WO2008083973A1 - Composition and manufacturing process of a decorative surface covering - Google Patents
Composition and manufacturing process of a decorative surface covering Download PDFInfo
- Publication number
- WO2008083973A1 WO2008083973A1 PCT/EP2008/000171 EP2008000171W WO2008083973A1 WO 2008083973 A1 WO2008083973 A1 WO 2008083973A1 EP 2008000171 W EP2008000171 W EP 2008000171W WO 2008083973 A1 WO2008083973 A1 WO 2008083973A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- styrene
- surface covering
- decorative surface
- polymer component
- covering according
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/201—Pre-melted polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C08L23/0876—Neutralised polymers, i.e. ionomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
- Y10T428/31587—Hydrocarbon polymer [polyethylene, polybutadiene, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
Definitions
- the present invention relates to a composition for decorative surface coverings and to a manufacturing process for said compositions.
- Synthetic decorative surface coverings such as floor coverings are generally based on PVC and have been known for decades .
- the key features of this kind of materials are essentially abrasion resistance (resistance to scratches) , dimensional stability, absence of creeping, low smell, stain resistance and tear resistance.
- Vulcanisable standard rubber floor covering compositions generally comprise less than 30 wt% rubber internally mixed with about 60 wt% of fillers and less than about 10wt% of curing agents and processing aids. Rubber floor coverings are known to be less tear and stain resistant than PVC floorings. Additionally, conventional PVC equipment cannot manage these compositions.
- Document WO 97/010298 discloses a flooring material based on crosslinked polyolefin's and unsaturated silane compounds. The floor covering composition comprises various additives and is free of organic fillers.
- Document WO 2006/005752 discloses a large variety of possible compositions combining a series of elastomers, thermoplastics and a high styrene resin cured with conventional curing systems like TBBS, ZBEC, CBS, sulphur, stearic acid and zinc oxide.
- the composition disclosed in the examples cannot be extruded on conventional PVC extruders, it sticks on the steel belts and can only be worked in a steel belt press in combination with silicon release paper. Furthermore, the obtained granules have a strong tendency to agglomerate in the transport containers.
- An additional drawback is the absence of flame retardant filler and the high production cost.
- US 2002/0168500 Al discloses an electrically conductive floor covering using a combination of a high styrene resin (HSR) and SBR rubber together with high amounts of carbon black. This composition cannot be worked on conventional extruders, making rubber equipment necessary.
- HSR high styrene resin
- EP 1 361 249 A2 discloses a substantially halogen- free thermoplastic elastomer composition for decorative surface coverings comprising a dynamically vulcanized blend of epoxydized rubbers such as natural rubber, EPDM, NBR and SBR, ionomers and diluent polymers.
- epoxydized rubbers such as natural rubber, EPDM, NBR and SBR, ionomers and diluent polymers.
- SBS, SBR or HSR with specific styrene contents are not disclosed and rubber equipment is used for the mixing of the different ingredients .
- the present invention aims to provide an improved composition for a substantially halogen-free decorative surface covering which overcomes the drawbacks of the prior art and which is convertible on conventional PVC extrusion equipment.
- the present invention discloses a decorative surface covering obtainable by a vulcanisable composition, said composition comprising:
- a first polymer component consisting of styrene butadiene styrene block copolymer
- a second polymer component selected from the group consisting of nitrile butadiene rubber and a random or partially random copolymer of butadiene and styrene having 40 wt% or less of bound styrene;
- a third polymer component consisting of a high styrene content styrene butadiene copolymer containing at least 55 wt% of bound styrene;
- additives selected from the group consisting of processing aids, stabilizers, pigments and compatibilizers .
- the present invention may comprise one or a combination of any of the following characteristics:
- the decorative surface covering further comprises a fourth polymer component consisting of an ionomer.
- the ionomer represents between 3 to 12 wt% of the total weight of the polymers.
- the ionomer is a partially or totally neutralised ethylene/methacrylic acid incorporating a third comonomer .
- the first polymer component is a styrene butadiene styrene block copolymer containing 35 to 45 wt% of bound styrene.
- the first polymer component is a styrene butadiene styrene block copolymer containing 40 wt% of bound styrene .
- the second polymer component is a random or a partially random copolymer of butadiene and styrene, containing 25 wt% of bound styrene.
- the third polymer component is a high styrene content styrene butadiene copolymer containing between 63 and 83 wt% of bound styrene.
- the third polymer component is a high styrene content styrene butadiene copolymer containing 63 wt% of bound styrene.
- the decorative surface covering composition comprises the following wt% relative to the total amount of the ingredients :
- the filler is selected from the group consisting of aluminium trihydrate, silica, clay, dolomite and calcium carbonate .
- the decorative surface covering composition comprises between 25 and 45 wt% of filler.
- the decorative surface covering composition is substantially halogen-free.
- the vulcanisation system is selected from the group consisting of sulphur, stearic acids, zinc oxide, sulfenamides and thiocarbamate or combinations thereof the surface covering additionally comprises a polyurethane-based top coating.
- the polyurethane-based top coating is a polyurethane acrylate .
- the present invention further discloses a process for manufacturing the decorative surface covering of the invention comprising the following steps:
- the step of dry mix comprising the various colour batches comprises the adding of additionally virgin styrene butadiene styrene granules .
- an additional polyurethane- based top coating is applied as a finish on the decorative surface covering.
- Decorative coverings include any design covering that provide an enhanced appearance to a substrate. These can include wall and floor coverings as well as ceilings.
- substantially halogen-free has to be understood as devoid of any halogen-containing polymer. This does not exclude the presence of impurities or additives in a concentration of less than 1%.
- polymer component has to be understood as a distinguishable polymer family which is part of the global composition such as the filler, vulcanisation system and additives.
- the composition of the decorative surface covering of the present invention is in its final state a vulcanised composition wherein all the vulcanisable components are at least partly vulcanised and wherein a vulcanisation system has reacted and does not any longer exist as such. Therefore the present invention discloses a vulcanisable composition which is the precursor of the vulcanised finished decorative surface covering.
- a vulcanisable composition which is the precursor of the vulcanised finished decorative surface covering.
- One of the key advantages of the invention is the processing of the mixture at the extruding step which is part of a conventional PVC process. Indeed, the usual rubber formulations need to be performed through internal mixers due to the high viscosity below the vulcanisation temperature. A conventional rubber could never be processed using an extruder at temperatures around 120 0 C, i.e.
- thermoplastic material thermoplastic rubbers and optionally ionomers
- the role of the thermoplastic material (thermoplastic rubbers and optionally ionomers) in the composition of the invention is to lower the viscosity of the mix at temperatures below the vulcanisation temperature, and thus to allow the processing through a conventional extruder.
- Another crucial step of the process of the invention is the grinding or granulating and the blending of granulates. Actually, these steps are only possible if the material after extrusion and cooling does not remain tacky. This is the reason why thermoplastic elastomers were added to the formulation. Thermoplastic elastomers and optionally ionomers are needed to allow the processing through conventional PVC equipments and are selected from the range of those which may enhance the final characteristics of the covering; for instance ionomers can optionally improve the abrasion resistance while high styrene content styrene butadiene copolymer will improve the stiffness of the covering, i.e. a key feature for an easy installation of the floor covering.
- the percentage of each component will be a fine balance between the processing, the requested features of the covering and the overall price of the whole formulation.
- 1 st polymer component block copolymer of SBS SBS or styrene butadiene styrene is considered as a thermoplastic elastomer that can be converted in extrusion equipments for thermoplastics .
- 2 nd polymer component SBR or NBR
- SBR SBR
- NBR NBR
- SBR a random or at least partially random copolymer of butadiene and styrene containing generally 40 wt% or less of styrene is meant.
- Nitrile butadiene rubber NBR
- HSR a high styrene content copolymer of butadiene and styrene is meant. These molecules are close to SBR but contain generally at least 55 wt% of bounded styrene .
- the ionomer examples according to the present invention are at least partially neutralized acid copolymers or terpolymers . - Surlyn ® 6320 - Dupont, ethylene/methacrylic acid incorporating a third comonomer
- the first and the second dry mix are fed into a double screw extruder Werner & Pfleiderer ZSK and mixed with various pigments at a material temperature below 120 0 C and subsequently granulated and cooled by air to room temperature .
- the mixed colour batches are then fed into a double belt press and heated up to 17O 0 C to be vulcanised.
- Example 2 This example was performed in the same way as Example 1 except that the polymer proportions were modified, in particular the SBS content was heavily decreased and the ionomer content heavily increased:
- Example 2 This example was performed in the same way as Example 1 except that the polymer proportions were modified, in particular the SBS content was heavily increased and the SBR content heavily decreased:
- Example 2 This example was performed in the same way as Example 1 except that the polymer proportions were modified, in particular a low proportion of HSR were tested:
- Example 2 This example was performed in the same way as Example 1 except that the polymer proportions were modified, in particular a high proportion of HSR and a low proportion of SBR were tested:
- Example 2 This example was performed in the same way as Example 1 except that the polymer proportions were modified, in particular a very high proportion of ionomer and a low proportion of SBR were tested:
- Example 2 This example was performed in the same way as Example 1 except that the polymer proportions were modified, in particular a very low proportion of an alternative ionomer and a lower proportion of SBR were tested:
- Example 2 This example was performed in the same way as Example 1 except that the polymer proportions were modified, in particular a lower proportion of SBS and a lower proportion of HSR combined with a higher proportion of SBR were tested:
- Example 2 This example was performed in the same way as Example 1 except that the polymer proportions were modified, in particular a high proportion of ionomer and a lower proportion of SBR were tested:
- Example 2 This example was performed in the same way as Example 1 except that the polymer proportions and nature were modified, in particular a high proportion of ionomer and a low proportion of NBR were tested, the NBR replacing the former SBR:
- Example 2 This example was performed in the same way as Example 1 except that the polymer proportions were modified, in particular a very high proportion of NBR and a lower proportion of SBS together with a lower proportion of ionomer were tested:
- Example 12 is identical to Example 1 except that the quantity of filler was increased and the nature of the filler was modified:
- the proportion of polymers is reduced proportionally to the increase of filler.
- Example 13 is identical to Example 1 except that the global filler amount was reduced:
- Example 14 is identical to Example 1 except that Kralex
- Example 2 This example was performed in the same way than Example 1 except that the polymer proportions were modified, in particular a lower proportion of SBS and a lower proportion of HSR combined with a higher proportion of SBR were tested:
- Ionomer (Iotek ® 7510 - Exxonmobil) Remark Not as good processing ability, very good scratch resistance .
- the apparatus with the scratching tool is placed over the sample so that a wagon can be pulled across the surface.
- the applied force starts with 0,5N and increase 0,5N each time until a scratch appears.
- the results are expressed as load (N) resulting in a scratch that can be seen corresponding to the first value in Table 1 and load (N) resulting in a scratch that can be felt corresponding to the second value in Table 1.
- the stiffness of a material is measured with a Clash & Berg stiffness tester.
- the sample is fixed by specimen grips, put in a water container and subjected to rotation. One side of the sample is under the subject of torsional moment. The angle is recorded after the test.
- Friction is measured with a modified Tortus friction tester. Instead of using the measuring foot, a sled is fastened to the machine by a line. The force required to drag the sled over the surface of the sample with the motor of the machine is recorded as the friction value.
- the test is used for determining the stain resistance against water-, alcohol- and oil-soluble colorants of a flooring sample. Put two drops of each staining agent of the surface and cover each staining agent with a watch glass . Remove the watch glasses after the test and clean the surface with the cleaning agents . The remaining stains are visually evaluated. [0055] Castor chair
- the test is based on EN 425 for determining the change of appearance and stability of a flooring material.
- the sample is fixed on the moving board by using adhesive, but by not fixing a certain area (10 * 20cm) , dimensional changes can appear when the material expands. About 25.000 rotations are performed on each sample . Any change of appearance or dimensional changes are recorded.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2675056A CA2675056C (en) | 2007-01-12 | 2008-01-11 | Composition and manufacturing process of a decorative surface covering |
AT08706999T ATE469193T1 (en) | 2007-01-12 | 2008-01-11 | COMPOSITION AND PRODUCTION PROCESS FOR DECORATIVE SURFACE COVERING |
PL08706999T PL2099875T3 (en) | 2007-01-12 | 2008-01-11 | Composition and manufacturing process of a decorative surface covering |
DE200860001368 DE602008001368D1 (en) | 2007-01-12 | 2008-01-11 | COMPOSITION AND PRODUCTION METHOD FOR DECORATIVE SURFACE COVER |
US12/514,242 US8192846B2 (en) | 2007-01-12 | 2008-01-11 | Composition and manufacturing process of a decorative surface covering |
EP20080706999 EP2099875B1 (en) | 2007-01-12 | 2008-01-11 | Composition and manufacturing process of a decorative surface covering |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07000622.6 | 2007-01-12 | ||
EP20070000622 EP1953202A1 (en) | 2007-01-12 | 2007-01-12 | Composition and manufacturing process of a decorative surface covering |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008083973A1 true WO2008083973A1 (en) | 2008-07-17 |
Family
ID=38068642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2008/000171 WO2008083973A1 (en) | 2007-01-12 | 2008-01-11 | Composition and manufacturing process of a decorative surface covering |
Country Status (11)
Country | Link |
---|---|
US (1) | US8192846B2 (en) |
EP (2) | EP1953202A1 (en) |
AT (1) | ATE469193T1 (en) |
CA (1) | CA2675056C (en) |
DE (1) | DE602008001368D1 (en) |
ES (1) | ES2345641T3 (en) |
PL (1) | PL2099875T3 (en) |
PT (1) | PT2099875E (en) |
RS (1) | RS51440B (en) |
RU (1) | RU2456319C2 (en) |
WO (1) | WO2008083973A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016184845A1 (en) | 2015-05-18 | 2016-11-24 | Tarkett Gdl | Halogen-free decorative homogeneous surface coverings |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009062962A1 (en) | 2007-11-14 | 2009-05-22 | Tarkett Sas | Weld seam for ground coating |
US8288467B2 (en) | 2008-12-08 | 2012-10-16 | Nike, Inc. | Zinc ionomer rubber activator |
DE102013103663B4 (en) * | 2013-04-11 | 2014-10-23 | Nora Systems Gmbh | A method for producing a decorative layer having elastomer flooring and elastomer flooring with a decorative layer |
CN105038085A (en) * | 2015-07-21 | 2015-11-11 | 福建恒力晟鞋业科技有限公司 | Anti-yellowing thermoplastic elastomer for shoe upper |
KR101917736B1 (en) * | 2017-03-31 | 2018-11-12 | 화인케미칼 주식회사 | Rubber composition for shoe sole and molded article comprising the same |
KR20200026554A (en) * | 2018-09-03 | 2020-03-11 | 화인케미칼 주식회사 | Rubber composition for shoe sole and molded article comprising the same |
CN113929988A (en) * | 2021-10-25 | 2022-01-14 | 张万鹏 | Floor cloth for railway passenger train and motor train unit and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2168362A (en) * | 1984-12-17 | 1986-06-18 | Bcl Ltd | Compositions for packaging films |
EP1616923A1 (en) * | 2004-07-13 | 2006-01-18 | Tarkett SAS | Rubber-polyolefin surface covering |
WO2006107763A2 (en) * | 2005-04-06 | 2006-10-12 | Henkel Corporation | Hot melt pressure sensitive adhesives based on blends of styrene/butadiene copolymers |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU373279A1 (en) * | 1970-01-08 | 1973-03-12 | FORMABLE POLYMER COMPOSITION | |
SE503631C2 (en) | 1995-09-15 | 1996-07-22 | Tarkett Ab | Halogen-free flooring material |
DE10112246C1 (en) | 2001-03-14 | 2002-08-08 | Freudenberg Carl Kg | Flooring |
US6921791B2 (en) | 2002-05-07 | 2005-07-26 | Awi Licensing Company | Thermoplastic elastomer |
-
2007
- 2007-01-12 EP EP20070000622 patent/EP1953202A1/en not_active Withdrawn
-
2008
- 2008-01-11 PT PT08706999T patent/PT2099875E/en unknown
- 2008-01-11 WO PCT/EP2008/000171 patent/WO2008083973A1/en active Application Filing
- 2008-01-11 ES ES08706999T patent/ES2345641T3/en active Active
- 2008-01-11 CA CA2675056A patent/CA2675056C/en not_active Expired - Fee Related
- 2008-01-11 US US12/514,242 patent/US8192846B2/en not_active Expired - Fee Related
- 2008-01-11 AT AT08706999T patent/ATE469193T1/en not_active IP Right Cessation
- 2008-01-11 EP EP20080706999 patent/EP2099875B1/en active Active
- 2008-01-11 RS RSP20100368 patent/RS51440B/en unknown
- 2008-01-11 RU RU2009123908/05A patent/RU2456319C2/en not_active IP Right Cessation
- 2008-01-11 DE DE200860001368 patent/DE602008001368D1/en active Active
- 2008-01-11 PL PL08706999T patent/PL2099875T3/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2168362A (en) * | 1984-12-17 | 1986-06-18 | Bcl Ltd | Compositions for packaging films |
EP1616923A1 (en) * | 2004-07-13 | 2006-01-18 | Tarkett SAS | Rubber-polyolefin surface covering |
WO2006005752A1 (en) * | 2004-07-13 | 2006-01-19 | Tarkett Sas | Rubber-polyolefin surface covering |
WO2006107763A2 (en) * | 2005-04-06 | 2006-10-12 | Henkel Corporation | Hot melt pressure sensitive adhesives based on blends of styrene/butadiene copolymers |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016184845A1 (en) | 2015-05-18 | 2016-11-24 | Tarkett Gdl | Halogen-free decorative homogeneous surface coverings |
EP3741820A1 (en) | 2015-05-18 | 2020-11-25 | Tarkett GDL | Process for the preparation of a halogen-free decorative homogeneous surface covering |
US11254835B2 (en) | 2015-05-18 | 2022-02-22 | Tarkett Gdl | Halogen-free decorative homogeneous surface coverings |
Also Published As
Publication number | Publication date |
---|---|
RU2009123908A (en) | 2011-02-20 |
EP2099875A1 (en) | 2009-09-16 |
PT2099875E (en) | 2010-09-03 |
ES2345641T3 (en) | 2010-09-28 |
RU2456319C2 (en) | 2012-07-20 |
DE602008001368D1 (en) | 2010-07-08 |
US20100003527A1 (en) | 2010-01-07 |
EP2099875B1 (en) | 2010-05-26 |
PL2099875T3 (en) | 2010-11-30 |
CA2675056A1 (en) | 2008-07-17 |
ATE469193T1 (en) | 2010-06-15 |
US8192846B2 (en) | 2012-06-05 |
RS51440B (en) | 2011-04-30 |
EP1953202A1 (en) | 2008-08-06 |
CA2675056C (en) | 2015-05-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2099875B1 (en) | Composition and manufacturing process of a decorative surface covering | |
RU2381248C2 (en) | Coating for surface of rubber-polyolefine composition | |
US6180703B1 (en) | Rubber composition | |
CA2247923A1 (en) | Higher modulus compositions incorporating particulate rubber | |
CN101080452B (en) | Silica-filled elastomeric compounds | |
WO2009017868A1 (en) | Compositions of thermoplastic polyurethane (tpu), polybutadiene and polydiene-based tpu | |
EP3299413A1 (en) | Rubber composition for a tire tread | |
US6921791B2 (en) | Thermoplastic elastomer | |
KR102092723B1 (en) | rubber composition for shoes outsole having abrasion resistance and anti slip function | |
JP5326402B2 (en) | Rubber composition for tire | |
CN106349633B (en) | High-fitting TPE (thermoplastic elastomer) foam material as well as preparation method and application thereof | |
WO2003031150A1 (en) | Process for the preparation of a dynamically vulcanized thermoplastic elastomer | |
KR980009367A (en) | Composition for slip prevention shoe outsole and method for manufacturing shoe outsole using same | |
Go et al. | Rheology and properties of EPDM/BR blends with or without a homogenizing agent or a coupling agent | |
JPH1053722A (en) | Production of surface-treated carbon black for rubber reinforcement | |
KR100208651B1 (en) | Sheet composition for manufacturing automobile floor mat | |
US8367759B2 (en) | High post consumer content mineral filler based on micronized recycled asphalt paving and thermoplastic compositions and polymeric emulsions derived from same | |
JP6635367B2 (en) | Black brightener used in black polymer composition | |
KR100810052B1 (en) | Thermoplastic elastomer mat | |
JPH08199009A (en) | Thermoplastic elastomer composition | |
JPS6058449A (en) | Chlorinated polyethylene composition | |
JPH08302116A (en) | Crosslinkable chlorosulfonated polyethylene composition | |
CN113710731A (en) | Method for improving UV weatherability of thermoplastic vulcanizate | |
CN113717475A (en) | Rubber floor raw material composition, rubber floor and preparation method and application thereof | |
JPS6023434A (en) | Dust sealing material |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 08706999 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008706999 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12514242 Country of ref document: US |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2675056 Country of ref document: CA |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2009123908 Country of ref document: RU Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: P-2010/0368 Country of ref document: RS |