキは、溶媒１０重量％、体質顔料４０重量％、水溶性樹脂（本発明における樹脂組成物）４０重量％、樹脂エマルジョン１０重量％、からなる。各材料の詳細を以下に説明する。
・溶媒：水
・体質顔料：炭酸カルシウム
・水溶性樹脂：ロジン変性マレイン酸樹脂２５重量％と、水（溶媒）６５重量％と、樹脂を水に溶解させるための塩基性化合物としてのトリエチルアミン１０重量％と、の混合物
・樹脂エマルジョン：ロジン変性マレイン酸樹脂４０重量％と水（溶媒）６０重量％との混合物
透明インキは上記材料を攪拌混合して製造した。
（２）印刷方法
段ボール原紙にＫライナーと中芯からなるＢフルートのシートを使用した。印刷には通常段ボール印刷で使用されるフレキソフォルダーグルアーを使用し、上記（１）の透明インキ＋有色インキの２色の３色を用意した。有色インキは、ＤＦ０４赤、ＤＦ２６スミ、を使用した。 Embodiments of the present invention will be described below with reference to the drawings.
[Example]
In the present Example, the printed matter which printed the imitation suppression design on the cardboard was manufactured using the transparent ink (transparent layer forming material in this invention) demonstrated below.
(1) Constitution of transparent ink The transparent ink of this example comprises 10% by weight of a solvent, 40% by weight of an extender pigment, 40% by weight of a water-soluble resin (resin composition in the present invention), and 10% by weight of a resin emulsion. Details of each material will be described below.
Solvent: water, extender pigment: calcium carbonate, water-soluble resin: 25% by weight of rosin-modified maleic resin, 65% by weight of water (solvent), and 10% of triethylamine as a basic compound for dissolving the resin in water A mixture of 40% by weight of rosin-modified maleic resin and 60% by weight of water (solvent) A transparent ink was produced by stirring and mixing the above materials.
(2) Printing method A B flute sheet consisting of a K liner and a core was used as the corrugated base paper. For printing, a flexo folder gluer usually used in corrugated cardboard printing was used, and three colors of transparent ink and colored ink (1) were prepared. As the colored ink, DF04 red and DF26 sumi were used.
［実施例］
本実施例では、以下に説明する透明インキ（本発明における透明層形成材料）を用いて、段ボールに模倣抑制デザインを印刷した印刷物を製造した。
（１）透明インキの構成
本実施例の透明インキは、溶媒１０重量％、体質顔料４０重量％、水溶性樹脂（本発明における樹脂組成物）４０重量％、樹脂エマルジョン１０重量％、からなる。各材料の詳細を以下に説明する。
・溶媒：水
・体質顔料：炭酸カルシウム
・水溶性樹脂：ロジン変性マレイン酸樹脂２５重量％と、水（溶媒）６５重量％と、樹脂を水に溶解させるための塩基性化合物としてのトリエチルアミン１０重量％と、の混合物
・樹脂エマルジョン：ロジン変性マレイン酸樹脂４０重量％と水（溶媒）６０重量％との混合物
透明インキは上記材料を攪拌混合して製造した。
（２）印刷方法
段ボール原紙にＫライナーと中芯からなるＢフルートのシートを使用した。印刷には通常段ボール印刷で使用されるフレキソフォルダーグルアーを使用し、上記（１）の透明インキ＋有色インキの２色の３色を用意した。有色インキは、ＤＦ０４赤、ＤＦ２６スミ、を使用した。 Embodiments of the present invention will be described below with reference to the drawings.
[Example]
In the present Example, the printed matter which printed the imitation suppression design on the cardboard was manufactured using the transparent ink (transparent layer forming material in this invention) demonstrated below.
(1) Constitution of transparent ink The transparent ink of this example comprises 10% by weight of a solvent, 40% by weight of an extender pigment, 40% by weight of a water-soluble resin (resin composition in the present invention), and 10% by weight of a resin emulsion. Details of each material will be described below.
Solvent: water, extender pigment: calcium carbonate, water-soluble resin: 25% by weight of rosin-modified maleic resin, 65% by weight of water (solvent), and 10% of triethylamine as a basic compound for dissolving the resin in water A mixture of 40% by weight of rosin-modified maleic resin and 60% by weight of water (solvent) A transparent ink was produced by stirring and mixing the above materials.
(2) Printing method A B flute sheet consisting of a K liner and a core was used as the corrugated base paper. For printing, a flexo folder gluer usually used in corrugated cardboard printing was used, and three colors of transparent ink and colored ink (1) were prepared. As the colored ink, DF04 red and DF26 sumi were used.
印刷条件を以下の表１に示す。印刷環境は通常の段ボール印刷の環境と同等とした。
The printing conditions are shown in Table 1 below. The printing environment was the same as the normal cardboard printing environment.
図１に、透明インキを使用して印刷された模倣抑制デザイン２の一例を示す。この模倣抑制デザイン２は、JURA社のGSアートスクリーンを使用して作成した。このソフトは任意の文字や記号をランダムに配置させて、その集合体で絵柄を作成することができるソフトであり、より模倣が困難な絵柄を作成することができる。
Fig. 1 shows an example of an imitation suppression design 2 printed using transparent ink. This imitation suppression design 2 was created using JURA's GS art screen. This software is a software that can arrange an arbitrary character or symbol at random and create a pattern with the aggregate, and can create a pattern that is more difficult to imitate.
続いて、有色インキを使用して、図２に示すように、模倣抑制デザイン２に重ねて通常デザイン３を印刷した。通常デザイン３を印刷した後の段ボール断面の模式図を図３に示す。通常デザイン３（有色インキ）は、模倣抑制デザイン２（透明インキ）上に印刷された領域と、段ボール１に直接印刷された領域と、が存在する。なお、この有色インキを使用して印刷された通常デザイン３が、本発明における有色層に相当する。
Subsequently, as shown in FIG. 2, a normal design 3 was printed on the imitation suppression design 2 using colored ink. FIG. 3 shows a schematic diagram of a corrugated board cross section after the normal design 3 is printed. The normal design 3 (colored ink) includes an area printed on the imitation suppression design 2 (transparent ink) and an area printed directly on the cardboard 1. In addition, the normal design 3 printed using this colored ink corresponds to the colored layer in the present invention.
なお、これら模倣抑制デザイン２と通常デザイン３の印刷は、上記フレキソフォルダーグルアーを１回通すことで実施した。
このように印刷された模倣抑制デザイン２は、段ボール１に正面から向かって見るとほぼ目視できないが、段ボールを斜め傾け光を当てると形状が確認できた。また、通常デザイン３は、模倣抑制デザイン２に印刷された領域と、段ボール１に直接印刷された領域と、に一瞥してわかる差異は無く、いずれの領域においても良好に印刷できた。
（３）効果を確認する試験
上記印刷方法にて印刷された段ボールの模倣抑制デザインに対し、以下の方法により模倣を試みた。
（３－１）スキャニング試験
（３－１－１）
スキャナ（セイコーエプソン株式会社製 ＥＳ－６０００ＨＳ）を使用し、解像度９６００ｄｐｉで、透明インキで模倣抑制デザインを印刷した段ボールをスキャニングした。透明インキで印刷された模倣抑制デザインをスキャニングした画像を図４に示す。 Theimitation suppression design 2 and the normal design 3 were printed by passing the flexo folder gluer once.
Theimitation suppression design 2 printed in this way is almost invisible when the cardboard 1 is viewed from the front, but the shape can be confirmed when the cardboard is tilted obliquely and irradiated with light. Further, the normal design 3 had no difference at a glance between the area printed on the imitation suppression design 2 and the area printed directly on the cardboard 1, and could be printed well in any area.
(3) Test for confirming the effect The imitation suppression design of the cardboard printed by the above printing method was tried to imitate by the following method.
(3-1) Scanning test (3-1-1)
Using a scanner (ES-6000HS manufactured by Seiko Epson Corporation), cardboard printed with imitation suppression design with transparent ink was scanned at a resolution of 9600 dpi. FIG. 4 shows an image obtained by scanning the imitation suppression design printed with the transparent ink.
このように印刷された模倣抑制デザイン２は、段ボール１に正面から向かって見るとほぼ目視できないが、段ボールを斜め傾け光を当てると形状が確認できた。また、通常デザイン３は、模倣抑制デザイン２に印刷された領域と、段ボール１に直接印刷された領域と、に一瞥してわかる差異は無く、いずれの領域においても良好に印刷できた。
（３）効果を確認する試験
上記印刷方法にて印刷された段ボールの模倣抑制デザインに対し、以下の方法により模倣を試みた。
（３－１）スキャニング試験
（３－１－１）
スキャナ（セイコーエプソン株式会社製 ＥＳ－６０００ＨＳ）を使用し、解像度９６００ｄｐｉで、透明インキで模倣抑制デザインを印刷した段ボールをスキャニングした。透明インキで印刷された模倣抑制デザインをスキャニングした画像を図４に示す。 The
The
(3) Test for confirming the effect The imitation suppression design of the cardboard printed by the above printing method was tried to imitate by the following method.
(3-1) Scanning test (3-1-1)
Using a scanner (ES-6000HS manufactured by Seiko Epson Corporation), cardboard printed with imitation suppression design with transparent ink was scanned at a resolution of 9600 dpi. FIG. 4 shows an image obtained by scanning the imitation suppression design printed with the transparent ink.
なお参考として、図５に、有色インキにて印刷した本試験の模倣抑制デザインの画像を示す。
図４に示すように、透明インキで印刷された模倣抑制デザインは全くスキャニングできなかった。これは、スキャナが媒体に対して垂直方向から光を当てて反射したデータを読み込む機械であるため、垂直方向から画像を認識できない限り、読み込むことは不可能であるためであると考えられる。
（３－１－２）
段ボールに透明インキで模倣抑制デザインを印刷し、その上から有色インキで通常デザインを印刷したものを、上記スキャナにてスキャニングした。スキャニングした画像を図６Ａに示す。図６Ａにおいて段ボール上に模倣抑制デザインは写っておらず、スキャニングができなかったことがわかる。 For reference, FIG. 5 shows an image of the imitation suppression design of this test printed with colored ink.
As shown in FIG. 4, the imitation suppression design printed with clear ink could not be scanned at all. This is considered to be because reading is impossible unless the image can be recognized from the vertical direction because the scanner is a machine that reads data reflected by applying light to the medium from the vertical direction.
(3-1-2)
The imitation suppression design was printed on the cardboard with transparent ink, and the normal design was printed with colored ink on the cardboard, which was then scanned with the scanner. The scanned image is shown in FIG. 6A. In FIG. 6A, the imitation suppression design is not shown on the cardboard, and it can be seen that scanning could not be performed.
図４に示すように、透明インキで印刷された模倣抑制デザインは全くスキャニングできなかった。これは、スキャナが媒体に対して垂直方向から光を当てて反射したデータを読み込む機械であるため、垂直方向から画像を認識できない限り、読み込むことは不可能であるためであると考えられる。
（３－１－２）
段ボールに透明インキで模倣抑制デザインを印刷し、その上から有色インキで通常デザインを印刷したものを、上記スキャナにてスキャニングした。スキャニングした画像を図６Ａに示す。図６Ａにおいて段ボール上に模倣抑制デザインは写っておらず、スキャニングができなかったことがわかる。 For reference, FIG. 5 shows an image of the imitation suppression design of this test printed with colored ink.
As shown in FIG. 4, the imitation suppression design printed with clear ink could not be scanned at all. This is considered to be because reading is impossible unless the image can be recognized from the vertical direction because the scanner is a machine that reads data reflected by applying light to the medium from the vertical direction.
(3-1-2)
The imitation suppression design was printed on the cardboard with transparent ink, and the normal design was printed with colored ink on the cardboard, which was then scanned with the scanner. The scanned image is shown in FIG. 6A. In FIG. 6A, the imitation suppression design is not shown on the cardboard, and it can be seen that scanning could not be performed.
また、比較例として、透明インキを一般的なニスに変更したものを、同様に上記スキャナにてスキャニングした。スキャニングした画像を図６Ｂに示す。図６Ｂには、図６Ａに見られない模倣抑制デザインによる「ＮＯＣＯＰＹ」の文字の一部が写し出されており、スキャニングが可能であった（模倣抑制の効果が小さい）ことがわかる。
（３－２）デジタルカメラでの撮影実験
デジタルカメラを使用して斜めアングルから撮影を行った。図７Ａ，７Ｂに、異なる段ボールに印刷した模倣抑制デザインを撮影した画像を示す。また図７Ｃに、参考として、有色インキで印刷した模倣抑制デザインを撮影した画像を示す。 Further, as a comparative example, a transparent ink changed to a general varnish was similarly scanned with the scanner. The scanned image is shown in FIG. 6B. In FIG. 6B, a part of the characters “NOCOPY” by the imitation suppression design not seen in FIG. 6A is copied, and it can be seen that scanning was possible (the effect of imitation suppression was small).
(3-2) Photographing experiment with digital camera Photographing was performed from an oblique angle using a digital camera. 7A and 7B show images taken of imitation suppression designs printed on different cardboards. Moreover, the image which image | photographed the imitation suppression design printed with colored ink for reference to FIG. 7C is shown.
（３－２）デジタルカメラでの撮影実験
デジタルカメラを使用して斜めアングルから撮影を行った。図７Ａ，７Ｂに、異なる段ボールに印刷した模倣抑制デザインを撮影した画像を示す。また図７Ｃに、参考として、有色インキで印刷した模倣抑制デザインを撮影した画像を示す。 Further, as a comparative example, a transparent ink changed to a general varnish was similarly scanned with the scanner. The scanned image is shown in FIG. 6B. In FIG. 6B, a part of the characters “NOCOPY” by the imitation suppression design not seen in FIG. 6A is copied, and it can be seen that scanning was possible (the effect of imitation suppression was small).
(3-2) Photographing experiment with digital camera Photographing was performed from an oblique angle using a digital camera. 7A and 7B show images taken of imitation suppression designs printed on different cardboards. Moreover, the image which image | photographed the imitation suppression design printed with colored ink for reference to FIG. 7C is shown.
デジタルカメラのアングルによっては、部分的に画像の撮影が可能となるが、その画像から複製に用いる画像データを抽出することはできない。
（４）真贋判定の手順
透明インキで模倣抑制デザインを作成し、さらに有色インキで通常デザインを印刷した段ボールと、その段ボールをスキャニングして作成された偽物の段ボールと、を判別するための真贋判定は、以下１～３の手順だけで十分に機能できる。 Depending on the angle of the digital camera, it is possible to partially capture an image, but image data used for copying cannot be extracted from the image.
(4) Authenticity Judgment Procedure Authenticity judgment to discriminate between corrugated cardboard created by creating imitation suppression design with transparent ink and printing normal design with colored ink, and counterfeit cardboard created by scanning the cardboard. Can function satisfactorily only by the followingsteps 1 to 3.
（４）真贋判定の手順
透明インキで模倣抑制デザインを作成し、さらに有色インキで通常デザインを印刷した段ボールと、その段ボールをスキャニングして作成された偽物の段ボールと、を判別するための真贋判定は、以下１～３の手順だけで十分に機能できる。 Depending on the angle of the digital camera, it is possible to partially capture an image, but image data used for copying cannot be extracted from the image.
(4) Authenticity Judgment Procedure Authenticity judgment to discriminate between corrugated cardboard created by creating imitation suppression design with transparent ink and printing normal design with colored ink, and counterfeit cardboard created by scanning the cardboard. Can function satisfactorily only by the following
１．透明インキで印刷されたデザインがあるか、ないか
２．透明インキで印刷したデザインが概要で合っているか
３．デザイン以外の隠し文字の有無
（５）発明の効果
上述した印刷物であれば、透明インキで印刷された模倣抑制デザインをスキャナにより読み取ることができないので、模倣抑制デザインの模倣を抑制することができる。それにより、当該模倣抑制デザインが形成された印刷物の偽物が製造されることを抑制できる。 1. 1. Are there any designs printed with clear ink? 2. Does the design printed with clear ink match the outline? Presence / absence of hidden characters other than design (5) Effects of the invention Since the imitation suppression design printed with transparent ink cannot be read by the scanner with the printed matter described above, imitation of the imitation suppression design can be suppressed. Thereby, it can suppress that the imitation of the printed matter in which the said imitation suppression design was formed is manufactured.
２．透明インキで印刷したデザインが概要で合っているか
３．デザイン以外の隠し文字の有無
（５）発明の効果
上述した印刷物であれば、透明インキで印刷された模倣抑制デザインをスキャナにより読み取ることができないので、模倣抑制デザインの模倣を抑制することができる。それにより、当該模倣抑制デザインが形成された印刷物の偽物が製造されることを抑制できる。 1. 1. Are there any designs printed with clear ink? 2. Does the design printed with clear ink match the outline? Presence / absence of hidden characters other than design (5) Effects of the invention Since the imitation suppression design printed with transparent ink cannot be read by the scanner with the printed matter described above, imitation of the imitation suppression design can be suppressed. Thereby, it can suppress that the imitation of the printed matter in which the said imitation suppression design was formed is manufactured.
また、上述した印刷物であれば、有色インキによる通常デザインによって、透明インキによる模倣抑制デザインを隠すことや模倣抑制デザインの形状を不明瞭にすることができるため、模倣抑制デザインの他者からの発見や模倣を抑制することができる。
In addition, with the above-mentioned printed matter, it is possible to conceal the imitation suppression design with transparent ink and obscure the shape of the imitation suppression design with the normal design with colored ink, so discovery from others by imitation suppression design And imitation can be suppressed.
また、この印刷物の印刷は、通常１台の印刷機にて印刷することができるため、通常の段ボール製造コストで印刷物を製造することができ、また従来の段ボール印刷の装置を変更せずに使用できることから、生産性が低下することも抑制できる。
（６）変形例
以上、本発明の実施例について説明したが、本発明は、上記実施例に何ら限定されることはなく、本発明の技術的範囲に属する限り種々の形態をとり得ることは言うまでもない。 In addition, since printing of this printed matter can usually be done with a single printing machine, the printed matter can be produced at a normal corrugated cardboard manufacturing cost, and it can be used without changing the conventional corrugated cardboard printing device. Since it can do, it can also suppress that productivity falls.
(6) Modifications The embodiments of the present invention have been described above. However, the present invention is not limited to the above embodiments, and can take various forms as long as they belong to the technical scope of the present invention. Needless to say.
（６）変形例
以上、本発明の実施例について説明したが、本発明は、上記実施例に何ら限定されることはなく、本発明の技術的範囲に属する限り種々の形態をとり得ることは言うまでもない。 In addition, since printing of this printed matter can usually be done with a single printing machine, the printed matter can be produced at a normal corrugated cardboard manufacturing cost, and it can be used without changing the conventional corrugated cardboard printing device. Since it can do, it can also suppress that productivity falls.
(6) Modifications The embodiments of the present invention have been described above. However, the present invention is not limited to the above embodiments, and can take various forms as long as they belong to the technical scope of the present invention. Needless to say.
例えば上記実施例では、透明インキ，水溶性樹脂，樹脂エマルジョンを構成する溶媒として水を用いる構成を例示したが、それ以外の溶媒を用いる構成であってもよい。例えば、水、グリセリン、グリコール、グリコール誘導体などを印刷環境に応じて選択的に単独若しくは併用することができる。上記グリコール成分としては、エチレングリコール、プロピレングリコール、ブチレングリコール、ジエチレングリコールなどのジオール化合物が利用でき、その誘導体としては、前記グリコールのメチル，エチル，プロピル，ブチル，ヘキシル，オクチルなどのアルキルエーテル化合物、酢酸エステル，酪酸エステルなどのエステル化合物、及びエステルエーテル化合物が利用できる。
For example, in the above-described embodiment, the configuration using water as the solvent constituting the transparent ink, the water-soluble resin, and the resin emulsion is exemplified, but a configuration using other solvents may be used. For example, water, glycerin, glycol, glycol derivatives and the like can be selectively used alone or in combination depending on the printing environment. Diol compounds such as ethylene glycol, propylene glycol, butylene glycol and diethylene glycol can be used as the glycol component, and derivatives thereof include alkyl ether compounds such as methyl, ethyl, propyl, butyl, hexyl and octyl of the glycol, acetic acid. Ester compounds such as esters and butyric acid esters, and ester ether compounds can be used.
なお、上述した透明インキ，水溶性樹脂，樹脂エマルジョンを構成する溶媒は、水０～１００重量％、グリセリン０～８０重量％、グリコールおよびグリコール誘導体の群から選択される１種以上の溶媒０～５０重量％の含有比率とするとよい。
The solvent constituting the transparent ink, the water-soluble resin, and the resin emulsion is 0 to 100% by weight of water, 0 to 80% by weight of glycerin, one or more solvents selected from the group consisting of glycol and glycol derivatives. The content ratio is preferably 50% by weight.
また、上記実施例では、体質顔料として炭酸カルシウムを用いる構成を例示したが、通常、フレキソ凸版用印刷インキで使用される白色のものがそのまま使用できる。具体的には、炭酸カルシウム以外に、カオリン、クレー、硫酸バリウム、水酸化アルミニウム、タルク、酸化チタンなどを用いてもよい。なお、体質顔料はこれらのうち１種類のみを用いる構成であってもよいし、複数の混合物を用いる構成であってもよい。
Further, in the above-described embodiment, the configuration using calcium carbonate as the extender is exemplified, but the white one usually used for flexographic relief printing ink can be used as it is. Specifically, in addition to calcium carbonate, kaolin, clay, barium sulfate, aluminum hydroxide, talc, titanium oxide, or the like may be used. In addition, the structure which uses only 1 type may be sufficient as an extender, and the structure which uses a some mixture may be sufficient as it.
また、上記実施例では、水溶性樹脂および樹脂エマルジョンを構成する樹脂として、ロジン変性マレイン酸樹脂を用いる構成を例示したが、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群のうちから選択される樹脂を用いることができる。なお、水溶性樹脂および樹脂エマルジョンを構成する樹脂は、同じ樹脂であってもよいし、異なる樹脂であってもよい。
Further, in the above-described examples, the configuration using the rosin-modified maleic acid resin as the resin constituting the water-soluble resin and the resin emulsion is exemplified, but the rosin-modified maleic resin, acrylic resin, styrene-acrylic resin, styrene- A resin selected from the group consisting of a maleic resin and a styrene-acrylic-maleic resin can be used. The water-soluble resin and the resin constituting the resin emulsion may be the same resin or different resins.
また、水溶性樹脂を構成する塩基性化合物としてトリエチルアミンを用いる構成を例示したが、それ以外の有機アミン化合物（モノエタノールアミン，トリエタノールアミン等）であってもよいし、無機塩基性化合物（水酸化ナトリウム、水酸化カリウム、水酸化アンモニウム等）であってもよい。なお、塩基性化合物として有機アミン化合物を用いると、上記実施例のようにアルキルアンモニウム塩が生成される。一方、無機塩基性化合物を用いると、樹脂のケン化物が生成される。いずれが生成されても、上記実施例と同様に樹脂エマルジョンに含まれる樹脂の共重合体と共に透明層を形成することができ、また透明層表面に良好に有色インキを印刷させることができる。
Moreover, although the structure which uses a triethylamine as a basic compound which comprises water-soluble resin was illustrated, other organic amine compounds (monoethanolamine, a triethanolamine, etc.) may be sufficient, and an inorganic basic compound (water Sodium oxide, potassium hydroxide, ammonium hydroxide, etc.). When an organic amine compound is used as the basic compound, an alkylammonium salt is produced as in the above examples. On the other hand, when an inorganic basic compound is used, a saponified resin is produced. Regardless of which is produced, the transparent layer can be formed together with the copolymer of the resin contained in the resin emulsion in the same manner as in the above embodiment, and the colored ink can be printed favorably on the surface of the transparent layer.
また、水溶性樹脂における樹脂、水、および塩基性化合物の混合割合は、樹脂が１５～２５重量％、水が６０～８４重量％、塩基性化合物が１～１５重量％の範囲が良好である。
The mixing ratio of the resin, water, and basic compound in the water-soluble resin is preferably in the range of 15 to 25% by weight of the resin, 60 to 84% by weight of water, and 1 to 15% by weight of the basic compound. .
また、樹脂エマルジョンにおける樹脂と水との混合割合は、樹脂が４０～５０重量％、水が５０～６０重量％の範囲が良好である。
また、透明インキにおける各構成要素の含有比率は、溶媒が０～３０重量％、体質顔料が０～５０重量％、水溶性樹脂が２０～５０重量％、樹脂エマルジョンが５～２０重量％の範囲が良好である。体質顔料は必ずしも含まれる必要はないが、体質顔料を含有することで、透明インキの乾燥性を向上させることができる。また、この透明インキには、顔料分散剤、ワックス、消泡剤、転移性向上剤、レベリング剤などの各種添加剤を添加してもよい。 The mixing ratio of the resin and water in the resin emulsion is preferably in the range of 40 to 50% by weight of resin and 50 to 60% by weight of water.
In addition, the content ratio of each component in the transparent ink ranges from 0 to 30% by weight of the solvent, 0 to 50% by weight of the extender pigment, 20 to 50% by weight of the water-soluble resin, and 5 to 20% by weight of the resin emulsion. Is good. The extender pigment does not necessarily need to be contained, but by including the extender, the drying property of the transparent ink can be improved. Moreover, you may add various additives, such as a pigment dispersant, a wax, an antifoamer, a transferability improvement agent, a leveling agent, to this transparent ink.
また、透明インキにおける各構成要素の含有比率は、溶媒が０～３０重量％、体質顔料が０～５０重量％、水溶性樹脂が２０～５０重量％、樹脂エマルジョンが５～２０重量％の範囲が良好である。体質顔料は必ずしも含まれる必要はないが、体質顔料を含有することで、透明インキの乾燥性を向上させることができる。また、この透明インキには、顔料分散剤、ワックス、消泡剤、転移性向上剤、レベリング剤などの各種添加剤を添加してもよい。 The mixing ratio of the resin and water in the resin emulsion is preferably in the range of 40 to 50% by weight of resin and 50 to 60% by weight of water.
In addition, the content ratio of each component in the transparent ink ranges from 0 to 30% by weight of the solvent, 0 to 50% by weight of the extender pigment, 20 to 50% by weight of the water-soluble resin, and 5 to 20% by weight of the resin emulsion. Is good. The extender pigment does not necessarily need to be contained, but by including the extender, the drying property of the transparent ink can be improved. Moreover, you may add various additives, such as a pigment dispersant, a wax, an antifoamer, a transferability improvement agent, a leveling agent, to this transparent ink.
また、透明インキには、紫外線吸収剤および赤外線吸収剤のうちいずれか一方または両方が含まれていてもよい。紫外線吸収剤が含まれている場合、紫外線を照射することにより紫外線吸収剤が発光して浮き出すため、容易に透明層の存在を確認することができる。また赤外線吸収剤が含まれている場合、赤外線を照射すると赤外線吸収剤が赤外線を吸収するため、赤外線吸収測定装置を用いることにより容易に透明層の存在を確認することができる。
In addition, the transparent ink may contain one or both of an ultraviolet absorber and an infrared absorber. When an ultraviolet absorber is contained, the ultraviolet absorber emits light and emerges when irradiated with ultraviolet rays, so that the presence of the transparent layer can be easily confirmed. When an infrared absorber is contained, the infrared absorber absorbs infrared rays when irradiated with infrared rays. Therefore, the presence of the transparent layer can be easily confirmed by using an infrared absorption measuring device.
そして、このように容易に透明層を確認することができるため、透明層を有する段ボールと、透明層を有さない偽物の段ボールとの真贋判定を容易に行うことができる。
なお、上記紫外線吸収剤としては、例えば、ベンゾフェノン系、ベンゾトリアゾール系、アクリレート系、サリチレート系等の紫外線吸収剤を用いることができる。具体的には２－（２‘－ヒドロキシー５’－メチルフェニル）ベンゾトリアゾール（チヌビンＰ、チバガイギー社製）、２－（２‘－ヒドロキシー３’－ｔ－ブチルー５‘－メチルフェニル）－５－クロロベンゾトリアゾール（チヌビン３２６、チバガイギー社製）、２-〔２－ヒドロキシ―３，５－ビス（α，α―ジメチルベンジル）〕フェニル〕―２Ｈ―ベンゾトリアゾール（チヌビン２３４、チバガイギー社製）等を挙げることが出来る。 And since a transparent layer can be confirmed easily in this way, the authenticity determination of the corrugated cardboard which has a transparent layer, and the fake cardboard which does not have a transparent layer can be performed easily.
In addition, as said ultraviolet absorber, ultraviolet absorbers, such as a benzophenone type, a benzotriazole type, an acrylate type, a salicylate type, can be used, for example. Specifically, 2- (2′-hydroxy-5′-methylphenyl) benzotriazole (Tinuvin P, manufactured by Ciba Geigy), 2- (2′-hydroxy-3′-t-butyl-5′-methylphenyl) -5 Chlorobenzotriazole (Tinuvin 326, manufactured by Ciba Geigy), 2- [2-hydroxy-3,5-bis (α, α-dimethylbenzyl)] phenyl] -2H-benzotriazole (Tinuvin 234, manufactured by Ciba Geigy), etc. I can list them.
なお、上記紫外線吸収剤としては、例えば、ベンゾフェノン系、ベンゾトリアゾール系、アクリレート系、サリチレート系等の紫外線吸収剤を用いることができる。具体的には２－（２‘－ヒドロキシー５’－メチルフェニル）ベンゾトリアゾール（チヌビンＰ、チバガイギー社製）、２－（２‘－ヒドロキシー３’－ｔ－ブチルー５‘－メチルフェニル）－５－クロロベンゾトリアゾール（チヌビン３２６、チバガイギー社製）、２-〔２－ヒドロキシ―３，５－ビス（α，α―ジメチルベンジル）〕フェニル〕―２Ｈ―ベンゾトリアゾール（チヌビン２３４、チバガイギー社製）等を挙げることが出来る。 And since a transparent layer can be confirmed easily in this way, the authenticity determination of the corrugated cardboard which has a transparent layer, and the fake cardboard which does not have a transparent layer can be performed easily.
In addition, as said ultraviolet absorber, ultraviolet absorbers, such as a benzophenone type, a benzotriazole type, an acrylate type, a salicylate type, can be used, for example. Specifically, 2- (2′-hydroxy-5′-methylphenyl) benzotriazole (Tinuvin P, manufactured by Ciba Geigy), 2- (2′-hydroxy-3′-t-butyl-5′-methylphenyl) -5 Chlorobenzotriazole (Tinuvin 326, manufactured by Ciba Geigy), 2- [2-hydroxy-3,5-bis (α, α-dimethylbenzyl)] phenyl] -2H-benzotriazole (Tinuvin 234, manufactured by Ciba Geigy), etc. I can list them.
また、赤外線吸収剤としては、シアニン系色素、フタロシアニン系色素、ナフトキノン系色素、アントラキノン系色素、ジオール系色素、トリフェニルメタン系色素など赤外線吸収剤を用いることができる。具体的には金属ナフタロシアニン顔料が挙げられる。
As the infrared absorber, infrared absorbers such as cyanine dyes, phthalocyanine dyes, naphthoquinone dyes, anthraquinone dyes, diol dyes, and triphenylmethane dyes can be used. Specific examples include metal naphthalocyanine pigments.
また、上記実施例では、フレキソフォルダーグルアー１回の処理で透明インキと有色インキを印刷する構成を例示したが、別々に印刷してもよい。
また、上記実施例では、模倣抑制デザインと一部が重なるように通常デザインが印刷される構成を例示したが、模倣抑制デザイン全体を覆うように通常デザインが印刷されていてもよいし、模倣抑制デザインと重ならないように通常デザインが印刷されていてもよい。また、模倣抑制デザインのみを段ボールに印刷する構成であってもよい。 Moreover, in the said Example, although the structure which prints a transparent ink and a colored ink by the process of a flexo folder gluer once was illustrated, you may print separately.
Further, in the above-described embodiment, the configuration in which the normal design is printed so as to partially overlap the imitation suppression design is illustrated, but the normal design may be printed so as to cover the entire imitation suppression design, and the imitation suppression may be suppressed. The normal design may be printed so as not to overlap the design. Moreover, the structure which prints only an imitation suppression design on a cardboard may be sufficient.
また、上記実施例では、模倣抑制デザインと一部が重なるように通常デザインが印刷される構成を例示したが、模倣抑制デザイン全体を覆うように通常デザインが印刷されていてもよいし、模倣抑制デザインと重ならないように通常デザインが印刷されていてもよい。また、模倣抑制デザインのみを段ボールに印刷する構成であってもよい。 Moreover, in the said Example, although the structure which prints a transparent ink and a colored ink by the process of a flexo folder gluer once was illustrated, you may print separately.
Further, in the above-described embodiment, the configuration in which the normal design is printed so as to partially overlap the imitation suppression design is illustrated, but the normal design may be printed so as to cover the entire imitation suppression design, and the imitation suppression may be suppressed. The normal design may be printed so as not to overlap the design. Moreover, the structure which prints only an imitation suppression design on a cardboard may be sufficient.
特に、模倣抑制デザイン全体を覆うように通常デザインが印刷されていることで、段ボール表面の模倣抑制デザインを通常デザインによって隠すことができるため、模倣抑制デザインの発見をさらに困難にすることができる。
Especially, since the normal design is printed so as to cover the entire imitation suppression design, the imitation suppression design on the surface of the corrugated cardboard can be hidden by the normal design, so that the detection of the imitation suppression design can be made more difficult.
Claims (17)
- 基材と、
少なくとも樹脂エマルジョンおよび樹脂組成物を含有し、前記基材表面に配置される透明層と、を有しており、
前記樹脂組成物は、樹脂を、有機アミン化合物および無機塩基性化合物のうち少なくともいずれか一方の存在下にて、水，グリセリン，グリコール，グリコール誘導体からなる群から選択される１種以上からなる溶媒に溶解させたものである
ことを特徴とする印刷物。 A substrate;
Containing at least a resin emulsion and a resin composition, and having a transparent layer disposed on the surface of the substrate,
The resin composition is a solvent comprising at least one selected from the group consisting of water, glycerin, glycol, and glycol derivatives in the presence of at least one of an organic amine compound and an inorganic basic compound. Printed matter characterized by being dissolved in. - 前記樹脂エマルジョンは、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群のから選択される１種以上の樹脂と、水，グリセリン，グリコール，グリコール誘導体からなる群から選択される１種以上からなる溶媒と、を含有するものである
ことを特徴とする請求項１に記載の印刷物。 The resin emulsion is at least one resin selected from the group consisting of a rosin-modified maleic resin, an acrylic resin, a styrene-acrylic resin, a styrene-maleic resin, and a styrene-acrylic-maleic resin. And a solvent composed of one or more selected from the group consisting of water, glycerin, glycol, and glycol derivatives. - 前記樹脂組成物における樹脂は、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群から選択される１種以上の樹脂である
ことを特徴とする請求項１または請求項２に記載の印刷物。 The resin in the resin composition is at least one selected from the group consisting of rosin-modified maleic resin, acrylic resin, styrene-acrylic resin, styrene-maleic resin, and styrene-acrylic-maleic resin. The printed matter according to claim 1, wherein the printed matter is a resin. - 前記透明層は、体質顔料を含有する
ことを特徴とする請求項１から請求項３のいずれかに記載の印刷物。 The printed matter according to any one of claims 1 to 3, wherein the transparent layer contains an extender pigment. - 前記基材表面および／または前記透明層表面における少なくとも一部の領域上に有色層が形成されてなる
ことを特徴とする請求項１から請求項４のいずれかに記載の印刷物。 The printed matter according to any one of claims 1 to 4, wherein a colored layer is formed on at least a part of the surface of the substrate and / or the surface of the transparent layer. - 前記有色層は、前記透明層表面を全て覆うように形成される
ことを特徴とする請求項５に記載の印刷物。 The printed matter according to claim 5, wherein the colored layer is formed so as to cover the entire surface of the transparent layer. - 前記透明層は、紫外線吸収剤を含有する
ことを特徴とする請求項１から請求項６のいずれかに記載の印刷物。 The printed matter according to any one of claims 1 to 6, wherein the transparent layer contains an ultraviolet absorber. - 前記透明層は、赤外線吸収剤を含有する
ことを特徴とする請求項１から請求項７のいずれかに記載の印刷物。 The printed matter according to claim 1, wherein the transparent layer contains an infrared absorber. - 基材表面に、樹脂エマルジョンおよび樹脂組成物を含有する透明層形成材料を塗布することで透明層を形成する透明層形成工程を備えており、
前記樹脂組成物は、樹脂を、有機アミン化合物および無機塩基性化合物のうち少なくともいずれか一方の存在下にて、水，グリセリン，グリコール，グリコール誘導体からなる群から選択される１種以上からなる溶媒に溶解させたものである
ことを特徴とする印刷物製造方法。 A transparent layer forming step of forming a transparent layer by applying a transparent layer forming material containing a resin emulsion and a resin composition on the surface of the substrate;
The resin composition is a solvent comprising at least one selected from the group consisting of water, glycerin, glycol, and glycol derivatives in the presence of at least one of an organic amine compound and an inorganic basic compound. A method for producing a printed matter, characterized by being dissolved in - 前記樹脂エマルジョンは、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群から選択される１種以上の樹脂と、水，グリセリン，グリコール，グリコール誘導体からなる群から選択される１種以上からなる溶媒と、を含有するものである
ことを特徴とする請求項９に記載の印刷物製造方法。 The resin emulsion includes at least one resin selected from the group consisting of rosin-modified maleic resin, acrylic resin, styrene-acrylic resin, styrene-maleic resin, and styrene-acrylic-maleic resin. And a solvent comprising at least one selected from the group consisting of water, glycerin, glycol, and glycol derivatives. - 前記樹脂組成物における樹脂は、ロジン変性マレイン酸樹脂、アクリル系樹脂、スチレン－アクリル系樹脂、スチレン－マレイン酸系樹脂、スチレン－アクリル系－マレイン酸系樹脂からなる群から選択される１種以上の樹脂である
ことを特徴とする請求項９または請求項１０に記載の印刷物製造方法。 The resin in the resin composition is at least one selected from the group consisting of rosin-modified maleic resin, acrylic resin, styrene-acrylic resin, styrene-maleic resin, and styrene-acrylic-maleic resin. The printed material manufacturing method according to claim 9, wherein the printed material is a resin. - 前記透明層形成材料は、体質顔料を含有する
ことを特徴とする請求項９から請求項１１のいずれかに記載の印刷物製造方法。 The method for producing a printed material according to any one of claims 9 to 11, wherein the transparent layer forming material contains an extender pigment. - 前記基材表面および／または前記透明層表面における少なくとも一部の領域上に有色層を形成する有色層形成工程を備える
ことを特徴とする請求項９から請求項１２のいずれかに記載の印刷物製造方法。 The printed matter production according to any one of claims 9 to 12, further comprising a colored layer forming step of forming a colored layer on at least a part of the surface of the substrate and / or the surface of the transparent layer. Method. - 前記有色層は、前記透明層表面を全て覆うように形成される
ことを特徴とする請求項１３に記載の印刷物製造方法。 The printed material manufacturing method according to claim 13, wherein the colored layer is formed so as to cover the entire surface of the transparent layer. - 前記透明層形成材料は、紫外線吸収剤を含有する
ことを特徴とする請求項９から請求項１４のいずれかに記載の印刷物製造方法。 The method for producing a printed material according to any one of claims 9 to 14, wherein the transparent layer forming material contains an ultraviolet absorber. - 前記透明層形成材料は、赤外線吸収剤を含有する
ことを特徴とする請求項９から請求項１５のいずれかに記載の印刷物製造方法。 The said transparent layer forming material contains an infrared absorber. The printed matter manufacturing method in any one of Claims 9-15 characterized by the above-mentioned. - 前記透明層形成工程は、フレキソ印刷により実行される
ことを特徴とする請求項９から請求項１６のいずれかに記載の印刷物製造方法。 The printed matter manufacturing method according to any one of claims 9 to 16, wherein the transparent layer forming step is executed by flexographic printing.
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| JP2010517985A JP5243542B2 (en) | 2008-06-19 | 2009-06-19 | Printed matter and printed matter manufacturing method |
| CN200980123233.8A CN102066120A (en) | 2008-06-19 | 2009-06-19 | Printed material and method for producing printed material |
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| CN115369693A (en) * | 2022-03-03 | 2022-11-22 | 浙江特美新材料股份有限公司 | Intelligent production system of tipping paper for cigarettes and printing ink used by same |
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| FR3014014B1 (en) * | 2013-12-03 | 2015-11-20 | Seb Sa | METHOD FOR DECORATING BY FLEXOGRAPHY AN ARTICLE COMPRISING A THERMOSTABLE COATING |
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| JPH05171087A (en) * | 1991-12-20 | 1993-07-09 | Toyo Ink Mfg Co Ltd | Water-base flexographic ink composition |
| JPH08176486A (en) * | 1994-12-21 | 1996-07-09 | Sakata Corp | Water-base printing ink composition for paper |
| JPH1142845A (en) * | 1997-07-24 | 1999-02-16 | Osaka Insatsu Ink Seizo Kk | Printed container |
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| JP2006002033A (en) * | 2004-06-17 | 2006-01-05 | Sakata Corp | Water base printing ink composition |
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2009
- 2009-06-19 WO PCT/JP2009/061243 patent/WO2009154281A1/en active Application Filing
- 2009-06-19 JP JP2010517985A patent/JP5243542B2/en not_active Expired - Fee Related
- 2009-06-19 CN CN200980123233.8A patent/CN102066120A/en active Pending
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| JPS63227674A (en) * | 1987-03-17 | 1988-09-21 | Toyo Ink Mfg Co Ltd | Aqueous printing ink composition |
| JPH05171087A (en) * | 1991-12-20 | 1993-07-09 | Toyo Ink Mfg Co Ltd | Water-base flexographic ink composition |
| JPH08176486A (en) * | 1994-12-21 | 1996-07-09 | Sakata Corp | Water-base printing ink composition for paper |
| JPH1142845A (en) * | 1997-07-24 | 1999-02-16 | Osaka Insatsu Ink Seizo Kk | Printed container |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115369693A (en) * | 2022-03-03 | 2022-11-22 | 浙江特美新材料股份有限公司 | Intelligent production system of tipping paper for cigarettes and printing ink used by same |
| CN115369693B (en) * | 2022-03-03 | 2024-03-15 | 浙江特美新材料股份有限公司 | Intelligent production system of tipping paper for cigarettes and printing ink used by intelligent production system |
Also Published As
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| JPWO2009154281A1 (en) | 2011-12-01 |
| CN102066120A (en) | 2011-05-18 |
| JP5243542B2 (en) | 2013-07-24 |
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