WO2009013275A9 - Lubricating composition for use in diesel engines compatible with biofuel - Google Patents

Lubricating composition for use in diesel engines compatible with biofuel Download PDF

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Publication number
WO2009013275A9
WO2009013275A9 PCT/EP2008/059543 EP2008059543W WO2009013275A9 WO 2009013275 A9 WO2009013275 A9 WO 2009013275A9 EP 2008059543 W EP2008059543 W EP 2008059543W WO 2009013275 A9 WO2009013275 A9 WO 2009013275A9
Authority
WO
WIPO (PCT)
Prior art keywords
lubricating composition
biofuel
diesel engines
mass
compatible
Prior art date
Application number
PCT/EP2008/059543
Other languages
French (fr)
Other versions
WO2009013275A1 (en
Inventor
Noriaki Shinoda
Eiji Nagatomi
Original Assignee
Shell Int Research
Noriaki Shinoda
Eiji Nagatomi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research, Noriaki Shinoda, Eiji Nagatomi filed Critical Shell Int Research
Priority to CN200880100097.6A priority Critical patent/CN101796171B/en
Priority to US12/669,807 priority patent/US20100269774A1/en
Priority to BRPI0814579-2A priority patent/BRPI0814579B1/en
Priority to EP08786285.0A priority patent/EP2179011B1/en
Publication of WO2009013275A1 publication Critical patent/WO2009013275A1/en
Publication of WO2009013275A9 publication Critical patent/WO2009013275A9/en
Priority to US13/448,054 priority patent/US20130102509A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/06—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic nitrogen-containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C10M2203/1025—Aliphatic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/067—Polyaryl amine alkanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/068—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings having amino groups bound to polycyclic aromatic ring systems, i.e. systems with three or more condensed rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/081—Biodegradable compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/78—Fuel contamination
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
    • C10N2040/253—Small diesel engines

Abstract

The present invention provides a lubricating composition for use in diesel engines compatible with biofuel, the lubricating composition comprising a base oil belonging to Group III and/or Group II of the API base oil categories, from 0.5 to 5% by mass of a phenolic anti-oxidant and from 0.5 to 5% by mass of an amine-based anti-oxidant, the total content of the anti-oxidants being at least 2% by mass.
PCT/EP2008/059543 2007-07-23 2008-07-21 Lubricating composition for use in diesel engines compatible with biofuel WO2009013275A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN200880100097.6A CN101796171B (en) 2007-07-23 2008-07-21 Lubricating composition for use in diesel engines compatible with biofuel
US12/669,807 US20100269774A1 (en) 2007-07-23 2008-07-21 Lubricating composition for use in diesel engines compatible with biofuel
BRPI0814579-2A BRPI0814579B1 (en) 2007-07-23 2008-07-21 METHOD FOR OPERATING A DIESEL ENGINE
EP08786285.0A EP2179011B1 (en) 2007-07-23 2008-07-21 Lubricating composition for use in diesel engines compatible with biofuel
US13/448,054 US20130102509A1 (en) 2007-07-23 2012-04-16 Lubricating composition for use in diesel engines compatible with biofuel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-190658 2007-07-23
JP2007190658A JP2009024123A (en) 2007-07-23 2007-07-23 Lubricating oil composition for diesel engine corresponding to biofuel

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/448,054 Division US20130102509A1 (en) 2007-07-23 2012-04-16 Lubricating composition for use in diesel engines compatible with biofuel

Publications (2)

Publication Number Publication Date
WO2009013275A1 WO2009013275A1 (en) 2009-01-29
WO2009013275A9 true WO2009013275A9 (en) 2009-03-12

Family

ID=39791277

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/059543 WO2009013275A1 (en) 2007-07-23 2008-07-21 Lubricating composition for use in diesel engines compatible with biofuel

Country Status (8)

Country Link
US (2) US20100269774A1 (en)
EP (1) EP2179011B1 (en)
JP (1) JP2009024123A (en)
CN (1) CN101796171B (en)
AR (1) AR068609A1 (en)
BR (1) BRPI0814579B1 (en)
RU (1) RU2456333C2 (en)
WO (1) WO2009013275A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7960322B2 (en) * 2007-10-26 2011-06-14 Chevron Oronite Company Llc Lubricating oil compositions comprising a biodiesel fuel and an antioxidant
WO2010151514A1 (en) 2009-06-26 2010-12-29 The Lubrizol Corporation Engine oil formulations for biodiesel fuels
AR078233A1 (en) * 2009-08-05 2011-10-26 Basf Se LUBRICATING COMPOSITION
ES2898500T3 (en) 2012-11-19 2022-03-07 Lubrizol Corp Alkylene-coupled phenols for use in biodiesel engines
JP2017039841A (en) * 2015-08-19 2017-02-23 コスモ石油ルブリカンツ株式会社 Lubricant composition for internal combustion engine
US11162048B2 (en) 2016-12-27 2021-11-02 The Lubrizol Corporation Lubricating composition with alkylated naphthylamine
DK3562921T3 (en) 2016-12-27 2022-06-07 Lubrizol Corp LUBRICANT COMPOSITION INCLUDING N-ALKYLED DIANILINE
WO2018156304A1 (en) 2017-02-21 2018-08-30 Exxonmobil Research And Engineering Company Lubricating oil compositions and methods of use thereof

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US3652411A (en) * 1969-12-04 1972-03-28 Mobil Oil Corp Polyglycol base lubricant
EP0432089B1 (en) * 1989-11-08 1996-09-04 Ciba-Geigy Ag Lubricating oil compositions
EP0456925B1 (en) * 1990-05-14 1993-10-20 Ethyl Petroleum Additives Limited Antioxidant compositions
JPH04202398A (en) * 1990-11-30 1992-07-23 Tonen Corp Lubricating oil composition
DE69324746T2 (en) * 1992-09-02 1999-10-21 Lubrizol Corp Antioxidants for highly monounsaturated vegetable oils
JPH08157853A (en) * 1994-12-08 1996-06-18 Cosmo Sogo Kenkyusho:Kk Ester-based lubricating oil composition
US5672752A (en) * 1995-09-13 1997-09-30 The Bfgoodrich Company Liquid alkylated diphenylamine antioxidant
JP3935982B2 (en) * 1995-10-19 2007-06-27 出光興産株式会社 Hydraulic fluid composition
DE60029049T2 (en) * 1999-05-19 2007-06-21 Ciba Speciality Chemicals Holding Inc. Stabilized hydrorefined and hydrodewaxed lubricant compositions
RU2194742C2 (en) * 2001-03-16 2002-12-20 ООО "Лаборатория Триботехнологии" Antiwear and antifriction additive with friction modifier, lubricating material, and method of preparing friction modifier
US20050215441A1 (en) * 2002-03-28 2005-09-29 Mackney Derek W Method of operating internal combustion engine by introducing detergent into combustion chamber
WO2004081150A2 (en) * 2003-03-14 2004-09-23 Linnaeus Inc. Methyl esters of hydroxyl-containing fatty acids as biofuels
EP1471130A1 (en) * 2003-04-23 2004-10-27 Ethyl Petroleum Additives Ltd Fuel composition containing molybdenum source and metal-containing detergent, and its use in two-stroke engines
US20040266630A1 (en) * 2003-06-25 2004-12-30 The Lubrizol Corporation, A Corporation Of The State Of Ohio Novel additive composition that reduces soot and/or emissions from engines
US7667066B2 (en) * 2004-02-27 2010-02-23 Albemarle Corporation Preparation of sterically hindered hydroxyphenylcarboxylic acid esters
US20060223724A1 (en) * 2005-03-29 2006-10-05 Gatto Vincent J Lubricating oil composition with reduced phosphorus levels

Also Published As

Publication number Publication date
US20100269774A1 (en) 2010-10-28
BRPI0814579A2 (en) 2015-01-20
JP2009024123A (en) 2009-02-05
BRPI0814579B1 (en) 2018-03-27
RU2456333C2 (en) 2012-07-20
CN101796171A (en) 2010-08-04
AR068609A1 (en) 2009-11-25
CN101796171B (en) 2014-12-17
EP2179011A1 (en) 2010-04-28
WO2009013275A1 (en) 2009-01-29
US20130102509A1 (en) 2013-04-25
RU2010106057A (en) 2011-08-27
EP2179011B1 (en) 2018-06-27

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