WO2009116806A1 - Method for preparing cerium carbonate - Google Patents
Method for preparing cerium carbonate Download PDFInfo
- Publication number
- WO2009116806A1 WO2009116806A1 PCT/KR2009/001383 KR2009001383W WO2009116806A1 WO 2009116806 A1 WO2009116806 A1 WO 2009116806A1 KR 2009001383 W KR2009001383 W KR 2009001383W WO 2009116806 A1 WO2009116806 A1 WO 2009116806A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cerium carbonate
- cerium
- carbonate
- orthorhombic
- aqueous solution
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/224—Oxides or hydroxides of lanthanides
- C01F17/235—Cerium oxides or hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/247—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1409—Abrasive particles per se
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1454—Abrasive powders, suspensions and pastes for polishing
- C09K3/1463—Aqueous liquid suspensions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/31051—Planarisation of the insulating layers
- H01L21/31053—Planarisation of the insulating layers involving a dielectric removal step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
Definitions
- the present invention relates to a method for preparing cerium carbonate, a cerium carbonate powder, and a method for preparing a cerium oxide powder using the same. More specifically, the present invention relates to a method for preparing cerium carbonate which enables preparation of hexagonal cerium carbonate by a simplified process, a cerium carbonate powder prepared thereby, and a method for preparing a cerium oxide powder using the same.
- Cerium oxide is high functional ceramic material widely used as a catalyst, phosphor, cosmetics, abrasive, etc., and, recently, it is spotlighted as an abrasive for CMP (Chemical Mechanical Polishing) process in the field of semiconductor device.
- CMP Chemical Mechanical Polishing
- the cerium oxide is generally prepared by a liquid-phase method, a gas-phase method or a solid-phase method.
- a pH controlling agent such as ammonia is added to starting material, i.e., trivalent or tetravalent cerium salt to directly prepare cerium oxide from cerium salt.
- starting material i.e., trivalent or tetravalent cerium salt
- this method is economical because raw material cost and equipment cost is comparatively low, it is difficult to control particle growth because reaction between starting materials easily occurs from nucleation stage.
- a cerium metal salt precursor is vaporized and then combined with oxygen, etc. to directly prepare cerium oxide.
- This method includes flame combustion decomposition, gas condensation decomposition, plasma vaporization, laser vaporization, etc.
- this method has difficulty in terms of massification because costs of the cerium metal salt precursor and equipment are high, and the study thereof is still under progress.
- cerium oxide is sintered at high temperature to prepare cerium oxide.
- cerium carbonate is widely used, and the property and shape of cerium oxide change according to the kind and shape of cerium carbonate.
- it is required to control the kind or shape of precursor cerium carbonate precursor.
- the present invention provides a method for preparing cerium carbonate which enables preparation of hexagonal cerium carbonate by more simplified process, and a cerium carbonate powder prepared thereby.
- the present invention provides a method for preparing a cerium oxide powder using the cerium carbonate powder.
- the present invention provides CMP (Chemical Mechanical Polishing) slurry comprising cerium oxide powder prepared by the above method.
- the present invention provides a method for preparing cerium carbonate comprising the step of contact-reacting orthorhombic cerium carbonate with a primary alcohol aqueous solution comprising water and primary alcohol at a weight ratio of 1 : 0.1 or more at a temperature of 16O 0 C or more to form hexagonal cerium carbonate.
- the present invention also provides a cerium carbonate powder prepared by the above method, comprising orthorhombic cerium carbonate and hexagonal cerium carbonate at a volume ratio of 99:1 to 0:100.
- the present invention provides a method for preparing a cerium oxide powder comprising the step of sintering the above cerium carbonate powder.
- the present invention also provides CMP (Chemical Mechanical Polishing) slurry comprising the cerium oxide powder prepared by the above method as an abrasive.
- Fig. 1 shows XRD analysis results of cerium carbonate powders prepared in
- Fig. 2 shows XRD analysis results of cerium oxide powder prepared from the cerium carbonate powders of Examples 1 to 4, Comparative Example 1 and 2, according to Example 5.
- a method for preparing cerium carbonate, cerium carbonate powder, a method for preparing cerium oxide powder, and CMP slurry according to specific embodiments of the invention will now be explained.
- a method for preparing cerium carbonate comprising the step of contact-reacting orthorhombic cerium carbonate with a primary alcohol aqueous solution comprising water and primary alcohol at a weight ratio of 1 : 0.1 or more at a temperature of 16O 0 C or more to form hexagonal cerium carbonate is provided.
- cerium oxide having appropriate property or shape can be easily prepared from the cerium carbonate and applied for CMP slurry.
- the method for preparing cerium carbonate according to the embodiment of the invention will be explained in detail.
- the crystal structure of cerium carbonate is divided into orthorhombic or hexagonal according to the amounts of hydroxide group bound to carbonate functional group, and they can be prepared by precipitation reaction of cerium precursor and carbonate precursor. It is expected that orthorhombic cerium carbonate is produced according to the following Reaction Formula 1, and hexagonal cerium carbonate is produced according to the following Reaction Formula 2.
- hexagonal cerium carbonate a cerium precursor such as cerium salt and urea are dissolved in water and reacted.
- weak hydrolysis of Ce ion should occur before CO 3 2" is combined to Ce ion (see the above Reaction Formula 2), thus it is required to conduct the above reaction at high temperature.
- urea may be decomposed at high temperature to generate ammonia and carbon dioxide, etc., which may generate gas pressure, the above reaction had to be conducted under very high pressure, for example, pressure almost reaching 100 bar.
- hexagonal cerium carbonate can be prepared simply by contact-reacting orthorhombic cerium carbonate with a primary alcohol aqueous solution comprising water and primary alcohol at a specific weight ratio at a given temperature.
- hexagonal cerium carbonate can be obtained under a pressure not so high.
- hexagonal cerium carbonate can be obtained by more simplified process comprising contact-reacting orthorhombic cerium carbonate with a primary alcohol aqueous solution.
- the method according to one embodiment of the invention can largely contribute to improvement in economical efficiency and practicality of preparation process of hexagonal cerium carbonate.
- cerium carbonate of desired kind and shape can be easily obtained by converting orthorhombic cerium carbonate to hexagonal carbonate partially or wholly.
- the contact reaction between the orthorhombic cerium carbonate and the primary alcohol aqueous solution is conducted at 160 ° C or more, preferably 160-230 0 C .
- the contact reaction temperature is less than 160 ° C , reactivity of the orthorhombic cerium carbonate and primary alcohol aqueous solution is low, thus hexagonal cerium carbonate conversion rate is largely decreased, or hexagonal cerium carbonate conversion occurs little.
- reaction pressure may be increased too much for increasing reaction temperature, and additional effects for increasing hexagonal cerium carbonate conversion rate are not significant.
- weight ratio of the orthorhombic cerium carbonate and the primary alcohol aqueous solution is preferably 1 :0.5 to 1:100. If the weight ratio of the primary alcohol aqueous solution to the orthorhombic cerium carbonate is less than the above range, orthorhombic cerium carbonate may be converted to cerium oxide. If the weight ratio of the primary alcohol aqueous solution to the orthorhombic cerium carbonate is higher than the above range, hexagonal cerium carbonate conversion rate may be decreased.
- the contact time of the orthorhombic cerium carbonate and the primary alcohol aqueous solution can be controlled according to the composition of primary alcohol aqueous solution, weight ratio of orthorhombic cerium carbonate and primary alcohol aqueous solution, reaction temperature, etc. considering required hexagonal cerium carbonate conversion rate. Preferably, it is controlled within 1 hour to 60 hours.
- hexagonal cerium carbonate conversion time can be decreased by increasing the amount of alcohol in the primary alcohol aqueous solution or decreasing the weight ratio of the orthorhombic cerium carbonate to the primary alcohol aqueous solution.
- the weight ratio of the primary alcohol and water in the primary alcohol aqueous solution is 1 :0.1 or more, preferably 1 :0.1 to 1:4.
- the weight ratio of water and primary alcohol is less than 1 :0.1, hexagonal cerium carbonate conversion rate is largely decreased, or hexagonal cerium carbonate conversion occurs little.
- reaction pressure may be increased too much, and additional effects for increasing hexagonal cerium carbonate conversion rate are not significant.
- the primary alcohol comprised in the primary alcohol aqueous solution is not specifically limited only if it is has one alkyl group substituted for carbinol carbon. Examples thereof include methanol, ethanol, propanol, butanol, etc. without limitations, and ethanol or butanol is preferable.
- the orthorhombic cerium carbonate that is contact-reacted with the primary alcohol aqueous solution is in the form of Ce 2 O(CO 3 ) I 1 H 2 O, and it can be prepared by common method known in the art including precipitation reaction of cerium precursor and carbonate precursor as shown in the above Reaction Formula 1.
- cerium salt comprising trivalent or tetravalent cerium
- cerium nitrate Ce(NOs) 3 -xH 2 0
- cerium sulfate Ce(SO 4 ) 3 -xH 2 O or Ce(SO 4 ) 2 -xH 2 O
- cerium chloride CeCl 3 -xH 2 O
- diammonium cerium nitrate Ce(NH 4 ) 2 (NO 3 ) 6 or Ce(NH 4 ) 2 (NO 3 ) 5 -xH 2 O) (wherein, x is constant of from 0 to 10).
- urea CO(NH 2 )2
- carbonate salt As the carbonate precursor, urea (CO(NH 2 )2) or carbonate salt can be used, and it may also function as a pH controlling agent.
- the separation may be conducted by common separation method in the art, for example, separation by cooling or centrifugal separation.
- the washing is preferably conducted using DI water such that ion value may be 3 mS or less. Thereby, crystal size of sintered powder can be suitably controlled, and difficulties involved in milling can be prevented.
- the drying is preferably conducted at 60 ° C or more for 24 hours.
- hexagonal cerium carbonate can be prepared by simple contact reaction of a primary alcohol aqueous solution and orthorhombic cerium carbonate.
- a cerium carbonate powder comprising orthorhombic cerium carbonate and hexagonal cerium carbonate at an appropriate ratio can be obtained by changing reaction conditions of the contact reaction, for examples, composition of the primary ethanol aqueous solution, weight ratio of orthorhombic cerium carbonate and primary ethanol aqueous solution, or reaction temperature range, thereby controlling conversion rate of orthorhombic cerium carbonate to hexagonal cerium carbonate.
- a cerium carbonate powder of suitably controlled kind and shape can be obtained, and a cerium oxide powder with desired property and shape can be obtained therefrom and CMP slurry comprising the same can be easily obtained
- a cerium carbonate powder prepared by the above method may comprise orthorhombic cerium carbonate and hexagonal cerium carbonate at various ratios by the above method.
- it may comprise orthorhombic cerium carbonate and hexagonal cerium carbonate at various volume ratios within a range of from 99:1 to 0:100, preferably from 50:50 to 0:100.
- cerium oxide powder satisfying preferred property and shape as a CMP abrasive can be easily obtained.
- a method for preparing a cerium oxide powder comprising the step of sintering the above cerium carbonate powder is provided.
- the sintering may be conducted by common sintering method for preparing cerium oxide powder known in the art. For example, it may comprise the step of heating at 600 to 1200 ° C . And, the sintering is preferably conducted for 30 minutes ⁇ 4 hours. If the sintering time is less than 30 minutes, crystallinity of the prepared cerium oxide powder is low thus decreasing polishing rate when used as a CMP abrasive. If the sintering time exceeds 4 hours, crystal growth of cerium oxide is excessive thus causing serious scratch on the polished surface when used as an abrasive.
- the obtained cerium oxide powder can manifest desired polishing property.
- a cerium oxide powder (or abrasive) prepared from hexagonal cerium carbonate as a precursor has high polishing rate for silicon oxide film and low polishing rate for silicon nitride film, thus having excellent polishing selectivity between a silicon oxide film and a silicon nitride film as well as excellent global planarization.
- a cerium oxide powder (or abrasive) prepared from orthorhombic cerium carbonate as a precursor is advantageous for polishing of a silicon nitride film having high strength.
- a volume ratio of orthorhombic cerium carbonate and hexagonal cerium carbonate in a precursor cerium carbonate powder for example, within a range of from 99:l ⁇ 0:100, polishing property of cerium oxide powder as an abrasive, polishing rate for a silicon oxide film, polishing rate for a silicon nitride film, polishing selectivity between a silicon oxide film and a silicon nitride film or global planarization, etc. can be easily controlled.
- a CMP slurry comprising the above cerium oxide powder as an abrasive.
- the CMP slurry comprises the cerium oxide powder as an abrasive, and it may further comprise a dispersant and/or water.
- the content of the cerium oxide powder in the slurry is preferably 0.1 to 50 parts by weight, based on 100 parts by weight of the slurry. If the content of the abrasive cerium oxide powder is less than 0.1 parts by weight in the slurry, it is difficult to polish a surface to be polished, and if the content exceeds 50 parts by weight, a viscosity of the slurry increases to lowering dispersion stability.
- the dispersant is preferably contained in an amount of 0.5 to 10 parts by weight, based on 100 parts by weight of the abrasive. If the content of the dispersant is less than 0.5 parts by weight, dispersion ability is low thus accelerating precipitation, and thus precipitation may occur when transferring the slurry, which may cause non-uniform provision of the abrasive. If the content of the dispersant exceeds 10 parts by weight, a dispersant layer functioning as a cushion forms thickly around abrasive particles, and thus the surface of an abrasive is difficult to be contacted to the surface to be polished thus decreasing polishing rate.
- non-ionic polymer dispersant or anonic polymer dispersant can be used as the dispersant.
- the non-ionic polymer dispersant may be selected from the group consisting of polyvinyl alcohol(PAA), ethylene glycol(EG), glycerin, polyethylene glycol(PEG), polypropylene glycol(PPG), polyvinyl pyrrolidone(PVP) and a mixture thereof
- the anionic polymer dispersant may be selected from the group consisting of polyacrylic acid, polyacrylic acid ammonium salt, polyacryl maleic acid and a mixture thereof.
- the dispersant is not limited thereto, and various dispersants known to be useable for CMP slurry can be used without limitations.
- the CMP slurry is titrated to pH 6 to 8, after mixing the cerium oxide powder, dispersant and water.
- the titration may be conducted using IN KOH or IN HNO 2 .
- dispersion stabilization process is preferably conducted.
- the dispersion stabilization process is preferably conducted by wet milling dispersion method capable of exactly and finely controlling particle size, for example, ball mill, attrition mill, etc.
- the CMP slurry composition finally prepared by the dispersion stabilization preferably has particle size distribution of less than 3 ⁇ m, and average particle size of 50 to 1000 nm. If the average particle size is less than 50 nm, polishing rate for the surface to be polished is too low, and if it exceeds 1000 nm, fine scratch of the polished surface may be generated or storage stability of the slurry may be deteriorated.
- the particle size distribution is as measured by a particle size distribution analyzer (Horiba LA-910).
- the CMP slurry may further comprise other additives for improving polishing performance or dispersion stability.
- EXAMPLES The invention is further explained in more detail with reference to the following examples. These examples, however, should not be interpreted as limiting the scope of the invention in any manner.
- a cerium carbonate powder was prepared by the same method as Example 1 , except that the weight ratio of the ethanol aqueous solution and orthorhombic cerium carbonate was changed to 1 : 0.67 instead of 10:1.
- Example 4 Water and butanol were mixed at a weight ratio of 1 : 1 to prepare an butanol aqueous solution, and then, the butanol aqueous solution and orthorhombic cerium carbonate were introduced in a reactor at a weight ratio of 10:1, and agitated for 10 hours.
- the reaction temperature was adjusted to 200 0 C, and agitation speed was adjusted to 200 rpm.
- XRD analysis of the prepared cerium carbonate powder was conducted, and the result was shown in Fig. 1. From the result, it was confirmed that the whole orthorhombic cerium carbonate was converted to hexagonal cerium carbonate.
- Comparative Examples 1-2 A cerium carbonate powder was prepared by the same method as Example 1, except that the composition of the ethanol aqueous solution, weight ratio of orthorhombic cerium carbonate and ethanol aqueous solution, or reaction temperature was changed as shown in the following Table 1.
- the cerium carbonate powders prepared in Example 1 to 4, Comparative Examples 1 and 2 were heated at 900 0 C for 2 hours to prepare cerium oxide powders, and XRD analysis was conducted and the results were shown in Fig. 2. From the results, it was confirmed that the cerium carbonate powder was changed to cerium oxide.
- Example 6 0.5 kg of each cerium oxide powder prepared in the Example 3, 25g of polyacrylic acid dispersant (Aldrich) and 5 L of pure water were mixed to prepare cerium oxide dispersion.
- the prepared cerium oxide dispersion was titrated using ammonia water to pH 7.0, and then, dispersion stability improving and particle size distribution control processes were conducted with ball mill.
- the ball-mill was conducted at 250 rpm for 2 hours using 10Og of 1 mm zirconia bead.
- the dispersion was filtered with 1 ⁇ m filter, and then, pure water was added thereto such that the content of the cerium oxide powder may be 1 part by weight per 100 parts by weight of total slurry, to prepare a CMP slurry.
- the cerium oxide has an average particle size of 176nm, and particle size distribution of about 70 ⁇ 300 nm as measured by particle size distribution analyzer (Horiba LA-910) .
- Each CMP slurry prepared in the Example 6 was used for polishing under the following conditions for 1 minute, and then, the substrate was washed, and thickness change resulting from the polishing was measured to evaluate polishing performance. The results were shown in the following Table 2.
- Polishing equipment GNP POLY 400 (GNP Technology) Pad: polyurethane type
- Delta WIWNU (Within Wafer Non-Uniformity) was calculated by Standard deviation method (ASTM).
- cerium carbonate powders having different ratios of orthorhombic cerium carbonate and hexagonal cerium carbonate have different kinds and shapes, cerium oxide powders and CMP slurry prepared therefrom show different polishing performances.
Abstract
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Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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US12/933,576 US8216327B2 (en) | 2008-03-20 | 2009-03-18 | Method for preparing cerium carbonate |
CN2009801097590A CN101978017B (en) | 2008-03-20 | 2009-03-18 | Method for preparing cerium carbonate |
JP2011500704A JP5520926B2 (en) | 2008-03-20 | 2009-03-18 | Cerium carbonate production method |
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KR10-2008-0026010 | 2008-03-20 | ||
KR20080026010 | 2008-03-20 | ||
KR1020090022715A KR101184732B1 (en) | 2008-03-20 | 2009-03-17 | Method for preparing cerium carbonate |
KR10-2009-0022715 | 2009-03-17 |
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WO2009116806A1 true WO2009116806A1 (en) | 2009-09-24 |
WO2009116806A9 WO2009116806A9 (en) | 2009-11-26 |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20060162260A1 (en) * | 2005-01-26 | 2006-07-27 | Lg Chem, Ltd. | Cerium oxide abrasive and slurry containing the same |
WO2007035034A1 (en) * | 2005-09-20 | 2007-03-29 | Lg Chem, Ltd. | Cerium carbonate powder, method for preparing the same, cerium oxide powder made therefrom, method for preparing the same, and cmp slurry comprising the same |
KR20080011044A (en) * | 2006-07-28 | 2008-01-31 | 주식회사 엘지화학 | Cerium oxide powder, method for preparing the same, and cmp slurry comprising the same |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20060162260A1 (en) * | 2005-01-26 | 2006-07-27 | Lg Chem, Ltd. | Cerium oxide abrasive and slurry containing the same |
WO2007035034A1 (en) * | 2005-09-20 | 2007-03-29 | Lg Chem, Ltd. | Cerium carbonate powder, method for preparing the same, cerium oxide powder made therefrom, method for preparing the same, and cmp slurry comprising the same |
KR20080011044A (en) * | 2006-07-28 | 2008-01-31 | 주식회사 엘지화학 | Cerium oxide powder, method for preparing the same, and cmp slurry comprising the same |
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