WO2008106824A1 - Fuel cell - Google Patents

Fuel cell Download PDF

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Publication number
WO2008106824A1
WO2008106824A1 PCT/CN2007/000719 CN2007000719W WO2008106824A1 WO 2008106824 A1 WO2008106824 A1 WO 2008106824A1 CN 2007000719 W CN2007000719 W CN 2007000719W WO 2008106824 A1 WO2008106824 A1 WO 2008106824A1
Authority
WO
WIPO (PCT)
Prior art keywords
negative
positive
fuel cell
electrode
battery
Prior art date
Application number
PCT/CN2007/000719
Other languages
French (fr)
Chinese (zh)
Inventor
Zhongde Zheng
Jinliang Wang
Jinhua Ren
Dongkui Wang
Xiaorong Sun
Hongdan Yin
Original Assignee
Golden Energy Fuel Cell Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Golden Energy Fuel Cell Co., Ltd. filed Critical Golden Energy Fuel Cell Co., Ltd.
Priority to PCT/CN2007/000719 priority Critical patent/WO2008106824A1/en
Priority to CN2007800254171A priority patent/CN101485020B/en
Publication of WO2008106824A1 publication Critical patent/WO2008106824A1/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/247Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • H01M8/248Means for compression of the fuel cell stacks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/249Grouping of fuel cells, e.g. stacking of fuel cells comprising two or more groupings of fuel cells, e.g. modular assemblies
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • a fuel cell is a highly efficient clean electricity generator that directly converts chemical energy such as hydrogen and an oxidant such as oxygen in the air into electrical energy by an electrochemical reaction, and has an extremely broad application prospect.
  • the fuel cell comprises at least one battery unit, the battery unit has positive and negative baffles and membrane electrodes, the membrane electrode is located between the positive and negative baffles, and the membrane electrode is composed of a proton exchange membrane and positive and negative electrodes attached to both sides thereof.
  • Electrode reaction and battery reaction are:
  • the electrode participates in the positive reaction of the battery and the reaction heat of the fuel cell is directly emitted into the air, and requires various auxiliary devices such as a gas pump, a fan, a fan, a water pump, a cooling water plate, etc., which makes the fuel cell difficult to be miniaturized;
  • the fuel cell output voltage and current are single and inconvenient to use. Summary of the invention
  • the object of the present invention is to overcome the above drawbacks and provide a fuel cell which has a simple structure, small internal resistance, large output power, and can output various voltages and currents, is convenient to disassemble and maintain, is easy to be miniaturized, and is convenient to use.
  • a fuel cell comprising at least one battery unit having positive and negative baffles and a membrane electrode, the membrane electrode being located between the positive and negative baffles, wherein: the positive and negative baffles
  • a bolt hole is formed in the non-peripheral area, and a fastening bolt is inserted in the bolt hole.
  • the positive and negative baffles are insulating plates, and the non-peripheral regions of the positive and negative baffles are central regions.
  • the positive and negative baffles are insulating plates, and the non-peripheral regions of the positive and negative baffles are central regions.
  • a positive electrode conductive sheet is disposed between the positive electrode deflector and the membrane electrode of the battery unit, and a negative electrode conductive sheet is disposed between the negative electrode deflector and the membrane electrode, and the positive and negative conductive sheets and the membrane electrode are correspondingly provided with bolt holes.
  • the fastening hole is inserted into the bolt hole, and the positive electrode baffle and the positive electrode conductive plate respectively have a flow guiding hole and air communication, and the negative electrode baffle and the negative electrode conductive piece respectively have a diversion hole and a fuel chamber Connected.
  • the battery unit has one of the fuel cells, and the fuel chamber is surrounded by a groove on the back surface of the negative electrode deflector and a bottom cover.
  • the bottom cover is provided with a bolt hole, and the fastening hole is inserted into the bolt hole.
  • each battery cell There are a plurality of battery cells, and the battery cells are arranged side by side.
  • the fuel chamber of each battery cell is surrounded by a groove and a bottom cover on the back surface of the negative electrode deflector, and the bottom cover is provided with a bolt hole, and the bolt hole is worn inside.
  • the fastening bolts are connected to each other, and the bottom baffles of the battery cells are integrally connected.
  • the bottom cover of each battery unit is integrally connected, and the fuel chambers are connected, and the positive and negative conductive sheets of the adjacent battery cells are integrally connected.
  • the battery unit has a pair, and the negative electrode baffle is abutted against the anode, and the fuel chamber is formed by the recess of the back surface of the negative baffle.
  • the battery unit has a plurality of pairs, each pair of battery units are arranged side by side, and the negative electrode baffles of each pair of battery cells are oppositely facing each other, and the fuel chamber is formed by the corresponding recesses of the back surface of the negative electrode baffle plate, and each pair of batteries
  • the fuel chambers of the unit are connected, and the negative baffles of the respective battery cells are integrated, and the positive and negative conductive sheets of the adjacent two battery cells are integrated.
  • the positive electrode baffles of the battery cells are connected together.
  • the positive baffles of the pair of battery cells are connected together.
  • the fuel cell of the invention adopts a central bolt fastening method to connect the positive and negative deflectors, The membrane electrode and the positive and negative conductive sheets are pressed, and the positive and negative deflectors act as end plates.
  • the fastening bolts are located at the center of the positive and negative deflectors and the membrane electrode.
  • the fuel cell has a simple structure, convenient assembly and disassembly, and replacement of components. Easy and easy to maintain;
  • the fastening bolt only occupies a small space of the fuel cell, the catalytic active area of the membrane electrode is relatively large, and the central region of the fuel cell is also easy to be compacted. Under the same battery outer shape, the internal resistance of the fuel cell is small, and the output power is large;
  • the positive baffle Since there is no end plate, the positive baffle is completely exposed to the air, and the diversion hole is directly connected with the air.
  • the oxygen in the air directly diffuses to the membrane electrode to participate in the positive reaction of the battery, and the reaction heat of the fuel cell is directly emitted into the air, without An auxiliary device such as a gas pump, a fan, a fan, a water pump, a cooling water plate, etc., so that the fuel cell is easy to be miniaturized;
  • the negative baffle of each battery unit is integrated into one body, which not only simplifies the structure of the fuel cell, but also facilitates disassembly and assembly, and increases the overall strength
  • the positive baffle of each battery unit is integrated, which not only simplifies the structure of the fuel cell, It is more convenient to disassemble and assemble, and further increase the overall strength
  • the positive and negative conductive sheets of adjacent battery cells can be integrated into one body, and no welding and other conductive connecting members are needed, and the structure is simplified, and the disassembly and assembly is convenient.
  • Adjacent battery cells can be connected in series or in parallel (in series, the positive and negative conductive sheets of adjacent battery cells are connected together; when connected in parallel, the positive and negative conductive sheets of adjacent battery cells are connected together, negative and negative conductive sheets
  • the battery cells of the fuel cell can be conveniently connected in series, parallel, and mixed according to needs, thereby realizing various voltage and current outputs, and being convenient to use.
  • Fig. 1 is a plan view showing a first embodiment of the present invention.
  • Figure 2 is an enlarged cross-sectional view taken along line A - A of Figure 1;
  • Figure 3 is a plan view of a second embodiment of the present invention.
  • Figure 4 is an enlarged cross-sectional view taken along line B-B of Figure 3;
  • Figure 5 is a plan view of a third embodiment of the present invention.
  • Figure 6 is an enlarged cross-sectional view taken along line C-C of Figure 5;
  • Figure 7 is a cross-sectional view showing a fourth embodiment of the present invention.
  • Figure 8 is a cross-sectional view showing a fifth embodiment of the present invention.
  • Figure 9 is a cross-sectional view showing a sixth embodiment of the present invention.
  • Embodiment of the present invention W Example 1
  • the present invention is a fuel cell comprising a battery unit 10 having a positive electrode baffle 11, a negative electrode baffle 12 and a membrane electrode 13, and the membrane electrode 13 is located at the positive electrode conductance.
  • the center of the positive electrode baffle 11 and the negative electrode baffle 12 are correspondingly provided with bolt holes, and the fastening bolts 1 are bored in the bolt holes.
  • a positive electrode conductive sheet 14 is disposed between the positive electrode deflector 11 and the membrane electrode 13 of the battery unit 10, and a negative electrode conductive sheet 15, a positive electrode conductive sheet 14, and a negative electrode conductive sheet 15 are disposed between the negative electrode deflector 12 and the membrane electrode 13.
  • the center of the membrane electrode 13 is correspondingly provided with a bolt hole, the bolt hole is provided with a fastening bolt 1 , the positive electrode baffle 11 is provided with a flow guiding hole 111 , and the positive electrode conductive sheet 14 is provided with a guiding hole 141 , and a guiding hole 111, 141 is in communication with the air.
  • the anode baffle 12 has a flow guiding hole 121, and the negative electrode conductive sheet 15 has a flow guiding hole 151, and the flow guiding holes 121 and 151 communicate with the fuel chamber 3.
  • the fuel chamber 3 of the battery unit 10 is surrounded by a recess 122 and a bottom cover 6 on the back surface of the negative deflector 12, and a bolt hole is formed in the center of the bottom cover 6.
  • the fastening bolt 1 is sequentially passed through the bolt hole at the center of the bottom cover 6 through the negative electrode baffle 12, the negative electrode conductive plate 15, the membrane electrode 13, the positive electrode conductive plate 14, and the bolt hole at the center of the positive electrode deflector 11, and then the nut 2 is Locked.
  • the fuel chamber 3 has a fuel inlet 4 on one side and a fuel outlet 5 on the other side.
  • the fuel outlet 5 serves to evacuate and connect other battery unit fuel inlets.
  • the positive electrode baffle plate 11 and the negative electrode baffle plate 12 may be composed of a plastic plate.
  • the positive electrode conductive piece 14 and the negative electrode conductive piece 15 may be composed of a nickel piece, a stainless steel piece, a gold plated copper piece or the like, and the bottom cover 6 may be composed of a plastic plate.
  • the hydrogen fuel enters the fuel chamber 3 from the fuel inlet 4, and the hydrogen gas sequentially passes through the flow guiding hole 121 on the negative electrode deflector 12, the flow guiding hole 151 on the negative electrode conductive sheet 15, and reaches the negative electrode of the membrane electrode 13 to dissociate into protons and electrons;
  • the protons reach the positive electrode of the membrane electrode 13 through the proton exchange membrane;
  • the electrons pass through the negative electrode conductive sheet 15, the load, and the positive electrode conductive sheet 14 reach the positive electrode of the membrane electrode 13;
  • the oxygen passes through the flow guiding hole 111 on the positive electrode deflector 11, and the positive electrode conductive sheet 14
  • the upper flow guiding hole 141 reaches the positive electrode of the membrane electrode; the protons, electrons, and oxygen are combined in the positive electrode of the membrane electrode 13 to form water.
  • the positive electrode baffle 11 and the negative electrode baffle 12 not only serve to press the membrane electrode 13, the positive electrode conductive sheet 14, and the negative electrode conductive sheet 15, but also function as heat conduction and heat dissipation, and the flow guiding hole thereof 111, 121 also played a role in guiding air and guiding water.
  • the positive electrode conductive sheet 14 and the negative electrode conductive sheet 15 function as a conductive force, and the flow guiding holes 141 and 151 also function to conduct air and conduct water.
  • the fastening bolt 1 occupies only a small space of the fuel cell, and the membrane electrode 13 is catalyzed.
  • the active area is relatively large, and the central portion of the fuel cell is also easily compressed. Therefore, under the same battery size, the internal resistance of the fuel cell is small and the output power is large; since there is no end plate, the positive baffle 11 is completely exposed to the air.
  • the guiding hole 111 is directly connected with the air, and the oxygen in the air directly diffuses to the membrane electrode 13 to participate in the positive electrode reaction of the battery, and the reaction heat of the fuel cell is directly emitted into the air, without the aid of an air pump, a fan, a fan, a water pump, a cooling water plate, etc.
  • the device is thus easy to miniaturize and easy to use.
  • the present invention is a fuel cell comprising two battery cells 10, and the two battery cells 10 are arranged side by side.
  • the structure of each battery cell 10 is the same as that of the first embodiment, and each battery cell 10 is
  • the fuel chamber 3 is surrounded by a recess 122 and a bottom cover 6 on the back surface of the negative electrode deflector 12.
  • the negative baffles 12 of the two battery cells 10 are integrally connected, and the bottom cover 6 of the two battery cells 10 are connected.
  • the fuel cells 3 of the two battery cells 10 are in communication with a fuel inlet 4 on one side and a fuel outlet 5 on the other side.
  • the negative baffle 12 is integrally connected, and the bottom cover 6 is integrated, which not only simplifies the structure of the fuel cell, but also facilitates disassembly and assembly, and increases the overall strength.
  • the positive electrode conductive sheets 14 of the first battery unit 10 are integrated with the negative electrode conductive sheets 15 of the second battery unit 10, thereby connecting the two battery units 10 in series without soldering and other conductive connections. Parts, simplified structure, easy to disassemble.
  • the positive electrode conductive sheet 14 of the first battery unit 10 and the positive electrode conductive sheet 14 of the second battery unit 10 may be integrally connected, and the negative electrode conductive sheet 15 of the first battery unit 10 and the second battery may be connected.
  • the negative electrode conductive sheets 15 of the unit 10 are integrally connected, thereby connecting the two battery cells 10 in parallel.
  • a plurality of battery cells can be arranged side by side in the above manner, and the battery cells of the fuel cell can be conveniently connected in series, parallel, and mixed according to requirements, thereby realizing various voltage and current outputs, and being convenient to use.
  • Embodiment 3
  • the present invention is a fuel cell comprising two battery cells 10, the structure of which is basically the same as that of the second embodiment, except that the positive electrode baffles of the two battery cells 10 are connected.
  • the structure of the fuel cell is simplified, the disassembly and assembly is more convenient, and the overall strength of the fuel cell is further increased.
  • Embodiment 4 The working principle of this embodiment is the same as that of the first embodiment, and will not be repeated. Embodiment 4
  • the present invention is a fuel cell comprising a pair of battery cells 50 comprised of two battery cells 20, 30 stacked on a battery cell 20.
  • the battery unit 20 has a positive electrode baffle 21, a negative electrode baffle 22 and a membrane electrode 23, and the membrane electrode 23 is located between the positive electrode baffle 21 and the negative electrode baffle 22, and the positive electrode baffle 21 and the negative electrode baffle 22 A bolt hole is formed in the center, and a fastening bolt 1 is inserted in the bolt hole.
  • a positive electrode conductive sheet 24 is disposed between the positive electrode deflector 21 and the membrane electrode 23, and a negative electrode conductive sheet 25 is disposed between the negative electrode deflector 22 and the membrane electrode 23.
  • the center of the positive electrode conductive sheet 24, the negative electrode conductive sheet 25, and the membrane electrode 23 is correspondingly provided with a bolt hole through which the fastening bolt 1 is bored.
  • the positive electrode baffle 21 is provided with a flow guiding hole 21, and the positive electrode conductive piece 24 is provided with a flow guiding hole 241, and the guiding holes 21 1 and 241 are in communication with the air.
  • the anode baffle 22 has a flow guiding hole 221, and the negative electrode conductive sheet 25 has a flow guiding hole 251, and the guiding holes 221 and 251 communicate with the fuel chamber 3.
  • the battery unit 30 has a positive electrode baffle 31, a negative electrode baffle 32 and a membrane electrode 33.
  • the membrane electrode 33 is located between the positive electrode baffle 31 and the negative baffle 32, and the positive baffle 3 1 and the negative electrode conductance.
  • a bolt hole is formed in the center of the plate 32, and a fastening bolt 1 is bored in the bolt hole.
  • a positive electrode conductive sheet 34 is disposed between the positive electrode baffle 31 and the membrane electrode 33, and a negative electrode conductive sheet 35 is disposed between the negative electrode baffle 32 and the membrane electrode 33.
  • the center of the positive electrode conductive sheet 34, the negative electrode conductive sheet 35, and the membrane electrode 33 is correspondingly provided with a bolt hole through which the fastening bolt 1 is bored.
  • the positive electrode baffle plate 3 has a flow guiding hole 3, and the positive electrode conductive piece 34 has a flow guiding hole 341, and the guiding holes 31 1 and 341 communicate with the air.
  • the anode baffle 32 has a flow guiding hole.
  • the negative electrode conductive sheet 35 has a flow guiding hole 35.
  • the flow guiding holes 321 and 351 communicate with the fuel chamber 3.
  • the fastening bolt 1 passes through the positive electrode deflector 21 of the battery unit 20, the positive electrode conductive sheet 24, the membrane electrode 23, the negative electrode conductive sheet 25, the negative electrode deflector 22, and the battery unit in this order. After the center through-holes of the negative electrode baffle 32, the negative electrode conductive sheet 35, the membrane electrode 33, the positive electrode conductive sheet 34, and the positive electrode deflector 35 of 30, the nut 2 is locked.
  • the back surface of the negative electrode baffle 22 has a recess 222
  • the back surface of the negative electrode baffle 32 has a recess 322
  • the negative baffles 22, 32 are abutted against each other, and the recesses 222, 322 are relatively fastened to form a fuel chamber 3
  • fuel The chamber 3 has a fuel inlet 4 on one side and a fuel outlet 5 on the other side.
  • the positive electrode baffles 21, 3 1 and the negative electrode deflectors 22, 32 may be composed of a plastic plate, and the positive electrode conductive sheets 24, 34 and the negative electrode conductive sheets 25, 35 may be composed of a nickel piece, a stainless steel piece, a gold plated copper piece or the like.
  • fastening bolt 1 only one fastening bolt 1 is used to penetrate the center of the fuel cell, the structure is simple, the disassembly and assembly is convenient, the replacement parts are easy, and the maintenance is easy; the fastening bolt 1 occupies only a small space of the fuel cell, and the membrane electrode 23, 33 The catalytic active area is relatively large, and the central region of the fuel cell is also easily compacted.
  • the internal resistance of the fuel cell is small and the output power is large; since there is no end plate, the positive electrode baffles 21, 31 are completely Exposed to the air, the diversion holes 211, 3 11 are directly connected to the air, and the oxygen in the air directly diffuses to the membrane electrodes 23, 33 to participate in the positive electrode reaction of the battery, and the reaction heat of the fuel cell is directly emitted into the air, without the need of an air pump or a fan.
  • the auxiliary device such as a fan, a water pump, a cooling water plate, and the like, so that the fuel cell is easy to be miniaturized and convenient to use.
  • the present invention is a fuel cell comprising two pairs of battery cells 50, each pair of battery cells 50 being comprised of two battery cells 20, 30 stacked on a battery cell 20.
  • the structure of each pair of battery cells 50 is the same as that of the fourth embodiment.
  • the negative baffles 22 of the lower two battery cells 20 of the two pairs of battery cells 50 are integrally connected, and the negative baffles 32 of the upper two battery cells 30 of the two pairs of battery cells 50 are integrated, not only for the fuel cell
  • the structure is simplified, the disassembly and assembly is convenient, and the overall strength of the fuel cell is increased.
  • the negative electrode conductive sheets 25 of the first pair of battery cells 50 are integrated with the positive electrode conductive sheets 24 of the second pair of battery cells 50, thereby connecting the lower two battery cells 20 of the two pairs of battery cells 50 in series without soldering and the like.
  • Conductive connector simplified structure, easy to disassemble.
  • the positive conductive sheets 34 of the first pair of battery cells 50 are integrated with the negative conductive sheets 35 of the second pair of battery cells 50, thereby connecting the upper two battery cells 30 of the two pairs of battery cells 50 in series, without soldering and the like.
  • Conductive connector simplified structure, disassembly Convenience.
  • the positive electrode conductive sheets 24 of the lower two battery cells 20 of the two pairs of battery cells 50 may be integrally connected, and the negative electrode conductive sheets 25 of the lower two battery cells 20 of the two pairs of battery cells 50 may be integrated into one body.
  • the lower two battery cells 20 of the two pairs of battery cells 50 are thereby connected in parallel.
  • the positive electrode conductive sheets 34 of the upper two battery cells 30 of the two pairs of battery cells 50 are integrally connected, and the negative electrode conductive sheets 35 of the upper two battery cells 30 of the two pairs of battery cells 50 are integrally connected, thereby The upper two battery cells 30 of the battery unit 50 are connected in parallel.
  • a plurality of pairs of battery cells may be arranged side by side in the above manner, and each pair of battery cells of the fuel cell may be conveniently connected in series, parallel, and mixed according to requirements, thereby realizing various voltage and current outputs, and being convenient to use.
  • the present invention is a fuel cell comprising two pairs of battery cells 50, the structure of which is substantially the same as that of the fifth embodiment, except that the positive electrode conductance of the lower two battery cells 20 of the two pairs of battery cells 50 is different.
  • the plates 21 are integrated, and the positive baffles 31 of the two upper battery cells 30 of the two pairs of battery cells 50 are integrated into one body, which not only simplifies the structure of the fuel cell, but also facilitates disassembly and assembly, and further strengthens the overall strength of the fuel cell. Increase.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
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  • Fuel Cell (AREA)

Abstract

A fuel cell which comprises at least one battery unit. The battery unit comprises positive and negative electrode fluid guide plates and membrane electrodes. The membrane electrodes are disposed between the positive and negative electrode fluid guide plates, wherein a bolt hole is disposed on the non-periphery area of the positive and negative electrode fluid guide plates correspondingly. A fastening bolt is disposed in the bolt hole. A positive conductive plate is interposed between the positive fluid guide and the membrane electrode of the battery unit and a negative conductive plate is interposed between the negative fluid guide and the membrane electrode of the battery unit. A bolt hole is disposed on the positive and negative conductive plates and membrane electrodes correspondingly. A fastening bolt is disposed in the bolt hole. A fluid guide hole is provided on the positive fluid guide plate and the positive conductive plate respectively to connect the air. A fluid guide hole is provided on the negative fluid guide plate and the negative conductive plate respectively to connect the fuel room. The structure of the fuel cell of the invention is simple, the inner resistance is little, the output power is large, the disassembly and maintenance is convenient, the miniaturization is easy, multi-type voltage and current can be outputted and the operation is convenient.

Description

燃料电池 技术领域 本发明属于燃料电池, 特别涉及质子交换膜燃料电池。 背景技术 燃料电池是将氢气等燃料和空气中氧气等氧化剂的化学能通过 电化学反应直接转化为电能的高效洁静发电装置, 具有极其广阔的 应用前景。 燃料电池包括至少一个电池单元, 电池单元具有正、 负 极导流板和膜电极, 膜电极位于正、 负极导流板之间, 膜电极由质 子交换膜及附着在其两面上的正、 负极构成, 其工作原理是- 氢气通过负极导流板到达膜电极的负极解离成质子和电子; 质 子通过质子交换膜到达膜电极的正极; 电子通过负极导流板、 负载、 正极导流板到达膜电极的正极; 氧气通过正极导流板到达膜电极的 正极; 上述质子、 电子、 氧气在膜电极的正极复合成水。 电极反应 和电池反应为:  FUEL CELL FIELD OF THE INVENTION The present invention relates to fuel cells, and more particularly to proton exchange membrane fuel cells. Background Art A fuel cell is a highly efficient clean electricity generator that directly converts chemical energy such as hydrogen and an oxidant such as oxygen in the air into electrical energy by an electrochemical reaction, and has an extremely broad application prospect. The fuel cell comprises at least one battery unit, the battery unit has positive and negative baffles and membrane electrodes, the membrane electrode is located between the positive and negative baffles, and the membrane electrode is composed of a proton exchange membrane and positive and negative electrodes attached to both sides thereof. , its working principle is - hydrogen dissociates into protons and electrons through the negative electrode baffle reaching the negative electrode of the membrane electrode; protons reach the positive electrode of the membrane electrode through the proton exchange membrane; electrons reach the membrane through the negative deflector, load, positive baffle The positive electrode of the electrode; oxygen reaches the positive electrode of the membrane electrode through the positive electrode baffle; the proton, electron, and oxygen are combined into water at the positive electrode of the membrane electrode. Electrode reaction and battery reaction are:
负极反应: H2 = 2H+ + 2e Negative reaction: H 2 = 2H + + 2e
正极反应: 2H+ + 2e + 0.5O2 = H2O Positive electrode reaction: 2H + + 2e + 0.5O 2 = H 2 O
电池反应: H2 + 0.5O2 = H2O Battery reaction: H 2 + 0.5O 2 = H 2 O
现有燃料电池通常由电池单元层叠构成, 采用外框架和端压板 将各电池单元压紧。 由于外框架位于电池单元的外围, 端压板位于 燃料电池的两端, 不仅结构复杂, 拆装不便, 更换部件困难, 不利 于电池维护, 而且外框架和端压板占据了燃料电池较大空间, 在同 样电池外形尺寸下, 膜电极的催化活性区域面积相对较小, 燃料电 池的中部区域也不易压紧, 燃料电池内阻大, 输出功率小; 由于端 压板妨碍了空气中的氧气直接扩散到膜电极参与电池正极反应以及 燃料电池的反应热直接散发到空气中, 需要气泵、 风机、 风扇、 水 泵、 冷却水板等多种辅助装置, 导致燃料电池难于小型化; 由于各 电池单元层叠串联在一起, 燃料电池输出电压、 电流单一, 使用不 便。 发明内容 本发明的目的在于克服上述缺陷, 提供一种燃料电池, 它结构 简单, 内阻小, 输出功率大, 可输出多种电压、 电流, 拆装维护方 便, 易于小型化, 使用方便。 Existing fuel cells are usually constructed by laminating battery cells, and the battery cells are pressed by an outer frame and an end plate. Since the outer frame is located at the outer periphery of the battery unit, the end pressure plate is located at both ends of the fuel cell, which is not only complicated in structure, inconvenient to assemble and disassemble, but also difficult to replace parts, which is disadvantageous to battery maintenance, and the outer frame and the end plate occupy a large space of the fuel cell. In the same battery size, the catalytic active area of the membrane electrode is relatively small, the central region of the fuel cell is not easily compressed, the internal resistance of the fuel cell is large, and the output power is small; because the end pressure plate prevents the direct diffusion of oxygen in the air to the membrane. The electrode participates in the positive reaction of the battery and the reaction heat of the fuel cell is directly emitted into the air, and requires various auxiliary devices such as a gas pump, a fan, a fan, a water pump, a cooling water plate, etc., which makes the fuel cell difficult to be miniaturized; The fuel cell output voltage and current are single and inconvenient to use. Summary of the invention The object of the present invention is to overcome the above drawbacks and provide a fuel cell which has a simple structure, small internal resistance, large output power, and can output various voltages and currents, is convenient to disassemble and maintain, is easy to be miniaturized, and is convenient to use.
本发明的目的是这样实现的:  The object of the invention is achieved in this way:
一种燃料电池, 包括至少一个电池单元, 该电池单元具有正、 负极导流板和膜电极, 膜电极位于正、 负极导流板之间, 其特征在 于: 所述正、 负极导流板的非周边区域对应开有螺栓孔, 该螺栓孔 内穿有紧固螺栓。  A fuel cell comprising at least one battery unit having positive and negative baffles and a membrane electrode, the membrane electrode being located between the positive and negative baffles, wherein: the positive and negative baffles A bolt hole is formed in the non-peripheral area, and a fastening bolt is inserted in the bolt hole.
所述正、 负极导流板为绝缘板, 所述正、 负极导流板的非周边 区域是中部区域。  The positive and negative baffles are insulating plates, and the non-peripheral regions of the positive and negative baffles are central regions.
所述正、 负极导流板为绝缘板, 所述正、 负极导流板的非周边 区域是中心区域。  The positive and negative baffles are insulating plates, and the non-peripheral regions of the positive and negative baffles are central regions.
所述电池单元的正极导流板与膜电极之间布置有正极导电片, 负极导流板与膜电极之间布置有负极导电片, 该正、 负极导电片和 膜电极上对应开有螺栓孔, 该螺栓孔内穿有所述紧固螺栓, 该正极 导流板与正极导电片上分别开有导流孔与空气连通, 该负极导流板 与负极导电片上分别开有导流孔与燃料室连通。  A positive electrode conductive sheet is disposed between the positive electrode deflector and the membrane electrode of the battery unit, and a negative electrode conductive sheet is disposed between the negative electrode deflector and the membrane electrode, and the positive and negative conductive sheets and the membrane electrode are correspondingly provided with bolt holes. The fastening hole is inserted into the bolt hole, and the positive electrode baffle and the positive electrode conductive plate respectively have a flow guiding hole and air communication, and the negative electrode baffle and the negative electrode conductive piece respectively have a diversion hole and a fuel chamber Connected.
所述电池单元有一个, 所述燃料室由负极导流板背面的凹槽及 底盖围成, 底盖上开有螺栓孔, 该螺栓孔内穿有所述紧固螺栓。  The battery unit has one of the fuel cells, and the fuel chamber is surrounded by a groove on the back surface of the negative electrode deflector and a bottom cover. The bottom cover is provided with a bolt hole, and the fastening hole is inserted into the bolt hole.
所述电池单元有多个, 各电池单元并排布置, 各电池单元的燃 料室由负极导流板背面的凹槽及底盖围成, 底盖上开有螺栓孔, 该 螺栓孔内穿有所述紧固螺栓, 各电池单元的负极导流板连为一体, 各电池单元的底盖连为一体, 所述燃料室连通, 相邻电池单元的正、 负极导电片连为一体。  There are a plurality of battery cells, and the battery cells are arranged side by side. The fuel chamber of each battery cell is surrounded by a groove and a bottom cover on the back surface of the negative electrode deflector, and the bottom cover is provided with a bolt hole, and the bolt hole is worn inside. The fastening bolts are connected to each other, and the bottom baffles of the battery cells are integrally connected. The bottom cover of each battery unit is integrally connected, and the fuel chambers are connected, and the positive and negative conductive sheets of the adjacent battery cells are integrally connected.
所述电池单元有一对, 其负极导流板背对贴靠, 所述燃料室由 负极导流板背面的凹槽相对扣合构成。  The battery unit has a pair, and the negative electrode baffle is abutted against the anode, and the fuel chamber is formed by the recess of the back surface of the negative baffle.
所述电池单元有多对, 各对电池单元并排布置, 每对电池单元 的负极导流板背对贴靠, 所述燃料室由负极导流板背面的凹槽相对 扣合构成, 各对电池单元的燃料室连通, 各对电池单元的负极导流 板连为一体, 相邻两个电池单元的正、 负极导电片连为一体。  The battery unit has a plurality of pairs, each pair of battery units are arranged side by side, and the negative electrode baffles of each pair of battery cells are oppositely facing each other, and the fuel chamber is formed by the corresponding recesses of the back surface of the negative electrode baffle plate, and each pair of batteries The fuel chambers of the unit are connected, and the negative baffles of the respective battery cells are integrated, and the positive and negative conductive sheets of the adjacent two battery cells are integrated.
所述各电池单元的正极导流板连为一体。  The positive electrode baffles of the battery cells are connected together.
所述各对电池单元的正极导流板连为一体。  The positive baffles of the pair of battery cells are connected together.
本发明有以下积极有益效果:  The present invention has the following positive beneficial effects:
本发明的燃料电池采用中心螺栓紧固方式将正、 负极导流板、 膜电极和正、 负极导电片压紧, 正、 负极导流板起到了端压板的作 用, 紧固螺栓位于正、 负极导流板和膜电极的中心, 燃料电池结构 简单, 拆装方便, 更换部件容易, 易于维护; The fuel cell of the invention adopts a central bolt fastening method to connect the positive and negative deflectors, The membrane electrode and the positive and negative conductive sheets are pressed, and the positive and negative deflectors act as end plates. The fastening bolts are located at the center of the positive and negative deflectors and the membrane electrode. The fuel cell has a simple structure, convenient assembly and disassembly, and replacement of components. Easy and easy to maintain;
紧固螺栓只占据了燃料电池较小空间, 膜电极催化活性面积相 对较大, 燃料电池的中部区域也容易压紧, 在同样电池外形尺寸下, 燃料电池内阻小, 输出功率大;  The fastening bolt only occupies a small space of the fuel cell, the catalytic active area of the membrane electrode is relatively large, and the central region of the fuel cell is also easy to be compacted. Under the same battery outer shape, the internal resistance of the fuel cell is small, and the output power is large;
由于没有端压板, 正极导流板完全暴露在空气中, 其导流孔直 接与空气连通, 空气中的氧气直接扩散到膜电极参与电池正极反应, 燃料电池的反应热直接散发到空气中, 无需气泵、 风机、 风扇、 水 泵、 冷却水板等辅助装置, 因而燃料电池易于小型化;  Since there is no end plate, the positive baffle is completely exposed to the air, and the diversion hole is directly connected with the air. The oxygen in the air directly diffuses to the membrane electrode to participate in the positive reaction of the battery, and the reaction heat of the fuel cell is directly emitted into the air, without An auxiliary device such as a gas pump, a fan, a fan, a water pump, a cooling water plate, etc., so that the fuel cell is easy to be miniaturized;
各电池单元的负极导流板连为一体, 不仅使燃料电池结构简化, 拆装方便, 而且使整体强度加大, 各电池单元的正极导流板连为一 体, 不仅使燃料电池结构更加简化, 拆装更加方便, 而且使整体强 度进一步加大;  The negative baffle of each battery unit is integrated into one body, which not only simplifies the structure of the fuel cell, but also facilitates disassembly and assembly, and increases the overall strength, and the positive baffle of each battery unit is integrated, which not only simplifies the structure of the fuel cell, It is more convenient to disassemble and assemble, and further increase the overall strength;
相邻电池单元的正、 负极导电片可以连为一体, 无需焊接及其 它导电连接件, 结构简化, 拆装方便。 相邻电池单元可以串联或并 联 (串联时, 将相邻电池单元的正、 负极导电片连为一体; 并联时, 将相邻电池单元的正、 正极导电片连为一体, 负、 负极导电片连为 一体),燃料电池的各电池单元可以根据需要方便地进行串联、并联、 混联, 从而实现多种电压、 电流输出, 使用方便。 附图概述 图 1是本发明实施例一的俯视图。  The positive and negative conductive sheets of adjacent battery cells can be integrated into one body, and no welding and other conductive connecting members are needed, and the structure is simplified, and the disassembly and assembly is convenient. Adjacent battery cells can be connected in series or in parallel (in series, the positive and negative conductive sheets of adjacent battery cells are connected together; when connected in parallel, the positive and negative conductive sheets of adjacent battery cells are connected together, negative and negative conductive sheets As a whole, the battery cells of the fuel cell can be conveniently connected in series, parallel, and mixed according to needs, thereby realizing various voltage and current outputs, and being convenient to use. Brief Description of the Drawings Fig. 1 is a plan view showing a first embodiment of the present invention.
图 2是图 1 的 A— A放大剖视图。  Figure 2 is an enlarged cross-sectional view taken along line A - A of Figure 1;
图 3是本发明实施例二的俯视图。  Figure 3 is a plan view of a second embodiment of the present invention.
图 4是图 3的 B— B放大剖视图。  Figure 4 is an enlarged cross-sectional view taken along line B-B of Figure 3;
图 5是本发明实施例三的俯视图。  Figure 5 is a plan view of a third embodiment of the present invention.
图 6是图 5的 C一 C放大剖视图。  Figure 6 is an enlarged cross-sectional view taken along line C-C of Figure 5;
图 7是本发明实施例四的剖视图。  Figure 7 is a cross-sectional view showing a fourth embodiment of the present invention.
图 8是本发明实施例五的剖视图。  Figure 8 is a cross-sectional view showing a fifth embodiment of the present invention.
图 9是本发明实施例六的剖视图。 本发明的实施例 W 实施例一 Figure 9 is a cross-sectional view showing a sixth embodiment of the present invention. Embodiment of the present invention W Example 1
请参照图 1、 图 2, 本发明是一种燃料电池, 包括一个电池单 元 10, 该电池单元 10具有正极导流板 11、 负极导流板 12和膜电极 13, 膜电极 13位于正极导流板 11、 负极导流板 12之间, 正极导流 板 11、 负极导流板 12的中心对应开有螺栓孔, 该螺栓孔内穿有紧固 螺栓 1。  Referring to FIG. 1 and FIG. 2, the present invention is a fuel cell comprising a battery unit 10 having a positive electrode baffle 11, a negative electrode baffle 12 and a membrane electrode 13, and the membrane electrode 13 is located at the positive electrode conductance. Between the plate 11 and the negative electrode baffle 12, the center of the positive electrode baffle 11 and the negative electrode baffle 12 are correspondingly provided with bolt holes, and the fastening bolts 1 are bored in the bolt holes.
电池单元 10的正极导流板 11与膜电极 13之间布置有正极导电 片 14, 负极导流板 12与膜电极 13之间布置有负极导电片 15, 正极 导电片 14、 负极导电片 15和膜电极 13的中心对应开有螺栓孔, 该 螺栓孔内穿有紧固螺栓 1, 正极导流板 11 上开有导流孔 111, 正极 导电片 14上开有导流孔 141, 导流孔 111、 141与空气连通。  A positive electrode conductive sheet 14 is disposed between the positive electrode deflector 11 and the membrane electrode 13 of the battery unit 10, and a negative electrode conductive sheet 15, a positive electrode conductive sheet 14, and a negative electrode conductive sheet 15 are disposed between the negative electrode deflector 12 and the membrane electrode 13. The center of the membrane electrode 13 is correspondingly provided with a bolt hole, the bolt hole is provided with a fastening bolt 1 , the positive electrode baffle 11 is provided with a flow guiding hole 111 , and the positive electrode conductive sheet 14 is provided with a guiding hole 141 , and a guiding hole 111, 141 is in communication with the air.
负极导流板 12上开有导流孔 121, 负极导电片 15上开有导流 孔 151, 导流孔 121、 151与燃料室 3连通。  The anode baffle 12 has a flow guiding hole 121, and the negative electrode conductive sheet 15 has a flow guiding hole 151, and the flow guiding holes 121 and 151 communicate with the fuel chamber 3.
电池单元 10的燃料室 3 由负极导流板 12背面的凹槽 122及底 盖 6围成, 底盖 6的中心开有螺栓孔。  The fuel chamber 3 of the battery unit 10 is surrounded by a recess 122 and a bottom cover 6 on the back surface of the negative deflector 12, and a bolt hole is formed in the center of the bottom cover 6.
紧固螺栓 1由底盖 6中心的螺栓孔向上依次穿过负极导流板 12、 负极导电片 15、 膜电极 13、 正极导电片 14、 正极导流板 11 中心的 螺栓孔后, 由螺母 2锁紧。  The fastening bolt 1 is sequentially passed through the bolt hole at the center of the bottom cover 6 through the negative electrode baffle 12, the negative electrode conductive plate 15, the membrane electrode 13, the positive electrode conductive plate 14, and the bolt hole at the center of the positive electrode deflector 11, and then the nut 2 is Locked.
燃料室 3的一侧有燃料进口 4, 另一侧有燃料出口 5。 燃料出口 5可起排空作用以及连接其它电池单元燃料进口的作用。  The fuel chamber 3 has a fuel inlet 4 on one side and a fuel outlet 5 on the other side. The fuel outlet 5 serves to evacuate and connect other battery unit fuel inlets.
正极导流板 11、 负极导流板 12 可由塑料板构成, 正极导电片 14、 负极导电片 15可由镍片、 不锈钢片、 镀金铜片等构成, 底盖 6 可由塑料板构成。  The positive electrode baffle plate 11 and the negative electrode baffle plate 12 may be composed of a plastic plate. The positive electrode conductive piece 14 and the negative electrode conductive piece 15 may be composed of a nickel piece, a stainless steel piece, a gold plated copper piece or the like, and the bottom cover 6 may be composed of a plastic plate.
本实施例的工作原理是:  The working principle of this embodiment is:
氢气燃料由燃料进口 4进入燃料室 3 中, 氢气依次通过负极导 流板 12上的导流孔 121、 负极导电片 15上的导流孔 151 到达膜电 极 13 的负极解离成质子和电子; 质子通过质子交换膜到达膜电极 13 的正极; 电子通过负极导电片 15、 负载、 正极导电片 14到达膜 电极 13的正极; 氧气通过正极导流板 11上的导流孔 111、 正极导电 片 14上的导流孔 141到达膜电极的正极; 上述质子、 电子、 氧气在 膜电极 13的正极复合成水。  The hydrogen fuel enters the fuel chamber 3 from the fuel inlet 4, and the hydrogen gas sequentially passes through the flow guiding hole 121 on the negative electrode deflector 12, the flow guiding hole 151 on the negative electrode conductive sheet 15, and reaches the negative electrode of the membrane electrode 13 to dissociate into protons and electrons; The protons reach the positive electrode of the membrane electrode 13 through the proton exchange membrane; the electrons pass through the negative electrode conductive sheet 15, the load, and the positive electrode conductive sheet 14 reach the positive electrode of the membrane electrode 13; the oxygen passes through the flow guiding hole 111 on the positive electrode deflector 11, and the positive electrode conductive sheet 14 The upper flow guiding hole 141 reaches the positive electrode of the membrane electrode; the protons, electrons, and oxygen are combined in the positive electrode of the membrane electrode 13 to form water.
本实施例中, 正极导流板 11、 负极导流板 12不仅起到了压紧膜 电极 13、 正极导电片 14、 负极导电片 15的作用, 而且起到了导热、 散热的作用, 其导流孔 111、 121还起到了导气、 导水的作用。 正极导电片 14、负极导电片 15起到了导电作用,其导流孔 141、 151还起到导气、 导水的作用。 In the embodiment, the positive electrode baffle 11 and the negative electrode baffle 12 not only serve to press the membrane electrode 13, the positive electrode conductive sheet 14, and the negative electrode conductive sheet 15, but also function as heat conduction and heat dissipation, and the flow guiding hole thereof 111, 121 also played a role in guiding air and guiding water. The positive electrode conductive sheet 14 and the negative electrode conductive sheet 15 function as a conductive force, and the flow guiding holes 141 and 151 also function to conduct air and conduct water.
本实施例只使用了一根紧固螺栓 1 贯穿燃料电池的中心, 结构 简单, 拆装方便, 更换部件容易, 易于维护; 紧固螺栓 1 只占据了 燃料电池较小空间, 膜电极 13的催化活性面积相对较大, 燃料电池 的中部区域也容易压紧, 因而在同样电池外形尺寸下, 燃料电池内 阻小, 输出功率大; 由于没有端压板, 正极导流板 11完全暴露在空 气中, 其导流孔 111 直接与空气连通, 空气中的氧气直接扩散到膜 电极 13参与电池正极反应, 燃料电池的反应热直接散发到空气中, 无需气泵、 风机、 风扇、 水泵、 冷却水板等辅助装置, 因而燃料电 池易于小型化, 使用方便。 实施例二  In this embodiment, only one fastening bolt 1 is used to penetrate the center of the fuel cell, the structure is simple, the disassembly and assembly is convenient, the replacement parts are easy, and the maintenance is easy; the fastening bolt 1 occupies only a small space of the fuel cell, and the membrane electrode 13 is catalyzed. The active area is relatively large, and the central portion of the fuel cell is also easily compressed. Therefore, under the same battery size, the internal resistance of the fuel cell is small and the output power is large; since there is no end plate, the positive baffle 11 is completely exposed to the air. The guiding hole 111 is directly connected with the air, and the oxygen in the air directly diffuses to the membrane electrode 13 to participate in the positive electrode reaction of the battery, and the reaction heat of the fuel cell is directly emitted into the air, without the aid of an air pump, a fan, a fan, a water pump, a cooling water plate, etc. The device is thus easy to miniaturize and easy to use. Embodiment 2
请参照图 3、 图 4, 本发明是一种燃料电池, 包括两个电池单 元 10 , 这两个电池单元 10并排布置, 每个电池单元 10的结构与实 施例一相同, 每个电池单元 10的燃料室 3 由负极导流板 12背面的 凹槽 122及底盖 6围成, 这两个电池单元 10的负极导流板 12连为 一体, 这两个电池单元 10 的底盖 6连为一体, 这两个电池单元 10 的燃料室 3 连通, 该连通的燃料室一侧有燃料进口 4, 另一侧有燃 料出口 5。  Referring to FIG. 3 and FIG. 4, the present invention is a fuel cell comprising two battery cells 10, and the two battery cells 10 are arranged side by side. The structure of each battery cell 10 is the same as that of the first embodiment, and each battery cell 10 is The fuel chamber 3 is surrounded by a recess 122 and a bottom cover 6 on the back surface of the negative electrode deflector 12. The negative baffles 12 of the two battery cells 10 are integrally connected, and the bottom cover 6 of the two battery cells 10 are connected. Integrated, the fuel cells 3 of the two battery cells 10 are in communication with a fuel inlet 4 on one side and a fuel outlet 5 on the other side.
负极导流板 12连为一体, 底盖 6连为一体, 不仅使燃料电池结 构简化, 拆装方便, 而且使整体强度加大。  The negative baffle 12 is integrally connected, and the bottom cover 6 is integrated, which not only simplifies the structure of the fuel cell, but also facilitates disassembly and assembly, and increases the overall strength.
本实施例中, 第一个电池单元 10的正极导电片 14与第二个电 池单元 10的负极导电片 15连为一体,从而将这两个电池单元 10串 联在一起, 无需焊接及其它导电连接件, 结构简化, 拆装方便。  In this embodiment, the positive electrode conductive sheets 14 of the first battery unit 10 are integrated with the negative electrode conductive sheets 15 of the second battery unit 10, thereby connecting the two battery units 10 in series without soldering and other conductive connections. Parts, simplified structure, easy to disassemble.
本实施例的工作原理与实施例一相同, 不冗述。  The working principle of this embodiment is the same as that of the first embodiment, and is not redundant.
实施时, 也可以将第一个电池单元 10的正极导电片 14与第二 个电池单元 10的正极导电片 14连为一体,将第一个电池单元 10的 负极导电片 15与第二个电池单元 10的负极导电片 15连为一体,从 而将这两个电池单元 10并联在一起。  In practice, the positive electrode conductive sheet 14 of the first battery unit 10 and the positive electrode conductive sheet 14 of the second battery unit 10 may be integrally connected, and the negative electrode conductive sheet 15 of the first battery unit 10 and the second battery may be connected. The negative electrode conductive sheets 15 of the unit 10 are integrally connected, thereby connecting the two battery cells 10 in parallel.
实施时, 还可以按上述方式将多个电池单元并排布置排列在一 起, 燃料电池的各电池单元可以根据需要方便地进行串联、 并联、 混联, 从而实现多种电压、 电流输出, 使用方便。 实施例三 When implemented, a plurality of battery cells can be arranged side by side in the above manner, and the battery cells of the fuel cell can be conveniently connected in series, parallel, and mixed according to requirements, thereby realizing various voltage and current outputs, and being convenient to use. Embodiment 3
请参照图 5、 图 6, 本发明是一种燃料电池, 包括两个电池单 元 10, 其结构与实施例二基本相同, 所不同的是这两个电池单元 10 的正极导流板 1 1连为一体, 不仅使燃料电池结构更加简化, 拆装更 加方便, 而且使燃料电池整体强度进一步加大。  Referring to FIG. 5 and FIG. 6, the present invention is a fuel cell comprising two battery cells 10, the structure of which is basically the same as that of the second embodiment, except that the positive electrode baffles of the two battery cells 10 are connected. As a whole, not only the structure of the fuel cell is simplified, the disassembly and assembly is more convenient, and the overall strength of the fuel cell is further increased.
本实施例的工作原理与实施例一相同, 不重述。 实施例四  The working principle of this embodiment is the same as that of the first embodiment, and will not be repeated. Embodiment 4
请参照图 7, 本发明是一种燃料电池, 包括一对电池单元 50, 它由两个电池单元 20、 30组成,电池单元 30层叠在电池单元 20上。  Referring to Figure 7, the present invention is a fuel cell comprising a pair of battery cells 50 comprised of two battery cells 20, 30 stacked on a battery cell 20.
电池单元 20具有正极导流板 21、 负极导流板 22和膜电极 23, 膜电极 23位于正极导流板 21、负极导流板 22之间,正极导流板 21、 负极导流板 22的中心对应开有螺栓孔,该螺栓孔内穿有紧固螺栓 1。  The battery unit 20 has a positive electrode baffle 21, a negative electrode baffle 22 and a membrane electrode 23, and the membrane electrode 23 is located between the positive electrode baffle 21 and the negative electrode baffle 22, and the positive electrode baffle 21 and the negative electrode baffle 22 A bolt hole is formed in the center, and a fastening bolt 1 is inserted in the bolt hole.
正极导流板 21与膜电极 23之间布置有正极导电片 24, 负极导 流板 22与膜电极 23之间布置有负极导电片 25。  A positive electrode conductive sheet 24 is disposed between the positive electrode deflector 21 and the membrane electrode 23, and a negative electrode conductive sheet 25 is disposed between the negative electrode deflector 22 and the membrane electrode 23.
正极导电片 24、 负极导电片 25和膜电极 23的中心对应开有螺 栓孔, 该螺栓孔内穿有所述紧固螺栓 1。  The center of the positive electrode conductive sheet 24, the negative electrode conductive sheet 25, and the membrane electrode 23 is correspondingly provided with a bolt hole through which the fastening bolt 1 is bored.
正极导流板 21上开有导流孔 21 1,正极导电片 24上开有导流孔 241, 导流孔 21 1、 241与空气连通。  The positive electrode baffle 21 is provided with a flow guiding hole 21, and the positive electrode conductive piece 24 is provided with a flow guiding hole 241, and the guiding holes 21 1 and 241 are in communication with the air.
负极导流板 22上开有导流孔 221, 负极导电片 25 上开有导流 孔 251, 导流孔 221、 251与燃料室 3连通。  The anode baffle 22 has a flow guiding hole 221, and the negative electrode conductive sheet 25 has a flow guiding hole 251, and the guiding holes 221 and 251 communicate with the fuel chamber 3.
电池单元 30具有正极导流板 3 1、 负极导流板 32和膜电极 33, 膜电极 33位于正极导流板 3 1、负极导流板 32之间,正极导流板 3 1、 负极导流板 32的中心对应开有螺栓孔,该螺栓孔内穿有紧固螺栓 1。  The battery unit 30 has a positive electrode baffle 31, a negative electrode baffle 32 and a membrane electrode 33. The membrane electrode 33 is located between the positive electrode baffle 31 and the negative baffle 32, and the positive baffle 3 1 and the negative electrode conductance. A bolt hole is formed in the center of the plate 32, and a fastening bolt 1 is bored in the bolt hole.
正极导流板 31与膜电极 33之间布置有正极导电片 34, 负极导 流板 32与膜电极 33之间布置有负极导电片 35。  A positive electrode conductive sheet 34 is disposed between the positive electrode baffle 31 and the membrane electrode 33, and a negative electrode conductive sheet 35 is disposed between the negative electrode baffle 32 and the membrane electrode 33.
正极导电片 34、 负极导电片 35和膜电极 33的中心对应开有螺 栓孔, 该螺栓孔内穿有所述紧固螺栓 1。  The center of the positive electrode conductive sheet 34, the negative electrode conductive sheet 35, and the membrane electrode 33 is correspondingly provided with a bolt hole through which the fastening bolt 1 is bored.
正极导流板 3 1上开有导流孔 3 11,正极导电片 34上开有导流孔 341, 导流孔 31 1、 341与空气连通。  The positive electrode baffle plate 3 has a flow guiding hole 3, and the positive electrode conductive piece 34 has a flow guiding hole 341, and the guiding holes 31 1 and 341 communicate with the air.
负极导流板 32上开有导流孔 321, 负极导电片 35上开有导流 孔 35 1, 导流孔 321、 351与燃料室 3连通。  The anode baffle 32 has a flow guiding hole. The negative electrode conductive sheet 35 has a flow guiding hole 35. The flow guiding holes 321 and 351 communicate with the fuel chamber 3.
紧固螺栓 1 向上依次穿过电池单元 20 的正极导流板 21、 正极 导电片 24、 膜电极 23、 负极导电片 25、 负极导流板 22、 电池单元 30的负极导流板 32、 负极导电片 35、 膜电极 33、 正极导电片 34、 正极导流板 35的中心通孔后, 由螺母 2锁紧。 The fastening bolt 1 passes through the positive electrode deflector 21 of the battery unit 20, the positive electrode conductive sheet 24, the membrane electrode 23, the negative electrode conductive sheet 25, the negative electrode deflector 22, and the battery unit in this order. After the center through-holes of the negative electrode baffle 32, the negative electrode conductive sheet 35, the membrane electrode 33, the positive electrode conductive sheet 34, and the positive electrode deflector 35 of 30, the nut 2 is locked.
负极导流板 22 的背面有凹槽 222, 负极导流板 32 的背面有凹 槽 322, 负极导流板 22、 32背对贴靠, 凹槽 222、 322相对扣合构 成燃料室 3, 燃料室 3的一侧有燃料进口 4, 另一侧有燃料出口 5。  The back surface of the negative electrode baffle 22 has a recess 222, the back surface of the negative electrode baffle 32 has a recess 322, the negative baffles 22, 32 are abutted against each other, and the recesses 222, 322 are relatively fastened to form a fuel chamber 3, fuel The chamber 3 has a fuel inlet 4 on one side and a fuel outlet 5 on the other side.
正极导流板 21、 3 1 以及负极导流板 22、 32可由塑料板构成, 正极导电片 24、 34 以及负极导电片 25、 35可由镍片、 不锈钢片、 镀金铜片等构成。  The positive electrode baffles 21, 3 1 and the negative electrode deflectors 22, 32 may be composed of a plastic plate, and the positive electrode conductive sheets 24, 34 and the negative electrode conductive sheets 25, 35 may be composed of a nickel piece, a stainless steel piece, a gold plated copper piece or the like.
本实施例的工作原理与实施例一相同, 不复述。  The working principle of this embodiment is the same as that of the first embodiment, and will not be described again.
本实施例只使用了一根紧固螺栓 1 贯穿燃料电池的中心, 结构 简单, 拆装方便, 更换部件容易, 易于维护; 紧固螺栓 1 只占据了 燃料电池较小空间, 膜电极 23、 33的催化活性面积相对较大, 燃料 电池的中部区域也容易压紧, 因而在同样电池外形尺寸下, 燃料电 池内阻小, 输出功率大; 由于没有端压板, 正极导流板 21、 3 1完全 暴露在空气中, 其导流孔 211、 3 11直接与空气连通, 空气中的氧气 直接扩散到膜电极 23、 33参与电池正极反应, 燃料电池的反应热直 接散发到空气中, 无需气泵、 风机、 风扇、 水泵、 冷却水板等辅助 装置, 因而燃料电池易于小型化, 使用方便。 实施例五  In this embodiment, only one fastening bolt 1 is used to penetrate the center of the fuel cell, the structure is simple, the disassembly and assembly is convenient, the replacement parts are easy, and the maintenance is easy; the fastening bolt 1 occupies only a small space of the fuel cell, and the membrane electrode 23, 33 The catalytic active area is relatively large, and the central region of the fuel cell is also easily compacted. Therefore, under the same battery external dimensions, the internal resistance of the fuel cell is small and the output power is large; since there is no end plate, the positive electrode baffles 21, 31 are completely Exposed to the air, the diversion holes 211, 3 11 are directly connected to the air, and the oxygen in the air directly diffuses to the membrane electrodes 23, 33 to participate in the positive electrode reaction of the battery, and the reaction heat of the fuel cell is directly emitted into the air, without the need of an air pump or a fan. The auxiliary device such as a fan, a water pump, a cooling water plate, and the like, so that the fuel cell is easy to be miniaturized and convenient to use. Embodiment 5
请参照图 8, 本发明是一种燃料电池, 包括两对电池单元 50, 每对电池单元 50由两个电池单元 20、 30组成, 电池单元 30层叠在 电池单元 20上。 每对电池单元 50的结构与实施例四相同。  Referring to Figure 8, the present invention is a fuel cell comprising two pairs of battery cells 50, each pair of battery cells 50 being comprised of two battery cells 20, 30 stacked on a battery cell 20. The structure of each pair of battery cells 50 is the same as that of the fourth embodiment.
这两对电池单元 50的下层两个电池单元 20的负极导流板 22连 为一体, 这两对电池单元 50的上层两个电池单元 30的负极导流板 32连为一体, 不仅使燃料电池结构简化, 拆装方便, 而且使燃料电 池整体强度加大。  The negative baffles 22 of the lower two battery cells 20 of the two pairs of battery cells 50 are integrally connected, and the negative baffles 32 of the upper two battery cells 30 of the two pairs of battery cells 50 are integrated, not only for the fuel cell The structure is simplified, the disassembly and assembly is convenient, and the overall strength of the fuel cell is increased.
第一对电池单元 50的负极导电片 25与第二对电池单元 50的正 极导电片 24连为一体, 从而将这两对电池单元 50 的下层两个电池 单元 20串联在一起, 无需焊接及其它导电连接件, 结构简化, 拆装 方便。  The negative electrode conductive sheets 25 of the first pair of battery cells 50 are integrated with the positive electrode conductive sheets 24 of the second pair of battery cells 50, thereby connecting the lower two battery cells 20 of the two pairs of battery cells 50 in series without soldering and the like. Conductive connector, simplified structure, easy to disassemble.
第一对电池单元 50的正极导电片 34与第二对电池单元 50的负 极导电片 35连为一体, 从而将这两对电池单元 50的上层两个电池 单元 30串联在一起, 无需焊接及其它导电连接件, 结构简化, 拆装 方便。 The positive conductive sheets 34 of the first pair of battery cells 50 are integrated with the negative conductive sheets 35 of the second pair of battery cells 50, thereby connecting the upper two battery cells 30 of the two pairs of battery cells 50 in series, without soldering and the like. Conductive connector, simplified structure, disassembly Convenience.
本实施例的工作原理与实施例一相同, 不赘述。  The working principle of this embodiment is the same as that of the first embodiment, and details are not described herein.
实施时, 可以将这两对电池单元 50的下层两个电池单元 20的 正极导电片 24连为一体, 将这两对电池单元 50的下层两个电池单 元 20的负极导电片 25连为一体, 从而将这两对电池单元 50的下层 两个电池单元 20并联在一起。 将这两对电池单元 50的上层两个电 池单元 30的正极导电片 34连为一体,将这两对电池单元 50的上层 两个电池单元 30的负极导电片 35连为一体, 从而将这两对电池单 元 50的上层两个电池单元 30并联在一起。  In practice, the positive electrode conductive sheets 24 of the lower two battery cells 20 of the two pairs of battery cells 50 may be integrally connected, and the negative electrode conductive sheets 25 of the lower two battery cells 20 of the two pairs of battery cells 50 may be integrated into one body. The lower two battery cells 20 of the two pairs of battery cells 50 are thereby connected in parallel. The positive electrode conductive sheets 34 of the upper two battery cells 30 of the two pairs of battery cells 50 are integrally connected, and the negative electrode conductive sheets 35 of the upper two battery cells 30 of the two pairs of battery cells 50 are integrally connected, thereby The upper two battery cells 30 of the battery unit 50 are connected in parallel.
实施时, 还可以按上述方式将多对电池单元并排布置排列在一 起, 燃料电池各对电池单元可以根据需要方便地进行串联、 并联、 混联, 从而实现多种电压、 电流输出, 使用方便。 实施例六  In practice, a plurality of pairs of battery cells may be arranged side by side in the above manner, and each pair of battery cells of the fuel cell may be conveniently connected in series, parallel, and mixed according to requirements, thereby realizing various voltage and current outputs, and being convenient to use. Embodiment 6
请参照图 9, 本发明是一种燃料电池, 包括两对电池单元 50, 其结构与实施例五基本相同,所不同的是这两对电池单元 50的下层 两个电池单元 20的正极导流板 21连为一体, 这两对电池单元 50的 两个上层电池单元 30的正极导流板 3 1连为一体, 不仅使燃料电池 结构更加简化, 拆装更加方便, 而且使燃料电池整体强度进一步加 大。  Referring to FIG. 9, the present invention is a fuel cell comprising two pairs of battery cells 50, the structure of which is substantially the same as that of the fifth embodiment, except that the positive electrode conductance of the lower two battery cells 20 of the two pairs of battery cells 50 is different. The plates 21 are integrated, and the positive baffles 31 of the two upper battery cells 30 of the two pairs of battery cells 50 are integrated into one body, which not only simplifies the structure of the fuel cell, but also facilitates disassembly and assembly, and further strengthens the overall strength of the fuel cell. Increase.
本实施例的工作原理与实施例一相同, 不再述。  The working principle of this embodiment is the same as that of the first embodiment, and will not be described again.

Claims

权 利 要 求 书 Claim
1 . 一种燃料电池,包括至少一个电池单元, 该电池单元具有正、 负极导流板和膜电极, 膜电极位于正、 负极导流板之间, 其特征在What is claimed is: 1. A fuel cell comprising at least one battery cell having positive and negative baffles and a membrane electrode, the membrane electrode being located between the positive and negative baffles, characterized by
5 于: 所述正、 负极导流板的非周边区域对应幵有螺栓孔, 该螺栓孔 内穿有紧固螺栓。 5: The non-peripheral region of the positive and negative baffles corresponds to a bolt hole, and the bolt hole is provided with a fastening bolt.
2. 如权利要求 1所述的燃料电池, 其特征在于: 所述正、 负极 导流板为绝缘板, 所述正、 负极导流板的非周边区域是中部区域。  The fuel cell according to claim 1, wherein the positive and negative baffles are insulating plates, and the non-peripheral regions of the positive and negative baffles are central regions.
3. 如权利要求 1所述的燃料电池, 其特征在于: 所述正、 负极 L0 导流板为绝缘板, 所述正、 负极导流板的非周边区域是中心区域。  The fuel cell according to claim 1, wherein the positive and negative L0 deflectors are insulating plates, and the non-peripheral regions of the positive and negative deflectors are central regions.
4. 如权利要求 1所述的燃料电池, 其特征在于: 所述电池单元 的正极导流板与膜电极之间布置有正极导电片, 负极导流板与膜电 极之间布置有负极导电片, 该正、 负极导电片和膜电极上对应开有 螺栓孔, 该螺栓孔内穿有所述紧固螺栓, 该正极导流板与正极导电 4. The fuel cell according to claim 1, wherein: a positive electrode conductive sheet is disposed between the positive electrode deflector and the membrane electrode of the battery unit, and a negative electrode conductive sheet is disposed between the negative electrode deflector and the membrane electrode. a bolt hole is formed in the positive and negative conductive sheets and the membrane electrode, and the fastening bolt is inserted in the bolt hole, and the positive electrode deflector and the positive electrode are electrically conductive
15 片上分别开有导流孔与空气连通, 该负极导流板与负极导电片上分 别开有导流孔与燃料室连通。 15 channels are respectively provided with a flow guiding hole and air communication, and the negative electrode deflecting plate and the negative electrode conductive piece are respectively connected with a guiding hole to communicate with the fuel chamber.
5. 如权利要求 4所述的燃料电池, 其特征在于: 所述电池单元 有一个, 所述燃料室由负极导流板背面的凹槽及底盖围成, 底盖上 开有螺栓孔, 该螺栓孔内穿有所述紧固螺栓。  5. The fuel cell according to claim 4, wherein: the battery unit has one, the fuel chamber is surrounded by a groove and a bottom cover on the back surface of the negative electrode deflector, and the bottom cover is provided with a bolt hole. The fastening bolt is worn in the bolt hole.
20 6. 如权利要求 4所述的燃料电池, 其特征在于: 所述电池单元 有多个, 各电池单元并排布置, 各电池单元的燃料室由负极导流板 背面的凹槽及底盖围成, 底盖上开有螺栓孔, 该螺栓孔内穿有所述 紧固螺栓, 各电池单元的负极导流板连为一体, 各电池单元的底盖 连为一体, 所述燃料室连通, 相邻电池单元的正、 负极导电片连为 5 一体。  The fuel cell according to claim 4, wherein: the battery unit has a plurality of battery cells arranged side by side, and the fuel chamber of each battery unit is surrounded by a groove and a bottom cover of the back surface of the negative electrode deflector. The bottom cover is provided with a bolt hole, the fastening bolt is inserted into the bolt hole, and the negative baffle of each battery unit is integrally connected, and the bottom cover of each battery unit is integrally connected, and the fuel chamber is connected. The positive and negative conductive sheets of adjacent battery cells are connected in one piece.
7. 如权利要求 4所述的燃料电池, 其特征在于: 所述电池单元 有一对, 其负极导流板背对贴靠, 所述燃料室由负极导流板背面的 凹槽相对扣合构成。  7. The fuel cell according to claim 4, wherein: the battery unit has a pair, and the negative electrode baffle is abutted against the anode, and the fuel chamber is relatively fastened by a groove on the back surface of the negative baffle. .
8. 如权利要求 4所述的燃料电池, 其特征在于: 所述电池单元 0 有多对, 各对电池单元并排布置, 每对电池单元的负极导流板背对 贴靠, 所述燃料室由负极导流板背面的凹槽相对扣合构成, 各对电 池单元的燃料室连通, 各对电池单元的负极导流板连为一体, 相邻 两个电池单元的正、 负极导电片连为一体。  8. The fuel cell according to claim 4, wherein: the battery unit 0 has a plurality of pairs, each pair of battery units are arranged side by side, and the anode deflector of each pair of battery units is facing away from each other, the fuel chamber The recesses on the back surface of the negative deflector are relatively fastened, and the fuel chambers of the pair of battery cells are connected, and the negative baffles of the opposite battery cells are integrated, and the positive and negative conductive sheets of the adjacent two battery cells are connected. One.
9. 如权利要求 6所述的燃料电池, 其特征在于: 所述各电池单 元的正极导流板连为一体。 9. The fuel cell according to claim 6, wherein: each of the battery sheets The anode baffles of the element are connected together.
10. 如权利要求 8 所述的燃料电池, 其特征在于: 所述各对电 池单元的正极导流板连为一体。  10. The fuel cell according to claim 8, wherein: the positive electrode baffles of the respective pair of battery cells are integrally connected.
PCT/CN2007/000719 2007-03-06 2007-03-06 Fuel cell WO2008106824A1 (en)

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