WO2009108677A3 - Emission treatment systems and methods using passivated surfaces - Google Patents

Emission treatment systems and methods using passivated surfaces Download PDF

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Publication number
WO2009108677A3
WO2009108677A3 PCT/US2009/035102 US2009035102W WO2009108677A3 WO 2009108677 A3 WO2009108677 A3 WO 2009108677A3 US 2009035102 W US2009035102 W US 2009035102W WO 2009108677 A3 WO2009108677 A3 WO 2009108677A3
Authority
WO
WIPO (PCT)
Prior art keywords
methods
treatment systems
emission treatment
passivated
passivated surfaces
Prior art date
Application number
PCT/US2009/035102
Other languages
French (fr)
Other versions
WO2009108677A2 (en
Inventor
Joseph A. Patchett
Edgar V. Huennekes
Martin Kalwei
Original Assignee
Basf Catalysts Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Catalysts Llc filed Critical Basf Catalysts Llc
Publication of WO2009108677A2 publication Critical patent/WO2009108677A2/en
Publication of WO2009108677A3 publication Critical patent/WO2009108677A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/88—Handling or mounting catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9431—Processes characterised by a specific device
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066—Selective catalytic reduction [SCR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2067—Urea
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/208—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B01D2255/502—Beta zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/08—Adding substances to exhaust gases with prior mixing of the substances with a gas, e.g. air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/14—Arrangements for the supply of substances, e.g. conduits
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49345—Catalytic device making

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Toxicology (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

Provided are exhaust systems, components, and catalytic articles that have been passivated for use in conjunction with diesel engines that includes a NOx abatement system that uses a reductant. These items are passivated in order to minimize degradation of a reductant in their presence when, for example, they have been subjected to temperatures in excess of 650 °C.
PCT/US2009/035102 2008-02-25 2009-02-25 Emission treatment systems and methods using passivated surfaces WO2009108677A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US3117008P 2008-02-25 2008-02-25
US61/031,170 2008-02-25
US12/391,812 US8776499B2 (en) 2008-02-25 2009-02-24 Emission treatment systems and methods using passivated surfaces
US12/391,812 2009-02-24

Publications (2)

Publication Number Publication Date
WO2009108677A2 WO2009108677A2 (en) 2009-09-03
WO2009108677A3 true WO2009108677A3 (en) 2009-10-22

Family

ID=40996971

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/035102 WO2009108677A2 (en) 2008-02-25 2009-02-25 Emission treatment systems and methods using passivated surfaces

Country Status (2)

Country Link
US (1) US8776499B2 (en)
WO (1) WO2009108677A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9079162B2 (en) * 2008-04-28 2015-07-14 BASF SE Ludwigshafen Fe-BEA/Fe-MFI mixed zeolite catalyst and process for the treatment of NOX in gas streams
JP2009262098A (en) * 2008-04-28 2009-11-12 Ne Chemcat Corp Exhaust gas clarifying method using selective reduction catalyst
US8661797B2 (en) * 2010-11-15 2014-03-04 GM Global Technology Operations LLC NOx adsorber regeneration system and method
JP6594292B2 (en) * 2013-03-14 2019-10-23 ビーエーエスエフ コーポレーション Selective catalytic reduction catalyst system
US11585253B2 (en) 2015-08-07 2023-02-21 Cummins Emission Solutions Inc. Converging liquid reductant injector nozzle in selective catalytic reduction systems
DE102017122696A1 (en) * 2017-09-29 2019-04-04 Eberspächer Exhaust Technology GmbH & Co. KG Method for producing an exhaust system and exhaust system

Citations (5)

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US5497617A (en) * 1993-07-02 1996-03-12 Corning Incorporated Gas-enriched light-off
DE19646643C1 (en) * 1996-11-12 1998-02-12 Daimler Benz Ag Jet discharge process for reducing nitrogen oxide in automotive engine exhausts
US5976475A (en) * 1997-04-02 1999-11-02 Clean Diesel Technologies, Inc. Reducing NOx emissions from an engine by temperature-controlled urea injection for selective catalytic reduction
DE102004010496A1 (en) * 2004-03-04 2005-09-22 Robert Bosch Gmbh Device for cleaning exhaust gases
EP1832345A1 (en) * 2006-03-10 2007-09-12 Asahi Kasei Kabushiki Kaisha Catalyst for exhaust gas purification

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US3163251A (en) * 1962-08-08 1964-12-29 John H Rees Combined frame and exhaust system for motor vehicle
US3826815A (en) 1972-06-21 1974-07-30 I Mavrovic Recovery of residual ammonia from weak aqueous solutions thereof
US4021372A (en) 1973-02-05 1977-05-03 Standard Oil Company (Indiana) Catalyst for reducing oxides of nitrogen in the exhaust gas from internal combustion engines and process for making the catalyst
DE2658892A1 (en) 1976-12-24 1978-07-06 Degussa DEVICE FOR CATALYTIC CLEANING OF EXHAUST GASES
DE2734010A1 (en) 1977-07-28 1979-02-15 Degussa EXHAUST GAS PURIFICATION DEVICE FOR A COMBUSTION ENGINE OF VEHICLES, IN PARTICULAR MOTOR VEHICLES
US4087513A (en) 1977-08-12 1978-05-02 Olin Corporation Method of hydrolyzing urea contained in waste water streams
US4285838A (en) 1977-12-08 1981-08-25 Babcock-Hitachi Kabushiki Kaisha Method of producing plate-shaped catalyst unit for NOx reduction of exhaust gas
US4168299A (en) 1978-03-20 1979-09-18 Olin Corporation Catalytic method for hydrolyzing urea
GB2073730A (en) * 1980-04-03 1981-10-21 Standard Telephones Cables Ltd Corrosion inhibiting paint formulation and pigments therefor
US4842834A (en) 1987-02-02 1989-06-27 Fuel Tech, Inc. Process for reducing the concentration of pollutants in an effluent
DE8900467U1 (en) 1989-01-17 1990-05-17 Emitec Gesellschaft für Emissionstechnologie mbH, 5204 Lohmar Metallic honeycomb body, preferably catalyst carrier body with microstructures for flow mixing
DE4038054A1 (en) 1990-11-29 1992-06-04 Man Technologie Gmbh METHOD AND DEVICE FOR SELECTIVE CATALYTIC NO (DOWN ARROW) X (DOWN ARROW) REDUCTION IN OXYGEN-BASED EXHAUST GASES
US5281403B1 (en) 1991-09-27 1996-06-11 Noell Inc Method for converting urea to ammonia
EP0555746B1 (en) 1992-02-10 1997-09-10 MAN Nutzfahrzeuge Aktiengesellschaft Device for catalytic NOx reduction
CA2088713C (en) 1992-02-24 1999-11-16 Hans Thomas Hug Cleaning exhaust gases from combustion installations
DE69811545T2 (en) 1997-03-13 2003-11-20 Haldor Topsoe A/S, Lyngby Process for the selective reduction of NOx in exhaust gas
US5968464A (en) 1997-05-12 1999-10-19 Clean Diesel Technologies, Inc. Urea pyrolysis chamber and process for reducing lean-burn engine NOx emissions by selective catalytic reduction
FR2772432B1 (en) * 1997-12-12 2000-02-18 Magneti Marelli France PETROL INJECTOR WITH ANTI-CALAMINE COATING, FOR DIRECT INJECTION
DE19902207A1 (en) 1999-01-21 2000-07-27 Man Nutzfahrzeuge Ag Process for metering a reducing agent, and device for carrying out the process
DE19913462A1 (en) 1999-03-25 2000-09-28 Man Nutzfahrzeuge Ag Urea hydrolysis to generate ammonia for reducing nitrogen oxides in an exhaust gas catalytic converter comprises reacting urea with a side stream of exhaust gas
DE10206028A1 (en) 2002-02-14 2003-08-28 Man Nutzfahrzeuge Ag Process and apparatus for producing ammonia
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EP2117702B1 (en) * 2007-02-27 2020-11-11 BASF Corporation Bifunctional catalysts for selective ammonia oxidation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5497617A (en) * 1993-07-02 1996-03-12 Corning Incorporated Gas-enriched light-off
DE19646643C1 (en) * 1996-11-12 1998-02-12 Daimler Benz Ag Jet discharge process for reducing nitrogen oxide in automotive engine exhausts
US5976475A (en) * 1997-04-02 1999-11-02 Clean Diesel Technologies, Inc. Reducing NOx emissions from an engine by temperature-controlled urea injection for selective catalytic reduction
DE102004010496A1 (en) * 2004-03-04 2005-09-22 Robert Bosch Gmbh Device for cleaning exhaust gases
EP1832345A1 (en) * 2006-03-10 2007-09-12 Asahi Kasei Kabushiki Kaisha Catalyst for exhaust gas purification

Also Published As

Publication number Publication date
WO2009108677A2 (en) 2009-09-03
US20090211232A1 (en) 2009-08-27
US8776499B2 (en) 2014-07-15

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