WO2008087812A1 - Phosphorus-containing flame retardant and curable flame -retarded resin compositions containing the same - Google Patents

Phosphorus-containing flame retardant and curable flame -retarded resin compositions containing the same Download PDF

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Publication number
WO2008087812A1
WO2008087812A1 PCT/JP2007/074020 JP2007074020W WO2008087812A1 WO 2008087812 A1 WO2008087812 A1 WO 2008087812A1 JP 2007074020 W JP2007074020 W JP 2007074020W WO 2008087812 A1 WO2008087812 A1 WO 2008087812A1
Authority
WO
WIPO (PCT)
Prior art keywords
flame
flame retardant
phosphorus
curable
resin compositions
Prior art date
Application number
PCT/JP2007/074020
Other languages
French (fr)
Japanese (ja)
Inventor
Hui Li
Kentarou Takahashi
Hirotoshi Kamata
Original Assignee
Showa Highpolymer Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Highpolymer Co., Ltd. filed Critical Showa Highpolymer Co., Ltd.
Priority to JP2008553983A priority Critical patent/JPWO2008087812A1/en
Publication of WO2008087812A1 publication Critical patent/WO2008087812A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00Fireproofing materials
    • C09K21/06Organic materials
    • C09K21/12Organic materials containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/34Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348Hydroxycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4854Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67Unsaturated compounds having active hydrogen
    • C08G18/671Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • C08L75/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/22Secondary treatment of printed circuits
    • H05K3/28Applying non-metallic protective coatings
    • H05K3/285Permanent coating compositions
    • H05K3/287Photosensitive compositions

Abstract

The invention aims at providing a phosphorus-containing flame retardant free from halogen compounds; and curable flame-retarded resin compositions containing the flame retardant, which are curable through radical polymerization and excellent in curability and which can give cured articles excellent in flame retardance, curing properties, and flexibility. The invention relates to a phosphorus-containing flame retardant obtained by reacting (meth)acryloyl of a polyfunctional (meth)acrylate having a specific structure with a phosphorus compound having a P-H bond; and curable flame-retarded resin compositions each comprising the flame retardant, an alkali-soluble resin, a (meth)acrylate compound, an epoxy resin, a photopolymerization initiator and, if necessary, a filler.
PCT/JP2007/074020 2007-01-18 2007-12-13 Phosphorus-containing flame retardant and curable flame -retarded resin compositions containing the same WO2008087812A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2008553983A JPWO2008087812A1 (en) 2007-01-18 2007-12-13 Phosphorus-containing flame retardant and curable flame retardant resin composition containing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-009072 2007-01-18
JP2007009072 2007-01-18

Publications (1)

Publication Number Publication Date
WO2008087812A1 true WO2008087812A1 (en) 2008-07-24

Family

ID=39635817

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/074020 WO2008087812A1 (en) 2007-01-18 2007-12-13 Phosphorus-containing flame retardant and curable flame -retarded resin compositions containing the same

Country Status (4)

Country Link
JP (1) JPWO2008087812A1 (en)
CN (1) CN101573428A (en)
TW (1) TW200846353A (en)
WO (1) WO2008087812A1 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008299293A (en) * 2007-06-04 2008-12-11 Taiyo Ink Mfg Ltd Photosensitive resin composition and flexible wiring board obtained using the same
JP2011141451A (en) * 2010-01-07 2011-07-21 Mitsubishi Paper Mills Ltd Photocrosslinkable resin composition
JP2012220580A (en) * 2011-04-05 2012-11-12 Kaneka Corp Novel photosensitive resin composition and use of the same
JP5243966B2 (en) * 2006-12-01 2013-07-24 京セラケミカル株式会社 Photosensitive thermosetting resin composition and flexible printed wiring board
JP2013171135A (en) * 2012-02-20 2013-09-02 Tamura Seisakusho Co Ltd Ultraviolet curable transparent resin composition
JP5289309B2 (en) * 2007-05-11 2013-09-11 三井化学株式会社 Resin composition, dry film, and processed product obtained therefrom
CN104774343A (en) * 2015-03-10 2015-07-15 三峡大学 Phenyl phosphate flame retardant containing DOPO, and preparation method and application thereof
WO2019239291A1 (en) * 2018-06-11 2019-12-19 3M Innovative Properties Company Flame-retardant pressure-sensitive adhesive, flame-retardant pressure-sensitive adhesive sheet and method for preparing same

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106566155A (en) * 2016-11-13 2017-04-19 惠州市大亚湾科翔科技电路板有限公司 Insulation fire retardant for circuit board
CN109810134A (en) * 2018-12-29 2019-05-28 张家港康得新光电材料有限公司 High refractive index flame retardant type UV resin, preparation method and optical film
CN109957283B (en) * 2019-02-27 2021-09-10 江苏艾森半导体材料股份有限公司 High-flame-retardance solder resist ink
CN112662260A (en) * 2020-12-29 2021-04-16 山西中涂交通科技股份有限公司 Flame-retardant anti-skid road surface coating for tunnel
CN115260477A (en) * 2022-08-26 2022-11-01 深圳市瑞世兴科技有限公司 Intrinsic flame-retardant PET resin and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001213889A (en) * 2000-01-28 2001-08-07 Nippon Shokubai Co Ltd Reactive phosphorus compound
JP2003529644A (en) * 2000-04-03 2003-10-07 ユ セ ベ ソシエテ アノニム Phosphorus-containing substances, their production and use

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001312054A (en) * 2000-05-01 2001-11-09 Dainippon Ink & Chem Inc Energy beam-curable resin composition for resist

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001213889A (en) * 2000-01-28 2001-08-07 Nippon Shokubai Co Ltd Reactive phosphorus compound
JP2003529644A (en) * 2000-04-03 2003-10-07 ユ セ ベ ソシエテ アノニム Phosphorus-containing substances, their production and use

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5243966B2 (en) * 2006-12-01 2013-07-24 京セラケミカル株式会社 Photosensitive thermosetting resin composition and flexible printed wiring board
JP5289309B2 (en) * 2007-05-11 2013-09-11 三井化学株式会社 Resin composition, dry film, and processed product obtained therefrom
JP2008299293A (en) * 2007-06-04 2008-12-11 Taiyo Ink Mfg Ltd Photosensitive resin composition and flexible wiring board obtained using the same
JP2011141451A (en) * 2010-01-07 2011-07-21 Mitsubishi Paper Mills Ltd Photocrosslinkable resin composition
JP2012220580A (en) * 2011-04-05 2012-11-12 Kaneka Corp Novel photosensitive resin composition and use of the same
JP2013171135A (en) * 2012-02-20 2013-09-02 Tamura Seisakusho Co Ltd Ultraviolet curable transparent resin composition
CN104774343A (en) * 2015-03-10 2015-07-15 三峡大学 Phenyl phosphate flame retardant containing DOPO, and preparation method and application thereof
CN104774343B (en) * 2015-03-10 2017-08-01 三峡大学 A kind of phenyl phosphate fire retardant containing DOPO, preparation method and applications
WO2019239291A1 (en) * 2018-06-11 2019-12-19 3M Innovative Properties Company Flame-retardant pressure-sensitive adhesive, flame-retardant pressure-sensitive adhesive sheet and method for preparing same
US11866622B2 (en) 2018-06-11 2024-01-09 3M Innovative Properties Company Flame retardant pressure-sensitive adhesive, flame retardant pressure-sensitive adhesive sheet and method for preparing same

Also Published As

Publication number Publication date
CN101573428A (en) 2009-11-04
JPWO2008087812A1 (en) 2010-05-06
TW200846353A (en) 2008-12-01

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