WO2009047496A2 - Cement compositions comprising a high-density particulate elastomer and associated methods - Google Patents
Cement compositions comprising a high-density particulate elastomer and associated methods Download PDFInfo
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- WO2009047496A2 WO2009047496A2 PCT/GB2008/003402 GB2008003402W WO2009047496A2 WO 2009047496 A2 WO2009047496 A2 WO 2009047496A2 GB 2008003402 W GB2008003402 W GB 2008003402W WO 2009047496 A2 WO2009047496 A2 WO 2009047496A2
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- elastomer
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- particulate elastomer
- cement composition
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
- C09K8/424—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells using "spacer" compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/28—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/288—Halogen containing polymers
Definitions
- the present invention relates to subterranean treatment fluids and associated methods. More specifically, in certain embodiments, the present invention relates to cement compositions that comprise a particulate elastomer having a specific gravity of at least about 1.05 and associated methods.
- Cement compositions are one type of subterranean treatment fluid that may be used in a variety of subterranean applications.
- a pipe string e.g., casing, liners, expandable tubulars, etc.
- the process of cementing the pipe string in place is commonly referred to as "primary cementing.”
- primary cementing In a typical primary cementing method, a cement composition may be pumped into an annulus between the walls of the well bore and the exterior surface of the pipe string disposed therein.
- the cement composition sets in the annular space, thereby forming an annular sheath of hardened, substantially impermeable cement (i.e., a cement sheath) that may support and position the pipe string in the well bore and may bond the exterior surface of the pipe string to the subterranean formation.
- a cement sheath the cement sheath surrounding the pipe string functions to prevent the migration of fluids in the annulus, as well as protecting the pipe string from corrosion.
- Cement compositions also may be used in remedial cementing methods, for example, to seal cracks or holes in pipe strings or cement sheaths, to seal highly permeable formation zones or fractures, to place a cement plug, and the like.
- Cement compositions also may be used in surface applications, for example, construction cementing.
- the cement sheath may be subjected to a variety of cyclic, shear, tensile, impact, fiexural, and/or compressive stresses that may lead to failure of the cement sheath, resulting, for example, in fractures, cracks, and/or debonding of the cement sheath from the pipe string and/or the formation. This may lead to undesirable consequences such as lost production, environmental pollution, hazardous rig operations resulting from unexpected fluid flow from the formation caused by the loss of zonal isolation, and/or hazardous production operations. Furthermore, failure of the cement sheath also may be caused by forces exerted by shifts in subterranean formations surrounding the well bore, cement erosion, and repeated impacts from the drill bit and the drill pipe.
- various additives may be included in the cement composition to enable the cement composition to withstand cyclic changes in imposed stresses.
- hydrocarbon-based elastomers e.g., styrene-butadiene random and block copolymers, acrylonitrile-butadiene, and acrylonitrile-styrene-butadiene elastomers
- styrene-butadiene random and block copolymers acrylonitrile-butadiene, and acrylonitrile-styrene-butadiene elastomers
- such materials are used in the particulate form.
- the term "particulate” refers to materials in solid state having a well-defined physical shape as well as those with irregular geometries, including any particulates elastomers having the physical shape of platelets, shavings, fibers, flakes, ribbons, rods, strips, spheroids, hollow beads, toroids, pellets, tablets, or any other physical shape.
- the particulate elastomers may function to control shrinkage cracking in the early stages of the cement setting process, and also may provide resiliency, ductility, expansion, and toughness to the set cement composition ⁇ e.g., the cement sheath) so that it resists and seals cracking or fracturing.
- particulate elastomers used heretofore generally have a density equal to or less than water. Accordingly, these particulate elastomers may be particularly suited for use in lower-density cement compositions.
- These low-density particulate elastomers have also been used in higher-density cement compositions (e.g., greater than about 15 pounds per gallon), as no suitable higher-density particulate elastomers have been available.
- heavyweight additives may need to be used to compensate for the low-density particulate elastomers.
- concentration of the heavyweight additives that may be needed to compensate for the low-density particulate elastomers may undesirably affect certain properties of the cement compositions, such as its mixability and rheology.
- the present invention relates to subterranean treatment fluids and associated methods. More specifically, in certain embodiments, the present invention relates to cement compositions that comprise a particulate elastomer having a specific gravity of at least about 1.05 and associated methods.
- the present invention provides a method of treating a subterranean formation comprising: introducing a treatment fluid into a well bore, wherein the treatment fluid comprises a particulate elastomer having a specific gravity of at least about 1.6.
- the present invention provides a method of treating a subterranean formation comprising: introducing a treatment fluid into a well bore, wherein the treatment fluid comprises a particulate elastomer having a specific gravity of at least about 1.05, wherein the particulate elastomer comprise a halogenated thermoplastic.
- the present invention provides a treatment fluid comprising a particulate elastomer having a specific gravity of at least about 1.6.
- the present invention provides a treatment fluid comprising a particulate elastomer having a specific gravity of at least about 1.05, wherein the particulate elastomer comprises a halogenated thermoplastic.
- the present invention relates to subterranean treatment fluids and associated methods. More specifically, in certain embodiments, the present invention relates to cement compositions that comprise a particulate elastomer having a specific gravity of at least about 1.05 and associated methods. As used herein, a particulate elastomer having a specific gravity of at least about 1.05 will be referred to as a "high-density particulate elastomer.”
- the cement compositions of the present invention generally comprise cement, water, and a high-density particulate elastomer.
- the cement compositions of the present invention generally should have a density suitable for a particular application.
- the cement compositions of the present invention may have a density in the range of about 4 pounds per gallon ("lb/gal") to about 24 lb/gal.
- the cement compositions of the present invention have a density in the range of about 8 lb/gal to about 19 lb/gal.
- Embodiments of the cement compositions may be foamed or unfoamed or may comprise other means to reduce their densities, such as hollow microspheres, low-density elastic beads, or other density-reducing additives known in the art.
- embodiments of the cement composition may comprise heavyweight additives (e.g., hematite, magnesium oxide, etc.).
- heavyweight additives e.g., hematite, magnesium oxide, etc.
- the cement compositions of the present invention comprise a hydraulic cement.
- hydraulic cements that may be used include, but are not limited to, those that comprise calcium, aluminum, silicon, oxygen, and/or sulfur, which set and harden by reaction with water. Examples include, but are not limited to, Portland cements, pozzolanic cements, gypsum cements, calcium-phosphate cements, high-alumina-content cements, silica cements, high-alkalinity cements, and mixtures thereof.
- the water utilized in the cement compositions of the present invention may be fresh water, salt water (e.g., water containing one or more salts dissolved therein), brine (e.g., saturated salt water), or seawater.
- the water may be from any source, provided that it should not contain an excess of compounds that may adversely affect other components in the cement composition.
- the water may be present in an amount sufficient to form a pumpable slurry.
- the water is present in the cement composition in an amount in the range of about 30% to about 180% by weight of the cement ("bwoc") therein.
- the water is present in the cement composition in the range of about 40% to about 90% bwoc, In certain embodiments, the water is present in the cement composition in the range of about 40% to about 60% bwoc.
- the water is present in the cement composition in the range of about 40% to about 60% bwoc.
- the cement compositions of the present invention further comprise a high- density particulate elastomer.
- the high-density particulate elastomer should generally provide the set cement composition a lower Young's modulus, higher recoverable elongation, greater resilience/toughness without unduly compromising its compressive strength. Accordingly, the set cement composition, at least in some instances, should be more able to withstand the stresses encountered in a downhole environment that may, for example, lead to failure of a cement sheath.
- the high-density particulate elastomer included in the cement compositions of the present invention is generally heavier than the particulate elastomers used heretofore, in that the particulate elastomers used heretofore generally have a density equal to or less than water, i.e., a specific gravity of about 1.0.
- a specific gravity of about 1.0 i.e., a specific gravity of about 1.0.
- the high-density particulate elastomer included in the cement compositions of the present invention has a specific gravity of at least about 1.05.
- the high-density particulate elastomer may have a specific gravity of at least about 1.1 (e.g., about 1.2, about 1.3, about 1 ,4, about 1,5, about 1.6, about 1.7, about 1.8, about 1.9, about 2.0, about 2.1, about 2.2, etc.).
- the high-density particulate elastomer may have a specific gravity of at least about 1.6.
- the high-density particulate elastomer may have a specific gravity of at least about 2.0.
- the high-density particulate elastomer may have a specific gravity of about 2.15.
- specific gravity of the particulate elastomer used increases, the amount of the heavyweight additive that may be needed to prepare a cement composition of a particular density decreases.
- any of a variety of high-density particulate elastomers having a specific gravity of at least about 1.05 may be included in the cement compositions of the present invention.
- suitable high-density particulate elastomers include, but are not limited to, particulate elastomers that comprise a thermoplastic.
- suitable thermoplastics include, but are not limited to, halogenated thermoplastics, such as fluoroplastics.
- Thermoplastics that do not comprise fluorine atoms may also be suitable for use, in certain embodiments.
- fluoroplastics may be characterized by their high chemical resistance, for example, it is believed that the fluoroplastics do not degrade in a carbon dioxide environment.
- the fluoroplastics generally should undergo negligible, if any, swelling when exposed to fluids (e.g., brines, hydrocarbons, etc.) downhole.
- fluoroplastics may be suitable for use in carbon sequestration applications.
- fluoroplastics generally may be characterized by their temperature stability. For example, fluoroplastics generally may retain their structural integrity at temperatures in excess of 600 0 F. Accordingly, while the fluoroplastics are suitable for use in applications having a wide variety of temperatures, they may be particularly suitable for use in high-temperature applications, such as those having a bottom hole circulating temperature ("BHCT") greater than about 600 0 F.
- BHCT bottom hole circulating temperature
- Fluoroplastics that are suitable for use in embodiments of the cement compositions of the present invention generally include thermoplastic polymers that comprise fluorine atoms.
- suitable fluoroplastics include, but are not limited to: fluorinated polymers of ethylene and propylene; polymers of tetrafluoroethylene and perfluorovinylether; polymers of tetrafluoroethylene and ethylene; polymers of tetrafluoroethylene and hexafluoropropylene; polymers of vinylidene fluoride; polymers of tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride; polytetrafluoroethylene (PTFE); perfluoroalkoxy polymer resin (PFA); chlorotrifluoroethylene (CTFE); fluorinated ethylene-propylene (FEP); polyethylenetetrafluoroethylene (ETFE); polyvinylfluoride (PVF); polyethylenechlorotriflu
- suitable fluoroplastics may also be used.
- suitable fluroplastics are available from: Dyneon, a 3M company, under the brandname DYNEON fluorpolymers; from Dupont, under the brandnames VITON ® fluoropolymers, TEFZEL ® fluropolymer resin, KALREZ ® FFKM, and TEDLAR ® polyvinly fluoride; Solvay Solexis, under the brandnames TECNOFLON ® fluoropolymers and HALAR ® ECTFE; Arkema Inc., under the brandname KYNAR ® PVDF; Daikin America, Inc. under the brandname NEOFLON ® fluoropolymers.
- thermoplastics that do not comprise fluorine atoms may be also be suitable for use in certain embodiments.
- suitable thermoplastics that do not comprise fluorine atoms include, but are not limited to, polyamide imide (PAI), polyetherether ketone (PEEK), polyphenylene sulfide (PPS), polyetherketone (PEK), and combinations thereof.
- the high-density particulate elastomer generally should be present in the cement compositions of the present invention in an amount sufficient to provide the desired mechanical properties, such as, for example, resiliency, compressive strength, and tensile strength.
- the high-density particulate elastomer may be present in the cement compositions of the present invention in an amount from about 0.5% to about 50% bwoc, alternatively from about 1% to about 20% bwoc, and alternatively from about 4% to about 15% bwoc.
- the high-density particulate elastomer present in the cement compositions of the present invention may have a wide variety of shapes and sizes of individual particles suitable for use in the cement compositions of the present invention.
- the high-density particulate elastomers may have well-defined physical shapes as well as irregular geometries, including the physical shape of platelets, shavings, fibers, flakes, ribbons, rods, strips, spheroids, hollow beads, toroids, pellets, tablets, or any other physical shape.
- the high-density particulate elastomer may have a particle size in the range of about 5 microns to about 1,500 microns.
- the high-density particulate elastomer may have a particle size in the range of about 20 microns to about 500 microns. However, particle sizes outside these defined ranges also may be suitable for particular applications.
- the cement compositions of the present invention further may comprise a swellable elastomer.
- an elastomer is characterized as swellable when it swells upon contact with an oleaginous and/or an aqueous fluid, such as water.
- an aqueous fluid such as water.
- the inclusion of a swellable elastomer may help to provide zonal isolation, for example, by swelling to seal the annulus if any oleaginous or aqueous fluids flow through any cracks and/or micro- annulus that may be created in the cement sheath during well operations.
- Swellable elastomers suitable for use in the cement compositions of the present invention may generally swell by up to about 500% of their original size at the surface. Under downhole conditions, this swelling may be more or less depending on the conditions presented. For example, the swelling may be at least 10% at downhole conditions. In some embodiments, the swelling may be up to about 200% under downhole conditions.
- the actual swelling when the swellable elastomer is included in a cement composition may depend on, for example, the concentration of the swellable elastomer included in the cement composition.
- the swellable elastomers included in the cement compositions of the present invention have a specific gravity of about 1.0.
- suitable elastomers that swell upon contact with an oleaginous fluid and/or an aqueous fluid include, but are not limited to, natural rubber, acrylate butadiene rubber, polyacrylate rubber, isoprene rubber, choloroprene rubber, butyl rubber (HR), brominated butyl rubber (BIIR), chlorinated butyl rubber (CIIR), chlorinated polyethylene (CM/CPE), neoprene rubber (CR), styrene butadiene copolymer rubber (SBR), sulphonated polyethylene (CSM), ethylene acrylate rubber (EAM/AEM), epichlorohydrin ethylene oxide copolymer (CO, ECO), ethylene-propylene rubber (EPM and EDPM), ethylene-propylene-diene terpolymer rubber (EPT), ethylene vinyl
- Suitable elastomers that swell when in contact with aqueous fluid include, but are not limited to, nitrile rubber (NBR), hydrogenated nitrile rubber (HNBR, HNS), fluoro rubbers (FKM), perfluoro rubbers (FFKM), tetrafluorethylene/propylene (TFE/P), starch-polyacrylate acid graft copolymer, polyvinyl alcoholcyclic acid anhydride graft copolymer, isobutylene maleic anhydride, acrylic acid type polymers, vinylacetate-acrylate copolymer, polyethylene oxide polymers, carboxymethyl cellulose type polymers, starch- polyacrylonitrile graft copolymers and the like, polymethacrylate, polyacrylamide, and non- soluble acrylic polymers.
- NBR nitrile rubber
- HNBR hydrogenated nitrile rubber
- FKM fluoro rubbers
- FFKM perfluoro rubbers
- TFE/P te
- suitable swellable elastomer may also be used.
- a suitable swellable elastomer includes WellLife 665 additive, available from Halliburton Energy Services, Inc., Duncan, Oklahoma.
- Other swellable materials that behave in a similar fashion with respect to oleaginous fluids or aqueous fluids also may be suitable.
- Those of ordinary skill in the art, with the benefit of this disclosure, will be able to select an appropriate swellable elastomer for use in the compositions of the present invention based on a variety of factors, including the application in which the composition will be used and the desired swelling characteristics,
- the swellable elastomer generally may be present in the cement compositions of the present invention in an amount sufficient to provide the desired mechanical properties.
- the swellable elastomer may be present in the cement compositions of the present invention in an amount from about 0.5% to about 50% bwoc, alternatively from about 1% to about 20% bwoc, and alternatively from about 4% to about 15% bwoc.
- the ratio of the swellable elastomer to the high-density particulate elastomer may be optimized to the various properties of each elastomer, such as high-chemical resistance ⁇ e.g., the fluoroplastics) and swelling characteristics (e.g., the swellable elastomers).
- a cement composition may be designed to include a particular concentration of elastomeric materials.
- a method of the present invention may include determining a concentration of the particulate elastomer and the swellable elastomer to include based, for example, on the desired mechanical properties of the cement composition, desired swelling of elastomeric materials in the cement composition, desired chemical resistance of elastomeric materials in the cement composition.
- the swellable elastomer that may be present in the cement compositions of the present invention may have a wide variety of shapes and sizes of individual particles suitable for use in the cement compositions of the present invention.
- the swellable elastomer may have a well-defined physical shape as well as an irregular geometry, including the physical shape of platelets, shavings, fibers, flakes, ribbons, rods, strips, spheroids, hollow beads, toroids, pellets, tablets, or any other physical shape.
- the swellable elastomer may have a particle size in the range of about 5 microns to about 1,500 microns.
- the swellable elastomer may have a particle size in the range of about 20 microns to about 500 microns. However, particle sizes outside these defined ranges also may be suitable for particular applications.
- additives suitable for use in subterranean cementing operations also may be added to the cement compositions of the present invention.
- additives include, but are not limited to, strength-retrogression additives, set accelerators, weighting agents, weight-reducing additives, heavyweight additives, lost-circulation materials, filtration-control additives, dispersants, defoaming agents, foaming agents, and combinations thereof.
- Specific examples of these, and other, additives include, but are not limited to, crystalline silica, amorphous silica, salts, fibers, hydratable clays, vitrified shale, microspheres, fly ash, lime, latex, thixotropic additives, combinations thereof and the like.
- the cement compositions of the present invention may be used in a variety of subterranean applications, including, but not limited to, primary cementing and remedial cementing.
- primary cementing applications the cement compositions may be introduced into an a ⁇ nulus between a pipe string located in a subterranean formation and the subterranean formation and allowed to set therein.
- subterranean formation encompasses both areas below exposed earth and areas below earth covered by water, such as ocean or fresh water.
- remedial cementing applications the cement compositions may used, for example, in squeeze cementing operations or in the placement of cement plugs.
- the cement compositions of the present invention also may be used in surface applications, such as construction cementing.
- a cement composition may be introduced into a selected location and allowed to set therein.
- the selected location may any suitable location above ground or in a well bore where it is desired for the cement composition to set into a hardened mass.
- the selected location may in a well bore penetrating a subterranean formation, such as an annulus between a pipe string located in the subterranean formation and the subterranean formation.
- a high-density particulate elastomer in well cementing methods, those of ordinary skill in the art will appreciate that the present technique also encompasses the use of high-density particulate elastomers in a variety of different subterranean treatments, including drilling fluids, completing fluids, stimulation fluids, spacer fluids, and well clean-up fluids.
- a high-density particular elastomer may be included in a spacer fluid.
- a spacer fluid may be placed between two fluids contained in or to be pumped within a well bore.
- spacer fluids examples include between cement compositions, and drilling fluids, between different drilling fluids during drilling fluid changeouts and between drilling fluids and completion brines.
- spacer fluids may be used to enhance drilling fluid and filter cake removal from the walls of well bores, to enhance displacement efficiency and to physically separate chemically incompatible fluids.
- a hydraulic cement composition and a drilling fluid may be separated by a spacer fluid when the cement composition is placed in the well bore.
- the spacer fluid may prevent, or at least partially reduce, intermixing of the cement composition and the drilling fluid and may facilitate the removal of filter cake and gelled drilling fluid from the walls of the well bore during displacement of the drilling fluid by the cement composition.
- cement compositions were designed having a density of 17 lb/gal. As illustrated by Tables 1 and 2 below, the cement composition with the high-density particulate elastomer maintained a density of 17 lb/gal without the addition of a heavyweight additive, improving mixability of the cement composition. However, to maintain the density of 17 lb/gal, the cement composition with the low-density particulate elastomer needed 40% bwoc of a heavyweight additive. [0035] Sample Cement Composition No. 1 included the low-density particulate elastomer. As illustrated by Table 1 below, Sample Cement Composition No.
- Sample Composition No. 2 included the high-density particulate elastomer. As illustrated by Table 2, Sample Composition No. 2 was designed to include water in an amount of 49.2% bwoc, Portland Class H cement, a high-density particulate elastomer (DYNEONTM PFA) in an amount of 8% bwoc, a set retarder (SCR- 100TM cement additive) in an amount of 0.5% bwoc, a fluid-loss-control additive (HALAD-413TM fluid-loss additive) in an amount of 0.6% bwoc, a cement dispersant (CFR-3TM cement dispersant) in an amount of 0.2% bwoc, silica flour (SSA-1TM cement additive) in an amount of 20% bwoc, and course silica flour (SSA-2TM cement additive) in an amount of 20% bwoc.
- SCR- 100TM cement additive set retarder
- HALAD-413TM fluid-loss additive HALAD-4
- Sample Cement Composition No. 2 did not need any of the heavyweight additive to provide a density of 17 lb/gal because the high-density particulate elastomer was used rather than the low-density particulate elastomer.
- a cement composition was prepared having a density of 14.7 lb/gal and containing water in an amount of 67% bwoc, Portland Class H cement, fly ash in an amount of 27% bwoc, a high-density particulate elastomer (DYNEONTM PFA) in an amount of 20% bwoc, a fmid-loss-control additive (HALAD-344TM EXP fluid-loss additive from Halliburton Energy Services, Inc.) in an amount of 0,6% bwoc, and a cement dispersant (CFR-3 T cement dispersant) in an amount of 0.1 gallons per 94 pound sack of the cement.
- This sample cement composition was then tested to determine the compressive strength, Young's modulus, and Poisson's ratio.
- the compressive-strength tests were performed in accordance with API Specification 10.
- the Young's modulus and Poisson's ratio were statically determined by means of compression testing using a load frame, The Young's modulus (or modulus of elasticity) for each sample was obtained by taking a ratio of a simple tension stress applied to each sample to a resulting strain parallel to the tension in that sample.
- the Poisson's ratio for each sample was determined by calculating a ratio of transverse strain to a corresponding axial strain resulting from uniformly distributed axial stress below a proportional limit of each sample. The values determined for two series of tests for this sample cement composition are set forth below in Table 3.
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Abstract
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Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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MX2010003903A MX2010003903A (en) | 2007-10-10 | 2008-10-09 | Cement compositions comprising a high-density particulate elastomer and associated methods. |
BRPI0817546 BRPI0817546A2 (en) | 2007-10-10 | 2008-10-09 | Method of treatment of an underground formation, and, treatment fluid. |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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US97895107P | 2007-10-10 | 2007-10-10 | |
US60/978,951 | 2007-10-10 | ||
US12/206,299 | 2008-09-08 | ||
US12/206,299 US8888713B2 (en) | 2007-03-07 | 2008-09-08 | Safety blood collection assembly with indicator |
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WO2009047496A2 true WO2009047496A2 (en) | 2009-04-16 |
WO2009047496A3 WO2009047496A3 (en) | 2009-05-28 |
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PCT/GB2008/003402 WO2009047496A2 (en) | 2007-10-10 | 2008-10-09 | Cement compositions comprising a high-density particulate elastomer and associated methods |
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BR (1) | BRPI0817546A2 (en) |
MX (1) | MX2010003903A (en) |
WO (1) | WO2009047496A2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010146334A1 (en) * | 2009-06-15 | 2010-12-23 | Halliburton Energy Services. Inc. | Cement compositions comprising particulate foamed elastomers and associated methods |
AU2016229304B2 (en) * | 2015-03-10 | 2018-07-19 | Baker Hughes, A Ge Company, Llc | Cement spacer system for wellbores, methods of making, and methods of use |
AU2016229302B2 (en) * | 2015-03-10 | 2018-07-26 | Baker Hughes a GE Company, LLC | Segregating fluids, methods of making, and methods of use |
US10110089B2 (en) | 2014-08-18 | 2018-10-23 | Eddy Current Limited Partnership | Tuning of a kinematic relationship between members |
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WO2002059452A1 (en) * | 2001-01-26 | 2002-08-01 | E2 Tech Limited | Device and method to seal boreholes |
US20040180794A1 (en) * | 2003-03-11 | 2004-09-16 | Reddy B. Raghava | Methods and compositions for sealing oil containing subterranean zones |
WO2008001112A1 (en) * | 2006-06-29 | 2008-01-03 | Halliburton Energy Services, Inc. | Swellable elastomers and associated methods |
-
2008
- 2008-10-09 MX MX2010003903A patent/MX2010003903A/en active IP Right Grant
- 2008-10-09 BR BRPI0817546 patent/BRPI0817546A2/en not_active IP Right Cessation
- 2008-10-09 WO PCT/GB2008/003402 patent/WO2009047496A2/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002059452A1 (en) * | 2001-01-26 | 2002-08-01 | E2 Tech Limited | Device and method to seal boreholes |
US20040180794A1 (en) * | 2003-03-11 | 2004-09-16 | Reddy B. Raghava | Methods and compositions for sealing oil containing subterranean zones |
WO2008001112A1 (en) * | 2006-06-29 | 2008-01-03 | Halliburton Energy Services, Inc. | Swellable elastomers and associated methods |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010146334A1 (en) * | 2009-06-15 | 2010-12-23 | Halliburton Energy Services. Inc. | Cement compositions comprising particulate foamed elastomers and associated methods |
US8592352B2 (en) | 2009-06-15 | 2013-11-26 | Halliburton Energy Services, Inc. | Cement compositions comprising particulate foamed elastomers and associated methods |
US8807216B2 (en) | 2009-06-15 | 2014-08-19 | Halliburton Energy Services, Inc. | Cement compositions comprising particulate foamed elastomers and associated methods |
US10087357B2 (en) | 2009-06-15 | 2018-10-02 | Halliburton Energy Services, Inc. | Cement compositions comprising particulate foamed elastomers and associated methods |
US10110089B2 (en) | 2014-08-18 | 2018-10-23 | Eddy Current Limited Partnership | Tuning of a kinematic relationship between members |
AU2016229304B2 (en) * | 2015-03-10 | 2018-07-19 | Baker Hughes, A Ge Company, Llc | Cement spacer system for wellbores, methods of making, and methods of use |
AU2016229302B2 (en) * | 2015-03-10 | 2018-07-26 | Baker Hughes a GE Company, LLC | Segregating fluids, methods of making, and methods of use |
Also Published As
Publication number | Publication date |
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MX2010003903A (en) | 2010-06-01 |
BRPI0817546A2 (en) | 2015-03-31 |
WO2009047496A3 (en) | 2009-05-28 |
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