WO2009101127A2 - Method and apparatus for cooling a hydrocarbon stream - Google Patents

Method and apparatus for cooling a hydrocarbon stream Download PDF

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Publication number
WO2009101127A2
WO2009101127A2 PCT/EP2009/051621 EP2009051621W WO2009101127A2 WO 2009101127 A2 WO2009101127 A2 WO 2009101127A2 EP 2009051621 W EP2009051621 W EP 2009051621W WO 2009101127 A2 WO2009101127 A2 WO 2009101127A2
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WO
WIPO (PCT)
Prior art keywords
stream
cooled
overhead
hydrocarbon
overhead stream
Prior art date
Application number
PCT/EP2009/051621
Other languages
French (fr)
Other versions
WO2009101127A3 (en
Inventor
Marco Dick Jager
Wouter Jan Meiring
Original Assignee
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij B.V. filed Critical Shell Internationale Research Maatschappij B.V.
Priority to JP2010546326A priority Critical patent/JP5683277B2/en
Priority to EP09710397A priority patent/EP2245403A2/en
Priority to US12/866,049 priority patent/US10539363B2/en
Publication of WO2009101127A2 publication Critical patent/WO2009101127A2/en
Publication of WO2009101127A3 publication Critical patent/WO2009101127A3/en

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0229—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
    • F25J1/0231—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock for the working-up of the hydrocarbon feed, e.g. reinjection of heavier hydrocarbons into the liquefied gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
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    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
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    • F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
    • F25J1/0215—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle
    • F25J1/0216—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle using a C3 pre-cooling cycle
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    • F25J1/0235—Heat exchange integration
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    • F25J1/0239—Purification or treatment step being integrated between two refrigeration cycles of a refrigeration cascade, i.e. first cycle providing feed gas cooling and second cycle providing overhead gas cooling
    • F25J1/0241—Purification or treatment step being integrated between two refrigeration cycles of a refrigeration cascade, i.e. first cycle providing feed gas cooling and second cycle providing overhead gas cooling wherein the overhead cooling comprises providing reflux for a fractionation step
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    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/74—Refluxing the column with at least a part of the partially condensed overhead gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/06—Splitting of the feed stream, e.g. for treating or cooling in different ways
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/02—Mixing or blending of fluids to yield a certain product
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/62—Ethane or ethylene
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/64—Propane or propylene
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/66—Butane or mixed butanes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00—Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/62—Separating low boiling components, e.g. He, H2, N2, Air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00—Processes or apparatus involving steps for expanding of process streams
    • F25J2240/30—Dynamic liquid or hydraulic expansion with extraction of work, e.g. single phase or two-phase turbine
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2245/00—Processes or apparatus involving steps for recycling of process streams
    • F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/12—External refrigeration with liquid vaporising loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/60—Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons

Definitions

  • the present invention relates to a method and apparatus for cooling a hydrocarbon stream, and to a liquefied natural gas plant or facility including such apparatus .
  • a common hydrocarbon stream to be cooled, optionally to full liquefaction, is natural gas.
  • Natural gas is a useful fuel source, as well as being a source of various hydrocarbon compounds. It is often desirable to liquefy natural gas in a liquefied natural gas (LNG) plant at or near the source of a natural gas stream for a number of reasons. For example, natural gas can be stored and transported over long distances more readily as a liquid than in gaseous form, because it occupies a smaller volume and does not need to be stored at high pressure.
  • LNG liquefied natural gas
  • natural gas comprising predominantly methane
  • the purified gas is processed through a plurality of cooling stages using heat exchangers to progressively reduce its temperature until liquefaction is achieved.
  • the liquid natural gas is then further cooled and expanded to final atmospheric pressure suitable for storage and transportation.
  • natural gas usually includes some heavier hydrocarbons and non-hydrocarbons, including but not limited to carbon dioxide, mercury, sulphur, hydrogen sulphide and other sulphur compounds, nitrogen, helium, water and other non-hydrocarbon acid gases, ethane, propane, butanes, C 5 + hydrocarbons and aromatic hydrocarbons.
  • hydrocarbons and non-hydrocarbons including but not limited to carbon dioxide, mercury, sulphur, hydrogen sulphide and other sulphur compounds, nitrogen, helium, water and other non-hydrocarbon acid gases, ethane, propane, butanes, C 5 + hydrocarbons and aromatic hydrocarbons.
  • NGL natural gas liquids
  • NGL recovery conventionally involves cooling, condensation and fractionation steps that require significant amounts of refrigeration and other power consumption. It is desirable to recover NGLs from a natural gas stream with the most efficient or minimal power consumption .
  • EP 1 469 266 Al describes a process for the recovery of components heavier than methane from natural gas, including withdrawing from an absorber column a bottom stream enriched in components heavier than methane, and separating this into a stream containing methane and ethane, and one or more streams enriched in components heavier than ethane.
  • a problem with EP 1 469 266 Al is that its methane and ethane stream is liquefied in its main heat exchanger. This requires an extra bundle of cooling pipes in the main heat exchanger to accommodate the extra stream, and takes away cooling duty of the main heat exchanger from the main methane stream being liquefied.
  • the present invention provides a method of cooling a hydrocarbon stream comprising at least the steps of: (a) passing an initial hydrocarbon stream through a first separator to provide an initial overhead stream and a mixed hydrocarbon feed stream;
  • the present invention also provides an apparatus for cooling a hydrocarbon stream comprising at least: a first separator through which an initial hydrocarbon stream passes to provide an initial overhead stream and a mixed hydrocarbon feed stream; a cooling system to cool, preferably liquefy, the initial overhead stream to provide a cooled, preferably liquefied, hydrocarbon stream such as LNG; an NGL recovery system to separate at least a Cl overhead stream and one or more C2, C3 and C4 overhead streams from the mixed hydrocarbon feed stream; a combiner to cool at least a fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; by admixing with the Cl overhead stream, to provide a cooled stream; and one or more heat exchangers for further cooling the cooled stream against at least a fraction of the cooled, preferably liquefied, hydrocarbon stream to provide an at least partly liquefied cooled stream; wherein there are no expansion or compression devices between the Cl overhead stream and the at least partly liquefied cooled
  • the present invention also provides a liquefied natural gas plant or facility including an apparatus as hereindefined .
  • Figure 1 is a first diagrammatic scheme for a method of cooling according to one embodiment of the present invention
  • Figure 2 shows a third diagrammatic scheme for a method of cooling according to another embodiment
  • Figure 3 is a second diagrammatic scheme for a method of cooling according to a second group of embodiments .
  • a single reference number will be assigned to a line as well as a stream carried in that line.
  • the present disclosure shows cooling of one or more streams separated from a related mixed hydrocarbon feed stream as part of a multi-column natural gas liquids (NGL) recovery system and arrangement.
  • NNL natural gas liquids
  • Embodiments described herein provide a highly efficient configuration for the production of an at least partly, preferably fully, liquefied cooled stream from one or more streams separated from an NGL recovery system.
  • the apparatus comprise at least: a first separator through which an initial hydrocarbon stream passes to provide an initial overhead stream and a mixed hydrocarbon feed stream; a cooling system to cool, preferably liquefy, the initial overhead stream to provide a cooled, preferably liquefied, hydrocarbon stream such as LNG; an NGL recovery system to separate at least a Cl overhead stream and one or more C2, C3 and C4 overhead streams from the mixed hydrocarbon feed stream; means to cool at least a fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; with the Cl overhead stream, to provide a cooled stream; and one or more heat exchangers for further cooling the cooled stream against at least a fraction of the cooled, preferably liquefied, hydrocarbon stream to provide an at least partly liquefied cooled stream.
  • a first separator through which an initial hydrocarbon stream passes to provide an initial overhead stream and a mixed hydrocarbon feed stream
  • a cooling system to cool, preferably liquefy, the
  • the cooling of the at least the fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; with the Cl overhead stream is achieved by admixing.
  • the apparatus could comprise a combiner to admix the at least the fraction with the Cl overhead stream.
  • the term "substantially the same” means that the difference between the pressure of the Cl overhead stream, provided at the first pressure, and the at least partly liquefied cooled stream, provided at the second pressure, is less than a de minimis, indeliberate, pressure loss resulting from the flow through piping and heat exchanger (s) .
  • the proposed group of embodiments takes as much as possible advantage of the pressure that was already available in the Cl overhead stream. And advantageously, no expansion or compression devices need to be provided between the Cl overhead stream and the at least partly liquefied cooled stream.
  • the cooling of the at least the fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; is achieved by indirect heat exchange with the Cl overhead stream. Since admixing is avoided, this allows for a dedicated use of the relatively pure Cl overhead stream. No substantial pressure reduction or increase needs be imposed before the indirect heat exchanging.
  • the present invention may be applied to provide first cooling of a stream from NGL recovery by a Cl overhead stream, and subsequent further cooling, preferably fully liquefying, by a fraction of the main cooled, preferably liquefied, hydrocarbon stream, such as end-flash gas.
  • a fraction of the main cooled, preferably liquefied, hydrocarbon stream such as end-flash gas.
  • step (b) of the method of the present invention avoids taking away cooling duty in step (b) of the method of the present invention, which would diminish cooling of the main hydrocarbon stream.
  • cold energy for the cooling of the main hydrocarbon stream (by a separate refrigerant, refrigeration system and/or circuit) need not be diverted to be involved in NGL recovery, increasing the efficiency of other processes or sections of a liquefaction plant such as an LNG plant.
  • Embodiments of the present invention provide flexibility for using the cooling of a Cl overhead stream from the NGL recovery to cool at least a fraction of any one of, or any combination of, C2, C3 and C4 overhead streams .
  • the need for an extra bundle of cooling pipes in a main heat exchanger to accommodate an NGL recovery stream may herewith be avoided, thereby avoiding the additional CAPEX and OPEX required in EP 1 469 266 Al for its integrated main heat exchanger.
  • the initial hydrocarbon stream may be any suitable hydrocarbon stream such as, but not limited to, a hydrocarbon-containing gas stream able to be cooled.
  • a natural gas stream obtained from a natural gas or petroleum reservoir.
  • the natural gas stream may also be obtained from another source, also including a synthetic source such as a Fischer-Tropsch process .
  • Such an initial hydrocarbon stream is comprised substantially of methane.
  • such an initial feed stream comprises at least 60 mol% methane, more preferably at least 80 mol% methane.
  • the Cl, C2, C3 and C4 overhead streams may be provided by any known NGL recovery system.
  • An NGL recovery system usually involves one or more distillation columns.
  • the first, and any of second, third or fourth distillation columns useable in the present invention may be any form of separator adapted to provide at least one overhead stream, usually a gaseous overhead stream, and usually being enriched in one or more lighter hydrocarbons, and at least one bottom stream, usually a liquid stream, and usually being enriched in one or more heavier hydrocarbons.
  • an overhead stream and/or a bottom stream may be a mixed phase stream.
  • An example of a suitable first distillation column is a "demethanizer” designed to provide a methane- enriched overhead stream, and one or more liquid streams at or near the bottom enriched in C2+ hydrocarbons.
  • a second distillation column may be a "deethanizer”
  • a third distillation column may be a “depropanizer”
  • a fourth distillation column may be a "debutanizer” .
  • Such columns are known in the art.
  • the first bottom stream of the present invention can hereinafter be defined as a C2+ hydrocarbon stream.
  • the second bottom liquid stream may be defined as a C3+ hydrocarbon stream, and the second overhead gaseous stream is preferably >60 mol% ethane, more preferably >85 mol% and even more preferably >90 mol% ethane.
  • Each distillation column of the present invention may involve one or more columns, and one or each of such columns could provide individual liquid streams of certain heavier hydrocarbons such as ethane, propane, etc. Commonly, NGL recovery results in a C5+ hydrocarbon stream.
  • mixed hydrocarbon feed stream relates to a feed stream comprising methane (Cl) and at least 5 mol% of one or more hydrocarbons selected from the group comprising: ethane (C2), propane (C3), butanes (C4), and C5+ hydrocarbons.
  • C5+ hydrocarbon stream relates to a stream comprising "pentanes” and heavier hydrocarbons, often also termed 'light condensates'.
  • C2+ refers to a stream comprising ethane and heavier hydrocarbons, propane and heavier hydrocarbons, et al . Any C2, C3, and C4 stream may still comprise a minor
  • each such stream is preferably >80 mol%, more preferably >95 mol%, of its main component, ethane, propane and the butanes, respectively .
  • the division of a stream such as a feed stream or an overhead stream into two or more part streams may be carried out using any suitable stream splitter or divider, which may be a distinct unit, or a simpler division of a line such as a T-piece.
  • Figure 1 shows a simplified and first general scheme of a liquefied natural gas plant 2 for a method for cooling an initial hydrocarbon stream 8 which separated into a mixed hydrocarbon feed stream 10 and a methane- enriched stream 110, which methane-enriched stream 110 is subsequently cooled, preferably liquefied, to provide a cooled, preferably liquefied, hydrocarbon stream 120, preferably LNG.
  • Figure 1 also shows an NGL recovery system 1 wherein the mixed hydrocarbon feed stream 10 is separated into a Cl stream (20) and one or more C2, C3 and C4 streams (40, 50, 60, respectively) .
  • the initial feed stream 7 may contain natural gas. It is cooled by a pre-cooling heat exchanger 14 to provide a cooled and partly condensed initial hydrocarbon stream 8.
  • the pre-cooling heat exchanger 14 may comprise one or more heat exchangers either in parallel, series or both, in a manner known in the art. Cooling in the pre- cooling heat exchanger 14 is provided by a first refrigerant stream 100, which is warmed in the pre- cooling heat exchanger 14 to provide a warmed first refrigerant stream 100a.
  • the cooling of the initial feed stream 7 may be part of a liquefaction process, such as a pre-cooling stage involving a propane refrigerant circuit as described hereinafter in relation to Figure 2, or a separate process .
  • Cooling of the initial feed stream 7 may involve reducing the temperature of the initial feed stream 7 to below -0 0 C, for example, in the range -10 0 C to -70 0 C.
  • the cooled initial hydrocarbon stream 8 is passed into a first separator 16 such as a scrub column 16, operating at an above ambient pressure in a manner known in the art.
  • the scrub column 16 provides a condensed mixed hydrocarbon feed stream 10, preferably having a temperature below -0 0 C, and an initial overhead steam, in the present specification also referred to as the methane-enriched stream 110.
  • the initial gaseous overhead stream 110 is usually greater than 80 mol% methane, and is an enriched-methane stream compared to the cooled initial hydrocarbon stream 8.
  • the mixed hydrocarbon feed stream 10 comprises methane and one or more of C2, C3, C4 and C5+ hydrocarbons.
  • the proportion of methane in the mixed hydrocarbon feed stream 10 is 30-50 mol%, with a significant fraction of ethane and propane, such as 5-10 mol% each.
  • NGL recovery it is desired to recover any methane in a mixed hydrocarbon stream (for use as a fuel or to be liquefied in the LNG plant 2 and provided as additional LNG) , and to provide one or more of a C2 stream, a C3 stream, a C4 stream, and a C5+ stream.
  • the mixed hydrocarbon feed stream 10 passes into the NGL recovery system 1, through a valve 18 to provide a reduced pressure mixed hydrocarbon feed stream 10a, and then enters a first distillation column 12 at or near the top thereof.
  • the reduced pressure mixed hydrocarbon feed stream 10a is typically a mixed phased stream, and the first distillation column 12 is adapted to separate the gaseous and vapour phases, so as to provide a Cl overhead stream 20 and a first bottom stream 30.
  • the nature of the streams provided by the first distillation column 12 can be varied according to the size and type of distillation column, and its operating conditions and parameters, in a manner known in the art.
  • the Cl overhead stream 20 it is desired for the Cl overhead stream 20 to be methane-enriched, preferably to be >90 mol% methane.
  • the first distillation column 12 also includes a first reboiler 13 and a first reboiler vapour return stream 13a in a manner known in the art.
  • the first bottom stream 30 is predominantly a C2+ hydrocarbon stream, such as >90 or >95 mol% ethane and heavier hydrocarbons.
  • the first bottom stream 30 is cooled by one or more ambient coolers, such as a water and/or air cooler 21, to provide a cooled first bottom stream 31, followed by a passage through a valve 19 and entry into a second distillation column 22.
  • the type, size and capacity of the second distillation column 22, as well as its operating conditions and parameters, will control the nature of the streams provided by the second distillation column 22.
  • the second distillation column 22 provides a C2 overhead stream 40 being predominantly ethane, preferably >85 mol% or >90 mol% ethane, and a second bottom stream 47, generally being a C3+ stream comprising >98 mol% propane and heavier hydrocarbons.
  • the second distillation column 22 also includes a second reboiler 23 and a second reboiler vapour return stream 23a.
  • a fraction of the mixed hydrocarbon feed stream 10 is provided as a side stream 10b.
  • the side stream 10b can pass through a valve 24 to provide a reduced pressure stream 25, which has a temperature that is low enough, such as between 0 0 C and -50 0 C, to provide cooling in a first heat exchanger 26 to the C2 overhead stream 40.
  • the first heat exchanger 26 may be one or more heat exchangers in parallel, series or both.
  • the cold energy of the reduced pressure stream 25 withdraws warmth from the C2 overhead stream 40 to at least partially condense, preferably fully condense, the C2 overhead stream 40 in the heat exchanger 26, and provide an at least partly condensed C2 stream 40a.
  • the at least partly condensed C2 stream 40a can be divided by a separator 27 to provide a separator bottom stream 41, which could pass into a pump 28 and be divided into a C2 reflux stream 43 for return to the second distillation column 22, and a C2 product stream 44.
  • the C2 product stream 44 itself can then be divided by a divider 29 into a first C2 fraction 46 for use outside a liquefaction plant, or as a refrigerant or as a component of a refrigerant in a liquefaction plant, such as in a mixed refrigerant known in the art, and a second C2 fraction 45 for use with the present invention as discussed hereinafter.
  • the percentage ratio of the division of the separator bottom stream 41 and/or the C2 product stream 44 as discussed above may be any suitable ratio between 0-100%. Factors influencing the ratio include the operating conditions and parameters of the second distillation column 22, the external or internal requirement for C2 for use as a refrigerant, or to replenish or supplement a refrigerant, etc.
  • the heat exchange of the C2 overhead stream 40 and the reduced pressure stream 25 also provides a warmer reduced pressure stream 10c, which can be passed into the first distillation column 12.
  • the second bottom stream 47 is predominately a C3+ hydrocarbon stream, such as >90 or >95 mol% of propane and heavier hydrocarbons.
  • the second bottom stream 47 passes through a valve 31 to provide a reduced pressure second bottom stream 48, which passes into a third distillation column 32.
  • the type, size and capacity of the third distillation column 32, as well as its operating conditions and parameters, will control the nature of the streams provided by the third distillation column 32.
  • the third distillation column 32 provides a C3 overhead stream 50 being predominately propane, preferably being >85 mol% or >90 mol% propane, and a third bottom stream 57, generally being a C4+ stream comprising >90 mol% butanes and heavier hydrocarbon.
  • the third distillation column 32 also includes a third reboiler 33 and third reboiler vapour return stream 33a.
  • the C3 overhead stream 50 passes through one or more ambient coolers, such as a water and/or air cooler 34, to provide a cooled C3 overhead stream 51, which is divided by a separator 35 to provide a separator bottom stream 52 which passes into a pump 36 and is divided into a C3 reflux stream 53 for return to the third distillation column 32, and a C3 product stream 54.
  • ambient coolers such as a water and/or air cooler 34
  • the C3 product stream 54 itself can then be divided by a divider 59 into a first C3 fraction 56 for use outside a liquefaction plant, or as a refrigerant or as a component of a refrigerant in a liquefaction plant, such as in a mixed refrigerant known in the art, and a second C3 fraction 55 for use with the present invention as discussed hereinafter .
  • the percentage ratio of the division of the separator bottom stream 52 and/or the C3 product stream 54 as discussed above may be any suitable ratio between 0-100%. Factors influencing the ratio include the operating conditions and parameters of the second distillation column 32, the external or internal requirement for C3 for use as a refrigerant, or to replenish or supplement a refrigerant, etc.
  • the third bottom stream 57 passes through a valve 38 to provide a reduced pressure third bottom stream 58, which passes into a fourth distillation column 42.
  • the type, size and capacity of the fourth distillation column 42, as well as its operating conditions and parameters, will control the nature of the streams provided by the fourth distillation column 42.
  • the fourth distillation column 42 provides a C4 overhead stream 60 being predominately butane and/or i-butane, preferably >85 or >90 mol% butane (s), and a C5+ bottom stream 67.
  • the C5 bottom stream 67 may pass through one or more ambient coolers such as a water and/or air cooler 91 to provide a C5+ product stream 68 in a manner known in the art.
  • the fourth distillation column 42 also includes a fourth reboiler 92 and a fourth reboiler vapour return stream 92a.
  • the C4 overhead stream 60 may pass through one or more ambient coolers such as a water and/or air cooler 93 to provide a cooled C4 overhead stream 61, which passes into a separator 94 to provide a separator bottom stream 62, which could pass into a pump 95 and be divided into a C4 reflux stream 63 for return to the fourth distillation column 42, and C4 a product stream 64.
  • ambient coolers such as a water and/or air cooler 93 to provide a cooled C4 overhead stream 61, which passes into a separator 94 to provide a separator bottom stream 62, which could pass into a pump 95 and be divided into a C4 reflux stream 63 for return to the fourth distillation column 42, and C4 a product stream 64.
  • the C4 product stream 64 itself can then be divided by a divider 96 into a first C4 fraction 66 for use outside a liquefaction plant, or as a refrigerant or as a component of a refrigerant in a liquefaction plant, such as in a mixed refrigerant known in the art, and a second C4 fraction 65 for use with the present invention.
  • the percentage ratio of the division of the separator bottom stream 62 and/or the C4 product stream 64 as discussed above may be any suitable ratio between 0-100%. Factors influencing the ratio include the operating conditions and parameters of the fourth distillation column 32, the external or internal requirement for C4 for use as a refrigerant, or to replenish or supplement a refrigerant, etc.
  • the second C4 fraction 65 is combined by a combiner 97 with the second C3 fraction 55 to provide a combined C3 and C4 product stream 81.
  • the Cl overhead stream 20 is combined by a combiner 82 with the second C2 fraction 45 to provide a combined Cl and C2 stream 84, which is then also combined with the combined C3 and C4 stream 81 by a combiner 86 to provide a cooled stream 70.
  • Cl overhead stream 20 has a temperature below 0 0 C, such as in the range -10 0 C to -100 0 C, more usually in the range -30 0 C to -70 0 C.
  • the second C2 fraction 45 typically has a temperature below 10 0 C, such as between 10 0 C and -20 0 C, more usually in the range 5 0 C to -10 0 C.
  • the second C3 fraction 55 and the second C4 fraction 65 typically have a temperature above O 0 C, usually in the range O 0 C to 60 0 C.
  • the Cl overhead stream 20 with at least a fraction of a least of one of the group comprising; the C2 overhead stream 40, the C3 overhead stream 50 and the C4 overhead stream 60; said at least fraction (s) are cooled by the Cl overhead stream 20 because the Cl overhead stream 20 is the coolest of said streams and fractions.
  • the piping combining the Cl overhead stream 20 with at least said fraction (s) provide the means to cool said fraction (s).
  • Figure 1 shows an arrangement where second fractions 45, 55, 65 of each of the C2 overhead stream 40, the C3 overhead stream 50 and the C4 overhead stream 60, are cooled by the Cl overhead stream 20, by being combined therewith, and therefore being in admixture therewith. In this way, the Cl overhead stream 20 provides direct cooling to the second fractions 45, 55, 65.
  • the combination or admixture of the Cl overhead stream 20, the second C2 fraction 45 and the combined C3 and C4 stream 81 provide a cooled stream 70 as a single stream.
  • the cooled stream 70 has a temperature below O 0 C.
  • the cooled stream 70 may be a mixed phase stream, i.e. partly liquid.
  • Figure 1 also shows the initial overhead stream 110 from the scrub column 16 passing into a main heat exchanger 112 to provide a further cooled and at least partially condensed, preferably fully condensed or liquefied, hydrocarbon stream 120. Cooling in the main heat exchanger 112 is provided by a second refrigerant stream 114, which is warmed in the main heat exchanger 112 to provide a warmed second refrigerant stream 114a.
  • the cooled, preferably liquefied, hydrocarbon stream 120 passes through a valve 116 and into an end gas/liquid separator such as an end-flash vessel 118.
  • the action of an end-flash vessel 118 is known in the art, and it provides an overhead stream, which may be termed end- flash gas 130, and a liquefied product stream 140, which is preferably LNG.
  • the cooled stream 70 can then be further cooled, preferably sub- cooled, by passing it through a second heat exchanger 122. This provides an at least partly liquefied cooled
  • the at least partly liquefied cooled stream 71 is combined with the cooled hydrocarbon stream 120, either upstream of the end flash vessel 118 (e.g. using any type of junction or combiner known in the art) or directly in the end-flash vessel 118 as shown in Fig. 1.
  • Cooling for the second heat exchanger 122 can be provided by the end-flash gas 130, and the warmed end- flash gas stream 132 thereafter can be compressed by a end-compressor 134 to provide a compressed end-stream 136, which can be cooled one or more ambient coolers 138 to provide a fuel stream 139 for use in a manner known in the art.
  • the pressure of the reduced-pressure cooled stream 72 is the same or similar to the pressure of the expanded cooled hydrocarbon stream after the valve 116, such that they can be readily and easily combined, such as in the end-flash vessel 118.
  • the at least partly liquefied cooled stream 71 is within 40 0 C, preferably within 10 0 C, of the cooled, preferably liquefied, hydrocarbon stream 120.
  • the present invention can achieve re-injection of at least fractions of the overhead streams from one or more of the distillation columns 12, 22, 32, 42 into the end step or stage of a liquefaction process, such as the end- flash vessel 118 shown in Figure 1.
  • An advantage of sub-cooling the cooled stream 70 is that less flash vapour will form during the pressure reduction while passing through valve 124, and hence a larger fraction of the cooled stream 70 will end up in the liquid product stream 140 from the end-flash vessel 118.
  • the Cl overhead stream 20 is particularly useful in being able to cool at least a fraction of at least one of the group comprising: the C2 overhead stream 40, the C3 overhead stream 50 and the C4 overhead stream 60; which would otherwise be too warm for liquefaction and combining with the cooled hydrocarbon stream 120. It is apparent from the foregoing that there is no need to recompress or decompress the Cl overhead stream 20 or a stream combined with it until after the generation of the at least partly liquefied cooled stream 71. Thus, the pressure of the at least partly liquefied cooled stream 71 is substantially the same as the Cl overhead stream, with none of the intervening steps resulting in a substantial increase in pressure.
  • the present invention does not require any recompression of the Cl overhead stream 20, generated from the mixed hydrocarbon feed stream 10 prior to the cooling of the at least the fraction of the at least one of the C2, C3 or C4 overhead streams 45, 55, 65 with the Cl overhead stream 20 to provide a cooled stream 70.
  • no recompression of the cooled stream 70 is required before further cooling in the heat exchanger 122 to provide the at least partly liquefied cooled stream 71.
  • the method and apparatus according to this group of embodiments is advantageous because there is no need to recompress the Cl overhead stream 20 or a stream containing it, up until after the at least partly liquefied cooled stream 71 is expanded to provide reduced-pressure cooled stream 72 and passed to the end flash vessel 118.
  • the point at which the reduced-pressure cooled stream 72 is combined with the cooled hydrocarbon stream 120 is chosen such that no pressurisation of the reduced-pressure cooled stream 72 is required.
  • the cooled stream 70 which can be at a sixth pressure, can thus be further cooled against at least a fraction of the cooled hydrocarbon stream 120, at substantially the same pressure as the Cl overhead stream 20.
  • This further cooling step provides an at least partly liquefied cooled stream 71.
  • Lower pressure streams will liquefy at a lower temperature, such that by avoiding the need to decompress these streams, the at least partial liquefaction in heat exchanger 122 is improved, compared to a system in which one or more of these streams are expanded prior to the at least partial liquefaction step.
  • cooled stream 70 as described herein can be at a pressure of approximated 35 bar, substantially the same pressure as the Cl overhead stream from which it is derived.
  • the cooling of such a non- depressurised cooled stream 70 in second heat exchanger 122 against the end-flash gas 130, to provide the at least part liquefied stream 71, subsequent expansion in valve 124 to approximately ambient pressure as reduced- pressure cooled stream 72 and then flashing in end-flash vessel 118 can provide 22% more liquefied hydrocarbon from the reduced-pressure cooled stream 72 compared to a cooled stream 70 which has been let down to a pressure of approximately 10 bar using an expansion device prior to cooling in the second heat exchanger 122, expanding to about ambient pressure and then carrying out an end flash step as described herein.
  • the comparison is based on an equal flow rate of stream 70 and an equal size heat exchanger 122.
  • Figure 2 is a more detailed scheme of the method and arrangement shown in Figure 1.
  • Figure 2 shows the LNG plant 2 incorporating the NGL recovery system 1 shown in Figure 1.
  • Figure 2 shows an initial feed stream 7 being cooled by three pre-cooling heat exchangers 14a, 14b and 14c (equivalent to the pre-cooling heat exchanger 14 shown in Figure 1) to provide the cooled initial hydrocarbon stream 8 which passes into the scrub column 16.
  • the scrub column 16 provides the condensed mixed hydrocarbon feed stream 10, which passes into the NGL recovery system 1 described above, to provide a cooled stream 70 and first C2, C3, C4 fractions 46, 56, 66, and a C5+ product stream 68.
  • the scrub column 16 also provides an initial overhead stream 110 which passes into the main heat exchanger 112, is part-cooled thereby, and provides a side stream 200 which passes into a separator 202 which provides a bottom reflux stream 204 for return into the scrub column 16, and an overhead stream 206.
  • a first fraction, usually ⁇ 5 vol%, of the overhead stream 206 can be provided as a side stream 206a, whilst the majority of the overhead stream 206 is passed as a second fraction stream 206b back into the main heat exchanger 112 for liquefaction to provide a cooled, preferably liquefied stream 120.
  • Figure 2 also shows a main refrigerant circuit 210 for providing the cooling to the main heat exchanger 112.
  • Refrigerant circuits are known in the art, and typically comprise one or more refrigerant compressors, ambient coolers, refrigerant coolers, and division of the refrigerant stream into light and heavy refrigerant fractions which can be separately used in the main heat exchanger 112 in a manner known in the art.
  • the cooled hydrocarbon stream 120 passes through a third heat exchanger 212, an expander 214, and a valve 216, for entry into the end-flash vessel 118.
  • the end-flash gas 130 passes through the second heat exchanger 122 to provide cooling to the cooled stream 70, prior to its compression and cooling to provide a fuel stream 139.
  • Figure 2 also shows cooling of the side stream 206a in the second heat exchanger 122 by the end-flash gas
  • the Cl overhead stream 20 is part of the cooled stream 70, and the cooled stream 70 is subsequently liquefied against a fraction of the cooled hydrocarbon stream 120, in particular the end-flash gas 130.
  • the at least partly liquefied cooled stream 71 created thereby is subsequently combined with the cooled hydrocarbon stream 120.
  • the pressure of the at least partly liquefied cooled stream 71 in the embodiments of Figures 1 and 2 is substantially the same as the pressure of the Cl overhead stream 20.
  • the pressure of the cooled stream 70, which is intermediary between the Cl overhead stream 20 and the at least partly liquefied cooled stream 71, is also at substantially the same pressure as these other streams. This means that no compression or expansion steps are necessary between the Cl overhead stream 20 and the at least partly liquefied cooled stream 71.
  • the term "substantially the same” means that the difference between the pressure of the Cl overhead stream 20, provided at a first pressure, and the at least partly liquefied cooled stream 71, provided at a second pressure is less than a de minimus pressure loss resulting from flow through piping and heat exchanger ( s ), which may be less than 10 bar, more preferably less than 5 bar, even more preferably less than 1 bar.
  • the cooled stream is further cooled against at least a fraction of the cooled hydrocarbon stream at a higher pressure compared to other systems in which one or more pressure reductions are carried out. At such higher pressures, the latent heat required to provide the at least partly liquefied cooled stream is believed to be lower, leading to a more efficient further cooling operation.
  • the first pressure at which the Cl overhead stream is provided is also a beneficial pressure for the further cooling of the cooled stream.
  • Figure 3 shows an alternative scheme 4 according to another embodiment of the present invention.
  • the cooling of the at least the fraction of the at least one of the group defined in step (d) - the group comprising the C2 overhead stream, the C3 overhead stream, and the C4 overhead stream - is effected by indirect heat exchange with the Cl overhead stream 20, which does not require admixing with the Cl overhead stream 20.
  • the Cl overhead stream 20a may be used, for instance, as fuel gas.
  • the initial feed stream 7 containing natural gas is cooled by three pre-cooling heat exchangers 14a, 14b, 14c to provide a cooled and partially condensed initial hydrocarbon stream 8, which passes directly into the main heat exchanger 112 to provide a further cooled initial hydrocarbon stream 18a.
  • the further cooled hydrocarbon stream 18a passes into a separator 240 to provide, as a bottom stream, a mixed hydrocarbon feed stream 10 which can then pass into an NGL recovery system 1 as described above to provide a Cl overhead stream 20, a second C2 fraction 45, a second C3 fraction 55 and a second C4 fraction 65 as herein before described.
  • the second C2, C3 and C4 fractions 45, 55, 65 are combined to form a combined stream 242 which passes into a fourth heat exchanger 244. Also passing into the fourth heat exchanger 244 is the Cl overhead stream 20, which, being cooler, provides cooling to the combined stream 242 to provide a warmed Cl overhead stream 20a, and a cooled stream 70a.
  • the fourth heat exchanger 244 is one means to cool said fraction (s).
  • the warmed Cl overhead stream 20a can be combined with one or more other methane-predominant streams, such as a compressed end-flash gas stream 136, for use as a fuel stream 139a.
  • the cooled stream 70a passes through a heat exchanger 122a to provide an at least partly liquefied cooled stream 71a, which can be passed through a valve 124, and optionally combined with a liquefied side stream 206c as described hereinbefore, to provide a reduced pressure combined stream 72a which can then pass into an end-flash vessel 118.
  • the main overhead fraction 206b from the separator 240 is at least partially, preferably fully, condensed in the main heat exchanger 112 to provide a cooled, preferably liquefied, hydrocarbon stream 120.
  • the cooled hydrocarbon stream 120 passes through a third heat exchanger 212, expander 214 and a valve 216, to provide an end-feed stream 222 which passes into an end-flash vessel 118.
  • Table 1 below gives an overview of estimated compositions, phases, pressures and temperatures of some of the streams at various parts of an example process of the arrangement shown in Figure 2.

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Abstract

Method and apparatus cooling a hydrocarbon stream such as natural gas. An initial hydrocarbon stream (8) is passed through a first separator (16) to provide an initial overhead stream (110) and a mixed hydrocarbon feed stream (10). The initial overhead stream (110) is cooled to provide a cooled hydrocarbon stream (120) such as LNG, and at least a Cl overhead stream (20) and one or more C2, C3 and C4 overhead streams (40, 50, 60) are separated from the mixed hydrocarbon feed stream. At least a fraction (45, 55, 65) of at least one of the group comprising: the C2 overhead stream (40), the C3 overhead stream (50) and the C4 overhead stream (60); is cooled with the C1 overhead stream (20) to provide a cooled stream (70), which is further cooled against at least a fraction of the cooled, preferably liquefied, hydrocarbon stream (120) to provide an at least partly liquefied cooled stream (71).

Description

METHOD AND APPARATUS FOR COOLING A HYDROCARBON STREAM
The present invention relates to a method and apparatus for cooling a hydrocarbon stream, and to a liquefied natural gas plant or facility including such apparatus . A common hydrocarbon stream to be cooled, optionally to full liquefaction, is natural gas.
Natural gas is a useful fuel source, as well as being a source of various hydrocarbon compounds. It is often desirable to liquefy natural gas in a liquefied natural gas (LNG) plant at or near the source of a natural gas stream for a number of reasons. For example, natural gas can be stored and transported over long distances more readily as a liquid than in gaseous form, because it occupies a smaller volume and does not need to be stored at high pressure.
Usually, natural gas, comprising predominantly methane, enters an LNG plant at elevated pressures and is pre-treated to produce a purified feed stream suitable for liquefaction at cryogenic temperatures. The purified gas is processed through a plurality of cooling stages using heat exchangers to progressively reduce its temperature until liquefaction is achieved. The liquid natural gas is then further cooled and expanded to final atmospheric pressure suitable for storage and transportation.
In addition to methane, natural gas usually includes some heavier hydrocarbons and non-hydrocarbons, including but not limited to carbon dioxide, mercury, sulphur, hydrogen sulphide and other sulphur compounds, nitrogen, helium, water and other non-hydrocarbon acid gases, ethane, propane, butanes, C5+ hydrocarbons and aromatic hydrocarbons. These and any other common or known heavier hydrocarbons and non-hydrocarbons either prevent or hinder the usual known methods of liquefying the methane, especially the most efficient methods of liquefying methane. Most if not all known or proposed methods of liquefying hydrocarbons, especially liquefying natural gas, are based on reducing as far as possible the levels of the non-hydrocarbons prior to the liquefying process, and reducing the levels of the heavier hydrocarbons at least for the main methane-based stream being liquefied.
Hydrocarbons heavier than methane and usually ethane are typically condensed and recovered as natural gas liquids (NGL) from a natural gas stream. The NGLs are usually fractionated in an NGL recovery system to yield valuable hydrocarbon products, either as products steams per se, or for use in liquefaction, for example as a component of a refrigerant or for reintroduction downstream with the main methane-based liquefied product stream.
However, NGL recovery conventionally involves cooling, condensation and fractionation steps that require significant amounts of refrigeration and other power consumption. It is desirable to recover NGLs from a natural gas stream with the most efficient or minimal power consumption .
EP 1 469 266 Al describes a process for the recovery of components heavier than methane from natural gas, including withdrawing from an absorber column a bottom stream enriched in components heavier than methane, and separating this into a stream containing methane and ethane, and one or more streams enriched in components heavier than ethane. However, a problem with EP 1 469 266 Al is that its methane and ethane stream is liquefied in its main heat exchanger. This requires an extra bundle of cooling pipes in the main heat exchanger to accommodate the extra stream, and takes away cooling duty of the main heat exchanger from the main methane stream being liquefied.
The present invention provides a method of cooling a hydrocarbon stream comprising at least the steps of: (a) passing an initial hydrocarbon stream through a first separator to provide an initial overhead stream and a mixed hydrocarbon feed stream;
(b) cooling, preferably liquefying, the initial overhead stream to provide a cooled, preferably liquefied, hydrocarbon stream such as LNG;
(c) separating at least a Cl overhead stream at a first pressure and one or more C2, C3 and C4 overhead streams from the mixed hydrocarbon feed stream;
(d) cooling at least a fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; by admixing with the Cl overhead stream, to provide a cooled stream; and
(e) further cooling the cooled stream against at least a fraction of the cooled, preferably liquefied, hydrocarbon stream to provide an at least partly liquefied cooled stream at a second pressure which is substantially the same as the first pressure.
The present invention also provides an apparatus for cooling a hydrocarbon stream comprising at least: a first separator through which an initial hydrocarbon stream passes to provide an initial overhead stream and a mixed hydrocarbon feed stream; a cooling system to cool, preferably liquefy, the initial overhead stream to provide a cooled, preferably liquefied, hydrocarbon stream such as LNG; an NGL recovery system to separate at least a Cl overhead stream and one or more C2, C3 and C4 overhead streams from the mixed hydrocarbon feed stream; a combiner to cool at least a fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; by admixing with the Cl overhead stream, to provide a cooled stream; and one or more heat exchangers for further cooling the cooled stream against at least a fraction of the cooled, preferably liquefied, hydrocarbon stream to provide an at least partly liquefied cooled stream; wherein there are no expansion or compression devices between the Cl overhead stream and the at least partly liquefied cooled stream.
The present invention also provides a liquefied natural gas plant or facility including an apparatus as hereindefined .
Embodiments and examples of the present invention will now be described by way of example only and with reference to the accompanying non-limiting drawings in which:
Figure 1 is a first diagrammatic scheme for a method of cooling according to one embodiment of the present invention;
Figure 2 shows a third diagrammatic scheme for a method of cooling according to another embodiment; and
Figure 3 is a second diagrammatic scheme for a method of cooling according to a second group of embodiments . For the purpose of this description, a single reference number will be assigned to a line as well as a stream carried in that line.
The present disclosure shows cooling of one or more streams separated from a related mixed hydrocarbon feed stream as part of a multi-column natural gas liquids (NGL) recovery system and arrangement.
Embodiments described herein provide a highly efficient configuration for the production of an at least partly, preferably fully, liquefied cooled stream from one or more streams separated from an NGL recovery system.
Disclosed are various methods and apparatus. These methods comprise at least the steps of: (a) passing an initial hydrocarbon stream through a first separator to provide an initial overhead stream and a mixed hydrocarbon feed stream;
(b) cooling, preferably liquefying, the initial overhead stream to provide a cooled, preferably liquefied, hydrocarbon stream;
(c) separating at least a Cl overhead stream and one or more C2, C3 and C4 overhead streams from the mixed hydrocarbon feed stream;
(d) cooling at least a fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; with the Cl overhead stream, to provide a cooled stream; and
(e) further cooling the cooled stream against at least a fraction of the cooled, preferably liquefied, hydrocarbon stream to provide an at least partly liquefied cooled stream.
The apparatus comprise at least: a first separator through which an initial hydrocarbon stream passes to provide an initial overhead stream and a mixed hydrocarbon feed stream; a cooling system to cool, preferably liquefy, the initial overhead stream to provide a cooled, preferably liquefied, hydrocarbon stream such as LNG; an NGL recovery system to separate at least a Cl overhead stream and one or more C2, C3 and C4 overhead streams from the mixed hydrocarbon feed stream; means to cool at least a fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; with the Cl overhead stream, to provide a cooled stream; and one or more heat exchangers for further cooling the cooled stream against at least a fraction of the cooled, preferably liquefied, hydrocarbon stream to provide an at least partly liquefied cooled stream.
In one group of embodiments, the cooling of the at least the fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; with the Cl overhead stream, is achieved by admixing. To this end, the apparatus could comprise a combiner to admix the at least the fraction with the Cl overhead stream. In this group of embodiments, it is advantageous to further cool the cooled (and admixed) stream at substantially the same pressure as the pressure of the Cl overhead stream as it was separated from the mixed hydrocarbon feed stream. As used herein, the term "substantially the same" means that the difference between the pressure of the Cl overhead stream, provided at the first pressure, and the at least partly liquefied cooled stream, provided at the second pressure, is less than a de minimis, indeliberate, pressure loss resulting from the flow through piping and heat exchanger (s) .
By not deliberately lowering the pressure, liquefaction efficiency during the further cooling is not sacrificed. Increasing the pressure would theoretically take the further cooling to a more favourable portion in the phase diagram, but it would adversely require additional capital expenditure and plot space. Thus the proposed group of embodiments takes as much as possible advantage of the pressure that was already available in the Cl overhead stream. And advantageously, no expansion or compression devices need to be provided between the Cl overhead stream and the at least partly liquefied cooled stream. In another group of embodiments, the cooling of the at least the fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; is achieved by indirect heat exchange with the Cl overhead stream. Since admixing is avoided, this allows for a dedicated use of the relatively pure Cl overhead stream. No substantial pressure reduction or increase needs be imposed before the indirect heat exchanging.
In either case, the present invention may be applied to provide first cooling of a stream from NGL recovery by a Cl overhead stream, and subsequent further cooling, preferably fully liquefying, by a fraction of the main cooled, preferably liquefied, hydrocarbon stream, such as end-flash gas. This avoids taking away cooling duty in step (b) of the method of the present invention, which would diminish cooling of the main hydrocarbon stream. Thus, cold energy for the cooling of the main hydrocarbon stream (by a separate refrigerant, refrigeration system and/or circuit) need not be diverted to be involved in NGL recovery, increasing the efficiency of other processes or sections of a liquefaction plant such as an LNG plant. Embodiments of the present invention provide flexibility for using the cooling of a Cl overhead stream from the NGL recovery to cool at least a fraction of any one of, or any combination of, C2, C3 and C4 overhead streams . The need for an extra bundle of cooling pipes in a main heat exchanger to accommodate an NGL recovery stream may herewith be avoided, thereby avoiding the additional CAPEX and OPEX required in EP 1 469 266 Al for its integrated main heat exchanger. The initial hydrocarbon stream may be any suitable hydrocarbon stream such as, but not limited to, a hydrocarbon-containing gas stream able to be cooled. One example is a natural gas stream obtained from a natural gas or petroleum reservoir. As an alternative the natural gas stream may also be obtained from another source, also including a synthetic source such as a Fischer-Tropsch process .
Usually such an initial hydrocarbon stream is comprised substantially of methane. Preferably such an initial feed stream comprises at least 60 mol% methane, more preferably at least 80 mol% methane.
Although the method according to the present invention is applicable to various hydrocarbon streams, it is particularly suitable for natural gas streams to be liquefied. As the person skilled readily understands how to liquefy a hydrocarbon stream, this is not discussed herein detail . The Cl, C2, C3 and C4 overhead streams may be provided by any known NGL recovery system. An NGL recovery system usually involves one or more distillation columns. The first, and any of second, third or fourth distillation columns useable in the present invention, may be any form of separator adapted to provide at least one overhead stream, usually a gaseous overhead stream, and usually being enriched in one or more lighter hydrocarbons, and at least one bottom stream, usually a liquid stream, and usually being enriched in one or more heavier hydrocarbons. In certain circumstances, an overhead stream and/or a bottom stream may be a mixed phase stream.
An example of a suitable first distillation column is a "demethanizer" designed to provide a methane- enriched overhead stream, and one or more liquid streams at or near the bottom enriched in C2+ hydrocarbons. Similarly, a second distillation column may be a "deethanizer", a third distillation column may be a "depropanizer", and a fourth distillation column may be a "debutanizer" . Such columns are known in the art.
Thus, where the first distillation column is a demethanizer, the first bottom stream of the present invention can hereinafter be defined as a C2+ hydrocarbon stream. Where the second distillation column is a deethanizer, the second bottom liquid stream may be defined as a C3+ hydrocarbon stream, and the second overhead gaseous stream is preferably >60 mol% ethane, more preferably >85 mol% and even more preferably >90 mol% ethane.
Each distillation column of the present invention may involve one or more columns, and one or each of such columns could provide individual liquid streams of certain heavier hydrocarbons such as ethane, propane, etc. Commonly, NGL recovery results in a C5+ hydrocarbon stream.
The term "mixed hydrocarbon feed stream" as used herein relates to a feed stream comprising methane (Cl) and at least 5 mol% of one or more hydrocarbons selected from the group comprising: ethane (C2), propane (C3), butanes (C4), and C5+ hydrocarbons.
The term "C5+ hydrocarbon stream" relates to a stream comprising "pentanes" and heavier hydrocarbons, often also termed 'light condensates'.
The terms "C2+", "C3+" et al relate to a stream comprising ethane and heavier hydrocarbons, propane and heavier hydrocarbons, et al . Any C2, C3, and C4 stream may still comprise a minor
(<10 mol%) amount of methane; each such stream is preferably >80 mol%, more preferably >95 mol%, of its main component, ethane, propane and the butanes, respectively . The division of a stream such as a feed stream or an overhead stream into two or more part streams may be carried out using any suitable stream splitter or divider, which may be a distinct unit, or a simpler division of a line such as a T-piece. Figure 1 shows a simplified and first general scheme of a liquefied natural gas plant 2 for a method for cooling an initial hydrocarbon stream 8 which separated into a mixed hydrocarbon feed stream 10 and a methane- enriched stream 110, which methane-enriched stream 110 is subsequently cooled, preferably liquefied, to provide a cooled, preferably liquefied, hydrocarbon stream 120, preferably LNG. Meanwhile, Figure 1 also shows an NGL recovery system 1 wherein the mixed hydrocarbon feed stream 10 is separated into a Cl stream (20) and one or more C2, C3 and C4 streams (40, 50, 60, respectively) .
The initial feed stream 7 may contain natural gas. It is cooled by a pre-cooling heat exchanger 14 to provide a cooled and partly condensed initial hydrocarbon stream 8. The pre-cooling heat exchanger 14 may comprise one or more heat exchangers either in parallel, series or both, in a manner known in the art. Cooling in the pre- cooling heat exchanger 14 is provided by a first refrigerant stream 100, which is warmed in the pre- cooling heat exchanger 14 to provide a warmed first refrigerant stream 100a.
The cooling of the initial feed stream 7 may be part of a liquefaction process, such as a pre-cooling stage involving a propane refrigerant circuit as described hereinafter in relation to Figure 2, or a separate process .
Cooling of the initial feed stream 7 may involve reducing the temperature of the initial feed stream 7 to below -00C, for example, in the range -100C to -700C.
The cooled initial hydrocarbon stream 8 is passed into a first separator 16 such as a scrub column 16, operating at an above ambient pressure in a manner known in the art. The scrub column 16 provides a condensed mixed hydrocarbon feed stream 10, preferably having a temperature below -00C, and an initial overhead steam, in the present specification also referred to as the methane-enriched stream 110. The initial gaseous overhead stream 110 is usually greater than 80 mol% methane, and is an enriched-methane stream compared to the cooled initial hydrocarbon stream 8.
The mixed hydrocarbon feed stream 10 comprises methane and one or more of C2, C3, C4 and C5+ hydrocarbons. Typically, the proportion of methane in the mixed hydrocarbon feed stream 10 is 30-50 mol%, with a significant fraction of ethane and propane, such as 5-10 mol% each. In NGL recovery, it is desired to recover any methane in a mixed hydrocarbon stream (for use as a fuel or to be liquefied in the LNG plant 2 and provided as additional LNG) , and to provide one or more of a C2 stream, a C3 stream, a C4 stream, and a C5+ stream. In Figure 1, at least a fraction, usually all, of the mixed hydrocarbon feed stream 10 passes into the NGL recovery system 1, through a valve 18 to provide a reduced pressure mixed hydrocarbon feed stream 10a, and then enters a first distillation column 12 at or near the top thereof. The reduced pressure mixed hydrocarbon feed stream 10a is typically a mixed phased stream, and the first distillation column 12 is adapted to separate the gaseous and vapour phases, so as to provide a Cl overhead stream 20 and a first bottom stream 30. The nature of the streams provided by the first distillation column 12 can be varied according to the size and type of distillation column, and its operating conditions and parameters, in a manner known in the art. For the arrangement shown in Figure 1, it is desired for the Cl overhead stream 20 to be methane-enriched, preferably to be >90 mol% methane.
The first distillation column 12 also includes a first reboiler 13 and a first reboiler vapour return stream 13a in a manner known in the art. The first bottom stream 30 is predominantly a C2+ hydrocarbon stream, such as >90 or >95 mol% ethane and heavier hydrocarbons. The first bottom stream 30 is cooled by one or more ambient coolers, such as a water and/or air cooler 21, to provide a cooled first bottom stream 31, followed by a passage through a valve 19 and entry into a second distillation column 22. Again, the type, size and capacity of the second distillation column 22, as well as its operating conditions and parameters, will control the nature of the streams provided by the second distillation column 22.
In the arrangement shown in Figure 1, the second distillation column 22 provides a C2 overhead stream 40 being predominantly ethane, preferably >85 mol% or >90 mol% ethane, and a second bottom stream 47, generally being a C3+ stream comprising >98 mol% propane and heavier hydrocarbons. The second distillation column 22 also includes a second reboiler 23 and a second reboiler vapour return stream 23a.
Optionally, a fraction of the mixed hydrocarbon feed stream 10 is provided as a side stream 10b. The side stream 10b can pass through a valve 24 to provide a reduced pressure stream 25, which has a temperature that is low enough, such as between 00C and -500C, to provide cooling in a first heat exchanger 26 to the C2 overhead stream 40. The first heat exchanger 26 may be one or more heat exchangers in parallel, series or both.
The cold energy of the reduced pressure stream 25 withdraws warmth from the C2 overhead stream 40 to at least partially condense, preferably fully condense, the C2 overhead stream 40 in the heat exchanger 26, and provide an at least partly condensed C2 stream 40a.
The at least partly condensed C2 stream 40a can be divided by a separator 27 to provide a separator bottom stream 41, which could pass into a pump 28 and be divided into a C2 reflux stream 43 for return to the second distillation column 22, and a C2 product stream 44. The C2 product stream 44 itself can then be divided by a divider 29 into a first C2 fraction 46 for use outside a liquefaction plant, or as a refrigerant or as a component of a refrigerant in a liquefaction plant, such as in a mixed refrigerant known in the art, and a second C2 fraction 45 for use with the present invention as discussed hereinafter.
The percentage ratio of the division of the separator bottom stream 41 and/or the C2 product stream 44 as discussed above may be any suitable ratio between 0-100%. Factors influencing the ratio include the operating conditions and parameters of the second distillation column 22, the external or internal requirement for C2 for use as a refrigerant, or to replenish or supplement a refrigerant, etc.
The heat exchange of the C2 overhead stream 40 and the reduced pressure stream 25 also provides a warmer reduced pressure stream 10c, which can be passed into the first distillation column 12. The second bottom stream 47 is predominately a C3+ hydrocarbon stream, such as >90 or >95 mol% of propane and heavier hydrocarbons. The second bottom stream 47 passes through a valve 31 to provide a reduced pressure second bottom stream 48, which passes into a third distillation column 32. The type, size and capacity of the third distillation column 32, as well as its operating conditions and parameters, will control the nature of the streams provided by the third distillation column 32. In the arrangement shown in Figure 1, the third distillation column 32 provides a C3 overhead stream 50 being predominately propane, preferably being >85 mol% or >90 mol% propane, and a third bottom stream 57, generally being a C4+ stream comprising >90 mol% butanes and heavier hydrocarbon. The third distillation column 32 also includes a third reboiler 33 and third reboiler vapour return stream 33a. The C3 overhead stream 50 passes through one or more ambient coolers, such as a water and/or air cooler 34, to provide a cooled C3 overhead stream 51, which is divided by a separator 35 to provide a separator bottom stream 52 which passes into a pump 36 and is divided into a C3 reflux stream 53 for return to the third distillation column 32, and a C3 product stream 54. The C3 product stream 54 itself can then be divided by a divider 59 into a first C3 fraction 56 for use outside a liquefaction plant, or as a refrigerant or as a component of a refrigerant in a liquefaction plant, such as in a mixed refrigerant known in the art, and a second C3 fraction 55 for use with the present invention as discussed hereinafter .
The percentage ratio of the division of the separator bottom stream 52 and/or the C3 product stream 54 as discussed above may be any suitable ratio between 0-100%. Factors influencing the ratio include the operating conditions and parameters of the second distillation column 32, the external or internal requirement for C3 for use as a refrigerant, or to replenish or supplement a refrigerant, etc.
The third bottom stream 57 passes through a valve 38 to provide a reduced pressure third bottom stream 58, which passes into a fourth distillation column 42. The type, size and capacity of the fourth distillation column 42, as well as its operating conditions and parameters, will control the nature of the streams provided by the fourth distillation column 42. In the arrangement shown in Figure 1, the fourth distillation column 42 provides a C4 overhead stream 60 being predominately butane and/or i-butane, preferably >85 or >90 mol% butane (s), and a C5+ bottom stream 67. The C5 bottom stream 67 may pass through one or more ambient coolers such as a water and/or air cooler 91 to provide a C5+ product stream 68 in a manner known in the art. The fourth distillation column 42 also includes a fourth reboiler 92 and a fourth reboiler vapour return stream 92a.
The C4 overhead stream 60 may pass through one or more ambient coolers such as a water and/or air cooler 93 to provide a cooled C4 overhead stream 61, which passes into a separator 94 to provide a separator bottom stream 62, which could pass into a pump 95 and be divided into a C4 reflux stream 63 for return to the fourth distillation column 42, and C4 a product stream 64. The C4 product stream 64 itself can then be divided by a divider 96 into a first C4 fraction 66 for use outside a liquefaction plant, or as a refrigerant or as a component of a refrigerant in a liquefaction plant, such as in a mixed refrigerant known in the art, and a second C4 fraction 65 for use with the present invention.
The percentage ratio of the division of the separator bottom stream 62 and/or the C4 product stream 64 as discussed above may be any suitable ratio between 0-100%. Factors influencing the ratio include the operating conditions and parameters of the fourth distillation column 32, the external or internal requirement for C4 for use as a refrigerant, or to replenish or supplement a refrigerant, etc.
In the arrangement shown in Figure 1, the second C4 fraction 65 is combined by a combiner 97 with the second C3 fraction 55 to provide a combined C3 and C4 product stream 81.
Meanwhile, the Cl overhead stream 20 is combined by a combiner 82 with the second C2 fraction 45 to provide a combined Cl and C2 stream 84, which is then also combined with the combined C3 and C4 stream 81 by a combiner 86 to provide a cooled stream 70.
Typically, Cl overhead stream 20 has a temperature below 00C, such as in the range -100C to -1000C, more usually in the range -300C to -700C.
The second C2 fraction 45 typically has a temperature below 100C, such as between 100C and -200C, more usually in the range 50C to -100C.
The second C3 fraction 55 and the second C4 fraction 65 typically have a temperature above O0C, usually in the range O0C to 600C.
Thus, by using the Cl overhead stream 20 with at least a fraction of a least of one of the group comprising; the C2 overhead stream 40, the C3 overhead stream 50 and the C4 overhead stream 60; said at least fraction (s) are cooled by the Cl overhead stream 20 because the Cl overhead stream 20 is the coolest of said streams and fractions. The piping combining the Cl overhead stream 20 with at least said fraction (s) provide the means to cool said fraction (s).
Figure 1 shows an arrangement where second fractions 45, 55, 65 of each of the C2 overhead stream 40, the C3 overhead stream 50 and the C4 overhead stream 60, are cooled by the Cl overhead stream 20, by being combined therewith, and therefore being in admixture therewith. In this way, the Cl overhead stream 20 provides direct cooling to the second fractions 45, 55, 65. In the arrangement shown in Figure 1, the combination or admixture of the Cl overhead stream 20, the second C2 fraction 45 and the combined C3 and C4 stream 81 provide a cooled stream 70 as a single stream.
Preferably, the cooled stream 70 has a temperature below O0C. The cooled stream 70 may be a mixed phase stream, i.e. partly liquid.
Figure 1 also shows the initial overhead stream 110 from the scrub column 16 passing into a main heat exchanger 112 to provide a further cooled and at least partially condensed, preferably fully condensed or liquefied, hydrocarbon stream 120. Cooling in the main heat exchanger 112 is provided by a second refrigerant stream 114, which is warmed in the main heat exchanger 112 to provide a warmed second refrigerant stream 114a. The cooled, preferably liquefied, hydrocarbon stream 120 passes through a valve 116 and into an end gas/liquid separator such as an end-flash vessel 118. The action of an end-flash vessel 118 is known in the art, and it provides an overhead stream, which may be termed end- flash gas 130, and a liquefied product stream 140, which is preferably LNG.
In the arrangement shown in Figure 1, the cooled stream 70 can then be further cooled, preferably sub- cooled, by passing it through a second heat exchanger 122. This provides an at least partly liquefied cooled
(or sub-cooled) stream 71, which, after passing through a valve 124, provides a reduced-pressure cooled stream 72, which then passes into the end-flash vessel 118. Hence, the at least partly liquefied cooled stream 71 is combined with the cooled hydrocarbon stream 120, either upstream of the end flash vessel 118 (e.g. using any type of junction or combiner known in the art) or directly in the end-flash vessel 118 as shown in Fig. 1. Cooling for the second heat exchanger 122 can be provided by the end-flash gas 130, and the warmed end- flash gas stream 132 thereafter can be compressed by a end-compressor 134 to provide a compressed end-stream 136, which can be cooled one or more ambient coolers 138 to provide a fuel stream 139 for use in a manner known in the art.
Preferably, the pressure of the reduced-pressure cooled stream 72 is the same or similar to the pressure of the expanded cooled hydrocarbon stream after the valve 116, such that they can be readily and easily combined, such as in the end-flash vessel 118.
Also preferably, the at least partly liquefied cooled stream 71 is within 400C, preferably within 100C, of the cooled, preferably liquefied, hydrocarbon stream 120.
It is another advantage of the present invention that no external refrigeration is required for the combination of the at least partially liquefied cooled stream 71 with the cooled hydrocarbon stream 120. Thus, the present invention can achieve re-injection of at least fractions of the overhead streams from one or more of the distillation columns 12, 22, 32, 42 into the end step or stage of a liquefaction process, such as the end- flash vessel 118 shown in Figure 1.
An advantage of sub-cooling the cooled stream 70 is that less flash vapour will form during the pressure reduction while passing through valve 124, and hence a larger fraction of the cooled stream 70 will end up in the liquid product stream 140 from the end-flash vessel 118.
The Cl overhead stream 20 is particularly useful in being able to cool at least a fraction of at least one of the group comprising: the C2 overhead stream 40, the C3 overhead stream 50 and the C4 overhead stream 60; which would otherwise be too warm for liquefaction and combining with the cooled hydrocarbon stream 120. It is apparent from the foregoing that there is no need to recompress or decompress the Cl overhead stream 20 or a stream combined with it until after the generation of the at least partly liquefied cooled stream 71. Thus, the pressure of the at least partly liquefied cooled stream 71 is substantially the same as the Cl overhead stream, with none of the intervening steps resulting in a substantial increase in pressure.
The present invention does not require any recompression of the Cl overhead stream 20, generated from the mixed hydrocarbon feed stream 10 prior to the cooling of the at least the fraction of the at least one of the C2, C3 or C4 overhead streams 45, 55, 65 with the Cl overhead stream 20 to provide a cooled stream 70. Similarly, no recompression of the cooled stream 70 is required before further cooling in the heat exchanger 122 to provide the at least partly liquefied cooled stream 71. Thus, the method and apparatus according to this group of embodiments is advantageous because there is no need to recompress the Cl overhead stream 20 or a stream containing it, up until after the at least partly liquefied cooled stream 71 is expanded to provide reduced-pressure cooled stream 72 and passed to the end flash vessel 118. In this way, the point at which the reduced-pressure cooled stream 72 is combined with the cooled hydrocarbon stream 120 is chosen such that no pressurisation of the reduced-pressure cooled stream 72 is required. This provides significant CAPEX savings because there is no requirement for a compressor in the NGL recovery system 1 and OPEX savings in terms of the operation power saved by dispensing with such recompression.
There is also no need to expand the Cl overhead stream 20 or a stream containing it until after the generation of the at least partly liquefied cooled hydrocarbon stream 71. The cooled stream 70 which can be at a sixth pressure, can thus be further cooled against at least a fraction of the cooled hydrocarbon stream 120, at substantially the same pressure as the Cl overhead stream 20. This further cooling step provides an at least partly liquefied cooled stream 71. Lower pressure streams will liquefy at a lower temperature, such that by avoiding the need to decompress these streams, the at least partial liquefaction in heat exchanger 122 is improved, compared to a system in which one or more of these streams are expanded prior to the at least partial liquefaction step.
For instance, cooled stream 70 as described herein can be at a pressure of approximated 35 bar, substantially the same pressure as the Cl overhead stream from which it is derived. The cooling of such a non- depressurised cooled stream 70 in second heat exchanger 122 against the end-flash gas 130, to provide the at least part liquefied stream 71, subsequent expansion in valve 124 to approximately ambient pressure as reduced- pressure cooled stream 72 and then flashing in end-flash vessel 118 can provide 22% more liquefied hydrocarbon from the reduced-pressure cooled stream 72 compared to a cooled stream 70 which has been let down to a pressure of approximately 10 bar using an expansion device prior to cooling in the second heat exchanger 122, expanding to about ambient pressure and then carrying out an end flash step as described herein. The comparison is based on an equal flow rate of stream 70 and an equal size heat exchanger 122.
Figure 2 is a more detailed scheme of the method and arrangement shown in Figure 1. Figure 2 shows the LNG plant 2 incorporating the NGL recovery system 1 shown in Figure 1. Figure 2 shows an initial feed stream 7 being cooled by three pre-cooling heat exchangers 14a, 14b and 14c (equivalent to the pre-cooling heat exchanger 14 shown in Figure 1) to provide the cooled initial hydrocarbon stream 8 which passes into the scrub column 16. The scrub column 16 provides the condensed mixed hydrocarbon feed stream 10, which passes into the NGL recovery system 1 described above, to provide a cooled stream 70 and first C2, C3, C4 fractions 46, 56, 66, and a C5+ product stream 68. The scrub column 16 also provides an initial overhead stream 110 which passes into the main heat exchanger 112, is part-cooled thereby, and provides a side stream 200 which passes into a separator 202 which provides a bottom reflux stream 204 for return into the scrub column 16, and an overhead stream 206. A first fraction, usually <5 vol%, of the overhead stream 206 can be provided as a side stream 206a, whilst the majority of the overhead stream 206 is passed as a second fraction stream 206b back into the main heat exchanger 112 for liquefaction to provide a cooled, preferably liquefied stream 120.
Figure 2 also shows a main refrigerant circuit 210 for providing the cooling to the main heat exchanger 112. Refrigerant circuits are known in the art, and typically comprise one or more refrigerant compressors, ambient coolers, refrigerant coolers, and division of the refrigerant stream into light and heavy refrigerant fractions which can be separately used in the main heat exchanger 112 in a manner known in the art.
The cooled hydrocarbon stream 120 passes through a third heat exchanger 212, an expander 214, and a valve 216, for entry into the end-flash vessel 118. From the end-flash vessel 118, the end-flash gas 130 passes through the second heat exchanger 122 to provide cooling to the cooled stream 70, prior to its compression and cooling to provide a fuel stream 139.
Figure 2 also shows cooling of the side stream 206a in the second heat exchanger 122 by the end-flash gas
130, which cooled side stream 206c can then be let down in pressure via valve 125, and subsequently combined with the at least partly liquefied cooled stream 71 prior to the valve 124 or downstream of valve 124. In Figures 1 and 2, the Cl overhead stream 20 is part of the cooled stream 70, and the cooled stream 70 is subsequently liquefied against a fraction of the cooled hydrocarbon stream 120, in particular the end-flash gas 130. The at least partly liquefied cooled stream 71 created thereby is subsequently combined with the cooled hydrocarbon stream 120.
In particular, the pressure of the at least partly liquefied cooled stream 71 in the embodiments of Figures 1 and 2 is substantially the same as the pressure of the Cl overhead stream 20. Thus, the pressure of the cooled stream 70, which is intermediary between the Cl overhead stream 20 and the at least partly liquefied cooled stream 71, is also at substantially the same pressure as these other streams. This means that no compression or expansion steps are necessary between the Cl overhead stream 20 and the at least partly liquefied cooled stream 71. As used herein, the term "substantially the same" means that the difference between the pressure of the Cl overhead stream 20, provided at a first pressure, and the at least partly liquefied cooled stream 71, provided at a second pressure is less than a de minimus pressure loss resulting from flow through piping and heat exchanger ( s ), which may be less than 10 bar, more preferably less than 5 bar, even more preferably less than 1 bar.
By producing the at least partly liquefied cooled stream 71 at substantially the same pressure as the Cl overhead stream 20, on the one hand, no compression of the Cl overhead stream 20, or the cooled stream 84, 70 which is formed from it, is required. Thus, there need not to be any compressors between the Cl overhead stream 20 and the at least partly liquefied cooled stream 71. This line-up provides significant CAPEX savings because compressors in the NGL recovery system and for the cooled stream are rendered unnecessary. OPEX savings are also provided in terms of the operation power saved by dispensing with the need to drive compressors to compress one or more of these streams.
In addition, on the other hand, there is no requirement to reduce the pressure of the Cl, C2, C3 and C4 overhead streams and the cooled stream 70 in the present configuration either. Thus, there do not need to be any expansion devices between the Cl overhead stream 20 and the at least partly liquefied cooled stream 71. By avoiding the need for such a reduction in pressure of the streams, the cooled stream is further cooled against at least a fraction of the cooled hydrocarbon stream at a higher pressure compared to other systems in which one or more pressure reductions are carried out. At such higher pressures, the latent heat required to provide the at least partly liquefied cooled stream is believed to be lower, leading to a more efficient further cooling operation. Thus, the first pressure at which the Cl overhead stream is provided is also a beneficial pressure for the further cooling of the cooled stream. Figure 3 shows an alternative scheme 4 according to another embodiment of the present invention. Here, the cooling of the at least the fraction of the at least one of the group defined in step (d) - the group comprising the C2 overhead stream, the C3 overhead stream, and the C4 overhead stream - is effected by indirect heat exchange with the Cl overhead stream 20, which does not require admixing with the Cl overhead stream 20. After having been warmed by the indirect heat exchange, the Cl overhead stream 20a may be used, for instance, as fuel gas.
In the arrangement shown in Figure 3, the initial feed stream 7 containing natural gas is cooled by three pre-cooling heat exchangers 14a, 14b, 14c to provide a cooled and partially condensed initial hydrocarbon stream 8, which passes directly into the main heat exchanger 112 to provide a further cooled initial hydrocarbon stream 18a.
The further cooled hydrocarbon stream 18a passes into a separator 240 to provide, as a bottom stream, a mixed hydrocarbon feed stream 10 which can then pass into an NGL recovery system 1 as described above to provide a Cl overhead stream 20, a second C2 fraction 45, a second C3 fraction 55 and a second C4 fraction 65 as herein before described.
The second C2, C3 and C4 fractions 45, 55, 65 are combined to form a combined stream 242 which passes into a fourth heat exchanger 244. Also passing into the fourth heat exchanger 244 is the Cl overhead stream 20, which, being cooler, provides cooling to the combined stream 242 to provide a warmed Cl overhead stream 20a, and a cooled stream 70a. The fourth heat exchanger 244 is one means to cool said fraction (s).
The warmed Cl overhead stream 20a can be combined with one or more other methane-predominant streams, such as a compressed end-flash gas stream 136, for use as a fuel stream 139a. Meanwhile, the cooled stream 70a passes through a heat exchanger 122a to provide an at least partly liquefied cooled stream 71a, which can be passed through a valve 124, and optionally combined with a liquefied side stream 206c as described hereinbefore, to provide a reduced pressure combined stream 72a which can then pass into an end-flash vessel 118.
The main overhead fraction 206b from the separator 240 is at least partially, preferably fully, condensed in the main heat exchanger 112 to provide a cooled, preferably liquefied, hydrocarbon stream 120. The cooled hydrocarbon stream 120 passes through a third heat exchanger 212, expander 214 and a valve 216, to provide an end-feed stream 222 which passes into an end-flash vessel 118. Table 1 below gives an overview of estimated compositions, phases, pressures and temperatures of some of the streams at various parts of an example process of the arrangement shown in Figure 2. Table 1
Figure imgf000028_0001
V=vapour, L=liquid
The person skilled in the art will understand that the present invention can be carried out in many various ways without departing from the scope of the appended claims .

Claims

C L A I M S
1. A method of cooling a hydrocarbon stream, comprising at least the steps of:
(a) passing an initial hydrocarbon stream through a first separator to provide an initial overhead stream and a mixed hydrocarbon feed stream;
(b) cooling the initial overhead stream to provide a cooled hydrocarbon stream such as LNG;
(c) separating at least a Cl overhead stream at a first pressure and one or more C2, C3 and C4 overhead streams from the mixed hydrocarbon feed stream;
(d) cooling at least a fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; by admixing with the Cl overhead stream, to provide a cooled stream; and (e) further cooling the cooled stream against at least a fraction of the cooled hydrocarbon stream to provide an at least partly liquefied cooled stream at a second pressure, which is substantially the same as the first pressure .
2. A method as claimed in Claim 1, wherein the cooling in step (b) comprises liquefying, whereby the cooled hydrocarbon stream is a liquefied hydrocarbon stream.
3. A method as claimed in Claim 1 or Claim 2, wherein said further cooling of step (e) comprises sub-cooling of the cooled stream, whereby the at least partly liquefied cooled stream is a sub-cooled liquefied stream.
4. A method as claimed in one or more of the preceding claims, wherein the at least the fraction of the cooled hydrocarbon stream is end-flash gas.
5. A method as claimed in one or more of the preceding claims, wherein the at least partly liquefied cooled stream is subsequently combined with at least a fraction of the cooled hydrocarbon stream.
6. A method as claimed in one or more of the preceding claims, wherein the at least partly liquefied cooled stream is within 400C, preferably within 100C, of the at least a fraction of the cooled hydrocarbon stream of step (e) .
7. A method as claimed in one or more of the preceding claims, wherein step (d) comprises at least the steps of: (i) passing at least a fraction of the mixed hydrocarbon feed stream into a first distillation column to provide a Cl overhead stream and a first bottom stream; (ϋ) passing at least a fraction of the first bottom stream into at least one of the group comprising: second, third and fourth distillation columns; to provide at least one of the group comprising: a C2 overhead stream and a C3 overhead stream and a C4 overhead stream.
8. A method as claimed in one or more of the preceding claims, further comprising providing a first distillation column, second distillation column, a third distillation column, and a fourth distillation column, to provide the Cl overhead stream, and a C2 overhead stream, a C3 overhead stream and a C4 overhead stream, respectively.
9. A method as claimed in claim 8, wherein at least a fraction of each of the C2 overhead stream, the C3 overhead stream and the C4 overhead stream is cooled by the Cl overhead stream.
10. A method as claimed in one or more of the preceding Claims, wherein the cooled stream has a temperature below 00C.
11. A method as claimed in one or more of the preceding claims, wherein the hydrocarbon stream consists essentially of natural gas, to provide LNG.
12. A method as claimed in one or more of the preceding claims, wherein the Cl overhead stream is part of the cooled stream.
13. Apparatus for cooling a hydrocarbon stream, comprising at least: a first separator through which an initial hydrocarbon stream passes to provide an initial overhead stream and a mixed hydrocarbon feed stream; a cooling system to cool the initial overhead stream to provide a cooled hydrocarbon stream; an NGL recovery system to separate at least a Cl overhead stream and one or more C2, C3 and C4 overhead streams from the mixed hydrocarbon feed stream; a combiner to cool at least a fraction of at least one of the group comprising: the C2 overhead stream, the C3 overhead stream and the C4 overhead stream; by admixing with the Cl overhead stream to provide a cooled stream; one or more heat exchangers for further cooling the cooled stream against at least a fraction of the cooled hydrocarbon stream to provide an at least partly liquefied cooled stream; and wherein there are no expansion or compression devices between the Cl overhead stream and the at least partly liquefied cooled stream.
14. A liquefied natural gas plant or facility including apparatus as defined in claim 13.
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