WO2009035851A3 - Methods and apparatus for producing ethanol from syngas with high carbon efficiency - Google Patents

Methods and apparatus for producing ethanol from syngas with high carbon efficiency Download PDF

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Publication number
WO2009035851A3
WO2009035851A3 PCT/US2008/074456 US2008074456W WO2009035851A3 WO 2009035851 A3 WO2009035851 A3 WO 2009035851A3 US 2008074456 W US2008074456 W US 2008074456W WO 2009035851 A3 WO2009035851 A3 WO 2009035851A3
Authority
WO
WIPO (PCT)
Prior art keywords
syngas
selectivities
alcohols
ethanol
methods
Prior art date
Application number
PCT/US2008/074456
Other languages
French (fr)
Other versions
WO2009035851A2 (en
Inventor
Heinz Juergen Robota
Original Assignee
Range Fuels Inc
Heinz Juergen Robota
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Range Fuels Inc, Heinz Juergen Robota filed Critical Range Fuels Inc
Priority to BRPI0815534-8A2A priority Critical patent/BRPI0815534A2/en
Priority to CA2698414A priority patent/CA2698414A1/en
Priority to AU2008299253A priority patent/AU2008299253A1/en
Priority to MX2010002545A priority patent/MX2010002545A/en
Priority to EP08798789A priority patent/EP2185490A2/en
Publication of WO2009035851A2 publication Critical patent/WO2009035851A2/en
Publication of WO2009035851A3 publication Critical patent/WO2009035851A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The present invention discloses and teaches new methods of converting syngas into ethanol and/or other higher alcohols. Preferred embodiments recycle methanol, partially convert it to syngas, and then convert this additional syngas also to C2+ alcohols. Generally, the invention provides reactors comprising catalysts capable of converting syngas to alcohols with low selectivities to carbon dioxide and methane, and further provides process strategies to separate and recycle unreacted syngas as well as methanol produced by the catalyst. The invention is capable of turning modest per-pass reaction selectivities to a particular alcohol, such as ethanol, into economically significant net selectivities and yields.
PCT/US2008/074456 2007-09-07 2008-08-27 Methods and apparatus for producing ethanol from syngas with high carbon efficiency WO2009035851A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BRPI0815534-8A2A BRPI0815534A2 (en) 2007-09-07 2008-08-27 "METHOD FOR PRODUCING AT LEAST ONE ALCOHOL C2-C4 FROM SYNTHESIS GAS, METHOD FOR PRODUCING ETHANOL FROM SYNTHESIS GAS ABLE TO REPRODUCE AT LEAST ONE ALCOHOL C2-G4 FROM A
CA2698414A CA2698414A1 (en) 2007-09-07 2008-08-27 Methods and apparatus for producing ethanol from syngas with high carbon efficiency
AU2008299253A AU2008299253A1 (en) 2007-09-07 2008-08-27 Methods and apparatus for producing ethanol from syngas with high carbon efficiency
MX2010002545A MX2010002545A (en) 2007-09-07 2008-08-27 Methods and apparatus for producing ethanol from syngas with high carbon efficiency.
EP08798789A EP2185490A2 (en) 2007-09-07 2008-08-27 Methods and apparatus for producing ethanol from syngas with high carbon efficiency

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US97066007P 2007-09-07 2007-09-07
US60/970,660 2007-09-07
US12/198,208 US20090069452A1 (en) 2007-09-07 2008-08-26 Methods and apparatus for producing ethanol from syngas with high carbon efficiency
US12/198,208 2008-08-26

Publications (2)

Publication Number Publication Date
WO2009035851A2 WO2009035851A2 (en) 2009-03-19
WO2009035851A3 true WO2009035851A3 (en) 2009-04-30

Family

ID=40432573

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/074456 WO2009035851A2 (en) 2007-09-07 2008-08-27 Methods and apparatus for producing ethanol from syngas with high carbon efficiency

Country Status (7)

Country Link
US (1) US20090069452A1 (en)
EP (1) EP2185490A2 (en)
AU (1) AU2008299253A1 (en)
BR (1) BRPI0815534A2 (en)
CA (1) CA2698414A1 (en)
MX (1) MX2010002545A (en)
WO (1) WO2009035851A2 (en)

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EP2382174A4 (en) 2009-01-29 2013-10-30 Trustees Of The University Of Princeton Conversion of carbon dioxide to organic products
US9663363B2 (en) 2009-06-09 2017-05-30 Sundrop Fuels, Inc. Various methods and apparatuses for multi-stage synthesis gas generation
US8709112B2 (en) * 2009-06-09 2014-04-29 Sundrop Fuels, Inc. Systems and methods for quenching, gas clean up, and ash removal
US8814961B2 (en) 2009-06-09 2014-08-26 Sundrop Fuels, Inc. Various methods and apparatuses for a radiant-heat driven chemical reactor
EP2483452A4 (en) * 2009-10-04 2016-08-17 Nanomaterials Discovery Corp Process for co-production of power and carboxylic acids
US8721866B2 (en) * 2010-03-19 2014-05-13 Liquid Light, Inc. Electrochemical production of synthesis gas from carbon dioxide
US8500987B2 (en) 2010-03-19 2013-08-06 Liquid Light, Inc. Purification of carbon dioxide from a mixture of gases
US8845877B2 (en) * 2010-03-19 2014-09-30 Liquid Light, Inc. Heterocycle catalyzed electrochemical process
US8585789B2 (en) 2010-04-13 2013-11-19 Ineos Usa Llc Methods for gasification of carbonaceous materials
US8580152B2 (en) 2010-04-13 2013-11-12 Ineos Usa Llc Methods for gasification of carbonaceous materials
US8999021B2 (en) 2010-04-13 2015-04-07 Ineos Usa Llc Methods for gasification of carbonaceous materials
US8524066B2 (en) 2010-07-29 2013-09-03 Liquid Light, Inc. Electrochemical production of urea from NOx and carbon dioxide
US8845878B2 (en) 2010-07-29 2014-09-30 Liquid Light, Inc. Reducing carbon dioxide to products
US8961774B2 (en) 2010-11-30 2015-02-24 Liquid Light, Inc. Electrochemical production of butanol from carbon dioxide and water
US8568581B2 (en) 2010-11-30 2013-10-29 Liquid Light, Inc. Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide
US9090976B2 (en) 2010-12-30 2015-07-28 The Trustees Of Princeton University Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction
US8562811B2 (en) 2011-03-09 2013-10-22 Liquid Light, Inc. Process for making formic acid
BR112014000052A2 (en) 2011-07-06 2017-02-07 Liquid Light Inc reduction of carbon dioxide in carboxylic acids, glycols and carboxylates
AU2012278948A1 (en) 2011-07-06 2014-01-16 Liquid Light, Inc. Carbon dioxide capture and conversion to organic products
US20140066527A1 (en) * 2012-03-16 2014-03-06 Melissa Gaucher Synthesis Gas Reaction and Processing System
US9149739B2 (en) 2012-05-17 2015-10-06 Fluor Technologies Coporation Production of higher alcohols with minimum methanol content from the gasification of carbonaceous materials
US10221115B2 (en) 2012-05-17 2019-03-05 Fluor Technologies Corporation Methods and system for decreasing gas emissions from landfills
EA201591126A1 (en) 2012-12-20 2015-12-30 Хальдор Топсёэ А/С METHOD AND DEVICE FOR OBTAINING HIGH ALCOHOLS
CN104788284B (en) * 2015-05-07 2017-01-04 中石化上海工程有限公司 The continuous producing method of low carbon alcohol by synthetic gas
US10287507B2 (en) 2016-01-19 2019-05-14 Fluor Technologies Corporation Conversion of waste CO2 into useful transport fuels using steam methane reformer in a gas to liquids plant
FR3050123B1 (en) * 2016-04-15 2021-01-22 Engie DEVICE AND METHOD FOR HYDROGENATION OF CO2 TO PRODUCE METHANOL AND DEVICE AND PROCESS FOR COGENERATION OF METHANOL AND SYNTHETIC METHANE
DE102016006709A1 (en) 2016-06-01 2017-12-07 Linde Aktiengesellschaft Process and plant for the production of ethanol
DE102016006707A1 (en) * 2016-06-01 2017-12-07 Linde Aktiengesellschaft Process and plant for the production of ethanol
DE102016006713A1 (en) 2016-06-01 2017-12-07 Linde Aktiengesellschaft Process and plant for the production of ethanol
DE102017003840A1 (en) 2017-04-20 2018-10-25 Linde Aktiengesellschaft Process and plant for the production of ethanol

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1983003409A1 (en) * 1982-03-26 1983-10-13 Bradley, Michael, William Process for the production of ethanol
US4751248A (en) * 1987-07-02 1988-06-14 Phillips Petroleum Company Preparation of alcohols from synthesis gas
EP0353920A2 (en) * 1988-08-01 1990-02-07 Texaco Development Corporation Slurry-phase process to increase yield of mixed alcohols from synthesis gas
US6248796B1 (en) * 1999-11-13 2001-06-19 Powerenercat. Inc. Method for production of mixed alcohols from synthesis gas

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4301253A (en) * 1980-09-25 1981-11-17 Union Carbide Corporation Process for the selective production of ethanol and methanol directly from synthesis gas
US4882360A (en) * 1984-07-30 1989-11-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4670473A (en) * 1985-08-09 1987-06-02 Amoco Corporation Syn gas conversion
WO2002074760A1 (en) * 2001-03-16 2002-09-26 E.I. Dupont De Nemours And Company Production of 5-methylbutyrolactone from levulinic acid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1983003409A1 (en) * 1982-03-26 1983-10-13 Bradley, Michael, William Process for the production of ethanol
US4751248A (en) * 1987-07-02 1988-06-14 Phillips Petroleum Company Preparation of alcohols from synthesis gas
EP0353920A2 (en) * 1988-08-01 1990-02-07 Texaco Development Corporation Slurry-phase process to increase yield of mixed alcohols from synthesis gas
US6248796B1 (en) * 1999-11-13 2001-06-19 Powerenercat. Inc. Method for production of mixed alcohols from synthesis gas

Also Published As

Publication number Publication date
BRPI0815534A2 (en) 2015-02-10
EP2185490A2 (en) 2010-05-19
AU2008299253A1 (en) 2009-03-19
MX2010002545A (en) 2010-05-20
US20090069452A1 (en) 2009-03-12
WO2009035851A2 (en) 2009-03-19
CA2698414A1 (en) 2009-03-19

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