WO2009043686A2 - Mélanges fongicides - Google Patents

Mélanges fongicides Download PDF

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Publication number
WO2009043686A2
WO2009043686A2 PCT/EP2008/061809 EP2008061809W WO2009043686A2 WO 2009043686 A2 WO2009043686 A2 WO 2009043686A2 EP 2008061809 W EP2008061809 W EP 2008061809W WO 2009043686 A2 WO2009043686 A2 WO 2009043686A2
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WO
WIPO (PCT)
Prior art keywords
methyl
compound
carboxamide
compounds
pyrazole
Prior art date
Application number
PCT/EP2008/061809
Other languages
German (de)
English (en)
Other versions
WO2009043686A3 (fr
Inventor
Ulf Groeger
Egon Haden
Siegfried Strathmann
Matthias NIEDENBRÜCK
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of WO2009043686A2 publication Critical patent/WO2009043686A2/fr
Publication of WO2009043686A3 publication Critical patent/WO2009043686A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton

Definitions

  • the present invention relates to fungicidal mixtures containing as active components
  • the invention relates to a method for controlling harmful fungi with mixtures of the compound I with the compound II and the use of the compounds tileg I with the compound II for the preparation of such mixtures and compositions containing these mixtures.
  • the strobilurin active ingredient kresoxime-methyl described above as component 1 is (E) -methoxyimino [ ⁇ - (o-tolyloxy) -o-tolyl] -acetic acid methyl ester, its preparation and its action against harmful fungi are known from the literature (EP-A 253 213). , The strengthening and crop-increasing effect of strobilurin active ingredients on plants is also known (US Pat. No. 7,098,170).
  • the active ingredient simeconazole mentioned above as component 2 is (RS) -2- (4-fluorophenyl) -1- (1 / - / - 1, 2,4-triazol-1-yl) -3- (trimethylsilyl) propane-2 -ol, its production and action against harmful fungi is also known (Proc. BCPC Conf. - Pests Dis., Vol. 2, p. 557 (2000)).
  • the object of the invention is to provide an improved action against harmful fungi, in particular for certain indications, with a reduced total amount of applied active substances.
  • the mixtures of the compound I and the compound II, or the simultaneous joint or separate use of the compound I and the compound II are distinguished by a strengthening and crop-increasing effect on plants, in particular legumes, and an outstanding activity against a broad spectrum of phytopathogenic fungi, in particular of the class of the Ascomycetes, Deuteromycetes, Basidiomycetes and Peronosporomycetes (Syn. Oomycetes). They are partially systemically effective and can be used in crop protection as foliar, pickling and soil fungicides.
  • Alternaria species on vegetables oilseed rape, sugarbeet, fruit, rice, soybeans, as well as on potatoes (for example A. solani or A. alternata) and tomatoes (for example A. solani or A. alternata) and Alternaria ssp. (Earhocks) on wheat, Aphanomyces species on sugar beet and vegetables, Ascochyta species on cereals and vegetables e.g. Ascochyta tritici (leaf drought) on wheat, Bipolaris and Drechslera species on maize (eg D.
  • the maydis maydis), cereals, rice and turf, Blumeria graminis (powdery mildew) on cereals (eg wheat or barley), Botrytis cinerea (gray horse) on strawberries , Vegetables, flowers, vines and wheat (cereal), Bremia lactucae on salad,
  • Drechslera species Pyrenophora species on maize, cereals, rice and turf, barley (e.g., D. teres) and wheat (e.g., D. tritici-repentis),
  • Fusarium and Verticillium species on different plants e.g. F. graminearum or
  • F. culmorum root rot
  • cereals e.g., wheat or barley
  • F. oxysporum on tomatoes and Fusarium solani (stalk disease) on soybean Gaeumanomyces graminis (root black) on cereals (for example wheat or barley)
  • Gibberella species on cereals and rice e.g., Gibberella fujikuroi
  • Michrodochium nivale (snow mold) on cereals (for example wheat or barley),
  • Microsphaera diffusa (powdery mildew) on soybeans, Mycosphaerella species on cereals, bananas and peanuts, e.g. M. graminicola on wheat or M. fijiensis on bananas,
  • Peronospora species on cabbage e.g., P. brassicae
  • bulbous plants e.g., P. destructor
  • Peronospora manshurica downy mildew
  • Phakopsara pachyrhizi (soybean rust) and Phakopsara meibomiae (soybean rust) on soya beans
  • Phytophthora species on various plants e.g. P. capsici on peppers, Phytopthora megasperma (leaf / stem rot) on soybeans, Phytophthora infestans on potatoes and tomatoes,
  • Pseudocercosporella herpotrichoides (straw break) on cereals (wheat or barley), Pseudoperonospora on various plants e.g. P. cubensis on cucumber or P. humili on hops, pseudo-pedicel tracheiphilai on grapevine,
  • Puccinia species on various plants e.g. P. triticina, P. striformins, P. hordei or P. graminis on cereals (for example wheat or barley) or asparagus (for example P. asparagi),
  • Rhizoctonia species on cotton, rice, potatoes, turf, corn, oilseed rape, potatoes, sugar beets, vegetables and various other plants e.g. Rhizoctonia solani (root / stem rot) on soybeans or Rhizoctonia cerealis (pointed eye spot) on wheat or barley,
  • Rhynchosporium secalis on barley, rye and triticale Sclerotinia species on rape, sunflower and e.g. Sclerotinia sclerotiorum (stalk disease) or Sclerotinia rolfsii (stalk disease) on soybeans, Septoria glycines (leaf stain) on soybeans,
  • Septoria tritici (Blattseptoria) and Stagonospora nodorum on wheat, Erysiphe (syn. Uncinula) necator on grapevine, Setospaeria species on corn and turf, Sphacelotheca reilinia on corn, Stagonospora nodorum (Ear septoria) on wheat, Thievaliopsis species on soybean and cotton, Tilletia species on cereals,
  • Typhula incarnata (snow) on wheat or barley, Ustilago species on cereals, maize (e.g., U. maydis) and sugarcane, Venturia species (scab) on apples (e.g., V. inaequalis) and pears.
  • the mixtures of compounds I and II are also suitable for controlling harmful fungi in the protection of materials (eg wood, paper, paint dispersions, fibers or fabrics) and in the protection of stored products.
  • harmful fungi Ascomycetes such as Ophiostoma spp., Ceratocystis spp., Aureosidium pullulans, Sclerophoma spp., Chaetomium spp., Humicola spp., Petriella spp., Trichurus spp .; Basidiomycetes such as Coniophora spp., Coriolus spp., Gloeophyl lum spp., Lentinus spp., Pleurotus spp., Poria spp., Serpula spp.
  • Tyromyces spp. Deuteromycetes such as Aspergillus spp., Cladosporium spp., Penicillium spp., Trichoderm spp., Alternaria spp., Paecilomyces spp. and Zygomycetes such as Mucor spp., moreover, in the protection of the following yeasts: Candida spp. and Saccharomyces cerevisae.
  • the compounds I and II can be applied simultaneously together or separately or one after the other, the sequence in the case of separate application generally having no effect on the control result.
  • Such further active ingredients in the above sense are preferably selected from the following list:
  • bitertanol bromuconazoles, cyproconazole, difenoconazole, diniconazole, enilconazole, epoxiconazole, fenbuconazole, flusilazole, fluquinconazole, flutriol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, tebuconazole, tetraconazole, triadimenol , Triadimefon, triticonazole;
  • - imidazoles cyazofamide, imazalil, pefurazoate, prochloraz, triflumizole;
  • Benzimidazoles benomyl, carbendazim, fuberidazole, thiabendazole; - Other: Ethaboxam, Etridiazole, Hymexazole;
  • Azoxystrobin Dimoxystrobin, Enestroburin, Fluoxastrobin, Metominostrobin, Picoxy-strobin, Pyraclostrobin, Trifloxystrobin, Orysastrobin, (2-Chloro-5- [1- (3-methylbenzyl-oxyimino) -ethyl] -benzyl) -carbamic acid methyl ester, (2 Ethyl chloro-5- [1- (6-methyl-pyridin-2-ylmethoxyimino) -ethyl] -benzyl) -carbamic acid, 2- (ortho- (2,5-dimethyl-phenyl-oxymethylene) -phenyl) -3- methoxy-methyl acrylate;
  • Carboxylic acid anilides benalaxyl, benodanil, boscalid, carboxin, mepronil, fenfuram, fenhexamide, flutolanil, furametpyr, metalaxyl, ofurace, oxadixyl, oxycarboxin,
  • Benzoic acid amides flumetover, fluopicolide (picobenzamide), zoxamide; - Other carboxamides: carpropamide, diclocymet, mandipropamide, flumetone, carpropamide, N- (2- ⁇ 4- [3- (4-chlorophenyl) prop-2-ynyloxy] -3-methoxyphenyl ⁇ ethyl) -2- methanesulfonylamino-3-methylbutyramide, N- (2- ⁇ 4- [3- (4-chlorophenyl) -prop-2-ynyloxy] -3-methoxyphenyl ⁇ ethyl) -2-ethanesulfonylamino-3-methyl-butyramide;
  • Pyridines Pyrifenox, 3- [5- (4-Chloro-phenyl) -2,3-dimethyl-isoxazolidin-3-yl] -pyridine;
  • Pyrimidines bupirimate, cyprodinil, ferimzone, fenarimol, mepanipyrim, nuarimol, pyrimethanil; - Piperazine: Triforine "
  • Dicarboximides iprodione, procymidone, vinclozolin;
  • Dithiocarbamates Ferbam, Mancozeb, Maneb, Metiram, Metam, Propineb, Thiram, Zineb, Ziram; Carbamates: diethofencarb, flubenthiavalicarb, iprovalicarb, propamocarb,
  • guanidines dodine, iminoctadine, guazatine
  • Sulfur-containing heterocyclyl compounds isoprothiolanes, dithianone;
  • Organophosphorus compounds edifenphos, fosetyl, fosetyl-aluminum, Iprobenfos, pyrazophos, tolclofos-methyl, phosphorous acid and their salts;
  • Organochlorine compounds thiophanates methyl, chlorothalonil, dichlofluanid, toluylfluanid, flusulfamides, phthalides, hexachlorobenzene, pencycuron, quintozene;
  • Nitrophenyl derivatives binapacryl, dinocap, dinobuton;
  • Inorganic active substances Bordeaux broth, copper acetate, copper hydroxide, copper oxychloride, basic copper sulphate, sulfur; - Other: Spiroxamine, Cyflufenamid, Cymoxanil, Metrafenone.
  • the active compounds can also be used in the form of their agriculturally acceptable salts. Usually come for alkali or alkaline earth salts, such as sodium, potassium or calcium salts in question.
  • the compound I and the compound II are usually used in a weight ratio of 100: 1 to 1: 100, preferably 20: 1 to 1:20, in particular 10: 1 to 1:10 applied.
  • the further active components are added to compound I in a ratio of from 20: 1 to 1:20.
  • the application rates of the mixtures according to the invention are from 5 g / ha to 2000 g / ha, preferably from 50 to 900 g / ha, in particular from 50 to 750 g / ha.
  • the application rates for the compound I are accordingly generally 1 to 1000 g / ha, preferably 10 to 900 g / ha, in particular 20 to 750 g / ha.
  • the application rates for the active compound II are correspondingly generally 1 to 2000 g / ha, preferably 10 to 900 g / ha, in particular 40 to 500 g / ha.
  • seed treatment e.g. By dusting, coating or impregnating seeds, in general application rates of mixture of 1 to 1000 g / 100 kg of seed, preferably 1 to 750 g / 100 kg, in particular 5 to 500 g / 100 kg are used.
  • the application rate of active ingredient depends on the type of application and the desired effect. Usual application rates in material protection are, for example, 0.001 g to 2 kg, preferably 0.005 g to 1 kg of active ingredient per cubic meter of material treated.
  • the method for controlling harmful fungi is by the separate or combined application of the compound I and the compound II or the mixtures of the compound I and the compound II by spraying or dusting the seeds, the plants or the soil before or after sowing the plants or before or after emergence of the plants.
  • the mixtures according to the invention, or compound I and compound II, can be converted into the customary formulations, e.g. Solutions, emulsions, suspensions, dusts, powders, pastes and granules.
  • the application form depends on the respective purpose; It should in any case ensure a fine and uniform distribution of the compound according to the invention.
  • the formulations are prepared in a known manner, e.g. by stretching the active compound with solvents and / or excipients, if desired with use of emulsifiers and dispersants.
  • Suitable solvents / auxiliaries are essentially:
  • solvent mixtures can also be used
  • Carriers such as ground natural minerals (e.g., kaolins, clays, talc, chalk) and ground synthetic minerals (e.g., fumed silica, silicates); Emulsifiers such as nonionic and anionic emulsifiers (e.g., polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates) and dispersants such as lignin
  • the surface-active substances used are alkali metal, alkaline earth metal, ammonium salts of lignin sulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid, alkylarylsulfonates, alkyl sulfates, alkyl sulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, and condensation products of sulfonated naphthalene and naphthalene derivatives with formaldehyde , Condensation products of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ethers, tributylphenyl
  • Powders, dispersants and dusts may be prepared by mixing or co-grinding the active substances with a solid carrier.
  • Granules e.g. Coated, impregnated and homogeneous granules can be prepared by binding the active compounds to solid carriers.
  • Solid carriers are e.g. Mineral earths, such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulphate, magnesium oxide, ground plastics, fertilizers, e.g. Ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products such as cereal flour, bark, wood and nutshell flour, cellulose powder and other solid carriers.
  • Mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulphate, magnesium oxide, ground plastics,
  • the formulations generally contain between 0.01 and 95 wt .-%, preferably between 0.1 and 90 wt .-% of the active ingredient.
  • the active ingredients are used in a purity of 90% to 100%, preferably 95% to 100% (according to NMR spectrum).
  • formulations are: 1. Products for dilution in water
  • a Water-soluble concentrates (SL, LS)
  • the active compounds 20 parts by weight are dissolved in 70 parts by weight of cyclohexanone with the addition of 10 parts by weight of a dispersant, e.g. Polyvinylpyrrolidone dissolved. Dilution in water gives a dispersion.
  • a dispersant e.g. Polyvinylpyrrolidone dissolved. Dilution in water gives a dispersion.
  • the active ingredient content is 20% by weight
  • the active compounds 25 parts by weight of the active compounds are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight).
  • This mixture is added to water by means of an emulsifying machine (e.g., Ultraturax) in 30 parts by weight and made into a homogeneous emulsion. Dilution in water results in an emulsion.
  • the formulation has an active ingredient content of 25% by weight.
  • the active ingredients 20 parts by weight of the active ingredients are comminuted with the addition of 10 parts by weight of dispersants and wetting agents and 70 parts by weight of water or an organic solvent in a stirred ball mill to a fine active substance suspension. Dilution in water results in a stable suspension of the active ingredient.
  • the active ingredient content in the formulation is 20% by weight.
  • the active ingredients are finely ground with the addition of 50 parts by weight of dispersants and wetting agents and prepared by means of technical equipment (for example extrusion, spray tower, fluidized bed) as water-dispersible or water-soluble granules. Dilution in water results in a stable dispersion or solution of the active substance.
  • the formulation has an active ingredient content of 50% by weight.
  • Water-dispersible and water-soluble powders 75 parts by weight of the active compounds are ground in a rotor-stator mill with the addition of 25 parts by weight of dispersing and wetting agents and silica gel. Dilution in water results in a stable dispersion or solution of the active ingredient.
  • the active ingredient content of the formulation is 75% by weight.
  • 0.5 parts by weight of the active ingredients are finely ground and treated with 99.5 parts by weight of connected. Common processes are extrusion, spray drying or fluidized bed. This gives a granulate for direct application with 0.5 wt .-% active ingredient content.
  • LS water-soluble concentrates
  • FS suspensions
  • DS dusts
  • WS water-dispersible and water-soluble powders
  • ES emulsions
  • EC emulsifiable concentrates
  • gel formulations GF
  • the active compounds may be used as such, in the form of their formulations or the forms of use prepared therefrom, e.g. in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dusts, litter, granules by spraying, misting, dusting, scattering or pouring.
  • the forms of application depend entirely on the intended use; In any case, they should ensure the finest possible distribution of the active compounds according to the invention.
  • Aqueous application forms can be prepared from emulsion concentrates, pastes or wettable powders (spray powders, oil dispersions) by adding water.
  • the substances as such or dissolved in an oil or solvent, can be homogenized in water by means of wetter, tackifier, dispersant or emulsifier.
  • the active compound concentrations in the ready-to-use preparations can be varied within wide ranges. In general, they are between 0.0001 and 10%, preferably between 0.01 and 1%.
  • the active ingredients can also be used with great success in the ultra-low-volume (ULV) process, it being possible to apply formulations containing more than 95% by weight of active ingredient or even the active ingredient without additives.
  • UUV ultra-low-volume
  • the active substances may include oils of various types, wetting agents, adjuvants, herbicides, fungicides, other pesticides, bactericides, if appropriate also only be added immediately before application (tank mix). These agents can be added to the compositions according to the invention in a weight ratio of 1: 100 to 100: 1, preferably 1:10 to 10: 1.
  • the active ingredients were formulated separately or together as stock solution with a concentration of 10,000 ppm in DMSO.
  • the active ingredient simeconazole was used as a commercially available formulation (SANLIT WP, Sankyo Agro) and diluted with water in relation to the active ingredient.
  • the measured parameters were compared with the growth of the drug-free control variant and the fungus- and drug-free blank to determine the relative growth in% of the pathogens in the individual drugs.
  • the active compounds were prepared separately or together as a stock solution with 25 mg of active ingredient, which with a mixture of acetone and / or DMSO and the emulsifier Uniperol® EL (wetting agent with emulsifying and dispersing action based on ethoxylated alkylphenols) in the volume ratio solvent- Emulsifier from 99 to 1 ad 10 ml was filled. It was then made up to 100 ml with water. This stock solution was diluted with the described solvent-emulsifier-water mixture to the drug concentration given below.
  • Uniperol® EL wetting agent with emulsifying and dispersing action based on ethoxylated alkylphenols
  • Leaves of potted wheat seedlings of the "Riband" variety were sprayed to drip point with aqueous suspension in the concentration of active compound specified below.
  • the suspension or emulsion was prepared from a stock solution containing 10% active ingredient in a mixture consisting of 85% cyclohexanone and 5% emulsifier. 24 hours after the spray coating had dried on, they were inoculated with an aqueous spore suspension of Septoria tritici.
  • the suspension contained 2.0 x 10 6 spores / ml.
  • the test plants were then placed in the greenhouse at temperatures between 18 and 22 ° C and a relative humidity near 100%. After 2 weeks, the extent of disease development was determined visually in% infestation of the total leaf area.
  • the efficiency (W) is calculated according to the formula of Abbot as follows:
  • ⁇ corresponds to the fungal infestation of the treated plants in% and ⁇ corresponds to the fungal infestation of the untreated (control) plants in%
  • the infestation of the treated plants corresponds to that of the untreated control plants; at an efficiency of 100, the treated plants have no infestation.

Abstract

La présente invention concerne des mélanges fongicides contenant comme principes actifs du krésoxim-méthyle et du siméconazole en une quantité synergiquement active, un procédé pour lutter contre des champignons parasites avec des mélanges de principes actifs, et l'utilisation de ces principes actifs pour préparer de tels mélanges ainsi que des agents contenant ces mélanges.
PCT/EP2008/061809 2007-09-27 2008-09-05 Mélanges fongicides WO2009043686A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07117377 2007-09-27
EP07117377.7 2007-09-27

Publications (2)

Publication Number Publication Date
WO2009043686A2 true WO2009043686A2 (fr) 2009-04-09
WO2009043686A3 WO2009043686A3 (fr) 2010-01-07

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PCT/EP2008/061809 WO2009043686A2 (fr) 2007-09-27 2008-09-05 Mélanges fongicides

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AR (1) AR068572A1 (fr)
UY (1) UY31368A1 (fr)
WO (1) WO2009043686A2 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102835418A (zh) * 2012-08-22 2012-12-26 广西田园生化股份有限公司 一种含硅氟唑和甲氧基丙烯酸酯类杀菌剂的杀菌组合物
CN103563969A (zh) * 2012-07-31 2014-02-12 江苏丰源种业有限公司 防治植物病害的一种杀菌组合物
CN103583561A (zh) * 2012-08-15 2014-02-19 陕西美邦农药有限公司 一种含硅氟唑的杀菌组合物
CN109924204A (zh) * 2019-04-16 2019-06-25 亳州职业技术学院 一种可用于防治白芍白绢病的药剂组合物及其应用

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EP0531837A1 (fr) * 1991-09-12 1993-03-17 BASF Aktiengesellschaft Mélanges fongicides
WO2006069701A1 (fr) * 2004-12-23 2006-07-06 Basf Aktiengesellschaft Melanges fongicides contenant de l'enestroburine et au moins un principe actif du groupe des azoles

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EP0531837A1 (fr) * 1991-09-12 1993-03-17 BASF Aktiengesellschaft Mélanges fongicides
WO2006069701A1 (fr) * 2004-12-23 2006-07-06 Basf Aktiengesellschaft Melanges fongicides contenant de l'enestroburine et au moins un principe actif du groupe des azoles

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103563969A (zh) * 2012-07-31 2014-02-12 江苏丰源种业有限公司 防治植物病害的一种杀菌组合物
CN103583561A (zh) * 2012-08-15 2014-02-19 陕西美邦农药有限公司 一种含硅氟唑的杀菌组合物
CN103583561B (zh) * 2012-08-15 2015-09-09 陕西美邦农药有限公司 一种含硅氟唑的杀菌组合物
CN102835418A (zh) * 2012-08-22 2012-12-26 广西田园生化股份有限公司 一种含硅氟唑和甲氧基丙烯酸酯类杀菌剂的杀菌组合物
CN109924204A (zh) * 2019-04-16 2019-06-25 亳州职业技术学院 一种可用于防治白芍白绢病的药剂组合物及其应用
CN109924204B (zh) * 2019-04-16 2022-03-15 亳州职业技术学院 一种可用于防治白芍白绢病的药剂组合物及其应用

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AR068572A1 (es) 2009-11-18
UY31368A1 (es) 2009-04-30
WO2009043686A3 (fr) 2010-01-07

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