WO2008074912A1 - Method and apparatus for filtering process gas - Google Patents
Method and apparatus for filtering process gas Download PDFInfo
- Publication number
- WO2008074912A1 WO2008074912A1 PCT/FI2007/000295 FI2007000295W WO2008074912A1 WO 2008074912 A1 WO2008074912 A1 WO 2008074912A1 FI 2007000295 W FI2007000295 W FI 2007000295W WO 2008074912 A1 WO2008074912 A1 WO 2008074912A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- filtering
- gas
- chamber
- solids
- discharge
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/02—Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
- B01D46/04—Cleaning filters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/02—Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/42—Auxiliary equipment or operation thereof
- B01D46/48—Removing dust other than cleaning filters, e.g. by using collecting trays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/66—Regeneration of the filtering material or filter elements inside the filter
- B01D46/68—Regeneration of the filtering material or filter elements inside the filter by means acting on the cake side involving movement with regard to the filter elements
- B01D46/682—Regeneration of the filtering material or filter elements inside the filter by means acting on the cake side involving movement with regard to the filter elements by nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/66—Regeneration of the filtering material or filter elements inside the filter
- B01D46/79—Regeneration of the filtering material or filter elements inside the filter by liquid process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/06—Spray cleaning
Definitions
- the present invention relates to a method and an apparatus for filtering process gas created in the ferroalloy smelting process, i.e. carbon monoxide gas, in order to essentially reduce the quantity of solids contained in the gas.
- process gas created in the ferroalloy smelting process i.e. carbon monoxide gas
- a venturi scrubber For cleaning exhaust gases created in metal smelting processes of solids, for instance for cleaning gases created in a ferroalloy smelting process, there is generally used a venturi scrubber.
- the solids bearing gas to be cleaned is conducted through the top part of the scrubber to a venturi scrubber, and a water jet is directed to the downwards proceeding gas flow. Owing to the water jet, solids contained in the gas are washed in the water, and the cleaned gas is conducted away from the venturi scrubber through a discharge aperture provided in the top part.
- two or more venturi scrubbers can be installed in series, so that the gas to be cleaned is conducted through all scrubbers.
- this method results in a purity level of only 50-200 mg/Nm 3 which is not sufficient, in case the cleaned gas should be utilized without any problems in the various different process steps in ferroalloy production, or elsewhere in demanding targets.
- the object of the present invention is to eliminate drawbacks of the prior art and to achieve an improved method and apparatus for cleaning solids from process gas, i.e. carbon monoxide gas created in a ferroalloy process, so that the process gas can be advantageously utilized for instance for heating in process steps preceding the smelting process and/or following the smelting process.
- process gas i.e. carbon monoxide gas created in a ferroalloy process
- the method and apparatus according to the invention for cleaning process gas i.e. carbon monoxide gas created in the ferroalloy smelting process
- process gas i.e. carbon monoxide gas created in the ferroalloy smelting process
- gas scrubber known as such
- the cleaned process gas i.e. carbon monoxide gas
- gas filtering unit where the filtering is performed as dry separation.
- a gas blower in which case the gas flowing rate between the scrubber and the filtering unit can be increased.
- the gas filtering unit is formed of a filtering chamber with a cross-sectional surface that is preferably essentially round and essentially cylindrical in shape.
- a conical bottom part can be advantageously provided in the filtering chamber of the gas filtering unit.
- the gas filtering unit also is made compact.
- a conduit for feeding the gas to be processed to the filtering chamber at the first end of the cylindrical element or near the first end thereof, there is installed a conduit for feeding the gas to be processed to the filtering chamber, and at the other end of the cylindrical element or near the other end of the cylindrical element, there is installed a conduit for discharging gas from the filtering chamber.
- the filtering chamber is advantageously installed in an essentially vertical position, in which case in the lower part of the filtering chamber, or in a bottom part connected to the lower part thereof, there also is formed a discharge aperture for the solids separated from the gas.
- the cross-sectional surface of a filtering chamber according to the invention can also be essentially rectangular or for example oval-shaped.
- inside the filtering chamber there are advantageously installed several filtering elements. It is also possible to install only one filtering element in the filtering chamber, in case the quantity of the processed gas is essentially small, but with respect to installing and maintaining elements, it is more advantageous to use several filtering elements in the chamber.
- the filtering elements are installed in the filtering chamber so that the filtering elements essentially cover the whole cross-sectional surface in the filtering chamber, or advantageously at least that part of the cross-sectional surface through which the gas to be processed in the filtering chamber is conducted from the filtering chamber inlet aperture to the outlet aperture.
- the filtering element is preferably made of a porous material, plastic or other such material, for example ceramic material, through which the gas to be cleaned can flow. Thus the solid material contained in the gas can be separated therefrom, because the passage of solids through the filtering element is prevented.
- the filtering element can also be made of metal.
- the filtering chamber in a filtering unit according to the invention is provided with a conduit through which an inert gas used for cleaning the filtering elements, such as a nitrogen, is conducted, and with a conduit through which a liquid medium, such as water, used for removing the solids, separated from the filtering elements, from the filtering chamber, is conducted to the filtering chamber.
- an inert gas used for cleaning the filtering elements such as a nitrogen
- a liquid medium such as water
- the conduit for the gas used for cleaning the filtering elements is provided with a control unit, by which it is adjusted for instance the duration or strength of one blast of gas flowing through the conduit, as well as the frequency of the blast period.
- the liquid medium, such as a water, used for discharging the solids stuck on the filtering elements from the filtering chamber is by means of the nozzles advantageously directed so that when using several nozzles, at least part of them are preferably pointed so that the liquid medium flowing through the nozzles is directed towards the solids detached from the filtering elements, from the filtering chamber walls, and part of the nozzles are pointed towards removing solids from the free space of the filtering chamber.
- the solids are removed by means of said medium either continuously or preferably in repeated periods.
- the slurry formed of the liquid medium and the solids separated from the gas are discharged from the filtering chamber through a slurry discharge aperture formed in the lower part of the chamber or in a bottom part connected to the filtering chamber.
- the solids discharge aperture in the filtering chamber is connected to a discharge conduit, preferably a discharge pipe, which is provided, in the solids flowing direction, essentially near to the first end of the discharge conduit and thus to the end connected to the filtering chamber, by two blocking elements, one of them being installed in the immediate vicinity of the discharge aperture, and the other blocking element being installed at a distance from the first blocking element.
- the space left between the blocking elements in the discharge conduit constitutes the solids discharge chamber.
- the discharge chamber can also be a separate part with respect to the discharge conduit, provided with blocking elements, in which case the discharge conduit is connected to the discharge chamber.
- the discharge chamber is on one hand connected to the solids discharge aperture of the filtering chamber, and on the other hand to the discharge conduit, so that both the discharge aperture of the filtering chamber and the junction of the discharge conduit are provided with blocking elements.
- the blocking elements are made to function reciprocally, so that at least one of the blocking elements is always closed, when carbon monoxide gas to be cleaned flows through the filtering chamber.
- the closed blocking element By means of the closed blocking element, the carbon monoxide gas is prevented from flowing from the discharge chamber to the discharge conduit or to the part provided in the discharge conduit in succession to the discharge chamber, and therethrough to the surrounding space.
- the discharge conduit is advantageously designed so that in the discharge conduit, there can be created a liquid seal, such as a water seal.
- the discharge conduit can also be connected to an element in which there can be created a liquid seal, such as a water seal. By means of liquid seal it is preferably prevented the access of carbon monoxide in the gaseous state to the free surrounding space.
- the feeding of the liquid medium, as well as the operation of the blocking elements constituting the discharge chamber, are in the method according to the invention advantageously adjusted by the same control unit that also conducts the feeding of the inert gas into the filtering chamber.
- the feeding of inert gas and liquid medium as well as the operation of the discharge chamber blocking elements can also be adjusted through a separate control unit.
- the gas obtained from a metal smelting process and containing solids-bearing exhaust gas i.e. carbon monoxide gas
- a venturi scrubber known as such, where a water jet is directed to the downwards proceeding gas flow.
- part of the solids contained in the carbon monoxide gas are removed along the water flow to the lower part of the scrubber, whereas the gas is made to flow upwards, towards the gas discharge aperture.
- the carbon monoxide gas is conducted either directly to the filtering unit or first to a gas blower, in which the carbon monoxide gas pressure can be increased by blasting before entering the filtering unit.
- a blower is significant at least when the pressure of the gas emitted from the scrubber is insufficient with respect to the pressure loss taking place in the filtering unit.
- the filtering elements For cleaning the filtering elements, they are subjected to nitrogen gas blasting, the duration, pressure and periodic frequency is adjusted by a control unit.
- nozzles installed in the filtering unit water is fed in the filtering unit for conducting the solid material detached from the filtering elements to the lower part of the filtering unit.
- the first blocking element for discharging the slurry, formed of water and the solids removed from the filtering elements, from the filtering chamber to the solids discharge chamber.
- the second blocking element provided in the flowing direction of the discharge aperture used for removing slurry is opened, and the slurry is allowed to flow to the part of the discharge conduit that is located after the discharge chamber.
- the discharge conduit is advantageously designed so that the slurry flows through a water seal created in the discharge conduit and therethrough to further processing.
- the carbon monoxide gas possibly carried along with the slurry can be removed before the slurry proceeds to the surrounding free space after the discharge conduit.
- the process gas filtered according the method and apparatus of the invention is carbon monoxide gas, that already in small contents is very dangerous to life, it is important, that during filtering of carbon monoxide gas the access of the gas is prevented to the surrounding free space.
- the solid content in the carbon monoxide gas after filtering is less than 5 mg/Nm 3 , preferably less than 1 mg/Nm 3 .
- Fig. 1 illustrates a filtering unit according to the invention in a partly cross- sectional side-view illustration
- Fig. 2 illustrates a flowsheet connected to the filtering unit according to the invention.
- conduits for the input 2 and outlet 3 of the carbon monoxide gas to be treated in the filtering unit there are connected conduits for the input 2 and outlet 3 of the carbon monoxide gas to be treated in the filtering unit.
- conduits for feeding inert gas 4 for feeding water 5 and for removing 6 the solids separated from the gas.
- the carbon monoxide gas flowing to the filtering chamber 1 is conducted through the inlet aperture of the conduit 2 to a filtering element 7 that is made of finely ground polyethylene by heat treatment, and through which the carbon monoxide gas has access to flow. After flowing through the filtering element 7, the carbon monoxide gas is conducted through the outlet aperture of the conduit 3 to be utilized further.
- the solids that were contained in the carbon monoxide gas remain on the surface of the filtering element 7, to which there is directed nitrogen gas periodically in continuous operation through gas nozzles 8 connected to the conduit 4.
- the nitrogen gas blast is controlled by a control unit 9 connected to the conduit 4.
- the solids removed by the nitrogen gas are lowered down towards the bottom part 10 of the filtering chamber 1 , and in order to facilitate the removal of solids, water is conducted to the filtering chamber 1 through a conduit 5 and directed, by nozzles 11 connected to the conduit 5, at least partly onto the filtering chamber walls.
- the slurry formed of solids and water flows towards the bottom of the bottom part 10, which is provided with a blocking element 13.
- the blocking element 13 is used for adjusting the flowing of the slurry to a discharge chamber 12 provided underneath the bottom part 10.
- the carbon monoxide gas possibly carried along with the slurry is prevented from flowing out of the filtering unit 1 to the surroundings, so that the discharge chamber 12 is provided with a blocking element 14 also at the other end with respect to the slurry flowing direction.
- the operation of the blocking elements 13 and 14 is adjusted by means of the control unit 9, so that only one of the blocking elements 13 or 14 is in turn in the open position, while the other is in the closed position.
- the slurry discharged from the discharge chamber 12 is conducted to a discharge conduit 6 provided with a water seal 15 to ensure that the carbon monoxide has no access to flow to the surroundings, in case the mutual operation of the blocking elements 13 and 14 should be disturbed, for example.
- the control unit 9 is also used for controlling the use of the water nozzles 11.
- the carbon monoxide gas obtained from the smelting furnace 21 is first conducted to a gas scrubber 22, where part of the solids contained in the gas is removed when necessary.
- the gas is conducted to the filtering chamber 1 of the filtering unit 24 through a blower 23.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Separation Of Particles Using Liquids (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
- Filtering Materials (AREA)
- Treating Waste Gases (AREA)
- Industrial Gases (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07858319.2A EP2099548B1 (en) | 2006-12-19 | 2007-12-18 | Method and apparatus for filtering process gas |
CN2007800472797A CN101578128B (en) | 2006-12-19 | 2007-12-18 | Method and apparatus for filtering process gas |
AU2007336147A AU2007336147B2 (en) | 2006-12-19 | 2007-12-18 | Method and apparatus for filtering process gas |
US12/519,540 US20100071555A1 (en) | 2006-12-19 | 2007-12-18 | Method and apparatus for filtering process gas |
CA2672162A CA2672162C (en) | 2006-12-19 | 2007-12-18 | Method and apparatus for filtering process gas |
EA200900696A EA016239B1 (en) | 2006-12-19 | 2007-12-18 | Method and apparatus for filtering process gas |
BRPI0720377A BRPI0720377B8 (en) | 2006-12-19 | 2007-12-18 | METHOD AND DEVICE FOR FILTERING PROCESS GAS. |
NO20092628A NO341386B1 (en) | 2006-12-19 | 2009-07-10 | Process and apparatus for filtration of process gas |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20061133 | 2006-12-19 | ||
FI20061133A FI20061133A0 (en) | 2006-12-19 | 2006-12-19 | Equipment for filtering process gas |
FI20070961 | 2007-12-11 | ||
FI20070961A FI121368B (en) | 2006-12-19 | 2007-12-11 | Method and equipment for filtering process gas |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008074912A1 true WO2008074912A1 (en) | 2008-06-26 |
Family
ID=38951497
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FI2007/000295 WO2008074912A1 (en) | 2006-12-19 | 2007-12-18 | Method and apparatus for filtering process gas |
Country Status (9)
Country | Link |
---|---|
US (1) | US20100071555A1 (en) |
EP (1) | EP2099548B1 (en) |
AU (1) | AU2007336147B2 (en) |
BR (1) | BRPI0720377B8 (en) |
CA (1) | CA2672162C (en) |
EA (1) | EA016239B1 (en) |
FI (1) | FI121368B (en) |
NO (1) | NO341386B1 (en) |
WO (1) | WO2008074912A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010072894A1 (en) * | 2008-12-22 | 2010-07-01 | Outotec Oyj | Method and arrangement for removing solid particles and tar component from carbon monoxide gas |
WO2013150498A2 (en) | 2012-04-05 | 2013-10-10 | Tenova Pyromet (Proprietary) Limited | Method and apparatus for dry filtering process gas |
DE102014207160A1 (en) * | 2014-04-15 | 2015-10-15 | Eos Gmbh Electro Optical Systems | Recirculation filter device for a device for producing a three-dimensional object in layers |
CN116474506A (en) * | 2023-03-27 | 2023-07-25 | 广州市晶科电器有限公司 | Intelligent waste gas treatment equipment |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016201812A1 (en) * | 2016-02-05 | 2017-08-10 | Eos Gmbh Electro Optical Systems | Device and method for producing a three-dimensional object |
CN112604392B (en) * | 2020-11-27 | 2022-07-26 | 河北晴空环保科技有限公司 | Filtering mechanism of waste gas pipeline for environmental protection |
CN113476911A (en) * | 2021-07-15 | 2021-10-08 | 湖北中煜环保科技有限公司 | High-efficient environment-friendly industrial waste gas administers device |
CN114870533B (en) * | 2022-05-23 | 2023-07-04 | 成都易态科技有限公司 | Ash discharging balancing device and filter |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB672458A (en) * | 1949-08-12 | 1952-05-21 | Metallgesellschaft Ag | Improvements in or relating to electrofilters |
DE2540003A1 (en) * | 1975-09-09 | 1977-03-10 | Schuler Filtertech Wilhelm | Cleaning hot gas filters by water injection - causing pressure wave on clean gas side to release filter cake |
US5112585A (en) * | 1988-12-06 | 1992-05-12 | Kernforschungszentrum Karlsruhe Gmbh | Process of removing flue gas cleaning residues during the wet cleaning of flue gases by drying and construction |
EP0864347B1 (en) * | 1997-03-13 | 2003-01-15 | Forschungszentrum Karlsruhe GmbH | Process and apparatus for cleaning filters containing dust and aerosol particles |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3022203A1 (en) * | 1980-06-13 | 1981-12-24 | Mikropul Gesellschaft für Mahl- und Staubtechnik mbH, 5000 Köln | Gas filter bags cleaned while still in casing - by external liquid sprays in upper zone and internal gas pressure pulses |
EP1027131B1 (en) * | 1997-10-31 | 2002-01-16 | Niro A/S | A method of cleaning a filter unit, and a filter unit for filtering gas |
-
2007
- 2007-12-11 FI FI20070961A patent/FI121368B/en active IP Right Grant
- 2007-12-18 EP EP07858319.2A patent/EP2099548B1/en active Active
- 2007-12-18 BR BRPI0720377A patent/BRPI0720377B8/en active IP Right Grant
- 2007-12-18 WO PCT/FI2007/000295 patent/WO2008074912A1/en active Application Filing
- 2007-12-18 US US12/519,540 patent/US20100071555A1/en not_active Abandoned
- 2007-12-18 EA EA200900696A patent/EA016239B1/en not_active IP Right Cessation
- 2007-12-18 CA CA2672162A patent/CA2672162C/en active Active
- 2007-12-18 AU AU2007336147A patent/AU2007336147B2/en active Active
-
2009
- 2009-07-10 NO NO20092628A patent/NO341386B1/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB672458A (en) * | 1949-08-12 | 1952-05-21 | Metallgesellschaft Ag | Improvements in or relating to electrofilters |
DE2540003A1 (en) * | 1975-09-09 | 1977-03-10 | Schuler Filtertech Wilhelm | Cleaning hot gas filters by water injection - causing pressure wave on clean gas side to release filter cake |
US5112585A (en) * | 1988-12-06 | 1992-05-12 | Kernforschungszentrum Karlsruhe Gmbh | Process of removing flue gas cleaning residues during the wet cleaning of flue gases by drying and construction |
EP0864347B1 (en) * | 1997-03-13 | 2003-01-15 | Forschungszentrum Karlsruhe GmbH | Process and apparatus for cleaning filters containing dust and aerosol particles |
Non-Patent Citations (1)
Title |
---|
See also references of EP2099548A4 * |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010072894A1 (en) * | 2008-12-22 | 2010-07-01 | Outotec Oyj | Method and arrangement for removing solid particles and tar component from carbon monoxide gas |
US20110252967A1 (en) * | 2008-12-22 | 2011-10-20 | Outotec Oyj | Method and arrangement for removing solid particles and tar component from carbon monoxide gas |
EP2384236A1 (en) * | 2008-12-22 | 2011-11-09 | Outotec OYJ | Method and arrangement for removing solid particles and tar component from carbon monoxide gas |
CN102264453A (en) * | 2008-12-22 | 2011-11-30 | 奥图泰有限公司 | Method and arrangement for removing solid particles and tar component from carbon monoxide gas |
US8673058B2 (en) | 2008-12-22 | 2014-03-18 | Outotec Oyj | Method and arrangement for removing solid particles and tar component from carbon monoxide gas |
AU2009332877B2 (en) * | 2008-12-22 | 2014-09-04 | Outotec Oyj | Method and arrangement for removing solid particles and tar component from carbon monoxide gas |
EA021010B1 (en) * | 2008-12-22 | 2015-03-31 | Ототек Оюй | Method and arrangement for removing solid particles and tar component from carbon monoxide gas |
EP2384236A4 (en) * | 2008-12-22 | 2017-04-05 | Outotec Oyj | Method and arrangement for removing solid particles and tar component from carbon monoxide gas |
WO2013150498A2 (en) | 2012-04-05 | 2013-10-10 | Tenova Pyromet (Proprietary) Limited | Method and apparatus for dry filtering process gas |
DE102014207160A1 (en) * | 2014-04-15 | 2015-10-15 | Eos Gmbh Electro Optical Systems | Recirculation filter device for a device for producing a three-dimensional object in layers |
CN116474506A (en) * | 2023-03-27 | 2023-07-25 | 广州市晶科电器有限公司 | Intelligent waste gas treatment equipment |
Also Published As
Publication number | Publication date |
---|---|
NO20092628L (en) | 2009-09-17 |
AU2007336147B2 (en) | 2012-08-09 |
EP2099548A1 (en) | 2009-09-16 |
FI20070961A (en) | 2008-06-20 |
EA200900696A1 (en) | 2010-02-26 |
AU2007336147A1 (en) | 2008-06-26 |
EP2099548A4 (en) | 2010-06-16 |
CA2672162A1 (en) | 2008-06-26 |
NO341386B1 (en) | 2017-10-30 |
BRPI0720377B1 (en) | 2018-06-12 |
EA016239B1 (en) | 2012-03-30 |
EP2099548B1 (en) | 2013-11-20 |
BRPI0720377A2 (en) | 2013-12-31 |
BRPI0720377B8 (en) | 2023-03-28 |
FI121368B (en) | 2010-10-29 |
US20100071555A1 (en) | 2010-03-25 |
FI20070961A0 (en) | 2007-12-11 |
CA2672162C (en) | 2015-11-24 |
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