WO2008120783A1 - Water-and-oil-repellent antifouling antireflection film, process for producing the same, lens, glass plate, and glass each having the same, and optical device, apparatus for utilizing solar energy, and display each employing these - Google Patents

Water-and-oil-repellent antifouling antireflection film, process for producing the same, lens, glass plate, and glass each having the same, and optical device, apparatus for utilizing solar energy, and display each employing these Download PDF

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Publication number
WO2008120783A1
WO2008120783A1 PCT/JP2008/056373 JP2008056373W WO2008120783A1 WO 2008120783 A1 WO2008120783 A1 WO 2008120783A1 JP 2008056373 W JP2008056373 W JP 2008056373W WO 2008120783 A1 WO2008120783 A1 WO 2008120783A1
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WO
WIPO (PCT)
Prior art keywords
water
oil
same
glass
repellent antifouling
Prior art date
Application number
PCT/JP2008/056373
Other languages
French (fr)
Japanese (ja)
Inventor
Kazufumi Ogawa
Original Assignee
Kazufumi Ogawa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kazufumi Ogawa filed Critical Kazufumi Ogawa
Priority to US12/593,874 priority Critical patent/US20100119774A1/en
Publication of WO2008120783A1 publication Critical patent/WO2008120783A1/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1675—Polyorganosiloxane-containing compositions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/68—Particle size between 100-1000 nm
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11—Anti-reflection coatings
    • G02B1/118—Anti-reflection coatings having sub-optical wavelength surface structures designed to provide an enhanced transmittance, e.g. moth-eye structures
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/18—Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/0006—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 with means to keep optical surfaces clean, e.g. by preventing or removing dirt, stains, contamination, condensation
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
    • C03C2217/42—Coatings comprising at least one inhomogeneous layer consisting of particles only
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/73—Anti-reflective coatings with specific characteristics
    • C03C2217/732—Anti-reflective coatings with specific characteristics made of a single layer
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/76—Hydrophobic and oleophobic coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24364—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.] with transparent or protective coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y10T428/24413—Metal or metal compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y10T428/24421—Silicon containing

Abstract

A water-and-oil-repellent antifouling antireflection film which has water-and-oil repellency, unsusceptibility to fouling, waterdrop repellency, and durability; a process for producing the film; a lens, glass plate, and glass each having a water-and-oil-repellent antifouling antireflection film formed on a surface thereof; and an optical device, apparatus for utilizing solar energy, and display each employing the lens, glass plate, and glass. The glass plate (10) having a water-and-oil-repellent antifouling antireflection film formed comprises: a platy substrate (5); fine transparent particles (1a) with water-and-oil repellency and unsusceptibility to fouling which have been fusion-bonded to a surface of the substrate (5); and a coating film (8) which is made of a water-and-oil-repellent antifouling substance and with which those areas in the surface of the substrate (5) which do not have fine transparent particles (1a) fusion-bonded thereto are covered. The surface of each fine transparent particle (1) has been partly fusion-bonded to the surface of the substrate (5), and the exposed part of the particle has been covered with the coating film (8) made of a water-and-oil-repellent antifouling substance.
PCT/JP2008/056373 2007-03-30 2008-03-31 Water-and-oil-repellent antifouling antireflection film, process for producing the same, lens, glass plate, and glass each having the same, and optical device, apparatus for utilizing solar energy, and display each employing these WO2008120783A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/593,874 US20100119774A1 (en) 2007-03-30 2008-03-31 Water-repellent, oil-repellent, and antifouling antireflection film and method for manufacturing the same, lens, glass sheet, and glass coated with the same, and optical apparatus, solar energy system, and display equipped with these components

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-093641 2007-03-30
JP2007093641A JP5347124B2 (en) 2007-03-30 2007-03-30 Water and oil repellent and antifouling antireflection film, method for producing the same, lens, glass plate and glass formed therewith, optical device using them, solar energy utilization device, display

Publications (1)

Publication Number Publication Date
WO2008120783A1 true WO2008120783A1 (en) 2008-10-09

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ID=39808363

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PCT/JP2008/056373 WO2008120783A1 (en) 2007-03-30 2008-03-31 Water-and-oil-repellent antifouling antireflection film, process for producing the same, lens, glass plate, and glass each having the same, and optical device, apparatus for utilizing solar energy, and display each employing these

Country Status (3)

Country Link
US (1) US20100119774A1 (en)
JP (1) JP5347124B2 (en)
WO (1) WO2008120783A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8658888B2 (en) 2007-12-12 2014-02-25 Empire Technology Development Llc Solar energy utilization device and method for manufacturing the same
US9447284B2 (en) 2007-05-01 2016-09-20 Empire Technology Development Llc Water repellent glass plates
US10150889B2 (en) 2013-09-16 2018-12-11 Honeywell International Inc. Poly fluorine-containing siloxane coatings

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JP2008282750A (en) * 2007-05-14 2008-11-20 Kagawa Gakusei Venture:Kk Ice-accretion and snow-accretion preventive antenna and electric wire, insulator having water-repellent and oil-repellent anti-fouling surfaces, and their manufacturing method
JP2008282751A (en) * 2007-05-14 2008-11-20 Kagawa Gakusei Venture:Kk Ice-accretion and snow-accretion preventive insulator and electric wire, antenna, their manufacturing method, and power transmission steel tower using them
JP5564658B2 (en) * 2009-06-05 2014-07-30 国立大学法人 香川大学 Translucent member for display device, method for producing the same, display device using the same, and article
JP6049979B2 (en) * 2009-07-03 2016-12-21 ソニー株式会社 Optical element and display device
US8816974B2 (en) 2011-05-27 2014-08-26 Honeywell International Inc. Systems and methods for smudge control for touch screen human interface devices
EP2751848A1 (en) * 2011-08-29 2014-07-09 Saint-Gobain Glass France Thin-film photovoltaic module with hydrophobic rear-side coating
EP2871206B1 (en) * 2013-08-02 2020-09-30 LG Chem, Ltd. Anti-fingerprint films and electrical and electronic apparatus
US10640521B2 (en) * 2014-12-05 2020-05-05 Velox Flow, Llc Multifunctional superhydrophobic particles for chemical adhesion and blooming
JP2017110979A (en) * 2015-12-15 2017-06-22 株式会社ミツトヨ Measuring instrument
JP7004620B2 (en) * 2018-07-27 2022-02-10 京セラ株式会社 Coupling method, lens, holding mechanism, camera device and moving object

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WO2004052640A1 (en) * 2002-12-10 2004-06-24 Nippon Sheet Glass Co., Ltd. Article having functional coating film thereon, method for manufacture thereof, and applying material for forming functional coating film
JP2007333291A (en) * 2006-06-14 2007-12-27 Kagawa Univ Solar energy using device and method of manufacturing the same
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JP2008007363A (en) * 2006-06-28 2008-01-17 Kagawa Univ Water-repellent, oil-repellent and antifouling glass plate, method for manufacturing the same, and transport equipment, building and optical instrument using the same

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JPH04239633A (en) * 1991-01-23 1992-08-27 Matsushita Electric Ind Co Ltd Water and repelling film and manufacture thereof
JP2001180981A (en) * 1999-12-24 2001-07-03 Asahi Glass Co Ltd Glass member for facing having glare-proof coating and method of setting it up
WO2004052640A1 (en) * 2002-12-10 2004-06-24 Nippon Sheet Glass Co., Ltd. Article having functional coating film thereon, method for manufacture thereof, and applying material for forming functional coating film
JP2007333291A (en) * 2006-06-14 2007-12-27 Kagawa Univ Solar energy using device and method of manufacturing the same
JP2008007365A (en) * 2006-06-28 2008-01-17 Kagawa Univ Solar energy utilization equipment and method for manufacturing the same
JP2008007363A (en) * 2006-06-28 2008-01-17 Kagawa Univ Water-repellent, oil-repellent and antifouling glass plate, method for manufacturing the same, and transport equipment, building and optical instrument using the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9447284B2 (en) 2007-05-01 2016-09-20 Empire Technology Development Llc Water repellent glass plates
US8658888B2 (en) 2007-12-12 2014-02-25 Empire Technology Development Llc Solar energy utilization device and method for manufacturing the same
US10150889B2 (en) 2013-09-16 2018-12-11 Honeywell International Inc. Poly fluorine-containing siloxane coatings

Also Published As

Publication number Publication date
JP5347124B2 (en) 2013-11-20
US20100119774A1 (en) 2010-05-13
JP2008247699A (en) 2008-10-16

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