WO2008120666A1 - Method for producing bisphenol compound and cation-exchange resin catalyst - Google Patents

Method for producing bisphenol compound and cation-exchange resin catalyst Download PDF

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Publication number
WO2008120666A1
WO2008120666A1 PCT/JP2008/055884 JP2008055884W WO2008120666A1 WO 2008120666 A1 WO2008120666 A1 WO 2008120666A1 JP 2008055884 W JP2008055884 W JP 2008055884W WO 2008120666 A1 WO2008120666 A1 WO 2008120666A1
Authority
WO
WIPO (PCT)
Prior art keywords
cation
exchange resin
compound
resin catalyst
mercapto group
Prior art date
Application number
PCT/JP2008/055884
Other languages
French (fr)
Japanese (ja)
Inventor
Susumu Tsutsuminai
Original Assignee
Mitsubishi Chemical Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corporation filed Critical Mitsubishi Chemical Corporation
Publication of WO2008120666A1 publication Critical patent/WO2008120666A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
    • C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
    • C07C39/16—Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Disclosed is a method for producing a bisphenol compound, which enables to produce a bisphenol compound with high conversion rate and high selectivity. Also disclosed is a cation-exchange resin catalyst having high activity. Specifically, a phenol compound is reacted with a carbonyl compound in the presence of a cation-exchange resin catalyst having a constitutional unit represented by the general formula (1) below and a compound having a mercapto group or a protected mercapto group, or alternatively in the presence of a cation-exchange resin catalyst having a constitutional unit obtained by modifying a constitutional unit represented by the general formula (1) below with a compound having a mercapto group or a protected mercapto group. (In the formula (1), R1, R2 and R3 independently represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted aryl group or a halogen atom; X represents an electron-withdrawing group substituting only one aromatic ring bonded to the main chain of the cation-exchange resin; and n represents an integer of 1-4.)
PCT/JP2008/055884 2007-03-30 2008-03-27 Method for producing bisphenol compound and cation-exchange resin catalyst WO2008120666A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-092697 2007-03-30
JP2007092697 2007-03-30

Publications (1)

Publication Number Publication Date
WO2008120666A1 true WO2008120666A1 (en) 2008-10-09

Family

ID=39808248

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/055884 WO2008120666A1 (en) 2007-03-30 2008-03-27 Method for producing bisphenol compound and cation-exchange resin catalyst

Country Status (4)

Country Link
JP (1) JP2008273951A (en)
KR (1) KR20090123846A (en)
TW (1) TW200916437A (en)
WO (1) WO2008120666A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010173949A (en) * 2009-01-28 2010-08-12 Mitsubishi Chemicals Corp Method for producing bisphenols
US8445731B2 (en) 2009-01-22 2013-05-21 Mitsubishi Chemical Corporation Process for producing bisphenol compound

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5332846B2 (en) * 2009-04-10 2013-11-06 三菱化学株式会社 Strongly acidic ion-exchange resin catalyst for bisphenol compound production and method for producing bisphenol compound using the same
KR101644362B1 (en) * 2013-12-31 2016-08-02 주식회사 삼양사 Cation exchange resin for bisphenol synthesis and method for preparing the same, and method for synthesizing bisphenol by using the cation exchange resin
JP7371682B2 (en) * 2019-03-18 2023-10-31 三菱ケミカル株式会社 Method for producing bisphenol and method for producing polycarbonate resin

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05111641A (en) * 1991-03-07 1993-05-07 Dow Chem Co:The Oxidation resisting cation-exchange resin
JPH07116525A (en) * 1993-10-21 1995-05-09 Tokyo Organ Chem Ind Ltd Cation exchange resin
JP2002060360A (en) * 2000-08-16 2002-02-26 Mitsubishi Chemicals Corp Method for producing bisphenol
JP2003160526A (en) * 2001-11-27 2003-06-03 Manac Inc Method for producing dimer and trimer of hydroquinone

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05111641A (en) * 1991-03-07 1993-05-07 Dow Chem Co:The Oxidation resisting cation-exchange resin
JPH07116525A (en) * 1993-10-21 1995-05-09 Tokyo Organ Chem Ind Ltd Cation exchange resin
JP2002060360A (en) * 2000-08-16 2002-02-26 Mitsubishi Chemicals Corp Method for producing bisphenol
JP2003160526A (en) * 2001-11-27 2003-06-03 Manac Inc Method for producing dimer and trimer of hydroquinone

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8445731B2 (en) 2009-01-22 2013-05-21 Mitsubishi Chemical Corporation Process for producing bisphenol compound
JP2010173949A (en) * 2009-01-28 2010-08-12 Mitsubishi Chemicals Corp Method for producing bisphenols

Also Published As

Publication number Publication date
JP2008273951A (en) 2008-11-13
TW200916437A (en) 2009-04-16
KR20090123846A (en) 2009-12-02

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