WO2009027029A2 - Composition herbicide et procédé d'utilisation - Google Patents

Composition herbicide et procédé d'utilisation Download PDF

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Publication number
WO2009027029A2
WO2009027029A2 PCT/EP2008/006772 EP2008006772W WO2009027029A2 WO 2009027029 A2 WO2009027029 A2 WO 2009027029A2 EP 2008006772 W EP2008006772 W EP 2008006772W WO 2009027029 A2 WO2009027029 A2 WO 2009027029A2
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WIPO (PCT)
Prior art keywords
mesotrione
spp
clopyralid
weeds
composition
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PCT/EP2008/006772
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English (en)
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WO2009027029A3 (fr
Inventor
Cheryl Lynn Dunne
John R. James
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Syngenta Participations Ag
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Publication of WO2009027029A2 publication Critical patent/WO2009027029A2/fr
Publication of WO2009027029A3 publication Critical patent/WO2009027029A3/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

Definitions

  • the present invention relates to a method of controlling the growth of weeds, in particular white clover, using a herbicidal composition comprising mesotrione and clopyralid.
  • herbicidal active ingredients have been shown to be more effective in combination than when applied individually, and this is referred to as "synergism", since the combination demonstrates a potency or activity level exceeding that which it would be expected to have based on knowledge of the individual potencies of the components.
  • the present invention resides in the discovery that mesotrione, or a salt or metal chelate thereof, and clopyralid, already known individually for their herbicidal properties, display a synergistic effect when applied in combination to weeds such as white clover.
  • the herbicidal compounds forming the composition of this invention are independently known in the art for their effects on plant growth. They are disclosed in 'The Pesticide Manual', ibid, and are also commercially available.
  • Mesotrione (2-(2'-nitro-4'-methylsulphonylbenzoyl)-l,3-cyclohexanedione) is a member of an important class of selective herbicides, the triketones and works by affecting carotenoid biosynthesis. In particular, it inhibits the enzyme 4-hydroxyphenyl-pyruvate dioxygenase (it is an HPPD-inhibitor).
  • its structure can be represented as:
  • mesotrione In addition to the acid form, mesotrione also forms salts and metal chelate, for example, a copper chelate.
  • metal chelates are disclosed, inter alia, in US Patent No. 5,912,207 (the disclosure of which is herein incorporated by reference) where they are shown to have unexpectedly superior stability in certain environments when compared to unchelated mesotrione.
  • Mesotrione is best known for its ability to control a wide spectrum of broadleaf weeds at a wide range of growth stages when applied post-emergence on corn and turfgrass. It is typically used at a low rate (100-225 grams of active ingredient per hectare depending on herbicide formulation on application timing) to control weeds which are present at application and which emerge for up to four weeks afterwards. Once applied, mesotrione is rapidly absorbed by the leaves, shoots, roots and seeds. In susceptible weeds, it disrupts carotenoid biosynthesis, an essential process for plant growth and this leads to plant death. Unlike weeds, corn plants and certain turfgrass species are able to tolerate mesotrione by rapidly breaking down the active compound into inactive compounds.
  • Clopyralid is a selective systemic herbicide from the class of pyridinecarboxylic acids.
  • the chemical name for clopyralid is 3,6-chloro-2-pyridinecarboxylic acid, and its structure can be represented as:
  • the present invention provides a method for controlling or modifying the growth of large crabgrass or white clover, comprising applying to the locus of the large crabgrass or white clover, a herbicidally effective amount of a composition comprising a mixture of mesotrione and clopyralid.
  • the composition contains a herbicidally effective amount of a combination of mesotrione and clopyralid.
  • 'herbicide' as used herein denotes a compound which controls or modifies the growth of plants.
  • 'herbicidally effective amount' indicates the quantity of such a compound or combination of such compounds which is capable of producing a controlling or modifying effect on the growth of plants. Controlling or modifying effects include all deviation from natural development, for example: killing, retardation, leaf burn, albinism, dwarfing and the like. For example, plants that are not killed are often stunted and non-competitive with flowering disrupted.
  • the term 'plants' refers to all physical parts of a plant, including seeds, seedlings, saplings, roots, tubers, stems, stalks, foliage and fruits.
  • mesotrione is only one of a number of herbicides that act as HPPD inhibitors.
  • Other HPPD inhibitors are also known and may be used in the composition of the present invention in place of mesotrione.
  • other HPPD inhibitors for use in the present invention may be selected from the group consisting of triketones, isoxazoles, pyrazoles, benzobicyclon and ketospiradox. Further details of the individual compounds which fall within the triketones, isoxazoles and pyrazoles may be found in PCT Publication No.
  • HPPD inhibitors for use in the present invention in place of mesotrione include tembotrione, topramezone, and a compound of formula I
  • the designation 'mesotrione' includes the salts and chelated forms of mesotrione as well as the acid form and also includes any enolic tautomeric forms that may - A -
  • the mesotrione is present as the acid form. In a further embodiment, mesotrione is present as a salt or a metal chelate.
  • Suitable salts of mesotrione include salts of cations or anions which are known and accepted in the art for the formation of salts for agricultural or horticultural use. Such salts may be formed, for example, using amines, alkali metal bases, alkaline earth metal bases and quaternary ammonium bases.
  • metal chelates of 2-(substituted benzoyl)- 1,3-cyclohexanedione compounds including mesotrione are described, inter alia, in US Patent No. 5,912,207.
  • suitable metal chelates of mesotrione have the general structure:
  • M represents a di- or trivalent metal ion.
  • the di- or trivalent metal ion may be a Cu 2+ , Co 2+ , Zn 2+ , Ni 2+ , Ca 2+ , Al 3+ , Ti 3+ or Fe 3+ ion. More suitably, the metal ion may be a divalent transition metal ion such as
  • Herbicidal metal chelates of mesotrione for use in this invention may be prepared by the methods described in the aforementioned US Patent, or by the application and adaptation of known methods used or described in the chemical literature, hi particular, any appropriate salt which would be a source of a di- or trivalent metal ion may be used to form the metal chelate of the dione compound in accordance with this invention.
  • Particularly suitable salts include chlorides, sulphates, nitrates, carbonates, phosphates and acetates.
  • the composition for use in the invention comprises mesotrione and clopyralid in a synergistically effective amount.
  • the weight ratio of mesotrione to clopyralid at which the herbicidal effect is synergistic lies within the range of from about 1:50 to about 50:1 by weight.
  • the weight ratio of mesotrione to clopyralid is from about 1 :25 to about 25:1 by weight. More suitably, the weight ratio of mesotrione to clopyralid herbicide is from about 1 :10 to about 10:1 by weight, with a weight ratio of from about 6: 1 to about 1 :2 by weight being particularly suitable.
  • compositions of the invention can be applied at an application rate of between 0.005 kilograms/hectare (kg/ha) and about 5.0kg/ha, based on the total amount of active ingredient (mesotrione and clopyralid) in the composition.
  • An application rate of between about 0.1 kg/ha and about 3.0 kg/ha is preferred, with an application rate of between about 0.5 kg/ha and 1.2 kg/ha being especially preferred. It is noted that the rates used in the examples below are glasshouse rates and are lower than those normally applied in the field as herbicide effects tend to be magnified in such conditions.
  • composition of the invention may be used to control a large number of agronomically important weeds, including monocotyledonous weeds and dicotyledonous weeds.
  • the invention may be used to control dicotyledonous weeds such as Abutilon spp., Ambrosia spp., Amaranthus spp., Chenopodium spp., Erysimum spp., Euphorbia spp., Fallopia spp., Galium spp., Hydrocotyle spp., Ipomoea spp., Lamium spp., Medicago spp., Oxalis spp., Plantago spp., Polygonum spp., Richardia spp., 5t ⁇ spp., Sinapis spp., Solarium spp., Stellaria spp., Taraxacum spp., T ⁇ folium spp., Veronica spp., F/o/ ⁇ spp. and Xanthium spp..
  • dicotyledonous weeds such as Abutilon spp., Ambrosia
  • the invention may also be used to control monocotyledonous weeds such as Agrostis spp., Alopecurus spp., Apera spp., Avena spp., Brachiaria spp., Bromus spp., Digitaria spp., Echinochloa spp., Eleusine spp., Eriochloa spp., Leptochloa spp., Lolium spp., Ottochloa spp., Panicum spp., Paspalum spp., Phalaris spp., Po ⁇ spp., Rottboellia spp., Setaria spp., Sorghum spp., both intrinsically sensitive as well as resistant (e.g.
  • monocotyledonous weeds such as grasses (e.g. barnyard grass (Echinochloa crus-galli), large and smooth crabgrass ⁇ Digitaria sanguinalis, Digitaria ischaemum), goosegrass ⁇ Eleusine indic ⁇ ), bent grass ⁇ Agrostis spp.) and nimbleweed) and dicotyledonous weeds such as dandelion ⁇ Taraxacum spp.), white and red clover ⁇ Trifolium spp.), chickweed ⁇ Stellaria media), henbit ⁇ Lamium amplexicaule), corn speedwell (Veronica arvensis), oxalis (Oxalis spp.), buckhorn and broadleaf plantain (Plantago lanceolata, Plantago major), dollar weed (Hydrocotyle umbellat ⁇ ), FL pusley (
  • grasses e.g. barnyard grass (Echinochloa crus
  • compositions of the invention may be used to control dicot weeds such as clover.
  • the clover is white clover.
  • the term 'weeds' includes undesirable crop species such as volunteer crops.
  • creeping bentgrass putting green turf can be considered a 'volunteer' if found in a fairway section where a different variety of grass is being cultivated.
  • the other grasses listed below can, similarly, be considered weeds when found in the wrong place.
  • the 'locus' is intended to include soil, seeds, and seedlings as well as established vegetation.
  • the benefits of the present invention are seen most when the pesticidal composition is applied to kill weeds in growing crops of useful plants: such as maize (corn) including field corn, pop corn and sweet corn; cotton, wheat, rice, oats, potato sugarbeet, plantation crops (such as bananas, fruit trees, rubber trees, tree nurseries), vines, asparagus, bushberries (such as blueberries), canebe ⁇ es, cranberries, flax, grain sorghum, okra, peppermint, rhubarb, spearmint and sugarcane.
  • maize corn
  • corn including field corn, pop corn and sweet corn
  • plantation crops such as bananas, fruit trees, rubber trees, tree nurseries
  • vines asparagus
  • bushberries such as blueberries
  • canebe ⁇ es canebe ⁇ es
  • cranberries flax, grain sorghum, okra, peppermint, rhubarb, spearmint and sugarcan
  • 'Crops' are understood to also include various turf grasses including, but not limited to, the cool-season turf grasses and the warm-season turf grasses.
  • the crop is turfgrass.
  • Cool season turfgrasses include, for example, bluegrasses (Poa L.), such as Kentucky bluegrass (Poa pratensis L.), rough bluegrass (Poa trivialis L.), Canada bluegrass (Poa compressa L.) and annual bluegrass (Poa annua L.); bentgrasses (Agrostis L.), such as creeping bentgrass (Agrostis palustris Huds.), colonial bentgrass (Agrostis tenius Sibth.), velvet bentgrass (Agrostis canina L.) and redtop (Agrostis alba L.); fescues (Festuca L.), such as tall fescue (Festuca arundinacea Schreb.), meadow fescue (Festuca elatior L.) and fine fescues such as creeping red fescue (Festuca rubra L.), chewings fescue (Festuca rubra var.
  • ryegrasses such as perennial ryegrass (Lolium perenne L.) and annual (Italian) ryegrass (Lolium multiflorum Lam.).
  • Warm season turfgrasses include, for example, Bermudagrasses (Cynodon L. C. Rich), including hybrid and common Bermudagrass; Zoysiagrasses (Zoysia Willd.), St. Augustinegrass (Stenotaphrum secundatum (Walt.) Kuntze); and centipedegrass (Eremochloa ophiuroides (Munro.) hack.).
  • Crops' are to be understood to include those crops that have been made tolerant to pests and pesticides, including herbicides or classes of herbicides (and, suitably, the herbicides of the present invention), as a result of conventional methods of breeding or genetic engineering.
  • Tolerance to herbicides means a reduced susceptibility to damage caused by a particular herbicide compared to conventional crop breeds.
  • Crops can be modified or bred so as to be tolerant, for example, to HPPD inhibitors such as mesotrione, EPSPS inhibitors such as glyphosate or to glufosinate. It is noted that corn is naturally tolerant to mesotrione.
  • composition of the present invention is useful in controlling the growth of undesirable vegetation by pre-emergence or post-emergence application to the locus where control is desired, depending on the crop over which the combination is applied.
  • the herbicidal composition of the invention is applied as a pre- emergent application.
  • the herbicidal composition of the invention is applied as a post-emergent application.
  • the compounds of the invention may be applied either simultaneously or sequentially. If administered sequentially, the components may be administered in any order in a suitable timescale, for example, with no longer than 24 hours between the time of administering the first component and the time of administering the last component.
  • all the components are administered within a timescale of a few hours, such as one hour. If the components are administered simultaneously, they may be administered separately or as a tank mix or as a pre- formulated mixture of all the components or as a pre- formulated mixture of some of the components tank mixed with the remaining components. In one embodiment the mixture or composition of the present invention may be applied to a crop as a seed treatment prior to planting.
  • compositions of the invention are applied as a formulation containing the various adjuvants and carriers known to or used in the industry.
  • the compositions of the invention may thus be formulated as granules (and, suitably, as stabilised granules, as described below), as wettable powders, as emulsif ⁇ able concentrates, as powders or dusts, as flowables, as solutions, as suspensions or emulsions, or as controlled release forms such as microcapsules.
  • These formulations may contain as little as about 0.5% to as much as about 95% or more by weight of active ingredient. The optimum amount for any given compound will depend on formulation, application equipment and nature of the plants to be controlled.
  • Wettable powders are in the form of finely divided particles which disperse readily in water or other liquid carriers.
  • the particles contain the active ingredient retained in a solid matrix.
  • Typical solid matrices include fuller's earth, kaolin clays, silicas and other readily wet organic or inorganic solids. Wettable powders normally contain about 5% to about 95% of the active ingredient plus a small amount of wetting, dispersing or emulsifying agent.
  • Emulsifiable concentrates are homogeneous liquid compositions dispersible in water or other liquid and may consist entirely of the active compound with a liquid or solid emulsifying agent, or may also contain a liquid carrier, such as xylene, heavy aromatic naphthas, isophorone and other non-volatile organic solvents. In use, these concentrates are dispersed in water or other liquid and normally applied as a spray to the area to be treated. The amount of active ingredient may range from about 0.5% to about 95% of the concentrate.
  • Granular formulations include both extrudates and relatively coarse particles and are usually applied without dilution to the area in which suppression of vegetation is desired.
  • Typical carriers for granular formulations include fertiliser, sand, fuller's earth, attapulgite clay, bentonite clays, montmorillonite clay, vermiculite, perlite, calcium carbonate, brick, pumice, pyrophyllite, kaolin, dolomite, plaster, wood flour, ground corn cobs, ground peanut hulls, sugars, sodium chloride, sodium sulphate, sodium silicate, sodium borate, magnesia, mica, iron oxide, zinc oxide, titanium oxide, antimony oxide, cryolite, gypsum, diatomaceous earth, calcium sulphate and other organic or inorganic materials which absorb or which can be coated with the active compound.
  • a fertiliser granule carrier particularly suitable is a fertiliser granule carrier.
  • Granular formulations normally contain about 5% to about 25% active ingredients which may include surface-active agents such as heavy aromatic naphthas, kerosene and other petroleum fractions, or vegetable oils; and/or stickers such as dextrins, glue or synthetic resins.
  • the granular formulation may be a stabilised composition which comprises at least one granular substrate material containing at least one metal chelate of mesotrione and clopyralid.
  • the granular substrate material can be one of the typical carriers mentioned above and/or can be a fertiliser material e.g.
  • urea/formaldehyde fertilisers urea, potassium chloride, ammonium compounds, phosphorus compounds, sulphur, similar plant nutrients and micronutrients and mixtures or combinations thereof.
  • the metal chelate of mesotrione and the clopyralid may be homogeneously distributed throughout the granule or may be spray impregnated or absorbed onto the granule substrate after the granules are formed.
  • Dusts are free-flowing admixtures of the active ingredient with finely divided solids such as talc, clays, flours and other organic and inorganic solids which act as dispersants and carriers.
  • Microcapsules are typically droplets or granules of the active material enclosed in an inert porous shell which allows escape of the enclosed material to the surroundings at controlled rates.
  • Encapsulated droplets are typically about 1 to 50 microns in diameter.
  • the enclosed liquid typically constitutes about 50 to 95% of the weight of the capsule and may include solvent in addition to the active compound.
  • Encapsulated granules are generally porous granules with porous membranes sealing the granule pore openings, retaining the active species in liquid form inside the granule pores.
  • Granules typically range from 1 millimetre to 1 centimetre, preferably 1 to 2 millimetres in diameter. Granules are formed by extrusion, agglomeration or prilling, or are naturally occurring.
  • Shell o membrane materials include natural and synthetic rubbers, cellulosic materials, styrene- butadiene copolymers, polyacrylonitriles, polyacrylates, polyesters, polyamides, polyureas, polyurethanes and starch xanthates.
  • compositions for herbicidal applications include simple solutions of the active ingredients in a solvent in which it is completely soluble at the desired concentration, such as acetone, alkylated naphthalenes, xylene and other organic solvents.
  • Pressurised sprayers wherein the active ingredient is dispersed in finely-divided form as a result of vaporisation of a low boiling dispersant solvent carrier, may also be used.
  • formulations described above include wetting, dispersing or emulsifying agents.
  • examples are alkyl and alkylaryl sulphonates and sulphates and their salts, polyhydric alcohols; polyethoxylated alcohols, esters and fatty amines.
  • These agents when used, normally comprise from 0.1% to 15% by weight of the formulation.
  • Suitable agricultural adjuvants and carriers that are useful in formulating the compositions for use in the invention in the formulation types described above are well known to those skilled in the art. Suitable examples of the different classes are found in the non-limiting list below.
  • Liquid carriers that can be employed include water, toluene, xylene, petroleum naphtha, crop oil, acetone, methyl ethyl ketone, cyclohexanone, acetic anhydride, acetonitrile, acetophenone, amyl acetate, 2-butanone, chlorobenzene, cyclohexane, cyclohexanol, alkyl acetates, diacetonalcohol, 1,2-dichloropropane, diethanolamine, p- diethylbenzene, diethylene glycol, diethylene glycol abietate, diethylene glycol butyl ether, diethylene glycol ethyl ether, diethylene glycol methyl ether, N,N-dimethyl formamide, dimethyl sulfoxide, 1,4-dioxane, dipropylene glycol, dipropylene glycol methyl ether, dipropylene glycol dibenzoate, diproxi
  • Water is generally the carrier of choice for the dilution of concentrates.
  • Suitable solid carriers include talc, titanium dioxide, pyrophyllite clay, silica, attapulgite clay, kieselguhr, chalk, diatomaxeous earth, lime, calcium carbonate, bentonite clay, fuller's earth, fertiliser, cotton seed hulls, wheat flour, soybean flour, pumice, wood flour, walnut shell flour, lignin and the like.
  • a broad range of surface-active agents are advantageously employed in both said liquid and solid compositions, especially those designed to be diluted with carrier before application.
  • the surface- active agents can be anionic, cationic, non-ionic or polymeric in character and can be employed as emulsifying agents, wetting agents, suspending agents or for other purposes.
  • Typical surface active agents include salts of alkyl sulfates, such as diethanolammonium lauryl sulphate; alkylarylsulfonate salts, such as calcium dodecylbenzenesulfonate; alkylphenol-alkylene oxide addition products, such as nonylphenol-C.sub.
  • alcohol-alkylene oxide addition products such as tridecyl alcohol-C.sub. 16 ethoxylate
  • soaps such as sodium stearate
  • alkylnaphthalenesulfonate salts such as sodium dibutylnaphthalenesulfonate
  • dialkyl esters of sulfosuccinate salts such as sodium di(2-ethylhexyl) sulfosuccinate
  • sorbitol esters such as sorbitol oleate
  • quaternary amines such as lauryl trimethylammonium chloride
  • polyethylene glycol esters of fatty acids such as polyethylene glycol stearate
  • salts of mono and dialkyl phosphate esters such as mono and dialkyl phosphate esters.
  • compositions commonly utilized in agricultural compositions include crystallisation inhibitors, viscosity modifiers, suspending agents, spray droplet modifiers, pigments, antioxidants, foaming agents, light-blocking agents, compatibilizing agents, antifoam agents, sequestering agents, neutralising agents and buffers, corrosion inhibitors, dyes, odorants, spreading agents, penetration aids, micronutrients, emollients, lubricants, sticking agents, and the like.
  • the compositions can also be formulated with liquid fertilizers or solid, particulate fertiliser carriers such as ammonium nitrate, urea and the like.
  • a beneficial crop is susceptible to the effects of the herbicide.
  • an herbicide must cause minimal damage (preferably no damage) to the beneficial crop while maximizing damage to weed species which infest the locus of the crop.
  • herbicides in combination with an antidote if necessary.
  • 'antidote' describes a compound which has the effect of establishing herbicide selectivity, i.e. continued herbicidal phytotoxicity to weed species by the herbicide and reduced or non- phytotoxicity to the cultivated crop species.
  • the term 'antidotally effective amount' describes an amount of an antidote compound which counteracts to some degree a phytotoxic response of a beneficial crop to an herbicide. If necessary or desired for a particular application or crop, the composition of the present invention may contain an antidotally effective amount of an antidote for the herbicides of the invention. Those skilled in the art will be familiar with antidotes which are suitable for use with mesotrione and clopyralid and can readily determine an antidotally effective amount for a particular compound and application.
  • the antidote may include, for example, benoxacor, fenclorim, cloquintocet-mexyl, mefenpyr-diethyl, furilazole, dicyclonon, fluxofenim, dichlormid, flurazole, isoxadifen-ethyl, fenchlorazole-ethyl, primisulfuron-methyl, cyprosulfamide, the compound of formula II
  • compositions may contain, in addition to mesotrione and clopyralid, other herbicides, insecticides, fungicides, bactericides, acaracides, nematicides and/or plant growth regulators, in order to broaden the spectrum of activity.
  • Each of the above formulations can be prepared as a package containing the herbicide together with other ingredients of the formulation (diluents, emulsifiers, surfactants, etc.).
  • the formulations can also be prepared by a tank mix method, in which the ingredients are obtained separately and combined at the grower site.
  • Dust and liquid compositions can be applied by the use of power-dusters, broom and hand sprayers and spray dusters.
  • the formulations can also be applied from airplanes as a dust or a spray or by rope wick applications.
  • dust and liquid formulations can be distributed in the soil to a depth of at least one-half inch below the soil surface or applied to the soil surface only, by spraying or sprinkling.
  • the formulations can also be applied by addition to irrigation water. This permits penetration of the formulations into the soil together with the irrigation water. Dust compositions, granular compositions or liquid formulations applied to the surface of the soil can be distributed below the surface of the soil by conventional means such as discing, dragging or mixing operations.
  • the present invention can be used in any situation in which weed control is desired, for example in agriculture, on golf courses, or in gardens.
  • the present invention is particularly suitable for the selective control of weeds such as white clover in turfgrass.
  • Mixtures of mesotrione and clopyralid coated on or impregnated in a fertiliser granule are particularly useful.
  • herbicides were applied at reduced field rates because herbicide effects are magnified in a glasshouse environment.
  • the rates tested were selected to give between about 50 and 70% control with herbicides applied alone, so that any synergistic effect could be readily detected when testing mixtures.
  • Example 1 Control of white clover with mesotrione and clopyralid applied pre-emergence
  • results are shown in Table 1.
  • the results were evaluated using the Colby formula.
  • the expected result for (A+B) is (A+B) - (AxB/100) where A and B are the 'observed' results for A and B on their own.
  • Control from the tank mixture is synergistic if the actual result is significantly higher than the expected result (significance based on Student-Newman-Keuls multiple range test).

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
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  • Engineering & Computer Science (AREA)
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Abstract

L'invention concerne un procédé destiné à stopper la croissance des mauvaises herbes, en particulier le trèfle blanc, à l'aide d'une composition herbicide à base de mésotrione et de clopyralide.
PCT/EP2008/006772 2007-08-27 2008-08-18 Composition herbicide et procédé d'utilisation WO2009027029A2 (fr)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102326549A (zh) * 2011-06-17 2012-01-25 陕西韦尔奇作物保护有限公司 一种含甲基磺草酮的除草组合物
CN103027042A (zh) * 2012-12-14 2013-04-10 青岛东生药业有限公司 含硝磺草酮和二氯吡啶酸的复配组合物

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WO2007011847A2 (fr) * 2005-07-19 2007-01-25 Oms Investments, Inc. Compositions de mesotrione granulaires sures pour le gazon

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ANONYMOUS: "New synergistic and selective herbicide compositions" RESEARCH DISCLOSURE, MASON PUBLICATIONS, HAMPSHIRE, GB, vol. 452, no. 61, 1 December 2001 (2001-12-01), XP007129416 ISSN: 0374-4353 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102326549A (zh) * 2011-06-17 2012-01-25 陕西韦尔奇作物保护有限公司 一种含甲基磺草酮的除草组合物
CN102326549B (zh) * 2011-06-17 2014-08-13 陕西韦尔奇作物保护有限公司 一种含甲基磺草酮的除草组合物
CN103027042A (zh) * 2012-12-14 2013-04-10 青岛东生药业有限公司 含硝磺草酮和二氯吡啶酸的复配组合物

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