WO2009060721A1 - Method for cutting carbon nonotube - Google Patents

Method for cutting carbon nonotube Download PDF

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Publication number
WO2009060721A1
WO2009060721A1 PCT/JP2008/069177 JP2008069177W WO2009060721A1 WO 2009060721 A1 WO2009060721 A1 WO 2009060721A1 JP 2008069177 W JP2008069177 W JP 2008069177W WO 2009060721 A1 WO2009060721 A1 WO 2009060721A1
Authority
WO
WIPO (PCT)
Prior art keywords
cnt
mask
molecules
solvent
cutting
Prior art date
Application number
PCT/JP2008/069177
Other languages
French (fr)
Japanese (ja)
Inventor
Masako Yudasaka
Tsutomu Yoshitake
Sumio Iijima
Original Assignee
Nec Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nec Corporation filed Critical Nec Corporation
Publication of WO2009060721A1 publication Critical patent/WO2009060721A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/168After-treatment
    • C01B32/174Derivatisation; Solubilisation; Dispersion in solvents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/168After-treatment
    • C01B32/176Cutting

Abstract

Monodispersing CNT in a solvent is necessary for expanding the application of carbon nanotubes (hereinafter referred to as CNT) as a material. Long CNTs produced, for example, by CVD are disadvantageously aggregated with each other to form a bundle by intermolecular attractive force, and, thus, monodispersing CNT in a solvent is difficult. Therefore, the long CNT should be cut into short sizes. Accordingly, the present invention provides a method for cutting CNT, which is excellent in mass producibility and can cut CNT while controlling the length of CNT. The method for cutting CNT is characterized by comprising a covering step of mixing CNT with molecules for a mask in a solvent to cover places of CNT with the molecules for a mask, and an oxidation step of heating the CNT covered with the molecules for a mask in a hydrogen peroxide solution while applying light to allow CNT in its parts not covered with the molecules for a mask to disappear by oxidation.
PCT/JP2008/069177 2007-11-05 2008-10-23 Method for cutting carbon nonotube WO2009060721A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007287255 2007-11-05
JP2007-287255 2007-11-05

Publications (1)

Publication Number Publication Date
WO2009060721A1 true WO2009060721A1 (en) 2009-05-14

Family

ID=40625620

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/069177 WO2009060721A1 (en) 2007-11-05 2008-10-23 Method for cutting carbon nonotube

Country Status (1)

Country Link
WO (1) WO2009060721A1 (en)

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003012313A (en) * 2001-06-26 2003-01-15 Kansai Tlo Kk Carbon nanotube with protective cover
JP2004043258A (en) * 2002-07-15 2004-02-12 National Institute Of Advanced Industrial & Technology Method of cutting carbon nanotube
JP2004058194A (en) * 2002-07-26 2004-02-26 Fujikura Ltd Working process of carbon nanotube
JP2004210608A (en) * 2003-01-06 2004-07-29 Japan Science & Technology Agency Method of selecting carbon nanotube structure by light irradiation
JP2004319211A (en) * 2003-04-15 2004-11-11 Noritake Co Ltd Manufacturing method of electron emission source
JP2005502572A (en) * 2001-09-06 2005-01-27 ロゼッター、ホールディングス、リミテッド Nanoparticle and nanotube production apparatus and production method, and their use for gas storage
JP2005059147A (en) * 2003-08-13 2005-03-10 National Institute Of Advanced Industrial & Technology Cutting method and cutting device of carbon nanotube
JP2005191214A (en) * 2003-12-25 2005-07-14 Fuji Xerox Co Ltd Method of manufacturing ultra-fine electronic device
JP2005522398A (en) * 2002-04-08 2005-07-28 ウィリアム・マーシュ・ライス・ユニバーシティ Method for cutting single-walled carbon nanotubes via fluorination
JP2005251698A (en) * 2004-03-08 2005-09-15 Mitsubishi Electric Corp Cold cathode and manufacturing method thereof
JP2007112706A (en) * 2005-10-18 2007-05-10 Samsung Sdi Co Ltd Method of cutting carbon nanotube, carbon nanotube, field emitter, catalyst support and mixed material of carbon nanotube

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003012313A (en) * 2001-06-26 2003-01-15 Kansai Tlo Kk Carbon nanotube with protective cover
JP2005502572A (en) * 2001-09-06 2005-01-27 ロゼッター、ホールディングス、リミテッド Nanoparticle and nanotube production apparatus and production method, and their use for gas storage
JP2005522398A (en) * 2002-04-08 2005-07-28 ウィリアム・マーシュ・ライス・ユニバーシティ Method for cutting single-walled carbon nanotubes via fluorination
JP2004043258A (en) * 2002-07-15 2004-02-12 National Institute Of Advanced Industrial & Technology Method of cutting carbon nanotube
JP2004058194A (en) * 2002-07-26 2004-02-26 Fujikura Ltd Working process of carbon nanotube
JP2004210608A (en) * 2003-01-06 2004-07-29 Japan Science & Technology Agency Method of selecting carbon nanotube structure by light irradiation
JP2004319211A (en) * 2003-04-15 2004-11-11 Noritake Co Ltd Manufacturing method of electron emission source
JP2005059147A (en) * 2003-08-13 2005-03-10 National Institute Of Advanced Industrial & Technology Cutting method and cutting device of carbon nanotube
JP2005191214A (en) * 2003-12-25 2005-07-14 Fuji Xerox Co Ltd Method of manufacturing ultra-fine electronic device
JP2005251698A (en) * 2004-03-08 2005-09-15 Mitsubishi Electric Corp Cold cathode and manufacturing method thereof
JP2007112706A (en) * 2005-10-18 2007-05-10 Samsung Sdi Co Ltd Method of cutting carbon nanotube, carbon nanotube, field emitter, catalyst support and mixed material of carbon nanotube

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
LIU J. ET AL., FULLERENE PIPES, SCIENCE, vol. 280, 22 May 1998 (1998-05-22), pages 1253 - 1256 *
YUDASAKA M. ET AL.: "Diameter-selective removal of single-wall carbon nanotubes through light- assisted oxidation", CHEMICAL PHYSICS LETTERS, vol. 374, no. 1-2, 4 June 2003 (2003-06-04), pages 132 - 136 *
ZHANG M. ET AL.: "Changes in the Fluorescence Spectrum of Individual Single-Wall Carbon Nanotubes Induced by Light-Assisted Oxidation with Hydroperoxide", THE JOURNAL OF PHYSICAL CHEMISTRY B, vol. 110, no. 18, 11 May 2006 (2006-05-11), pages 8935 - 8940 *

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