WO2009124704A1 - Wood fibre based panels with a thin surface layer - Google Patents

Wood fibre based panels with a thin surface layer Download PDF

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Publication number
WO2009124704A1
WO2009124704A1 PCT/EP2009/002523 EP2009002523W WO2009124704A1 WO 2009124704 A1 WO2009124704 A1 WO 2009124704A1 EP 2009002523 W EP2009002523 W EP 2009002523W WO 2009124704 A1 WO2009124704 A1 WO 2009124704A1
Authority
WO
WIPO (PCT)
Prior art keywords
surface layer
layer
core
fibres
anyone
Prior art date
Application number
PCT/EP2009/002523
Other languages
French (fr)
Inventor
Darko Pervan
Jan Jacobsson
Kent Lindgren
Göran ZIEGLER
Niclas HÅKANSSON
Eddy Boucké
Original Assignee
Välinge Innovation Belgium BVBA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Välinge Innovation Belgium BVBA filed Critical Välinge Innovation Belgium BVBA
Priority to PL09731199T priority Critical patent/PL2344311T3/en
Priority to ES09731199.7T priority patent/ES2693125T3/en
Priority to EP09731199.7A priority patent/EP2344311B1/en
Priority to EP18189881.8A priority patent/EP3470193B1/en
Priority to CN200980112247.XA priority patent/CN101998896B/en
Priority to LTEP09731199.7T priority patent/LT2344311T/en
Publication of WO2009124704A1 publication Critical patent/WO2009124704A1/en
Priority to HRP20181597TT priority patent/HRP20181597T1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/06Making particle boards or fibreboards, with preformed covering layers, the particles or fibres being compressed with the layers to a board in one single pressing operation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/02Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board the layer being formed of fibres, chips, or particles, e.g. MDF, HDF, OSB, chipboard, particle board, hardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B21/06Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/10Next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/12Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board next to a particulate layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/14Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood board or veneer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/02Layered products comprising a layer of paper or cardboard next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/04Layered products comprising a layer of paper or cardboard next to a particulate layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/263Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer having non-uniform thickness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/06Embossing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/30Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being formed of particles, e.g. chips, granules, powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/24Pressing or stamping ornamental designs on surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0469Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
    • B44C5/0476Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper with abrasion resistant properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/028Paper layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • B32B2262/067Wood fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2264/00Composition or properties of particles which form a particulate layer or are present as additives
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2264/00Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10Inorganic particles
    • B32B2264/102Oxide or hydroxide
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2264/00Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10Inorganic particles
    • B32B2264/107Ceramic
    • B32B2264/108Carbon, e.g. graphite particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/10Properties of the layers or laminate having particular acoustical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/402Coloured
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • B32B2419/04Tiles for floors or walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B2479/00Furniture
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2201/00Joining sheets or plates or panels
    • E04F2201/01Joining sheets, plates or panels with edges in abutting relationship
    • E04F2201/0138Joining sheets, plates or panels with edges in abutting relationship by moving the sheets, plates or panels perpendicular to the main plane
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2201/00Joining sheets or plates or panels
    • E04F2201/01Joining sheets, plates or panels with edges in abutting relationship
    • E04F2201/0153Joining sheets, plates or panels with edges in abutting relationship by rotating the sheets, plates or panels around an axis which is parallel to the abutting edges, possibly combined with a sliding movement

Definitions

  • the invention generally relates but is not limited to the field of wood fibre based building panels with a thin surface layer, preferably floor panels.
  • the invention relates but is not limited to building panels with such surface layer and to equipment and methods to produce such panels.
  • the present invention is particularly suitable for use in floating floors, which are formed of floor panels with a wood fibre core and a thin decorative wear resistant surface.
  • floating floors which are formed of floor panels with a wood fibre core and a thin decorative wear resistant surface.
  • Wood fibre based direct pressed laminated flooring usually comprises a core of a 6-12 mm fibre board, a 0.2 mm thick upper decorative surface layer of laminate and a 0.1-0.2 mm thick lower balancing layer of laminate, plastic, paper or like material.
  • a laminate surface generally comprise two paper sheets, a 0.1 mm thick printed decorative paper and a transparent 0.05-0.1 mm thick overlay intended to protect the decorative paper from abrasion.
  • the transparent overlay which is made of ⁇ -cellulose fibres, comprises small hard and transparent aluminium oxide particles, which gives the thin surface layer a high wear resistance.
  • the printed decorative paper and the overlay are impregnated with melamine resin and laminated to a wood fibre based core under heat and pressure.
  • the two papers have prior to pressing a total thickness of about 0.3 mm and they are after pressing compressed to about 0.2 mm.
  • the most common core material is fibreboard with high density and good stability usually called HDF - High Density Fibreboard with a density exceeding 800 kg/cm 2 .
  • HDF High Density Fibreboard
  • MDF Medium Density Fibreboard - with a density of 600-800 kg/cm 2 is used as core.
  • Other core materials could also be used such as particleboard, plywood, and plastic materials and similar.
  • a balancing layer is generally applied on the rear side of the board in order to keep the panel flat when humidity changes.
  • HDF is produced as follows: Roundwood such as for example pine, larch or spruce are reduced to wood chips and then broken down into individual fibres in a refiner. The fibres are thereafter mixed with binders and then subjected to high pressure and temperature to form a board.
  • Floor panels with such thin surface layer are very cost effective compared to for example solid wood, stones and tiles.
  • the major disadvantage is that properties related to deep surface structures, impact resistance and sound are inferior to the real products that they aim to copy.
  • Laminate floorings could be produced with very advanced designs where a printed pattern is coordinated with an embossed structure of the surface.
  • the embossing is made during lamination when the surface is pressed against a steel sheet with an embossed structure.
  • the depth of the embossing is limited by the paper that could be damaged when the embossing is made with sharp edges or to a depth, which exceeds a few tenths of a millimetre.
  • the embossing is mainly obtained by a compression of the overlay and the decorative paper. Embossed surfaces similar to a rough stone surface or a hand scraped wood surface or deep grooves that could be used to make bevels in a panel are not possible to make with the present pressing technology and with a reasonable cost structure maintaining the present technical properties and design.
  • bevels and surface embossing could be made by a compression of the surface papers and the upper part of the core under the surface layer.
  • WO 03/078761 Value Innovation AB
  • WO 2006/066776 WO 2006/066776.
  • This method has several disadvantages. It could only be used in panels with a soft core such as MDF. This gives a low impact resistance and it is difficult to form high quality locking systems in such soft materials.
  • panels with a HDF core only limited and local embossing could be reached with conventional presses used in laminate production where the surface layer is formed and attached to a core (DPL technology). A considerable higher pressing force and longer pressing time is generally required to form surfaces similar to stone and rough wood surfaces.
  • the visible surface of the installed floor panel is called “front side”, while the opposite side of the floor panel, facing the sub floor, is called “rear side”.
  • the sheet-shaped material that comprises the major part of a floor panel is called “core”.
  • the core has a surface layer closest to the front side and preferably also a balancing layer closest to the rear side, it forms a semi-manufacture, which is called “floor board” or “floor element” in the case where the semi-manufacture, in a subsequent operation, is divided into a plurality of floor elements.
  • floor board or “floor element”
  • the floor elements are machined along their edges so as to obtain their final shape with the joint system, they are called “floor panels”.
  • surface layer is meant all layers applied to the core closest to the front side and covering preferably the entire front side of the floorboard.
  • decorative surface layer is meant a layer, which is mainly intended to give the floor its decorative appearance.
  • Weight layer relates to a layer, which is mainly adapted to improve the durability of the front side.
  • horizontal plane is meant a plane, which extends parallel to the outer part of the surface layer.
  • horizontal is meant parallel to the horizontal plane.
  • up is meant towards the front face and by “down” towards the rear face.
  • Wood fibre based floorings with thin surface layers similar to laminate and wood veneer floorings could capture a considerably larger market share if deep embossing and increased impact resistance could be reached in combination with a cost effective production method.
  • An overall objective of an embodiment of the present invention is to provide a building panel, preferably a floor panel, with a thin surface layer, which has a more attractive surface design and/or better surface properties and/or cost structure than present known floorings with conventional thin surface layers.
  • a specific objective of an embodiment of the invention is to provide a method to produce a floor panel with new attractive design features such as deep embossing which preferably could be combined with high impact and wear resistance, improved sound properties and cost effective production.
  • a method and a panel which comprises a sub layer between a surface layer and a core.
  • This sub layer comprises or consists of small individual fibres and an uncured binder and is applied on the core as a powder.
  • the small fibres are not bonded to each other as for example fibres in paper layers and a HDF core, and could easily be compressed, formed and displaced in all directions during a part of a pressing operation until the binder cures.
  • the uncured sub layer behaves similar to a paste or a liquid substance and creates a uniform counter pressure in all parts under the surface layer even in surface parts with deep and sharp embossing.
  • a thin surface layer will usually not be damaged, significantly or at all, during pressing and the sub layer will after curing provide a strong base for the thin surface layer. Such a base could be stronger than the core and improved impact resistance could be reached.
  • a production method is provided to produce a floor board comprising a wood fibre based core, a thin surface layer and a sub layer between the surface layer and the core.
  • the sub layer comprises or consists of wood fibres and a binder. The method comprises the steps of:
  • the first aspect offers the advantage that the sub layer could be produced with higher density than the core and this could give the floor panel a high impact resistance even in the case when the surface layer is thin or the core rather thin or soft.
  • a core material could also have a rather uneven core surface, which could be filled by the sub layer. This makes it possible to use for example particleboard or un-sanded HDF board in a DPL production based on one decorative paper and one overlay.
  • the wood fibre based sub layer is very cost efficient compared to for example a core paper.
  • the curing time and the required pressure force in the press could be the same as for conventional laminate floorings.
  • the sub layer could comprise colour pigments with a different colour than the surface layer and decorative grooves, where the surface layer is removed and the sub layer is visible, could be formed.
  • the sub layer could also comprise particles, for example cork particles, which could give the floor panel improved sound properties and flexibility.
  • a cork layer could be used in combination with known surface materials such as laminate, resilient surfaces, fibre based surfaces, wood, wood veneer, linoleum, cork veneer and similar.
  • surface materials such as laminate, resilient surfaces, fibre based surfaces, wood, wood veneer, linoleum, cork veneer and similar.
  • a thin surface layer for example a wood veneer could be applied, prior to pressing, on a sub layer comprising cork particles and binders. Pressing could take place against a press plate, which could create a deep embossing, or deep grooves.
  • the thin surface layer will be formed and laminated to the sub layer.
  • the thin surface layer will not be damaged since the cork particles will be compressed and formed according to the structure of the press plate.
  • This forming technology could also be used in a panel where the sub layer comprises wood fibres or other type of fibres that could be formed by pressing.
  • the method further comprises the step of pressing the surface layer with an embossed pressing matrix such that the surface layer obtains upper portions and embossed portions which are lower than the upper portions by shaping of the sublayer
  • the embossed portions are preferably obtained by compression of the sublayer located under the embossed portion and/or by shifting fibres located under the embossed portion to the upper portions.
  • a part of the sub layer is more compressed under an embossed portion than a part of the surface layer located under an upper portion.
  • An embodiment of the invention offers the advantages that the sub layer during the initial stage of the pressing is uncured and soft and comprises particles, which easily could be displaced during pressing.
  • Very deep embossing could be formed with normal pressing force. Deep surface embossing of for example up to 0.5 mm and even more could easily be reached with a surface layer comprising a decorative paper, a foil, wood veneer and similar.
  • the embossing is preferably formed when the surface is pressed against an embossed steel sheet or belt or a paper matrix.
  • a major advantage is that deep embossing of the surface layer and the sub layer could be formed without any compression of the core material.
  • a compression of the core material is however not excluded. Such a compression of the core could take place if the sub layer for example is very thin.
  • the sub layer could comprise fibres and binders, which are suitable for a second pressing step where further embossing and forming could be formed in a press or with roll forming.
  • the thin surface layers should preferably have a thickness before pressing of about 0.3 - 1.0 mm. Thinner layers with a thickness of 0.1-0.2 mm are not excluded and very deep embossing could be formed with such thin surface layers of for example foils and papers.
  • the surface layer could also be a print, paint or coating that is applied prior or after the pressing. Thicker layers of more than 1 mm could also be used, for example linoleum, resilient floor surfaces and similar.
  • the production could be made in continuous or discontinuous presses.
  • a surface layer which comprises a homogenous mix of wood fibres, wear resistant particles binders and colour pigments.
  • Such surface layer is below referred to as Solid Laminate Surface Layer.
  • the surface layer preferably comprises natural resins, e.g. lignin, of bio based material, e.g. from wood.
  • the surface layer and the sub layer are in this embodiment rather similar regarding material properties and material composition.
  • the surface layer comprises however wear resistant particles for example aluminium oxide and colour pigments.
  • the binders and the fibres could be similar in both layers.
  • the size of the fibres and the resin content could however vary. Very deep surface embossing and bevels of more than 1 mm depth could easily be formed.
  • a building panel comprising a thin surface layer, a wood fibre based core and a sub layer between the surface layer and the core.
  • the sub layer comprises wood fibres and a binder and the average fibre length in the sub layer is shorter than the average length of the wood fibres in the core.
  • the panel could have all surface layers mentioned above.
  • Overlay, decorative papers, core papers and HDF are made of individual fibres with a thickness of a few hundreds of a millimetre and a length of several millimetres, generally in the range of 3-5 mm. This corresponds to a length/thickness ratio (LTR) of about 100.
  • the sub layer according to the invention is formed of wood fibres that are mechanically cut into wood powder fibres. The average length of the fibres should preferably not exceed about 1 mm and this fibre length is considerably shorter than the length of the fibres in core.
  • the LTR is in the region of about 30 or smaller. It is even more preferred that the fibres are smaller than 0.5 mm. Very high quality sub layers have been obtained with very small fibres with an average length of 0.1 - 0.3 mm and an average LRT of less than 10.
  • Short fibres are easier to apply on a core in well-defined layers and they provide a soft sub layer, which is easy to form and compress. They are easier to mix with resins especially is such resins are in dry powder form. Another advantage is that recycled and short fibres, which are not possible to use in paper production due to low strength, could be used to form a strong sub layer.
  • a building panel wherein the surface layer comprises upper portions and embossed portions lower than the upper portions wherein a part of the sub layer is more compressed under an embossed portion than under an upper portion.
  • the sub layer could comprise for example about 70-85% (weight) wood fibres and about 15-30% melamine resin.
  • the layer could have a thickness, which is for example in the range of 0.1 mm - 1 mm or even more. Other combinations are of course also possible.
  • the mixture should be adapted to the desired properties and cost structures.
  • the binders contribute in general to give the surface a high impact and moisture resistance but they are rather costly.
  • Other hard and heavy particles such as aluminium oxide or stone powder could be included in the sub layer in order to increase the density and to improve the impact resistance.
  • the solid laminate surface layer could comprise for example about 25% (weight) aluminium oxide, about 25% wood fibres, about 25% melamine resin and about 25% colour pigments.
  • the surface layer could have a thickness, which is for example in the range of 0.1 mm - 3 mm or even more. Other combinations are of course also possible.
  • the melamine part could vary for example between 10 - 35%.
  • the content of the colour pigments could be very low for example only about 0.1-5%.
  • Wear resistant particles could be in the same range and could for example vary from a few percent to 35% and even higher.
  • the mixture should be adapted to the desired properties and cost structures.
  • the pressure is preferably about 300N - 800N/cm 2 and the temperature could be 120-220 degrees C.
  • the pressing time could vary for example from 20 seconds to 5 minutes. It is possible to use very short pressing times, for example about 10 seconds or shorter, especially in embodiments where a rather thin surface and sub layers are applied on an HDF core before pressing.
  • Thermoplastic binders such as PVC, PE, PP, etc could also be used.
  • a dry process to form the sub layer and the solid laminate surface layer.
  • the different materials and mixtures of different materials such as fibres, wear resistant particles, binders and colour pigments are distributed and scattered in a dry form. Scattering could be made with several stations comprising embossed or engraved rollers and brushes that could apply one or several layers of dry material.
  • a panel could of course be formed without a surface layer. Only a sub layer as described above could be applied on a core.
  • the sub layer which in this case has a surface of wood fibres and binders, could be made with a flat or embossed structure.
  • a final decorative surface could be applied for example as a print in the factory or as a paint or coating or similar by the consumer.
  • the panel could also be used without any additional decorative layer over the sub layer.
  • New types of core materials could also be produced with for example a core and a sub layer applied on the core. The advantage is that core materials could be used which for example is not suitable to use in wood and laminate flooring. They could for example be too soft or difficult to laminate or glue.
  • the sub layer could however create a strong and suitable base for the application of a surface layer. More cost effective core materials or core materials with other properties than HDF could be used.
  • Decorative sub layers make it possible to form decorative grooves or bevels.
  • All preferred embodiments with and without wear resistant particles could be used to make panels, which could be applied vertically on a wall as wall panels in interior or exterior applications.
  • Such panels could have a mechanical locking system on long edges that is possible to lock with angling and optional on short edges a locking system with for example a flexible tongue that allows vertical folding as described in for example WO 2006/043893.
  • a third aspect of an embodiment of the invention is floor production equipment which comprises a roller with needles or engraved protruding portions and a brush for applying dry materials comprising small wood fibres and binders and preferably wear resistant particles and colour pigments on a board material.
  • the amount of needles or engraved protruding portions should be adapted to the dry materials and to the type and size of fibres, which are applied on the board material, to obtain an even flow of fibres and a clean roller after it has passed the brush.
  • the amount of needles or the engraved protruding portions is more than about 20 per cm 2 and most preferably in the range of about 40 - 120 per cm 2 .
  • This equipment could also be used in the production of WFF floor board as described in PCT/EP2008/065489.
  • Figs 1a-1d illustrate a known floor panel with an embossed surface.
  • Figs 2a-e illustrate a floor panel according to the invention.
  • Figs 3a-d illustrate a production method to apply particles on a core.
  • Figs 4a-c illustrate a panel surface and production method to form an embossed surface
  • Figs 5a-c illustrate panels according to the invention.
  • Figs 6a-d illustrate a panel surface with decorative grooves and bevels.
  • Figs 7a-e illustrate a method to form an in register embossed surface.
  • Figure 1a shows a laminated floor panel 1 according to known technology comprising a surface layer 5, a core 6 and a balancing layer 7.
  • Figure 1c shows the surface layer 5. It has an upper wear layer 13 of a transparent material with great wearing strength.
  • a wear layer comprises generally a transparent paper impregnated with melamine resin and with aluminium oxide particles 12 added.
  • a decorative layer 10 comprising paper with a printed pattern 11 is impregnated with melamine resin and placed under this transparent wear layer 13.
  • the wear layer 13 and the decorative layer 10 are laminated to the core, generally a fibre based core such as HDF, under pressure and heat to an about 0.2 mm thick surface layer 5.
  • Figure 1b shows the balancing layer 7 that generally also is a melamine-impregnated paper. This balancing layer keeps the floor panel flat when humidity varies over time.
  • the transparent wear layer is generally 0.05 - 0.10 mm thick.
  • Figure 1d shows a laminate flooring with an embossed surface layer according to known technology.
  • the surface layer 5 comprises upper portions 5a and embossed portions 5b, which are compressed and located lower than the upper portions.
  • the embossing is made to a depth of about 0.1 mm and only the overlay 13 and the decorative paper (10) are compressed.
  • Figures 2a -2d shows a floor panel 1 according to one embodiment of the invention where the surface layer 5 is a Solid Laminate Surface Layer.
  • a panel 1 is provided with a wood fibre based core 6, a non-transparent decorative surface layer 5 and preferably a balancing layer 7 as shown in Figure 2a.
  • Figure 2b shows the surface layer 5 that comprises wood fibres 14, small hard wear resistant particles 12, 12' and a binder 19.
  • the wood fibres are unrefined and comprise lignin.
  • wear resistant particles (12,12') are preferably aluminium oxide particles.
  • Other suitable materials are for example silica or silicon carbide. Diamond crystals or powder, could also be added into the surface layer. In general all materials with a hardness of Rockwell C hardness HRC of 70 or more could be used and they do not have to be transparent. A mixture of two or more materials could be used.
  • An embodiment of the invention offers the advantage that the wear resistant surface layer 5 could be made much thicker than in known floor panels.
  • the thickness of the wear resistant and decorative surface layer could vary from for example about 0.1 mm to for example about4 mm or even more. Wear resistance with maintained decorative properties could be extremely high, for example in the region of 100,000 revolutions or more in a surface layer that is about 1.0 mm thick.
  • a preferable binder is melamine or urea formaldehyde resin. Any other binder, preferably thermosetting resins, could be used
  • Figure 2c show that a balancing layer 7 comprising preferably wood fibres 14' and a binder could be provided on the lower side of the floor panel.
  • the fibres, the binder and also the pressing temperature should be adapted in an appropriate way to balance the surface layer and to keep the panel flat.
  • the balancing layer 7 is preferably pressed with a higher temperature for example 5- 20 °C higher than the surface layer 5
  • the surface layer could comprise of for example 25% (weight) aluminium oxide, 25% wood fibres, 25% melamine resin and 25% colour pigments.
  • the surface layer could have a thickness, which is for example in the range of 0.1 mm - 3 mm or even more. The most preferable thickness is 0.5 - 1.5 mm.
  • the surface layer comprises preferably wood powder with particle which are in the range of about 0.1 -0.3 mm or even smaller.
  • a particularly high quality surface layer 5 could be achieved if the wood fibres, which are mixed with the binding agent, colour pigments and wear resistant particles, are already pre coated and fully or partly pre cured with a binder, for example a melamine or urea formaldehyde resin, or pressed and then separated mechanically into wood fibre powder or wood fibre chips which are preferably smaller and more compact than the original wood fibres.
  • a binder for example a melamine or urea formaldehyde resin
  • Such a fibre composition is especially well suited to be mixed with wear resistant particles and could create a well defined base for the printing operation with wear resistant particles evenly spread over the whole surface layer.
  • Such coated fibres could be obtained from recycled HDF.
  • Figure 2d show a panel where the surface layer 5 has been formed on a core 6 that has been produced in a prior separate operation, for example a HDF panel.
  • a connection 34 between the core 6 and the surface layer 5.
  • the connection 34 could be very strong since binders 19 from the surface layer 5 penetrate into the upper part of the core 6, especially if the core is HDF or a wood based panel such as for example particleboard. Different binders or binder contents could be used in the upper and lower parts of the surface layer 5.
  • a sub layer 6a is applied between the surface layer 5 and the core 6. This sub layer 6a could be produced in the same way as the Solid Laminate Surface Layer described above and the same material compositions could be used except for the fact that in some embodiments wear resistant particles and colour pigments are not included.
  • Such materials could however be included in the sub layer 6a in order to for example create decorative grooves or to increase the impact resistance.
  • the binders 19 in the sub layer 6a could be specially adapted to penetrate and reinforce the upper parts of the core 6 in order to for example increase the moisture resistance of the upper parts of the core.
  • Figure 2e shows that pressing a matrix to the surface 5 could create grooves 37, bevels, grout lines and similar. Such embossing could be made much deeper than in traditional laminate floorings where the paper will be damaged. Embossing with a depth of for example 1-2 mm or even more could easily be obtained.
  • the production cost could be decreased if the thickness of the surface layer 5 is reduced and replaced with a sub layer 6a that only comprises wood fibres and binders.
  • Such sub layer could increase impact resistance, reduce sound and create a layer that could be compressed and cured during pressing such that deep surface structures could be obtained which are deeper than the thickness of the Solid Laminate Surface Layer.
  • Figure 3a show a scattering station 60 which could be used to distribute dry materials in layers in order to form a Solid Laminate Surface Layer or a sub layer 6a.
  • Fibres, wear resistant particles, binders in powder form and colour pigments in powder form could for example be mixed and applied into an container 55 that is in contact with an engraved roller 53.
  • This roller 53 brings during rotation the mixed material 55 into contact with a brush roller 54 and the material 55 is applied on a conveyor belt 20 or on another layer or board material.
  • Liquid resins or water 61 could be applied on the core or sprayed over the fibres in order to stabilize the fibre layer prior to pressing. This facilitates the pressing and the application of a surface layer over the sub layer.
  • water containing for example 1% weight content of a wetting agent for example BYK-348 from BYK Chemie which is applied on an core 10-100g/m 2 could be used. 10-20 g/m 2 is preferred.
  • Other types of wetting agents can also be used, as e.g., soap and the like.
  • the surface of the roller 53 comprises a large amount of thin needles or spikes, which are preferably made of a strong and polished metal.
  • the amount of needles or spikes should be adapted to the type and size of fibres, and to the other dry materials, which are applied on the board, to obtain an even flow of fibres and a clean roller after it has passed the brush. Further parameters, which should be considered, are the diameter and the length of the needles and the spikes. This is shown in figure 3b.
  • the length of the needles is preferably about 1 mm and the thickness about 0.5 mm.
  • rollers which comprises about 80 needles/cm 2 , needle diameters of 0.5 mm and needle lengths of 0.8 mm, as shown in figure 3c. 40-120 needles/cm 2 could also be used depending on the size of the powder particles and the material composition.
  • the roller 53 has preferably a diameter of about 100 - 300 mm. It is preferred to use an oscillating brush 54 that moves along the length of the roller 53. Scattering equipment with such rollers could be used to apply materials in powder form and to create Solid Laminate Surface Layers and sub layers as describe in all preferred embodiments.
  • An embodiment of the invention provides equipment and a method to produce a floorboard by applying dry materials comprising small wood fibres and binders and preferably wear resistant particles and colour pigments on a board material.
  • the equipment comprises a roller with needles or engraved protruding portions and a brush.
  • the amount of needles or the engraved protruding portions is more than about 20 per cm 2 and most preferably in the range of about 40 - 120 per cm 2 .
  • Figure 3d shows that several scattering stations 60a, 60b could be used to apply one or several layers 5, 6a on a core 6.
  • Figures 4a-c show how a thin surface layer 5, preferably a wood veneer layer, a printed paper with an overlay or a foil with a thickness of for example 0.3- 1.0 mm, could be formed with deep structures that give an appearance similar to solid wood.
  • Figure 4a shows how a floorboard could be produced.
  • a thin surface layer 5 is applied on a sub layer 6a comprising for example cork or wood fibres mixed with a binder, preferably a thermosetting binder.
  • the sub layer 6a is applied on for example a wood fibre based core, preferably a HDF core. Other core materials could be used such as particleboard, plywood, plastic materials etc.
  • a balancing layer 7 could also be applied to the core 6.
  • Figure 4b show how the core and the layers are pressed together.
  • This pressing forms the sub layer 6a and the surface layer 5, which are cured and connected to each other under heat and pressure. Very deep embossing could be obtained and a rough surface similar to hand scraped solid wood could be created with a thin wood veneer.
  • the sub layer could be used to improve the properties of the surface layer, for example sound absorption and impact resistance.
  • This sub layer comprises or consists of small individual fibres and an uncured binder and is applied on the core as a powder.
  • the small fibres are not bonded to each other as for example long fibres in paper layers and a HDF core, and could easily be compressed, formed and displaced in all direction during the initial part of a pressing operation until the binder cures.
  • the uncured sub layer 6a behaves similar to a paste or a liquid substance and creates a uniform counter pressure in all parts under the surface layer even in surface parts with deep and sharp embossing.
  • a first step takes place when a heated press plate, or a steel belt in case a continuous press is used, is in initial contact with the surface layer and the protruding portions of the pres plate/belt are deforming parts of the surface layer.
  • the sub layer material which is in powder form, is partly displaced horizontally but also vertically upwards towards the cavities of the press plate/belt where parts of the surface layer could be pressed upwards into the cavities.
  • a locally increased compression of the core under the protruding portions of the press plate/belt could take place if the sub layer is thin or if the initial pressure is high or if the embossing is deep. Such a compression of the core could however be avoided if thicker sub layers are used.
  • the sub layer material will be converted to a paste form in a second step when heat increases and the melamine binder becomes liquid.
  • the pressure is substantially evenly distributed in the whole surface layer and sub layer. The pressure could now be increased and this will not cause any increased local compressions of the core or the surface layer.
  • a curing of the binders will take place in the final third step when heat and pressure reaches the maxim level and the sub layer will obtain its final properties related to shape and density.
  • a panel with a HDF core and surface layer comprising a decorative paper, an overlay and an embossed structure with a depth that exceeds the thickness of the surface layer and wherein the upper part of the HDF core is flat and essentially parallel with the horizontal plane HP.
  • a thin surface layer will usually not be damaged, significantly or at all, during pressing and the sub layer will after curing provide a strong base for the thin surface layer. Such a base could be stronger than the core and improved impact resistance could be reached.
  • Very deep embossing could be obtained with a surface layer that comprises conventional decorative paper and overlay used in conventional laminate floorings.
  • the pressure time and the pressing force could also be similar to conventional laminate production.
  • Conventionally a lamination pressure of about 400 N/cm 2 is used.
  • Embossing depth where the compressed portions 5b are about 0.3- 1.0 mm below the upper portions 5a can be made even when the surface structure comprises rather sharp embossed portions, for example with an angle exceeding 45 degrees against the horizontal plane HP 1 as shown in figure 4c.
  • Even deeper structures could be made but such structures are generally not suitable for floorings since they are difficult to clean and to place furniture on.
  • Such deep embossing could however be used in wall panels and to form bevels at the edges of a floor panel.
  • Figures 5a and 5b show fibre structure of floor panels according to preferred embodiments of the invention.
  • Fig 5a shows a floor panel with a HDF core 6.
  • a core comprises individual fibres with a thickness of about 0.03 mm and a length of about 2-5 mm.
  • the surface layer 5 comprises a decorative paper 10 and an overlay 13, which comprises individual fibres of the same size as the core 6.
  • the sub layer 6a comprises fibres, which are mechanically cut and essentially shorter. They have preferably an average length that does not exceed 1 mm. This means that the fibres in the sub layer have an average length which is 50% or less than the average length of the wood fibres in the core. Shorter fibres are even more preferred, for example of an average size of 30% of the length of core fibres or less.
  • fibres which have a length of only 0.1-0.3 mm.
  • Such micro fibres are very suitable to form high quality Solid Laminate Surface Layers.
  • Short fibres are easier to apply on a core in well- defined layers and they provide a soft sub layer, which is easy to form and compress to a solid and compact layer. They are easier to mix with resins especially if such resins are in dry powder form and a high internal bonding and moisture resistance could be reached.
  • Another advantage is that recycled and short fibres, which are not possible to use in paper production due to low bonding strength, could be used to form a strong sub layer in a floor panel. Long fibres similar to fibres used in HDF and paper could be used to form a sub layer. Such a layer will however give a much lower quality and the production will be more complicated and costly.
  • Figure 5b shows a panel with a particleboard core 6.
  • a particleboard core consists of small wood chips 14a comprising several fibres 14 which are connected with glue to a board.
  • the chips could have a thickness of 0.5-1.0 mm and a length of 2-4 mm.
  • Particleboard is softer and has a lower density than HDF.
  • the surface layer 5 is a Solid Laminate Surface Layer comprising short fibres.
  • the sub layer comprises the same fibre size as the surface layer.
  • the short fibres 14 in the two upper layers 6a, 5 could provide a very hard surface with high impact resistance even in the case when the core 6 is made of a rather soft material.
  • High impact resistance and a smooth surface layer similar to an HDF based panel can also be reached with a core of particleboard and with surface layers comprising paper or foil provided that the sub layer is compact and has a sufficient thickness to over bridge the irregularities of the soft core surface under the sub layer.
  • Figure 5c shows that a panel could be made which only has a core 6 and a sub layer 6a.
  • a balancing layer 7 could also be provided if needed.
  • Such a panel could be used as composite core material in laminate and wood flooring production.
  • Several sub layers 6a with different properties regarding density, moisture, sound, flexibility etc. could be used.
  • the sub layer should preferably have different materials or different material properties than the core. Different combinations of fibres, fibre size, density and binders could be used to make a cost effective core with high quality.
  • Figure 6a shows a panel with surface layers 5, and a sub layer 6a with preferably different design or structure.
  • Decorative grooves 8 could be formed to a depth such that the lower sub layer 6a is visible, as shown in Figure 6b.
  • Figure 6c shows that embossing could be made in connection with pressing and that such embossing 5b could form bevels at the edges of a floor panel when the floorboard and a floor panel is formed with mechanical locking systems.
  • Figure 6d shows that sharp embossing with an angle A of 45 degrees and more, extending upwardly from the horizontal plane HP, could be made. 45- 60 degrees is possible and even 90 degrees could be reached.
  • Such deep embossing could be combined with for example a surface layer 5 comprising paper sheets and with a depth D that exceeds the thickness of the surface layer 5 and a core surface, which is flat and parallel with the horizontal plane HP. No local compression of the core 6 is needed and this simplifies the production and allows deeper embossing.
  • Such embossing could be made with a depth D that is 2 times or even three times deeper than the thickness of the surface layer 5.
  • Figures 7a-e show a preferable method to create a surface layer with an in register embossed surface (EIR) 1 especially in a flooring according to embodiments of this disclosure.
  • An embossed pressure matrix 23 is provided preferably as a sheet, a structured paper, a roller, a belt and similar with a surface that comprises embossed protrusions 29 as shown in Figure 7a.
  • a decorative material for example paint or coloured fibres or similar is applied on the protrusions 29 with an application device for example a rubber roller 28 or similar.
  • a surface layer 5 comprising uncured fibres and binders is provided as shown in Figure 7c and the pressure matrix 23 is pressed against the surface layer 5, as shown in Figure 7d.
  • the decorative material 29 will be positioned at the lowest surface portions and a perfect in register embossing will be obtained as shown in Figure 7e.
  • This method is very suitable for all types of surfaces where decorative parts could be included in the surface during the final forming and curing of the surface in a pressing operation. Paint could be used that during pressing penetrates into the basic fibre structure. A print could be applied into a fibre layer, on an overlay or decorative paper or on a wood veneer.
  • a Solid Laminate Surface layer could be formed in several alternative ways. It is possible to produce such surface layer without colour pigments or wear resistant particles.
  • a thermosetting binder for example melamine, could in some embodiments be sufficient, if it is for example combined with fibres, preferably wear resistant fibres, that could be used to replace the wear resistant particles.
  • Plastic fibres or granulates for example nylon fibres or mineral fibres such as glass fibres, could improve the wear resistance considerably in a basic surface layer material that also comprises wood fibres.
  • Wood fibres in the sub layer could also partly or completely be replaced with plastic fibres or granulates, mineral fibres or vegetable fibres in the same way as described above for the surface layer and the same type of materials could be used.
  • the sub layer could also be used to produce for example a composite laminate similar to a conventional high-pressure laminate.
  • Such conventional laminates consists of one, or several phenol impregnated core papers under a melamine impregnated decorative paper.
  • the laminate is generally glued to a board. All or some of the core papers could be replaced with a sub layer comprising small wood fibres and binders as described in any of the preferred embodiments above.
  • the mix of wood fibres and binders could for example be applied on a core paper.
  • the fibres in the mix are preferably smaller than the fibres in the core paper or the decorative paper.
  • a decorative paper could be applied on the mix of wood fibres and binders.
  • Wood fibres, binders, core paper and decorative paper could be subjected to heat and pressure until the binder cures. Such a composite laminate could also be produced without a core paper.
  • a fibre layer could be applied directly on a release paper, a steal sheet or most preferably on a steal belt of a continuous press.
  • a composite laminate as described above is more cost efficient than conventional laminates. Deeper embossing, increased impact resistance and flexibility and a better sound level could for example be reached if one or several core papers are replaced with a wood fibre layer. Decorative grooves and bevels could be formed if the sub layer comprises colour pigments. Such a sub layer of a composite laminate could have a thickness of for example 0.1 - 1.0 mm and the total thickness of the solid laminate could be about 0.2 - 1.2 mm. Ticker layers of for example 1-3 mm or more are also possible.
  • the composite laminate could for example be glued to a board and used for example as a floor panel, wall panel or a furniture component.
  • All surface layers as described in the preferred embodiments could be used to form a composite layer in the same way as described above for the composite laminate.
  • a wood veneer preferably with a thickness of 0.3 - 1.0 mm, could for example be used in combination with a sub layer to produce a 2-4 mm veneer composite layer, which could be applied on a lamella core and used in an 12-15 mm engineered parquet floor in order to replace a 3 mm parquet strip of solid wood.
  • Foils and Solid Laminate Surface Layers could be combined with wood fibres and binders in order to form a composite layer. All of the above described embodiments could be used individually or in combinations.
  • an overlay with wear resistant particles is not excluded and this could increase the wear resistance of a wood veneer.
  • Dry and wet overlays which are produced by production methods where for example thermosetting resins in dry or wet form are mixed with aluminium oxide, without any fibres could also be used. Aluminium oxide particles mixed with melamine powder could for example be applied on a wood veneer prior to pressing and a wear resistant surface could be obtained without any surface coating after pressing.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Forests & Forestry (AREA)
  • Textile Engineering (AREA)
  • Floor Finish (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Laminated Bodies (AREA)

Abstract

Floor board (1) comprising a wood fibre based core (6) such as HDF, a thin surface layer (5) such as wood veneer, and a sub layer (6a) between the surface layer (5) and the core (6). The sub layer (6a) comprises wood fibres (14) and an uncured binder (19) and is applied on the core (6) as a powder. The layers (5, 6a) are connected to the core (6) and embossed in register by heating and pressing, the uncured sub layer (6a) behaving similar to a paste or a liquid substance and creating a uniform counter pressure under the thin surface layer (5), thus providing an easier forming of deep and sharp embossing without damaging the surface layer (5).

Description

WOOD FIBRE BASED PANELS WITH A THIN SURFACE LAYER
Technical field
The invention generally relates but is not limited to the field of wood fibre based building panels with a thin surface layer, preferably floor panels. The invention relates but is not limited to building panels with such surface layer and to equipment and methods to produce such panels.
Field of Application of the Invention
The present invention is particularly suitable for use in floating floors, which are formed of floor panels with a wood fibre core and a thin decorative wear resistant surface. The following description of prior-art technique, problems of known systems and objects and features of the invention will therefore, as a non-restrictive example, be aimed above all at this field of application and in particular at floorings which are similar to traditional wood fibre based laminate floorings.
It should be emphasized that the invention can also be used in other applications as for example wall panels, ceilings, and furniture components and similar.
Background
Wood fibre based direct pressed laminated flooring usually comprises a core of a 6-12 mm fibre board, a 0.2 mm thick upper decorative surface layer of laminate and a 0.1-0.2 mm thick lower balancing layer of laminate, plastic, paper or like material.
A laminate surface generally comprise two paper sheets, a 0.1 mm thick printed decorative paper and a transparent 0.05-0.1 mm thick overlay intended to protect the decorative paper from abrasion. The transparent overlay, which is made of α-cellulose fibres, comprises small hard and transparent aluminium oxide particles, which gives the thin surface layer a high wear resistance.
The printed decorative paper and the overlay are impregnated with melamine resin and laminated to a wood fibre based core under heat and pressure. The two papers have prior to pressing a total thickness of about 0.3 mm and they are after pressing compressed to about 0.2 mm.
Other common thin surface materials are wood veneer and foils, which are glued to a core.
The most common core material is fibreboard with high density and good stability usually called HDF - High Density Fibreboard with a density exceeding 800 kg/cm2. Sometimes also MDF - Medium Density Fibreboard - with a density of 600-800 kg/cm2 is used as core. Other core materials could also be used such as particleboard, plywood, and plastic materials and similar.
A balancing layer is generally applied on the rear side of the board in order to keep the panel flat when humidity changes.
HDF is produced as follows: Roundwood such as for example pine, larch or spruce are reduced to wood chips and then broken down into individual fibres in a refiner. The fibres are thereafter mixed with binders and then subjected to high pressure and temperature to form a board.
Floor panels with such thin surface layer are very cost effective compared to for example solid wood, stones and tiles. The major disadvantage is that properties related to deep surface structures, impact resistance and sound are inferior to the real products that they aim to copy.
Laminate floorings could be produced with very advanced designs where a printed pattern is coordinated with an embossed structure of the surface. The embossing is made during lamination when the surface is pressed against a steel sheet with an embossed structure.
The depth of the embossing is limited by the paper that could be damaged when the embossing is made with sharp edges or to a depth, which exceeds a few tenths of a millimetre. The embossing is mainly obtained by a compression of the overlay and the decorative paper. Embossed surfaces similar to a rough stone surface or a hand scraped wood surface or deep grooves that could be used to make bevels in a panel are not possible to make with the present pressing technology and with a reasonable cost structure maintaining the present technical properties and design.
Several methods have been used to increase the depths of the embossed surface structure.
It is known that one or several impregnated core paper sheets could be applied under the decorative surface paper and that deeper embossing up to 0.3 - 0.4 mm could be reached by a compression of the surface layer and the core paper. A similar method is described in WO 2004/067874. Such methods are expensive due to the fact that the pressure and pressing time must be increased from the normal level of 300-400 N/cm2 to about 800 N/cm2 and additional expensive material such as a core paper must be included in the panel under the decorative paper. Usually even the balancing layer has to be made thicker and this will increase the cost further.
It is also known that bevels and surface embossing could be made by a compression of the surface papers and the upper part of the core under the surface layer. Such a method is described in WO 03/078761 (Valinge Innovation AB) or WO 2006/066776. This method has several disadvantages. It could only be used in panels with a soft core such as MDF. This gives a low impact resistance and it is difficult to form high quality locking systems in such soft materials. In panels with a HDF core only limited and local embossing could be reached with conventional presses used in laminate production where the surface layer is formed and attached to a core (DPL technology). A considerable higher pressing force and longer pressing time is generally required to form surfaces similar to stone and rough wood surfaces.
Sufficient impact resistance can only be reached if thin surface layers are applied on a rather thick core with a high density. This means that the core material will be expensive and generally a board quality must be used that has better properties than what is needed for the overall stability of the panel and the strength of the locking system.
Definition of Some Terms
In the following text, the visible surface of the installed floor panel is called "front side", while the opposite side of the floor panel, facing the sub floor, is called "rear side". The sheet-shaped material that comprises the major part of a floor panel is called "core". When the core has a surface layer closest to the front side and preferably also a balancing layer closest to the rear side, it forms a semi-manufacture, which is called "floor board" or "floor element" in the case where the semi-manufacture, in a subsequent operation, is divided into a plurality of floor elements. When the floor elements are machined along their edges so as to obtain their final shape with the joint system, they are called "floor panels". By "surface layer" is meant all layers applied to the core closest to the front side and covering preferably the entire front side of the floorboard. By "decorative surface layer" is meant a layer, which is mainly intended to give the floor its decorative appearance. "Wear layer" relates to a layer, which is mainly adapted to improve the durability of the front side.
By "horizontal plane" is meant a plane, which extends parallel to the outer part of the surface layer. By "horizontally" is meant parallel to the horizontal plane. By "up" is meant towards the front face and by "down" towards the rear face.
Summary of the Invention
Wood fibre based floorings with thin surface layers similar to laminate and wood veneer floorings could capture a considerably larger market share if deep embossing and increased impact resistance could be reached in combination with a cost effective production method.
An overall objective of an embodiment of the present invention is to provide a building panel, preferably a floor panel, with a thin surface layer, which has a more attractive surface design and/or better surface properties and/or cost structure than present known floorings with conventional thin surface layers.
A specific objective of an embodiment of the invention is to provide a method to produce a floor panel with new attractive design features such as deep embossing which preferably could be combined with high impact and wear resistance, improved sound properties and cost effective production.
The problem has been solved, contrary to the known methods where several paper layers or a core is compressed, with a method and a panel, which comprises a sub layer between a surface layer and a core. This sub layer comprises or consists of small individual fibres and an uncured binder and is applied on the core as a powder. The small fibres are not bonded to each other as for example fibres in paper layers and a HDF core, and could easily be compressed, formed and displaced in all directions during a part of a pressing operation until the binder cures. The uncured sub layer behaves similar to a paste or a liquid substance and creates a uniform counter pressure in all parts under the surface layer even in surface parts with deep and sharp embossing. The result is an improved and easier forming with lower pressing force and improved surface quality. A thin surface layer will usually not be damaged, significantly or at all, during pressing and the sub layer will after curing provide a strong base for the thin surface layer. Such a base could be stronger than the core and improved impact resistance could be reached.
According to a first aspect of an embodiment of the invention a production method is provided to produce a floor board comprising a wood fibre based core, a thin surface layer and a sub layer between the surface layer and the core. The sub layer comprises or consists of wood fibres and a binder. The method comprises the steps of:
• mixing particles comprising wood fibres and an uncured binder for the sub layer,
• applying the wood fibres and the uncured binder for the sub layer on the core,
• applying a surface layer on the wood fibres and the uncured binder,
• bringing the core (6), the surface layer (5), the wood fibres (14) and the uncured binder (19) under increased pressure and temperature and forming them to a floor board (1) by curing the binder (19). The first aspect offers the advantage that the sub layer could be produced with higher density than the core and this could give the floor panel a high impact resistance even in the case when the surface layer is thin or the core rather thin or soft. A core material could also have a rather uneven core surface, which could be filled by the sub layer. This makes it possible to use for example particleboard or un-sanded HDF board in a DPL production based on one decorative paper and one overlay.
The wood fibre based sub layer is very cost efficient compared to for example a core paper. The curing time and the required pressure force in the press could be the same as for conventional laminate floorings.
The sub layer could comprise colour pigments with a different colour than the surface layer and decorative grooves, where the surface layer is removed and the sub layer is visible, could be formed.
The sub layer could also comprise particles, for example cork particles, which could give the floor panel improved sound properties and flexibility.
A cork layer could be used in combination with known surface materials such as laminate, resilient surfaces, fibre based surfaces, wood, wood veneer, linoleum, cork veneer and similar. Several advantages could be reached. A thin surface layer, for example a wood veneer could be applied, prior to pressing, on a sub layer comprising cork particles and binders. Pressing could take place against a press plate, which could create a deep embossing, or deep grooves. The thin surface layer will be formed and laminated to the sub layer. The thin surface layer will not be damaged since the cork particles will be compressed and formed according to the structure of the press plate. This forming technology could also be used in a panel where the sub layer comprises wood fibres or other type of fibres that could be formed by pressing.
According to a preferred embodiment of the first aspect, the method further comprises the step of pressing the surface layer with an embossed pressing matrix such that the surface layer obtains upper portions and embossed portions which are lower than the upper portions by shaping of the sublayer The embossed portions are preferably obtained by compression of the sublayer located under the embossed portion and/or by shifting fibres located under the embossed portion to the upper portions.
In a preferred embodiment a part of the sub layer is more compressed under an embossed portion than a part of the surface layer located under an upper portion.
An embodiment of the invention offers the advantages that the sub layer during the initial stage of the pressing is uncured and soft and comprises particles, which easily could be displaced during pressing. Very deep embossing could be formed with normal pressing force. Deep surface embossing of for example up to 0.5 mm and even more could easily be reached with a surface layer comprising a decorative paper, a foil, wood veneer and similar. The embossing is preferably formed when the surface is pressed against an embossed steel sheet or belt or a paper matrix.
A major advantage is that deep embossing of the surface layer and the sub layer could be formed without any compression of the core material. A compression of the core material is however not excluded. Such a compression of the core could take place if the sub layer for example is very thin.
The sub layer could comprise fibres and binders, which are suitable for a second pressing step where further embossing and forming could be formed in a press or with roll forming.
The thin surface layers should preferably have a thickness before pressing of about 0.3 - 1.0 mm. Thinner layers with a thickness of 0.1-0.2 mm are not excluded and very deep embossing could be formed with such thin surface layers of for example foils and papers. The surface layer could also be a print, paint or coating that is applied prior or after the pressing. Thicker layers of more than 1 mm could also be used, for example linoleum, resilient floor surfaces and similar.
The production could be made in continuous or discontinuous presses.
According to another preferred embodiment of the first aspect a surface layer is provided which comprises a homogenous mix of wood fibres, wear resistant particles binders and colour pigments. Such surface layer is below referred to as Solid Laminate Surface Layer. The surface layer preferably comprises natural resins, e.g. lignin, of bio based material, e.g. from wood.
The surface layer and the sub layer are in this embodiment rather similar regarding material properties and material composition. The surface layer comprises however wear resistant particles for example aluminium oxide and colour pigments. The binders and the fibres could be similar in both layers. The size of the fibres and the resin content could however vary. Very deep surface embossing and bevels of more than 1 mm depth could easily be formed.
According to a second aspect of an embodiment of the invention a building panel is provided comprising a thin surface layer, a wood fibre based core and a sub layer between the surface layer and the core. The sub layer comprises wood fibres and a binder and the average fibre length in the sub layer is shorter than the average length of the wood fibres in the core.
The panel could have all surface layers mentioned above.
Overlay, decorative papers, core papers and HDF are made of individual fibres with a thickness of a few hundreds of a millimetre and a length of several millimetres, generally in the range of 3-5 mm. This corresponds to a length/thickness ratio (LTR) of about 100. The sub layer according to the invention is formed of wood fibres that are mechanically cut into wood powder fibres. The average length of the fibres should preferably not exceed about 1 mm and this fibre length is considerably shorter than the length of the fibres in core. The LTR is in the region of about 30 or smaller. It is even more preferred that the fibres are smaller than 0.5 mm. Very high quality sub layers have been obtained with very small fibres with an average length of 0.1 - 0.3 mm and an average LRT of less than 10.
Short fibres are easier to apply on a core in well-defined layers and they provide a soft sub layer, which is easy to form and compress. They are easier to mix with resins especially is such resins are in dry powder form. Another advantage is that recycled and short fibres, which are not possible to use in paper production due to low strength, could be used to form a strong sub layer.
According to a preferred embodiment of the second aspect of the invention a building panel is provided, wherein the surface layer comprises upper portions and embossed portions lower than the upper portions wherein a part of the sub layer is more compressed under an embossed portion than under an upper portion.
It could be mentioned as a non-restricting example that the sub layer could comprise for example about 70-85% (weight) wood fibres and about 15-30% melamine resin. The layer could have a thickness, which is for example in the range of 0.1 mm - 1 mm or even more. Other combinations are of course also possible. The mixture should be adapted to the desired properties and cost structures. The binders contribute in general to give the surface a high impact and moisture resistance but they are rather costly. Other hard and heavy particles such as aluminium oxide or stone powder could be included in the sub layer in order to increase the density and to improve the impact resistance. It could be mentioned as a non-restricting example that the solid laminate surface layer could comprise for example about 25% (weight) aluminium oxide, about 25% wood fibres, about 25% melamine resin and about 25% colour pigments. The surface layer could have a thickness, which is for example in the range of 0.1 mm - 3 mm or even more. Other combinations are of course also possible. The melamine part could vary for example between 10 - 35%. The content of the colour pigments could be very low for example only about 0.1-5%. Wear resistant particles could be in the same range and could for example vary from a few percent to 35% and even higher. The mixture should be adapted to the desired properties and cost structures.
The pressure is preferably about 300N - 800N/cm2 and the temperature could be 120-220 degrees C. The pressing time could vary for example from 20 seconds to 5 minutes. It is possible to use very short pressing times, for example about 10 seconds or shorter, especially in embodiments where a rather thin surface and sub layers are applied on an HDF core before pressing. Thermoplastic binders such as PVC, PE, PP, etc could also be used.
It is preferred in all embodiments to use a dry process to form the sub layer and the solid laminate surface layer. The different materials and mixtures of different materials such as fibres, wear resistant particles, binders and colour pigments are distributed and scattered in a dry form. Scattering could be made with several stations comprising embossed or engraved rollers and brushes that could apply one or several layers of dry material.
A panel could of course be formed without a surface layer. Only a sub layer as described above could be applied on a core. The sub layer, which in this case has a surface of wood fibres and binders, could be made with a flat or embossed structure. A final decorative surface could be applied for example as a print in the factory or as a paint or coating or similar by the consumer. The panel could also be used without any additional decorative layer over the sub layer. New types of core materials could also be produced with for example a core and a sub layer applied on the core. The advantage is that core materials could be used which for example is not suitable to use in wood and laminate flooring. They could for example be too soft or difficult to laminate or glue. The sub layer could however create a strong and suitable base for the application of a surface layer. More cost effective core materials or core materials with other properties than HDF could be used. Decorative sub layers make it possible to form decorative grooves or bevels.
All preferred embodiments with and without wear resistant particles could be used to make panels, which could be applied vertically on a wall as wall panels in interior or exterior applications. Such panels could have a mechanical locking system on long edges that is possible to lock with angling and optional on short edges a locking system with for example a flexible tongue that allows vertical folding as described in for example WO 2006/043893.
A third aspect of an embodiment of the invention is floor production equipment which comprises a roller with needles or engraved protruding portions and a brush for applying dry materials comprising small wood fibres and binders and preferably wear resistant particles and colour pigments on a board material. The amount of needles or engraved protruding portions should be adapted to the dry materials and to the type and size of fibres, which are applied on the board material, to obtain an even flow of fibres and a clean roller after it has passed the brush. In a preferred embodiment the amount of needles or the engraved protruding portions is more than about 20 per cm2 and most preferably in the range of about 40 - 120 per cm2. This equipment could also be used in the production of WFF floor board as described in PCT/EP2008/065489.
Brief Description of the Drawings
Figs 1a-1d illustrate a known floor panel with an embossed surface.
Figs 2a-e illustrate a floor panel according to the invention. Figs 3a-d illustrate a production method to apply particles on a core.
Figs 4a-c illustrate a panel surface and production method to form an embossed surface
Figs 5a-c illustrate panels according to the invention.
Figs 6a-d illustrate a panel surface with decorative grooves and bevels.
Figs 7a-e illustrate a method to form an in register embossed surface.
Description of Embodiments of the Invention
Figure 1a shows a laminated floor panel 1 according to known technology comprising a surface layer 5, a core 6 and a balancing layer 7. Figure 1c shows the surface layer 5. It has an upper wear layer 13 of a transparent material with great wearing strength. Such a wear layer comprises generally a transparent paper impregnated with melamine resin and with aluminium oxide particles 12 added. A decorative layer 10 comprising paper with a printed pattern 11 is impregnated with melamine resin and placed under this transparent wear layer 13. The wear layer 13 and the decorative layer 10 are laminated to the core, generally a fibre based core such as HDF, under pressure and heat to an about 0.2 mm thick surface layer 5. Figure 1b shows the balancing layer 7 that generally also is a melamine-impregnated paper. This balancing layer keeps the floor panel flat when humidity varies over time. The transparent wear layer is generally 0.05 - 0.10 mm thick.
Figure 1d shows a laminate flooring with an embossed surface layer according to known technology. The surface layer 5 comprises upper portions 5a and embossed portions 5b, which are compressed and located lower than the upper portions. The embossing is made to a depth of about 0.1 mm and only the overlay 13 and the decorative paper (10) are compressed.
Figures 2a -2d shows a floor panel 1 according to one embodiment of the invention where the surface layer 5 is a Solid Laminate Surface Layer. A panel 1 is provided with a wood fibre based core 6, a non-transparent decorative surface layer 5 and preferably a balancing layer 7 as shown in Figure 2a. Figure 2b shows the surface layer 5 that comprises wood fibres 14, small hard wear resistant particles 12, 12' and a binder 19. Preferably the wood fibres are unrefined and comprise lignin. Such wear resistant particles (12,12') are preferably aluminium oxide particles. Other suitable materials are for example silica or silicon carbide. Diamond crystals or powder, could also be added into the surface layer. In general all materials with a hardness of Rockwell C hardness HRC of 70 or more could be used and they do not have to be transparent. A mixture of two or more materials could be used.
An embodiment of the invention offers the advantage that the wear resistant surface layer 5 could be made much thicker than in known floor panels. The thickness of the wear resistant and decorative surface layer could vary from for example about 0.1 mm to for example about4 mm or even more. Wear resistance with maintained decorative properties could be extremely high, for example in the region of 100,000 revolutions or more in a surface layer that is about 1.0 mm thick.
A preferable binder is melamine or urea formaldehyde resin. Any other binder, preferably thermosetting resins, could be used
Figure 2c show that a balancing layer 7 comprising preferably wood fibres 14' and a binder could be provided on the lower side of the floor panel. The fibres, the binder and also the pressing temperature should be adapted in an appropriate way to balance the surface layer and to keep the panel flat. The balancing layer 7 is preferably pressed with a higher temperature for example 5- 20 °C higher than the surface layer 5
It could be mentioned as a non-restricting example that the surface layer could comprise of for example 25% (weight) aluminium oxide, 25% wood fibres, 25% melamine resin and 25% colour pigments. The surface layer could have a thickness, which is for example in the range of 0.1 mm - 3 mm or even more. The most preferable thickness is 0.5 - 1.5 mm.
The surface layer comprises preferably wood powder with particle which are in the range of about 0.1 -0.3 mm or even smaller.
A particularly high quality surface layer 5 could be achieved if the wood fibres, which are mixed with the binding agent, colour pigments and wear resistant particles, are already pre coated and fully or partly pre cured with a binder, for example a melamine or urea formaldehyde resin, or pressed and then separated mechanically into wood fibre powder or wood fibre chips which are preferably smaller and more compact than the original wood fibres. Such a fibre composition is especially well suited to be mixed with wear resistant particles and could create a well defined base for the printing operation with wear resistant particles evenly spread over the whole surface layer. Such coated fibres could be obtained from recycled HDF.
Figure 2d show a panel where the surface layer 5 has been formed on a core 6 that has been produced in a prior separate operation, for example a HDF panel. There is a distinct connection 34 between the core 6 and the surface layer 5. The connection 34 could be very strong since binders 19 from the surface layer 5 penetrate into the upper part of the core 6, especially if the core is HDF or a wood based panel such as for example particleboard. Different binders or binder contents could be used in the upper and lower parts of the surface layer 5. A sub layer 6a is applied between the surface layer 5 and the core 6. This sub layer 6a could be produced in the same way as the Solid Laminate Surface Layer described above and the same material compositions could be used except for the fact that in some embodiments wear resistant particles and colour pigments are not included. Such materials could however be included in the sub layer 6a in order to for example create decorative grooves or to increase the impact resistance. The binders 19 in the sub layer 6a could be specially adapted to penetrate and reinforce the upper parts of the core 6 in order to for example increase the moisture resistance of the upper parts of the core.
Figure 2e shows that pressing a matrix to the surface 5 could create grooves 37, bevels, grout lines and similar. Such embossing could be made much deeper than in traditional laminate floorings where the paper will be damaged. Embossing with a depth of for example 1-2 mm or even more could easily be obtained. The production cost could be decreased if the thickness of the surface layer 5 is reduced and replaced with a sub layer 6a that only comprises wood fibres and binders. Such sub layer could increase impact resistance, reduce sound and create a layer that could be compressed and cured during pressing such that deep surface structures could be obtained which are deeper than the thickness of the Solid Laminate Surface Layer.
Figure 3a show a scattering station 60 which could be used to distribute dry materials in layers in order to form a Solid Laminate Surface Layer or a sub layer 6a. Fibres, wear resistant particles, binders in powder form and colour pigments in powder form could for example be mixed and applied into an container 55 that is in contact with an engraved roller 53. This roller 53 brings during rotation the mixed material 55 into contact with a brush roller 54 and the material 55 is applied on a conveyor belt 20 or on another layer or board material. Liquid resins or water 61 could be applied on the core or sprayed over the fibres in order to stabilize the fibre layer prior to pressing. This facilitates the pressing and the application of a surface layer over the sub layer. It is preferred to use water containing for example 1% weight content of a wetting agent for example BYK-348 from BYK Chemie which is applied on an core. 10-100g/m2 could be used. 10-20 g/m2 is preferred. Other types of wetting agents can also be used, as e.g., soap and the like.
Small wood fibres which are 1.0 mm or shorter and which are mixed with other dry materials such as melamine powder, colour pigments and small wear resistant particles as described above are very difficult to distribute in well defined layers. Conventional scattering equipment cannot be used. This problem could be solved if the surface of the roller 53 comprises a large amount of thin needles or spikes, which are preferably made of a strong and polished metal. The amount of needles or spikes should be adapted to the type and size of fibres, and to the other dry materials, which are applied on the board, to obtain an even flow of fibres and a clean roller after it has passed the brush. Further parameters, which should be considered, are the diameter and the length of the needles and the spikes. This is shown in figure 3b. The length of the needles is preferably about 1 mm and the thickness about 0.5 mm. Very good results have been reached with rollers which comprises about 80 needles/cm2, needle diameters of 0.5 mm and needle lengths of 0.8 mm, as shown in figure 3c. 40-120 needles/cm2 could also be used depending on the size of the powder particles and the material composition. The roller 53 has preferably a diameter of about 100 - 300 mm. It is preferred to use an oscillating brush 54 that moves along the length of the roller 53. Scattering equipment with such rollers could be used to apply materials in powder form and to create Solid Laminate Surface Layers and sub layers as describe in all preferred embodiments. As a non-limiting example it could be mentioned that 400 gr/m2 of powder material could be applied with a speed of 10 m/min. This corresponds to a pressed sub layer of about 0.2 mm. Lower speed and/or several scattering stations could be used if thicker layers are required.
An embodiment of the invention provides equipment and a method to produce a floorboard by applying dry materials comprising small wood fibres and binders and preferably wear resistant particles and colour pigments on a board material. The equipment comprises a roller with needles or engraved protruding portions and a brush. In a preferred embodiment the amount of needles or the engraved protruding portions is more than about 20 per cm2 and most preferably in the range of about 40 - 120 per cm2.
Figure 3d shows that several scattering stations 60a, 60b could be used to apply one or several layers 5, 6a on a core 6.
Figures 4a-c show how a thin surface layer 5, preferably a wood veneer layer, a printed paper with an overlay or a foil with a thickness of for example 0.3- 1.0 mm, could be formed with deep structures that give an appearance similar to solid wood. Figure 4a shows how a floorboard could be produced. A thin surface layer 5 is applied on a sub layer 6a comprising for example cork or wood fibres mixed with a binder, preferably a thermosetting binder. The sub layer 6a is applied on for example a wood fibre based core, preferably a HDF core. Other core materials could be used such as particleboard, plywood, plastic materials etc. A balancing layer 7 could also be applied to the core 6. Figure 4b show how the core and the layers are pressed together. This pressing forms the sub layer 6a and the surface layer 5, which are cured and connected to each other under heat and pressure. Very deep embossing could be obtained and a rough surface similar to hand scraped solid wood could be created with a thin wood veneer. The sub layer could be used to improve the properties of the surface layer, for example sound absorption and impact resistance.
This sub layer comprises or consists of small individual fibres and an uncured binder and is applied on the core as a powder. The small fibres are not bonded to each other as for example long fibres in paper layers and a HDF core, and could easily be compressed, formed and displaced in all direction during the initial part of a pressing operation until the binder cures. The uncured sub layer 6a behaves similar to a paste or a liquid substance and creates a uniform counter pressure in all parts under the surface layer even in surface parts with deep and sharp embossing.
The conversion from a layer of uncured unbonded fibres to a solid layer could be described by the following process:
1. A first step takes place when a heated press plate, or a steel belt in case a continuous press is used, is in initial contact with the surface layer and the protruding portions of the pres plate/belt are deforming parts of the surface layer. The sub layer material, which is in powder form, is partly displaced horizontally but also vertically upwards towards the cavities of the press plate/belt where parts of the surface layer could be pressed upwards into the cavities. A locally increased compression of the core under the protruding portions of the press plate/belt could take place if the sub layer is thin or if the initial pressure is high or if the embossing is deep. Such a compression of the core could however be avoided if thicker sub layers are used. 2. The sub layer material will be converted to a paste form in a second step when heat increases and the melamine binder becomes liquid. The pressure is substantially evenly distributed in the whole surface layer and sub layer. The pressure could now be increased and this will not cause any increased local compressions of the core or the surface layer.
3. A curing of the binders will take place in the final third step when heat and pressure reaches the maxim level and the sub layer will obtain its final properties related to shape and density.
Materials, material compositions, heat and pressure could according to an embodiment of the invention be adapted in order to form a high quality surface even in the case when deep and sharp embossing in combination with thin surface layers are used as a surface in a building panel. According to one preferred embodiment a panel with a HDF core and surface layer is provided comprising a decorative paper, an overlay and an embossed structure with a depth that exceeds the thickness of the surface layer and wherein the upper part of the HDF core is flat and essentially parallel with the horizontal plane HP.
The result is an improved and easier forming with lower pressing force and improved surface quality. A thin surface layer will usually not be damaged, significantly or at all, during pressing and the sub layer will after curing provide a strong base for the thin surface layer. Such a base could be stronger than the core and improved impact resistance could be reached.
Very deep embossing could be obtained with a surface layer that comprises conventional decorative paper and overlay used in conventional laminate floorings. The pressure time and the pressing force could also be similar to conventional laminate production. Conventionally a lamination pressure of about 400 N/cm2 is used. Embossing depth where the compressed portions 5b are about 0.3- 1.0 mm below the upper portions 5a can be made even when the surface structure comprises rather sharp embossed portions, for example with an angle exceeding 45 degrees against the horizontal plane HP1 as shown in figure 4c. Even deeper structures could be made but such structures are generally not suitable for floorings since they are difficult to clean and to place furniture on. Such deep embossing could however be used in wall panels and to form bevels at the edges of a floor panel.
Figures 5a and 5b show fibre structure of floor panels according to preferred embodiments of the invention. Fig 5a shows a floor panel with a HDF core 6. Such a core comprises individual fibres with a thickness of about 0.03 mm and a length of about 2-5 mm. The surface layer 5 comprises a decorative paper 10 and an overlay 13, which comprises individual fibres of the same size as the core 6. The sub layer 6a comprises fibres, which are mechanically cut and essentially shorter. They have preferably an average length that does not exceed 1 mm. This means that the fibres in the sub layer have an average length which is 50% or less than the average length of the wood fibres in the core. Shorter fibres are even more preferred, for example of an average size of 30% of the length of core fibres or less. Very compact and high quality layers have been obtained with fibres, which have a length of only 0.1-0.3 mm. Such micro fibres are very suitable to form high quality Solid Laminate Surface Layers. Short fibres are easier to apply on a core in well- defined layers and they provide a soft sub layer, which is easy to form and compress to a solid and compact layer. They are easier to mix with resins especially if such resins are in dry powder form and a high internal bonding and moisture resistance could be reached. Another advantage is that recycled and short fibres, which are not possible to use in paper production due to low bonding strength, could be used to form a strong sub layer in a floor panel. Long fibres similar to fibres used in HDF and paper could be used to form a sub layer. Such a layer will however give a much lower quality and the production will be more complicated and costly.
Figure 5b shows a panel with a particleboard core 6. Such a core consists of small wood chips 14a comprising several fibres 14 which are connected with glue to a board. The chips could have a thickness of 0.5-1.0 mm and a length of 2-4 mm. Particleboard is softer and has a lower density than HDF. The surface layer 5 is a Solid Laminate Surface Layer comprising short fibres. The sub layer comprises the same fibre size as the surface layer. The short fibres 14 in the two upper layers 6a, 5 could provide a very hard surface with high impact resistance even in the case when the core 6 is made of a rather soft material. High impact resistance and a smooth surface layer similar to an HDF based panel can also be reached with a core of particleboard and with surface layers comprising paper or foil provided that the sub layer is compact and has a sufficient thickness to over bridge the irregularities of the soft core surface under the sub layer.
Figure 5c shows that a panel could be made which only has a core 6 and a sub layer 6a. A balancing layer 7 could also be provided if needed. Such a panel could be used as composite core material in laminate and wood flooring production. Several sub layers 6a with different properties regarding density, moisture, sound, flexibility etc. could be used. The sub layer should preferably have different materials or different material properties than the core. Different combinations of fibres, fibre size, density and binders could be used to make a cost effective core with high quality.
Figure 6a shows a panel with surface layers 5, and a sub layer 6a with preferably different design or structure. Decorative grooves 8 could be formed to a depth such that the lower sub layer 6a is visible, as shown in Figure 6b. Very accurate and attractive design effects could be obtained. Figure 6c shows that embossing could be made in connection with pressing and that such embossing 5b could form bevels at the edges of a floor panel when the floorboard and a floor panel is formed with mechanical locking systems. Figure 6d shows that sharp embossing with an angle A of 45 degrees and more, extending upwardly from the horizontal plane HP, could be made. 45- 60 degrees is possible and even 90 degrees could be reached. Such deep embossing could be combined with for example a surface layer 5 comprising paper sheets and with a depth D that exceeds the thickness of the surface layer 5 and a core surface, which is flat and parallel with the horizontal plane HP. No local compression of the core 6 is needed and this simplifies the production and allows deeper embossing. Such embossing could be made with a depth D that is 2 times or even three times deeper than the thickness of the surface layer 5.
Figures 7a-e show a preferable method to create a surface layer with an in register embossed surface (EIR)1 especially in a flooring according to embodiments of this disclosure. An embossed pressure matrix 23 is provided preferably as a sheet, a structured paper, a roller, a belt and similar with a surface that comprises embossed protrusions 29 as shown in Figure 7a. A decorative material for example paint or coloured fibres or similar is applied on the protrusions 29 with an application device for example a rubber roller 28 or similar. A surface layer 5 comprising uncured fibres and binders is provided as shown in Figure 7c and the pressure matrix 23 is pressed against the surface layer 5, as shown in Figure 7d. The decorative material 29 will be positioned at the lowest surface portions and a perfect in register embossing will be obtained as shown in Figure 7e.
This method is very suitable for all types of surfaces where decorative parts could be included in the surface during the final forming and curing of the surface in a pressing operation. Paint could be used that during pressing penetrates into the basic fibre structure. A print could be applied into a fibre layer, on an overlay or decorative paper or on a wood veneer.
A Solid Laminate Surface layer could be formed in several alternative ways. It is possible to produce such surface layer without colour pigments or wear resistant particles. A thermosetting binder, for example melamine, could in some embodiments be sufficient, if it is for example combined with fibres, preferably wear resistant fibres, that could be used to replace the wear resistant particles. Plastic fibres or granulates, for example nylon fibres or mineral fibres such as glass fibres, could improve the wear resistance considerably in a basic surface layer material that also comprises wood fibres. It is also possible to replace wood fibres in the Solid Laminate Surface Layer completely or partly with other fibres such as vegetable fibres for example jute, linen, flax, cotton, hemp, bamboo, bagasse and sisal and to use wear resistant particle, for example aluminium oxide, to create a vegetable fibre based wear resistant surface layer.
Wood fibres in the sub layer could also partly or completely be replaced with plastic fibres or granulates, mineral fibres or vegetable fibres in the same way as described above for the surface layer and the same type of materials could be used.
The sub layer could also be used to produce for example a composite laminate similar to a conventional high-pressure laminate. Such conventional laminates consists of one, or several phenol impregnated core papers under a melamine impregnated decorative paper. The laminate is generally glued to a board. All or some of the core papers could be replaced with a sub layer comprising small wood fibres and binders as described in any of the preferred embodiments above. The mix of wood fibres and binders could for example be applied on a core paper. The fibres in the mix are preferably smaller than the fibres in the core paper or the decorative paper. A decorative paper could be applied on the mix of wood fibres and binders. Wood fibres, binders, core paper and decorative paper could be subjected to heat and pressure until the binder cures. Such a composite laminate could also be produced without a core paper. A fibre layer could be applied directly on a release paper, a steal sheet or most preferably on a steal belt of a continuous press.
A composite laminate as described above is more cost efficient than conventional laminates. Deeper embossing, increased impact resistance and flexibility and a better sound level could for example be reached if one or several core papers are replaced with a wood fibre layer. Decorative grooves and bevels could be formed if the sub layer comprises colour pigments. Such a sub layer of a composite laminate could have a thickness of for example 0.1 - 1.0 mm and the total thickness of the solid laminate could be about 0.2 - 1.2 mm. Ticker layers of for example 1-3 mm or more are also possible. The composite laminate could for example be glued to a board and used for example as a floor panel, wall panel or a furniture component.
All surface layers as described in the preferred embodiments could be used to form a composite layer in the same way as described above for the composite laminate. A wood veneer, preferably with a thickness of 0.3 - 1.0 mm, could for example be used in combination with a sub layer to produce a 2-4 mm veneer composite layer, which could be applied on a lamella core and used in an 12-15 mm engineered parquet floor in order to replace a 3 mm parquet strip of solid wood. Foils and Solid Laminate Surface Layers could be combined with wood fibres and binders in order to form a composite layer. All of the above described embodiments could be used individually or in combinations.
Using an overlay with wear resistant particles is not excluded and this could increase the wear resistance of a wood veneer. Dry and wet overlays, which are produced by production methods where for example thermosetting resins in dry or wet form are mixed with aluminium oxide, without any fibres could also be used. Aluminium oxide particles mixed with melamine powder could for example be applied on a wood veneer prior to pressing and a wear resistant surface could be obtained without any surface coating after pressing.

Claims

1. A method of manufacturing a floor board (1) comprising a wood fibre based core (6) a thin surface layer (5) and a sub layer (6a) between the surface layer and the core, the sub layer comprises wood fibres (14) and a binder (19), wherein the method comprises the steps of:
• mixing particles comprising wood fibres (14) and an uncured binder (19) for the sub layer (6a);
• applying the wood fibres (14) and the uncured binder (19) for the sub layer on the core (6) ; • applying a surface layer (5) on the wood fibres (14) and the uncured binder; and (19)
• bringing the core (6), the surface layer (5), the wood fibres (14) and the uncured binder (19) under increased pressure and temperature and forming them to a floor board (1) by curing the binder (19).
2. The method as claimed in claim 1 , wherein the method further comprises the step of pressing the surface layer 5) with an embossed pressing matrix (23) such that the surface layer (5) obtains upper portions (5a) and embossed portions (5b) lower than the upper portions, essentially by shaping of the sublayer.
3.The method as claimed in anyone of claims 1 and 2, wherein the core (6) is HDF.
4. The method as claimed in anyone of the claims 1-3, wherein the thin surface layer (5) has a thickness of about 0.3-1.0 mm.
5. The method as claimed in anyone of the claims 1-4, wherein the binder
(19) in the sub layer (6) is a thermosetting resin, preferably a melamine resin.
6. The method as claimed in anyone of claims 1-5, wherein the method further comprises applying water or a liquid resin on the core (6) or into the fibres (14) of the sub layer (6a) prior to pressing.
7. The method as claimed in anyone of the claims 1-6, wherein the surface layer (5) comprises a homogenous solid mix of wood fibres (14), wear resistant particles (12), binders (19) and colour pigments (15).
8. The method as claimed in claim 7, wherein the wear resistant particles (12) comprise aluminium oxide.
9. The method as claimed in anyone of the claims 1-8, wherein the surface layer (5) comprises a binder (19) of a thermosetting resin.
10. The method as claimed in anyone of the claims 1-8, wherein the surface layer (5) comprises a binder (19) of a thermoplastic resin.
11. The method as claimed in anyone of the claims 1-6, wherein the surface layer (5) is a printed paper (10) with an overlay (13).
12. The method as claimed in anyone of the claims 1-6, wherein the surface layer (5) is a wood veneer.
13. The method as claimed in anyone of claims 1-12, wherein the method comprises a machining operation comprising forming the floor board to a floor panel (1) with mechanical locking systems (4, 4') at opposite edges.
14. The method as claimed in anyone of claims 1-13, wherein the step of applying the wood fibres and the binder is with a roller (53) comprising needles (62) or engraved protruding portions (63).
15. The method as claimed in claim 14, wherein the amount of needles
(62) or the engraved protruding portions (63) is about 40 - 120 per cm2.
16. A building panel, comprising a thin surface layer (5), a wood fibre based core (6) and a sub layer (6a) between the surface layer (5) and the core (6), the sub layer (6a) comprises wood fibres (14) and a binder (19) characterised in that that the sub layer (6a) comprises fibres with an average length (L2) which is shorter than the average length (L1) of the wood fibres in the core (6).
17.The building panel as claimed in claim 16, wherein the surface layer (5) comprises upper portions (5a) and embossed portions (5b) lower than the upper portions (5a) whereby a part of the sub layer (6a) is more compressed under an embossed portion (5b) than under an upper portion (5a).
18.The building panel as claimed in claims 16 or 17, wherein the average length (L2) of the fibres in the sub layer (6a) does not exceed 50% of the average length (L1) of the fibres in the core (6).
19.The building panel as claimed in claim 18, wherein the length (L2) of the fibres in the sub layer (6a) does not exceed 30% of the length (L1) of the fibres in the core (6).
2O.The building panel as claimed in anyone of the claims 16-19, wherein the building panel is a floor panel comprising a balancing layer (7).
21. The building panel as claimed in anyone of the claims 16-20, wherein the binder (19) in the sub layer (6a) is a thermosetting or resin.
22. The building panel as claimed in claim 21 wherein the binder (19) in the sub layer (6a) is a melamine resin.
23. The building panel as claimed in claims 16-20, wherein the binder (19) in the sub layer (6a) comprises a thermosetting resin.
24. The building panel as claimed in anyone of the claims 16-23 wherein the core (6) comprises HDF.
25. The building panel as claimed in anyone of claims 16-24 wherein the thin surface layer (5) comprises a substantially homogenous mix of wood fibres (14), which comprise natural resins, a binder (19) and wear resistant particles (12).
26. The building panel as claimed in claim 25, wherein the wear resistant particles (12) comprise aluminium oxide.
27. The building panel as claimed in claim 26, wherein the surface layer
(5) further comprises colour pigments (15) and a melamine resin.
28.The building panel as claimed in anyone of claims 16-24, wherein the surface layer (5) is a wood veneer.
29. The building panel as claimed in anyone of claims 16-24, wherein the surface layer (5) comprises a decorative paper (10) and an overlay (13).
30. The building panel as claimed in anyone of claims 17 -24, wherein the surface layer (5) comprises a decorative paper (10) and an overlay (13) and the embossed portions (5b) a part with an edge which is formed with an angle (A) exceeding 45 degrees to the horizontal plane (HP)
31. The building panel as claimed in claim 30 wherein the embossed structure (5b) comprises a part with a depth (D) that exceeds the thickness of the surface layer (5) and wherein the upper part of the core (6) is flat and essentially parallel with a horizontal plane (HP).
32. The building panel as claimed in anyone of claims 16-24, wherein the surface layer (5) comprises a foil comprising a thermoplastic resin.
33. The building panel as claimed in anyone of claims 16- 32, wherein the surface layer has a thickness, which does not exceed 1.0 mm.
34. The building panel as claimed in anyone of claims 16- 33, wherein the sub layer comprises cork particles.
35. A floorboard production equipment (60) characterised in that that the equipment (60) comprises a roller (53) with needles (62) or engraved protruding portions (63) and a brush (54) for applying dry materials comprising small wood fibres (14) and binders (19) on a board material (6)
36. The equipment as claimed in claim 35 wherein the amount of needles (62) or the engraved protruding portions (63) is more than about 20 pieces per cm2.
37. The equipment as claimed in claim 35, wherein the amount of needles (62) or the engraved protruding portions (63) is about 40 - 120 pieces per cm2.
38. The equipment as claimed in anyone of the claims 35 -37 wherein the dry materials comprise wear resistant particles (12) and colour pigments (15).
PCT/EP2009/002523 2008-04-07 2009-04-06 Wood fibre based panels with a thin surface layer WO2009124704A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
PL09731199T PL2344311T3 (en) 2008-04-07 2009-04-06 Method of manufacturing a wood fibre based floor board
ES09731199.7T ES2693125T3 (en) 2008-04-07 2009-04-06 Method of manufacturing a floor board based on wood fiber
EP09731199.7A EP2344311B1 (en) 2008-04-07 2009-04-06 Method of manufacturing a wood fibre based floor board
EP18189881.8A EP3470193B1 (en) 2008-04-07 2009-04-06 Method of manufacturing a building panel
CN200980112247.XA CN101998896B (en) 2008-04-07 2009-04-06 Fibre based panels with a wear resistance surface
LTEP09731199.7T LT2344311T (en) 2008-04-07 2009-04-06 Method of manufacturing a wood fibre based floor board
HRP20181597TT HRP20181597T1 (en) 2008-04-07 2018-10-04 Method of manufacturing a wood fibre based floor board

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
SE0800776 2008-04-07
SE0800776-7 2008-04-07
EP2008/065489 2008-11-13
EP08065489 2008-11-13

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EP (2) EP2344311B1 (en)
ES (1) ES2693125T3 (en)
HR (1) HRP20181597T1 (en)
LT (1) LT2344311T (en)
PL (1) PL2344311T3 (en)
WO (1) WO2009124704A1 (en)

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