WO2009043847A2 - Joint sealant - Google Patents

Joint sealant Download PDF

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Publication number
WO2009043847A2
WO2009043847A2 PCT/EP2008/063076 EP2008063076W WO2009043847A2 WO 2009043847 A2 WO2009043847 A2 WO 2009043847A2 EP 2008063076 W EP2008063076 W EP 2008063076W WO 2009043847 A2 WO2009043847 A2 WO 2009043847A2
Authority
WO
WIPO (PCT)
Prior art keywords
joint sealant
granules
materials
gaps
sealant
Prior art date
Application number
PCT/EP2008/063076
Other languages
French (fr)
Other versions
WO2009043847A3 (en
Inventor
Corinna Pane
Original Assignee
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij B.V. filed Critical Shell Internationale Research Maatschappij B.V.
Priority to EP08834879.2A priority Critical patent/EP2195280B1/en
Publication of WO2009043847A2 publication Critical patent/WO2009043847A2/en
Publication of WO2009043847A3 publication Critical patent/WO2009043847A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02—Agglomerated materials, e.g. artificial aggregates
    • C04B18/022—Agglomerated materials, e.g. artificial aggregates agglomerated by an organic binder
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/26—Bituminous materials, e.g. tar, pitch
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00—Details of pavings
    • E01C11/02—Arrangement or construction of joints; Methods of making joints; Packing for joints
    • E01C11/04—Arrangement or construction of joints; Methods of making joints; Packing for joints for cement concrete paving
    • E01C11/10—Packing of plastic or elastic materials, e.g. wood, resin
    • E01C11/103—Joints with packings prepared only in situ; Materials therefor
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00—Pavings made of prefabricated single units
    • E01C5/003—Pavings made of prefabricated single units characterised by material or composition used for beds or joints; characterised by the way of laying
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00663—Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
    • C04B2111/00672—Pointing or jointing materials
    • C04B2111/00689—Pointing or jointing materials of the setting type
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80—Optical properties, e.g. transparency or reflexibility
    • C04B2111/805—Transparent material

Definitions

  • the invention relates to a joint sealant and a method of sealing joints.
  • Background of the Invention Joint sealants are used to seal the gaps between paving stones, cobblestones, tramway rails and modular materials.
  • the sealants typically comprise bituminous materials and are typically applied by heating the sealant material so that it flows, and pouring the sealant into the gaps between the paving stones.
  • FR 2706477 describes a joint sealant that is composed of a colourless synthetic bitumen and a mineral.
  • the sealant is applied via a traditional method wherein the sealant is heated in a mixer with oil bath and liquid sealant is applied between the gaps in the paving stones. Sand is applied to the surface of the sealant to accentuate the finish and the colour, and also to provide a surface crust that confers rigidity and thermal protection to the surface.
  • the known methods of applying joint sealants are effective, but typically require the use of apparatus in which the sealant is heated. Such apparatus, often known as a kettle, can be expensive. Additionally, in the known methods, hot liquid sealant is applied to the gaps, and the operator must therefore take appropriate safety precautions. Furthermore, it can be difficult to seal small gaps, e.g.
  • the present invention provides a joint sealant comprising a bituminous material or a clear synthetic binder material, and comprising a mineral filler, wherein the joint sealant is in the form of granules .
  • the present invention further provides a method of sealing gaps between materials by applying a joint sealant, wherein the joint sealant comprises a bituminous material or a clear synthetic binder material, and comprises a mineral filler, wherein the joint sealant is in the form of granules, comprising steps of
  • the joint sealant comprises a bituminous material or a synthetic binder material.
  • the bituminous material may be bitumen having a penetration in the range of 0 to 220 dmm (tested at 25°C) .
  • the joint sealant comprises a clear synthetic binder material. Clear synthetic binder material is preferred because the resulting sealed material is aesthetically improved because the joints can be colourless or coloured rather than black. Also, staining of the materials to be joined is reduced when using a clear synthetic binder material instead of a bituminous material.
  • Clear synthetic binder materials are known to the skilled person and include combinations of a mineral lubricating oil extract and a modified petroleum resin and/or coumarone-indene resin as described in US 4,629,754.
  • a preferred synthetic binder material is Mexphalte ® C from Shell.
  • the clear synthetic binder material may also be a binder material based upon materials of vegetable origin, such as those disclosed in EP 1 466 878, e.g. the clear synthetic binder material may comprise 40 to 70wt% of natural or modified natural resin of vegetable origin, and 30 to 60wt% of vegetable oil.
  • the joint sealant also comprises a mineral filler.
  • the mineral filler preferably comprises sand, having a particle size lower than 0.5mm, and fines, having a particle size lower than or equal to 0.08mm.
  • the amount of mineral filler in the joint sealant is preferably more than 30wt%, more preferably more than 50wt%, and preferably less than 90wt%, more preferably less than 70wt%.
  • the mineral filler is silica sand.
  • the joint sealant further comprises a fibrous filler.
  • the fibrous filler is preferably cellulose fibre, e.g. Arbocel® fibres from JRS.
  • the average diameter of the fibres is preferably lower than 0.5mm, preferably lower than 0.1mm.
  • the average length of the fibres is preferably from 0.5mm to 5mm.
  • the amount of fibrous filler in the joint sealant is preferably from 0.1 to 10wt%, based upon the weight of the joint sealant, more preferably from 0.5 to 5wt%.
  • the bituminous material or the clear synthetic binder material comprises one or more polymer materials, e.g. from 2 to 20wt% polymer material, based upon the weight of the bituminous material or the clear synthetic binder material.
  • the joint sealant is in the form of granules.
  • the term "granule" is used to describe discrete units of joint sealant and does not limit the shape of the units, e.g.
  • a granule may be spherical, egg-shaped, cubic or any other shape.
  • the preferred size of the granules is determined by the size of the gaps between the materials to be sealed; the granules must be small enough to fit in the gaps.
  • Typical gaps, e.g. between paving stones, are between 10 and 20mm, so preferably the longest dimension of the granules is less than 20mm, more preferably less than 10mm and most preferably less than 5mm.
  • the longest dimension of the granules is at least 0.5mm, more preferably at least lmm.
  • Joint sealant in the form of granules may be prepared by any process known in the field of granulation, such as granulation after extrusion, manual granulation, cooling drops of hot materials, crushing of blocks etc.
  • Manual granulation can be achieved by melting and blending the joint sealant components and pouring into a mould.
  • a metal mould is used, and the mould is lined with greaseproof paper. Glycerine and talc may be used to stick the greaseproof paper to the mould.
  • a thin layer of joint sealant e.g. less than 10mm, or less than 5mm in thickness, is preferably formed in the mould and is left for approximately one hour to harden.
  • the layer of joint sealant is turned out of the mould and is cut into granules using a hot knife.
  • the formed granules are coated in a fine layer of mineral filler material so that they are non sticky and do not agglomerate .
  • the joint sealant of the invention is used in a method wherein the granules are placed in the gaps between materials and are heated such that the joint sealant flows and seals the gaps between the materials.
  • the materials to be sealed may be paving stones, concrete blocks or other similar construction materials where it is required to seal between the materials.
  • the sealant may be used in a process to seal the gap between a metal material such as a tram rail and another metal material or construction material.
  • the joint sealant is used in a method to seal the gaps between paving stones.
  • the term "paving stones" is used in the present description to describe any paving material having gaps between elements of the paving material that require sealing, e.g. flagstones or cobblestones .
  • the granules may be placed in the gaps by a simple method of scattering the granules over the gaps and brushing the granules into the gaps.
  • the granules are then heated whilst present in the gaps between the paving stones.
  • the granules are preferably heated to at least 100 0 C, more preferably at least 120 0 C.
  • the temperature must be high enough so that the granules soften and flow, and the joint sealant seals the gap between the materials.
  • the granules are preferably not heated above 200 0 C and are more preferably not heated above 160 0 C. It is preferred that lower temperatures are used to minimise energy usage.
  • the method of the invention preferably comprises a further step of (c) applying sand to the joint sealant. This accentuates the finish and the colour of the joint, and also provides a surface crust that confers rigidity and thermal protection to the surface.
  • a metallic mould (20cmx20cmx0.5cm) was coated with a mixture of talc and glycerine and was then lined with greaseproof paper. Mexphalte C Joint P3J binder from
  • Shell® (a clear synthetic binder plus a mineral filler) was heated to 100 0 C above its softening point, poured into the mould, and left to cool and harden for approximately one hour. The hardened bitumen was removed from the mould and was cut into granules using a heated knife. The granules were approximately 8mm in diameter.
  • the granules were coated with a fine layer of sand by contacting the granules with sand.

Abstract

A joint sealant, a method of making the joint sealant and a method of sealing gaps between materials by applying a joint sealant are disclosed. The joint sealant comprises a bituminous material or a clear synthetic binder material, and comprises a mineral filler. The joint sealant is in the form of granules.

Description

JOINT SEALANT
Field of the Invention
The invention relates to a joint sealant and a method of sealing joints. Background of the Invention Joint sealants are used to seal the gaps between paving stones, cobblestones, tramway rails and modular materials. The sealants typically comprise bituminous materials and are typically applied by heating the sealant material so that it flows, and pouring the sealant into the gaps between the paving stones.
FR 2706477 describes a joint sealant that is composed of a colourless synthetic bitumen and a mineral. The sealant is applied via a traditional method wherein the sealant is heated in a mixer with oil bath and liquid sealant is applied between the gaps in the paving stones. Sand is applied to the surface of the sealant to accentuate the finish and the colour, and also to provide a surface crust that confers rigidity and thermal protection to the surface. The known methods of applying joint sealants are effective, but typically require the use of apparatus in which the sealant is heated. Such apparatus, often known as a kettle, can be expensive. Additionally, in the known methods, hot liquid sealant is applied to the gaps, and the operator must therefore take appropriate safety precautions. Furthermore, it can be difficult to seal small gaps, e.g. between cobblestones, because the sealant is typically applied using a lance and the lance may be too big to fit into the small gaps . The present inventors have sought to provide an alternative joint sealant and an alternative method of applying the joint sealant. Summary of the Invention Accordingly, the present invention provides a joint sealant comprising a bituminous material or a clear synthetic binder material, and comprising a mineral filler, wherein the joint sealant is in the form of granules . The present invention further provides a method of sealing gaps between materials by applying a joint sealant, wherein the joint sealant comprises a bituminous material or a clear synthetic binder material, and comprises a mineral filler, wherein the joint sealant is in the form of granules, comprising steps of
(a) placing the granules in the gaps between the materials; and
(b) heating the granules such that the joint sealant flows and seals the gaps between the materials. The present inventors have discovered that a joint sealant can be manufactured in the form of granules, and the granules can be utilised in an advantageous method of application wherein the granules are placed in the gaps between materials and heat is subsequently applied. This method of application can use simple heating apparatus and does not require the use of an expensive heating kettle. Furthermore, this method of application limits the operator's exposure to hot liquid sealant. Additionally the method of application enables the sealing of small gaps that potentially could not have been sealed using prior art methods. Detailed Description of the Invention
The joint sealant comprises a bituminous material or a synthetic binder material. The bituminous material may be bitumen having a penetration in the range of 0 to 220 dmm (tested at 25°C) . In a preferred embodiment of the invention, the joint sealant comprises a clear synthetic binder material. Clear synthetic binder material is preferred because the resulting sealed material is aesthetically improved because the joints can be colourless or coloured rather than black. Also, staining of the materials to be joined is reduced when using a clear synthetic binder material instead of a bituminous material. Clear synthetic binder materials are known to the skilled person and include combinations of a mineral lubricating oil extract and a modified petroleum resin and/or coumarone-indene resin as described in US 4,629,754. A preferred synthetic binder material is Mexphalte ® C from Shell. The clear synthetic binder material may also be a binder material based upon materials of vegetable origin, such as those disclosed in EP 1 466 878, e.g. the clear synthetic binder material may comprise 40 to 70wt% of natural or modified natural resin of vegetable origin, and 30 to 60wt% of vegetable oil. The joint sealant also comprises a mineral filler.
The mineral filler preferably comprises sand, having a particle size lower than 0.5mm, and fines, having a particle size lower than or equal to 0.08mm. The amount of mineral filler in the joint sealant is preferably more than 30wt%, more preferably more than 50wt%, and preferably less than 90wt%, more preferably less than 70wt%. In a preferred embodiment of the invention, the mineral filler is silica sand. In one embodiment of the invention, the joint sealant further comprises a fibrous filler. The fibrous filler is preferably cellulose fibre, e.g. Arbocel® fibres from JRS. The average diameter of the fibres is preferably lower than 0.5mm, preferably lower than 0.1mm. The average length of the fibres is preferably from 0.5mm to 5mm. The amount of fibrous filler in the joint sealant is preferably from 0.1 to 10wt%, based upon the weight of the joint sealant, more preferably from 0.5 to 5wt%. In one embodiment of the invention, the bituminous material or the clear synthetic binder material comprises one or more polymer materials, e.g. from 2 to 20wt% polymer material, based upon the weight of the bituminous material or the clear synthetic binder material. The joint sealant is in the form of granules. The term "granule" is used to describe discrete units of joint sealant and does not limit the shape of the units, e.g. a granule may be spherical, egg-shaped, cubic or any other shape. The preferred size of the granules is determined by the size of the gaps between the materials to be sealed; the granules must be small enough to fit in the gaps. Typical gaps, e.g. between paving stones, are between 10 and 20mm, so preferably the longest dimension of the granules is less than 20mm, more preferably less than 10mm and most preferably less than 5mm. For handling purposes, it is preferred that the longest dimension of the granules is at least 0.5mm, more preferably at least lmm.
Joint sealant in the form of granules may be prepared by any process known in the field of granulation, such as granulation after extrusion, manual granulation, cooling drops of hot materials, crushing of blocks etc. Manual granulation can be achieved by melting and blending the joint sealant components and pouring into a mould. Preferably a metal mould is used, and the mould is lined with greaseproof paper. Glycerine and talc may be used to stick the greaseproof paper to the mould. A thin layer of joint sealant, e.g. less than 10mm, or less than 5mm in thickness, is preferably formed in the mould and is left for approximately one hour to harden. The layer of joint sealant is turned out of the mould and is cut into granules using a hot knife. Preferably, the formed granules are coated in a fine layer of mineral filler material so that they are non sticky and do not agglomerate .
The joint sealant of the invention is used in a method wherein the granules are placed in the gaps between materials and are heated such that the joint sealant flows and seals the gaps between the materials. The materials to be sealed may be paving stones, concrete blocks or other similar construction materials where it is required to seal between the materials. Alternatively, the sealant may be used in a process to seal the gap between a metal material such as a tram rail and another metal material or construction material. Preferably the joint sealant is used in a method to seal the gaps between paving stones. The term "paving stones" is used in the present description to describe any paving material having gaps between elements of the paving material that require sealing, e.g. flagstones or cobblestones .
The granules may be placed in the gaps by a simple method of scattering the granules over the gaps and brushing the granules into the gaps. The granules are then heated whilst present in the gaps between the paving stones. The granules are preferably heated to at least 1000C, more preferably at least 1200C. The temperature must be high enough so that the granules soften and flow, and the joint sealant seals the gap between the materials. The granules are preferably not heated above 2000C and are more preferably not heated above 1600C. It is preferred that lower temperatures are used to minimise energy usage.
The method of the invention preferably comprises a further step of (c) applying sand to the joint sealant. This accentuates the finish and the colour of the joint, and also provides a surface crust that confers rigidity and thermal protection to the surface.
Examples
The invention will now be described by reference to examples which are not intended to be limiting of the invention .
Preparation of Granules
A metallic mould (20cmx20cmx0.5cm) was coated with a mixture of talc and glycerine and was then lined with greaseproof paper. Mexphalte C Joint P3J binder from
Shell® (a clear synthetic binder plus a mineral filler) was heated to 1000C above its softening point, poured into the mould, and left to cool and harden for approximately one hour. The hardened bitumen was removed from the mould and was cut into granules using a heated knife. The granules were approximately 8mm in diameter.
The granules were coated with a fine layer of sand by contacting the granules with sand.
Sealing of Gaps Between Paving Stones The granules were manually spread between paving stones. The granules were heated to approximately 1200C for 20 minutes using an infra-red heater from Altenwerder Gussasphalt Technology. This provided seals between the paving stones having the same appearance as seals prepared using conventional methods .

Claims

C L A I M S
1. A joint sealant comprising a bituminous material or a clear synthetic binder material, and comprising a mineral filler, wherein the joint sealant is in the form of granules.
2. A joint sealant according to claim 1, comprising a clear synthetic binder material.
3. A joint sealant according to claim 1 or claim 2, wherein the longest dimension of the granules is less than 20mm.
4. A method of making a joint sealant according to any one of claims 1 to 3, wherein the bituminous material or clear synthetic binder material and the mineral filler are heated, blended and poured into a mould, wherein a layer of joint sealant is formed in the mould, and wherein the layer of joint sealant is cut into granules using a knife .
5. A method of making a joint sealant according to any one of claims 1 to 3, comprising a step wherein the bituminous material or clear synthetic binder material and the mineral filler are combined and extruded.
6. A method of sealing gaps between materials by applying a joint sealant according to any one of claims 1 to 3, comprising steps of
(a) placing the granules in the gaps between the materials; and
(b) heating the granules such that the joint sealant flows and seals the gaps between the materials.
7. A method of sealing gaps between materials according to claim 5, wherein the materials are paving stones.
8. A method of sealing gaps between materials according to claim 6 or claim 7, comprising a further step of (c) applying sand to the joint sealant.
PCT/EP2008/063076 2007-10-02 2008-09-30 Joint sealant WO2009043847A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP08834879.2A EP2195280B1 (en) 2007-10-02 2008-09-30 Method of sealing gaps between materials

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07291204 2007-10-02
EP07291204.1 2007-10-02

Publications (2)

Publication Number Publication Date
WO2009043847A2 true WO2009043847A2 (en) 2009-04-09
WO2009043847A3 WO2009043847A3 (en) 2009-06-11

Family

ID=40146119

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/063076 WO2009043847A2 (en) 2007-10-02 2008-09-30 Joint sealant

Country Status (2)

Country Link
EP (1) EP2195280B1 (en)
WO (1) WO2009043847A2 (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5927954A (en) * 1982-08-10 1984-02-14 Nippon Hodo Co Ltd Modifier for paving asphalt
DE4407822C2 (en) * 1994-03-09 1997-01-23 Carl Ungewitter Trinidad Lake Process for the production of pourable and storage-stable granulate from natural asphalt
DE10010451A1 (en) * 2000-03-03 2001-09-13 Rainer R Hart Production of thermoplastic filler, used for eliminating surface damage to concrete or asphalt surfaces, involves homogeneously mixing gravel, sand, finely ground material and bituminous binder, and rapidly adding coolant

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None

Also Published As

Publication number Publication date
EP2195280B1 (en) 2016-09-07
EP2195280A2 (en) 2010-06-16
WO2009043847A3 (en) 2009-06-11

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