WO2008078580A1 - Adamantyl ethanol and process for production thereof - Google Patents

Adamantyl ethanol and process for production thereof Download PDF

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Publication number
WO2008078580A1
WO2008078580A1 PCT/JP2007/074125 JP2007074125W WO2008078580A1 WO 2008078580 A1 WO2008078580 A1 WO 2008078580A1 JP 2007074125 W JP2007074125 W JP 2007074125W WO 2008078580 A1 WO2008078580 A1 WO 2008078580A1
Authority
WO
WIPO (PCT)
Prior art keywords
adamantyl
general formula
represented
ethanol
producing
Prior art date
Application number
PCT/JP2007/074125
Other languages
French (fr)
Japanese (ja)
Inventor
Katsuki Ito
Hidetoshi Ono
Original Assignee
Idemitsu Kosan Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co., Ltd. filed Critical Idemitsu Kosan Co., Ltd.
Priority to JP2008551033A priority Critical patent/JPWO2008078580A1/en
Publication of WO2008078580A1 publication Critical patent/WO2008078580A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/22—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system
    • C07C35/37—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with a hydroxy group on a condensed system having three rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/31—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/70—Ring systems containing bridged rings containing three rings containing only six-membered rings
    • C07C2603/74—Adamantanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Disclosed are: an adamantyl ethanol which is useful as a raw material for a medicine or a highly functional industrial material or the like; and a process for producing the adamantyl ethanol. Specifically disclosed are: an adamantyl ethanol represented by the general formula (I) or (II); a process for producing an adamantyl ethanol represented by the general formula (I), comprising the steps of reacting an adamantanone represented by the general formula (III) with a compound represented by the general formula (IV) to synthesize an adamantyl acetate represented by the general formula (V) and reducing the adamantyl acetate, thereby producing the adamantyl ethanol; and a process for producing an adamantyl ethanol represented by the general formula (II), comprising the steps of reacting an adamantanone represented by the general formula (III) with a compound represented by the general formula (VI) to synthesize an adamantyl acetate represented by the general formula (VII) and reducing the adamantyl acetate, thereby producing the adamantyl ethanol. In the formulae, Y represents H or the like; n represents an integer of 1 to 14; R1 to R3 independently represent H or the like; and R4 to R6 independently represent C2H5 or the like.
PCT/JP2007/074125 2006-12-26 2007-12-14 Adamantyl ethanol and process for production thereof WO2008078580A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2008551033A JPWO2008078580A1 (en) 2006-12-26 2007-12-14 Adamantyl ethanol and process for producing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006350046 2006-12-26
JP2006-350046 2006-12-26

Publications (1)

Publication Number Publication Date
WO2008078580A1 true WO2008078580A1 (en) 2008-07-03

Family

ID=39562373

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/074125 WO2008078580A1 (en) 2006-12-26 2007-12-14 Adamantyl ethanol and process for production thereof

Country Status (2)

Country Link
JP (1) JPWO2008078580A1 (en)
WO (1) WO2008078580A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009292784A (en) * 2008-06-06 2009-12-17 Idemitsu Kosan Co Ltd Adamantyl alkane polyol, adamantyl alkane (meth)acrylate, their production method, resin composition comprising the same di(meth)acrylate and optical electronic part material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002020334A (en) * 2000-07-04 2002-01-23 Idemitsu Petrochem Co Ltd Method for producing tertiary alcohol having adamantane skeleton
JP2003107705A (en) * 2001-09-28 2003-04-09 Fuji Photo Film Co Ltd Negative resist composition for electron beam or x-ray

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002020334A (en) * 2000-07-04 2002-01-23 Idemitsu Petrochem Co Ltd Method for producing tertiary alcohol having adamantane skeleton
JP2003107705A (en) * 2001-09-28 2003-04-09 Fuji Photo Film Co Ltd Negative resist composition for electron beam or x-ray

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009292784A (en) * 2008-06-06 2009-12-17 Idemitsu Kosan Co Ltd Adamantyl alkane polyol, adamantyl alkane (meth)acrylate, their production method, resin composition comprising the same di(meth)acrylate and optical electronic part material

Also Published As

Publication number Publication date
JPWO2008078580A1 (en) 2010-04-22

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