WO2009101281A3 - Novel system for optimising the production of high octane gasoline and the coproduction of aromatic bases - Google Patents

Novel system for optimising the production of high octane gasoline and the coproduction of aromatic bases Download PDF

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Publication number
WO2009101281A3
WO2009101281A3 PCT/FR2008/001676 FR2008001676W WO2009101281A3 WO 2009101281 A3 WO2009101281 A3 WO 2009101281A3 FR 2008001676 W FR2008001676 W FR 2008001676W WO 2009101281 A3 WO2009101281 A3 WO 2009101281A3
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WO
WIPO (PCT)
Prior art keywords
production
high octane
aromatic
coproduction
optimising
Prior art date
Application number
PCT/FR2008/001676
Other languages
French (fr)
Other versions
WO2009101281A2 (en
Inventor
Souhir Mathieu
Jacques Rault
Original Assignee
Ifp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ifp filed Critical Ifp
Priority to CN200880120898.9A priority Critical patent/CN102037102B/en
Priority to BRPI0822083-2A priority patent/BRPI0822083B1/en
Publication of WO2009101281A2 publication Critical patent/WO2009101281A2/en
Publication of WO2009101281A3 publication Critical patent/WO2009101281A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G61/00—Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen
    • C10G61/02—Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen plural serial stages only
    • C10G61/04—Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen plural serial stages only the refining step being an extraction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G5/00—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G7/00—Distillation of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
    • C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/305—Octane number, e.g. motor octane number [MON], research octane number [RON]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention relates to a concatenation of at least three units: an aromatic separation unit (SEP), a catalytic reforming unit (RC) and a so-called complex aromatic unit (CA) for simultaneously obtaining gasoline having a high octane index and aromatic bases, essentially xylenes, benzene and toluene, wherein the distribution between the production of high octane index gasoline and the production of aromatic bases may vary in any manner.
PCT/FR2008/001676 2007-12-17 2008-12-01 Novel system for optimising the production of high octane gasoline and the coproduction of aromatic bases WO2009101281A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN200880120898.9A CN102037102B (en) 2007-12-17 2008-12-01 Novel system for optimising the production of high octane gasoline and the coproduction of aromatic bases
BRPI0822083-2A BRPI0822083B1 (en) 2007-12-17 2008-12-01 ??? GASOLINE PRODUCTION PROCESS WITH OCTANE INDEX UP TO 95 AND COPRODUCTION OF AROMATIC BASES ??

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR07/08853 2007-12-17
FR0708853A FR2925065B1 (en) 2007-12-17 2007-12-17 NEW DIAGRAM FOR OPTIMIZING HIGH OCTANE INDEX PRODUCTION AND COPRODUCTION OF AROMATIC BASES

Publications (2)

Publication Number Publication Date
WO2009101281A2 WO2009101281A2 (en) 2009-08-20
WO2009101281A3 true WO2009101281A3 (en) 2010-07-29

Family

ID=39675254

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2008/001676 WO2009101281A2 (en) 2007-12-17 2008-12-01 Novel system for optimising the production of high octane gasoline and the coproduction of aromatic bases

Country Status (5)

Country Link
KR (1) KR101572702B1 (en)
CN (1) CN102037102B (en)
BR (1) BRPI0822083B1 (en)
FR (1) FR2925065B1 (en)
WO (1) WO2009101281A2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101724427B (en) * 2009-12-24 2013-02-13 中国寰球工程公司 Rectification system for separating mixture rich in aromatic hydrocarbon
WO2011156182A2 (en) * 2010-06-11 2011-12-15 Uop Llc Process and apparatus for the reduction of gasoline benzene content by alkylation with dilute ethylene
NO2737022T3 (en) * 2011-07-29 2018-03-03
FR2984914A1 (en) * 2011-12-27 2013-06-28 Total Raffinage Marketing PROCESS FOR MAXIMIZING AROMATIC PRODUCTION
EP2844722B1 (en) 2012-05-02 2021-01-20 Saudi Arabian Oil Company Apparatus and process for maximizing aromatics production from hydrocracked naphtha
FR3014895B1 (en) * 2013-12-17 2017-02-10 Ifp Energies Now CATALYTIC REFORMING PROCESS
FR3014894B1 (en) * 2013-12-17 2017-02-10 Ifp Energies Now CATALYTIC REFORMING PROCESS
US9434894B2 (en) 2014-06-19 2016-09-06 Uop Llc Process for converting FCC naphtha into aromatics
KR102429723B1 (en) * 2014-07-07 2022-08-04 알베마를 유럽 에스피알엘 Alkylation process using a catalyst comprising cerium rich rare earth containing zeolites and a hydrogenation metal
US10633596B2 (en) * 2016-06-17 2020-04-28 Basf Corporation FCC catalyst having alumina derived from crystalline boehmite
US10093873B2 (en) 2016-09-06 2018-10-09 Saudi Arabian Oil Company Process to recover gasoline and diesel from aromatic complex bottoms
US11066344B2 (en) 2017-02-16 2021-07-20 Saudi Arabian Oil Company Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock
WO2018158377A1 (en) * 2017-03-01 2018-09-07 Albemarle Europe Sprl Alkylation process with improved octane number
FR3068967B1 (en) * 2017-07-13 2019-06-28 IFP Energies Nouvelles METHOD AND METHOD FOR CONVERTING ETHYLENE PRESENT IN THE HEAD EFFLUENT OF AN FCC TO INCREASE PROPYLENE PRODUCTION
FR3074176B1 (en) 2017-11-29 2020-06-26 IFP Energies Nouvelles PROCESS FOR THE PRODUCTION OF AROMATICS WITH EXTRACTION BEFORE AROMATISATION
FR3121446B1 (en) 2021-03-30 2024-05-03 Ifp Energies Now Valorization of aromatics from catalytic cracked gasolines to the aromatic complex
US11591526B1 (en) 2022-01-31 2023-02-28 Saudi Arabian Oil Company Methods of operating fluid catalytic cracking processes to increase coke production

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2740751A (en) * 1952-02-23 1956-04-03 Universal Oil Prod Co Reforming of both straight run and cracked gasolines to provide high octane fuels
US2768126A (en) * 1952-02-23 1956-10-23 Universal Oil Prod Co Multiple stage reforming process
US2908628A (en) * 1956-06-28 1959-10-13 Sun Oil Co Hydrocarbon conversion
US2915453A (en) * 1955-05-26 1959-12-01 Universal Oil Prod Co Hydrocarbon conversion process with subsequent reforming of selected hydrocarbon fractions
US2933445A (en) * 1955-04-08 1960-04-19 Sun Oil Co Catalytic reforming process employing a blend of selected hydrocarbon fractions
US3001928A (en) * 1959-08-07 1961-09-26 Universal Oil Prod Co Reforming process
GB2163177A (en) * 1984-08-17 1986-02-19 Chevron Res Method of catalytically producing high aromatic content products
WO1994002438A1 (en) * 1992-07-24 1994-02-03 Chevron Chemical Company Reforming process for producing high-purity benzene
US5858209A (en) * 1994-08-15 1999-01-12 Uop Catalytic reforming process with increased aromatics yield
EP1010745A1 (en) * 1998-12-18 2000-06-21 Chevron Chemical Company LLC Dehydrocyclization process with downstream dimethylbutane removal

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1285707C (en) * 2005-07-07 2006-11-22 华东理工大学 Naphtha optimized utilization method
JP2007084768A (en) 2005-09-26 2007-04-05 Idemitsu Kosan Co Ltd Method for treating naphtha-reformed oil and apparatus usable therefor
JP4812437B2 (en) 2006-01-19 2011-11-09 石油コンビナート高度統合運営技術研究組合 Process for producing benzene and gasoline base from petrochemical raffinate
JP4812439B2 (en) 2006-01-19 2011-11-09 石油コンビナート高度統合運営技術研究組合 Process for producing benzene and gasoline base from petrochemical raffinate
JP4812438B2 (en) 2006-01-19 2011-11-09 石油コンビナート高度統合運営技術研究組合 Process for producing benzene and gasoline base from petrochemical raffinate

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2740751A (en) * 1952-02-23 1956-04-03 Universal Oil Prod Co Reforming of both straight run and cracked gasolines to provide high octane fuels
US2768126A (en) * 1952-02-23 1956-10-23 Universal Oil Prod Co Multiple stage reforming process
US2933445A (en) * 1955-04-08 1960-04-19 Sun Oil Co Catalytic reforming process employing a blend of selected hydrocarbon fractions
US2915453A (en) * 1955-05-26 1959-12-01 Universal Oil Prod Co Hydrocarbon conversion process with subsequent reforming of selected hydrocarbon fractions
US2908628A (en) * 1956-06-28 1959-10-13 Sun Oil Co Hydrocarbon conversion
US3001928A (en) * 1959-08-07 1961-09-26 Universal Oil Prod Co Reforming process
GB2163177A (en) * 1984-08-17 1986-02-19 Chevron Res Method of catalytically producing high aromatic content products
WO1994002438A1 (en) * 1992-07-24 1994-02-03 Chevron Chemical Company Reforming process for producing high-purity benzene
US5858209A (en) * 1994-08-15 1999-01-12 Uop Catalytic reforming process with increased aromatics yield
EP1010745A1 (en) * 1998-12-18 2000-06-21 Chevron Chemical Company LLC Dehydrocyclization process with downstream dimethylbutane removal

Also Published As

Publication number Publication date
KR20100093601A (en) 2010-08-25
FR2925065A1 (en) 2009-06-19
FR2925065B1 (en) 2012-11-30
BRPI0822083B1 (en) 2017-11-21
KR101572702B1 (en) 2015-11-27
WO2009101281A2 (en) 2009-08-20
BRPI0822083A2 (en) 2015-12-15
CN102037102A (en) 2011-04-27
CN102037102B (en) 2014-07-09

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