WO2009122153A2 - Electroluminescent displays - Google Patents
Electroluminescent displays Download PDFInfo
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- WO2009122153A2 WO2009122153A2 PCT/GB2009/000835 GB2009000835W WO2009122153A2 WO 2009122153 A2 WO2009122153 A2 WO 2009122153A2 GB 2009000835 W GB2009000835 W GB 2009000835W WO 2009122153 A2 WO2009122153 A2 WO 2009122153A2
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- WIPO (PCT)
- Prior art keywords
- layer
- liquid crystal
- barrier layer
- electroluminescent display
- backlight
- Prior art date
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Classifications
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
- G02F1/133602—Direct backlight
- G02F1/133603—Direct backlight with LEDs
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1334—Constructional arrangements; Manufacturing methods based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2201/00—Constructional arrangements not provided for in groups G02F1/00 - G02F7/00
- G02F2201/50—Protective arrangements
Definitions
- This invention is concerned with electroluminescent displays, and more specifically to displays that are electroluminescent/liquid crystal hybrids.
- Certain materials are electroluminescent - that is, they emit light, and so glow, when an electric field is generated across them.
- the first known electroluminescent materials were inorganic particulate substances such as zinc sulphide, while more recently-found electroluminescent materials include a number of small-molecule organic emitters known as organic light emitting diodes (OLEDs) and some plastics - synthetic organic polymeric substances - known as light-emitting polymers (LEPs) .
- OLEDs organic light emitting diodes
- LEPs light-emitting polymers
- Inorganic particulates in a doped and encapsulated form, are still in use, particularly when mixed into a binder and applied to a substrate surface as a relatively thick layer; LEPs can be used both as particulate materials in a binder matrix or, with some advantages, on their own as a relatively thin continuous film.
- an electroluminescent (EL) material - generally referred to in this context as a phosphor - is provided to form a backlight which can be seen through a mask that defines whatever characters the display is to show.
- the displays are arranged with shaped electrodes such that small individual areas of EL material can be selectively activated.
- These displays have many applications; examples are a simple digital time and date display (to be used in a watch or clock) , a mobile phone display, the control panel of a household device (such as a dishwasher or washing machine) , and a handheld remote controller (for a television, video or DVD player, a digibox, stereo or music centre or similar entertainment device) .
- WO 2005/0121878 describes an electroluminescent display (Hybrid Display) with a Liquid Crystal (LC) mask that is switchable in individual areas, between "on” /transparent (so that the backlight can shine therethrough) and "off /opaque (so that the backlight' s light is blocked thereby) .
- the LC mask and the EL backlight are formed as a single integral unit wherein both components (the LC mask and EL backlight) are operated using common electrodes - the EL backlight being created as an electroluminescent material layer mounted directly on the rear of or behind the layer of liquid crystal material.
- a polymer dispersed liquid crystal (PDLC) film consisting of droplets of liquid crystal, typically nematic or cholestic in nature, dispersed in a polymer matrix (binder) is suitable for the LC mask of such a hybrid display.
- PDLC polymer dispersed liquid crystal
- the unpowered state can be strongly absorbing as well as scattering, whilst the powered state combines transparency with low absorption.
- This type of PDLC is known as NCAP (entrapped nematic curvilinear aligned phase) and the inventor has found the NCAP type of PDLC to be particularly suitable for use as the LC material in the hybrid display.
- NCAP PDLCs minimise dye migration into the binder, and so do not degrade the achievable contrast.
- These films can be constructed using an emulsification method, or by using one of a number of phase separation techniques.
- the emulsification method uses mechanical shear to disperse dyed liquid crystal organic oil into an aqueous-based medium comprising a water-soluble polymer, for example polyvinyl alcohol (PVA) , which is to form the polymer matrix.
- PVA polyvinyl alcohol
- WO 2005/0121878 discloses a method wherein each of the various layers is screen-printed into place (apart from the ITO front electrode, which is usually sputtered onto the substrate) , through masks that define the shape, size and position of each layer of the display, using suitable pastes that are subsequently dried, set or cured, as appropriate, prior to the next layer or collection of layers being applied.
- NCAP PDLC material with PVA as a binder is unsatisfactory because, even though the PVA is an excellent binder, providing very stable emulsions, it absorbs water readily from the atmosphere, which in turn degrades the electro-optic performance of the PDLC through water dependent leakage currents. Accordingly, displays manufactured using PVA as a binder in the LC layer have poor environmental stability, which can result in defects, such as spotting of the display.
- UK patent application No: 0625114.4 proposes a solution to this problem wherein the PDLC layer comprises UV curable polyurethane.
- a display having such a PDLC layer may have increased environmental stability and improved electro-optical behaviour.
- hybrid displays comprising a PDLC layer fade when exposed to elevated temperatures, such as 50 or 60 0 C.
- This fading has been observed as an increase in the reflectivity of the display, particular in non-illuminated areas of the display. This increase in reflectivity decreases the contrast between the illuminated and non- illuminated areas of the display and hence reduces legibility of the display.
- the print quality of the phosphor layer printed onto the PDLC is lower than a phosphor layer printed onto an ITO layer.
- an electroluminescent display comprising a mask defining the information to be displayed, an electroluminescent (EL) backlight, the mask comprising a layer of physically stabilised liquid crystal switchable to define the information to the displayed mounted in front of an EL layer of the backlight, at least one pair of electrodes arranged to generate, in use, an electric field across both the EL layer and the LC layer and a barrier layer between the LC layer EL layer that restricts migration of liquid crystal from the LC layer to the EL layer.
- EL electroluminescent
- the barrier layer reduces, or even prevents, the migration of liquid crystal from the liquid crystal layer to the EL layer reducing or even eliminating fading of the display.
- a method of manufacturing a display comprising forming a mask defining the information to be displayed, the mask comprising a layer of physically stabilised liquid crystal, forming a barrier layer, forming an EL layer of a backlight with the liquid crystal layer mounted in front of the EL layer and forming at least one pair of electrodes arranged to generate, in use, an electric field across both the EL layer and the LC layer, wherein the barrier layer restricts migration of liquid crystal from the liquid crystal layer to the EL layer,
- front means the side of the display from which the display is to be viewed.
- the liquid crystal layer is in a physically stabilised form rather than its normal liquid mobile form, for example the liquid crystal may be liquid crystal vesicles encapsulated in a polymer matrix, such as a polymer- dispersed liquid crystal (PDLC) , or a polymer stabilised liquid crystal (PSLC) .
- PDLC polymer- dispersed liquid crystal
- PSLC polymer stabilised liquid crystal
- Layers forming the backlight may be printed directly on the barrier layer.
- layers of the EL backlight may be formed at a unit separate (i.e. remote) from the LC layer and the barrier layer, which is then adhered to the rear of the barrier layer.
- the barrier layer may be arranged to limit the migration of liquid crystal from the LC layer to layers behind the mask such that no significant fading of the display occurs due to migration of the liquid crystal under pre-determined criteria. It will be understood that the term "significant fading” is used herein to mean changes in contrast of the display that are noticeable to the naked eye,
- the barrier layer may be arranged to limit the migration of liquid crystal from the LC layer to layers behind the mask such that, when the display is heated to 85 degrees over 18hrs, there is virtually no change, and preferably no change whatsoever, in contrast between illuminated and non-illuminated areas of the display.
- the EL material backlight may comprise an insulating layer behind a layer of electroluminescent material.
- the barrier layer may comprise a material in which the liquid crystal has low solubility. As liquid crystal particles in the LC layer cannot dissolve in the barrier layer, migration of liquid crystal through the barrier layer to the EL backlight is reduced or even eliminated.
- the barrier layer may comprise a material in which the liquid crystal has solubility lower than the solubility of liquid crystal in phosphor.
- the barrier layer may comprise material in which the liquid crystal has a low enough solubility such that no significant fading of layers behind the LC layer occurs due to migration of the liquid crystal under pre-determined criteria, for example, no significant fading of the layers behind the LC layer occurs due to migration of the liquid crystal when the display is heated at a set temperature for a set time, for example 85°C for approximately 18 hrs.
- Solubility can be measured as the maximum amount of solute that can dissolve per amount of solvent under specified conditions.
- the barrier layer may comprise a material in which the liquid crystal has substantially zero, and preferably zero, solubility at room temperature and atmospheric pressure.
- the barrier layer may comprise a hydrophilic layer, in particular a hydrophilic polymer.
- the polymer may be a water soluble polymer such as polyvinyl alcohol, polyvinyl alcohol copolymer, such as an ethylene vinyl alcohol copolymer, polyvinyl butyral, gelatin and its derivatives, cellulose derivatives, polyacrylics and derived polymers and polyacrylic acids and derived polymers.
- the polymer may be a non- water soluble polymer that can be carried in an emulsion and/or dispersion, such as polyurethanes, polyethylene-acrylic acid copolymer and derived copolymers, polymethacrylics and derived copolymers and polymethacrylic acids and derived copolymers.
- the polymer may be a hydrophobic polymer, such as polyvinylidenefluorude, polyamides, polysiloxanes, polyvinyl esters.
- the polymer is a polyvinyl alcohol (PVA) , or a polyvinyl alcohol copolymer such as an ethylene vinyl alcohol copolymer.
- PVA polyvinyl alcohol
- the polyvinyl alcohol or polyvinyl alcohol copolymer has a degree of hydrolysis of between 72% and 99%.
- the degree of hydrolysis may be between 75% and 99%, and/or an ethylene content may be less than 51%.
- the ethylene content may be between 5 and 51%. It has been found that PVA and polyvinyl alcohol copolymers are suitable for use as the barrier layer because liquid crystal has low solubility in this material and the material have the required level of hydrophilicity to function as desired.
- the barrier layer may comprise a polymer in which the liquid crystal has low solubility and a further polymer to improve the adhesion of the barrier layer with the LC layer and/or the EL layer.
- a hydrophilic barrier layer When a hydrophilic barrier layer absorbs water it increases its electrical conductivity (reduces its resistivity) such that the electrical characteristics of the display may be similar to such a display without the barrier layer.
- a completely dry hydrophilic polymer layer may have a resistance of about 10 10 ⁇ cm, whereas, after absorbing water from the environment, its resistivity may reduce to 10 6 or even 10 5 ⁇ cm. In this way, the introduction of a hydrophilic barrier layer has little, or even no, impact on the electrical characteristics of the display, but acts to prevent migration of the liquid crystal.
- the polymer matrix of the liquid crystal layer may be any one of water based, monomer free radiation curable urethane oligomer dispersions; acrylic functional polyurethane dispersions and acrylic urethane emulsions.
- the polymer matrix is a UV curable polymer matrix, for example a UV curable aliphatic polyurethane resin, such as those supplied by DSM Neoresin under the trade names NeoRez® R440, R440, R445, R401 and R501.
- the matrix may comprise other film forming UV curable polymers, for example, UV curable polyurethane dispersions (known in the art as UV-PUD) , acrylic dispersions, silicones and mixtures therefore.
- the matrix resin can be formed from an aqueous solution or emulsion that contains very low levels, and preferably no, co-solvent.
- the polymer matrix comprises substantially no PVA.
- substantially no PVA means the polymer matrix comprises less than 5% PVA, preferably less than 1% PVA and most preferably, no PVA.
- a number of different component materials could be used to form a shell of the vesicles.
- One example of a pair of component materials that may be used for the shell is a multifunctional iscocyanate (e.g. Desmodur N3200 - sold by Bayer) and a diamine, such as ethylene diamine.
- the reaction may be catalysed by a tertiary amine, such as DABCO.
- the liquid crystal may be any one of the main types such material - such as nematic and cholesteric or chiral nematic - the requirement is, generally, for a liquid crystal based material that allows polariserless high contrast electro-optical shuttering operation between a field "on” state that is optically transmissive and a base field “off” state that us less transmissive than the "on” state.
- the liquid crystal contains a dye.
- the liquid crystal includes up to 6% by weight of a dye, preferably a dichroic dye.
- levels of dye in the liquid crystal are 3- 5% by weight.
- the dye attaches to the liquid crystal molecules and acts to obscure light when no field is applied across the liquid crystal but when a field is applied, the dye molecules are aligned for allowing the transmission of light.
- the barrier layer limits the migration of both the liquid crystal and dye to layers behind the liquid crystal layer.
- the LC mask and the EL backlight may be constructed as a single entity. By this, it is meant that the LC mask is adhered to the EL backlight or sandwiched between layers of the display to be immovable with respect to the backlight.
- an electrically-insulating transparent front layer known as the substrate usually made of glass or plastic, such as polyethylene terephthalate (PET) or polyethylene naphthalate (PEN) ; a first electrically-conductive film, for example, made from a material such as indium tin oxide (ITO) , forming one electrode - the front electrode - of the backlight; the electroluminescent (EL) layer (usually a particulate phosphor within a binder matrix); an electrically-insulating layer of a material - usually a ceramic - having a relatively high dielectric constant (relative permittivity) of around 50 (in some applications, such as the present invention, this layer is most desirably significantly optically-reflective, while in others it preferably has low reflectivity) ; and disposed over the rear face of the electrically-insulating layer, an electrically conductive film forming a second electrode-conductive film forming a second electrode - the rear electrode - of the back
- the display of the invention may incorporate disposed over the entire rear face of the substrate a single (front) electrode, and disposed over the rear face of the reflective electrically-insulating layer a patterned (rear) electrode defining areas of both the liquid crystal layer and the electroluminescent layer that can be selected to be switched "on” or “off” .
- a patterned (rear) electrode defining areas of both the liquid crystal layer and the electroluminescent layer that can be selected to be switched "on” or "off” .
- both electrodes it is possible as an alternative to pattern the front electrode and to have a single "whole-face" rear electrode.
- both electrodes it is possible for both electrodes to be patterned - as will need be the case if the display is going to be a matrix device where a multitude of very small areas can be illuminated at will so as to enable almost any shape and size of displayed image simply by selecting which areas are lit and which are dark.
- a method of reducing fading of an electroluminescent display comprising a mask defining the information to be displayed, an electroluminescent (EL) backlight, the mask comprising a layer of physically-stabilised liquid crystal mounted in front of an EL layer of the backlight, and at least one pair of electrodes arranged to generate, in use, an electric field across both the EL layer and the LC layer, the method comprising providing a barrier layer between the LC layer and the EL layer that restricts migration of liquid crystal from the LC layer to the EL layer.
- EL electroluminescent
- the method may comprise identifying a material that, when used as a barrier layer, limits the migration of liquid crystal from the LC layer to layers behind the LC layer such that no significant fading of the display occurs due to migration of the liquid crystal and using the identified material for the barrier layer.
- a method of determining a material suitable for use as a barrier layer in an electroluminescent display comprising forming a layered structure comprising a physically-stabilised liquid crystal (LC) layer mounted in front of a test layer and a layer of material between the LC layer and the test layer that has potential as the material of the barrier layer, heating the layered structure to a predetermined temperature for a predetermined length of time, examining the test layer for liquid crystal migration, and determining whether the material is suitable for use as a barrier layer based on whether there is liquid crystal migration.
- LC physically-stabilised liquid crystal
- the layered structure may comprise a display comprising a mask defining the information to be displayed and an electroluminescent (EL) backlight, the mask comprising a layer of physically-stabilised liquid crystal (LC) mounted in front of an EL layer of the backlight, at least one pair of electrodes arranged to generate, in use, an electric field across both the EL layer and the LC layer and the layer of material that has potential as the material of the barrier layer being between the LC layer and the test layer mounted behind the EL.
- EL electroluminescent
- LC physically-stabilised liquid crystal
- the test layer may be of a material in which liquid crystal is soluble and may be an insulator.
- a method of manufacturing an electroluminescent display comprising forming a mask defining the information to be displayed, the mask comprising a layer of physically stabilised liquid, forming a barrier layer, forming an EL layer of a backlight with the LC layer mounted in front of the EL layer and forming at least one pair of electrodes arranged to generate, in use, an electric field across both the EL layer and the LC layer, wherein the barrier layer is made of material identified as suitable for use as a barrier layer in accordance with the fourth aspect of the invention.
- an electroluminescent display comprising a mask defining the information to be displayed, an electroluminescent (EL) backlight, the mask comprising a layer of physically-stabilised liquid crystal switchable to define the information to the displayed mounted in front of an EL layer of the backlight, at least one pair of electrodes arranged to generate, in use, an electric field across both the EL layer and the LC layer and a barrier layer between the mask and the EL layer, wherein the barrier layer is made of material identified as suitable for use as a barrier layer in accordance with the fourth aspect of the invention.
- Figure 1 shows a section through a display according to an embodiment of the invention
- Figure 2 shows the display of Figure 1 in plan view
- Figure 3 is a table illustrating the suitability of different materials as a barrier layer.
- the structure of the embodiment of the display of the invention depicted in Figure 1 of the accompanying drawings can be seen to be, from front to back: a relatively thick protective electrically-insulating transparent front layer (11 ; the substrate) ; over the rear face of the substrate 11 , a very thin transparent electrically-conductive film (12) forming the front electrode of the display; covering the rear face of the front electrode 12, a relatively thin layer (13) of LC material (14) physically-stabilised by being dispersed within a supporting polymer matrix (15) (PDLC layer) ; formed directly on, and covering the rear face of the liquid crystal layer (13) , a relatively thin barrier layer (10) of PVA that restricts migration of liquid crystal from the PDLC layer (13) to layers (16, 19,20) to the rear of the LC layer; a relatively thin layer of electroluminescent/phosphor material (17) dispersed within a supporting matrix (18) ; over the rear face of the phosphor layer (16
- the front and rear electrodes together define discrete areas of both the liquid crystal layer and the electroluminescent layer that can be selected to be switched "on” or “off” .
- the LC layer defines a mask defining the information to be displayed and the EL layer a backlight to illuminate the areas defined by the mask.
- the back electrode layer may be covered with a protective film (not shown here) .
- the dielectric constant of the electrically insulating layer may be around 50.
- the PDLC layer (13) of the display is formed in the manner described in GB 0625114.4 with liquid crystal vesicles encapsulated in a UV cured polyurethane matrix.
- the term “relatively thick” means thicknesses in the range of 30 to 300 micrometres. Furthermore, it will be understood that the term “relatively thin” means thicknesses of 50 micrometres or less. In a preferred embodiment, the relatively thick layers are around 100 micrometres and the relatively thin layers are 25 micrometres or less.
- Figure 2 is an example of the types of information that may appear on the display.
- a number of materials were evaluated as barrier layers by coating a layer of diluted polymer solution onto a sample of PDLC prepared as described in GB 0625114.4. After drying the layer an EL lamp construction was printed onto the rear side of the layer of diluted polymer solution. Each display was then aged by placing the display in an oven held at 85°C for approximately 18 to 24 hrs, at which point it was examined for visible signs of liquid crystal/dye migration. A second display having a barrier layer of each material was characterised electro-optically before and after a similar aging process.
- FIG. 3 illustrates the results of these tests.
- Celvol 205 PVA can be identified as particularly suitable for use as the barrier layer with Celvol 205/EAA at a ratio of 9: 1 may also be suitable depending on the required electro-optical performance of the display.
- test displays prepared using PVA as a barrier layer (Mowiol 23-88) were prepared and subjected to a hot-humid aging test at
- barrier layer may be suitable for use as a barrier layer. It is believed these suitable materials can be determined by testing the material in the manner described above. The suitability of the material for the barrier layer will depend on the required performance for the display. Therefore, the temperature to which the display is heated and the time for which the display is heated during the test may be varied depending on the required performance. Materials identified as suitable for a barrier layer then can be used to manufacture a display in accordance with the invention.
- suitable materials will be those in which liquid crystal has low solubility.
- barrier layers it may also be advantageous to include a polymer to improve the adhesion of the barrier layer with the LC layer and/or the EL layer.
- separate electrodes may be used for driving the backlight and the mask. It will be understood that it is not necessary to print a whole display in order to test the suitability of a material as a barrier layer but such a determination could be carried out by printing a layer of the material to be tested between a PDLC layer and a test layer, such as an insulator in which liquid crystal is soluble, and carrying out the above-described heat test on the resulting layered structure. If liquid crystal has migrated through to the test layer, the material is deemed inappropriate for use as a barrier layer.
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- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Chemical & Material Sciences (AREA)
- Optics & Photonics (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Mathematical Physics (AREA)
- Liquid Crystal (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Electroluminescent Light Sources (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09727547.3A EP2279449B1 (en) | 2008-03-29 | 2009-03-27 | Electroluminescent displays |
CN2009801168609A CN102037398B (en) | 2008-03-29 | 2009-03-27 | Electroluminescent displays |
US12/892,288 US8704975B2 (en) | 2008-03-29 | 2010-09-28 | Electroluminescent displays |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0805751.5A GB0805751D0 (en) | 2008-03-29 | 2008-03-29 | Electoluminescent displays |
GB0805751.5 | 2008-03-29 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/892,288 Continuation US8704975B2 (en) | 2008-03-29 | 2010-09-28 | Electroluminescent displays |
Publications (2)
Publication Number | Publication Date |
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WO2009122153A2 true WO2009122153A2 (en) | 2009-10-08 |
WO2009122153A3 WO2009122153A3 (en) | 2010-02-18 |
Family
ID=39386988
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2009/000835 WO2009122153A2 (en) | 2008-03-29 | 2009-03-27 | Electroluminescent displays |
Country Status (6)
Country | Link |
---|---|
US (1) | US8704975B2 (en) |
EP (1) | EP2279449B1 (en) |
KR (1) | KR20110000746A (en) |
CN (1) | CN102037398B (en) |
GB (1) | GB0805751D0 (en) |
WO (1) | WO2009122153A2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0625114D0 (en) * | 2006-12-16 | 2007-01-24 | Pelikon Ltd | Electroluminescent displays |
WO2013142319A1 (en) * | 2012-03-21 | 2013-09-26 | Mflex Uk Limited | Transflective display with color shift reduction |
US11175544B2 (en) | 2017-03-07 | 2021-11-16 | President And Fellows Of Harvard College | Stretchable electrooptical and mechanooptical devices comprising a liquid crystal cell disposed between first and second ionic conducting gel layers |
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US5121234A (en) * | 1990-10-29 | 1992-06-09 | Honeywell Incorporated | Dichroic liquid crystal display with integral electroluminescent backlighting |
WO2002031589A1 (en) * | 2000-10-12 | 2002-04-18 | Durel Corporation | El lamp with heater electrode |
WO2003083523A2 (en) * | 2002-03-27 | 2003-10-09 | Avery Dennison Corporation | Switchable electro-optical laminates |
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EP1731949A1 (en) * | 2004-03-31 | 2006-12-13 | NEC Corporation | Liquid crystal panel, manufacturing method thereof, and electronic device using the liquid crystal panel |
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JPH0375686A (en) * | 1989-08-17 | 1991-03-29 | Alps Electric Co Ltd | Electroluminescence element |
JPH08104874A (en) * | 1994-10-06 | 1996-04-23 | Fujitsu Ltd | Liquid crystal material, liquid crystal display apparatus and its production |
JP2003530459A (en) * | 2000-04-05 | 2003-10-14 | カリフォルニア インスティテュート オブ テクノロジー | Polymers for controlling the alignment state and stability of liquid crystals |
US20020113753A1 (en) * | 2000-12-18 | 2002-08-22 | Alan Sullivan | 3D display devices with transient light scattering shutters |
US6627273B2 (en) * | 2001-03-13 | 2003-09-30 | Cryovac, Inc. | Lidstock laminate |
FR2827397B1 (en) * | 2001-07-12 | 2003-09-19 | Saint Gobain | ELECTROCOMMANDABLE DEVICE WITH VARIABLE OPTICAL PROPERTIES OR HOLOGRAPHIC, THERMOTROPIC OR SUSPENDED PARTICLE SYSTEM |
KR100630475B1 (en) * | 2001-09-06 | 2006-10-02 | 샤프 가부시키가이샤 | Display, Method of Manufacturing the Same, and Method of Driving the Same |
US7248235B2 (en) * | 2001-09-14 | 2007-07-24 | Sharp Kabushiki Kaisha | Display, method of manufacturing the same, and method of driving the same |
JP4285935B2 (en) * | 2002-03-06 | 2009-06-24 | 株式会社リコー | Liquid crystal gel composition, display medium using the same, display device, and display body |
US20050129875A1 (en) * | 2003-12-15 | 2005-06-16 | Eastman Kodak Company | Aligned liquid crystal layer containing onium salts and process for increasing the tilt |
EP1693698A1 (en) * | 2005-02-16 | 2006-08-23 | SONY DEUTSCHLAND GmbH | A method for forming a polymer dispersed liquid crystal cell, a cell formed by such method and uses of such cell |
GB0625114D0 (en) * | 2006-12-16 | 2007-01-24 | Pelikon Ltd | Electroluminescent displays |
JP2008249896A (en) * | 2007-03-29 | 2008-10-16 | Fujifilm Corp | Polarizing plate protection film, polarizing plate and liquid crystal display device |
-
2008
- 2008-03-29 GB GBGB0805751.5A patent/GB0805751D0/en not_active Ceased
-
2009
- 2009-03-27 CN CN2009801168609A patent/CN102037398B/en active Active
- 2009-03-27 EP EP09727547.3A patent/EP2279449B1/en active Active
- 2009-03-27 KR KR1020107024480A patent/KR20110000746A/en not_active Application Discontinuation
- 2009-03-27 WO PCT/GB2009/000835 patent/WO2009122153A2/en active Application Filing
-
2010
- 2010-09-28 US US12/892,288 patent/US8704975B2/en not_active Expired - Fee Related
Patent Citations (6)
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US5121234A (en) * | 1990-10-29 | 1992-06-09 | Honeywell Incorporated | Dichroic liquid crystal display with integral electroluminescent backlighting |
WO2002031589A1 (en) * | 2000-10-12 | 2002-04-18 | Durel Corporation | El lamp with heater electrode |
WO2003083523A2 (en) * | 2002-03-27 | 2003-10-09 | Avery Dennison Corporation | Switchable electro-optical laminates |
EP1380879A1 (en) * | 2002-07-11 | 2004-01-14 | Kabushiki Kaisha Toyota Jidoshokki | Display unit |
EP1731949A1 (en) * | 2004-03-31 | 2006-12-13 | NEC Corporation | Liquid crystal panel, manufacturing method thereof, and electronic device using the liquid crystal panel |
WO2005121878A1 (en) * | 2004-06-11 | 2005-12-22 | Pelikon Limited | Electroluminescent displays |
Also Published As
Publication number | Publication date |
---|---|
GB0805751D0 (en) | 2008-04-30 |
EP2279449B1 (en) | 2017-11-08 |
US20110234084A1 (en) | 2011-09-29 |
EP2279449A2 (en) | 2011-02-02 |
US8704975B2 (en) | 2014-04-22 |
KR20110000746A (en) | 2011-01-05 |
CN102037398B (en) | 2013-08-28 |
WO2009122153A3 (en) | 2010-02-18 |
CN102037398A (en) | 2011-04-27 |
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