WO2009144412A3 - Method for producing medium distillates by hydrocracking of charges arising from the fischer-tropsch process with an amorphous material catalyst - Google Patents

Method for producing medium distillates by hydrocracking of charges arising from the fischer-tropsch process with an amorphous material catalyst Download PDF

Info

Publication number
WO2009144412A3
WO2009144412A3 PCT/FR2009/000556 FR2009000556W WO2009144412A3 WO 2009144412 A3 WO2009144412 A3 WO 2009144412A3 FR 2009000556 W FR2009000556 W FR 2009000556W WO 2009144412 A3 WO2009144412 A3 WO 2009144412A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrocracking
fischer
producing medium
amorphous material
medium distillates
Prior art date
Application number
PCT/FR2009/000556
Other languages
French (fr)
Other versions
WO2009144412A2 (en
Inventor
Christophe Bouchy
Alexandra Chaumonnot
Original Assignee
Ifp
Eni S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ifp, Eni S.P.A. filed Critical Ifp
Publication of WO2009144412A2 publication Critical patent/WO2009144412A2/en
Publication of WO2009144412A3 publication Critical patent/WO2009144412A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/62—Synthesis on support in or on other molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/394—Metal dispersion value, e.g. percentage or fraction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The invention relates to a method for producing medium distillates from a paraffinic charge produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst containing at least one hydro-dehydrogenating metal selected from the group of metals of periodic classification Group VIB and Group VIII and a substrate formed from at least one amorphous material containing silicon having hierarchical and organized porosity, consisting of at least two elementary spherical particles, each of said particles including a mesostructured silicon oxide matrix having a mesopore diameter of 1.5 to 30 nm and having amorphous microporous walls of a thickness of 1.5 to 50 nm, said elementary spherical particles having a maximum diameter of 200 microns.
PCT/FR2009/000556 2008-05-28 2009-05-13 Method for producing medium distillates by hydrocracking of charges arising from the fischer-tropsch process with an amorphous material catalyst WO2009144412A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR08/02.954 2008-05-28
FR0802954A FR2931833B1 (en) 2008-05-28 2008-05-28 PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATES BY HYDROCRACKING FISCHER-TROPSCH PROCESS CHARGES WITH A CATALYST BASED ON AMORPHOUS MATERIAL

Publications (2)

Publication Number Publication Date
WO2009144412A2 WO2009144412A2 (en) 2009-12-03
WO2009144412A3 true WO2009144412A3 (en) 2010-01-21

Family

ID=40198364

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2009/000556 WO2009144412A2 (en) 2008-05-28 2009-05-13 Method for producing medium distillates by hydrocracking of charges arising from the fischer-tropsch process with an amorphous material catalyst

Country Status (2)

Country Link
FR (1) FR2931833B1 (en)
WO (1) WO2009144412A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2934794B1 (en) 2008-08-08 2010-10-22 Inst Francais Du Petrole PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATES BY HYDROCRACKING FISCHER-TROSPCH-BASED LOADS IN THE PRESENCE OF A CATALYST COMPRISING AN IZM-2 SOLID
FR2934793B1 (en) 2008-08-08 2010-11-19 Inst Francais Du Petrole CATALYST COMPRISING ZEOLITE IZM-2 AND AT LEAST ONE METAL AND ITS USE IN PROCESSING HYDROCARBONS
FR2934796B1 (en) * 2008-08-08 2010-09-03 Inst Francais Du Petrole IZM-2 ZEOLITE CATALYST AND METHOD FOR HYDROCONVERSION / HYDROCRACKING HYDROCARBON LOADS
WO2010065128A1 (en) * 2008-12-05 2010-06-10 Exxonmobil Research And Engineering Company Amorphous acidic materials, their synthesis and use
CN102481555B (en) 2009-06-12 2015-10-07 阿尔比马尔欧洲有限公司 SAPO molecular sieve catalyst and preparation thereof and purposes
FR2984911B1 (en) * 2011-12-22 2014-08-29 IFP Energies Nouvelles PROCESS FOR CONVERTING BIOMASS PARAFFINIC CHARGES TO MEDIUM DISTILLATE BASES USING AT LEAST ONE IZM-2 ZEOLITE CATALYST
CN110467197B (en) * 2018-05-09 2021-07-16 惠生工程（中国）有限公司 ZSM-5 molecular sieve and preparation method thereof
CN116116456A (en) * 2023-03-07 2023-05-16 国家能源集团宁夏煤业有限责任公司 Modified Pt/ZSM-23 catalyst, preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000014184A2 (en) * 1998-09-04 2000-03-16 Exxon Research And Engineering Company ISOPARAFFINIC BASE STOCKS BY DEWAXING FISCHER-TROPSCH WAX HYDROISOMERATE OVER Pt/H-MORDENITE
EP1108678A1 (en) * 1999-12-14 2001-06-20 Institut Francais Du Petrole Micro- and mesoporous silicoaluminate solid, process for its preparation, use thereof as catalysator and in the conversion of hydrocarbons
EP1627852A1 (en) * 2004-06-24 2006-02-22 Institut Français du Pétrole Mesostructured aluminosilicate material
WO2006128989A1 (en) * 2005-06-02 2006-12-07 Institut Francais Du Petrole Mesostructured material with high aluminum content
EP1250287B1 (en) * 2000-01-05 2007-03-07 ExxonMobil Chemical Patents Inc. Porous inorganic macrostructure materials and process for their preparation

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2909012B1 (en) * 2006-11-23 2009-05-08 Inst Francais Du Petrole CATALYST BASED ON HIERARCHISED POROSITY MATERIAL COMPRISING SILICON AND METHOD FOR HYDROCRACKING / HYDROCONVERSION AND HYDROPROCESSING HYDROCARBON LOADS.

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000014184A2 (en) * 1998-09-04 2000-03-16 Exxon Research And Engineering Company ISOPARAFFINIC BASE STOCKS BY DEWAXING FISCHER-TROPSCH WAX HYDROISOMERATE OVER Pt/H-MORDENITE
EP1108678A1 (en) * 1999-12-14 2001-06-20 Institut Francais Du Petrole Micro- and mesoporous silicoaluminate solid, process for its preparation, use thereof as catalysator and in the conversion of hydrocarbons
EP1250287B1 (en) * 2000-01-05 2007-03-07 ExxonMobil Chemical Patents Inc. Porous inorganic macrostructure materials and process for their preparation
EP1627852A1 (en) * 2004-06-24 2006-02-22 Institut Français du Pétrole Mesostructured aluminosilicate material
WO2006128989A1 (en) * 2005-06-02 2006-12-07 Institut Francais Du Petrole Mesostructured material with high aluminum content

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
BAOJIAN ZHANG ET AL: "Starch gel templating of spongelike macroporous silicalite monoliths and mesoporous films", CHEMISTRY OF MATERIALS, AMERICAN CHEMICAL SOCIETY, WASHINGTON, US, vol. 14, no. 3, 1 March 2002 (2002-03-01), pages 1369 - 1375, XP002414825, ISSN: 0897-4756 *
HUANG L ET AL: "Hierarchical porous structures by using zeolite nanocrystals as building blocks", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER SCIENCE PUBLISHING, NEW YORK, US, vol. 48, no. 1-3, 1 November 2001 (2001-11-01), pages 73 - 78, XP002414828, ISSN: 1387-1811 *
NAYDENOV V ET AL: "Self-bonded zeolite beta/MCM-41 composite spheres", JOURNAL OF POROUS MATERIALS, SPRINGER, DORDRECHT, NL, vol. 12, no. 3, 1 July 2005 (2005-07-01), pages 193 - 199, XP002414827, ISSN: 1380-2224 *
TAKAHASHI R ET AL: "Synthesis of monolithic zeolites with macropores", NIPPON SERAMIKKUSU KYOKAI GAKUJUTSU ROMBUSHI - JOURNAL OF THECERAMIC SOCIETY OF JAPAN, NIPPON SERAMIKKUSU KYOKAI, TOKYO, JP, vol. 114, no. 5, 1 May 2006 (2006-05-01), pages 421 - 424, XP002414823, ISSN: 0914-5400 *

Also Published As

Publication number Publication date
FR2931833B1 (en) 2011-06-10
FR2931833A1 (en) 2009-12-04
WO2009144412A2 (en) 2009-12-03

Similar Documents

Publication Publication Date Title
WO2009144412A3 (en) Method for producing medium distillates by hydrocracking of charges arising from the fischer-tropsch process with an amorphous material catalyst
WO2009144411A3 (en) Method for producing medium distillates by hydrocracking of charges arising from the fischer-tropsch process with crystallized material catalyst
WO2008068398A3 (en) Catalyst based on a silicon-containing material with hierarchical porosity and method for the hydrocracking/hydroconversion and hydroprocessing of hydrocarbon feedstocks
Kumar et al. Transient modes of zeolite surface growth from 3D gel-like islands to 2D single layers
Yadroitsev et al. Strategy of manufacturing components with designed internal structure by selective laser melting of metallic powder
Chen et al. Micro-machinability of bulk metallic glass in ultra-precision cutting
FR2887556B1 (en) PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF FISCHER-TROPSCH PROCESSES USING A MACROPORE CONTROLLED-CONTROLLED CONTOURED ALOPINE-SILICA DOPE CATALYST
CN103547363B (en) Spherical material comprising metallic nanoparticles trapped in a mesostructured oxide matrix and use thereof as catalyst in hydrocarbon refining processes
WO2006016949A3 (en) Optimization of gas-to-liquids hydrocracker
TW200613215A (en) Process for the production of nanoparticles with tailor-made surface chemistry and corresponding colloids
ZA200708413B (en) Method for producing middle distillates by the hydroisomerization and hydrocracking of feedstocks obtained from the fischer-tropsch method
Topolski et al. Progress in hydrostatic extrusion of titanium
FR2926087B1 (en) MULTI-PROCESS PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF AN EFFLUENT PRODUCED BY THE FISCHER-TROPSCH PROCESS
Chaturvedi et al. Design process for nanomaterials
FR2826971B1 (en) PROCESS FOR PRODUCING MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF FILLERS ARISING FROM THE FISCHER-TROPSCH PROCESS
FR2926086B1 (en) PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING SEQUENCES OF AN EFFLUENT PRODUCED BY THE FISCHER-TROPSCH PROCESS
CN100374397C (en) Nano repairing process for pore of ceramic coating by laser melting covering
Shanenkov et al. Effect of gaseous medium pressure on plasmadynamic synthesis product in the CN system with melamine
Xu et al. Micro‐Embossing Formability of a Superlight Dual‐Phase Mg–Li Alloy Processed by High‐Pressure Torsion
Rizlan et al. Process parameters optimization of silica sand nanoparticles production using low speed ball milling method
FR2917419B1 (en) PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF A HEAVY FRACTION FROM A FISCHER-TROPSCH EFFLUENT
Hoshyargar et al. Diffusion-driven formation of MoS2 nanotube bundles containing MoS2 nanopods
CN102781575B (en) Hydroprocessing catalysts and their production
ZA201004890B (en) Method for producing middle distillates by hydroisomerization and hydrocracking of feedstocks comiong from the fischer-tropsch process
Van de Velde et al. Production and trade in KETs-based products: The EU position in global value chains and specialization patterns within the EU

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 09754062

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 09754062

Country of ref document: EP

Kind code of ref document: A2