WO2009085048A1 - Dynamic leak control for system with working fluid - Google Patents

Dynamic leak control for system with working fluid Download PDF

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Publication number
WO2009085048A1
WO2009085048A1 PCT/US2007/089041 US2007089041W WO2009085048A1 WO 2009085048 A1 WO2009085048 A1 WO 2009085048A1 US 2007089041 W US2007089041 W US 2007089041W WO 2009085048 A1 WO2009085048 A1 WO 2009085048A1
Authority
WO
WIPO (PCT)
Prior art keywords
pressure
set forth
threshold
heat source
sensor
Prior art date
Application number
PCT/US2007/089041
Other languages
French (fr)
Inventor
Lance D. Woolley
Sean P. Breen
Original Assignee
Utc Power Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Utc Power Corporation filed Critical Utc Power Corporation
Priority to PCT/US2007/089041 priority Critical patent/WO2009085048A1/en
Priority to US12/810,239 priority patent/US8555912B2/en
Priority to EP07866080.0A priority patent/EP2235331A4/en
Publication of WO2009085048A1 publication Critical patent/WO2009085048A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/08Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
    • F01K25/10Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K13/00General layout or general methods of operation of complete plants
    • F01K13/02Controlling, e.g. stopping or starting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/0318Processes
    • Y10T137/0391Affecting flow by the addition of material or energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/7722Line condition change responsive valves
    • Y10T137/7758Pilot or servo controlled

Definitions

  • This disclosure relates generally to closed loop systems with a pressurized working fluid, and, more particularly, to a method and apparatus for preventing the migration of contaminant gases into the system during shut down.
  • Closed loop systems often contain a working fluid with properties specific to the successful or efficient operation of the equipment.
  • the working fluid properties may be degraded by the addition of foreign particles.
  • Closed loop systems generally operate at elevated pressures relative to ambient pressure. This ensures that leaks propagate out of the system during operation. During system shutdown, this scenario may be reversed with the closed loop system pressure at or below ambient pressure. As a result, molecules such as oxygen and nitrogen may migrate into the system. These pollute the working fluid and negatively impact the subsequent operation and efficiency of the system.
  • related systems require a purge device that extracts the system pollutants from the working fluid.
  • One such closed loop system is that of an organic rankinc cycle system which includes in serial flow relationship, an evaporator or boiler, a turbine, a condenser and a pump.
  • an organic rankinc cycle system which includes in serial flow relationship, an evaporator or boiler, a turbine, a condenser and a pump.
  • Such a system is shown and described in US Patent 7,174,716, assigned to the predecessor of the assignee of the present invention.
  • a heat source is opcrativcly connected to the evaporator and has a control which is responsive to a condition sensor for maintaining the pressure in the system above a predetermined threshold.
  • a process of preventing migration of impurities into a closed loop system during shut down includes the steps of sensing the pressure in the system and responsively operating a heat source so as to maintain the pressure in the system above a predetermined threshold.
  • FIG. 1 is a schematic illustration of an organic rankine cycle system with the present invention incorporated therein.
  • FIG. 2 is a graphical illustration of the manner in which the pressure is controlled in accordance with the present invention.
  • FIG. 3 is a schematic illustration of an organic rankine cycle system with a modified embodiment of the present invention incorporated therein.
  • Fig. 1 Shown in Fig. 1 is an organic rankine cycle system which includes, in serial working-fluid-flow relationship, an evaporator 1 1, a turbine 12, a condenser 13 and a pump 14.
  • the working fluid flowing therethrough can be of any suitable refrigerant such as refrigerant R-245fa, R134, pentane, for example.
  • 0011 J The energy which is provided to drive the system is from of a primary heat source 16 by way of a closed loop which connects to the evaporator 1 1 by way of lines 17 and 18.
  • a valve 20 is provided to turn this flow on or off and may be located either upstream or downstream from the heat exchanger 16.
  • the primary heat source 16 may be of various types such as, for example a geothermal source, wherein naturally occurring hot fluids are available below the surface of the earth.
  • The' temperatures of such geothermal sources are generally greater than 150- F, sufficient to operate most working fluids well above atmospheric pressure.
  • the turbine 12 is drivingly attached to a generator 19 for generating electrical power that then passes to the grid 21 for further distribution.
  • the working fluid After passing to the turbine 12, the working fluid, which is now a vapor which is at a reduced temperature and pressure vapor, passes to the condenser 13, which is fluidly connected to a cooling water source 22 by lines 23 and 24.
  • the condenser 13 functions to condense the working fluid vapor into a liquid, which then flows along line 26 to the pump 14, which then pumps the liquid working fluid back to the evaporator 1 1 by way of line 27.
  • a sensor 27 is provided to sense a condition indicative of pressure in the system, such as the temperature or pressure within the evaporator 11, and to send a responsive signal along line 28 to a control 29.
  • Control 29 is connected by a line 31 to a valve 32 with the valve 32 then being operated by the control 29 in response to the sensed temperature/pressure in such a manner as to maintain the temperature/pressure in the evaporator 1 1 at a level which will remain above the ambient pressure/temperature and therefore prevent the migration of unwanted gases into the system during periods of shut down.
  • the pressure within the system is shown as a function of time in which the system is operating normally and then is shut down, with the present invention then operating to prevent migration of the gases into the system.
  • ⁇ s will be seen, at time t
  • a second threshold of pressure equals P 2 and the control 20 then rcsponsivcly moves the valve 32 to a fully closed or at least a partially closed position.
  • the pressure of the system is then gradually reduced such that at time t$ it again reaches the lower threshold of P 3 wherein the control 29 again opens the valve 32 to add heat to the system.
  • the control again moves the valve 32 to a more closed position. This cycle is repeated so as to maintain the system at a pressure above that of ambient so that migration of gases into the system is prevented during shut down.
  • the control 29 remains in an inactive condition until called on to be activated by the sensor 27 when, for example, the system is again shut down.
  • FIG. 3 An alterative embodiment is shown in Fig. 3 wherein a sensor 33 senses the pressure within the condenser 13 rather than within the evaporator 1 1.
  • a sensor 33 senses the pressure within the condenser 13 rather than within the evaporator 1 1.
  • the pressures in the evaporator 1 1 and in the condenser 13 tend toward equalization since they are only separated on one side by the pump 14 which provides nearly complete restriction between the two, and on the other side by the turbine 12 which provides only a partial restriction between the two tanks.
  • a supplementary heat source 36 rather than the primary heat source 16 during periods of shut down.
  • a supplementary heat source might be steam or hot water from a source other than the primary heat source 16, or it may be by way of an electrical resistance heater.
  • the sensor 33 s sends a signal to the control 34 which then responsivcly operates the supplementary heat source 36 to maintain the pressure in the system above the ambient pressure during shut down.
  • As another alterative, Io ensure that the two tanks i.e. the evaporator

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)

Abstract

An organic rankine cycle system includes a sensor for sensing a condition indicative of pressure within the system and a control which responsively provides heat to said system when the pressure within the system is sensed to be at a predetermined threshold, near ambient pressure, during periods in which the system is shut down or preparing to operate. Provision is also made to remove the heat from the system when the pressure therein rises to a predetermined higher pressure threshold.

Description

Dynamic Leak Control for System with Working Fluid
Technical Field
[0001] This disclosure relates generally to closed loop systems with a pressurized working fluid, and, more particularly, to a method and apparatus for preventing the migration of contaminant gases into the system during shut down.
Background of the Disclosure
|0002] Closed loop systems often contain a working fluid with properties specific to the successful or efficient operation of the equipment. The working fluid properties may be degraded by the addition of foreign particles. Closed loop systems generally operate at elevated pressures relative to ambient pressure. This ensures that leaks propagate out of the system during operation. During system shutdown, this scenario may be reversed with the closed loop system pressure at or below ambient pressure. As a result, molecules such as oxygen and nitrogen may migrate into the system. These pollute the working fluid and negatively impact the subsequent operation and efficiency of the system. Currently, related systems require a purge device that extracts the system pollutants from the working fluid. [0003] One such closed loop system is that of an organic rankinc cycle system which includes in serial flow relationship, an evaporator or boiler, a turbine, a condenser and a pump. Such a system is shown and described in US Patent 7,174,716, assigned to the predecessor of the assignee of the present invention.
Disclosure
[0004J In accordance with one aspect of the disclosure, a heat source is opcrativcly connected to the evaporator and has a control which is responsive to a condition sensor for maintaining the pressure in the system above a predetermined threshold.
]0005| In accordance with another aspect of the disclosure, a process of preventing migration of impurities into a closed loop system during shut down includes the steps of sensing the pressure in the system and responsively operating a heat source so as to maintain the pressure in the system above a predetermined threshold.
|0006| In the drawings as hereinafter described, a preferred embodiment is depicted; however, various other modifications and alternate constructions can be made thereto without departing from the spirit and scope of the disclosure.
Brief Description of the Drawings
[0007) FIG. 1 is a schematic illustration of an organic rankine cycle system with the present invention incorporated therein.
[0008| FIG. 2 is a graphical illustration of the manner in which the pressure is controlled in accordance with the present invention.
[0009] FIG. 3 is a schematic illustration of an organic rankine cycle system with a modified embodiment of the present invention incorporated therein.
Detailed Description of the Disclosure
|0010| Shown in Fig. 1 is an organic rankine cycle system which includes, in serial working-fluid-flow relationship, an evaporator 1 1, a turbine 12, a condenser 13 and a pump 14. The working fluid flowing therethrough can be of any suitable refrigerant such as refrigerant R-245fa, R134, pentane, for example. |0011 J The energy which is provided to drive the system is from of a primary heat source 16 by way of a closed loop which connects to the evaporator 1 1 by way of lines 17 and 18. A valve 20 is provided to turn this flow on or off and may be located either upstream or downstream from the heat exchanger 16. The primary heat source 16 may be of various types such as, for example a geothermal source, wherein naturally occurring hot fluids are available below the surface of the earth. The' temperatures of such geothermal sources are generally greater than 150- F, sufficient to operate most working fluids well above atmospheric pressure. |0012] After the working fluid is heated in the evaporator 1 1, it passes as a high temperature, high pressure vapor to the turbine 12 where the energy is converted to motive power. The turbine 12 is drivingly attached to a generator 19 for generating electrical power that then passes to the grid 21 for further distribution. {0013( After passing to the turbine 12, the working fluid, which is now a vapor which is at a reduced temperature and pressure vapor, passes to the condenser 13, which is fluidly connected to a cooling water source 22 by lines 23 and 24. The condenser 13 functions to condense the working fluid vapor into a liquid, which then flows along line 26 to the pump 14, which then pumps the liquid working fluid back to the evaporator 1 1 by way of line 27.
10014| During normal operation of the above described organic rankine cycle system, because of the energy added by the primary heat source 16, the working fluid always remains at a pressure substantially greater than ambient pressure. However, during selected periods of time, such as during oil warm up or when the system is shut down, such as, for example, during periods of maintenance and/or repair, then the working fluid therein slowly cools and eventually may reach ambient temperature. At this point, because of the thermodynamic properties of the working fluid that relates temperature and pressure of a saturated system, the pressure within the system will tend to further decrease to a level below ambient pressure. This low pressure condition will then allow the migration of contaminating gases, such as oxygen and/or nitrogen, to migrate into the system from the atmosphere. The present disclosure is intended to prevent such a migration from occurring.
[0015| In one form of the disclosure, a sensor 27 is provided to sense a condition indicative of pressure in the system, such as the temperature or pressure within the evaporator 11, and to send a responsive signal along line 28 to a control 29. Control 29 is connected by a line 31 to a valve 32 with the valve 32 then being operated by the control 29 in response to the sensed temperature/pressure in such a manner as to maintain the temperature/pressure in the evaporator 1 1 at a level which will remain above the ambient pressure/temperature and therefore prevent the migration of unwanted gases into the system during periods of shut down. [0016| Referring now to Fig. 2, the pressure within the system is shown as a function of time in which the system is operating normally and then is shut down, with the present invention then operating to prevent migration of the gases into the system. [0017] Λs will be seen, at time t| the system is operating normally such that the pressure is at Pi. Further, at time t2, the system is shut down and the pressure begins to decline, and at time tj, reaches a threshold level of Pj, which is lightly above the anticipated ambient pressure P4 for the environment of the warming system. When this threshold pressure is reached, the sensor 27 signals the control 29 which then opens the valve 32 to provide heat to the evaporator 1 1 to thereby cause the pressure in the system to be gradually increased.
[0018] At time U. a second threshold of pressure equals P2 and the control 20 then rcsponsivcly moves the valve 32 to a fully closed or at least a partially closed position. The pressure of the system is then gradually reduced such that at time t$ it again reaches the lower threshold of P3 wherein the control 29 again opens the valve 32 to add heat to the system. At time tή, the control again moves the valve 32 to a more closed position. This cycle is repeated so as to maintain the system at a pressure above that of ambient so that migration of gases into the system is prevented during shut down. When normal operation resumes, the control 29 remains in an inactive condition until called on to be activated by the sensor 27 when, for example, the system is again shut down.
[0019] An alterative embodiment is shown in Fig. 3 wherein a sensor 33 senses the pressure within the condenser 13 rather than within the evaporator 1 1. In this regard, it is recognized that during the period following shut down, the pressures in the evaporator 1 1 and in the condenser 13 tend toward equalization since they are only separated on one side by the pump 14 which provides nearly complete restriction between the two, and on the other side by the turbine 12 which provides only a partial restriction between the two tanks.
|0020| Another alterative is to use a supplementary heat source 36 rather than the primary heat source 16 during periods of shut down. Such a supplementary heat source might be steam or hot water from a source other than the primary heat source 16, or it may be by way of an electrical resistance heater. Similar to the Fig. 1 embodiment, the sensor 33s sends a signal to the control 34 which then responsivcly operates the supplementary heat source 36 to maintain the pressure in the system above the ambient pressure during shut down. |002J| As another alterative, Io ensure that the two tanks i.e. the evaporator
1 1 and the condenser 13, are maintained at substantially the same pressure during pressure shut down, the two may be selectively fluidly interconnected by way of a line 37 and valve 38, with the valve 38 being controlled by way of the control 34. |0022| While the present invention has been particularly shown and described with reference to preferred and modified embodiments as illustrated in the drawings, it will be understood by one skilled in the art that various changes in detail may be made thereto without departing from the spirit and scope of the disclosure as defined by the claims.

Claims

Wc Claim:
1. A method of preventing migration of gases into a closed loop organic rankine cycle system during selected periods of time comprising the steps of: establishing a threshold pressure to be maintained in the system in order to prevent migration of gases thereinto when the system is in a shut down condition; providing a sensor for sensing a characteristic indicative of the pressure within the system during such periods; and wherein said threshold pressure is sensed, providing heat to said system to cause the pressure therein to rise above the threshold pressure so as to prevent migration of gases into the system.
2. A method as set forth in claim 1 wherein said sensor is a pressure sensor.
3. A method as set forth in claim 1 wherein the condition sensed is in the evaporator of the system.
4. A method as set forth in claim 1 wherein said established threshold is above the anticipated external or ambient pressure relative to the system.
5. A method as set forth in claim 4 wherein said threshold pressure is slightly above the anticipated external or ambient pressure rcalative to the system.
6. A method as set forth in claim 1 wherein the step of providing heat is by way of a primary heat source, which is a heat source used during normal operation of the organic rankine cycle system.
7. A method as set forth in claim 1 wherein the step of providing heal to the system is by way of a secondary heat source, which is separate from the heat source used in the norma] operation of the organic rankine cycle system.
8. A method as set forth in claim 1 and including the further steps of: establishing a second higher threshold pressure; and when the sensed pressure in the system reaches said second higher threshold, removing heat from the system.
9. A method as set forth in claim 1 wherein the condition sensed is in the condenser.
10. A method as set forth in claim 1 and including the further step of fluidly interconnecting an evaporator and a condenser of the system when said threshold pressure is sensed.
1 1. An apparatus for preventing migration of gases into a closed loop organic rankine cycle system during periods of shut down, comprising: a sensor for sensing a condition indicative of pressure within the system during period of shut down; a heater for selectively providing heat to said system during periods of shut down; and a control responsive to said sensor to cause said heater to provide heat to said system when (he sensed pressure reaches a predetermined lower threshold level.
12. An apparatus as set forth in claim 11 wherein said sensor is a pressure sensor.
13. An apparatus as set forth in claim 11 wherein said sensor is connected to sense the condition within the evaporator.
14. An apparatus as set forth in claim 11 wherein said predetermined lower threshold is a pressure above the anticipated ambient pressure of the system.
15. An apparatus as set forth in claim 4 wherein said threshold is slightly above the anticipated ambient pressure of the system.
16. An apparatus as sel forth in claim 11 wherein said heat source comprises a primary heat source that is used during normal operation of the organic rankine cycle system.
17. An apparatus as set forth in claim 1 1 wherein said heat source is a secondary heat source which is different from a primary heat source which is used for normal operation of the organic rankine cycle system.
18. An apparatus as set forth in claim 1 1 wherein said control is responsive to a second threshold, higher than said first threshold, for removing the heat from said system.
19. An apparatus as set forth in claim 1 1 wherein said condition sensed is in the condenser of the system.
20. An apparatus as set forth in claim 1 1 and including a fluid connection between a condenser and an evaporator of the organic rankine cycle system made response to the control when said first threshold is sensed.
PCT/US2007/089041 2007-12-28 2007-12-28 Dynamic leak control for system with working fluid WO2009085048A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
PCT/US2007/089041 WO2009085048A1 (en) 2007-12-28 2007-12-28 Dynamic leak control for system with working fluid
US12/810,239 US8555912B2 (en) 2007-12-28 2007-12-28 Dynamic leak control for system with working fluid
EP07866080.0A EP2235331A4 (en) 2007-12-28 2007-12-28 Dynamic leak control for system with working fluid

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PCT/US2007/089041 WO2009085048A1 (en) 2007-12-28 2007-12-28 Dynamic leak control for system with working fluid

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WO2009085048A1 true WO2009085048A1 (en) 2009-07-09

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US8794002B2 (en) * 2009-09-17 2014-08-05 Echogen Power Systems Thermal energy conversion method
US8813497B2 (en) * 2009-09-17 2014-08-26 Echogen Power Systems, Llc Automated mass management control
US9845711B2 (en) * 2013-05-24 2017-12-19 Cummins Inc. Waste heat recovery system
US11187212B1 (en) 2021-04-02 2021-11-30 Ice Thermal Harvesting, Llc Methods for generating geothermal power in an organic Rankine cycle operation during hydrocarbon production based on working fluid temperature
US11480074B1 (en) 2021-04-02 2022-10-25 Ice Thermal Harvesting, Llc Systems and methods utilizing gas temperature as a power source
US11493029B2 (en) 2021-04-02 2022-11-08 Ice Thermal Harvesting, Llc Systems and methods for generation of electrical power at a drilling rig
US11592009B2 (en) 2021-04-02 2023-02-28 Ice Thermal Harvesting, Llc Systems and methods for generation of electrical power at a drilling rig
US11644015B2 (en) 2021-04-02 2023-05-09 Ice Thermal Harvesting, Llc Systems and methods for generation of electrical power at a drilling rig
US11326550B1 (en) 2021-04-02 2022-05-10 Ice Thermal Harvesting, Llc Systems and methods utilizing gas temperature as a power source
US11421663B1 (en) 2021-04-02 2022-08-23 Ice Thermal Harvesting, Llc Systems and methods for generation of electrical power in an organic Rankine cycle operation
US11293414B1 (en) 2021-04-02 2022-04-05 Ice Thermal Harvesting, Llc Systems and methods for generation of electrical power in an organic rankine cycle operation
US11486370B2 (en) 2021-04-02 2022-11-01 Ice Thermal Harvesting, Llc Modular mobile heat generation unit for generation of geothermal power in organic Rankine cycle operations

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US8555912B2 (en) 2013-10-15
US20110000552A1 (en) 2011-01-06
EP2235331A4 (en) 2014-01-08
EP2235331A1 (en) 2010-10-06

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