WO2008072042A3 - Equipment for the ethyl alcohol's catalytic thermo-fission to hydrogen and carbonic oxide for the feeding of fuel cells - Google Patents

Equipment for the ethyl alcohol's catalytic thermo-fission to hydrogen and carbonic oxide for the feeding of fuel cells Download PDF

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Publication number
WO2008072042A3
WO2008072042A3 PCT/IB2007/002831 IB2007002831W WO2008072042A3 WO 2008072042 A3 WO2008072042 A3 WO 2008072042A3 IB 2007002831 W IB2007002831 W IB 2007002831W WO 2008072042 A3 WO2008072042 A3 WO 2008072042A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen
fission
ethyl alcohol
fuel cells
carbonic oxide
Prior art date
Application number
PCT/IB2007/002831
Other languages
French (fr)
Other versions
WO2008072042A2 (en
Inventor
Rocco Tulino Rosario
Letiza Santino
Original Assignee
Rocco Tulino Rosario
Letiza Santino
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rocco Tulino Rosario, Letiza Santino filed Critical Rocco Tulino Rosario
Publication of WO2008072042A2 publication Critical patent/WO2008072042A2/en
Publication of WO2008072042A3 publication Critical patent/WO2008072042A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C01B2203/1229—Ethanol
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Abstract

Compact equipment unit for continuous ethyl alcohol catalytic thermo-fission suitable to produce hydrogen and carbonic oxide and composed by five devices placed in series from which one obtaines hydrogen suitable to feed fuel cells and carbonic oxide that is used to feed all the ancillary devices required to run the system. The equipment allows the conversion of ethanol to electrical energy to supply electric motors of auto-traction.
PCT/IB2007/002831 2006-12-12 2007-09-18 Equipment for the ethyl alcohol's catalytic thermo-fission to hydrogen and carbonic oxide for the feeding of fuel cells WO2008072042A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT000146A ITPI20060146A1 (en) 2006-12-12 2006-12-12 CATALYTIC THERMO-DETECTION EQUIPMENT OF ETHYL ALCOHOL IN HYDROGEN AND CARBON OXIDE FOR THE SUPPLY OF FUEL CELLS.
ITPI2006A000146 2006-12-12

Publications (2)

Publication Number Publication Date
WO2008072042A2 WO2008072042A2 (en) 2008-06-19
WO2008072042A3 true WO2008072042A3 (en) 2009-07-23

Family

ID=39512146

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2007/002831 WO2008072042A2 (en) 2006-12-12 2007-09-18 Equipment for the ethyl alcohol's catalytic thermo-fission to hydrogen and carbonic oxide for the feeding of fuel cells

Country Status (2)

Country Link
IT (1) ITPI20060146A1 (en)
WO (1) WO2008072042A2 (en)

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1437957A (en) * 1973-03-19 1976-06-03 Ici Ltd Combustible gases
US3986350A (en) * 1974-03-06 1976-10-19 Reinhold Schmidt Method of and apparatus for improved methanol operation of combustion systems
GB1509557A (en) * 1975-05-15 1978-05-04 Ici Ltd Catalyst precursor compositions
EP0038682A1 (en) * 1980-04-23 1981-10-28 The British Petroleum Company p.l.c. Process for the production of synthesis gas from methanol
EP0050525A1 (en) * 1980-10-22 1982-04-28 The British Petroleum Company p.l.c. Synthetic modified crystalline silica
US4632774A (en) * 1983-09-14 1986-12-30 The Standard Oil Company Process for reforming alcohols
EP0207620A2 (en) * 1985-06-04 1987-01-07 Imperial Chemical Industries Plc Energy recovery
US5904880A (en) * 1996-12-31 1999-05-18 Exxon Chemical Patents Inc. One step conversion of methanol to hydrogen and carbon dioxide
US6541142B1 (en) * 2000-10-04 2003-04-01 General Motors Corporation Fuel cell system having a methanol decomposition reactor
US20040137288A1 (en) * 2002-10-18 2004-07-15 Monsanto Technology Llc Use of metal supported copper catalysts for reforming alcohols
US20050244329A1 (en) * 2004-03-10 2005-11-03 Dominique Casanave Process for the production of hydrogen with very high purity from alcohols that comprise at least two carbon atoms

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1437957A (en) * 1973-03-19 1976-06-03 Ici Ltd Combustible gases
US3986350A (en) * 1974-03-06 1976-10-19 Reinhold Schmidt Method of and apparatus for improved methanol operation of combustion systems
GB1509557A (en) * 1975-05-15 1978-05-04 Ici Ltd Catalyst precursor compositions
EP0038682A1 (en) * 1980-04-23 1981-10-28 The British Petroleum Company p.l.c. Process for the production of synthesis gas from methanol
EP0050525A1 (en) * 1980-10-22 1982-04-28 The British Petroleum Company p.l.c. Synthetic modified crystalline silica
US4632774A (en) * 1983-09-14 1986-12-30 The Standard Oil Company Process for reforming alcohols
EP0207620A2 (en) * 1985-06-04 1987-01-07 Imperial Chemical Industries Plc Energy recovery
US5904880A (en) * 1996-12-31 1999-05-18 Exxon Chemical Patents Inc. One step conversion of methanol to hydrogen and carbon dioxide
US6541142B1 (en) * 2000-10-04 2003-04-01 General Motors Corporation Fuel cell system having a methanol decomposition reactor
US20040137288A1 (en) * 2002-10-18 2004-07-15 Monsanto Technology Llc Use of metal supported copper catalysts for reforming alcohols
US20050244329A1 (en) * 2004-03-10 2005-11-03 Dominique Casanave Process for the production of hydrogen with very high purity from alcohols that comprise at least two carbon atoms

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
J. LLORCA, R. RAMIREZ DE LA PISCINA, J. SALES, N. HOMS: "Direct production of hydrogen from ethanolic aqueous solutions over oxide catalysts", CHEMICAL COMMUNICATIONS, 2001, pages 641 - 642, XP002524231 *
J-M-DAVIDSON, C.MCGREGOR, L.K.DORAISWAMY: "The Kinetics of the Palladium-catalyzed Vapor-Phase Thermal Decomposition of Ethanol", IND. ENG. CHEM. RES., vol. 40, 2001, pages 101 - 107, XP002524553 *
SCHICI DUAN, SELIM SENKAN: "Catalytic Conversion of Ethanol to Hydrogen Using Combinatorial Methods", IND. ENG. CHEM. RES., vol. 44, 2005, pages 6381 - 6386, XP002495562 *

Also Published As

Publication number Publication date
WO2008072042A2 (en) 2008-06-19
ITPI20060146A1 (en) 2007-03-13

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