WO2008034204A3 - Croissance de nanotubes de carbone au moyen de nanoparticules sans métal - Google Patents

Croissance de nanotubes de carbone au moyen de nanoparticules sans métal Download PDF

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Publication number
WO2008034204A3
WO2008034204A3 PCT/BE2007/000109 BE2007000109W WO2008034204A3 WO 2008034204 A3 WO2008034204 A3 WO 2008034204A3 BE 2007000109 W BE2007000109 W BE 2007000109W WO 2008034204 A3 WO2008034204 A3 WO 2008034204A3
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WO
WIPO (PCT)
Prior art keywords
metal
carbon nanotubes
growth
nanoparticles
free nanoparticles
Prior art date
Application number
PCT/BE2007/000109
Other languages
English (en)
Other versions
WO2008034204A2 (fr
Inventor
Caroline Whelan
Santiago Cruz Esconjauregui
Original Assignee
Imec Inter Uni Micro Electr
Nanocyl Sa
Caroline Whelan
Santiago Cruz Esconjauregui
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imec Inter Uni Micro Electr, Nanocyl Sa, Caroline Whelan, Santiago Cruz Esconjauregui filed Critical Imec Inter Uni Micro Electr
Priority to EP07815688A priority Critical patent/EP2069234A2/fr
Priority to US12/441,132 priority patent/US20100047152A1/en
Priority to JP2009528558A priority patent/JP2010504268A/ja
Publication of WO2008034204A2 publication Critical patent/WO2008034204A2/fr
Publication of WO2008034204A3 publication Critical patent/WO2008034204A3/fr

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/16Preparation
    • C01B32/162Preparation characterised by catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20Carbon compounds
    • B01J27/22Carbides
    • B01J27/224Silicon carbide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Catalysts (AREA)

Abstract

La présente invention concerne un procédé permettant de former au moins un nanotube de carbone (16) au moyen de nanoparticules de catalyseur sans métal (14), par exemple des nanoparticules comprenant Si ou Ge. Ce procédé consiste à décomposer un gaz source carbonique de façon à former des fragments de carbone qui sont ensuite recombinés au niveau des nanoparticules de catalyseur sans métal (14) afin de faire croître les nanotubes de carbone (16). Le procédé selon certains modes de réalisation de l'invention donne des nanotubes de carbone (16) qui ne comprennent pas d'impuretés métalliques.
PCT/BE2007/000109 2006-09-21 2007-09-21 Croissance de nanotubes de carbone au moyen de nanoparticules sans métal WO2008034204A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP07815688A EP2069234A2 (fr) 2006-09-21 2007-09-21 Croissance de nanotubes de carbone au moyen de nanoparticules sans métal
US12/441,132 US20100047152A1 (en) 2006-09-21 2007-09-21 Growth of carbon nanotubes using metal-free nanoparticles
JP2009528558A JP2010504268A (ja) 2006-09-21 2007-09-21 メタルフリーナノ粒子を用いたカーボンナノチューブの成長

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US84655806P 2006-09-21 2006-09-21
US60/846,558 2006-09-21

Publications (2)

Publication Number Publication Date
WO2008034204A2 WO2008034204A2 (fr) 2008-03-27
WO2008034204A3 true WO2008034204A3 (fr) 2008-11-27

Family

ID=39200861

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/BE2007/000109 WO2008034204A2 (fr) 2006-09-21 2007-09-21 Croissance de nanotubes de carbone au moyen de nanoparticules sans métal

Country Status (4)

Country Link
US (1) US20100047152A1 (fr)
EP (1) EP2069234A2 (fr)
JP (1) JP2010504268A (fr)
WO (1) WO2008034204A2 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2937895A1 (fr) * 2008-11-04 2010-05-07 Commissariat Energie Atomique Moule presentant une surface nanostructuree pour realiser des pieces polymeres nanostructurees et procede de fabrication d'un tel moule.
WO2011014258A2 (fr) * 2009-07-31 2011-02-03 Massachusetts Institute Of Technology Systèmes et procédés associés à la formation de nanostructures à base de carbone
US20110162957A1 (en) * 2009-11-25 2011-07-07 Massachusetts Institute Of Technology Systems and methods for enhancing growth of carbon-based nanostructures
WO2012091789A1 (fr) 2010-10-28 2012-07-05 Massachusetts Institute Of Technology Formation de nanostructure à base de carbone à l'aide de structures de croissance active à grande échelle
US20130072077A1 (en) 2011-09-21 2013-03-21 Massachusetts Institute Of Technology Systems and methods for growth of nanostructures on substrates, including substrates comprising fibers
US9440855B2 (en) * 2012-02-13 2016-09-13 Osaka University High purity carbon nanotube, process for preparing the same and transparent conductive film using the same
JP6373284B2 (ja) 2013-02-28 2018-08-15 エヌ12 テクノロジーズ, インク.N12 Technologies, Inc. ナノ構造フィルムのカートリッジベース払い出し
WO2014150944A1 (fr) 2013-03-15 2014-09-25 Seerstone Llc Procédés de production d'hydrogène et de carbone solide
WO2014151144A1 (fr) * 2013-03-15 2014-09-25 Seerstone Llc Reduction d'oxyde de carbone par des catalyseurs intermetalliques et de carbure
US10086349B2 (en) 2013-03-15 2018-10-02 Seerstone Llc Reactors, systems, and methods for forming solid products
EP3129133A4 (fr) 2013-03-15 2018-01-10 Seerstone LLC Systèmes de production de carbone solide par réduction d'oxydes de carbone
ES2900814T3 (es) 2013-03-15 2022-03-18 Seerstone Llc Electrodos que comprenden carbono nanoestructurado
WO2018022999A1 (fr) 2016-07-28 2018-02-01 Seerstone Llc. Produits solides en carbone comprenant des nanotubes de carbone comprimés dans un récipient et procédés pour leur formation
CN113213454B (zh) * 2021-04-21 2022-06-24 温州大学 以石墨烯为催化剂制备单壁碳纳米管的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040101468A1 (en) * 2002-11-21 2004-05-27 Liang Liu Carbon nanotube array and method for forming same
WO2006061599A2 (fr) * 2004-12-07 2006-06-15 University Of Southampton Procede de fabrication de nanotubes de carbone

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7132161B2 (en) * 1999-06-14 2006-11-07 Energy Science Laboratories, Inc. Fiber adhesive material
GB0226590D0 (en) * 2002-11-14 2002-12-24 Univ Cambridge Tech Method for producing carbon nanotubes and/or nanofibres
US20050207964A1 (en) * 2004-03-22 2005-09-22 Dojin Kim Method for synthesizing carbon nanotubes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040101468A1 (en) * 2002-11-21 2004-05-27 Liang Liu Carbon nanotube array and method for forming same
WO2006061599A2 (fr) * 2004-12-07 2006-06-15 University Of Southampton Procede de fabrication de nanotubes de carbone

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
D. TAGAKI, H. HIBINO, S. SUZUKI, Y. KOBAYASHI, Y. HOMMA: "Carbon Nanotube Growth from Semiconductor Nanoparticles", NANO LETTERS, vol. 7, no. 8, 19 July 2007 (2007-07-19), pages 2272 - 2275, XP002497374 *
M. H. RÜMMELI, C. KRAMBERGER, A. GRÜNEIS, P. AYALA, T. GEMMING, B. BÜCHNER, T. PICHLER, CHEMISTRY OF MATERIALS, vol. 19, no. 17, 27 July 2007 (2007-07-27), pages 4105 - 4107, XP002497375 *
UCHINO T ET AL: "Ge-catalyzed Vapour-Liquid-Solid growth of Carbon Nanotubes", SOLID-STATE DEVICE RESEARCH CONFERENCE, 2006. ESSDERC 2006. PROCEEDING OF THE 36TH EUROPEAN, IEEE, PI, 1 September 2006 (2006-09-01), pages 214 - 217, XP031047031, ISBN: 978-1-4244-0301-1 *

Also Published As

Publication number Publication date
US20100047152A1 (en) 2010-02-25
EP2069234A2 (fr) 2009-06-17
WO2008034204A2 (fr) 2008-03-27
JP2010504268A (ja) 2010-02-12

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