WO2009037309A1 - Cool artificial turf - Google Patents

Cool artificial turf Download PDF

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Publication number
WO2009037309A1
WO2009037309A1 PCT/EP2008/062434 EP2008062434W WO2009037309A1 WO 2009037309 A1 WO2009037309 A1 WO 2009037309A1 EP 2008062434 W EP2008062434 W EP 2008062434W WO 2009037309 A1 WO2009037309 A1 WO 2009037309A1
Authority
WO
WIPO (PCT)
Prior art keywords
artificial turf
turf surface
artificial
fibrous material
light
Prior art date
Application number
PCT/EP2008/062434
Other languages
French (fr)
Inventor
Francesco Antonius Lodewijk Harmeling
Original Assignee
Bonar Yarns & Fabrics Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bonar Yarns & Fabrics Ltd. filed Critical Bonar Yarns & Fabrics Ltd.
Priority to EP08804374A priority Critical patent/EP2203596B1/en
Priority to CN200880108243XA priority patent/CN101802310B/en
Priority to BRPI0816957 priority patent/BRPI0816957A2/en
Priority to AU2008300528A priority patent/AU2008300528B2/en
Priority to US12/675,495 priority patent/US20110117297A1/en
Priority to ES08804374T priority patent/ES2401044T3/en
Priority to JP2010525347A priority patent/JP5101699B2/en
Publication of WO2009037309A1 publication Critical patent/WO2009037309A1/en

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Classifications

    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C13/00Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
    • E01C13/08Surfaces simulating grass ; Grass-grown sports grounds
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/04Pigments
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49826Assembling or joining
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/2938Coating on discrete and individual rods, strands or filaments

Definitions

  • the present invention pertains to artificial turfs, in particular to artificial turf surfaces.
  • the first artificial turfs developed and installed already in the early 60ies were a far harder surface than grass, and soon became known as an unforgiving playing surface, which was prone to cause more injuries.
  • the other sort has a base of expanded polypropylene, a foamy material originally developed as a shock absorber for the car industry.
  • the grass is also made of lubricated polyethylene fibers, but they are shorter and more densely packed than on an infilled pitch, and are also interspersed with short, curly, spring-like fibers that keep the blades upright.
  • the finishing touch is an 8- millimeter filling of rubber granules.
  • artificial turfs are mostly applied in sport arenas, in the context of this invention the meaning of "artificial turf” is used in a broader sense, encompassing any applications and modification that comprise synthetic grass, i.e. grass that is made of a synthetic material, usually a polymer such as polyethylene, polypropylene and the like.
  • additional applications comprise but are not limited to landscape applications and to green roofs on buildings.
  • the components used for artificial turf surfaces comprise - as mentioned above - fibers, filaments and tapes, and if applicable infill materials.
  • US 3,740,303 discloses an artificial playing surface that comprise a pile fabric with pile fibers having pigments and materials to stabilize against UV light. These stabilizers usually are sterically hindered amines that catch the radicals generated by the energy of the UV light.
  • US 2004/0214000 is directed to aggregate turf filler for use with the turf of athletic fields and landscape area, which comprise crushed silica sand particles. Such fillers may be colored to enhance the appearance of the surface.
  • US 5,958,527 discloses a synthetic grass turf with a unique multiple course resilient particulate infill.
  • the infill consists of brightly colored sand and should serve the purpose to reduce the heat retention of the infill.
  • US 2003/0056432 discloses a synthetic grass surface with widely spaced rows of ribbons projecting from a flexible backing sheet which grass surface comprises thermal regulation means attached to the backing sheet in the spaces.
  • the synthetic grass surface could comprise synthetic ribbons that could be made from heat reflecting material.
  • an artificial turf surface comprising fibrous materials, such as fibers, filaments and/or tapes, and if applicable infill materials, wherein the artificial turf surface additionally comprises one or more additive(s) that reflect(s) light, characterized in that the additive(s) is or are incorporated in the fibrous material, preferably located at the surface of the fibrous material.
  • the present invention restricts the presence of the additives and/or pigments to be incorporated into the fibrous material with a preferred location at the surface of the fibrous material, possibly with kind of a concentration gradient from the inner to the outer portions of the fibrous material, i.e. the concentration becoming higher in those portions that are closer to the surface. That leaves the other properties of the fibrous material substantially unchanged, which is important for the suitability of the artificial turf for e.g. ball rolling etc.
  • an artificial turf assembly typically includes a pile fabric with a flexible sheet backing and rows of upstanding synthetic ribbons tufted through the flexible backing, representing grass blades, extending upwardly from an upper surface of the backing.
  • the term "fibrous material" thus predominately encompasses those fibers filaments and tapes that form the sheet backing and the synthetic ribbons, among them the synthetic ribbons are preferred as location for the additives and/or pigments.
  • the light reflectance obtained by the addition of the additives and/or pigments is at least 10 % higher in spectral reflectance and/or IR reflectance measurements compared to artificial turf surfaces without these additives and/or pigments.
  • the term "light” is used in its physical meaning and encompasses a wavelength range of the total solar reflectance, which is the sum of ultraviolet, visible and near infra-red reflectance. The higher the solar reflectance the cooler the object will stay.
  • reflectance is applied in the range from about 380 nm to about 1 mm, i.e. the spectrum of both the visible light (from about 380 nm to about 780 nm) and the infrared light (from about 700 nm to about 1 mm).
  • Particularly preferred is the reflectance of the heat radiation in the infrared spectrum as IR makes up 52% of the spectrum and thus a significant portion of the sun's energy.
  • NIR near infrared
  • the light reflectance is at least as high as that of a natural grass turf surface, preferably 10 %, even more preferred 20 %, higher than that of a natural grass turf surface.
  • the additives or pigments thus have the property to reflect heat generated by sunlight and other light or heat sources in at least the same order of magnitude as Chlorophyll - the green pigment in natural turf - does, whilst pigments currently used in artificial turf have a higher IR absorption.
  • the additive(s) or pigment(s) is or are incorporated in the fibrous material, even more preferably it is or are located at or near the surface of the fibrous material.
  • any pigment that is capable to reflect light preferably infra red light
  • any pigment that is capable to reflect light can be used as additive. It is, however, preferred to apply as additives those pigments that are selected from a group containing metal oxides, mixed metal oxides, cobalt compounds and chromium compounds such as titanium dioxide, aluminium platelet pigments and chromium oxide.
  • additives such as MgAI 2 O 4 , after which this class of minerals is named
  • spinels mixed oxides such as MgAI 2 O 4 , after which this class of minerals is named
  • additives and/or pigments of the class metal-oxide titanates based on antimony, chromium, tin and cobalt are all non toxic and have both FDA and EEC purity approvals in the quantities used.
  • IR reflective inorganic pigments such as C.I. Pigment Black 30, a spinel formulated primarily with nickel, manganese, chrome and iron, and C.I. Pigment Green 17, a chromium green black hematite, are known to the skilled person.
  • the fibrous material is made of a synthetic polymer, even more preferred if the polymer is selected from a group containing polyethylene, polypropylene, plastomer blends, nylon and copolymers and/or blends thereof.
  • the pigments are added in an amount that ranges from about 0.5% to about 4% wt.-% in relation to the polymer.
  • This invention is especially an advantage for sport fields and landscape applications to increase the player's and users comfort and safety aspects.
  • Another important claim for this invention is energy savings. Where artificial turf is used as a kind of insulation material to prevent - heat build up - of that what has been covered by it. For example green roofs on buildings etc. to reduce energy cost for climate control systems.
  • this invention pertains also to the use of the artificial turf surface for sport fields and landscape applications and to the use of the artificial turf as heat insulation in green roofs on buildings.
  • the invention is further elucidated by the following non-limiting example(s).
  • Hemispherical spectral reflectance measurements were performed in accordance with ASTM Standard Test Method E903 (1996). The measurements were performed with a Perkin-Elmer Lambda 950 Spectrophotometer utilizing an integrating sphere (Fig A1.3 of E903 [1996]). Total reflectance measurements were obtained in the solar spectrum from 2500 nm to 300 nm at an incident angle of 8°. The measurements employ a detector-baffled, wall-mounted-integrating sphere that precludes the necessity of employing a reference standard except to define the instrument's 100% line. The measurements are properly denoted as being ' hemispherical spectral reflectance'.
  • Total solar p reflectance was obtained by integrating the spectral data against Air Mass 1.5 (ASTM G159-98) direct solar spectrum utilizing 105 weighted ordinates.
  • the NIR region from 724 nm to 2494 nm was obtained by integrating the spectral data against Air Mass 1.5 (ASTM G159-98) direct solar spectrum utilizing 66 weighted ordinates.
  • the measured artificial grass specimens were cut from larger specimens that were used for a temperature study.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Road Paving Structures (AREA)

Abstract

An artificial turf surface comprising fibrous materials, such as fibers, filaments and/or tapes, and if applicable infill materials, wherein the artificial turf surface additionally comprises one or more additive(s) that reflect(s) light, characterized in that the additive(s) is or are incorporated in the fibrous material, preferably located at the surface of the fibrous material.

Description

Cool Artificial Turf
Description:
The present invention pertains to artificial turfs, in particular to artificial turf surfaces.
Artificial turfs or synthetic turfs are known as grass-like man-made surfaces manufactured from synthetic materials. They are most often used in arenas for sports that were originally or are normally played on grass; however, it is now being used on residential lawns and commercial applications, as well.
The first artificial turfs developed and installed already in the early 60ies were a far harder surface than grass, and soon became known as an unforgiving playing surface, which was prone to cause more injuries.
In the early 21 st century, new artificial playing surfaces using sand and/or rubber infill were developed. These "next generation", of artificial grass surfaces are often virtually indistinguishable from grass when viewed from any distance, and are generally regarded as being about as safe to play on as a typical grass surface — perhaps even safer in cold conditions.
Many clubs have installed the new synthetic turf surfaces (most commonly as part of an all-weather training capability), while some clubs which have maintained grass surfaces are now re-considering artificial turf. With football clubs in Europe looking to reduce both maintenance costs and the number of winter matches that are cancelled due to frozen pitches, the issue has also been re-visited by that sport's governing bodies. The most common type uses polyethylene "grass" about 5 centimeters long, which is lubricated and tufted into a woven backing fabric the rear of which is coated with a polyurethane or latex backing medium to lock the tufts in to place. The whole thing is then infilled to the client's specification with sand and rubber granules, which keeps the fibers upright and provides the right level of shock absorbency and deformability. The majority of the 15 or so turf manufacturers approved by FIFA use this technology. The other sort has a base of expanded polypropylene, a foamy material originally developed as a shock absorber for the car industry. The grass is also made of lubricated polyethylene fibers, but they are shorter and more densely packed than on an infilled pitch, and are also interspersed with short, curly, spring-like fibers that keep the blades upright. The finishing touch is an 8- millimeter filling of rubber granules.
Although artificial turfs are mostly applied in sport arenas, in the context of this invention the meaning of "artificial turf" is used in a broader sense, encompassing any applications and modification that comprise synthetic grass, i.e. grass that is made of a synthetic material, usually a polymer such as polyethylene, polypropylene and the like. Such additional applications comprise but are not limited to landscape applications and to green roofs on buildings.
The components used for artificial turf surfaces comprise - as mentioned above - fibers, filaments and tapes, and if applicable infill materials.
Whilst already having advantages over natural grass surfaces in cold areas or in the wintertime, the overall comfort of artificial turfs in hotter climates or seasons is still subject to improvement.
US 3,740,303 discloses an artificial playing surface that comprise a pile fabric with pile fibers having pigments and materials to stabilize against UV light. These stabilizers usually are sterically hindered amines that catch the radicals generated by the energy of the UV light.
US 2004/0214000 is directed to aggregate turf filler for use with the turf of athletic fields and landscape area, which comprise crushed silica sand particles. Such fillers may be colored to enhance the appearance of the surface.
US 5,958,527 discloses a synthetic grass turf with a unique multiple course resilient particulate infill. The infill consists of brightly colored sand and should serve the purpose to reduce the heat retention of the infill.
US 2003/0056432 discloses a synthetic grass surface with widely spaced rows of ribbons projecting from a flexible backing sheet which grass surface comprises thermal regulation means attached to the backing sheet in the spaces. The synthetic grass surface could comprise synthetic ribbons that could be made from heat reflecting material.
It is thus an objective of the invention to provide an artificial turf that offers comfort and safety both under hot and cold conditions and which can easily and reliably be manufactured and installed.
This objective is being achieved by an artificial turf surface comprising fibrous materials, such as fibers, filaments and/or tapes, and if applicable infill materials, wherein the artificial turf surface additionally comprises one or more additive(s) that reflect(s) light, characterized in that the additive(s) is or are incorporated in the fibrous material, preferably located at the surface of the fibrous material.
In contrast to the prior art, the present invention restricts the presence of the additives and/or pigments to be incorporated into the fibrous material with a preferred location at the surface of the fibrous material, possibly with kind of a concentration gradient from the inner to the outer portions of the fibrous material, i.e. the concentration becoming higher in those portions that are closer to the surface. That leaves the other properties of the fibrous material substantially unchanged, which is important for the suitability of the artificial turf for e.g. ball rolling etc.
Typically, an artificial turf assembly includes a pile fabric with a flexible sheet backing and rows of upstanding synthetic ribbons tufted through the flexible backing, representing grass blades, extending upwardly from an upper surface of the backing. The term "fibrous material" thus predominately encompasses those fibers filaments and tapes that form the sheet backing and the synthetic ribbons, among them the synthetic ribbons are preferred as location for the additives and/or pigments.
The light reflectance obtained by the addition of the additives and/or pigments is at least 10 % higher in spectral reflectance and/or IR reflectance measurements compared to artificial turf surfaces without these additives and/or pigments.
The terms additives and pigments are being used likewise in the description of the invention.
For this invention the term "light" is used in its physical meaning and encompasses a wavelength range of the total solar reflectance, which is the sum of ultraviolet, visible and near infra-red reflectance. The higher the solar reflectance the cooler the object will stay. Preferably, reflectance is applied in the range from about 380 nm to about 1 mm, i.e. the spectrum of both the visible light (from about 380 nm to about 780 nm) and the infrared light (from about 700 nm to about 1 mm). Particularly preferred is the reflectance of the heat radiation in the infrared spectrum as IR makes up 52% of the spectrum and thus a significant portion of the sun's energy.
For this reason additives and/or pigments with an increased reflectance in the so- called near infrared (NIR) range, i.e. in the wavelength range from about 700 nm to about 3000 nm, even more preferred from 800 nm to 2500 nm, are preferred.
Preferably, the light reflectance is at least as high as that of a natural grass turf surface, preferably 10 %, even more preferred 20 %, higher than that of a natural grass turf surface.
The additives or pigments thus have the property to reflect heat generated by sunlight and other light or heat sources in at least the same order of magnitude as Chlorophyll - the green pigment in natural turf - does, whilst pigments currently used in artificial turf have a higher IR absorption. Preferably, the additive(s) or pigment(s) is or are incorporated in the fibrous material, even more preferably it is or are located at or near the surface of the fibrous material.
Any pigment that is capable to reflect light, preferably infra red light, can be used as additive. It is, however, preferred to apply as additives those pigments that are selected from a group containing metal oxides, mixed metal oxides, cobalt compounds and chromium compounds such as titanium dioxide, aluminium platelet pigments and chromium oxide.
Among suitable additives the so-called spinels (mixed oxides such as MgAI2O4, after which this class of minerals is named) are particularly preferred. Further preferred are additives and/or pigments of the class metal-oxide titanates based on antimony, chromium, tin and cobalt. These pigments are all non toxic and have both FDA and EEC purity approvals in the quantities used.
IR reflective inorganic pigments such as C.I. Pigment Black 30, a spinel formulated primarily with nickel, manganese, chrome and iron, and C.I. Pigment Green 17, a chromium green black hematite, are known to the skilled person.
It is preferred that the fibrous material is made of a synthetic polymer, even more preferred if the polymer is selected from a group containing polyethylene, polypropylene, plastomer blends, nylon and copolymers and/or blends thereof.
The pigments are added in an amount that ranges from about 0.5% to about 4% wt.-% in relation to the polymer.
Artificial turfs having a surface according to the invention exhibit a considerably reduced surface temperature. A temperature decrease by 15 0C can easily be achieved.
This invention is especially an advantage for sport fields and landscape applications to increase the player's and users comfort and safety aspects.
Another important claim for this invention is energy savings. Where artificial turf is used as a kind of insulation material to prevent - heat build up - of that what has been covered by it. For example green roofs on buildings etc. to reduce energy cost for climate control systems.
As a consequence this invention pertains also to the use of the artificial turf surface for sport fields and landscape applications and to the use of the artificial turf as heat insulation in green roofs on buildings.
The invention is further elucidated by the following non-limiting example(s).
Hemispherical spectral reflectance measurements were performed in accordance with ASTM Standard Test Method E903 (1996). The measurements were performed with a Perkin-Elmer Lambda 950 Spectrophotometer utilizing an integrating sphere (Fig A1.3 of E903 [1996]). Total reflectance measurements were obtained in the solar spectrum from 2500 nm to 300 nm at an incident angle of 8°. The measurements employ a detector-baffled, wall-mounted-integrating sphere that precludes the necessity of employing a reference standard except to define the instrument's 100% line. The measurements are properly denoted as being 'hemispherical spectral reflectance'.
Total solar p reflectance was obtained by integrating the spectral data against Air Mass 1.5 (ASTM G159-98) direct solar spectrum utilizing 105 weighted ordinates.
The NIR region from 724 nm to 2494 nm was obtained by integrating the spectral data against Air Mass 1.5 (ASTM G159-98) direct solar spectrum utilizing 66 weighted ordinates.
The measured artificial grass specimens were cut from larger specimens that were used for a temperature study.
With all test methods, there typically is a level of uncertainty for the test data due to the acceptable operating tolerances of the instrumentation and variation caused by the test method. The estimated tolerances are expected to be less than plus or minus 2% for most materials tested to ASTM E903. Table
Figure imgf000008_0001

Claims

Cool Artificial TurfClaims:
1. An artificial turf surface comprising fibrous materials, such as fibers, filaments and/or tapes, and if applicable infill materials, wherein the artificial turf surface additionally comprises one or more additive(s) that reflect(s) light, characterized in that the additive(s) is or are incorporated in the fibrous material, preferably located at the surface of the fibrous material.
2. The artificial turf surface of claim 1 , wherein the light is the infrared (IR) light in a wavelength range from about 700 nm to about 1 mm.
3. The artificial turf surface according to any of the preceding claims, wherein the additives are pigments selected from a group containing metal oxides, mixed metal oxides, cobalt compounds and chromium compounds.
4. The artificial turf surface according to any of the preceding claims, wherein the fibrous material is selected from a group containing polyethylene, polypropylene, plastomer blends, nylon, and copolymers and blends thereof.
5. Use of the artificial turf surface according to any of the preceding claims for sport fields and landscape applications.
6. Use of the artificial turf surface according to any of the preceding claims as heat insulation in green roofs on buildings.
PCT/EP2008/062434 2007-09-22 2008-09-18 Cool artificial turf WO2009037309A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP08804374A EP2203596B1 (en) 2007-09-22 2008-09-18 Cool artificial turf
CN200880108243XA CN101802310B (en) 2007-09-22 2008-09-18 Cool artificial turf
BRPI0816957 BRPI0816957A2 (en) 2007-09-22 2008-09-18 Fibrous material, artificial turf surface, and use of artificial turf surface
AU2008300528A AU2008300528B2 (en) 2007-09-22 2008-09-18 Cool artificial turf
US12/675,495 US20110117297A1 (en) 2007-09-22 2008-09-18 Cool artificial turf
ES08804374T ES2401044T3 (en) 2007-09-22 2008-09-18 Fresh artificial grass
JP2010525347A JP5101699B2 (en) 2007-09-22 2008-09-18 Cool artificial grass

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07018670A EP2039830A1 (en) 2007-09-22 2007-09-22 Cool artifical turf
EP07018670.5 2007-09-22

Publications (1)

Publication Number Publication Date
WO2009037309A1 true WO2009037309A1 (en) 2009-03-26

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Country Status (9)

Country Link
US (1) US20110117297A1 (en)
EP (3) EP2039830A1 (en)
JP (1) JP5101699B2 (en)
CN (1) CN101802310B (en)
AU (1) AU2008300528B2 (en)
BR (1) BRPI0816957A2 (en)
ES (1) ES2401044T3 (en)
PT (1) PT2203596E (en)
WO (1) WO2009037309A1 (en)

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US20130034671A1 (en) * 2011-08-03 2013-02-07 Milo George Chlorophyll cooling agent for synthetic turf components
US20130177718A1 (en) * 2011-07-14 2013-07-11 Turf Group Llc Special Coatings for Artificial Turf

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US8795834B2 (en) 2009-02-09 2014-08-05 Sapturf, Llc Synthetic turf having cooling layer
US9435083B2 (en) 2011-07-14 2016-09-06 Turf Group Llc Special coatings and infill for artificial turf
CN102797322A (en) * 2012-08-14 2012-11-28 青岛青禾人造草坪有限公司 Artificial lawn with infrared reflecting function for greening roof
KR101398802B1 (en) 2014-02-11 2014-05-27 필드마스터 주식회사 Artificial grass composition of thermal shutdown function, and artificial grass structure using the composition
US10563361B2 (en) 2016-01-12 2020-02-18 Ch3 Solutions, Llc System and method for customizing a playing field
US10060083B2 (en) 2016-01-12 2018-08-28 Versacourt, Llc Spring tension system for tile
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ES2401044T3 (en) 2013-04-16
AU2008300528A1 (en) 2009-03-26
AU2008300528B2 (en) 2011-09-08
EP2039830A1 (en) 2009-03-25
BRPI0816957A2 (en) 2015-03-24
EP2546416A1 (en) 2013-01-16
PT2203596E (en) 2013-03-05
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CN101802310A (en) 2010-08-11
CN101802310B (en) 2012-08-08

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