WO2008068054A1 - Procédé de fabrication d'un support d'informations - Google Patents

Procédé de fabrication d'un support d'informations Download PDF

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Publication number
WO2008068054A1
WO2008068054A1 PCT/EP2007/053837 EP2007053837W WO2008068054A1 WO 2008068054 A1 WO2008068054 A1 WO 2008068054A1 EP 2007053837 W EP2007053837 W EP 2007053837W WO 2008068054 A1 WO2008068054 A1 WO 2008068054A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
receiving layer
pattern
receiving
layer configuration
Prior art date
Application number
PCT/EP2007/053837
Other languages
English (en)
Inventor
Luc Leenders
David Terrell
Eddie Daems
Original Assignee
Agfa-Gevaert
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agfa-Gevaert filed Critical Agfa-Gevaert
Priority to EP07728297A priority Critical patent/EP2091753B1/fr
Priority to AT07728297T priority patent/ATE465020T1/de
Priority to DE602007006050T priority patent/DE602007006050D1/de
Priority to CN200780045086.8A priority patent/CN101595000B/zh
Publication of WO2008068054A1 publication Critical patent/WO2008068054A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30—Identification or security features, e.g. for preventing forgery
    • B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
    • B42D25/378—Special inks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0029—Formation of a transparent pattern using a liquid marking fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40—Manufacture
    • B42D25/405—Marking
    • B42D25/43—Marking by removal of material
    • B42D2033/04—
    • B42D2033/08—
    • B42D2035/34—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40—Manufacture
    • B42D25/45—Associating two or more layers
    • B42D25/465—Associating two or more layers using chemicals or adhesives

Definitions

  • the present invention relates to a method for producing an information carrier.
  • the security field encompasses not only personalized documents such as passports, driving licenses, identity cards (ID cards) and admission documents such as visa's and entry tickets, but also the authentification and identification of goods to avoid counterfeiting, tampering and fraud such as lottery tickets, share certificates, transaction documents, labels on luggage and the packaging of pharmaceuticals and high value products in general.
  • identity card encompasses cards requiring bearer identification and range from national identity cards to establish the national identity of their civilians to cards involved in the electronic transfer of money such as bank cards, pay cards, credit cards and shopping cards to security cards authorizing access to the bearer of the card to particular areas such as a company (employee ID card) , the military, a public service, the safe deposit departments of banks, etc. to social security cards to membership cards of clubs and societies.
  • ID cards usually contain information referring both to the authority issuing the card on the one hand and to the owner of the card on the other.
  • the first type of information may be general information such as a name and/or logo of the issuing authority, or security marks, such as a watermark and security print, e.g. a repeating monochrome pattern or a gradually changing colour pattern which are difficult to counterfeit.
  • the second type includes e.g. the unique card number, personal data such as a birth day, a photo of the owner, and a signature.
  • the card can further contain hidden information and therefore contain a magnetic strip or an electronic chip (“smart cards”) .
  • a large set of ID cards are usually prepared on a large web or sheet by a step and repeat process, after which the web or sheet is cut into multiple items with the appropriate dimensions each representing a personal ID card.
  • Smart cards and ID cards now have the standardized dimensions of 85.6 mm x 54.0 mm x 0.76 mm.
  • the card is protected by a plastic sheet material for example by lamination of the card to a plastic sheet or, as is usually the case, by lamination between two plastic sheets.
  • US 4,032,691 discloses a recording material which comprises a support having thereon a highly thermally insulating porous resin layer and a metal, dye or synthetic resin which is thermally deformed, foams, colors, discolors, sublimes, evaporates, or becomes transparent, translucent or opaque when exposed to radiation having a high energy density.
  • EP-A 1 362 710 discloses a method for producing a tamper proof carrier of information, said method comprising the following steps, in order: (1) providing a two-layer assemblage comprising (i) a rigid sheet or web support, and (ii) a porous opaque ink receiving layer comprising a pigment and a binder whereby either the surface of said support, or the surface of said opaque layer carries a first set of printed information, (2) printing a second set of information, different from said first set, onto said porous opaque ink receiving layer by means of ink jet printing, (3) covering totally, partially, or pattern-wise the thus obtained assemblage with a UV-curable lacquer composition, by means of coating, printing, spraying or jetting, whereby on penetration of the lacquer in said porous opaque ink receiving layer this layer becomes substantially transparent, (4) curing said lacquer composition by means of an overall UV exposure, thereby improving the adhesion between said support and said ink receiving layer, and the cohesive strength of said ink receiving layer.
  • EP-A 1 398 175 discloses four different embodiments of an information carrier.
  • the information carrier comprising: a rigid sheet or web support; an opaque porous receiving layer capable of being rendered substantially transparent by penetration by a lacquer, said receiving layer containing a pigment and a binder; an image provided onto and/or in said receiving layer; a cured pattern of a varnish provided onto said receiving layer provided with said image or onto and/or in said receiving layer provided with said image if said varnish is incapable of rendering said receiving layer transparent; and a cured layer of said lacquer provided on said receiving layer provided with said image and said cured pattern of said varnish, said lacquer having rendered said parts of said receiving layer in contact therewith substantially transparent, wherein said cured pattern of said varnish forms an opaque watermark.
  • the information carrier comprising: a rigid sheet or web support; an opaque porous receiving layer capable of being rendered substantially transparent by penetration by a varnish, said receiving layer containing a pigment and a binder; an image provided onto and/or in said receiving layer; a cured pattern of said varnish provided in said receiving layer provided with said image; and a cured layer of a lacquer provided onto said receiving layer provided with said image and said cured pattern of said varnish, or onto and/or in said receiving layer provided with said image and said cured pattern of said varnish if said lacquer is incapable of rendering said receiving layer transparent, said varnish having rendered said parts of said receiving layer in contact therewith substantially transparent, wherein said cured pattern of said lacquer forms a substantially transparent watermark.
  • the information carrier comprising: a rigid sheet or web support; a transparent porous receiving layer capable of being rendered substantially opaque by penetration by a lacquer, said receiving layer containing a pigment and a binder; an image provided onto and/or in said receiving layer; a cured pattern of a varnish provided onto said receiving layer provided with said image, or onto and/or in said receiving layer provided with said image if said varnish is incapable of rendering said receiving layer opaque; and a cured layer of said lacquer provided on said receiving layer provided with said image and said cured pattern of said varnish, said lacquer having rendered said parts of said receiving layer in contact therewith substantially opaque, wherein said cured pattern of said varnish forms a transparent watermark.
  • the information carrier comprising: a rigid sheet or web support; a transparent porous receiving layer capable of being rendered substantially opaque by penetration by a varnish, said receiving layer containing a pigment and a binder; an image provided onto and/or in said receiving layer; a cured pattern of said varnish provided in said receiving layer provided with said image; and a cured layer of a lacquer provided onto said receiving layer provided with said image and said cured pattern of said varnish, or onto and/or in said receiving layer provided with said image and said cured pattern of said varnish if said lacquer is incapable of rendering said receiving layer opaque, said varnish having rendered said parts of said receiving layer in contact therewith substantially opaque, wherein said cured pattern of said lacquer forms a substantially opaque watermark.
  • GB 1 073 433 discloses the method of forming an image on a porous, opaque layer comprising applying an imaging material in imagewise configuration which is of similar refractive index to the opaque layer and reducing the viscosity of said imaging material so that it flows into the pores to fill the pores of said opaque layer to render said opaque layer clear in said image areas.
  • US 4,252,601 discloses an information recording kit for making transparencies for projection of information or for making photographic negatives for reproductions comprising an opaque recording material, a writing liquid for recording information on the recording material and means for applying the writing liquid on the opaque recording material in the form of transparent lines wherein said recording material comprises a transparent backing sheet and an opaque layer adhered to one surface of said backing sheet, said opaque layer comprising a finely divided particulate organic styrene resin pigment uniformly distributed throughout a polyvinylidene chloride film-forming resin binder, said writing liquid comprising a solvent for the organic styrene resin pigment, whereby when said writing liquid is applied to said opaque layer according to a pattern of information the opaque layer becomes transparent to visible light according to said pattern.
  • WO 81/01389A1 discloses a self-supporting microvoid-containing sheet material which is substantially insensitive to marking by the localized application of heat or pressure but which is receptive to ink, pencil, crayon or similar markings and which is adapted to being temporarily or permanently provided with markings by the application of a colorless liquid, comprising in combination: a self-supporting base sheet and, bonded over at least one side of said base sheet, a reflective opaque white to pastel layer comprising particles bonded by a binder, said particles and binder both having a refractive index in the range of 1.3 to 2.2, interconnected microvoids being present throughout said layer, characterized in that the binder : particle volume ratio being in the range of about 1:20 to 2:3, so that the particles are held in pseudo-sintered juxtaposition, the void volume of the layer being in the range of 15-70%, said binder being thermoset, and layer having an image force of at least 200 grams-force.
  • US 4,499,211 discloses a microporous molded article having an open-cell structure and comprising a thermoplastic material which possesses an inherent latent structural convertibility and includes effective pores of a diameter in the range from about 0.002 to 10 ⁇ m, said thermoplastic material comprising at least about 70 percent by weight of a terpolymer which is composed of from about 20 to 80 percent by weight, relative to the total weight of the terpolymer, of copolymerized fluorinated olefin selected from the group consisting of ethylene and propylene, up to about 40 percent by weight, relative to the total weight of the terpolymer, of copolymerized olefin selected from the group consisting of ethylene and propylene, and from about 80 to 20 percent by weight, relative to the total weight of the copolymer, of copolymerized vinyl acetate, with at least 5 percent of the total proportion of acetate groups contained in the copolymer being converted by saponification into OH groups after copolymer
  • EP-A 0 390 638 discloses a base sheet comprising a layer capable of becoming, in reversible manner, transparent by contact with a liquid, resistant to a marking by localized application of pressure and/or heat, characterized by the fact that it comprises: at least one flexible sheet, at least one layer applied in aqueous form on the flexible sheet and then dried, said sheet being microporous, opaque, and containing at least non-thermoset particles, at least one binder and optionally other additives.
  • JP 10-157280A discloses a recording material capable of being printed repeatedly by ink jet printing without deteriorating its recording performance even in the case of using many times by incorporating mat or porous surface and a solvent receiving layer which becomes opaque when no solvent exists and transparent when solvent is received.
  • US 5,660,925 discloses an authenticatible, tamper-indicating label, comprising: a normally opaque, transparentizable microporous film having first and second major surfaces, a first indicia proximate said first surface a second indicia on said first surface, and an adhesive proximate said first surface; wherein said microporous film can be changed from an opaque state to a transparent state by application of a first liquid that is not a solvent for said first and second indicia to said microporous film to thereby sufficiently fill the pores of said microporous film to cause said film to become transparent; wherein when said microporous film is in its opaque state, said first and second indicia are not visually perceptible when said label is viewed from said second surface, and when said microporous film is in its transparent state, at least said first indicia is visually perceptible when said label is viewed from said second surface, thereby providing an indication of the authenticity of said label; and wherein application of a second liquid that is
  • US 6,364,993 discloses a laminate comprising a substrate having a first substrate surface containing an image thereon and a polymeric film laminated to said first substrate surface overlying said image, said film containing an exposed water activatable opaque layer having a thickness ranging from about 0.6 mil to about 2.0 mil, said opaque layer derived from a coating formulation comprising from about 5 to about 40 wt. % aluminum silicate and from about 60 to about 95 wt. % binder, wherein the binder comprises a mixture of solvent, butyl acetate, ethylene glycol monobutyl ether and propylene glycol.
  • US 6,723,383 discloses a process for producing a dry image comprising the steps of: (a) applying an opaque coating composition to the surface of a substrate to form an opaque coating on the substrate, wherein the surface is selected from the group consisting of a light-emitting surface, a reflective surface, a glossy surface, a luminescent surface, and a combination thereof; and (b) contacting the coated substrate with a recording liquid, wherein the opaque coating composition includes an opaque coating agent comprising a polymeric polyacid and a polymeric polybase, and wherein the opaque coating contacted with the recording liquid becomes transparent as a result of the contact.
  • WO 04/052655A1 discloses a multi-layer opaque and matte ink-jet recording medium, suitable for recording images with dye and pigmented inks, which goes through phase change from opaque to transparent and glossy in at least one printed area to reveal the surface of a substrate and thereby provide light-emitting, reflective, glossy, metallic-looking images or to show holographic images
  • the recording medium comprises a substrate coated with at least two chemically layers comprising: (a) a first transparent ink-receptive layer comprising a polymeric binder and a cross-linker and optionally having a plasticizer and pigment particles such as alumina and silica coated over the substrate, wherein the cross-linker comprises an azetidinium polymer or a salt thereof, and/or a polyfunctional aziridine or a salt thereof, or a polyfunctional oxazoline and metallic salts ; and (b) a second ink- receptive layer comprising an opaque or semi-opaque coating composition, wherein the opaque or
  • EP-A 1 362 710 and EP-A 1 398 175 both disclose a porous opaque ink receiving layer comprising a pigment and a binder, which is capable of being transparentized with a UV- curable lacquer.
  • a porous opaque ink receiving layer comprising a pigment and a binder, which is capable of being transparentized with a UV- curable lacquer.
  • the writing or modification of machine readable information can be realized in a layer or element, or pattern in the layer or element, capable of machine readable change covered by an opaque porous layer.
  • This is achieved by temporarily transparentizing the opaque porous layer with a liquid and in the resulting transparentized state using a visible, UV or IR light source to modify or write the machine-readable information in the layer or element capable of machine readable change or in a pattern in the layer or element. Evaporation of the liquid then restores the opacity of the covering layer and this opacity can be rendered permanent by penetration by a lacquer, which does not transparentize the opaque porous layer, with optional subsequent curing, thereby realizing machine readable information which can no longer be changed.
  • aspects of the present invention are realized by a method for producing an information carrier comprising the steps of: (1) providing an information carrier precursor comprising a rigid sheet or support; a receiving layer configuration having an image- receiving side and a non-image-receiving side, the receiving layer configuration comprising at least one pigment and at least one binder, wherein at least one constituent layer of the receiving layer configuration is opaque; at least the outermost layer on the image-receiving side or a layer in diffusive contact with the outermost layer on the image-receiving side is opaque and porous; and the receiving layer configuration is capable of being rendered substantially transparent by penetration by a lacquer; and a layer or element, or pattern in the layer or element, capable of a machine-readable change upon absorbing UV, visible or IR radiation, the layer or element being either the surface of the rigid sheet or support or interposed between the rigid sheet or support and the non-image-receiving side of the receiving layer configuration; (2) pattern-wise or integrally at least partially transparentizing the receiving layer configuration with a vapor
  • information carrier precursor means an intermediate product used in the realization of information carriers.
  • 'porous layer means a layer with pores, which can be in the ingredients of the layer and/or in addition to the ingredients of the layer e.g. a layer containing a porous ingredient is a porous layer.
  • opaque and non-transparent layer refer to a layer where less than 10% of the incident light is allowed to pass through the layer.
  • substantially transparent layer at least 50% of the incident visible light, preferably more than 65 and particularly preferably more than 75%, passes through the layer.
  • non-transparentizing lacquer means a liquid under the application conditions, which comprises at least one polymer and/or at least one wax and/or at least one polymerizable substance (e.g. monomers and oligomers) and can solidify upon cooling, become solid upon evaporation of solvent or harden/cross-link upon exposure to moisture or radiation e.g. visible light, UV-radiation and electron beams i.e. is curable which does not transparentize the receiving layer configuration.
  • transparentizing lacquer means a liquid under the application conditions, which comprises at least one polymer and/or at least one wax and/or at least one polymerizable substance (e.g.
  • the term "capability of being rendered substantially transparent by a "vaporizable liquid”, as used in disclosing the present invention, means that the receiving layer configuration at least becomes transparent upon penetration of the liquid and is maintained as long as the liquid is present.
  • the term "at least partially non-transparent”, as used in disclosing the present invention, means not completely non- transparent but insufficiently non-transparent to prevent the pattern in the layer or element capable of a machine-readable change upon absorbing UV, visible or IR radiation being changed by UV, visible or IR radiation.
  • on means that penetration of the layer may or may not occur
  • onto means at least 90% on the top of i.e. there is no substantial penetration into the layer
  • in means that penetration into the respective layer or layers occurs.
  • inventions refers to impact printing processes as well as to non-impact printing processes.
  • the term includes but is not restricted to ink-jet printing, intaglio printing, screen printing, flexographic printing, driographic printing, electrophotographic printing, electrographic printing, offset printing, stamp printing, gravure printing, thermal and laser-induced processes and also includes a printing process rendering areas of a conductive layer non-conductive in a single pass process, such as disclosed in EP 1 054 414A and WO 03/025953A, but excludes processes such as evaporation, etching, diffusion processes used in the production of conventional electronics e.g. silicon-based electronics.
  • impact printing process means a printing process in which contact is made between the medium in which the print is produced and the printing system e.g. printers that work by striking an ink ribbon such as daisy-wheel, dot-matrix and line printers, and direct thermal printers in which the thermographic material is printed by direct contact with heating elements in a thermal head and printers in which a master is covered with an ink layer on areas corresponding to a desired image or shape, after which the ink is transferred to the medium, such as offset, gravure or flexographic printing.
  • the printing system e.g. printers that work by striking an ink ribbon such as daisy-wheel, dot-matrix and line printers, and direct thermal printers in which the thermographic material is printed by direct contact with heating elements in a thermal head and printers in which a master is covered with an ink layer on areas corresponding to a desired image or shape, after which the ink is transferred to the medium, such as offset, gravure or flexographic printing.
  • non-impact printing process means a printing process in which no contact is made between the medium in which the print is produced and the printing system e.g. electrographic printers, electrophotographic printers, laser printers, ink jet printers in which prints are produced without needing to strike the print medium.
  • pattern includes holograms, images, representations, guilloches, graphics and regular and irregular arrays of symbols, images, geometric shapes and non-geometric shapes and can consist of pixels, continuous tone, lines, geometric shapes and/or any random configuration .
  • pattern-wise means as a pattern and embraces the term image-wise.
  • layer means a coating covering the whole area of the entity referred to e.g. a support.
  • discontinuous layer means a coating not covering the whole area of the entity referred to e.g. a support.
  • PET is an abbreviation for polyethylene terephthalate .
  • PETG is an abbreviation for polyethylene terephthalate glycol, the glycol indicating glycol modifiers which are incorporated to minimize brittleness and premature aging that occur if unmodified amorphous polyethylene terephthalate (APET) is used in the production of cards.
  • APET amorphous polyethylene terephthalate
  • aspects of the present invention are realized by a method for producing an information carrier comprising the steps of: (1) providing an information carrier precursor comprising a rigid sheet or support; a receiving layer configuration having an image- receiving side and a non-image-receiving side, the receiving layer configuration comprising at least one pigment and at least one binder, wherein at least one constituent layer of the receiving layer configuration is opaque; at least the outermost layer on the image-receiving side or a layer in diffusive contact with the outermost layer on the image-receiving side is opaque and porous; and the receiving layer configuration is capable of being rendered substantially transparent by penetration by a lacquer; and a layer or element, or pattern in the layer or element, capable of a machine-readable change upon absorbing UV, visible or IR radiation, the layer or element being either the surface of the rigid sheet or support or interposed between the rigid sheet or support and the non-image-receiving side of the receiving layer configuration; (2) pattern-wise or integrally at least partially transparentizing the receiving layer configuration with a vapor
  • Vaporizable transparentizing liquids include water, organic solvents, mixtures of water with organic solvents and solvent mixtures. Selection is dependent upon the refractive index of the liquid, its ease of evaporation, its viscosity and its ability to wet the pores in the receiving layer configuration and therefore enable penetration of the receiving layer configuration. If the pores have a hydrophilic character, hydrophilic liquids with the requisite refractive index will be required and if the pores have a hydrophobic character, hydrophobic liquids with the requisite refractive index will be required.
  • the refractive index should differ from that of the pigment used in the receiving layer configuration by no more than 0.1, with a difference of 0.04 being preferred and a difference of 0.02 being particularly prepared.
  • porous silica e.g. silica gel
  • the following vaporizable liquids are suitable for obtaining temporary transparentization :
  • the method further comprises applying a permanent pattern to the outermost layer of the receiving layer configuration.
  • the method further comprises applying a permanent pattern to the outermost layer of the receiving layer configuration and the permanent pattern is applied to the outermost surface of the receiving layer using a conventional printing technique, with non-impact printing or impact printing being preferred and ink-jet printing being particularly preferred.
  • the method further comprises applying a permanent pattern to the outermost layer of the receiving layer configuration and the method of applying a permanent pattern to the outermost surface of the receiving layer configuration is a non-impact printing technique selected from the group consisting of electrophotographic printing, electrophoretic printing and ink-jet printing.
  • the method further comprises applying a permanent pattern to the outermost layer of the receiving layer configuration and the method of applying a coloured permanent pattern to the outermost surface of the receiving layer configuration is an impact printing technique selected from the group consisting of thermal dye sublimation printing, thermal dye transfer printing, screen printing, offset printing, gravure printing and flexographic printing.
  • the method further comprises applying a permanent pattern to the outermost layer of the receiving layer configuration and the permanent pattern is applied using a conventional printing process only to the opaque, porous parts of the outermost layer of the receiving layer configuration remaining after permanent pattern-wise transparent!zation .
  • the method further comprises applying a pattern to the outermost layer of the receiving layer configuration and the application of the pattern to the outermost layer is performed subsequent to the writing or the modifying of the pattern in the layer or element capable of a machine-readable change upon absorption of UV, visible or IR radiation .
  • the light source is a laser.
  • a hologram is written on or applied to the outermost surface of the information carrier.
  • an embossable layer is applied to the outermost surface of the information carrier and the embossable layer is then embossed e.g. as a hologram.
  • a UV- hardenable black image is printed on the outermost surface of the information carrier and the black image is UV-hardened to form a relief image.
  • a metal fibre or strip is applied to the outermost surface of the information carrier in a hardenable composition.
  • the security print is repeatedly applied over multiple areas of the web or sheet by a step and repeat process thus giving rise to multiple identical items.
  • These multiple identical items are distributed over the support according to a fixed pattern, e.g. a rectangular grid.
  • the method further comprises applying a permanent pattern to the outermost layer of the receiving layer configuration and the permanent pattern applied to the outermost layer of the receiving layer configuration is a digitally stored set of information, applied, for example, by means of ink jet printing, thermal dye sublimation printing or thermal dye transfer printing. Printing techniques using toner particles can however also be used.
  • the method further comprises applying a permanent pattern to the outermost layer of the receiving layer configuration and the permanent pattern applied to the outermost layer of the receiving layer configuration is a digitally stored set of information, which is personalized information different for each individual item present on the information carrier.
  • this personalized information may be a unique individual card number assigned to the future bearer of the card, or the expiry date of the validity of the card, or personal data of the future bearer, e.g. a date of birth, and/or a photo.
  • the ink jet printing step is repeated over multiple areas of the support in register with the security print pattern when present, thereby providing each item with different personalized information.
  • the application and curing of the varnish is repeated over multiple areas of the information carrier fully or partially in register with the multiple different items already present consisting of optional security print and personalized information.
  • the pattern-wise or integrally at least partial non- transparentization of the receiving layer configuration is carried out by coating, printing, spraying or jetting a lacquer composition on the outermost surface of the receiving layer configuration, with the lacquer preferably being curable and particularly preferably being radiation curable e.g. UV-curable.
  • the at least partial transparentization is preferably carried out by ink-jet printing.
  • UV-curing can be carried out with medium pressure mercury vapour lamps with or without electrodes, or pulsed xenon lamps.
  • These ultraviolet light sources are usually equipped with a cooling installation, an installation to remove the ozone produced and optionally a nitrogen inflow to exclude air from the surface of the product to be cured during radiation processing.
  • a UV-light intensity of 40 to 240 W/cm in the 200-400 nm spectral region is usually employed.
  • An example of a commercially available UV-curing unit is the DRSE-120 conveyor from Fusion UV Systems Ltd., UK with a VPS/1600 UV lamp, an ultraviolet medium-pressure electrodeless mercury vapour lamp.
  • the DRSE-120 conveyor can operate at different transport speeds and different UV power settings over a width of 20 cm and a length in the transport direction of 0.8 cm. Moreover, it can also be used with metal halide-doped Hg vapour or XeCl excimer lamps, each with its specific UV emission spectrum. This permits a higher degree of freedom in formulating the curing composition: a more efficient curing is possible using the lamp with the most appropriate spectral characteristics.
  • a pulsed xenon flash lamp is commercially available from 1ST Strahlentechnik GmbH, Nurtingen, Germany.
  • Ink compositions for ink jet typically include following ingredients: dyes or pigments, water and/or organic solvents, humectants such as glycols, detergents, thickeners, polymeric binders, preservatives, etc. It will be readily understood that the optimal composition of such an ink is dependent on the ink jetting method used and on the nature of the substrate to be printed.
  • the ink compositions can be roughly divided into: - water based: drying mechanism involves absorption, penetration and evaporation; - oil based: drying involves absorption and penetration; - solvent based: drying mechanism involves primarily evaporation;
  • the ink vehicle is liquid at the ejection temperature but solid at room temperature; drying is replaced by solidification; - UV-curable: drying is replaced by photopolymerization .
  • the colorants present in the ink jet ink may be dyes which are molecularly dissolved in the ink fluid, e.g. acid dyes which are bound by a cationic mordant in the ink receiver, or they may be pigments which are finely dispersed in the ink fluid.
  • the methods for producing an information carrier use an information carrier precursor comprising a rigid sheet or support; a receiving layer configuration comprising a single layer or multiple layers, each layer comprising at least one binder and at least one pigment, the receiving layer configuration being opaque and porous and capable of being transparentized by penetration with a vaporizable liquid; a layer or element capable of a machine-readable change upon absorbing radiation; and optionally an opaque element between the side of the receiving layer configuration closer to the support and the support, which may be contiguous or non-contiguous with the side of the receiving layer configuration closer to the support.
  • the information carrier precursor further comprises an opaque element between the side of the receiving layer configuration nearer the support and the support.
  • the receiving layer configuration comprises at least one pigment and at least one binder, wherein at least one constituent layer of the receiving layer configuration is opaque; at least the outermost layer on the image-receiving side or a layer in diffusive contact with the outermost layer on the image-receiving side is opaque and porous; and the receiving layer configuration is capable of being rendered substantially transparent by penetration by a lacquer.
  • Such opaque and porous layers preferably comprise at least one pigment and at least one binder.
  • Multiple layers comprising the receiving layer configuration can be coated or printed simultaneously or sequentially and may have the same or different compositions e.g. to vary the porosity of the individual layers .
  • the receiving layer configuration may be coated onto the support by any conventional coating technique, such as dip coating, knife coating, extrusion coating, spin coating, slide hopper coating and curtain coating, and any conventional printing technique, such as screen printing, offset printing, ink-jet printing, gravure printing and intaglio printing.
  • any conventional coating technique such as dip coating, knife coating, extrusion coating, spin coating, slide hopper coating and curtain coating
  • any conventional printing technique such as screen printing, offset printing, ink-jet printing, gravure printing and intaglio printing.
  • composition of individual layers in the receiving layer configuration can be modified after deposition by coating or printing by, for example, pattern-wise or non-pattern-wise deposition of a substance in a form which can mix with, e.g. upon partial dissolution of the uppermost part of the layer, or diffuse into layer.
  • the constituent receiving layers and the optional supplementary layers used in the information carrier precursor, according to the present invention may further contain well-known conventional ingredients, such as surfactants serving as coating aids, hardening agents, plasticizers, whitening agents and matting agents.
  • surfactants serving as coating aids, hardening agents, plasticizers, whitening agents and matting agents.
  • Suitable surfactants are any of the cationic, anionic, amphoteric, and non-ionic ones as described in JP-A 62-280068 (1987) .
  • surfactants are N-alkylamino acid salts, alkylether carboxylic acid salts, acylated peptides, alkylsulphonic acid salts, alkylbenzene and alkylnaphthalene sulphonic acid salts, sulfosuccinic acid salts, ⁇ -olefin sulphonic acid salts, N- acylsulphonic acid salts, sulphonated oils, alkylsulphonic acid salts, alkylether sulphonic acid salts, alkylallylethersulphonic acid salts, alkylamidesulphonic acid salts, alkylphosphoric acid salts, alkyletherphosphoric acid salts, alkylallyletherphosphoric acid salts, alkyl and alkylallylpolyoxyethylene ethers, alkylallyl- formaldehyde condensed acid salts, alkylallylethersulphonic acid salts, alkylamidesulphonic acid salts, alkyl
  • Useful cationic surfactants include N-alkyl dimethyl ammonium chloride, palmityl trimethyl ammonium chloride, dodecyldimethyl- amine, tetradecyldimethylamine, ethoxylated alkyl guanidine-amine complex, oleamine hydroxypropyl bistrimonium chloride, oleyl imidazoline, stearyl imidazoline, cocamine acetate, palmitamine, dihydroxyethylcocamine, cocotrimonium chloride, alkyl polyglycol- ether ammonium sulphate, ethoxylated oleamine, lauryl pyridinium chloride, N-oleyl-1, 3-diaminopropane, stearamidopropyl dimethylamine lactate, coconut fatty amide, oleyl hydroxyethyl imidazoline, isostearyl ethylimidonium ethosulphate, lauramidopropyl P
  • These surfactants are commercially available from DuPont and 3M.
  • the concentration of the surfactant component in the receiving layer is typically in the range of 0.1 to 2 %, preferably in the range of 0.4 to 1.5 % and is most preferably 0.75 % by weight based on the total dry weight of the layer.
  • the constituent receiving layers may be lightly crosslinked to provide such desired features as waterfastness and non-blocking characteristics.
  • the degree of cross-linking should be such that neither the diffusion of the functional species or functional species precursor nor the penetration of the lacquer should be substantially affected.
  • Crosslinking is also useful in providing abrasion resistance and resistance to the formation of fingerprints on the element as a result of handling.
  • crosslinking agents also known as hardening agents - that will function to crosslink film forming binders. Hardening agents can be used individually or in combination and in free or in blocked form.
  • a great many hardeners, useful for the present invention are known, including formaldehyde and free dialdehydes, such as succinaldehyde and glutaraldehyde, blocked dialdehydes, active esters, sulphonate esters, active halogen compounds, isocyanate or blocked isocyanates, polyfunctional isocyanates, melamine derivatives, s-triazines and diazines, epoxides, active olefins having two or more active bonds, carbodiimides, zirconium complexes, e.g.
  • N-carbamoylpyridinium salts hardeners of mixed function, such as halogen-substituted aldehyde acids (e.g. mucochloric and mucobromic acids) , onium substituted acroleins and vinyl sulphones and polymeric hardeners, such as dialdehyde starches and copoly (acroleinmethacrylic acid), and oxazoline functional polymers, e.g. EPOCROS WS-500, and EPOCROS K-1000 series, and maleic anhydride copolymers, e.g. GANTREZ AN119.
  • halogen-substituted aldehyde acids e.g. mucochloric and mucobromic acids
  • onium substituted acroleins and vinyl sulphones such as dialdehyde starches and copoly (acroleinmethacrylic acid)
  • oxazoline functional polymers e.g.
  • the constituent receiving layers and the optional supplementary layers used in the information carrier precursor, according to the present invention may also comprise a plasticizer such as ethylene glycol, diethylene glycol, propylene glycol, polyethylene glycol, glycerol monomethylether, glycerol monochlorohydrin, ethylene carbonate, propylene carbonate, tetrachlorophthalic anhydride, tetrabromophthalic anhydride, urea phosphate, triphenylphosphate, glycerolmonostearate, propylene glycol monostearate, tetramethylene sulphone, n-methyl-2-pyrrolidone, n-vinyl-2-pyrrolidone .
  • a plasticizer such as ethylene glycol, diethylene glycol, propylene glycol, polyethylene glycol, glycerol monomethylether, glycerol monochlorohydrin, ethylene carbonate, propylene carbonate, tetrachlorophthalic anhydr
  • the constituent receiving layers and the optional supplementary layers used in the information carrier precursor, according to the present invention may also comprise ingredients to improve the lightfastness of the printed image, such as antioxidants, UV- absorbers, peroxide scavengers, singlet oxygen quenchers such as hindered amine light stabilizers, (HALS compounds) .
  • Stilbene compounds are a preferred type of UV-absorber.
  • the receiving layer pigment may be chosen from the inorganic pigments well-known in the art such as silica, talc, clay, hydrotalcite, kaolin, diatomaceous earth, calcium carbonate, magnesium carbonate, basic magnesium carbonate, aluminosilicate, aluminium trihydroxide, aluminium oxide (alumina) , titanium oxide, zinc oxide, barium sulphate, calcium sulphate, zinc sulphide, satin white, boehmite (alumina hydrate), zirconium oxide or mixed oxides.
  • the main pigment is chosen from silica, aluminosilicate, alumina, calcium carbonate, alumina hydrate, and aluminium trihydroxide.
  • the pigment is an inorganic pigment.
  • the pigment is silica.
  • aluminium oxide alumina
  • US 5,041,328 US 5,182,175, US 5,266,383, EP 218956, EP 835762 and EP 972650.
  • aluminium oxide (alumina) examples include (X-AI2O3 types, such as NORTON E700, available from Saint-
  • Gobain Ceramics & Plastics, Inc ⁇ -Al2 ⁇ 3 types, such as ALUMINUM OXID C from Degussa, Other Aluminium oxide grades, such as BAIKALOX CR15 and CR30 from Baikowski Chemie; DURALOX grades and MEDIALOX grades from Baikowski Chemie, BAIKALOX CR80, CR140, CR125, B105CR from Baikowski Chemie; CAB-O-SPERSE PG003 trademark from Cabot, CATALOX GRADES and CATAPAL GRADES from from Sasol, such as PLURALOX HP14/150; colloidal AI2O3 types, such as ALUMINASOL 100; ALUMINASOL 200, ALUMINASOL 220, ALUMINASOL 300, and ALUMINASOL 520 trademarks from Nissan Chemical Industries or NALCO 8676 trademark from ONDEO Nalco.
  • ALUMINUM OXID C from Degussa
  • Other Aluminium oxide grades such as BAIKALOX CR15
  • a useful type of alumina hydrate is ⁇ -AlO (OH), also called boehmite, such as, in powder form, DISPERAL, DISPERAL HP14 and DISPERAL 40 from SASOL, MARTOXIN VPP2000-2 and GL-3 from Martinswerk GmbH.; Liquid boehmite alumina systems, e.g. DISPAL 23N4-20, DISPAL 14N-25, DISPERAL AL25 from SASOL.
  • Patents on alumina hydrate include EP 500021, EP 634286, US 5,624,428, EP 742108, US 6,238,047, EP 622244, EP 810101, etc..
  • Useful aluminium trihydroxides include Bayerite, or ⁇ -Al (OH) 3, such as PLURAL BT, available from SASOL, and Gibbsite, or ⁇ -Al (OH) 3, such as MARTINAL grades from Martinswerk GmbH, MARTIFIN grades, such as MARTIFIN OL104, MARTIFIN OL 107 and MARTIFIN OLlIl from Martinswerk GmbH , MICRAL grades, such as MICRAL 1440, MICRAL 1500; MICRAL 632; MICRAL 855; MICRAL 916; MICRAL 932; MICRAL 932CM; MICRAL 9400 from JM Huber company; HIGILITE grades, e.g.
  • HIGILITE H42 or HIGILITE H43M from Showa Denka K. K., HYDRAL GRADES such as HYDRAL COAT 2, HYDRAL COAT 5 and HYDRAL COAT 7, HYDRAL 710 and HYDRAL PGA, from Alcoa Industrial Chemicals.
  • zirconium oxide is NALCO OOSS008 trademark of ONDEO Nalco, acetate stabilized ZrO2, ZR20/20, ZR50/20, ZR100/20 and ZRYS4 trademarks from Nyacol Nano Technologies.
  • Useful mixed oxides are SIRAL grades from SASOL, colloidal metaloxides from Nalco such as Nalco 1056, Nalco TX10496, Nalco TX11678.
  • Silica as pigment in receiving elements is disclosed in numerous old and recent patents, e.g. US 4,892,591, US 4,902,568, EP 373573, EP 423829, EP 487350, EP 493100, EP 514633, etc..
  • Different types of silica may be used, such as crystalline silica, amorphous silica, precipitated silica, gel silica, fumed silica, spherical and non-spherical silica, calcium carbonate compounded silica such as disclosed in US 5,281,467, and silica with internal porosity such as disclosed in WO 00/02734.
  • the use of calcium carbonate in receiving layers is described in e.g. DE 2925769 and US 5,185,213.
  • alumino-silicate is disclosed in e.g. DE 2925769.
  • Mixtures of different pigments may be used.
  • the main pigment can be chosen from organic particles such as polystyrene, polymethyl methacrylate, silicones, melamine-formaldehyde condensation polymers, urea- formaldehyde condensation polymers, polyesters and polyamides.
  • Mixtures of inorganic and organic pigments can be used. However, most preferably the pigment is an inorganic pigment.
  • the pigment must be present in a sufficient coverage in order to render the receiving layer sufficiently opaque and porous.
  • the lower limit of the ratio by weight of the binder to the total pigment in the receiving layer is preferably about 1:50, most preferably 1:20, while the upper limit thereof is about 2:1, most preferably 1:1. If the amount of the pigment exceeds the upper limit, the strength of the receiving layer itself is lowered, and the resulting image hence tends to deteriorate in rub-off resistance and the like. On the other hand, if the binder to pigment ratio is too great, the ink-absorbing capacity of the resulting receiving layer is reduced, and so the image formed may possibly be deteriorated.
  • the transparentization process is dependent upon the refraction indices of the pigment on the one hand, and of the lacquer which penetrates the receiving layer (see description below) on the other hand should match each other as closely as possible. The closer the match of the refraction indices the better the transparency which will be obtained after impregnation of the receiver layer with the lacquer.
  • the most preferred pigment is a silica type, more particularly an amorphous silica having a average particle size ranging from 1 ⁇ m to 15 ⁇ m, most preferably from 2 to 10 ⁇ m.
  • a most useful commercial compound is the amorphous precipitated silica type SIPERNAT 570, trade name from Degussa Co. It is preferably present in the receiving layer in an amount ranging from 5 g/m to 30 g/m . It has following properties: - specific surface area (N2 absorption) : 750 m /g
  • the receiving layer binder (s) can be water-soluble, solvent soluble or a latex and can be chosen from a list of compounds well- known in the art including hydroxyethyl cellulose; hydroxypropyl cellulose; hydroxyethylmethyl cellulose; hydroxypropyl methyl cellulose; hydroxybutylmethyl cellulose; methyl cellulose; sodium carboxymethyl cellulose; sodium carboxymethylhydroxethyl cellulose; water soluble ethylhydroxyethyl cellulose; cellulose sulphate; polyvinyl alcohol; vinylalcohol copolymers; polyvinyl acetate; polyvinyl acetal; polyvinyl pyrrolidone; polyacrylamide; acrylamide/acrylic acid copolymer; polystyrene, styrene copolymers; acrylic or methacrylic polymers; styrene/acrylic copolymers; ethylene-vinylacetate copolymer; vinylmethyl ether/maleic acid cop
  • a preferred binder for the practice of the present invention is a polyvinylalcohol (PVA) , a vinylalcohol copolymer or modified polyvinyl alcohol.
  • the polyvinyl alcohol is a silanol modified polyvinyl alcohol.
  • Most useful commercially available silanol modified polyvinyl alcohols can be found in the POVAL R polymer series, trade name of Kuraray Co., Japan.
  • This R polymer series includes the grades R-1130, R-2105, R-2130, R-3109, which differ mainly in the viscosity of their respective aqueous solutions.
  • the silanol groups are reactive to inorganic substances such as silica or alumina.
  • R-polymers can be easily crosslinked by changing the pH of their aqueous solutions or by mixing with organic substances and can form water resistant films.
  • the receiving layer configuration comprises at least one latex in at least one receiving layer.
  • the receiving layer configuration comprises at least one latex in at least one receiving layer and the weight ratio of total pigment to total latex is in the range 3:1 to 6.5:1.
  • the information carrier precursor used in the methods for producing an information carrier comprises a layer or element capable of a machine-readable change upon absorbing UV, visible or IR radiation and the methods incorporate a step in which a light source is used to write a pattern in the layer or element capable of a machine-readable change upon absorption of UV, visible or IR radiation.
  • Lasers suitable for realizing the human-readable or machine- readable change are Nd-YAG, carbon dioxide and diode lasers e.g AlGaAs laser diodes.
  • the machine-readable change is an inductive, magnetic or electrical change .
  • the layer or element capable of a machine-readable change upon absorbing IR-radiation comprises a polymer resin.
  • the layer or element capable of a machine-readable change upon absorbing IR-radiation comprises a ferroelectric polymer.
  • the layer or element capable of a machine-readable change upon absorbing IR-radiation comprises an intrinsically conductive polymer e.g. a polythiophene, such as poly (3, 4-ethylenedioxy- thiophene) , a polyaniline, a polyacetylene or a polypyrrole.
  • the layer or element capable of a machine-readable change upon absorbing IR-radiation comprises a metal.
  • the rigid sheet or support comprises at least one layer and/or a multilayer laminate or co-extrudate .
  • suitable co-extrudates are PET/PETG and PET/polycarbonate .
  • the support can be a sheet or web support. According to a seventeenth embodiment of the information carrier precursor, according to the present invention, the support is a web support.
  • the support for use in the present invention can be transparent, translucent or opaque, and can be chosen from paper type and polymeric type supports well-known from photographic technology. Paper types include plain paper, cast coated paper, polyethylene coated paper and polypropylene coated paper. Polymeric supports include cellulose acetate propionate or cellulose acetate butyrate, polyesters such as polyethylene terephthalate and polyethylene naphthalate, polyamides, polycarbonates, polyimides, polyolefins, poly (vinylacetals) , polyethers and polysulfonamides .
  • useful high-quality polymeric supports for the present invention include opaque white polyesters and extrusion blends of polyethylene terephthalate and polypropylene. Polyester film supports and especially polyethylene terephthalate are preferred because of their excellent properties of dimensional stability. When such a polyester is used as the support material, a subbing layer may be employed to improve the bonding of the receiving layer configuration to the support.
  • Useful subbing layers for this purpose are well known in the photographic art and include, for example, polymers of vinylidene chloride such as vinylidene chloride /acrylonitrile/acrylic acid terpolymers or vinylidene chloride/methyl acrylate/itaconic acid terpolymers.
  • the support is coloured or whitened polyvinyl chloride or polyethylene terephthalate or polycarbonate.
  • non-transparentizing lacquer means a liquid under the application conditions, which comprises at least one polymer and/or at least one wax and can solidify upon cooling, become solid upon evaporation of solvent or harden/cross-link upon exposure to heat, moisture or radiation e.g. visible light, UV-radiation and electron beams i.e. is curable which does not transparentize the receiving layer configuration .
  • the substantial penetration of the receiving layer configuration by the non-transparentizing lacquer can be realized by controlling the penetration time and/or the viscosity of the composition.
  • the viscosity of the non-transparentizing lacquer composition is adjusted to ensure rapid penetration and hence rapid permanent opacity.
  • the non-transparentized areas of the receiving layer configuration are penetrated with a non- transparentizing lacquer.
  • the non-transparentizing lacquer is a curable lacquer e.g. thermally curable, electron beam curable or photopolymerizable .
  • the lacquer is a radiation curable lacquer.
  • the non-transparentizing lacquer is a photopolymerizable lacquer . Avoidance of transparentization depends upon the refraction indices of the pigment and of the lacquer which penetrates the receiving layer configuration not matching each other with the refractive index difference being greater than 0.12. Therefore, the choice of ingredients for the lacquer has to be such as to fulfil this requirement. Additional constraints on the composition of the lacquer are determined by whether the non-transparentizing lacquer is required to be curable and if curable which curing process has been selected.
  • the refractive index of the pigment and the refractive index of the non- transparentizing lacquer differ by more than 0.12.
  • the refractive index of curable lacquers based on styrenes are typically ca . 1.60 and hence the use of such compositions as lacquers, according to the present invention, will provide a good match with the refractive index of SIPERNAT 570 with a refractive index of 1.45 to 1.47, and hence no transparency is obtained. Lacquers with even higher refractive indices are possible e.g. those including N-vinyl carbazole as comonomer.
  • acrylate/methacrylate-based lacquers with a refractive index of 1.47 to 1.49 with receiving layer configurations comprising a porous alumina pigment such as MARTINOX GL-I with a refractive index of 1.6 also ensures that no transparency is obtained.
  • the transparentization process depends upon the refractive index of the pigment in the opaque and porous layer and the refractive index of the lacquer which penetrates the opaque and porous constituent layer or layers of the receiving layer configuration matching each other as closely as possible.
  • Additional constraints on the composition of the lacquer are determined by whether the lacquer is required to be curable and if curable which curing process has been selected.
  • the refractive index of the pigment and the refractive index should differ by no more than 0.1, preferably by not more than 0.04 and particularly preferably by no more than 0.02. Refractive indices of representative polymers are given below:
  • UV-curable lacquers such as acrylate/methacrylate-based lacquers
  • the substantial penetration of the receiving layer configuration by the transparentizing lacquer can be realized by controlling the penetration time and/or the viscosity of the composition.
  • the viscosity of the transparentizing lacquer is adjusted to ensure rapid penetration and hence rapid transparent!zation.
  • the transparentizing lacquer is preferably a curable lacquer e.g. thermally curable, electron beam curable or photopolymerizable, with a radiation curable lacquer being preferred and a photopolymerizable lacquer being particularly preferred.
  • a curable lacquer e.g. thermally curable, electron beam curable or photopolymerizable, with a radiation curable lacquer being preferred and a photopolymerizable lacquer being particularly preferred.
  • An essential ingredient of a curable lacquer is at least one monomer.
  • the lacquer will further contain at least one photoinitiator .
  • Suitable monomers for use in curable lacquers include the monomers disclosed in DE-OS 4005231, DE-OS 3516256, DE-OS 3516257, DE-OS 3632657 and US 4,629,676, unsaturated esters of polyols, particularly such esters of the OC-methylene carboxylic acids, e.g.
  • divinyl succinate divinyl adipate, divinyl phthalate, divinyl butane-1, 4-disulphonate; and unsaturated aldehydes, e.g. sorbaldehyde (hexadienal) .
  • Curable lacquers may also comprise polymers and/or oligomers comprising two or more different polymerizable functions, e.g. acrylated epoxies, polyester acrylates, urethane acrylates, etc. It is also possible to use monofunctional (meth) acrylic acid esters as monomer provided they are not too volatile and do not spread an unwanted odour. Suitable compounds include n-octylacrylate, decylacrylate, decylmethacrylate, stearylacrylate, stearylmethacrylate, cyclohexylaerylate, cyclohexylmethacrylate, phenylethylacrylate, phenylethylmethacrylate .
  • the most preferred compounds comprise one or more (meth) acrylate functional groups.
  • Preferred monomers for use in UV-curable photopolymerizable compositions have at least one (meth) acrylate functional group, such as those disclosed in EP-A 0 502 562.
  • photoinitiators include all compounds or compound combinations known for this purpose. Examples are benzoin ethers, benzil ketals, polycyclic quinones, benzophenone derivatives, triarylimidazolyl dimers, photosensitive trihalomethyl compounds, for example trichloromethyl-s-triazines .
  • Preferred photoinitiators are the 2,3- bisarylquinoxalines, as disclosed in US-A 3,765,898, and 2-aryl-4,6- bistrichloromethyl-s-triazines .
  • the amount of photoinitiator or photoinitiator combination is generally between 1 and 25% by weight of the photopolymerizable composition and preferably between 5 and 15% by weight.
  • Photopolymerizable lacquers may also contain a minor amount of a heat polymerization inhibitor which prevents premature polymerization before the UV curing step.
  • a heat polymerization inhibitor which prevents premature polymerization before the UV curing step.
  • examples of such inhibitors include p-methoxyphenol, hydroquinone, aryl- or alkyl substituted hydroquinone, t-butylcatechol, pyrogallol, copper (I) chloride, phenothiazine, chloranil, naphtylamine, OC-naphthol, 2,6- di-t-butyl-p-cresol, etc.
  • a preferred polymerization inhibitor is 2-methyl hydroquinone.
  • the heat polymerization inhibitors are preferable used in an amount of 0.001 to 5 parts by weight per 100 parts of monomer.
  • Curable lacquers may optionally contain a minor amount of organic solvent, e.g. ethyl acetate.
  • Suitable solvents for use in the transparentizing curable compositions used in the method for producing an information carrier, according to the present invention include the following commercially available compounds (chemical and commercial names) .
  • the lacquer further contains at least one colorant e.g. a dye or a pigment.
  • the information carrier is an identification card selected from the group consisting of an identity card, a security card, a driver' s licence card, a social security card, a health card, a membership card, a time registration card, a bank card, a pay card and a credit card.
  • the finished ID card can serve as an identity card, a security card, a driver' s licence card, a social security card, a bank card, a membership card, a time registration card, a pay card and a credit card, etc.
  • the finished ID card may comprise additional security elements or information carriers such as a hologram, a magnetic strip, or a chip ("smart cards”) .
  • the information carrier is in the form of a flexible sheet e.g. any page of a passport or a page of a passport with personalized data of the bearer.
  • the information carrier is an admission document e.g. a visa, a ticket for an event and lottery tickets.
  • the method for producing an information carrier can be utilized in the security field not only encompassing personalized documents such as passports, driving licenses, identity cards (ID cards) and admission documents such as visa's and entry tickets, but also the authentification and identification of goods to avoid counterfeiting, tampering and fraud such as lottery tickets, share certificates, transaction documents, labels on luggage and the packaging of pharmaceuticals and high value products in general.
  • personalized documents such as passports, driving licenses, identity cards (ID cards) and admission documents such as visa's and entry tickets
  • authentification and identification of goods to avoid counterfeiting, tampering and fraud such as lottery tickets, share certificates, transaction documents, labels on luggage and the packaging of pharmaceuticals and high value products in general.
  • SyloidTM W300 a colloidal silica from GRACE GMBH 75.6 g
  • PovalTM PVA R3109 a silanol modified polyvinyl alcohol from 2.3 g KURARAY CO.
  • CatflocTM T2 a cationic polyelectrolyte from CALGON EUROPE 5.6 g
  • Citric acid 0.3 g
  • PolysolTM EVA P-550 a 50% aqueous emulsion of an ethylene-vinyl 100 g acetate-vinyl versatate copolymer from SHOWA HIGH POLYMER CO.
  • AerosolTM OT a surfactant from CYTEC 1.5 g
  • TergitolTM 4 a surfactant from UNION CARBIDE i g
  • the photosensitive elements used in INVENTION EXAMPLE 2 were prepared by coating the solution in Table 3 below onto polyethylene paper to a wet thickness of 100 ⁇ m. After allowing the layers to dry for 2 minutes at room temperature the layers were dried in a drying cupboard at 50 °C for 3 minutes.
  • Photosensitive elements 1 to 3 were exposed through a grey level wedge with a constant of 0.15 with different light sources and different exposure times: 180s and 360s in contact with a UV-A lightbox with 8 Philips TL 20W/10UVA tubes, 600s in contact with a DL3000SP UV-source in vacuum and 300s with the DL3000SP but under glass and very near the lamp.
  • the optical densities before and after the different exposures were measured in transmission through a red filter with a Macbeth RD918-SB densitometer. The results are summarized in Table 4.
  • a sandwich was realized by placing the uncoated side of the sheet with the porous layer on the coated side of photosensitive element and after application of a droplet of liquid placing a 23 ⁇ m thick PET-film over the porous layer.
  • Photosensitive element 1 in the sandwich was then exposed for 300s on the UVA lightbox with 8 Philips TL 20W/10UVA tubes. This experiment was carried out twice and the optical density of photosensitive element 1 after exposure measured through a red filter in transmission with a Macbeth RD918- SB densitometer. The optical densities realized with the different liquids in the two experiments are given in Table 6.
  • security information can be applied using a light- source, such as a laser, in a layer or pattern beneath a porous layer, by applying the security information with the porous layer in a temporarily transparentized state and then rendering the porous layer opaque so that the added security information cannot be visually detected.
  • a light- source such as a laser
  • Such information could, for example, be inductively readable information and the pattern beneath the porous layer could be a pattern of an intrinsically conductive polymer, such as poly (3, 4-ethylenedioxythiophene) (PEDOT).
  • a lOO ⁇ m thick sheet of transparent polyethylene terephthalate subbed with subbing layer 1 was coated with the porous receiver layer dispersion with the composition given in Table 1 of INVENTION EXAMPLE 1 using a 100 ⁇ m wirebar followed by drying at 50 °C producing an opaque porous layer with a layer thickness of 22 ⁇ m and an optical density of 0.19 measured with a MacBeth RB918-SB densitometer with a visible filter and with a black sheet of cardboard with a density of 1.35 placed under the transparent polyethylene terephthalate support.
  • security information can be applied using a light- source, such as a laser, in a layer or pattern beneath a porous layer, by applying the security information with the porous layer in a temporarily transparentized state and then rendering the porous layer opaque so that the added security information cannot be visually detected.
  • a light- source such as a laser
  • Such information could, for example, be inductively readable information and the pattern beneath the porous layer could be a pattern of an intrinsically conductive polymer, such as poly (3, 4-ethylenedioxythiophene) (PEDOT) .

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Credit Cards Or The Like (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

L'invention concerne un procédé de fabrication d'un support d'informations, lequel procédé comprend les étapes consistant à : (1) se procurer un précurseur de support d'informations comprenant une feuille rigide ou un support rigide ; une configuration de couches de réception ayant un côté de réception d'image et un côté de non-réception d'image, la configuration de couches de réception comprenant au moins un pigment et au moins un liant, au moins une couche de constituant de la configuration de couches de réception étant opaque ; au moins la couche la plus à l'extérieur du côté de réception d'image ou une couche en contact de diffusion avec la couche la plus à l'extérieur sur le côté de réception d'image est opaque et poreuse ; et la configuration de couches de réception est capable d'être rendue sensiblement transparente par pénétration d'une laque ; et une couche ou un élément, ou un motif dans la couche ou l'élément, capable d'un changement lisible par une machine lors de l'absorption d'un rayonnement ultraviolet, visible ou infrarouge, la couche ou l'élément étant soit la surface de la feuille rigide ou du support rigide, soit interposé entre la feuille rigide ou le support rigide et le côté de non-réception d'image de la configuration de couches de réception ; (2) augmenter, au moins partiellement, selon un motif ou d'un seul tenant, la transparence de la configuration de couches de réception avec un liquide vaporisable, fournissant ainsi un motif transparent sur la couche de réception rendue au moins partiellement transparente ; (3) utiliser une source lumineuse pour inscrire un motif ou modifier le motif dans la couche ou l'élément capable d'un changement lisible par une machine lors de l'absorption d'un rayonnement ultraviolet, visible ou infrarouge, après une transmission à travers au moins une partie des zones rendues transparentes de la configuration de couches de réception ; faire évaporer le liquide vaporisable ; et, après que le liquide vaporisable a été évaporé selon un motif ou d'un seul tenant, rendre la configuration de couches de réception, de façon permanente, au moins partiellement non transparente avec une laque n'augmentant pas la transparence, produisant ainsi un support d'informations.
PCT/EP2007/053837 2006-12-07 2007-04-19 Procédé de fabrication d'un support d'informations WO2008068054A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP07728297A EP2091753B1 (fr) 2006-12-07 2007-04-19 Procédé de fabrication d'un support d'informations
AT07728297T ATE465020T1 (de) 2006-12-07 2007-04-19 Verfahren zur herstellung eines informationsträgers
DE602007006050T DE602007006050D1 (de) 2006-12-07 2007-04-19 Verfahren zur herstellung eines informationsträgers
CN200780045086.8A CN101595000B (zh) 2006-12-07 2007-04-19 制造信息载体的方法

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US86960906P 2006-12-12 2006-12-12
US86960706P 2006-12-12 2006-12-12
US86960206P 2006-12-12 2006-12-12
US60/869,607 2006-12-12
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DE102015107829A1 (de) * 2015-05-19 2016-11-24 Delfortgroup Ag Umhüllungspapier mit durchscheinenden Bereichen
DE102015107829B4 (de) * 2015-05-19 2017-06-14 Delfortgroup Ag Umhüllungspapier, Verfahren zu dessen Herstellung und Zigarette mit einem Umhüllungspapier

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ATE465020T1 (de) 2010-05-15
US7939124B2 (en) 2011-05-10
DE602007006050D1 (de) 2010-06-02
EP2091753A1 (fr) 2009-08-26
US20080136161A1 (en) 2008-06-12
EP2091753B1 (fr) 2010-04-21

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