WO2009106704A3 - Method of producing middle distillates by sequenced hydroisomeration and hydrocracking of effluent produced by the fischer-tropsch process - Google Patents

Method of producing middle distillates by sequenced hydroisomeration and hydrocracking of effluent produced by the fischer-tropsch process Download PDF

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Publication number
WO2009106704A3
WO2009106704A3 PCT/FR2008/001744 FR2008001744W WO2009106704A3 WO 2009106704 A3 WO2009106704 A3 WO 2009106704A3 FR 2008001744 W FR2008001744 W FR 2008001744W WO 2009106704 A3 WO2009106704 A3 WO 2009106704A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrocracking
middle distillates
fischer
metal
hydroisomeration
Prior art date
Application number
PCT/FR2008/001744
Other languages
French (fr)
Other versions
WO2009106704A2 (en
Inventor
Christophe Bouchy
Emmanuelle Guillon
Johan Martens
Original Assignee
Ifp
Eni S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ifp, Eni S.P.A. filed Critical Ifp
Publication of WO2009106704A2 publication Critical patent/WO2009106704A2/en
Publication of WO2009106704A3 publication Critical patent/WO2009106704A3/en
Priority to ZA2010/04360A priority Critical patent/ZA201004360B/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J35/394—
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/14—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural parallel stages only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B01J35/615—
    • B01J35/635—
    • B01J35/66—
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products

Abstract

The invention describes a method of producing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis, comprising: separation of a heavy fraction having an initial boiling point between 120 and 200°C; hydroisomerization of at least part of said heavy fraction in the presence of a first hydroisomerization catalyst comprising at least one metal of group VIII and/or at least one metal of group VIB and at least one molecular sieve; hydrocracking of at least part of the hydroisomerized effluent in the presence of a second hydrocracking catalyst comprising at least one metal of group VIII and/or at least one metal of group VIB and a silica-alumina support or a zeolite Y-based support; and distillation of the final effluent in order to obtain middle distillates.
PCT/FR2008/001744 2008-01-04 2008-12-16 Method of producing middle distillates by sequenced hydroisomeration and hydrocracking of effluent produced by the fischer-tropsch process WO2009106704A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
ZA2010/04360A ZA201004360B (en) 2008-01-04 2010-06-21 Method of producing middle distillates by sequenced hydroisomerization and hydrocracking of effluent prodeced by the fischer-tropsch process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0800059A FR2926086B1 (en) 2008-01-04 2008-01-04 PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING SEQUENCES OF AN EFFLUENT PRODUCED BY THE FISCHER-TROPSCH PROCESS
FR0800059 2008-01-04

Publications (2)

Publication Number Publication Date
WO2009106704A2 WO2009106704A2 (en) 2009-09-03
WO2009106704A3 true WO2009106704A3 (en) 2010-01-14

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2008/001744 WO2009106704A2 (en) 2008-01-04 2008-12-16 Method of producing middle distillates by sequenced hydroisomeration and hydrocracking of effluent produced by the fischer-tropsch process

Country Status (3)

Country Link
FR (1) FR2926086B1 (en)
WO (1) WO2009106704A2 (en)
ZA (1) ZA201004360B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2926085B1 (en) * 2008-01-04 2010-02-12 Inst Francais Du Petrole PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF FISCHER-TROPSCH PROCESS
FR2926087B1 (en) * 2008-01-04 2010-02-12 Inst Francais Du Petrole MULTI-PROCESS PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF AN EFFLUENT PRODUCED BY THE FISCHER-TROPSCH PROCESS
CN102481555B (en) 2009-06-12 2015-10-07 阿尔比马尔欧洲有限公司 SAPO molecular sieve catalyst and preparation thereof and purposes
FR2950896B1 (en) * 2009-10-06 2013-01-04 Inst Francais Du Petrole PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF FISCHER-TROPSCH PROCESSES USING A CATALYST BASED ON SILICON CARBIDE
FR2951193B1 (en) * 2009-10-13 2011-12-09 Inst Francais Du Petrole HYDROCRACKING PROCESS USING MODIFIED ZEOLITHE
FR2951192B1 (en) 2009-10-13 2011-12-30 Inst Francais Du Petrole PROCESS FOR THE PRODUCTION OF MEDIUM DISTILLATE FROM FISCHER TROPSCH WAXES USING A MODIFIED ZEOLITHE CATALYST
CN106582708B (en) * 2015-10-20 2019-06-14 中国石油化工股份有限公司 A kind of method of loaded catalyst and application and Fischer-Tropsch synthesis
CN112742461A (en) * 2019-10-31 2021-05-04 中国石油化工股份有限公司 Catalyst carrier, preparation method thereof and hydrogenation catalyst

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0297949A1 (en) * 1987-07-01 1989-01-04 Institut Français du Pétrole Catalyst comprising a mineral support, phosphoras and boron, preparation method and use thereof for hydrotreatment of hydrocarbon fraction
US6261441B1 (en) * 1998-09-24 2001-07-17 Mobil Oil Corporation Integrated hydroprocessing scheme with segregated recycle
FR2826971A1 (en) * 2001-07-06 2003-01-10 Inst Francais Du Petrole PROCESS FOR PRODUCING MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF LOADS FROM THE FISCHER-TROPSCH PROCESS
US20040256286A1 (en) * 2003-06-19 2004-12-23 Miller Stephen J. Fuels and lubricants using layered bed catalysts in hydrotreating waxy feeds, including Fischer-Tropsch wax
WO2009103881A2 (en) * 2008-01-04 2009-08-27 Ifp Multistep process for producing middle distillates by hydroisomerization and hydrocracking of an effluent produced by the fischer-tropsch process
WO2009106705A2 (en) * 2008-01-04 2009-09-03 Ifp Method of producing middle distillates by hydroisomerization and hydro­cracking of feedstocks coming from the fischer-tropsch process

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0297949A1 (en) * 1987-07-01 1989-01-04 Institut Français du Pétrole Catalyst comprising a mineral support, phosphoras and boron, preparation method and use thereof for hydrotreatment of hydrocarbon fraction
US6261441B1 (en) * 1998-09-24 2001-07-17 Mobil Oil Corporation Integrated hydroprocessing scheme with segregated recycle
FR2826971A1 (en) * 2001-07-06 2003-01-10 Inst Francais Du Petrole PROCESS FOR PRODUCING MEDIUM DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF LOADS FROM THE FISCHER-TROPSCH PROCESS
US20040256286A1 (en) * 2003-06-19 2004-12-23 Miller Stephen J. Fuels and lubricants using layered bed catalysts in hydrotreating waxy feeds, including Fischer-Tropsch wax
WO2009103881A2 (en) * 2008-01-04 2009-08-27 Ifp Multistep process for producing middle distillates by hydroisomerization and hydrocracking of an effluent produced by the fischer-tropsch process
WO2009106705A2 (en) * 2008-01-04 2009-09-03 Ifp Method of producing middle distillates by hydroisomerization and hydro­cracking of feedstocks coming from the fischer-tropsch process

Also Published As

Publication number Publication date
FR2926086A1 (en) 2009-07-10
WO2009106704A2 (en) 2009-09-03
ZA201004360B (en) 2011-03-30
FR2926086B1 (en) 2010-02-12

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