WO2008138190A1 - A glass fiber reinforced plastic door and window profile with reinforcing metal strip - Google Patents

A glass fiber reinforced plastic door and window profile with reinforcing metal strip Download PDF

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Publication number
WO2008138190A1
WO2008138190A1 PCT/CN2007/070307 CN2007070307W WO2008138190A1 WO 2008138190 A1 WO2008138190 A1 WO 2008138190A1 CN 2007070307 W CN2007070307 W CN 2007070307W WO 2008138190 A1 WO2008138190 A1 WO 2008138190A1
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WO
WIPO (PCT)
Prior art keywords
fiber
window
metal
metal strip
mold
Prior art date
Application number
PCT/CN2007/070307
Other languages
French (fr)
Chinese (zh)
Inventor
Mingyun Zhou
Chao Shi
Jie Lu
Original Assignee
Mingyun Zhou
Chao Shi
Jie Lu
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mingyun Zhou, Chao Shi, Jie Lu filed Critical Mingyun Zhou
Publication of WO2008138190A1 publication Critical patent/WO2008138190A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/20Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in a single direction, e.g. roofing or other parallel fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/08Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
    • B29C70/088Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of non-plastics material or non-specified material, e.g. supports
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/22Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/521Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement before the die
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B1/00Border constructions of openings in walls, floors, or ceilings; Frames to be rigidly mounted in such openings
    • E06B1/04Frames for doors, windows, or the like to be fixed in openings
    • E06B1/32Frames composed of parts made of different materials
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/04Wing frames not characterised by the manner of movement
    • E06B3/06Single frames
    • E06B3/08Constructions depending on the use of specified materials
    • E06B3/20Constructions depending on the use of specified materials of plastics
    • E06B3/22Hollow frames
    • E06B3/221Hollow frames with the frame member having local reinforcements in some parts of its cross-section or with a filled cavity

Definitions

  • the invention relates to a door and window profile and a production method thereof, in particular to a FRP door and window profile and a production method thereof.
  • the glass fiber material includes a long bundle of filaments, a woven fabric, a short bundle of fiber mats, and the like, which are impregnated with a resin mixture and then heated by a mold to form a profile. These materials are more prone to tensile deformation during the drawing process, resulting in various deformations of the profile, resulting in a decrease in the yield of the product.
  • the fiber material has a relatively high strength in the longitudinal direction, and the transverse strength is relatively weak.
  • the fiber bundle in the above reinforcing material is the main body of the reinforcing material, and the fiber cloth and the fiber mat are applied only to the inner and outer surfaces of the profile.
  • the fiber bundle has a good tensile strength only in the longitudinal direction of the profile.
  • the fiber cloth and the fiber felt have a limited effect on the transverse strength of the profile.
  • the longitudinal compressive strength and the transverse tensile strength of the profile are the weak links of the profile strength. This problem has not been solved very well, thus limiting the application range of FRP pultruded profiles.
  • the traditional FRP is a structure made of glass fiber and its products as a reinforcing material, based on thermosetting or thermoplastic resin, and formed by a certain molding process. Its scientific name is "glass fiber reinforced plastic".
  • the FRP profiles produced by the traditional FRP door and window profile production process are pure glass fiber and resin cured structures. Conventional FRP profiles have the disadvantage of weak lateral strength and poor grip strength with screw connectors.
  • the object of the present invention is to provide a metal reinforced FRP door and window pultrusion profile and a production method thereof, and to solve the problem that the transverse strength of the FRP profile is weak and the grip strength of the screw fastener is insufficient; Metal reinforced FRP doors and windows pultruded profiles processing and production costs and high cost.
  • the utility model uses the following technical solutions: a metal reinforced fiberglass door and window a pultruded profile having a shape of an elongated hollow member having a cavity formed by at least two longitudinal thin walls and at least two transverse thin walls, characterized in that: a metal strip is formed inside the at least one thin wall, The thin-walled cross-section has fiber mat, fiber cloth, fiber bundle, metal strip, and fiber cloth in order from the outside to the inside, and the above layers are impregnated and solidified by the resin mixture.
  • the thin-walled composite cavity may have an internal partition.
  • the outer surface of the thin wall may have a groove.
  • the metal strip may have a thickness of 0.5 to 1.0 mm.
  • the method for producing the above-mentioned metal reinforced FRP door and squeezing profile is characterized in that: the fiber reinforced material and the metal strip for forming the metal reinforced FRP door and window pultrusion profile are driven by the tractor, and the following steps are sequentially performed:
  • Step 1 using a tractor to pull the fiber mat, the fiber cloth, the fiber bundle and the metal belt from the creel and the yarn drum in the same direction;
  • Step 2 the drawn fiber bundle is impregnated into the resin mixture in the resin tank, commonly known as dipping; Step 3, continue to draw the fiber mat, the fiber cloth, the dipped fiber bundle and the metal strip so that they are respectively taken from the yarn splitter Pass through the predetermined gap and pass through the preform adjustment die;
  • Step 4 the fiber mat, the fiber cloth, the dipped fiber bundle and the metal strip are drawn into the heating mold to form and solidify after passing through the preform adjustment mold;
  • Step 5 The formed profile coming out of the heated forming mold is pulled to the cutting saw for cutting.
  • the first bracket (5) for placing the metal tape tray and the second bracket for placing the fiber mat tray can be connected to both sides of the creel.
  • the yarn splitter may be in the shape of a grid, and the upper and lower edges of the grille are provided with a flat hole of the fiber mat and a flat hole of the fiber cloth, and the edge of the inner hole of the yarn splitter is provided with a flat hole with a metal strip.
  • the core of the yarn has a square hole.
  • the heated molding die to the resin tank can be connected to a slanted resin return tank.
  • the above-mentioned metal reinforced fiberglass door and window pultrusion profile production device is characterized in that: the sequence is formed by a creel, a resin groove, a yarn splitter, a preforming adjustment die, a heating forming die, a tractor, a dicing saw, and a yarn. At least one layer of gauze is placed on the frame, a first bracket on which the metal tape tray is fixed on both sides, and a second bracket on which the fiber mat tray is placed, and the molding die is heated to the resin tank to connect to an inclined resin return groove.
  • the sequence is formed by a creel, a resin groove, a yarn splitter, a preforming adjustment die, a heating forming die, a tractor, a dicing saw, and a yarn.
  • At least one layer of gauze is placed on the frame, a first bracket on which the metal tape tray is fixed on both sides, and a second bracket on which the fiber mat tray is placed, and the molding die is heated to the resin tank to connect to an inclined
  • the invention increases the compressive strength and the transverse tensile strength of the FRP profile by increasing the metal reinforcing material of the FRP material in the FRP material. And for the gripping force of the screw connector, the FRP profile produced by this method can completely eliminate the lining for the connection during the assembly process of assembling the door and window and the installation process of the door and window, simplifying the assembly and installation process, and making the door and window The assembly process is simpler, the processing difficulty is reduced, and the cost is greatly saved, so that many downstream door and window processing units in the society can also produce the profiles of FRP doors and windows by relying on their own technical level.
  • the outstanding difference between the present invention and the pultrusion process commonly used at home and abroad is that the molding method is to compound a metal material in the profile forming process, thereby improving the mechanical properties of the product and further improving the quality of the profile. In particular, it improves the transverse mechanical properties of the profile and the holding force on the screw connection.
  • the profile produced by this method should be a composite type of FRP material, which combines FRP itself with other materials to make up for some shortcomings of FRP pultruded profiles and improve the performance of FRP pultruded profiles. , solved a big problem that has been plaguing people for a long time.
  • the invention makes the assembly process of the door and window simpler and the processing difficulty is lower, so that many downstream door and window processing units in the society can also produce the FRP window by relying on their own technical level, which is favorable for promoting the development of the FRP door and window.
  • the added metal strip is a unified whole, it can ensure that the profile does not twist and bend to a certain extent, and has positive significance for improving the flatness and lateral strength of the profile.
  • the force of the screw on the profile is directly applied to the metal strip, and then the metal strip is dispersed to various positions inside the profile, which greatly improves the stress state of the profile and improves the profile to the screw, etc.
  • the holding force of the connecting member can completely eliminate the lining of the profile assembled into the door and window ⁇ for reinforcing the connection, thereby reducing the design, manufacture and installation cost of the lining, greatly simplifying the production process of the door and window, and the assembly efficiency of the door and window is obtained. Great improvement.
  • Figure 1 is a schematic view of the connection between a conventional profile and a wall.
  • Figure 2 is a schematic view showing the connection of the profile of the present invention to a wall.
  • Figure 3 is a schematic view showing the distribution of the production process and production apparatus of the present invention.
  • Figure 4 is a schematic view of the creel.
  • Figure 5 is a schematic view of the yarn splitter.
  • FIG. 7 is a schematic enlarged view of the structure of Figure 6; [36] FIG. 8 is a schematic enlarged view of a portion B in FIG.
  • Figure 9 is a pultruded profile of the second embodiment of the present invention without an internal partition
  • Fig. 10 is a schematic enlarged view of the structure C at Fig. 9.
  • Embodiment 1 Referring to Figures 6 and 8, the pultruded profile 1 of the inner partition is composed of three longitudinal thin walls and two transverse thin walls to form an inner partition 106 having two cavities.
  • the elongated hollow member of the shape of 108, the outer surface of the thin wall has a groove 107, wherein: a metal strip 105 is disposed inside each of the two lateral thin walls, and the cross section of the thin wall is sequentially from the outside to the inside.
  • the inner partition 106 is sequentially impregnated and solidified by the mesh mat 101, the fiber bundle 104, and the mesh mat 101 with a resin mixture.
  • the pultruded profile 2 without internal partitions is composed of two longitudinal thin walls and two transverse thin walls to form an elongated hollow member having a cavity 108.
  • the outer surface of the thin wall has a groove 107, and is characterized in that: a metal strip 105 is disposed inside each of the two lateral thin walls, and the thin-walled cross-section has fiber mats 102 and fibers from the outside to the inside.
  • the cloth 103, the fiber bundle 104, the metal belt 105, and the fiber cloth 103 which are uniformly arranged in the longitudinal direction, are immersed and solidified by the resin mixture.
  • the shape and composition of the metal reinforced fiberglass door and window pultruded profile of the present invention are not limited to the above embodiments, and the shape and composition of the profile may be varied as needed.
  • a production method for producing the above-mentioned metal reinforced FRP door and squeezing profile characterized in that: a fiber reinforced material and a metal belt for making a metal reinforced FRP door and plunge profile are used in a tractor With the following steps, complete the following steps in order:
  • Step 1 using a tractor 15 to put the fiber mat, The fiber cloth, the fiber bundle and the metal strip are pulled from the creel 3 and the yarn drum 4 in the same direction.
  • the first bracket 5 on which the metal tape tray 6 is placed and the second bracket 7 on which the fiber mat tray 8 is placed are connected to both sides of the creel.
  • This step is mainly done in the creel area.
  • the creel is mainly used for placing bundled glass fiber yarns, which are taken out from the barrel and passed through the threading holes at the top of the creel into the dipping area. Also in this portion are strip-shaped fibrous materials such as fiber cloth, fiber mat, and mesh mat, which are mounted on a creel through a tray.
  • the fiber bundle 104 is the main reinforcing material for the FRP pultruded profile, which is the main part of the longitudinal force of the profile.
  • the fiber mat 102 is a felt which is laid out by short glass fiber filaments, and can bear the force in all directions. It is used on the outer surface of the profile to make the surface of the profile smoother and smoother.
  • the fiber cloth 103 is a cloth made of glass fiber, which is used for the surface layer of the profile wall and has a reinforcing effect on the transverse and longitudinal strength of the profile.
  • the above mesh mat can replace fiber cloth or fiber mat.
  • Step 2 the drawn fiber bundle is impregnated into the resin mixture 10 in the resin tank 9, commonly known as dipping.
  • the dipping area is mainly used for dipping glass fiber reinforced materials.
  • the resin tank contains resin and some other fillers.
  • the main functions are: maintaining the shape of the fiber reinforced material; transferring the force between the reinforcing materials; wrapping the surface of the fiber material to protect it from external physical and chemical factors.
  • Step 3 continue to draw the fiber mat, the fiber cloth, the dipped fiber bundle and the metal strip so that they first pass through a predetermined gap in the yarn splitter 11 and then pass through the preform adjustment mold 12.
  • the yarn splitter 11 is in the shape of a grid, and the upper and lower edges of the grille are respectively provided with a flat hole of the fiber mat and a flat hole of the fiber cloth, and the edge of the inner hole of the yarn splitter is opened with a flat hole of the metal strip.
  • the core of the yarn has a square hole.
  • the preform section and the profiled section of the profile are the most critical part of the process. Preforming is a necessary step before the dipped glass fiber enters the mold.
  • the yarn splitter After the dipped glass fiber exits the resin tank, it first enters the yarn splitter, and the glass fiber yarn is adjusted into upper, lower, left and right parts through the holes in the yarn splitter, which is the first step adjustment before the dipped glass fiber enters the mold. Through this step, the glass fiber yarn is first distributed in the approximate shape of the cross section of the molding material.
  • the dipped glass fiber enters the preforming adjustment mold.
  • the preforming adjustment mold is used for positioning the reinforcing materials, which causes the reinforcing materials to enter the mold in a set arrangement, ensuring that the reinforcing materials do not cause entanglement after entering the mold, and the excess resin on the glass fibers is also The bubbles contained in the resin are extruded to ensure the quality of the profile.
  • Step 4 the fiber mat, the fiber cloth, the dipped fiber bundle, and the metal strip are drawn into the heating mold 14 to form and cure after passing through the preform adjustment mold.
  • the molding die 14 is heated to the resin tank 9 to connect a slanted resin return tank 13.
  • Forming and curing is done in the profile mold and is the final step in profile forming.
  • the mold generally comprises a top mold, a bottom mold, a left mold, a right mold and a core iron, and the top, bottom, left and right side molds form a cavity of a certain shape around the core iron, and the cavity is a molding cavity of the profile.
  • the dipped glass fiber enters the mold directly after exiting from the preforming mold.
  • the dipped glass fiber fills the entire molding cavity by pressing each other, and the same mold is heated by the heating plate, and the resin mixture is also reacted under the heating of the mold. Curing, and passing through the mold driven by the tractor, the curing process is completed before the profile has been released.
  • Step 5 the formed profile 17 from the heated molding die 14 is pulled to the dicing saw 16 for cutting.
  • the automatic dicing saw automatically detects and cuts the profile to the required size according to the set length.
  • the production device of the metal reinforced FRP door and squeezing profile is characterized in that: the creel 3, the resin groove 9, the yarn distributor 11, the preform adjustment die 12, and the heating molding die 14 are sequentially arranged. , the tractor 15 and the dicing saw 16 are arranged in a zigzag manner, the creel 3 is placed with two or more layers of the yarn barrel 4, the first bracket 5 on which the metal belt tray 6 is fixed on both sides, and the second unit on which the fiber mat tray 8 is placed The holder 7, the thermoforming mold 14 to the resin tank 9 is connected to an inclined resin return tank 13.
  • the present invention does not require the addition of additional equipment, winds the metal strip into a roll and secures it on the creel using the tray mentioned above, and the working yoke metal strip enters the mold along with the glass fiber reinforced material under the pull of the yoke And solidification with the profile.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Moulding By Coating Moulds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

A glass fiber reinforced plastic door and window profile (1) with reinforcing metal strip includes a hollow part (108) formed by at least two perpendicular thin walls and at least two traverse thin walls. A reinforcing metal stip (105) is embedded in at least one thin wall. A fiber felt (102), a piece of fabric (103), a fiber bundle (104), a metal strip (105) and a piece of fabric (103) are orderly disposed in the cross section of the wall from outside to inside. And those layers are dipped with resin compound (10) and solidified into a whole.

Description

说明书 金属增强型玻璃钢门窗拉挤型材及其生产方法  Metal reinforced fiberglass door and window pultrusion profile and production method thereof
技术领域 Technical field
本发明涉及一种门窗型材及其生产方法, 特别是一种玻璃钢门窗型材及其生产 方法。  The invention relates to a door and window profile and a production method thereof, in particular to a FRP door and window profile and a production method thereof.
背景技术 Background technique
节约资源、 节省能源、 建设节约型社会是近年来世界范围内的重要话题, 而我 国一直是一个耗能大国, 根据测算我国建筑能耗约占总能耗的 1/3以上; 建筑使 用能耗又占建筑能耗的 1 2以上; 室内釆暖、 空调能耗是建筑使用能耗的 1 5以 上; 从整个建筑的能源流失来看, 能源损失中 70%是通过门窗流失的。 据有关专 家估算, 如果把我国非节能窗的 40%改造成节能窗, 全国每年可节省煤炭 1.56亿 吨 (折合人民币 249.6亿元) , 由此可见门窗节能的重要性。 从上世纪 90年代开 始, 随着国际能源的日趋紧张, 国家就已经开始对建筑节能有越来越高的要求 。 各级政府对建筑节能的要求也越来越明确。 1996年国家颁布了 《民用建筑节 能设计标准》 ; 2001年国家颁布了 《夏热冬冷地区居住建筑节能设计标准》 ; 2 004年北京市颁布北京市工程建设技术标准 《住宅建筑门窗应用技术规范》 明确 要求将外窗的传热系数控制在 2.8W/(m2.K)以内; 2005年 7月 1日国家又颁布实施 了我国第一部有关公共建筑节能的国家标准 《公共建筑节能设计标准》 , 其中 对公共建筑门窗的传热系数 (K值)有了明确的规定, 并对夏热冬暖地区的节能也 提出了要求。 所有这些标准、 规范的出台都预示着环保节能的玻璃钢门窗将迎 来更广阔的发展空间。 随着国民经济的发展, 能耗的增量和增速愈来愈快。 对 建筑门窗的质量、 使用功能要求会更高, 研究开发新型节能门窗是今后的主攻 方向, 玻璃钢门窗尤其适合这种发展趋势, 也逐渐为人们所认知。  Saving resources, saving energy, and building a conservation-oriented society are important topics in the world in recent years. China has always been a big energy-consuming country. According to estimates, China's building energy consumption accounts for more than 1/3 of total energy consumption. It also accounts for more than 12 of the building energy consumption; indoor heating and air conditioning energy consumption is more than 15 of the building energy consumption; from the energy loss of the entire building, 70% of the energy loss is lost through the doors and windows. According to relevant experts' estimates, if 40% of China's non-energy-saving windows are transformed into energy-saving windows, the country can save 156 million tons of coal per year (equivalent to RMB 24.96 billion), which shows the importance of energy saving for doors and windows. Since the 1990s, with the increasing international energy, the country has begun to have higher and higher requirements for building energy efficiency. Governments at all levels are increasingly clear about the requirements for building energy efficiency. In 1996, the State promulgated the "Design Standard for Energy Efficiency of Civil Buildings"; in 2001, the State promulgated the "Design Standard for Energy Efficiency of Residential Buildings in Hot Summer and Cold Winter Zones"; In 2002, Beijing promulgated the Beijing Municipal Engineering Construction Technical Standards "Technical Specifications for Residential Building Doors and Windows Applications" 》 Clearly required to control the heat transfer coefficient of the outer window to within 2.8W/(m2.K); On July 1, 2005, the state promulgated and implemented the first national standard for public building energy conservation in China. 》 , which has a clear regulation on the heat transfer coefficient (K value) of public building doors and windows, and also puts forward requirements for energy saving in the hot summer and warm winter areas. The introduction of all these standards and specifications indicates that environmentally-friendly and energy-saving FRP doors and windows will usher in a broader development space. With the development of the national economy, the increase and growth of energy consumption is getting faster and faster. The quality and function requirements of building doors and windows will be higher. Research and development of new energy-saving doors and windows is the main direction of the future. FRP doors and windows are particularly suitable for this development trend, and are gradually recognized by people.
由于玻璃钢材料对于螺钉连接件的握定力差, 在玻璃钢门窗的组装过程中需要 预先在玻璃钢型材空腔内加入若干衬件, 参见图 1。 这样对于不同的型材就需要 设计制作不同形状的衬件与之相配合, 并且要在门窗组装前将衬件伸入型材指 定位置并进行固定, 这就大大增加了加工与安装的复杂程度, 同吋也提高了门 窗的材料成本及人工成本。 Due to the poor gripping force of the FRP material for the screw joint, several linings need to be added to the FRP profile cavity in the assembly process of the FRP door and window, see Figure 1. In this way, different profiles need to be designed and matched with different shapes, and the linings should be inserted into the specified position of the profile and fixed before the door and window are assembled, which greatly increases the complexity of processing and installation.吋 also raised the door Material cost and labor cost of the window.
[4] 由于加工工艺、 安装工艺的复杂性以及成本的制约, 使玻璃钢门窗很难像其他 材料的门窗一样拥有众多的下游加工工厂, 大部分的玻璃钢门窗都只能由玻璃 钢门窗型材生产厂家加工生产, 社会上现有的门窗加工厂虽然认识到玻璃钢门 窗未来发展的必要性, 但是却对此望而却步, 非常害怕玻璃钢门窗这么复杂的 生产过程, 因此大大制约了玻璃钢门窗的发展。  [4] Due to the complexity of the processing technology, installation process and cost constraints, it is difficult for FRP doors and windows to have many downstream processing plants like the doors and windows of other materials. Most FRP doors and windows can only be processed by FRP door and window profiles manufacturers. Production, the existing window and door processing factory in the society recognizes the necessity of the future development of FRP doors and windows, but it is prohibitive. It is very afraid of the complicated production process of FRP doors and windows, thus greatly restricting the development of FRP doors and windows.
[5] 在玻璃钢门窗的型材生产上, 目前国内外都只能以柔软的玻璃纤维材料作为增 强材料。 玻璃纤维材料包括长束纤维丝, 编织而成的纤维布, 短束纤维杂序铺 列而成的纤维毡等, 它们浸渍树脂混合物后通过模具加热形成型材。 这些材料 在牵引过程中比较容易产生拉伸变形, 从而导致型材产生各种变形, 致使产品 的合格率下降。 另外纤维材料只有在纵向有比较高的强度, 横向的强度相对比 较薄弱。 上述增强材料中的纤维束是增强材料的主体, 纤维布、 纤维毡只应用 于型材的内外表面。 纤维束只在型材的纵向有良好的抗拉作用, 纤维布、 纤维 毡对于型材横向的强度起到的作用很有限, 那么型材纵向的抗压强度、 横向的 拉压强度就是型材强度的薄弱环节, 这个问题也一直没有得到很好的解决, 因 此限制了玻璃钢拉挤型材的应用范围。  [5] In the production of profiles for FRP doors and windows, soft fiberglass materials can only be used as reinforcing materials at home and abroad. The glass fiber material includes a long bundle of filaments, a woven fabric, a short bundle of fiber mats, and the like, which are impregnated with a resin mixture and then heated by a mold to form a profile. These materials are more prone to tensile deformation during the drawing process, resulting in various deformations of the profile, resulting in a decrease in the yield of the product. In addition, the fiber material has a relatively high strength in the longitudinal direction, and the transverse strength is relatively weak. The fiber bundle in the above reinforcing material is the main body of the reinforcing material, and the fiber cloth and the fiber mat are applied only to the inner and outer surfaces of the profile. The fiber bundle has a good tensile strength only in the longitudinal direction of the profile. The fiber cloth and the fiber felt have a limited effect on the transverse strength of the profile. Then the longitudinal compressive strength and the transverse tensile strength of the profile are the weak links of the profile strength. This problem has not been solved very well, thus limiting the application range of FRP pultruded profiles.
[6] 传统的玻璃钢是以玻璃纤维及其制品为增强材料, 以热固性或热塑性树脂为基 体, 通过一定的成型工艺而制成的一种结构物, 其学名是"玻璃纤维增强塑料"。 传统玻璃钢门窗型材生产工艺生产出来的玻璃钢型材是单纯的玻璃纤维与树脂 固化后的结构物。 传统的玻璃钢型材有横向强度薄弱和与螺钉连接件的握定力 差的缺陷。 [6] The traditional FRP is a structure made of glass fiber and its products as a reinforcing material, based on thermosetting or thermoplastic resin, and formed by a certain molding process. Its scientific name is "glass fiber reinforced plastic". The FRP profiles produced by the traditional FRP door and window profile production process are pure glass fiber and resin cured structures. Conventional FRP profiles have the disadvantage of weak lateral strength and poor grip strength with screw connectors.
对发明的公开  Disclosure of invention
技术问题  technical problem
[7] 本发明的目的是提供一种金属增强型玻璃钢门窗拉挤型材及其生产方法, 要解 决玻璃钢型材横向强度薄弱和对螺钉紧固件的握定力不足的问题; 同吋还要解 决金属增强型玻璃钢门窗拉挤型材加工生产以及成本偏高的问题。  [7] The object of the present invention is to provide a metal reinforced FRP door and window pultrusion profile and a production method thereof, and to solve the problem that the transverse strength of the FRP profile is weak and the grip strength of the screw fastener is insufficient; Metal reinforced FRP doors and windows pultruded profiles processing and production costs and high cost.
技术解决方案  Technical solution
[8] 为实现上述目的, 本实用新型釆用如下技术方案: 一种金属增强型玻璃钢门窗 拉挤型材, 由至少两个纵向的薄壁、 至少两个横向的薄壁围合成具有空腔的细 长空心杆件形状, 其特征在于: 在上述至少一个薄壁内部有一层金属带, 上述 薄壁的横断面自外至内依次有纤维毡、 纤维布、 纤维束、 金属带、 纤维布, 上 述各层由树脂混合物浸渍、 固化为一体。 [8] In order to achieve the above object, the utility model uses the following technical solutions: a metal reinforced fiberglass door and window a pultruded profile having a shape of an elongated hollow member having a cavity formed by at least two longitudinal thin walls and at least two transverse thin walls, characterized in that: a metal strip is formed inside the at least one thin wall, The thin-walled cross-section has fiber mat, fiber cloth, fiber bundle, metal strip, and fiber cloth in order from the outside to the inside, and the above layers are impregnated and solidified by the resin mixture.
上述薄壁围合成的空腔内可有内隔断。  The thin-walled composite cavity may have an internal partition.
上述薄壁的外表面可有凹槽。  The outer surface of the thin wall may have a groove.
上述金属带的厚度可为 0.5〜1.0mm。  The metal strip may have a thickness of 0.5 to 1.0 mm.
上述金属增强型玻璃钢门窗拉挤型材的生产方法, 其特征在于: 将制作金属增 强型玻璃钢门窗拉挤型材的纤维增强材料和金属带在牵引车的带动下, 依次完 成以下步骤:  The method for producing the above-mentioned metal reinforced FRP door and squeezing profile is characterized in that: the fiber reinforced material and the metal strip for forming the metal reinforced FRP door and window pultrusion profile are driven by the tractor, and the following steps are sequentially performed:
步骤 1, 用牵引机将纤维毡、 纤维布、 纤维束和金属带从纱架上和纱桶中同向 牵引;  Step 1, using a tractor to pull the fiber mat, the fiber cloth, the fiber bundle and the metal belt from the creel and the yarn drum in the same direction;
步骤 2, 将牵引出的纤维束在树脂槽内浸渗树脂混合物, 俗称浸胶; 步骤 3, 继续牵引上述纤维毡、 纤维布、 浸胶的纤维束和金属带使它们分别先 从分纱器中预定的空隙中穿过, 再穿过预成型调整模;  Step 2, the drawn fiber bundle is impregnated into the resin mixture in the resin tank, commonly known as dipping; Step 3, continue to draw the fiber mat, the fiber cloth, the dipped fiber bundle and the metal strip so that they are respectively taken from the yarn splitter Pass through the predetermined gap and pass through the preform adjustment die;
步骤 4, 上述纤维毡、 纤维布、 浸胶的纤维束和金属带在穿过预成型调整模具 后, 被牵引进入加热成型模具进行成型固化;  Step 4, the fiber mat, the fiber cloth, the dipped fiber bundle and the metal strip are drawn into the heating mold to form and solidify after passing through the preform adjustment mold;
步骤 5, 从加热成型模具中出来的已成型型材牵引至切割锯进行切断。  Step 5: The formed profile coming out of the heated forming mold is pulled to the cutting saw for cutting.
上述步骤 1中, 纱架的两侧可连接放置金属带托盘的第一支架 (5) 和放置纤维 毡托盘的第二支架。  In the above step 1, the first bracket (5) for placing the metal tape tray and the second bracket for placing the fiber mat tray can be connected to both sides of the creel.
上述步骤 3中, 分纱器可为格栅状, 格栅的上下左右边缘均开有纤维毡扁孔和 纤维布扁孔, 分纱器的内孔两侧边缘开有金属带扁孔, 分纱器的芯部有一个方 孔。  In the above step 3, the yarn splitter may be in the shape of a grid, and the upper and lower edges of the grille are provided with a flat hole of the fiber mat and a flat hole of the fiber cloth, and the edge of the inner hole of the yarn splitter is provided with a flat hole with a metal strip. The core of the yarn has a square hole.
上述步骤 4中, 加热成型模具至树脂槽可连接一倾斜的树脂回流槽。  In the above step 4, the heated molding die to the resin tank can be connected to a slanted resin return tank.
上述金属增强型玻璃钢门窗拉挤型材的生产装置, 其特征在于: 顺序由纱架、 树脂槽、 分纱器、 预成型调整模、 加热成型模具、 牵引机、 切割锯一字形排列 而成, 纱架上放置至少一层纱桶、 两边侧固定放置金属带托盘的第一支架和放 置纤维毡托盘的第二支架, 加热成型模具至树脂槽连接一倾斜的树脂回流槽。 有益效果 The above-mentioned metal reinforced fiberglass door and window pultrusion profile production device is characterized in that: the sequence is formed by a creel, a resin groove, a yarn splitter, a preforming adjustment die, a heating forming die, a tractor, a dicing saw, and a yarn. At least one layer of gauze is placed on the frame, a first bracket on which the metal tape tray is fixed on both sides, and a second bracket on which the fiber mat tray is placed, and the molding die is heated to the resin tank to connect to an inclined resin return groove. Beneficial effect
[22] 与现有技术相比具有以下特点和有益效果: 本发明通过在玻璃钢材料中增加玻 璃纤维材料的同吋增加金属增强材料, 增强了玻璃钢型材纵向的抗压强度、 横 向的拉压强度和对于螺钉连接件的握定力, 由此方法生产出来的玻璃钢型材在 组装成门窗的生产过程以及门窗的安装过程中可以完全取消用于连接的衬件, 简化了组装及安装工艺, 使门窗的组装过程更简单, 降低了加工难度, 并大大 节约了成本, 使社会上众多的下游门窗加工单位依靠自身的技术水平也能进行 玻璃钢门窗的型材的生产。  [22] Compared with the prior art, the following characteristics and beneficial effects are obtained: The invention increases the compressive strength and the transverse tensile strength of the FRP profile by increasing the metal reinforcing material of the FRP material in the FRP material. And for the gripping force of the screw connector, the FRP profile produced by this method can completely eliminate the lining for the connection during the assembly process of assembling the door and window and the installation process of the door and window, simplifying the assembly and installation process, and making the door and window The assembly process is simpler, the processing difficulty is reduced, and the cost is greatly saved, so that many downstream door and window processing units in the society can also produce the profiles of FRP doors and windows by relying on their own technical level.
[23] 本发明与目前国内外普遍使用的拉挤成型工艺的突出区别在于: 这种成型方法 是在型材成型过程中复合了金属材料, 通过该金属材料改善产品力学性能以及 更进一步提高型材质量, 尤其是改善型材的横向力学性能和对螺钉连接件的握 定力。 由该方法生产的型材确切的说应该是一种复合型的玻璃钢材料, 它将玻 璃钢本身与其他一些材料结合到一起, 弥补了玻璃钢拉挤型材的一些缺憾, 使 玻璃钢拉挤型材的性能得以完善, 解决了长期以来一直困扰人们的一大难题。  [23] The outstanding difference between the present invention and the pultrusion process commonly used at home and abroad is that the molding method is to compound a metal material in the profile forming process, thereby improving the mechanical properties of the product and further improving the quality of the profile. In particular, it improves the transverse mechanical properties of the profile and the holding force on the screw connection. The profile produced by this method should be a composite type of FRP material, which combines FRP itself with other materials to make up for some shortcomings of FRP pultruded profiles and improve the performance of FRP pultruded profiles. , solved a big problem that has been plaguing people for a long time.
[24] 下表为几种常用材质门窗的传热系数检测结果比较: [24] The following table compares the heat transfer coefficient test results for several common material doors and windows:
Figure imgf000006_0001
[25] 由上面数据可以看出普通的铝合金门窗在一些节能要求严格的地区将被彻底淘 汰。 但是我国门窗保温性能总体水平与国外还是有较大差距, 北欧和北美国家 门窗的传热系数一般都小于 2.0W/(m2.K), 有的达到 l.l〜1.2W/(m2.K), 要达到 国外的这种要求, 积极发展玻璃钢门窗是我国切实可行的建筑节能手段。
Figure imgf000006_0001
[25] It can be seen from the above data that ordinary aluminum alloy doors and windows will be completely eliminated in some areas where energy conservation is critical. However, the overall level of China's door and window insulation performance is still far from the foreign countries. The heat transfer coefficient of doors and windows in northern and North America is generally less than 2.0W/(m2.K), and some reach ll~1.2W/(m2.K). To achieve this requirement abroad, the active development of FRP doors and windows is a practical and feasible means of building energy conservation in China.
[26] 实验证明: 应用本发明组合成的玻璃钢门窗在冬天没有釆取任何取暖设施的情 况下, 室内温度可始终保持在 15°C - 16°C; 夏天在没有安装空调制冷的情况下 , 室内温度可长期保持在 22°C - 25°C。 此实验结果表明: 通过玻璃钢门窗节能 与墙体保温互相配合, 完全可以实现建筑低能耗, 甚至零能耗, 它对于资源的 耗损、 环境的污染都好于其他几类门窗。 另外还具有耐腐蚀、 强度高、 绿色环 保、 使用寿命长、 成本低廉等特点。 [26] Experimental evidence: The glass fiber reinforced plastic doors and windows combined with the invention can be kept at 15 ° C - 16 ° C in the winter without any heating facilities; in the summer without air conditioning and refrigeration, The room temperature can be maintained at 22 ° C - 25 ° C for a long time. The results of this experiment show that: through the cooperation between FRP door and window energy saving and wall insulation, it can completely achieve low energy consumption and even zero energy consumption of the building. It is better than other types of doors and windows for resource consumption and environmental pollution. It also features corrosion resistance, high strength, green environmental protection, long service life and low cost.
[27] 本发明使门窗的组装过程更简单, 加工难度更低, 使社会上众多的下游门窗加 工单位依靠自身的技术水平也能进行玻璃钢窗的生产, 有利于推动玻璃钢门窗 的发展。 [27] The invention makes the assembly process of the door and window simpler and the processing difficulty is lower, so that many downstream door and window processing units in the society can also produce the FRP window by relying on their own technical level, which is favorable for promoting the development of the FRP door and window.
[28] 由于加入的金属带是一个统一整体, 它可以在一定程度上保证型材不发生扭曲 和弯曲, 对于改善型材的平整度、 横向强度都有积极意义。 参见图 2, 用于连接 吋, 螺钉对型材的作用力实际直接作用到金属带上, 再由金属带分散到型材内 部的各个位置, 大大改善了型材的受力状态, 提高了型材对螺钉等连接件的握 定力, 因此可以完全取消型材组装成门窗吋用于加强连接的衬件, 这样也就减 少了衬件的设计、 制造、 安装成本, 使门窗生产过程大大简化, 门窗组装效率 得到了很大的提高。  [28] Since the added metal strip is a unified whole, it can ensure that the profile does not twist and bend to a certain extent, and has positive significance for improving the flatness and lateral strength of the profile. Referring to Fig. 2, for connecting the 吋, the force of the screw on the profile is directly applied to the metal strip, and then the metal strip is dispersed to various positions inside the profile, which greatly improves the stress state of the profile and improves the profile to the screw, etc. The holding force of the connecting member can completely eliminate the lining of the profile assembled into the door and window 吋 for reinforcing the connection, thereby reducing the design, manufacture and installation cost of the lining, greatly simplifying the production process of the door and window, and the assembly efficiency of the door and window is obtained. Great improvement.
附图说明  DRAWINGS
[29] 图 1是传统型材与墙体的连接示意图。  [29] Figure 1 is a schematic view of the connection between a conventional profile and a wall.
[30] 图 2是本发明型材与墙体的连接示意图。  [30] Figure 2 is a schematic view showing the connection of the profile of the present invention to a wall.
[31] 图 3是本发明的生产流程和生产装置分布示意图。  Figure 3 is a schematic view showing the distribution of the production process and production apparatus of the present invention.
[32] 图 4是纱架的示意图。  [32] Figure 4 is a schematic view of the creel.
[33] 图 5是分纱器的示意图。  [33] Figure 5 is a schematic view of the yarn splitter.
[34] 图 6是本发明实施例一带内隔断的拉挤型材;  6 is a pultruded profile with an inner partition according to an embodiment of the present invention;
[35] 图 7是图 6中 A处的放大结构示意图; [36] 图 8是图 6中 B处的放大结构示意图。 Figure 7 is a schematic enlarged view of the structure of Figure 6; [36] FIG. 8 is a schematic enlarged view of a portion B in FIG.
[37] 图 9是本发明实施例二不带内隔断的拉挤型材;  Figure 9 is a pultruded profile of the second embodiment of the present invention without an internal partition;
[38] 图 10是图 9中 C处的放大结构示意图。  [38] Fig. 10 is a schematic enlarged view of the structure C at Fig. 9.
[39] 图中: 1一带内隔断的拉挤型材、 2—不带内隔断的拉挤型材、 3 纱架、 4一纱 桶、 5 -第一支架、 6 -金属带托盘、 7 -第二支架、 8 -纤维毡托盘、 9 树脂槽 、 10 -树脂混合物、 11一分纱器、 12 -预成型调整模、 13 -树脂回流槽、 14 加热成型模具、 15—牵引机、 16—切割锯、 17 已成型型材、 18-用于加强连接 的衬件、 19-传统型材、 20-螺钉、 21-墙体、 101—网格毡、 102—纤维毡、 103— 纤维布、 104—纤维束、 105—金属带、 106—内隔断、 107 凹槽、 108 空腔。 本发明的最佳实施方式  [39] In the picture: 1 pultruded profile with internal partition, 2 - pultruded profile without internal partition, 3 creel, 4 yarn bucket, 5 - first bracket, 6 - metal belt tray, 7 - Two brackets, 8 - fiber felt tray, 9 resin tank, 10 - resin mixture, 11 yarn splitter, 12 - preform adjustment mold, 13 - resin return tank, 14 heat forming mold, 15 - tractor, 16 - cutting Saw, 17 profiled profiles, 18-liner for reinforcement connection, 19-traditional profile, 20-screw, 21-wall, 101-mesh felt, 102-fiber mat, 103-fiber cloth, 104-fiber Beam, 105-metal strip, 106-internal partition, 107 groove, 108 cavity. BEST MODE FOR CARRYING OUT THE INVENTION
[40] 实施例一参见图 6、 8所示, 这种带内隔断的拉挤型材 1由三个纵向的薄壁、 两 个横向的薄壁围合成带内隔断 106、 具有两个空腔 108的细长空心杆件形状, 上 述薄壁的外表面有凹槽 107, 其特征在于: 在两个横向的薄壁内部各有一层金属 带 105, 上述薄壁的横断面自外至内依次有纤维毡 102、 纤维布 103、 纤维束 104 、 金属带 105、 纤维布 103, 上述各层由树脂混合物浸渍、 固化为一体。  [40] Embodiment 1 Referring to Figures 6 and 8, the pultruded profile 1 of the inner partition is composed of three longitudinal thin walls and two transverse thin walls to form an inner partition 106 having two cavities. The elongated hollow member of the shape of 108, the outer surface of the thin wall has a groove 107, wherein: a metal strip 105 is disposed inside each of the two lateral thin walls, and the cross section of the thin wall is sequentially from the outside to the inside. There are a fiber mat 102, a fiber cloth 103, a fiber bundle 104, a metal strip 105, and a fiber cloth 103, and each of the above layers is impregnated and solidified by a resin mixture.
[41] 参见图 7, 内隔断 106依次由网格毡 101、 纤维束 104、 网格毡 101以树脂混合物 浸渍、 固化为一体。  [41] Referring to Fig. 7, the inner partition 106 is sequentially impregnated and solidified by the mesh mat 101, the fiber bundle 104, and the mesh mat 101 with a resin mixture.
[42] 实施例二参见图 9 10所示, 这种不带内隔断的拉挤型材 2由两个纵向的薄壁、 两个横向的薄壁围合成具有空腔 108的细长空心杆件形状, 上述薄壁的外表面有 凹槽 107, 其特征在于: 在两个横向的薄壁的内部各有一层金属带 105, 上述薄 壁的横断面自外至内依次有纤维毡 102、 纤维布 103、 沿长向均匀排列的纤维束 1 04、 金属带 105、 纤维布 103, 上述各层由树脂混合物浸渍、 固化为一体。  [42] Embodiment 2 Referring to FIG. 910, the pultruded profile 2 without internal partitions is composed of two longitudinal thin walls and two transverse thin walls to form an elongated hollow member having a cavity 108. The outer surface of the thin wall has a groove 107, and is characterized in that: a metal strip 105 is disposed inside each of the two lateral thin walls, and the thin-walled cross-section has fiber mats 102 and fibers from the outside to the inside. The cloth 103, the fiber bundle 104, the metal belt 105, and the fiber cloth 103 which are uniformly arranged in the longitudinal direction, are immersed and solidified by the resin mixture.
[43] 本发明的金属增强型玻璃钢门窗拉挤型材的形状和组成并不限于上述实施例, 型材的形状和组成可以根据需要变化。  The shape and composition of the metal reinforced fiberglass door and window pultruded profile of the present invention are not limited to the above embodiments, and the shape and composition of the profile may be varied as needed.
[44] 参见图 3 - 5, 一种生产上述金属增强型玻璃钢门窗拉挤型材的生产方法, 其特 征在于: 将制作金属增强型玻璃钢门窗拉挤型材的纤维增强材料和金属带在牵 引车的带动下, 依次完成以下步骤:  [44] Referring to Fig. 3 - 5, a production method for producing the above-mentioned metal reinforced FRP door and squeezing profile, characterized in that: a fiber reinforced material and a metal belt for making a metal reinforced FRP door and plunge profile are used in a tractor With the following steps, complete the following steps in order:
[45] 步骤 1, 用牵引机 15将纤维毡、 纤维布、 纤维束和金属带从纱架 3上和纱桶 4中同向牵引。 在步骤 1中, 纱架的两 侧连接放置金属带托盘 6的第一支架 5和放置纤维毡托盘 8的第二支架 7。 该步骤 主要在纱架区完成。 纱架主要用于摆放束状玻璃纤维纱, 玻璃纤维纱从桶中引 出, 并经过纱架顶的穿纱孔进入浸胶区。 在该部分还有纤维布、 纤维毡、 网格 毡等带状的纤维材料, 这些带状材料通过托盘安装在纱架上。 这些增强材料的 作用是: 纤维束 104是玻璃钢拉挤型材的主要增强材料, 它是承担型材纵向作用 力的主要部分。 纤维毡 102是由短玻璃纤维丝杂乱铺列的毡状物, 它可以承受各 个方向的作用力, 它用于型材外表面, 使型材表面更平整光洁。 纤维布 103是由 玻璃纤维编制成的布, 它用于型材壁的表层, 对于型材的横向、 纵向强度均有 加强作用。 上述网格毡可以替换纤维布或纤维毡。 [45] Step 1, using a tractor 15 to put the fiber mat, The fiber cloth, the fiber bundle and the metal strip are pulled from the creel 3 and the yarn drum 4 in the same direction. In step 1, the first bracket 5 on which the metal tape tray 6 is placed and the second bracket 7 on which the fiber mat tray 8 is placed are connected to both sides of the creel. This step is mainly done in the creel area. The creel is mainly used for placing bundled glass fiber yarns, which are taken out from the barrel and passed through the threading holes at the top of the creel into the dipping area. Also in this portion are strip-shaped fibrous materials such as fiber cloth, fiber mat, and mesh mat, which are mounted on a creel through a tray. The effect of these reinforcing materials is: The fiber bundle 104 is the main reinforcing material for the FRP pultruded profile, which is the main part of the longitudinal force of the profile. The fiber mat 102 is a felt which is laid out by short glass fiber filaments, and can bear the force in all directions. It is used on the outer surface of the profile to make the surface of the profile smoother and smoother. The fiber cloth 103 is a cloth made of glass fiber, which is used for the surface layer of the profile wall and has a reinforcing effect on the transverse and longitudinal strength of the profile. The above mesh mat can replace fiber cloth or fiber mat.
[46] 步骤 2, 将牵引出的纤维束在树脂槽 9内浸渗树脂混合物 10, 俗称浸胶。 浸胶区 主要用于对玻璃纤维增强材料进行浸胶。 树脂槽内盛放树脂以及其他一些填料 , 当纤维增强材料从树脂槽内通过吋, 树脂混合物浸渍到纤维增强材料上, 并 随纤维增强材料最终进入模具。 树脂是玻璃钢的基体材料, 主要作用是: 维持 纤维增强材料的成型形状; 在增强材料之间传递作用力; 包裹于纤维材料表面 保护其不受外界物理、 化学因素的破坏。 [46] Step 2, the drawn fiber bundle is impregnated into the resin mixture 10 in the resin tank 9, commonly known as dipping. The dipping area is mainly used for dipping glass fiber reinforced materials. The resin tank contains resin and some other fillers. When the fiber reinforcement passes through the crucible from the resin tank, the resin mixture is impregnated onto the fiber reinforcement and finally enters the mold with the fiber reinforcement. The resin is the base material of FRP. The main functions are: maintaining the shape of the fiber reinforced material; transferring the force between the reinforcing materials; wrapping the surface of the fiber material to protect it from external physical and chemical factors.
[47] 步骤 3, 继续牵引上述纤维毡、 纤维布、 浸胶的纤维束和金属带使它们分别先 从分纱器 11中预定的空隙中穿过, 再穿过预成型调整模 12。 在步骤 3中, 分纱器 11为格栅状, 格栅的上下左右边缘均开有纤维毡扁孔和纤维布扁孔, 分纱器的 内孔两侧边缘开有金属带扁孔, 分纱器的芯部有一个方孔。 预成型区与型材固 化的模具段是最关键的工艺部分。 预成型是浸胶玻璃纤维进入模具前的必要步 骤。 它包括分纱器与预成型调整模两个重要部件。 浸胶后的玻璃纤维从树脂槽 出来以后首先进入分纱器, 玻璃纤维纱通过分纱器上的孔调整成上下左右几个 部分, 这是浸胶玻璃纤维进入模具前的第一步调整, 通过该步骤玻璃纤维纱首 先被分布成型材断面的大致形状。  [47] Step 3, continue to draw the fiber mat, the fiber cloth, the dipped fiber bundle and the metal strip so that they first pass through a predetermined gap in the yarn splitter 11 and then pass through the preform adjustment mold 12. In the step 3, the yarn splitter 11 is in the shape of a grid, and the upper and lower edges of the grille are respectively provided with a flat hole of the fiber mat and a flat hole of the fiber cloth, and the edge of the inner hole of the yarn splitter is opened with a flat hole of the metal strip. The core of the yarn has a square hole. The preform section and the profiled section of the profile are the most critical part of the process. Preforming is a necessary step before the dipped glass fiber enters the mold. It consists of two important components: the yarn splitter and the preformed adjustment die. After the dipped glass fiber exits the resin tank, it first enters the yarn splitter, and the glass fiber yarn is adjusted into upper, lower, left and right parts through the holes in the yarn splitter, which is the first step adjustment before the dipped glass fiber enters the mold. Through this step, the glass fiber yarn is first distributed in the approximate shape of the cross section of the molding material.
[48] 经过分纱器的初步调整后, 浸胶玻璃纤维进入预成型调整模。 预成型调整模用 于给各增强材料定位, 它促使各增强材料按设定的排列方式进入模具, 保证各 增强材料在进入模具后不会产生纠缠错乱, 同吋将玻璃纤维上多余的树脂以及 树脂内包含的气泡挤出, 确保型材质量。 [48] After the initial adjustment of the yarn splitter, the dipped glass fiber enters the preforming adjustment mold. The preforming adjustment mold is used for positioning the reinforcing materials, which causes the reinforcing materials to enter the mold in a set arrangement, ensuring that the reinforcing materials do not cause entanglement after entering the mold, and the excess resin on the glass fibers is also The bubbles contained in the resin are extruded to ensure the quality of the profile.
[49] 步骤 4, 上述纤维毡、 纤维布、 浸胶的纤维束和金属带在穿过预成型调整模具 后, 被牵引进入加热成型模具 14进行成型固化。 步骤 4中, 加热成型模具 14至树 脂槽 9连接一倾斜的树脂回流槽 13。 成型固化在型材模具内完成, 是型材成型的 最终步骤。 模具一般有顶模、 底模、 左模、 右模、 芯铁组成, 顶、 底、 左、 右 侧模围绕芯铁形成一定形状的空腔, 该空腔即为型材的成型腔。 浸胶玻璃纤维 从预成型调整模出来以后直接进入模具, 进入模具后浸胶玻璃纤维由于互相挤 压而填充满整个成型腔, 同吋模具被加热板加热, 树脂混合物也在模具加热作 用下反应固化, 并在牵引机的带动下穿过模具, 固化过程在型材还没有出模具 之前就已经完成。 [49] Step 4, the fiber mat, the fiber cloth, the dipped fiber bundle, and the metal strip are drawn into the heating mold 14 to form and cure after passing through the preform adjustment mold. In step 4, the molding die 14 is heated to the resin tank 9 to connect a slanted resin return tank 13. Forming and curing is done in the profile mold and is the final step in profile forming. The mold generally comprises a top mold, a bottom mold, a left mold, a right mold and a core iron, and the top, bottom, left and right side molds form a cavity of a certain shape around the core iron, and the cavity is a molding cavity of the profile. The dipped glass fiber enters the mold directly after exiting from the preforming mold. After entering the mold, the dipped glass fiber fills the entire molding cavity by pressing each other, and the same mold is heated by the heating plate, and the resin mixture is also reacted under the heating of the mold. Curing, and passing through the mold driven by the tractor, the curing process is completed before the profile has been released.
[50] 步骤 5, 从加热成型模具 14中出来的已成型型材 17牵引至切割锯 16进行切断。  [50] Step 5, the formed profile 17 from the heated molding die 14 is pulled to the dicing saw 16 for cutting.
在拉挤生产线的末段, 自动切割锯根据设定长度自动检测并切割型材至所需要 的尺寸。  At the end of the pultrusion line, the automatic dicing saw automatically detects and cuts the profile to the required size according to the set length.
[51] 参见图 3 - 5, 金属增强型玻璃钢门窗拉挤型材的生产装置, 其特征在于: 顺序 由纱架 3、 树脂槽 9、 分纱器 11、 预成型调整模 12、 加热成型模具 14、 牵引机 15 、 切割锯 16—字形排列而成, 纱架 3上放置两层或多层纱桶 4、 两边侧固定放置 金属带托盘 6的第一支架 5和放置纤维毡托盘 8的第二支架 7, 加热成型模具 14至 树脂槽 9连接一倾斜的树脂回流槽 13。  [51] Referring to Fig. 3-5, the production device of the metal reinforced FRP door and squeezing profile is characterized in that: the creel 3, the resin groove 9, the yarn distributor 11, the preform adjustment die 12, and the heating molding die 14 are sequentially arranged. , the tractor 15 and the dicing saw 16 are arranged in a zigzag manner, the creel 3 is placed with two or more layers of the yarn barrel 4, the first bracket 5 on which the metal belt tray 6 is fixed on both sides, and the second unit on which the fiber mat tray 8 is placed The holder 7, the thermoforming mold 14 to the resin tank 9 is connected to an inclined resin return tank 13.
[52] 本发明不需要增加额外的设备, 把金属带缠绕成卷并利用上面提到的托盘在纱 架上固定, 工作吋金属带在牵弓 I机带动下随玻璃纤维增强材料一起进入模具并 与型材固化为一体。  [52] The present invention does not require the addition of additional equipment, winds the metal strip into a roll and secures it on the creel using the tray mentioned above, and the working yoke metal strip enters the mold along with the glass fiber reinforced material under the pull of the yoke And solidification with the profile.

Claims

权利要求书 Claim
[1] 1、 一种金属增强型玻璃钢门窗拉挤型材, 由至少两个纵向的薄壁、 至少两 个横向的薄壁围合成具有空腔 (108) 的细长空心杆件形状, 其特征在于: 在上述至少一个薄壁内部有一层金属带 (105) , 上述薄壁的横断面自外至 内依次有纤维毡 (102) 、 纤维布 (103) 、 纤维束 (104) 、 金属带 (105 ) 、 纤维布 (103) , 上述各层由树脂混合物浸渍、 固化为一体。  [1] 1. A metal reinforced fiberglass door and window pultruded profile, wherein an elongated hollow member having a cavity (108) is formed by at least two longitudinal thin walls and at least two transverse thin walls. The method comprises: a metal strip (105) inside the at least one thin wall, wherein the thin-walled cross-section has a fiber mat (102), a fiber cloth (103), a fiber bundle (104), and a metal strip (from the outside to the inside). 105), the fiber cloth (103), each of the above layers is impregnated and solidified by a resin mixture.
[2] 2、 根据权利要求 1所述的金属增强型玻璃钢门窗拉挤型材, 其特征在于: 上述薄壁围合成的空腔内有内隔断 (106) 。  [2] 2. The metal reinforced fiberglass door and window pultruded profile according to claim 1, wherein the thin-walled composite cavity has an internal partition (106).
[3] 3、 根据权利要求 1或 2所述的金属增强型玻璃钢门窗拉挤型材, 其特征在于 [3] 3. The metal reinforced fiberglass door and window pultruded profile according to claim 1 or 2, characterized in that
: 上述薄壁的外表面有凹槽 (107) 。 : The outer surface of the thin wall has a groove (107).
[4] 4、 根据权利要求 3所述的金属增强型玻璃钢门窗拉挤型材, 其特征在于: 上述金属带 (105) 的厚度为 0.5〜1.0mm。  [4] The metal reinforced fiberglass door and window pultruded profile according to claim 3, wherein the metal strip (105) has a thickness of 0.5 to 1.0 mm.
[5] 5、 一种权利要求 4所述的金属增强型玻璃钢门窗拉挤型材的生产方法, 其 特征在于: 将制作金属增强型玻璃钢门窗拉挤型材的纤维增强材料和金属 带在牵引车的带动下, 依次完成以下步骤:  [5] 5. A method for producing a metal reinforced fiberglass door and window pultruded profile according to claim 4, characterized in that: a fiber reinforced material and a metal strip for producing a metal reinforced fiberglass door and window pultruded profile are used in a tractor With the following steps, complete the following steps in order:
步骤 1, 用牵引机 (15) 将纤维毡、 纤维布、 纤维束和金属带从纱架 (3) 上和纱桶 (4) 中同向牵引;  Step 1. Pull the fiber mat, fiber cloth, fiber bundle and metal belt from the creel (3) and the yarn drum (4) in the same direction with a tractor (15);
步骤 2, 将牵引出的纤维束在树脂槽 (9) 内浸渗树脂混合物 (10) , 俗称 浸胶;  Step 2, impregnating the drawn fiber bundle into the resin tank (9) to impregnate the resin mixture (10), commonly known as dipping;
步骤 3, 继续牵引上述纤维毡、 纤维布、 浸胶的纤维束和金属带使它们分别 先从分纱器 (11) 中预定的空隙中穿过, 再穿过预成型调整模 (12) ; 步骤 4, 上述纤维毡、 纤维布、 浸胶的纤维束和金属带在穿过预成型调整模 具后, 被牵引进入加热成型模具 (14) 进行成型固化;  Step 3, continue to draw the fiber mat, the fiber cloth, the dipped fiber bundle and the metal strip so that they first pass through a predetermined gap in the yarn splitter (11), and then pass through the preform adjustment mold (12); Step 4, the fiber mat, the fiber cloth, the dipped fiber bundle and the metal strip are drawn into the heating forming mold (14) to form and cure after passing through the preform adjusting mold;
步骤 5, 从加热成型模具 (14) 中出来的已成型型材 (17) 牵引至切割锯 ( 16) 进行切断。  Step 5. The formed profile (17) from the heated molding die (14) is pulled to the cutting saw (16) for cutting.
[6] 6、 根据权利要求 5所述的金属增强型玻璃钢门窗拉挤型材的生产方法, 其 特征在于: 上述步骤 1中, 纱架的两侧连接放置金属带托盘 (6) 的第一支 架 (5) 和放置纤维毡托盘 (8) 的第二支架 (7) 。 [6] 6. The method for producing a metal reinforced fiberglass door and window pultruded profile according to claim 5, wherein: in the above step 1, the first bracket of the metal tape tray (6) is connected to both sides of the creel. (5) and place the second bracket (7) of the fiber felt tray (8).
7、 根据权利要求 5所述的金属增强型玻璃钢门窗拉挤型材的生产方法, 其 特征在于: 上述步骤 3中, 分纱器 (11) 为格栅状, 格栅的上下左右边缘均 开有纤维毡扁孔和纤维布扁孔, 分纱器的内孔两侧边缘开有金属带扁孔, 分纱器的芯部有一个方孔。 The method for producing a metal reinforced fiberglass door and window pultruded profile according to claim 5, wherein in the step 3, the yarn splitter (11) is in the form of a grid, and the upper and lower edges of the grille are opened. The fiber felt flat hole and the fiber cloth flat hole, the metal fiber flat hole is opened on both sides of the inner hole of the yarn splitter, and the core of the yarn splitter has a square hole.
8、 根据权利要求 5所述的金属增强型玻璃钢门窗拉挤型材的生产方法, 其 特征在于: 上述步骤 4中, 加热成型模具 (14) 至树脂槽 (9) 连接一倾斜 的树脂回流槽 (13) 。  The method for producing a metal reinforced fiberglass door and window pultrusion profile according to claim 5, wherein in the step 4, the heating molding die (14) is connected to the resin tank (9) to connect to an inclined resin return groove ( 13).
9、 一种权利要求 1或 2或 4所述的金属增强型玻璃钢门窗拉挤型材的生产装 置, 其特征在于: 顺序由纱架 (3) 、 树脂槽 (9) 、 分纱器 (11) 、 预成 型调整模 (12) 、 加热成型模具 (14) 、 牵引机 (15) 、 切割锯 (16) — 字形排列而成, 纱架 (3) 上放置至少一层纱桶 (4) 、 两边侧固定放置金 属带托盘 (6) 的第一支架 (5) 和放置纤维毡托盘 (8) 的第二支架 (7) 加热成型模具 (14) 至树脂槽 (9) 连接一倾斜的树脂回流槽 (13  9. A device for producing a metal reinforced fiberglass door and window pultruded profile according to claim 1 or 2 or 4, characterized by: a sequence of a creel (3), a resin tank (9), and a yarn splitter (11) , preforming adjustment mold (12), heating molding mold (14), tractor (15), cutting saw (16) - arranged in a glyph, placing at least one layer of yarn drum (4) on the creel (3), both sides The first bracket (5) on which the metal tape tray (6) is placed sideways and the second bracket (7) on which the fiber felt tray (8) is placed are heated to form a mold (14) to the resin tank (9) to connect a tilted resin return tank (13
PCT/CN2007/070307 2007-05-14 2007-07-17 A glass fiber reinforced plastic door and window profile with reinforcing metal strip WO2008138190A1 (en)

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CN2007102006093A CN101050684B (en) 2007-05-14 2007-05-14 Drawing and extruding section bar for metal reinforced glass fiber reinforced plastic door and window and its producing method

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105196570A (en) * 2015-11-11 2015-12-30 张宏文 Glass steel pultrusion arc-shaped profile production technology and device
CN108422676A (en) * 2018-04-08 2018-08-21 湖北中复能新型材料有限公司 The FRP connection section bars of steel band and its former and connection method built in a kind of
CN112482678A (en) * 2020-12-01 2021-03-12 南通德瑞森复合材料有限公司 Glass fiber reinforced plastic stair sloping beam shaped like Chinese character' ri

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201211335A (en) * 2010-06-18 2012-03-16 Interface Inc Portable creels with insertable yarn trays and improved headers and yarn handling methods
DE102011007018A1 (en) * 2011-04-08 2012-10-11 Voith Patent Gmbh Apparatus and process for the production of fiber preforms, which are in particular a precursor in the production of fiber-reinforced plastic components
CN103286963A (en) * 2012-03-02 2013-09-11 深圳光启创新技术有限公司 Preparation method of glass-reinforced plastic, and glass-reinforced plastic antenna housing and preparation method thereof
WO2013134191A1 (en) 2012-03-05 2013-09-12 Interface, Inc. Header system
CN102756281B (en) * 2012-06-27 2014-04-16 上海电机学院 Assembling line for glass-fiber reinforced plastic windows
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CN111473237B (en) * 2020-04-16 2020-12-22 常州市新创智能科技有限公司 Pultrusion plate body structure and preforming process thereof
CN112140592A (en) * 2020-09-11 2020-12-29 山东明珠材料科技有限公司 Manufacturing method and manufacturing device of reinforced polyurethane material for doors and windows
CN112721242A (en) * 2020-12-02 2021-04-30 安徽鑫煜门窗有限公司 Glass steel door die assembly

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19736393A1 (en) * 1997-08-21 1999-02-25 Huels Troisdorf Profile system for manufacturing windows and doors
CN1358622A (en) * 2001-12-23 2002-07-17 张国志 Method for making multi-cavity hollow profile glass fibre reinforced plastic material
EP1225297A1 (en) * 2001-01-19 2002-07-24 DFS Technology & Service AG Window construction and window frame
CN2573634Y (en) * 2002-07-18 2003-09-17 穆荣 Sections for glass fibre reinforced plastic door and window with reinforcing metal plate embedded in its wall
CN1584276A (en) * 2004-05-31 2005-02-23 钟林 Polyurethane and PVC door window structural section
CN1730270A (en) * 2005-08-02 2006-02-08 中材科技股份有限公司 Pultrusion method for thermoplastic composite material and forming die thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19736393A1 (en) * 1997-08-21 1999-02-25 Huels Troisdorf Profile system for manufacturing windows and doors
EP1225297A1 (en) * 2001-01-19 2002-07-24 DFS Technology & Service AG Window construction and window frame
CN1358622A (en) * 2001-12-23 2002-07-17 张国志 Method for making multi-cavity hollow profile glass fibre reinforced plastic material
CN2573634Y (en) * 2002-07-18 2003-09-17 穆荣 Sections for glass fibre reinforced plastic door and window with reinforcing metal plate embedded in its wall
CN1584276A (en) * 2004-05-31 2005-02-23 钟林 Polyurethane and PVC door window structural section
CN1730270A (en) * 2005-08-02 2006-02-08 中材科技股份有限公司 Pultrusion method for thermoplastic composite material and forming die thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105196570A (en) * 2015-11-11 2015-12-30 张宏文 Glass steel pultrusion arc-shaped profile production technology and device
CN108422676A (en) * 2018-04-08 2018-08-21 湖北中复能新型材料有限公司 The FRP connection section bars of steel band and its former and connection method built in a kind of
CN112482678A (en) * 2020-12-01 2021-03-12 南通德瑞森复合材料有限公司 Glass fiber reinforced plastic stair sloping beam shaped like Chinese character' ri

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